A residue-reducing and environmentally friendly propylene oxide saponification reaction method

By using inorganic alkali with controlled particle size to carry out saponification reaction with chlorohydrin, the production process of propylene oxide has been optimized, solving the problems of excessive waste and high energy consumption in existing technologies, and realizing efficient and environmentally friendly propylene oxide production.

CN120289386BActive Publication Date: 2026-02-13SHANDONG BEFAR GRP DONGRUI CHEM CO LTD +1
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Patent Information

Application Number
CN202510447879.2
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2025-04-10
Publication Date
2026-02-13
Estimated Expiration
2045-04-10

AI Technical Summary

Technical Problem

Among the existing methods for producing propylene oxide, the chlorohydrin method generates a large amount of waste residue, the ethylbenzene co-oxidation method is energy-intensive and toxic, the isobutane co-oxidation method produces many byproducts, and the direct hydrogen peroxide oxidation method is costly. Existing technologies struggle to find a balance between environmental protection and economic efficiency.

Method used

Inorganic bases with an average particle size D≤1000μm, such as Ca(OH)2 or CaO, are used to carry out saponification reactions with chlorohydrins in the presence of alkali. The saponification reaction temperature is controlled at 80-95℃, and waste residue is reduced through concentration and acidification treatment to optimize the propylene oxide production process.

Benefits of technology

It improves the efficiency of saponification reaction, reduces the amount of calcium hydroxide used and the amount of solid waste produced, and has significant economic and environmental advantages.

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Abstract

The present application relates to a kind of residue reduction environmental protection's epoxy propane saponification reaction method.The method includes: chlorohydrin occurs epoxidation in the presence of alkali, obtains epoxy propane;Wherein, the average particle size D of the alkali≤1000 μm.The method of the present application significantly improves the saponification reaction and the production efficiency of epoxy propane, and can significantly reduce the amount of calcium hydroxide and solid waste production, with significant economic advantage and environmental advantage.
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