Vinyl resin electrolytic bath and preparation method thereof

Abstract

The embodiment of the invention provides a vinyl resin electrolytic bath and a preparation method thereof, the vinyl resin electrolytic bath comprises an electrolytic bath body, the electrolytic bath body at least comprises a casting layer, the casting layer is formed by mixing and curing aggregate and an adhesive, the aggregate comprises barium sulfate, and the use amount of the barium sulfate is 85-90% of the weight of the casting layer.

Description

Technical Field

[0001] This specification relates to the field of electrolytic cells, and in particular to a vinyl resin electrolytic cell and its preparation method. Background Technology

[0002] With the increasing maturity of electrolysis technology, vinyl ester resin electrolytic cells are widely used in the electrolysis, electrowinning, and electrosolubilization of metals such as cobalt, copper, lead, and zinc. Currently, the concrete electrolytic cells commonly used in the domestic non-ferrous metal hydrometallurgical industry are prone to damage and destruction of their anti-corrosion layers, resulting in a short average lifespan. Developing vinyl ester resin electrolytic cells that meet production process requirements and have a long service life is of great significance to the electrolysis industry. Therefore, it is necessary to provide a vinyl ester resin electrolytic cell and its preparation method, which possesses excellent corrosion resistance, long service life, and low maintenance costs. Summary of the Invention

[0003] One embodiment of this specification provides a vinyl resin electrolytic cell, the vinyl resin electrolytic cell comprising an electrolytic cell body, the electrolytic cell body comprising at least a casting layer, the casting layer being formed by mixing and curing aggregates and binders, the aggregates comprising barium sulfate, wherein the amount of barium sulfate is 85%-90% of the weight of the casting layer.

[0004] In some embodiments, the aggregate comprises barium sulfate of the following mesh sizes by weight percentage: 6-8 mesh 20%-40%, 10-20 mesh 20%-30%, 30-70 mesh 5%-15%, 70-140 mesh 5%-15%, and 200-300 mesh 5%-10%.

[0005] In some embodiments, the adhesive comprises the following components by weight percentage: 90%-95% vinyl resin, 3%-10% diluent, 1%-5% curing agent, and 0.1%-2% accelerator.

[0006] In some embodiments, the electrolytic cell further includes an inner anti-corrosion layer and an outer anti-corrosion layer, wherein the inner anti-corrosion layer is located inside the casting layer and the outer anti-corrosion layer is located outside the casting layer.

[0007] In some embodiments, the inner anti-corrosion layer is made of polyester surface felt and vinyl resin. The manufacturing process includes mixing the polyester surface felt and the vinyl resin by hand application and then curing them. The amount of polyester surface felt is 15%-30% of the weight of the inner anti-corrosion layer, and the amount of vinyl resin is 70%-85% of the weight of the inner anti-corrosion layer.

[0008] In some embodiments, the outer anti-corrosion layer is made of polyester surface felt and vinyl resin, the manufacturing process including mixing the polyester surface felt and the vinyl resin by hand coating and then curing; the amount of polyester surface felt is 15%-30% of the weight of the inner anti-corrosion layer; the amount of vinyl resin is 70%-85% of the weight of the inner anti-corrosion layer.

[0009] In some embodiments, the vinyl resin electrolytic cell further includes a slag discharge hole and a liquid discharge hole, both of which are located at the bottom of the electrolytic cell body, and connecting parts are pre-embedded on the slag discharge hole and / or the liquid discharge hole.

[0010] One embodiment of this specification provides a method for manufacturing a vinyl ester resin electrolytic cell, comprising: manufacturing a steel mold; applying a polyester surface felt to the surface of the steel mold using vinyl ester resin; assembling the steel mold to obtain an assembled steel mold; preparing an adhesive; adding aggregate to the adhesive and mixing to obtain a casting layer material; wherein the aggregate includes barium sulfate, and the amount of barium sulfate is 85%-90% of the weight of the casting layer material; pouring the casting layer material into the assembled steel mold, pre-embedding connectors, and obtaining a vinyl ester resin electrolytic cell after vibration and curing treatment.

[0011] In some embodiments, the aggregate comprises barium sulfate of the following mesh sizes by weight percentage: 6-8 mesh 20%-40%, 10-20 mesh 20%-30%, 30-70 mesh 5%-15%, 70-140 mesh 5%-15%, and 200-300 mesh 5%-10%.

