Nucleating agent composition, olefin resin composition, molded article thereof, and method for producing olefin resin composition

Abstract

The present invention relates to a nucleating agent composition, an olefin resin composition, a molded article thereof, and a method for producing the olefin resin composition. Provided are: a nucleating agent composition which is capable of providing a molded article that imparts excellent crystallinity to an olefin resin and has excellent mechanical properties and transparency; an olefin resin composition; a molded article thereof; and a method for producing the olefin resin composition. The nucleating agent composition according to the present invention contains a nucleating agent and an auxiliary agent, and the nucleating agent contains an aromatic phosphate metal salt represented by general formula (1) (in general formula (1), R1 to R4 each represent an alkyl group having 1 to 6 carbon atoms, R5 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, n represents 1 or 2, M represents lithium or dihydroxy aluminum when n is 1, and M represents hydroxy aluminum when n is 2). The auxiliary agent is at least one selected from the group consisting of water and polyol compounds, and the content of the auxiliary agent is 1-10000 parts by mass per 100 parts by mass of the nucleating agent. # imgabs0 #

Description

[0001] This application is a divisional application of an application with a filing date of January 21, 2020, an application number of 202080010046.5, and an invention name of “Nucleating agent composition, olefin resin composition, molded article thereof, and method for producing olefin resin composition”. Technical Field

[0002] The present invention relates to a nucleating agent composition, an olefin resin composition (hereinafter also referred to as "resin composition"), a molded product thereof and a method for producing an olefin resin composition. More specifically, the present invention relates to a nucleating agent composition, an olefin resin composition, a molded product thereof and a method for producing an olefin resin composition, which can provide an olefin resin with excellent crystallinity and a molded product having excellent mechanical properties and transparency. Background Art

[0003] Olefin resins such as polyethylene, polypropylene and polybutene-1 are inexpensive and have excellent properties such as molding processability, sanitation, heat resistance, chemical resistance, mechanical properties, and low specific gravity. They are widely used in various molded bodies such as building materials, automotive materials, home electrical and electronic materials, fiber materials, packaging materials, agricultural materials, housing materials for home appliances, daily necessities, medical equipment, food containers, beverage containers, films, sheets, and structural parts. However, olefin resins have problems such as slow crystallization rate after heat molding and long molding cycle during processing.

[0004] In order to improve the crystallinity of olefin resins, nucleating agents are currently added to rapidly generate fine crystals. In addition, it is known that the addition of nucleating agents can improve the transparency or mechanical properties of molded products formed by molding olefin resins.

[0005] As nucleating agents for improving the crystallinity of olefin resins, for example, carboxylic acid metal salts, aromatic phosphate metal salts, benzylidene sorbitol compounds, amide compounds, rosin acid metal salts, talc, etc. are used. Among them, carboxylic acid metal salts such as sodium benzoate, 4-tert-butylbenzoic acid aluminum salt, sodium adipate, and disodium bicyclo[2.2.1]heptane-2,3-dicarboxylate, 2,2'-methylenebis(4,6-di-tert-butylphenyl) phosphate sodium, 2,2'-methylenebis(4,6-di-tert-butylphenyl) phosphate lithium, bis[2,2'-methylenebis(4,6-di-tert-butylphenyl) phosphate] basic aluminum, dibenzylidene sorbitol, bis(methylbenzylidene) sorbitol, and bis(methylbenzylidene) sorbitol are also known. Benzylidene sorbitol compounds such as bis(3,4-dimethylbenzylidene) sorbitol, bis(p-ethylbenzylidene) sorbitol and bis(dimethylbenzylidene) sorbitol, and amide compounds such as N,N',N"-tri[2-methylcyclohexyl]-1,2,3-propanetricarboxamide, N,N',N"-tricyclohexyl-1,3,5-benzenetricarboxamide, N,N'-dicyclohexylnaphthalene dicarboxamide and 1,3,5-tri(2,2-dimethylpropionamide)benzene.

[0006] In recent years, the diversification of applications has led to a demand for further improvement in the performance of molded articles formed from olefin resin compositions. However, simply adding a known nucleating agent is not sufficient, and research is ongoing on new methods for improving the performance of molded articles formed from olefin resin compositions.

[0007] For example, Patent Documents 1 and 2 describe methods for producing an olefin resin composition, comprising preparing an olefin resin composition containing a nucleating agent by polymerizing an olefin monomer in the presence of a nucleating agent, and then adding water to the olefin resin composition containing the nucleating agent.

[0008] Prior art literature

[0009] Patent Literature

[0010] Patent Document 1: Japanese Patent Application Publication No. 2014-095046

[0011] Patent Document 2: Japanese Patent Application Publication No. 2017-125116 Summary of the invention

[0012] Problem that the invention aims to solve

[0013] However, there is still room for improvement in mechanical properties and transparency of molded articles made of olefin resin compositions produced by the production methods described in Patent Documents 1 or 2.

[0014] Among them, the purpose of the present invention is to provide: a nucleating agent composition, an olefin resin composition, a molded product thereof, and a method for producing an olefin resin composition that can provide an olefin resin with excellent crystallinity and obtain a molded product having excellent mechanical properties and transparency.

[0015] Solutions for solving problems

[0016] The present inventors have conducted detailed studies to solve the above problems and have found that the physical properties of a molded article formed from an olefin resin composition can be significantly improved by using a combination of a specific aromatic phosphate metal salt and a specific auxiliary agent, thereby completing the present invention.

[0017] That is, the nucleating agent composition of the present invention is characterized in that it contains a nucleating agent and an auxiliary agent, and the nucleating agent contains an aromatic phosphate metal salt represented by the following general formula (1):

[0018]

[0019] (In general formula (1), R 1 ~R 4 represents an alkyl group having 1 to 6 carbon atoms, R 5 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, n represents 1 or 2, when n is 1, M represents lithium or dihydroxyaluminum, and when n is 2, M represents hydroxyaluminum.

[0020] The auxiliary agent is at least one selected from the group consisting of water and polyol compounds, and the content of the auxiliary agent is 1 to 10000 parts by mass based on 100 parts by mass of the nucleating agent.

[0021] In the nucleating agent composition of the present invention, it is preferred that the polyol compound be at least one selected from the group consisting of glycols, sugar alcohols, monofatty acid esters of sugar alcohols, and polyvinyl alcohol.

[0022] In addition, the olefin resin composition of the present invention is characterized in that it contains an olefin resin, a nucleating agent and an auxiliary agent, and the nucleating agent contains an aromatic phosphate metal salt represented by the following general formula (1):

[0023]

[0024] (In general formula (1), R 1 ~R 4 represents an alkyl group having 1 to 6 carbon atoms, R 5 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, n represents 1 or 2, when n is 1, M represents lithium or dihydroxyaluminum, and when n is 2, M represents hydroxyaluminum.

[0025] The auxiliary agent is at least one selected from the group consisting of water and polyol compounds,

[0026] The nucleating agent is contained in an amount of 0.001 to 5 parts by mass and the auxiliary agent is contained in an amount of 0.003 to 10 parts by mass based on 100 parts by mass of the olefin-based resin.

[0027] In the olefin resin composition of the present invention, it is preferred that the polyol compound be at least one selected from the group consisting of glycols, sugar alcohols, monofatty acid esters of sugar alcohols, and polyvinyl alcohol.

[0028] The molded article of the present invention is characterized by being obtained by molding the olefin-based resin composition of the present invention.

[0029] The method for producing an olefin resin composition of the present invention is characterized in that the method comprises:

[0030] a preparation step of preparing an olefin resin that does not contain a nucleating agent component; and

[0031] a compounding step of compounding a nucleating agent and an auxiliary agent into the olefin resin not containing a nucleating agent component prepared in the preparation step to obtain an olefin resin compound;

[0032] The nucleating agent comprises an aromatic phosphate metal salt represented by the following general formula (1):

[0033]

[0034] (In general formula (1), R 1 ~R 4 represents an alkyl group having 1 to 6 carbon atoms, R 5 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, n represents 1 or 2, when n is 1, M represents lithium or dihydroxyaluminum, and when n is 2, M represents hydroxyaluminum.

[0035] The auxiliary agent is at least one selected from the group consisting of water and polyol compounds,

[0036] In the mixing step, 0.001 to 5 parts by mass of the nucleating agent and 0.003 to 10 parts by mass of the auxiliary agent are mixed with respect to 100 parts by mass of the olefin resin not containing the nucleating agent component.

[0037] The method for producing an olefin resin composition of the present invention preferably further comprises a melt-kneading step of melt-kneading the olefin resin blend obtained in the above-mentioned blending step to obtain the olefin resin composition.

[0038] In the method for producing an olefin resin composition of the present invention, it is preferred that the polyol compound is at least one selected from the group consisting of glycols, sugar alcohols, monofatty acid esters of sugar alcohols, and polyvinyl alcohol.

[0039] Effects of the Invention

[0040] According to the present invention, there can be provided a nucleating agent composition, an olefin resin composition, a molded article thereof, and a method for producing an olefin resin composition that imparts excellent crystallinity to an olefin resin and can provide a molded article having excellent mechanical properties and transparency. DETAILED DESCRIPTION

[0041] The following is a detailed description of the embodiments of the present invention. First, the nucleating agent composition of the present invention is described. The nucleating agent composition of the present invention contains a nucleating agent and an auxiliary agent. Among them, the nucleating agent contains an aromatic phosphate metal salt represented by the following general formula (1), and the auxiliary agent is at least one selected from the group consisting of water and polyol compounds. For the nucleating agent composition of the present invention, the content of the auxiliary agent is 1 to 10000 parts by mass relative to 100 parts by mass of the nucleating agent.

[0042]

[0043] Among them, in the general formula (1), R 1 ~R 4 represents an alkyl group having 1 to 6 carbon atoms, R 5 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and n represents 1 or 2. When n is 1, M represents lithium or dihydroxyaluminum, and when n is 2, M represents hydroxyaluminum.

