Lithium manganese iron phosphate positive electrode material and preparation method thereof, positive electrode plate and lithium ion battery

By coating the surface of the lithium manganese iron phosphate core with a lithium iron phosphate shell, the problem of poor high-temperature storage performance of lithium manganese iron phosphate material is solved, achieving high-capacity and high-temperature stable lithium-ion battery performance.

CN120854541AActive Publication Date: 2025-10-28SICHUAN FULIN NEW ENERGY TECH CO LTD
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Patent Information

Application Number
CN202511350367.0
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-09-22
Publication Date
2025-10-28
Estimated Expiration
2045-09-22

AI Technical Summary

Technical Problem

Lithium manganese iron phosphate materials have poor high-temperature storage performance. After nano-sizing, the small particle size of the material leads to increased electrolyte erosion, increased Mn3+ disproportionation reaction, consumption of active lithium ions, and affects high-temperature storage performance.

Method used

Using lithium iron phosphate as the coating layer, it is uniformly coated on the surface of lithium manganese iron phosphate core through in-situ precipitation technology, which reduces electrolyte contact, reduces Mn3+ disproportionation reaction, and improves high-temperature cycle performance and storage performance.

Benefits of technology

It effectively isolates the electrolyte from corroding the lithium manganese iron phosphate core, reduces the Mn3+ disproportionation reaction, improves the high-temperature storage performance and capacity performance of the material, and achieves high capacity and high-temperature stability.

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Abstract

The invention discloses a lithium manganese iron phosphate positive electrode material and a preparation method thereof, a positive electrode plate and a lithium ion battery, and relates to the technical field of lithium ion batteries. The lithium manganese iron phosphate positive electrode material comprises a lithium manganese iron phosphate inner core and a coating shell layer, the surface of the lithium manganese iron phosphate inner core is coated with the coating shell layer; the coating shell layer comprises lithium iron phosphate; the positive electrode material can solve the problem of poor high-temperature storage performance of the lithium manganese iron phosphate material, so that the lithium manganese iron phosphate material has high capacity and high-temperature storage stability.
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