[0012] In some embodiments, the adhesive comprises the following components by weight percentage: 90%-95% vinyl resin, 3%-10% diluent, 1%-5% curing agent, and 0.1%-2% accelerator. Attached Figure Description

[0013] This specification will be further described by way of exemplary embodiments, which will be described in detail with reference to the accompanying drawings. These embodiments are not limiting; in these embodiments, the same reference numerals denote the same structures, wherein:

[0014] Figure 1 This is a schematic diagram of an exemplary vinyl resin electrolyzer according to some embodiments of this specification;

[0015] Figure 2 This is a flowchart illustrating an exemplary method for manufacturing a vinyl resin electrolytic cell according to some embodiments of this specification. Detailed Implementation

[0016] To more clearly illustrate the technical solutions of the embodiments in this specification, the accompanying drawings used in the description of the embodiments will be briefly introduced below. Obviously, the drawings described below are merely some examples or embodiments of this specification. For those skilled in the art, these drawings can be applied to other similar scenarios without creative effort. Unless obvious from the context or otherwise specified, the same reference numerals in the drawings represent the same structures or operations.

[0017] It should be understood that the terms “system,” “device,” “unit,” and / or “module” used herein are one way to distinguish different components, elements, parts, sections, or assemblies at different levels. However, if other terms can achieve the same purpose, they may be replaced by other expressions.

[0018] As indicated in this specification and claims, unless the context clearly indicates otherwise, the words "a," "an," "an," and / or "the" do not specifically refer to the singular and may also include the plural. Generally speaking, the terms "comprising" and "including" only indicate the inclusion of expressly identified steps and elements, which do not constitute an exclusive list, and the method or apparatus may also include other steps or elements.

[0019] Flowcharts are used in this specification to illustrate the operations performed by the system according to embodiments of this specification. It should be understood that the preceding or following operations are not necessarily performed in exact order. Instead, the steps can be processed in reverse order or simultaneously. Furthermore, other operations can be added to these processes, or one or more steps can be removed from them.

[0020] Figure 1 This is a schematic diagram of a vinyl ester resin electrolytic cell according to some embodiments of this specification. It is important to note that the following embodiments are merely illustrative of this specification and do not constitute a limitation thereof. In some embodiments, the vinyl ester resin electrolytic cell can be used for the hydrometallurgical smelting of metals such as nickel, cobalt, copper, lead, and zinc. In some embodiments, the vinyl ester resin electrolytic cell can be the site where an electrochemical reaction occurs. In some embodiments, the vinyl ester resin electrolytic cell can be manufactured by lining a steel mold with polyester surface felt using vinyl ester resin. In some embodiments, the vinyl ester resin electrolytic cell can include a vinyl ester resin barium sulfate electrolytic cell, a vinyl ester resin concrete electrolytic cell, etc.

[0021] In some embodiments, such as Figure 1 As shown, the vinyl resin electrolytic cell 100 may include an electrolytic cell body 110, which may be the main structure of the electrolytic cell.

[0022] In some embodiments, the electrolytic cell body 110 may include a casting layer 111. In some embodiments, the casting layer 111 may refer to the structure of an electrolytic cell body made using a casting method. In some embodiments, the casting method may refer to a method of injecting liquid monomers, resins, or any mixtures into a mold under no pressure or with slight pressure to form an article. In some embodiments, the casting layer 111 may be formed by mixing and curing aggregates and binders. The aggregates may be materials that serve as a skeleton and filler. In some embodiments, the aggregates may include barium sulfate, and the amount of barium sulfate may be 85%-90% of the total weight of the casting layer 111.

[0023] In some embodiments, the aggregate may have different particle sizes, such as 6 mesh, 10 mesh, 70 mesh, 200 mesh, etc. In some embodiments, the aggregate may comprise barium sulfate in the following mesh sizes by weight percentage: 6-8 mesh 20%-40%, 10-20 mesh 20%-30%, 30-70 mesh 5%-15%, 70-140 mesh 5%-15%, 200-300 mesh 5%-10%. In some embodiments, the aggregate may comprise barium sulfate in the following mesh sizes by weight percentage: 6-8 mesh 25%-35%, 10-20 mesh 23%-35%, 30-70 mesh 7%-15%, 70-140 mesh 7%-15%, 200-300 mesh 5%-10%. In some embodiments, the aggregate may comprise barium sulfate in the following mesh sizes by weight percentage: 6-8 mesh 25%-35%, 10-20 mesh 25%-30%, 30-70 mesh 12%-18%, 70-140 mesh 12%-18%, and 200-300 mesh 5%-8%.