[0044] The nucleating agent composition of the present invention can impart excellent crystallinity to an olefinic resin. In addition, the nucleating agent composition of the present invention can provide a molded article made of an olefinic resin having excellent mechanical properties and transparency.

[0045] As described above, the nucleating agent composition of the present invention contains a nucleating agent, and the nucleating agent contains a phosphoric acid ester metal salt represented by the general formula (1). 1 ~R 4 The alkyl group having 1 to 6 carbon atoms as represented by the general formula (1) may be, for example, methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, tert-butyl, isobutyl, pentyl, isopentyl, tert-pentyl, hexyl, 2-hexyl, 3-hexyl, etc. Among these, tert-butyl is preferred because of its excellent nucleating agent effect. 5 Examples of the alkyl group having 1 to 3 carbon atoms include methyl group, ethyl group, propyl group and isopropyl group.

[0046] Specific examples of the aromatic phosphoric acid ester metal salt represented by the general formula (1) include compounds represented by the following chemical formula.

[0047]

[0048] The nucleating agent contained in the nucleating agent composition of the present invention may contain a compound different from the aromatic phosphoric acid ester metal salt represented by the general formula (1). Examples of the compound different from the aromatic phosphoric acid ester metal salt represented by the general formula (1) include sodium 2,2'-methylenebis(4,6-di-tert-butylphenyl)phosphate, sodium benzoate, aluminum 4-tert-butylbenzoate, sodium adipate, disodium bicyclo[2.2.1]heptane-2,3-dicarboxylate, calcium cyclohexane-1,2-dicarboxylate and other carboxylic acid metal salts, N,N',N"-tris[2-methylcyclohexyl]-1,2,3-propanetricarboxamide, N,N',N"-tricyclohexyl-1,3,5-benzenetricarboxamide, N,N'-dicyclohexylnaphthalene dicarboxamide, 1,3,5-tris(dimethylisopropionylamino)benzene and other amide compounds. When the compound different from the aromatic phosphate metal salt represented by the general formula (1) is added, the total amount of the aromatic phosphate metal salt represented by the general formula (1) and the compound different from the aromatic phosphate metal salt represented by the general formula (1) is 0.001 to 5 parts by mass, preferably 0.005 to 5 parts by mass, and more preferably 0.01 to 1 part by mass, relative to 100 parts by mass of the olefin resin. It should be noted that the proportion of the aromatic phosphate metal salt represented by the general formula (1) in the total amount of the aromatic phosphate metal salt represented by the general formula (1) and the compound different from the aromatic phosphate metal salt represented by the general formula (1) is preferably 50% by mass or more, more preferably 60% by mass or more, further preferably 95% by mass or more, and particularly preferably 100% by mass.

[0049] As described above, the nucleating agent composition of the present invention contains an auxiliary agent, and the auxiliary agent is at least one selected from the group consisting of water and polyol compounds.

[0050] Examples of water include tap water, industrial water, purified water, etc. Examples of purified water include ion exchange water, ultrafiltration water, reverse osmosis water, distilled water, and the like.

[0051] The polyol compound is a compound having two or more hydroxyl groups. Specific examples of the polyol compound include 1,2-ethanediol, 1,3-propylene glycol, 1,2-propylene glycol, 1,4-butylene glycol, 1,3-butylene glycol, neopentyl glycol, diethylene glycol, triethylene glycol, polyethylene glycol, dipropylene glycol, tripropylene glycol, polypropylene glycol, cyclobutanediol, cyclopentanediol, cyclohexanediol, cycloheptanediol, cyclooctanediol, cyclohexanedimethanol, tricyclohexanedimethanol, tricyclodecane dimethanol, hydroxypropyl cyclohexanol, tricyclo[5,2,1,0,2,6]decane-dimethanol. , bicyclo[4,3,0]-nonanediol, bicyclohexanediol, tricyclo[5,3,1,1]dodecanediol, bicyclo[4,3,0]nonane dimethanol, tricyclo[5,3,1,1]dodecane-diethanol, hydroxypropyl tricyclo[5,3,1,1]dodecane alcohol, spiro[3,4]octanediol, butyl cyclohexanediol, 1,1'-bicyclohexylene glycol, 4,4'-isopropyl-bicyclohexanol, 4,4'-oxybicyclohexanol, bis(4-hydroxycyclohexyl)methane and other glycols, glycerol, erythrose methylol, pentaerythritol, dipentaerythritol, sorbitol, xylitol, maltitol, lactitol, mannitol, isomalt and other sugar alcohols, mono-fatty acid esters formed by these sugar alcohols and fatty acids such as myristic acid, palmitic acid, stearic acid, oleic acid, 12-hydroxystearic acid, etc., polyvinyl alcohol, polycaprolactone triol, cyclohexanetriol, trimethylolethane, trimethylolpropane, ditrimethylolpropane and other linear, branched or cyclic aliphatic polyols having three or more hydroxyl groups, cyclohexanediol, dihydroxybenzene, benzenetriol, hydroxy Aromatic polyols such as benzyl alcohol, dihydroxytoluene, 4,4'-oxybisphenol, 4,4'-dihydroxybenzophenone, 4,4'-thiobisphenol, phenolphthalein, bis(4-hydroxyphenyl)methane, 4,4'-(1,2-ethynyl)bisphenol, 4,4'-sulfonylbisphenol, 4,4'-isopropylidenebis(2,6-dibromophenol), 4,4'-isopropylidenebis(2,6-dichlorophenol), 4,4'-isopropylidenebis(2,3,5,6-tetrachlorophenol), and 4,4'-thiobiscyclohexanol.

[0052] Among these, from the viewpoint that the mechanical properties and transparency of the molded article can be further improved, glycols, sugar alcohols, mono fatty acid esters formed by sugar alcohols and fatty acids, and polyvinyl alcohol are preferred; ethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol, glycerin, erythritol, pentaerythritol, dipentaerythritol, xylitol, sorbitol, maltitol, lactitol, glyceryl monostearate, glyceryl monooleate, glyceryl mono-12-hydroxystearate, and polyvinyl alcohol are further preferred; ethylene glycol, glycerin, pentaerythritol, xylitol, glyceryl monostearate, and polyvinyl alcohol are particularly preferred.

[0053] The auxiliary agent contained in the nucleating agent composition of the present invention may contain only water, a polyol compound, or a mixture of water and a polyol compound.

[0054] The auxiliary agent contained in the nucleating agent composition of the present invention preferably contains water from the viewpoint of obtaining a molded product having excellent mechanical properties and transparency without greatly affecting properties other than mechanical properties and transparency.

[0055] In addition, from the viewpoint of imparting particularly excellent crystallinity to olefin resins, the auxiliary agent contained in the nucleating agent composition of the present invention preferably contains a polyol compound. When the auxiliary agent contains a polyol compound, from the viewpoint of suppressing the volatilization of the auxiliary agent during molding, the polyol compound is preferably solid or liquid at 230°C, more preferably solid or liquid at 250°C, and further preferably solid or liquid at 280°C.

[0056] The content of the auxiliary agent in the nucleating agent composition of the present invention is 1 to 10,000 parts by mass relative to 100 parts by mass of the nucleating agent. From the viewpoint of imparting particularly excellent nucleating agent performance to olefin resins, the content of the auxiliary agent is preferably 5 to 1,000 parts by mass, more preferably 10 to 500 parts by mass relative to 100 parts by mass of the nucleating agent.

[0057] The nucleating agent composition of the present invention may contain other additives that can be added to olefin resins, as long as the properties of the molded product are not significantly impaired. The nucleating agent composition of the present invention may also be a masterbatch further containing an olefin resin.

[0058] As other additives, there can be mentioned additives generally used in olefin resins, such as phenolic antioxidants, phosphorus antioxidants, sulfur antioxidants, ultraviolet absorbers, hindered amine compounds, flame retardants, flame retardant additives, lubricants, fillers, hydrotalcites, fatty acid metal salts, antistatic agents, fluorescent whitening agents, pigments, dyes, etc. In the nucleating agent composition of the present invention, the amount of other additives is within the range that does not impair the effects of the present invention, and when the nucleating agent composition of the present invention is mixed with an olefin resin for molding, the amount of the mixture can be a moderate amount that can give the desired performance to the molded product.

