Organic compound, light-emitting device, display device, and electronic apparatus
By using organic compounds with bicyclic guanidine skeletons and aromatic skeletons as electron injection layers, the problem of degradation of the organic compound layer during lithography processing is solved, efficient electron injection is achieved, and the reliability of light-emitting devices and the performance of display devices are improved.
Patent Information
- Application Number
- CN202480011261.5
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Priority Date
- 2023-02-24
- Filing Date
- 2024-02-16
- Publication Date
- 2025-09-16
AI Technical Summary
When using existing lithography technology to process organic semiconductor films, especially organic compound layers containing donor substances, they are easily affected by oxygen or water in the atmosphere, resulting in increased driving voltage and decreased current efficiency, which is particularly significant in series-type light-emitting devices.
Organic compounds with bicyclic guanidine skeletons and aromatic skeletons are used as electron injection layers or intermediate layers to replace traditional donor substances. By increasing the hydrophobicity and alkalinity of the aromatic skeleton, the solubility in water is reduced, and the planarity is reduced by the distortion within the polysubstituted aromatic skeleton, thereby avoiding the degradation of properties during the lithography process.
It effectively prevents the driving voltage of the light-emitting device from rising sharply and the current efficiency from decreasing significantly, increases the glass transition temperature of the organic compound, and enhances the reliability of the light-emitting device and the resolution, aperture ratio and reliability of the display device.
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Figure CN120659786A_ABST
Abstract
Claims
1. An organic compound represented by the general formula (G1). [Chemical Formula 1] (Note that in the general formula (G1), Ar is an aromatic skeleton represented by the general formula (Ar-1), L represents an alkylene group having 1 to 10 carbon atoms, a substituted or unsubstituted arylene group having 6 to 30 carbon atoms, or a substituted or unsubstituted heteroarylene group having 1 to 11 carbon atoms, n represents an integer from 0 to 3, m represents an integer from 1 to 6, and R 1 to R 12 Each independently represents hydrogen (including deuterium) or an alkyl group having 1 to 10 carbon atoms. In addition, when n is 2 or more, L may be the same or different from each other, and when m is 2 or more, L may be the same or different from each other, n may be the same or different from each other, and R 1 to R 12 In the general formula (Ar-1), ring A represents a benzene ring or a naphthalene ring, and Ar 1 to Ar 3 Each independently represents a substituted or unsubstituted aryl group having 6 to 30 carbon atoms or a substituted or unsubstituted heteroaryl group having 1 to 30 carbon atoms, Ring A and Ar 1 to Ar 3 Any m of the included carbon atoms have m bonds in the general formula (G1), k represents an integer from 1 to 3, and p represents an integer from 2 to 6. Note that a plurality of Ar 2 In addition, when k is 2 or more, p may be the same or different, and ring A may be the same or different, and Ar 2 They may be the same or different from each other.) 2. An organic compound represented by the general formula (G1). [Chemical Formula 2] (Note that in the general formula (G1), Ar is an aromatic skeleton represented by the general formula (Ar-2), L represents an alkylene group having 1 to 10 carbon atoms, a substituted or unsubstituted arylene group having 6 to 30 carbon atoms, or a substituted or unsubstituted heteroarylene group having 1 to 11 carbon atoms, n represents an integer from 0 to 3, m represents an integer from 1 to 6, and R 1 to R 12 Each independently represents hydrogen (including deuterium) or an alkyl group having 1 to 10 carbon atoms. In addition, when n is 2 or more, L may be the same or different from each other, and when m is 2 or more, L may be the same or different from each other, n may be the same or different from each other, and R 1 to R 12 They may be the same or different from each other. 1 to Ar 3 Each independently represents a substituted or unsubstituted aryl group having 6 to 30 carbon atoms or a substituted or unsubstituted heteroaryl group having 1 to 30 carbon atoms, Ar 1 to Ar 3 Any m of the included carbon atoms have m bonds in the general formula (G1), R 26 represents hydrogen (including deuterium), an alkyl group having 1 to 10 carbon atoms, a cycloalkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a substituted or unsubstituted heteroaryl group having 1 to 30 carbon atoms, k represents an integer from 1 to 3, and q represents an integer from 2 to 4. Note that multiple Ar 2 Also, when k is 2 or more, p may be the same or different from each other. 26 They may also be the same or different from each other, and Ar 2 They may be the same or different from each other.) 3. An organic compound represented by the general formula (G1). [Chemical Formula 3] (Note that in the general formula (G1), Ar is an aromatic skeleton represented by the general formula (Ar-3), L represents an alkylene group having 1 to 10 carbon atoms, a substituted or unsubstituted arylene group having 6 to 30 carbon atoms, or a substituted or unsubstituted heteroarylene group having 1 to 11 carbon atoms, n represents an integer from 0 to 3, m represents an integer from 1 to 6, and R 1 to R 12 Each independently represents hydrogen (including deuterium) or an alkyl group having 1 to 10 carbon atoms. In addition, when n is 2 or more, L may be the same or different from each other, and when m is 2 or more, L may be the same or different from each other, n may be the same or different from each other, and R 1 to R 12 They may be the same or different from each other. 21 to R 46 Any m of them represent m bonding positions in the general formula (G1), R 21 to R 46 The others in the group independently represent hydrogen (including deuterium), an alkyl group having 1 to 10 carbon atoms, a cycloalkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a substituted or unsubstituted heteroaryl group having 1 to 30 carbon atoms.
4. An organic compound represented by the general formula (G2). [Chemical Formula 4] (Note that in the general formula (G2), L represents an alkylene group having 1 to 10 carbon atoms, a substituted or unsubstituted arylene group having 6 to 30 carbon atoms, or a substituted or unsubstituted heteroarylene group having 1 to 11 carbon atoms, n represents an integer from 0 to 3, and R 1 to R 12 Each independently represents hydrogen (including deuterium) or an alkyl group having 1 to 10 carbon atoms. When n is 2 or greater, L may be the same or different. 21 to R 27 and R 29 to R 46 Each independently represents hydrogen (including deuterium), an alkyl group having 1 to 10 carbon atoms, a cycloalkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a substituted or unsubstituted heteroaryl group having 1 to 30 carbon atoms.
5. An organic compound represented by structural formula (100). [Chemical Formula 5] 6 . A light-emitting device using the organic compound according to claim 1 .
7. A display device comprising: The light-emitting device according to claim 6; as well as transistor or substrate.
8. An electronic device comprising: The display device according to claim 7; as well as Detection unit, input unit or communication unit.
Citation Information
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