[0024] The adhesive can be a material that acts as a bond. In some embodiments, the adhesive may comprise the following components by weight percentage: 90%-95% vinyl resin, 3%-10% diluent, 1%-5% curing agent, and 0.1%-2% accelerator.

[0025] In some embodiments, the diluent may be one or more of, but not limited to, styrene and other similar substances.

[0026] In some embodiments, the curing agent may be one or more combinations of, but not limited to, methyl ethyl ketone peroxide, copper cyclohexyl peroxide, etc. Preferably, the curing agent may be methyl ethyl ketone peroxide.

[0027] In some embodiments, the accelerator may be one or more combinations of cobalt naphthenate, cobalt isooctanoate, etc. Preferably, the accelerator may be cobalt isooctanoate.

[0028] In some embodiments, the electrolytic cell body 110 may further include an inner anti-corrosion layer 112 and an outer anti-corrosion layer 113, with the inner anti-corrosion layer 112 located inside the casting layer 111 and the outer anti-corrosion layer 113 located outside the casting layer 111.

[0029] In some embodiments, the inner anti-corrosion layer 112 may be formed by bonding and curing a polyester surface felt and a vinyl ester resin. In some embodiments, the amount of polyester surface felt may be 15%-30% of the weight of the inner anti-corrosion layer 112. In some embodiments, the amount of polyester surface felt may be 18%-27% of the weight of the inner anti-corrosion layer 112. In some embodiments, the amount of polyester surface felt may be 21%-24% of the weight of the inner anti-corrosion layer 112. In some embodiments, the amount of vinyl ester resin may be 70%-85% of the weight of the inner anti-corrosion layer 112. In some embodiments, the amount of vinyl ester resin may be 73%-82% of the weight of the inner anti-corrosion layer 112. In some embodiments, the amount of vinyl ester resin may be 76%-79% of the weight of the inner anti-corrosion layer 112. For a method of manufacturing the inner anti-corrosion layer 112, please refer to [reference needed]. Figure 2 The relevant descriptions will not be repeated here.

[0030] In some embodiments, the outer anti-corrosion layer 113 may be formed by bonding and curing a polyester surface felt and a vinyl ester resin. In some embodiments, the amount of polyester surface felt may be 15%-30% of the weight of the inner anti-corrosion layer 112. In some embodiments, the amount of polyester surface felt may be 18%-27% of the weight of the outer anti-corrosion layer 113. In some embodiments, the amount of polyester surface felt may be 21%-24% of the weight of the outer anti-corrosion layer 113. In some embodiments, the amount of vinyl ester resin may be 70%-85% of the weight of the outer anti-corrosion layer 113. In some embodiments, the amount of vinyl ester resin may be 73%-82% of the weight of the outer anti-corrosion layer 113. In some embodiments, the amount of vinyl ester resin may be 76%-79% of the weight of the outer anti-corrosion layer 113.

[0031] In some embodiments, the vinyl resin electrolytic cell 100 may further include a slag discharge hole 120, which is disposed at the bottom of the electrolytic cell. The slag discharge hole 120 can be used to remove the waste residue generated during the electrolysis process after the electrolysis reaction is completed, so as to avoid the slag generated by electrolysis from accumulating in the cell and solidifying with the inner wall of the electrolytic cell, making it difficult to clean and affecting the next electrolysis reaction.

[0032] In some embodiments, the vinyl resin electrolytic cell 100 may further include a drain hole 130, which is disposed at the bottom of the electrolytic cell body. The drain hole 130 can be used to drain the remaining electrolyte or waste liquid after electrolysis after the electrolysis production is completed, so as to keep the vinyl resin electrolytic cell clean and facilitate the next electrolysis production.

[0033] In some embodiments, connectors 140 and 150 may be pre-embedded on the slag discharge hole 120 and / or liquid discharge hole 130. The connectors can be used to connect pipes to discharge the waste slag and / or waste liquid generated in the electrolysis production to a designated location.