[0059] Examples of the phenolic antioxidant include 2,6-di-tert-butyl-4-ethylphenol, 2-tert-butyl-4,6-dimethylphenol, styrenated phenol, 2,2'-methylenebis(4-ethyl-6-tert-butylphenol), 2,2'-thiobis-(6-tert-butyl-4-methylphenol), 2,2'-thiodiethylenebis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], 2-methyl-4,6-bis(octylsulfanylmethyl)phenol, 2,2'-isobutylidenebis(4,6-dimethylphenol), isooctyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, 2-Ethylhexyl-3-(3',5'-di-tert-butyl-4'-hydroxyphenyl) propionate, 2,2'-ethylenebis(4,6-di-tert-butylphenol), esters of 3,5-di-tert-butyl-4-hydroxyphenylpropionic acid and C13-15 alkyl, 2,5-di-tert-amylhydroquinone, polymers of hindered phenols (ADEKA POLYMERADDITIVES EUROPE SAS company trade name "AO.OH.98"), 2,2'-methylenebis[6-(1-methylcyclohexyl)-p-cresol], 2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylbenzyl)-4-methylphenyl acrylate, 2-[1-(2-hydroxy-3,5-di-tert-pentylphenyl)ethyl]-4,6-di-tert-pentylphenyl acrylate, 6-[3-(3-tert-butyl-4-hydroxy- [5-(4-(2 ... reaction products of 2,6-di-tert-butyl-4-(4,6-bis(octylthio)-1,3,5-triazine-2-ylamino)phenol, DL-α-tocopherol (vitamin E), 2,6-bis(α-methylbenzyl)-4-methylphenol, bis[3,3-bis-(4'-hydroxy-3'-tert-butyl-phenyl)butyric acid] diol ester, 2,6-di-tert-butyl-p-cresol, 2,6-diphenyl-4-octadecyloxy phenol, stearyl (3,5-di-tert-butyl-4-hydroxyphenyl) propionate, distearyl (3,5-di-tert-butyl-4-hydroxybenzyl) phosphonate, tridecyl-3,5-tert-butyl-4-hydroxybenzyl thioacetate, thiodiethylene bis [(3,5-di-tert-butyl-4-hydroxyphenyl) propionate], 4,4'-thiobis (6-tert-butyl-m-cresol), 2-octylthio-4,6-di (3,5-di-tert-butyl-4-hydroxyphenoxy)-s-triazine, 2,2'-methylenebis(4-methyl-6-tert-butylphenol), bis[3,3-bis(4-hydroxy-3-tert-butylphenyl)butyric acid]diol ester, 4,4'-butylidenebis(2,6-di-tert-butylphenol), 4,4'-butylidenebis(6-tert-butyl-3-methylphenol), 2,2'-ethylidenebis(4,6-di-tert-butylphenol), 1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylbenzene 1,3,5-Tris(3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate, 1,3,5-tris(3,5-di-tert-butyl-4-hydroxybenzyl)-2,4,6-trimethylbenzene ... tert-butyl-4-hydroxyphenyl)propionyloxyethyl] isocyanurate, tetrakis[methylene-3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate]methane, 2-tert-butyl-4-methyl-6-(2-acryloyloxy-3-tert-butyl-5-methylbenzyl)phenol, 3,9-bis[2-(3-tert-butyl-4-hydroxy-5-methylhydrocinnamoyloxy)-1,1-dimethylethyl]-2,4,8,10-tetraoxaspiro[5.5]undecane, triethylamine 3-(3,5-dialkyl-4-hydroxyphenyl) propionic acid derivatives such as diol bis[β-(3-tert-butyl-4-hydroxy-5-methylphenyl) propionate], stearyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionamide, palmityl-3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionamide, myristyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionamide, and lauryl-3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionamide. The amount of the phenolic antioxidant to be added is preferably adjusted to 0.001 to 5 parts by mass, more preferably 0.03 to 3 parts by mass, relative to 100 parts by mass of the olefin resin. ,

[0060] Examples of the phosphorus antioxidant include triphenyl phosphite, diisooctyl phosphite, heptadecanyl phosphite, triisodecyl phosphite, diphenylisooctyl phosphite, diisooctylphenyl phosphite, diphenyltridecyl phosphite, triisooctyl phosphite, trilauryl phosphite, diphenyl phosphite, tri(dipropylene glycol)phosphite, dioleyl hydrogen phosphite, trilauryl trithiophosphite, bis(tridecyl)phosphite, tri(isodecyl)phosphite, tri(tridecyl)phosphite, diphenyldecyl phosphite, dinonylphenylbis(nonylphenyl)phosphite, poly(dipropylene glycol)phenyl phosphite, tetraphenyldipropyl glycol diphosphite, trinonylphenyl phosphite, tris(2,4-di-tert-butylphenyl)phosphite ) phosphite, tris(2,4-di-tert-butyl-5-methylphenyl) phosphite, tris〔2-tert-butyl-4-(3-tert-butyl-4-hydroxy-5-methylphenylthio)-5-methylphenyl〕phosphite, tris(decyl) phosphite, octyl diphenyl phosphite, di(decyl) monophenyl phosphite, mixture of distearyl pentaerythritol and calcium stearate, alkyl(C10) bisphenol A phosphite, tetraphenyl-tetra(tridecyl) pentaerythritol tetraphosphite, bis(2,4-di-tert-butyl-6-methylphenyl) ethyl phosphite, tetra(tridecyl) isopropylidene diphenol diphosphite, tetra(tridecyl)-4,4'-n-butylidene bis(2-tert-butyl-5-methylphenol) diphosphite, hexa(tridecyl) 1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane triphosphite, tetrakis(2,4-di-tert-butylphenyl)biphenylene diphosphite, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, (1-methyl-1-propenyl-3-ylidene)tris(1,1-dimethylethyl)-5-methyl-4,1-phenylene)hexa(tridecyl)phosphite, 2,2'-methylenebis(4,6-di-tert-butylphenyl)-2-ethylhexylphosphite, 2,2'-methylenebis(4,6-di-tert-butylphenyl)-octadecylphosphite, 2,2'-ethylidenebis(4,6-di-tert-butylphenyl)fluorophosphite, 4,4'-butylidenebis(3-methyl- 6-tert-butylphenyl di(tridecyl)) phosphite, tris(2-[(2,4,8,10-tetra-tert-butyldibenzo[d,f][1,3,2]dioxaphosphin-6-yl)oxy]ethyl)amine, 3,9-bis(4-nonylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5,5]undecane, 2,4,6-tri-tert-butylphenyl-2-butyl-2-ethyl-1,3-propanediol phosphite, poly-4,4'-isopropylidene diphenol C12-15 alcohol phosphite, bis(diisodecyl)pentaerythritol diphosphite, bis(tridecyl)pentaerythritol diphosphite, bis(octadecyl)pentaerythritol diphosphite, bis(nonylphenyl)pentaerythritol diphosphite, bis(2,4-di-tert-butylphenyl) pentaerythritol diphosphite, bis(2,4,6-tri-tert-butylphenyl) pentaerythritol diphosphite, bis(2,6-di-tert-butyl-4-methylphenyl) pentaerythritol diphosphite, bis(2,4-dicumylphenyl) pentaerythritol diphosphite, etc. The amount of the phosphorus-based antioxidant when added is preferably adjusted to 0.001 to 10 parts by mass, and more preferably adjusted to 0.01 to 0.5 parts by mass, relative to 100 parts by mass of the olefin-based resin. ,

[0061] Examples of the sulfur-based antioxidant include tetrakis[methylene-3-(laurylthio)propionate]methane, bis(methyl-4-[3-n-alkyl(C12 / C14)thiopropionyloxy]5-tert-butylphenyl)sulfide, ditridecyl-3,3'-thiodipropionate, dilauryl-3,3'-thiodipropionate, dimyristyl-3,3'-thiodipropionate, distearyl-3,3'-thiodipropionate, lauryl / stearylthiodipropionate, 4,4'-thiobis(6-tert-butyl-m-cresol), 2,2'-thiobis(6-tert-butyl-p-cresol), and distearyl disulfide. The amount of the sulfur-based antioxidant to be added is preferably adjusted to 0.001 to 10 parts by mass, and more preferably adjusted to 0.01 to 0.5 parts by mass, relative to 100 parts by mass of the olefin-based resin.

[0062] Examples of the ultraviolet absorber include 2-hydroxybenzophenones such as 2,4-dihydroxybenzophenone and 5,5'-methylenebis(2-hydroxy-4-methoxybenzophenone); 2-(2-hydroxy-5-methylphenyl)benzotriazole, 2-(2-hydroxy-5-tert-octylphenyl)benzotriazole, 2-(2-hydroxy-3,5-di-tert-butylphenyl)-5-chlorobenzotriazole, 2-(2-hydroxy-3-tert-butyl-5-methylphenyl)-5-chlorobenzotriazole, 2-(2-hydroxy-3,5-dicumylphenyl)benzotriazole, 2,2'- Methylbis(4-tert-octyl-6-benzotriazolylphenol), polyethylene glycol ester of 2-(2-hydroxy-3-tert-butyl-5-carboxyphenyl)benzotriazole, 2-[2-hydroxy-3-(2-acryloyloxyethyl)-5-methylphenyl]benzotriazole, 2-[2-hydroxy-3-(2-methacryloyloxyethyl)-5-tert-butylphenyl]benzotriazole, 2-[2-hydroxy-3-(2-methacryloyloxyethyl)-5-tert-octylphenyl]benzotriazole, 2-[2-hydroxy-3-(2-methacryloyloxyethyl)-5-tert-butylphenyl] -5-chlorobenzotriazole, 2-〔2-hydroxy-5-(2-methacryloyloxyethyl)phenyl〕benzotriazole, 2-〔2-hydroxy-3-tert-butyl-5-(2-methacryloyloxyethyl)phenyl〕benzotriazole, 2-〔2-hydroxy-3-tert-amyl-5-(2-methacryloyloxyethyl)phenyl〕benzotriazole, 2-〔2-hydroxy-3-tert-butyl-5-(3-methacryloyloxypropyl)phenyl〕-5-chlorobenzotriazole, 2-〔2-hydroxy-4-(2-methacryloyloxymethyl)phenyl〕benzotriazole, 2-〔2-hydroxy 2-(2-hydroxyphenyl)benzotriazoles such as 2-[2-hydroxy-4-(3-methacryloyloxy-2-hydroxypropyl)phenyl]benzotriazole and 2-[2-hydroxy-4-(3-methacryloyloxypropyl)phenyl]benzotriazole; substituted oxalanilides such as phenyl salicylate, resorcinol monobenzoate, 2-ethyl-2'-ethoxyoxalanilide, 2-ethoxy-4'-dodecyloxalanilide; cyanoacrylates such as ethyl-α-cyano-β,β-diphenylacrylate and methyl-2-cyano-3-methyl-3-(p-methoxyphenyl)acrylate;2-(4,6-diphenyl-1,3,5-triazine-2-yl)-5-hexyloxyphenol, 2-(2-hydroxy-4-octyloxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, trioctyl-2,2',2"-((1,3,5-triazine-2,4,6-triyl)tris(3-hydroxybenzene-4-,1-diyl)tripronate), 2-(4,6-diphenyl-1,3,5-triazine-2-yl)-5-[2-(2-ethylhexanoyloxy)ethoxy]phenol, 2,4, Triazines such as 6-tris(2-hydroxy-4-hexyloxy-3-methylphenyl)-1,3,5-triazine and 1,12-bis[2-[4-(4,6-diphenyl-1,3,5-triazine-2-yl)-3-hydroxyphenoxy]ethyl]dodecanedioate; various metal salts or metal chelates, especially nickel and chromium salts or chelates. The amount of the ultraviolet absorber when added is preferably adjusted to 0.001 to 10 parts by mass, more preferably 0.01 to 0.5 parts by mass, relative to 100 parts by mass of the olefin resin. ;