[0034] Figure 2 This is a flowchart illustrating an exemplary method for manufacturing a vinyl resin electrolytic cell according to some embodiments of this specification.

[0035] Step 210: Make a steel mold. After applying polyester surface felt to the surface of the steel mold with vinyl resin, assemble the steel mold to obtain the assembled steel mold.

[0036] The steel mold can be an electrolytic cell mold made of steel. In some embodiments, the steel mold can be used for injection molding of vinyl resin electrolytic cells. In some embodiments, the steel mold can be manufactured according to parameters such as the volume required for actual production and dimensions preset based on experience.

[0037] In some embodiments, the surface of the steel mold can be polished and waxed. In some embodiments, a layer of vinyl resin is evenly applied to the surface of the steel mold to form a gel coat, and 3-5 layers of polyester surface felt are attached. After it is fully cured, the steel mold is assembled and fastened, and then assembled on a vibrating bed in an upside-down manner to obtain the assembled steel mold.

[0038] By fabricating a steel mold and lining its surface with polyester surface felt using vinyl ester resin, an electrolytic cell mold that meets actual production needs can be obtained. This facilitates the subsequent application of polyester surface felt during electrolytic cell preparation, providing corrosion protection, leakage prevention, and liquid crystallization prevention, while simplifying the process and saving time and costs.

[0039] Step 220: Prepare the adhesive and add aggregate to the adhesive and mix to obtain the casting layer raw material.

[0040] In some embodiments, the vinyl resin can be mixed with diluent, curing agent and accelerator in the following weight percentage ratio: 90%-95% vinyl resin, 3%-10% diluent, 1%-5% curing agent and 0.1%-2% accelerator by weight, with a stirring speed of 500r / min-700r / min and a stirring time of 8min-15min.

[0041] For more information about the adhesive, please refer to the foregoing content and related descriptions in the instruction manual.

[0042] In some embodiments, aggregates may be added to the prepared binder and mixed to obtain the casting layer material. In some embodiments, the aggregates may include barium sulfate, with the amount of barium sulfate being 85%-90% of the weight of the casting layer material. In some embodiments, the aggregates may include barium sulfate of the following mesh sizes by weight percentage: 6-8 mesh 20%-40%, 10-20 mesh 20%-30%, 30-70 mesh 5%-15%, 70-140 mesh 5%-15%, and 200-300 mesh 5%-10%. The mixing speed is 60 r / min-90 r / min. The mixing time is 5 min-15 min.

[0043] For more information about aggregates, please refer to the foregoing content and related descriptions in the instruction manual.

[0044] By preparing a binder and adding aggregates to obtain the casting layer raw material, a uniformly mixed casting layer raw material can be obtained, which is convenient to add directly during the subsequent preparation of the electrolytic cell, and prevents the waste of manpower and material resources and production errors caused by repeated addition.

[0045] Step 230: Pour the casting layer material into the assembled steel mold and pre-embed the connectors. After vibration and curing treatment, a vinyl resin electrolytic cell is obtained.

[0046] In some embodiments, the casting material can be poured into the assembled steel mold, and connectors can be pre-embedded in the slag discharge hole and / or liquid discharge hole at the bottom of the electrolytic cell.

[0047] In some embodiments, the raw material of the casting layer, which is loaded into a steel mold, can be vibrated and cured, and then ejected using tools such as jacks to obtain a vinyl resin electrolytic cell.

[0048] In some embodiments, vibration treatment may involve vibrating the casting material placed in a steel mold as a whole. In some embodiments, the vibration frequency may be 40Hz to 120Hz. The vibration time may be 30min to 60min.

[0049] In some embodiments, the curing process may involve curing the vibration-treated casting material placed in a steel mold under constant temperature conditions. In some embodiments, the constant temperature may be 35-40 degrees Celsius. In some embodiments, the curing time may be 12-24 hours.

[0050] By pre-embedded connectors, pipe connections can be easily made and disassembled; after vibration and curing treatment, a vinyl resin electrolytic cell with a smooth surface, shape that fits the steel mold, and stable quality can be obtained, reducing the problem of unevenness in the vinyl resin electrolytic cell caused by insufficient vibration and curing.

[0051] In some embodiments, the method for manufacturing a vinyl resin electrolytic cell further includes processing operations such as deburring the surface after demolding, scraping the surface slurry, and spraying anti-corrosion coating.

[0052] It should be noted that the above description of process 200 is for illustrative purposes only and does not limit the scope of this specification. Those skilled in the art can make various modifications and changes to process 200 under the guidance of this specification. However, these modifications and changes are still within the scope of this specification. For example, performing step 220 before step 210, etc.

[0053] The vinyl resin electrolyzer and its preparation method will be described in detail below through Examples 1-12. It should be noted that the reaction conditions, reactants, and amounts of reactants in Examples 1-12 are only for illustrating the vinyl resin electrolyzer and its preparation method, and do not limit the scope of protection of this application. Example 1

[0054] This embodiment relates to the preparation of a vinyl resin electrolytic cell, and the specific preparation process includes the following steps:

[0055] Step 1: Make a steel mold. After applying polyester surface felt to the surface of the steel mold with vinyl resin, assemble the steel mold to obtain the assembled steel mold.

[0056] Step 2: Prepare the adhesive by weight percentage of 94% vinyl resin, 3% diluent, 1% accelerator, and 2% curing agent. Mix and stir for 2 minutes, then add the aggregate to the adhesive and mix for 10 minutes to obtain the casting layer material. The adhesive accounts for 15% of the casting layer material by weight, and the aggregate accounts for 85%. The aggregate consists of barium sulfate of the following mesh sizes by weight percentage: 6-8 mesh 15%, 10-20 mesh 25%, 30-70 mesh 30%, 70-140 mesh 15%, and 200-300 mesh 15%.

[0057] Step 3: Pour the casting layer material into the assembled steel mold and pre-embed the connectors. After vibration and curing treatment, a vinyl resin electrolytic cell is obtained. Example 2

[0058] This embodiment relates to the preparation of a vinyl resin electrolytic cell, and the specific preparation process includes the following steps:

[0059] Steps 1 and 3 are the same as in Example 1. In step 2, the aggregate consists of barium sulfate of the following mesh sizes by weight percentage: 6-8 mesh 20%, 10-20 mesh 30%, 30-70 mesh 20%, 70-140 mesh 20%, and 200-300 mesh 10%. The remaining operations are the same as in Example 1. Example 3

[0060] This embodiment relates to the preparation of a vinyl resin electrolytic cell, and the specific preparation process includes the following steps:

[0061] Steps 1 and 3 are the same as in Example 1. In step 2, the aggregate consists of barium sulfate of the following mesh sizes by weight percentage: 6-8 mesh 28%, 10-20 mesh 35%, 30-70 mesh 15%, 70-140 mesh 12%, and 200-300 mesh 10%. The remaining operations are the same as in Example 1.

[0062] The mechanical property test results of the sample tanks prepared in Examples 1-3 above are shown in Table 1 below. The mechanical properties are represented by bending strength and compressive strength. The higher the bending strength and compressive strength, the better the mechanical properties.

[0063] Table 1 Mechanical Performance Test Table for Examples 1-3

[0064] By comparing Examples 1 to 3, it can be seen that Example 3, with aggregate weight percentages within the ranges of 6-8 mesh 20-40%, 10-20 mesh 20-30%, 30-70 mesh 5-15%, 70-140 mesh 5-15%, and 200-300 mesh 5-10% as described in the aforementioned specification, exhibits the best flexural strength and compressive strength, and corresponding optimal mechanical properties. Example 4

[0065] This embodiment relates to the preparation of a vinyl resin electrolytic cell, and the specific preparation process includes the following steps:

[0066] Steps 2 and 3 are the same as in Example 3. In step 1, the size of the vinyl resin electrolytic cell cast by the steel mold is 30cm*30cm*30cm. The rest of the operation is the same as in Example 3.

[0067] Step 4: Prepare a test sample with a size of 80mm*80mm using the same raw material formulation as in Step 2 of Example 3.

[0068] Step 5: Prepare a 190g / L fluorosilicic acid aqueous solution in the cast small square tank, heat the liquid to 40 degrees Celsius with a heating rod, and then immerse the prepared test sample in the liquid for a 30-day immersion test. Example 5

[0069] This embodiment relates to the preparation of a vinyl resin electrolytic cell, and the specific preparation process includes the following steps:

[0070] Step 1: Make a steel mold. After applying polyester surface felt to the surface of the steel mold with vinyl resin, assemble the steel mold to obtain the assembled steel mold.