[0063] Examples of the hindered amine compound include 2,2,6,6-tetramethyl-4-piperidyl stearate, 1,2,2,6,6-pentamethyl-4-piperidyl stearate, 2,2,6,6-tetramethyl-4-piperidyl benzoate, bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate, tetrakis(2,2,6,6-tetramethyl-4-piperidyl)-1,2,3,4-butanetetracarboxylate, tetrakis(1,2,2,6,6-pentamethyl-4-piperidyl)-1,2,3,4-butanetetracarboxylate, bis(2,2,6,6-tetramethyl-4-piperidyl)-1,2,3,4-butanetetracarboxylate, bis(1,2,2,6,6-pentamethyl-4-piperidinyl)-di(tridecyl)-1,2,3,4-butanetetracarboxylate, bis(1,2,2,6,6-pentamethyl-4-piperidinyl)-di(tridecyl)-1,2,3,4-butanetetracarboxylate, bis(1,2,2,4,4-pentamethyl-4-piperidinyl)-2-butyl-2-(3,5-di-tert-butyl-4-hydroxybenzyl)malonate, 1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidinyl / diethyl succinate polycondensate, 1,6-bis(2,2,6,6-tetramethyl-4-piperidinylamino)hexane / 2,4-di Chloro-6-morpholinyl-s-triazine polycondensate, 1,6-bis(2,2,6,6-tetramethyl-4-piperidinylamino)hexane / 2,4-dichloro-6-tert-octylamino-s-triazine polycondensate, 1,5,8,12-tetrakis[2,4-bis(N-butyl-N-(2,2,6,6-tetramethyl-4-piperidinyl)amino)-s-triazine-6-yl]-1,5,8,12-tetraazadodecane, 1,5,8,12-tetrakis[2,4-bis(N-butyl-N-(1,2,2,6,6-pentamethyl-4-piperidinyl)amino)-s-triazine-6-yl]-1,5 ,8-12-tetraazadodecane, 1,6,11-tris[2,4-bis(N-butyl-N-(2,2,6,6-tetramethyl-4-piperidinyl)amino)-s-triazin-6-yl]aminoundecane, 1,6,11-tris[2,4-bis(N-butyl-N-(1,2,2,6,6-pentamethyl-4-piperidinyl)amino)-s-triazin-6-yl]aminoundecane, bis{4-(1-octyloxy-2,2,6,6-tetramethyl)piperidinyl}sebacate, bis{4-(2,2,6,6-tetramethyl-1-undecyloxy)piperidinyl}carbonate, etc. The amount of the hindered amine compound to be added is preferably adjusted to 0.001 to 10 parts by mass, more preferably 0.01 to 0.5 parts by mass, relative to 100 parts by mass of the olefin resin.

[0064] Examples of the flame retardant include triphenyl phosphate, tricresyl phosphate, tricresyl phosphate, cresyl diphenyl phosphate, cresyl-2,6-di-cresyl phosphate, resorcinol bis(diphenyl phosphate), (1-methylethylidene)-4,1-phenylenetetraphenyl diphosphate, 1,3-phenylenetetra(2,6-dimethylphenyl) phosphate, and ADEKA Corporation trade names "ADEKASTAB FP-500", "ADEKASTAB FP-600", "ADEKASTAB FP-700", "ADEKASTAB FP-800", "ADEKASTAB FP-900", "ADEKASTAB FP-1000", "ADEKASTAB FP-1100", "ADEKASTAB FP-1200", "ADEKASTAB FP-1300", "ADEKASTAB FP-1500", "ADEKASTAB FP-1600", "ADEKASTAB FP-1700", "ADEKASTAB FP-1800", "ADEKASTAB FP-1900", "ADEKASTAB FP-2000", "ADEKASTAB FP-2100" and "ADEKASTAB FP-2100" Phosphates such as aromatic phosphates, divinyl phenylphosphonate, diallyl phenylphosphonate, (1-butenyl) phenylphosphonate, phosphonates such as phenyl diphenylphosphinate, methyl diphenylphosphinate, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide derivatives, phosphonates such as bis(2-allylphenoxy)phosphazene, dimethyltoluenephosphazene, melamine phosphate, melamine pyrophosphate, melamine polyphosphate, polyphosphate melam, ammonium polyphosphate, piperazine phosphate, piperazine pyrophosphate, piperazine polyphosphate, phosphorus-containing vinylbenzyl compounds and red phosphorus and other phosphorus flame retardants, magnesium hydroxide, aluminum hydroxide and other metals Brominated flame retardants include hydroxides, brominated bisphenol A epoxy resins, brominated phenol novolac epoxy resins, hexabromobenzene, pentabromotoluene, ethylenebis(pentabromobenzene), ethylenebistetrabromophthalimide, 1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane, tetrabromocyclooctane, hexabromocyclododecane, bis(tribromophenoxy)ethane, brominated polyphenylene ether, brominated polystyrene, 2,4,6-tris(tribromophenoxy)-1,3,5-triazine, tribromophenylmaleimide, tribromophenyl acrylate, tribromophenyl methacrylate, tetrabromobisphenol A dimethacrylate, pentabromobenzyl acrylate, and brominated styrene. These flame retardants are preferably used in combination with anti-drip agents such as fluororesins, polyols, and flame retardant aids such as hydrotalcite. The amount of the flame retardant when added is preferably adjusted to 1 to 100 parts by mass, more preferably 10 to 70 parts by mass, based on 100 parts by mass of the olefin-based resin.

[0065] Lubricants are added for the purpose of imparting sliding properties to the surface of molded products and improving the anti-scratch effect. Examples of lubricants include unsaturated fatty acid amides such as oleamide and erucamide; saturated fatty acid amides such as behenamide and stearamide, butyl stearate, stearyl alcohol, stearic acid monoglyceride, sorbitan monopalmitate, sorbitan monostearate, mannitol, stearic acid, hydrogenated castor oil, stearamide, oleamide, ethylene bisstearamide, etc. These can be used alone or in combination of two or more. The amount of the lubricant to be added is preferably adjusted to 0.01 to 2 parts by mass, and more preferably adjusted to 0.03 to 1 part by mass, relative to 100 parts by mass of the olefin resin.

[0066] Fillers can be roughly divided into organic fillers and inorganic fillers. As organic fillers, polymers from nature such as starch, cellulose, wood powder, bean dregs, fir shells, wheat bran, or modified products thereof can be cited. In addition, as inorganic fillers, talc, calcium carbonate, zinc carbonate, calcite, silicon dioxide, mica, aluminum oxide, magnesium oxide, calcium silicate, sodium aluminate, calcium aluminate, sodium aluminosilicate, magnesium silicate, glass balls, carbon black, zinc oxide, antimony trioxide, zeolite, metal fiber, metal whisker, ceramic whisker, potassium titanate, boron nitride, graphite, carbon fiber, etc. The amount of the filler when mixed is preferably adjusted to 0.1 to 500 parts by mass, more preferably adjusted to 1 to 100 parts by mass, relative to 100 parts by mass of the olefin resin.

[0067] Hydrotalcites are complex salt compounds containing magnesium, aluminum, hydroxyl, carbonate and any crystal water, which are known as natural or synthetic products. Examples include: those in which a part of magnesium or aluminum is replaced by other metals such as alkali metals and zinc, and those in which hydroxyl and carbonate are replaced by other anionic groups. Specifically, for example, hydrotalcites represented by the following general formula (2) are those in which the metal is replaced by an alkali metal. In addition, as Al-Li-based hydrotalcites, compounds represented by the following general formula (3) can also be used.

[0068] Mg x1 Zn x2 Al2(OH) 2(x1+x2)+4 (CO3)pH2O (2)

[0069] In the general formula (2), x1 and x2 each represent a number satisfying the conditions shown in the following formula, and P represents 0 or a positive number.

[0070] [Li 1 / 3 Al 2 / 3 (OH)2]·[A q- 1 / 3q· pH2O] (3)

[0071] Among them, in the general formula (3), A q- represents a q-valent anion, and p represents 0 or a positive number.

[0072] Furthermore, part of the carbonate anions in the hydrotalcites may be replaced by other anions.

[0073] The hydrotalcites may be obtained by dehydrating the crystal water, or may be coated with higher fatty acids such as stearic acid, higher fatty acid metal salts such as oleic acid alkali metal salts, organic sulfonic acid metal salts such as dodecylbenzenesulfonic acid alkali metal salts, higher fatty acid amides, higher fatty acid esters, or waxes.

[0074] Hydrotalcites can be natural products, and can also be synthetic products. As a method for synthesizing the compound, the known methods described in Japanese Patent Publication No. 46-2280, Japanese Patent Publication No. 50-30039, Japanese Patent Publication No. 51-29129, Japanese Patent Publication No. 3-36839, Japanese Patent Publication No. 61-174270, Japanese Patent Publication No. 5-179052, etc. can be cited. In addition, hydrotalcites can be used without being restricted by their crystal structure, crystal grains, etc. The amount of hydrotalcites when mixed is preferably adjusted to 0.001 to 5 parts by mass relative to 100 parts by mass of olefin resin, and more preferably adjusted to 0.01 to 3 parts by mass.

[0075] As the fatty acid metal salt, a compound represented by the following general formula (4) is preferred from the viewpoint of obtaining heat resistance and a dispersion effect of a nucleating agent in a resin.

[0076]

[0077] Among them, in the general formula (4), R 6 It represents a linear or branched fatty acid having 12 to 20 carbon atoms, which may be substituted by a hydroxyl group. 2 represents a metal atom having a valence of 1 to 3, the metal atom may have a hydroxyl group, and m represents an integer of 1 to 3.

[0078] The fatty acid metal salt is preferably a metal salt of lauric acid, myristic acid, palmitic acid, stearic acid or 12-hydroxystearic acid. Examples of the metal salt of the fatty acid metal salt include sodium, potassium, lithium, calcium, zinc, barium, magnesium and hydroxyaluminum, and sodium, lithium and potassium are more preferred.

[0079] As antistatic agents, for example, low molecular weight antistatic agents based on nonionic, anionic, cationic or amphoteric surfactants and high molecular weight antistatic agents based on high molecular weight compounds can be cited. As nonionic surfactants, polyethylene glycol nonionic surfactants such as higher alcohol ethylene oxide adducts, fatty acid ethylene oxide adducts, higher alkylamine ethylene oxide adducts, and polypropylene glycol ethylene oxide adducts can be cited; polyol nonionic surfactants such as polyethylene oxide, fatty acid esters of glycerol, fatty acid esters of pentaerythritol, fatty acid esters of sorbitol or sorbitan, alkyl ethers of polyols, and aliphatic amides of alkanolamines can be cited; as anionic surfactants, for example, carboxylates such as alkali metal salts of higher fatty acids can be cited; sulfates such as higher alcohol sulfates and higher alkyl ether sulfates, sulfonates such as alkylbenzene sulfonates, alkyl sulfonates, and paraffin sulfonates can be cited; phosphates such as higher alcohol phosphates can be cited; as cationic surfactants, quaternary ammonium salts such as alkyltrimethylammonium salts can be cited. As amphoteric surfactants, amino acid-type amphoteric surfactants such as higher alkyl aminopropionates, betaine-type amphoteric surfactants such as higher alkyl dimethyl betaines and higher alkyl dihydroxyethyl betaines can be cited, among which anionic surfactants are preferred, and sulfonates such as alkylbenzene sulfonates, alkyl sulfonates, and paraffin sulfonates are particularly preferred. The amount of the low-molecular antistatic agent when mixed is preferably adjusted to 0.1 to 10 parts by mass, more preferably 0.5 to 5 parts by mass, relative to 100 parts by mass of the olefin resin.

[0080] As a polymer antistatic agent, ionomers, block polymers with polyethylene glycol as a hydrophilic part, etc. can be cited. As ionomers, ionomers described in Japanese Patent Publication No. 2010-132927 can be cited. As polymers with polyethylene glycol as a hydrophilic part, for example, polyether ester amides described in Japanese Patent Publication No. 7-10989, polymers formed by polyolefins and polyethylene glycol described in U.S. Patent No. 6552131, polymers formed by polyesters and polyethylene glycol described in Japanese Patent Publication No. 2016-023254, etc. can be cited. The amount of the polymer antistatic agent when mixed is preferably adjusted to 3 to 60 parts by mass relative to 100 parts by mass of the olefin resin, more preferably adjusted to 5 to 25 parts by mass, and further preferably adjusted to 7 to 20 parts by mass.

[0081] Fluorescent whitening agents are compounds that absorb ultraviolet light from sunlight or artificial light, and contribute to the whiteness and blue tone of the molded product by converting it into purple to blue visible light and radiating it through fluorescence. Examples of fluorescent whitening agents include benzoxazole compounds CIFluorescent Brightner 184; coumarin compounds CIFluorescent Brightner 52; diaminostilbene disulfonic acid compounds CIFluorescent Brightner 24, 85, 71, etc. When using a fluorescent whitening agent, the blending amount is preferably adjusted to 0.00001 to 0.1 parts by mass, and more preferably adjusted to 0.00005 to 0.05 parts by mass, relative to 100 parts by mass of the olefin resin.

[0082] As the pigment, commercially available pigments may be used, for example, Pigment Red 1, 2, 3, 9, 10, 17, 22, 23, 31, 38, 41, 48, 49, 88, 90, 97, 112, 119, 122, 123, 144, 149, 166, 168, 169, 170, 171, 177, 179, 180, 184, 185, 1 92, 200, 202, 209, 215, 216, 217, 220, 223, 224, 226, 227, 228, 240, 254; Pigment Orange 13, 31, 34, 36, 38, 43, 46, 48, 49, 51, 52, 55, 59, 60, 61, 62, 64, 65, 71; Pigment Yellow 1, 3, 12, 13, 14, 16, 17, 20, 24, 55, 60, 73, 81, 83, 86, 93, 95, 97, 98, 100, 109, 110, 113, 114, 117, 120, 125, 126, 127, 129, 137, 138, 139, 147, 148, 150, 151, 152, 153, 1 54, 166, 168, 175, 180, 185; Pigment Green 7, 10, 36; Pigment Blue 15, 15:1, 15:2, 15:3, 15:4, 15:5, 15:6, 22, 24, 29, 56, 60, 61, 62, 64; Pigment Violet 1, 15, 19, 23, 27, 29, 30, 32, 37, 40, 50, etc.

[0083] Examples of the dye include azo dyes, anthraquinone dyes, indigo dyes, triarylmethane dyes, xanthene dyes, alizarin dyes, acridine dyes, stilbene dyes, thiazole dyes, naphthol dyes, quinoline dyes, nitro dyes, indamine dyes, oxazine dyes, phthalocyanine dyes, and cyanine dyes, and these may be used in combination of a plurality of types.

[0084] Next, the olefin resin composition of the present invention is described. The olefin resin composition of the present invention contains an olefin resin, a nucleating agent and an auxiliary agent. The nucleating agent contains an aromatic phosphate metal salt represented by the following general formula (1), and the auxiliary agent is at least one selected from the group consisting of water and a polyol compound.

[0085]

[0086] Among them, in the general formula (1), R 1 ~R 4 represents an alkyl group having 1 to 6 carbon atoms, R 5 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, n represents 1 or 2, when n is 1, M represents lithium or dihydroxyaluminum, and when n is 2, M represents hydroxyaluminum. Furthermore, the olefin resin composition of the present invention contains 0.001 to 5 parts by mass of a nucleating agent and 0.003 to 10 parts by mass of an auxiliary agent based on 100 parts by mass of the olefin resin.

[0087] The olefin resin composition of the present invention has excellent crystallinity. In addition, the olefin resin composition of the present invention can provide a molded article having excellent mechanical properties and transparency.

[0088] As the polyolefin resin contained in the resin composition of the present invention, for example, low-density polyethylene (LDPE), linear low-density polyethylene (L-LDPE), high-density polyethylene (HDPE), isotactic polypropylene, syndiotactic polypropylene, semi-isotactic polypropylene, cycloolefin polymer, stereo block polypropylene, poly-3-methyl-1-butene, poly-3-methyl-1-pentene, poly-4-methyl-1-pentene and other α-olefin polymers, homopolypropylene, ethylene / propylene block copolymer or random copolymer, impact copolymer polypropylene, ethylene-methyl methacrylate copolymer, ethylene-methyl acrylate copolymer, ethylene-ethyl acrylate copolymer, ethylene-butyl acrylate copolymer, ethylene-vinyl acetate copolymer, ethylene-vinyl alcohol resin (EVOH) and other α-olefin copolymers can be used, and it can also be an elastomer containing olefin resin. The resin composition of the present invention can be blended with these two or more and used, and block copolymers can be formed to be used with block polymer type, and resin can also be alloyed. In addition, it can also be the chloride of these olefin resins.

[0089] As the elastomer containing olefin resin, there can be mentioned: as the hard segment, polyolefins such as polypropylene or polyethylene are used, as the soft segment, rubbers such as ethylene-propylene rubber are used, and elastomers obtained by blending them, or elastomers obtained by dynamic crosslinking. As the hard segment, for example, at least one selected from polypropylene homopolymer, polypropylene block copolymer, polypropylene random copolymer, etc. can be mentioned. As the soft segment, ethylene-propylene copolymer (EPM), ethylene-propylene-diene copolymer (EPDM), ethylene-vinyl acetate copolymer (EVA), vinyl acetate homopolymer, etc. can be mentioned. For the olefin resin composition of the present invention, these two or more can be blended and used.

[0090] For the resin composition of the present invention, the olefin-based resin is polypropylene, ethylene / propylene block or random copolymer, α-olefin / propylene block or random copolymer other than ethylene, and a mixture of these propylene-based polymers with other α-olefin polymers, and is particularly preferred because the effect of the present invention is significant.

[0091] The method for producing olefin resins is to use various polymerization catalysts such as Ziegler catalysts, Ziegler-Natta catalysts, and metallocene catalysts as cocatalysts, including catalyst carriers and chain transfer agents, in various polymerization methods such as gas phase polymerization, solution polymerization, emulsion polymerization, and bulk polymerization, and various polymerization conditions such as temperature, pressure, concentration, flow rate, or removal of catalyst residues can be appropriately selected to produce. The number average molecular weight, weight average molecular weight, molecular weight distribution, melt flow rate, melting point, melting peak temperature, stereoregularity such as isotactic and syndiotactic, the presence or degree of branching, specific gravity, the ratio of soluble components in various solvents, haze, gloss, impact strength, bending modulus, Olsen rigidity, other characteristics of the olefin resin, and whether the values ​​of each characteristic satisfy a specific formula can be appropriately selected according to the desired characteristics.

[0092] The olefin resin composition of the present invention may have a nucleating agent and an auxiliary agent that are the same as those contained in the nucleating agent composition of the present invention.

[0093] As described above, in the resin composition of the present invention, the content of the nucleating agent is 0.001 to 5 parts by mass relative to 100 parts by mass of the olefin resin. From the viewpoint that the addition effect of the nucleating agent can be fully obtained and the generation of nucleating agent agglomerates as foreign matter in the molded article can be suppressed, the content of the nucleating agent is preferably 0.005 to 5 parts by mass, and more preferably 0.01 to 1 part by mass relative to 100 parts by mass of the olefin resin.

[0094] In addition, as mentioned above, for the resin composition of the present invention, the content of the auxiliary agent is 0.003 to 10 parts by mass relative to 100 parts by mass of the olefin resin. If the content of the auxiliary agent is less than 0.003 parts by mass, the effect of the present invention will not be obtained. If it exceeds 10 parts by mass, the feedability of the composition will deteriorate, for example, a waist plug will be generated in the hopper or feeder of a processing machine such as an extruder, and foaming will occur during the extrusion processing of the composition, or bubbles will be generated in the molded product and damage the appearance. From the point of view that the effect of the present invention can be fully obtained and the deterioration of the feedability of the composition can be fully suppressed at the same time, the content of the auxiliary agent is preferably 0.01 to 5 parts by mass, more preferably 0.04 to 1 part by mass, relative to 100 parts by mass of the nucleating agent. In addition, the content of the auxiliary agent is preferably 1 to 10,000 parts by mass, more preferably 5 to 1,000 parts by mass, and further preferably 10 to 500 parts by mass.

[0095] On the other hand, from the viewpoint that the foaming during the molding process, which is too complicated and uneconomical, can be sufficiently suppressed, the water content of the resin composition of the present invention is preferably in the range of 0.003 to 0.05% by mass, and more preferably in the range of 0.005 to 0.03% by mass. The so-called "water content" here means the water content calculated from the water content measured using a polymer moisture meter "Aqua truck 3E" (manufactured by ITS Japan Co., Ltd.).

[0096] In the resin composition of the present invention, other additives that can be mixed in the olefin resin can be further mixed as long as the properties of the molded article are not greatly impaired. As other additives, the same as those used for the nucleating agent composition of the present invention can be used. The mixing amount of other additives is within the range that does not impair the effect of the present invention, and is an appropriate mixing amount in order to give the desired performance of the molded article when molding the resin composition of the present invention.

[0097] Next, the method for producing the olefin resin composition of the present invention is described. The method for producing the olefin resin composition of the present invention comprises: a preparation step of preparing an olefin resin that does not contain a nucleating agent component; and a mixing step of mixing a nucleating agent and an auxiliary agent into the olefin resin that does not contain a nucleating agent component prepared in the preparation step to obtain an olefin resin compound, wherein the nucleating agent contains an aromatic phosphate metal salt represented by the following general formula (1). Among them, the auxiliary agent is at least one selected from the group consisting of water and a polyol compound. Moreover, in the mixing step, the amount of the nucleating agent mixed is 0.001 to 5 parts by mass relative to 100 parts by mass of the olefin resin that does not contain a nucleating agent component, and the amount of the auxiliary agent mixed is 0.003 to 10 parts by mass relative to 100 parts by mass of the olefin resin that does not contain a nucleating agent component.

[0098]

[0099] Among them, in the general formula (1), R 1 ~R 4 represents an alkyl group having 1 to 6 carbon atoms, R 5 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and n represents 1 or 2. When n is 1, M represents lithium or dihydroxyaluminum, and when n is 2, M represents hydroxyaluminum.

[0100] According to the method for producing an olefin resin composition of the present invention, an olefin resin composition capable of imparting excellent transparency and mechanical properties to a molded article can be produced.

[0101] In the preparation step, an olefinic resin not containing a nucleating agent is prepared. Other additives that can be blended in the above-mentioned olefinic resin may be blended in the olefinic resin not containing a nucleating agent.

[0102] In the compounding step, a nucleating agent and an auxiliary agent are compounded with the olefinic resin not containing a nucleating agent component prepared in the preparation step to obtain an olefinic resin compound.

[0103] As described above, the amount of the nucleating agent blended is 0.001 to 5 parts by mass relative to 100 parts by mass of the olefin resin not containing the nucleating agent. From the viewpoint that the effect of the addition of the nucleating agent can be sufficiently obtained and the generation of agglomerates of the nucleating agent as foreign matter in the molded article can be suppressed, the amount of the nucleating agent blended is preferably 0.005 to 5 parts by mass, and more preferably 0.01 to 1 part by mass relative to 100 parts by mass of the olefin resin not containing the nucleating agent.

[0104] In addition, as mentioned above, the amount of the additive is 0.003 to 10 parts by mass relative to 100 parts by mass of the olefin resin without a nucleating agent. If the amount of the additive is less than 0.003 parts by mass, the effect of the present invention may not be obtained. When it exceeds 10 parts by mass, the feedability of the composition may deteriorate, for example, a waist plug may be generated in the hopper or feed hopper of a processing machine such as an extruder, or foaming may occur during the extrusion process of the composition, or bubbles may be generated in the molded product and damage the appearance. From the viewpoint that the effect of the present invention can be fully obtained and the deterioration of the feedability of the composition can be fully suppressed at the same time, the amount of the additive is preferably 0.01 to 5 parts by mass, more preferably 0.04 to 1 part by mass, relative to 100 parts by mass of the olefin resin without a nucleating agent. In addition, the amount of the additive is preferably 1 to 10,000 parts by mass, more preferably 5 to 1,000 parts by mass, and further preferably 10 to 500 parts by mass relative to 100 parts by mass of the nucleating agent.

[0105] In the compounding step, other additives that can be compounded with the above-mentioned olefin-based resin may be further compounded. The method for compounding the components in the compounding step is not particularly limited, and examples thereof include a method of compounding using a mixer such as a Henschel mixer or a tumbler mixer.

[0106] In the mixing step, when water is mixed as an auxiliary agent, the water may be mixed as a hydrate, a hydroxide, a water coordinated complex, etc. As the hydrate, for example, a compound having crystal water, a substance containing water in a molecular form, an inclusion compound, etc. may be mentioned. In addition, as the hydroxide, for example, metal hydroxides such as calcium hydroxide, magnesium hydroxide, aluminum hydroxide, and boehmite-type aluminum hydroxide may be mentioned. In addition, water may be mixed as a water-containing resin composition obtained by mixing an olefin resin with water.

[0107] As described above, the olefin resin composition of the present invention can be obtained in the form of an olefin resin compound.

[0108] The method for producing the olefin resin composition of the present invention is preferably further provided with a melt-kneading step: the olefin resin compound obtained in the compounding step is melt-kneaded. At this time, an olefin resin composition in which a nucleating agent and an auxiliary agent are uniformly dispersed in the olefin resin can be obtained. In addition, when water is compounded as an auxiliary agent, the excess water during melt-kneading will reduce the water content in the composition by volatilization, and the foaming during the molding of the composition can be fully suppressed. There is no particular limitation on the method of melt-kneading, and for example, methods using extruders such as a single-screw extruder and a twin-screw extruder can be cited. The temperature of melt-kneading is not particularly limited, for example, it can be only 180 to 300°C. In addition, for the melt-kneading step, other additives that can be compounded in the above-mentioned olefin resin can be further compounded, for example, using a side feed hopper.

[0109] As described above, the olefin resin composition of the present invention can be obtained as a melt-kneaded product of an olefin resin compound. The melt-kneaded product of an olefin resin compound obtained in this way can be granulated into pellets by, for example, a pelletizer or the like by strand cutting or the like.

[0110] Next, the molded product of the present invention will be described. The so-called molded product of the present invention refers to a product obtained by molding the olefin resin composition of the present invention. There is no particular limitation on the method for molding the resin composition of the present invention, and a known molding method can be used. For example, a molded product can be obtained by injection molding, extrusion molding, blow molding, rotational molding, vacuum molding, inflation molding, calendering, reduction molding, impregnation molding, foaming molding, etc. Among them, injection molding, extrusion molding, and blow molding are preferred.

[0111] As the molded article of the present invention, for example, there can be mentioned injection molded articles, fibers, flat yarns, biaxially stretched films, uniaxially stretched films, unstretched films, sheets, thermoformed articles, extrusion blow molded articles, injection blow molded articles, injection stretch blow molded articles, profile extrusion molded articles, rotational molded articles, etc. Among them, injection molded articles, films, sheets, and thermoformed articles are also preferred.

[0112] The molded article of the present invention can be used in various applications such as building materials, agricultural materials, parts for vehicles such as automobiles, trains, ships, and aircraft, packaging materials, sundries, toys, home appliances, and medical products. Specific examples include automotive parts such as bumpers, dashboards, instrument panels, battery boxes, trunks, door panels, door trims, and fender strips; resin parts for home appliances such as refrigerators, washing machines, and vacuum cleaners; household items such as tableware, bottle caps, buckets, and bath products; resin parts for connections such as connectors; sundry items such as toys, storage containers, and synthetic paper; medical molded products such as medical bags, syringes, catheters, medical tubes, syringe preparations, infusion bags, test drug containers, drinking drug containers, and drinking drug individual packages; building materials such as wall materials, floor materials, window frames, wallpapers, and windows; wire coating materials; agricultural materials such as houses, tunnels, and flat wire mesh bags; industrial materials such as pallets, barrels, back polishing glue, LCD protective tape, pipes, and modified silicone polymers for sealing materials; food packaging materials such as wrapping paper (Wrap), plates, cups, films, bottles, lids, and storage containers, 3D printer materials, battery separators, clothing, woven fabrics, non-woven fabrics, and other fibers. Furthermore, it can be used for various post-treatment applications, such as sterilization by radiation in medical applications, food packaging applications, etc., or improvement of surface properties such as paintability by low-temperature plasma treatment after molding, etc. The molded article of the present invention is particularly preferably used in automotive materials, household products, and packaging materials.

[0113] Example

[0114] The present invention will be described in more detail below with reference to Examples, but the present invention is not limited to the following Examples, etc. Evaluations in Examples were performed according to the following procedures.

[0115] <Crystallization temperature Tc (°C)>

[0116] The crystallization temperature (°C) of the pellets was measured using a differential scanning calorimeter (Diamond DSC manufactured by Perkin Elmer). The measurement method was to raise the temperature from room temperature to 230°C at a rate of 50°C / min, hold for 15 minutes, and then cool to 50°C at -10°C / min. In the resulting graph, the temperature at which the exothermic reaction during the cooling process reached a peak was taken as the crystallization temperature (°C).

[0117] <Flexural modulus (MPa)>

[0118] The pellets obtained by granulation were injection molded using an injection molding machine (EC100-2A; manufactured by Toshiba Machine Co., Ltd.) at a mold temperature of 50°C and a resin temperature of 200°C to produce test pieces of size 80 mm×10 mm×4 mm. After being allowed to stand in a constant temperature machine at 23°C for more than 48 hours, the flexural modulus (MPa) was measured using a flexural testing machine "AG-IS" manufactured by Shimadzu Corporation in accordance with ISO178.

[0119] <Izod impact strength (kJ / m 2 )>

[0120] The pellets obtained by granulation were injection molded by an injection molding machine (EC100-2A; manufactured by Toshiba Machine Co., Ltd.) under the conditions of a mold temperature of 50°C and a resin temperature of 200°C to produce a test piece (with a notch) of 80 mm×10 mm×4 mm. After being left to stand in a constant temperature machine at 23°C for more than 48 hours, the Izod impact strength (kJ / m 2 ).

[0121] < half crystallization time T 1 / 2 (seconds)>

[0122] The pellets obtained by granulation were used to measure the half crystallization time (T 1 / 2 The determination method is to heat from room temperature to 230°C at a rate of 50°C / min, hold for 15 minutes, and then cool to 135°C at a rate of -200°C / min. After reaching 135°C, the temperature is maintained, and the time required from the time point of reaching 135°C to the heat of half the heat enthalpy required for crystallization is calculated as the half-crystallization time (seconds).

[0123] <Haze (%)>

[0124] The pellets obtained by granulation were injection molded by an injection molding machine (EC100-2A; manufactured by Toshiba Machine Co., Ltd.) at a mold temperature of 50°C and a resin temperature of 200°C to produce a test piece of 60 mm×60 mm×2 mm in size. After the test piece was molded, it was immediately left to stand in a constant temperature machine at 23°C for 48 hours or more, and the haze (%) was measured using Haze guardi [manufactured by BYK Additives & Instruments] in accordance with ISO 14782.

[0125] <Feedability>

[0126] 20 g of an olefin resin composition obtained by weighing an olefin resin, a nucleating agent, water or a polyol compound, a phenolic antioxidant, a phosphorus antioxidant and a calcium stearate and blending them with a Henschel mixer was put into the hopper of a powder measurement and evaluation device (Multi tester MT-02 manufactured by Seishin Enterprise Co., Ltd.) to measure the time until the olefin resin composition was discharged. When the time required until the olefin resin composition was discharged was within 3.2 seconds, it was evaluated as good feedability, and when it exceeded 3.2 seconds, it was evaluated as poor feedability.

[0127] [Example 1-1 to Example 1-14, Comparative Example 1-1 to Comparative Example 1-3]

[0128] 0.05 parts by mass of a phenolic antioxidant [tetrakis[methylene-3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate]methane], 0.1 parts by mass of a phosphorus antioxidant [tris(2,4-di-tert-butylphenyl)phosphite], 0.05 parts by mass of a calcium stearate, 0.1 parts by mass of a nucleating agent described in Table 1, and water or a polyol compound in a blending amount described in Table 1 were mixed with 100 parts by mass of homopolypropylene (melt flow rate 8 g / 10 minutes; according to ISO Standard 1133, 2.16 kg×230° C.) as an olefin resin using a Henschel mixer at 1000 rpm×1 minute, and then melt-kneaded at an extrusion temperature of 230° C. using a twin-screw extruder (TEX-28V; manufactured by The Japan Steel Works, Ltd.) to form pellets. Among them, Comparative Example 1-1 did not mix a nucleating agent, water, and a polyol compound, and Comparative Example 1-2 did not mix water and a polyol compound. The moisture content of the obtained pellets was about 0.008% by mass. The pellets were dried at 60°C for 8 hours and used in the evaluation of crystallization temperature (°C) and flexural modulus (MPa). The moisture content of the pellets after drying was about 0.0055% by mass.

[0129] [Table 1]

[0130]

[0131] Compound 1: Lithium 2,2'-methylenebis(4,6-di-tert-butylphenyl)phosphate

[0132] [Example 2-1 to Example 2-6, Comparative Example 2-1 to Comparative Example 2-2]

[0133] 0.05 parts by mass of a phenolic antioxidant [tetrakis[methylene-3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate]methane], 0.1 parts by mass of a phosphorus antioxidant [tris(2,4-di-tert-butylphenyl)phosphite], 0.05 parts by mass of a calcium stearate, 0.1 parts by mass of a nucleating agent, and water or a polyol compound in the amounts described in Table 2 were mixed with 100 parts by mass of homopolypropylene (melt flow rate 8 g / 10 minutes; according to ISO Standard 1133, 2.16 kg×230° C.) as an olefin resin using a Henschel mixer at 1000 rpm×1 minute, and then melt-kneaded at an extrusion temperature of 230° C. using a twin-screw extruder (TEX-28V; manufactured by The Japan Steel Works, Ltd.) and pelletized into pellets. In Comparative Example 2-1, water and a polyol compound were not added. The moisture content of the obtained pellets was about 0.008 mass %.

[0134] The pellets were dried at 60°C for 8 hours and then used for crystallization temperature (°C), flexural modulus (MPa) and Izod impact strength (kJ / m 2 The moisture content of the pellets after drying was about 0.0055% by mass. Furthermore, the feedability was evaluated using the olefin resin composition just after blending with the Henschel mixer.

[0135] [Table 2]

[0136]

[0137] Compound 2: ADEKA Corporation, trade name "ADEKA STAB NA-21" (main component: a complex of bis[2,2'-methylenebis(4,6-di-tert-butylphenyl)phosphate]hydroxyaluminum)

[0138] [Example 3-1 to Example 3-2, Comparative Example 3-1 to Comparative Example 3-4]

[0139] 0.05 parts by mass of a phenolic antioxidant [tetrakis[methylene-3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate]methane], 0.1 parts by mass of a phosphorus antioxidant [tris(2,4-di-tert-butylphenyl)phosphite], 0.05 parts by mass of a calcium stearate, a nucleating agent in the amount described in Table 3, and water were mixed with 100 parts by mass of homopolypropylene (melt flow rate 8 g / 10 minutes; according to ISO Standard 1133, 2.16 kg×230° C.) as an olefin resin using a Henschel mixer at 1000 rpm×1 minute, and then melt-kneaded at an extrusion temperature of 230° C. using a twin-screw extruder (TEX-28V; manufactured by The Japan Steel Works, Ltd.) and pelletized into pellets. The moisture content of the obtained pellets was about 0.008% by mass. The pellets were dried at 60° C. for 8 hours and then used for evaluation of crystallization temperature (° C.) The moisture content of the pellets after drying was about 0.0055% by mass. These results are shown in Table 3.

[0140] [Table 3]

[0141]

[0142] ※1: Crystallization temperature when 0.3 parts by mass of water is added

[0143] ※2: Crystallization temperature when no water is added

[0144] ※3: Difference in crystallization temperature when 0.3 parts by mass of water is added and when no water is added

[0145] Control: No nucleating agent

[0146] HPN-20E: Made by Milliken, trade name "Hyperform HPN-20E"

[0147] NA-11: Trade name "ADEKA STAB NA-11" manufactured by ADEKA Co., Ltd.

[0148] Sodium Benzoate: Sodium Benzoate

[0149] [Example 4-1 to Example 4-2, Comparative Example 4-1 to Comparative Example 4-4]

[0150] 0.05 parts by mass of a phenolic antioxidant [tetrakis[methylene-3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate]methane], 0.1 parts by mass of a phosphorus antioxidant [tris(2,4-di-tert-butylphenyl)phosphite], 0.05 parts by mass of a calcium stearate, a nucleating agent in the amount described in Table 4, and water were mixed with 100 parts by mass of homopolypropylene (melt flow rate 8 g / 10 minutes; according to ISO Standard 1133, 2.16 kg×230° C.) as an olefin resin using a Henschel mixer at 1000 rpm×1 minute, and then melt-kneaded at an extrusion temperature of 230° C. using a twin-screw extruder (TEX-28V; manufactured by The Japan Steel Works, Ltd.) and pelletized into pellets. The moisture content of the obtained pellets was about 0.008% by mass. The pellets were dried at 60° C. for 8 hours and then used for evaluation of flexural modulus (MPa). The moisture content of the pellets after drying was about 0.0055% by mass. These results are shown in Table 4.

[0151] [Table 4]

[0152]

[0153] ※4: Flexural modulus when 0.3 parts by mass of water is added

[0154] ※5: Flexural modulus without adding water

[0155] ※6: Difference in flexural modulus when 0.3 parts by mass of water is added and when no water is added

[0156] [Example 5-1 to Example 5-2, Comparative Example 5-1 to Comparative Example 5-4]

[0157] 0.05 parts by mass of a phenolic antioxidant [tetrakis[methylene-3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate]methane], 0.1 parts by mass of a phosphorus antioxidant [tris(2,4-di-tert-butylphenyl)phosphite], 0.05 parts by mass of a calcium stearate, a nucleating agent in the amount described in Table 5, and water were mixed with 100 parts by mass of homopolypropylene (melt flow rate 8 g / 10 minutes; according to ISO Standard 1133, 2.16 kg×230° C.) as an olefin resin using a Henschel mixer at 1000 rpm×1 minute, and then melt-kneaded at an extrusion temperature of 230° C. using a twin-screw extruder (TEX-28V; manufactured by The Japan Steel Works, Ltd.) and pelletized into pellets. The moisture content of the obtained pellets was about 0.008% by mass. The pellets were dried at 60°C for 8 hours and then used for evaluation of HDT (°C). The moisture content of the pellets after drying was about 0.0055% by mass. The method for evaluating HDT (°C) was as follows. The results are shown in Table 5.

[0158] <Load deflection temperature HDT(℃)>

[0159] The pellets obtained by granulation were injection molded using an injection molding machine (EC100-2A; manufactured by Toshiba Machine Co., Ltd.) at a mold temperature of 50°C and a resin temperature of 200°C to produce test pieces of size 80 mm×10 mm×4 mm. After standing in a constant temperature machine at 23°C for more than 48 hours, the HDT (°C) was measured according to ISO75 (load 0.45 MPa).

[0160] [Table 5]

[0161]

[0162] ※7: HDT when 0.3 parts by mass of water is added

[0163] ※8: HDT without adding water

[0164] ※9: Difference in HDT between when 0.3 parts by mass of water is added and when no water is added

[0165] [Example 6-1 to Example 6-2, Comparative Example 6-1 to Comparative Example 6-4]

[0166] 0.05 parts by mass of a phenolic antioxidant [tetrakis[methylene-3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate]methane], 0.1 parts by mass of a phosphorus antioxidant [tris(2,4-di-tert-butylphenyl)phosphite], 0.05 parts by mass of a calcium stearate, a nucleating agent in the amount described in Table 6, and water were mixed with 100 parts by mass of homopolypropylene (melt flow rate 8 g / 10 minutes; according to ISO Standard 1133, 2.16 kg×230° C.) as an olefin resin using a Henschel mixer at 1000 rpm×1 minute, and then melt-kneaded at an extrusion temperature of 230° C. using a twin-screw extruder (TEX-28V; manufactured by The Japan Steel Works, Ltd.) and pelletized into pellets. The moisture content of the obtained pellets was about 0.008% by mass. The pellets were dried at 60° C. for 8 hours and then used for evaluation of the half crystallization time (seconds). The moisture content of the pellets after drying was about 0.0055% by mass. These results are shown in FIG6 .

[0167] [Table 6]

[0168]

[0169] ※10: Half crystallization time when 0.3 parts by mass of water is added

[0170] ※11: Half crystallization time without adding water

[0171] ※12: Difference in half crystallization time when 0.3 parts by mass of water is added and when no water is added

[0172] [Example 7-1 to Example 7-2, Comparative Example 7-1 to Comparative Example 7-4]

[0173] 0.05 parts by mass of a phenolic antioxidant [tetrakis[methylene-3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate]methane], 0.1 parts by mass of a phosphorus antioxidant [tris(2,4-di-tert-butylphenyl)phosphite], 0.05 parts by mass of a calcium stearate, and a nucleating agent and water in the amounts described in Table 7 were mixed with 100 parts by mass of homopolypropylene (melt flow rate 8 g / 10 minutes; according to ISO Standard 1133, 2.16 kg×230° C.) as an olefin resin by a Henschel mixer at 1000 rpm×1 minute, and then melt-kneaded at an extrusion temperature of 230° C. using a twin-screw extruder (TEX-28V; manufactured by The Japan Steel Works, Ltd.) to form pellets. The moisture content of the pellets obtained by granulation was about 0.008% by mass. The pellets were dried at 60° C. for 8 hours and then used for evaluation of haze (%). The moisture content of the pellets after drying was about 0.0055% by mass. These results are shown in FIG. 7 .

[0174] [Table 7]

[0175]

[0176] ※13: Haze when 0.3 parts by mass of water is added

[0177] ※14: Haze when 0.005 parts by mass of water is added

[0178] ※15: Difference in Haze between adding 0.3 parts by mass of water and adding 0.005 parts by mass of water

[0179] [Example 8]

[0180] As an olefin resin, 60 parts by mass of "Novatec PP BC03B" (olefin block copolymer, melt flow rate 30 g / 10 minutes; according to ISO standard 1133, 2.16 kg × 230°C) manufactured by Japan Polypropylene Co., Ltd., 20 parts by mass of an olefin elastomer (product name "Engage 8200" of The Dow Chemical Company), 20 parts by mass of a filler (product name "Crown Talc PP" of Matsumura Sangyo Co., Ltd.), 0.05 parts by mass of a phenolic antioxidant [tetrakis[methylene-3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate]methane], 0.1 parts by mass of a phosphorus antioxidant [tris(2,4-di-tert-butylphenyl)phosphite], 0.05 parts by mass of a stearic acid calcium salt, and 0.05 parts by mass of a hindered amine compound (ADEKASTAB LA-81) 0.3 mass parts, 0.1 mass parts of compound 1 and 0.3 mass parts of water were mixed in a Henschel mixer at 1000rpm×1 minute, and then melt-kneaded at an extrusion temperature of 230°C using a twin-screw extruder (TEX-28V; manufactured by Nippon Steel Works, Ltd.), and granulated into pellets. The moisture content of the obtained pellets was about 0.008 mass%. The pellets were dried at 60°C for 8 hours, and injection molded at 230°C to obtain a test piece with a thickness of 2 mm. The moisture content of the dried pellets was about 0.0055 mass%. The obtained test piece had less coloring and excellent weather resistance, and good physical properties such as flexural modulus and crystallization temperature. The olefin resin composition of the present invention can be applied to automotive materials.

[0181] [Example 9]

[0182] 0.05 parts by mass of a phenolic antioxidant [tetrakis[methylene-3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate]methane], 0.1 parts by mass of a phosphorus antioxidant [tris(2,4-di-tert-butylphenyl)phosphite], 0.05 parts by mass of calcium stearate, 0.05 parts by mass of compound 1 and 0.3 parts by mass of water were mixed with 100 parts by mass of polypropylene having a melt flow rate of 3 g / 10 minutes as an olefin resin by a Henschel mixer at 1000 rpm×1 minute, and then melt-kneaded at an extrusion temperature of 230° C. using a twin-screw extruder (TEX-28V; manufactured by The Japan Steel Works, Ltd.) and granulated into pellets. The obtained pellets had a moisture content of about 0.008% by mass. The pellets were dried at 60° C. for 8 hours and extruded at 230° C. to obtain sheets having a thickness of 1 mm. The moisture content of the pellets after drying was about 0.0055% by mass. The transparency and strength of a cup formed by thermoforming the obtained sheet were good. The olefin resin composition of the present invention can be applied to packaging materials such as food containers and beverage containers.

[0183] [Example 10-1 to Example 10-9, Comparative Example 10-1 to Comparative Example 10-2]

[0184] 100 parts by mass of "Prime Poly Pro R720" (olefin random copolymer, melt flow rate 12 g / 10 min; according to ISO standard 1133, 2.16 kg×230° C.) manufactured by Prime Polymer Co., Ltd. as an olefin resin, 0.05 parts by mass of tetrakis[methylene-3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate]methane as a phenolic antioxidant, 0.1 parts by mass of tris(2,4-di-tert-butylphenyl)phosphite as a phosphorus antioxidant, 0.05 parts by mass of calcium stearate, 0.1 parts by mass of a nucleating agent listed in Table 8 as a nucleating agent, and a polyol compound listed in Table 8 as an auxiliary agent were blended in the amounts listed in Table 8, and mixed using a Henschel mixer at 1000 rpm×1 minute. The obtained mixture was melt-kneaded at an extrusion temperature of 230°C using a twin-screw extruder (TEX-28V; manufactured by The Japan Steel Works, Ltd.) and then granulated into pellets. Comparative Example 10-1 did not contain a nucleating agent and a polyol compound, and Comparative Example 10-2 did not contain a polyol compound. The obtained pellets were dried at 60°C for 8 hours and used for the evaluation of crystallization temperature (°C).

[0185] [Table 8]

[0186]

[0187] As described above, it was confirmed that the olefin resin composition of the present invention has excellent crystallinity. In addition, it was confirmed that the olefin resin composition of the present invention can provide a molded article having excellent mechanical properties and transparency.

Claims

1. A nucleating agent composition, characterized in that The invention comprises a nucleating agent and an auxiliary agent, wherein the nucleating agent comprises an aromatic phosphate metal salt represented by the following general formula (1), the auxiliary agent is at least one selected from the group consisting of glycols, sugar alcohols, mono-fatty acid esters of sugar alcohols and polyvinyl alcohol, and the content of the auxiliary agent is 1 to 10000 parts by mass relative to 100 parts by mass of the nucleating agent. In the general formula (1), R 1 ~R 4 represents an alkyl group having 1 to 6 carbon atoms, R 5 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and n represents 1 or 2. When n is 1, M represents lithium or dihydroxyaluminum, and when n is 2, M represents hydroxyaluminum.

2. An olefin resin composition, characterized in that The invention comprises an olefin resin, a nucleating agent and an auxiliary agent, wherein the nucleating agent comprises an aromatic phosphate metal salt represented by the following general formula (1), and the auxiliary agent is at least one selected from the group consisting of glycols, sugar alcohols, mono-fatty acid esters of sugar alcohols and polyvinyl alcohol. The nucleating agent is contained in an amount of 0.001 to 5 parts by mass and the auxiliary agent is contained in an amount of 0.003 to 10 parts by mass relative to 100 parts by mass of the olefin resin. In the general formula (1), R 1 ~R 4 represents an alkyl group having 1 to 6 carbon atoms, R 5 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and n represents 1 or 2. When n is 1, M represents lithium or dihydroxyaluminum, and when n is 2, M represents hydroxyaluminum.

3. A molded product, characterized in that: The olefin resin composition according to claim 2 is molded.

4. A method for producing an olefin resin composition, characterized in that: The manufacturing method comprises: A preparation step of preparing an olefin resin that does not contain a nucleating agent component; and a compounding step of compounding a nucleating agent and an auxiliary agent into the olefin resin not containing a nucleating agent component prepared in the preparation step to obtain an olefin resin compound; The nucleating agent comprises an aromatic phosphate metal salt represented by the following general formula (1): The auxiliary agent is at least one selected from the group consisting of glycols, sugar alcohols, mono-fatty acid esters of sugar alcohols and polyvinyl alcohol, In the mixing step, 0.001 to 5 parts by weight of the nucleating agent and 0.003 to 10 parts by weight of the auxiliary agent are mixed with 100 parts by weight of the olefin resin not containing the nucleating agent component. In the general formula (1), R 1 ~R 4 represents an alkyl group having 1 to 6 carbon atoms, R 5 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and n represents 1 or 2. When n is 1, M represents lithium or dihydroxyaluminum, and when n is 2, M represents hydroxyaluminum.

5. The method for producing an olefin resin composition according to claim 4, wherein The method further comprises a melt-kneading step of melt-kneading the olefin resin compound obtained in the compounding step to obtain an olefin resin composition.

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