[0071] Step 2: Prepare the adhesive by weight percentage of 94% vinyl resin, 3% diluent, 1% accelerator, and 2% curing agent. Mix and stir for 2 minutes, then add aggregate to the adhesive and mix for 10 minutes to obtain the casting layer material. The adhesive accounts for 20% of the weight percentage of the casting layer material, and the aggregate accounts for 80% of the weight percentage, with barium sulfate comprising 100% of the aggregate.

[0072] Step 3: Pour the casting layer material into the assembled steel mold and pre-embed the connectors. After vibration and curing treatment, a vinyl resin electrolytic cell is obtained. Example 6

[0073] This embodiment relates to the preparation of a vinyl resin electrolytic cell, and the specific preparation process includes the following steps:

[0074] Steps 1 and 3 are the same as in Example 5. In step 2, the binder accounts for 10% of the weight percentage of the raw material of the casting layer, the aggregate accounts for 90% of the weight percentage of the raw material of the casting layer, and the barium sulfate content in the aggregate is 100%. The remaining operations are the same as in Example 5. Example 7

[0075] This embodiment relates to the preparation of a vinyl resin electrolytic cell, and the specific preparation process includes the following steps:

[0076] Steps 1 and 3 are the same as in Example 5. In step 2, the binder accounts for 15% of the weight percentage of the raw material of the casting layer, the aggregate accounts for 85% of the weight percentage of the raw material of the casting layer, and the barium sulfate content in the aggregate is 100%. The remaining operations are the same as in Example 5.

[0077] The mechanical property test results of the sample tanks prepared in Examples 5-7 are shown in Table 1 below. The mechanical properties are represented by bending strength and compressive strength. The higher the bending strength and compressive strength, the better the mechanical properties.

[0078] Table 2 Mechanical Performance Test Tables for Examples 5-7

[0079] By comparing Examples 5-7, it can be seen that Example 7, in which the binder accounts for 15% of the weight percentage of the casting layer raw material, the aggregate accounts for 85% of the weight percentage of the casting layer raw material, and the barium sulfate content in the aggregate is 100%, has the best flexural strength and compressive strength, and the corresponding mechanical properties are optimal. Example 8

[0080] This embodiment relates to the preparation of a vinyl resin electrolytic cell, and the specific preparation process includes the following steps:

[0081] Steps 2 and 3 are the same as in Example 7. In step 1, the steel mold corresponds to a vinyl resin electrolytic cell with dimensions of 30cm*30cm*30cm. The remaining operations are the same as in Example 1.

[0082] Step 4: Prepare a test sample with a size of 80mm*80mm using the same raw material formulation as in Step 2 of Example 7.

[0083] Step 5: Prepare a 190g / L fluorosilicic acid aqueous solution in the cast small square tank, heat the liquid to 40 degrees Celsius with a heating rod, and then immerse the prepared test sample in the liquid for a 30-day immersion test.

[0084] As can be seen from Example 8, Example 7, which uses the raw material aggregate, vinyl resin and polyester surface felt of the vinyl resin electrolytic cell described in this specification, and in which the weight percentage of barium sulfate in the casting layer is within the range of 85%-90% as described in the aforementioned specification, has good resistance to hydrofluoric acid corrosion.

[0085] The beneficial effects that the embodiments of this application may bring include, but are not limited to: (1) the vinyl resin electrolytic cell prepared by integral casting of vinyl resin and barium sulfate and covered with polyester surface felt can effectively resist hydrofluoric acid generated during lead electrolysis and has good hydrofluoric acid corrosion resistance; (2) the vinyl resin electrolytic cell prepared by using barium sulfate in the casting layer at a weight ratio of 85%-90% as described in this specification has improved mechanical properties and hydrofluoric acid corrosion resistance compared with vinyl resin electrolytic cells prepared by other components and ratios, which can effectively improve the service life of lead electrolytic cells and reduce maintenance costs. It should be noted that the beneficial effects that may be produced by different embodiments are different. In different embodiments, the beneficial effects that may be produced can be any one or a combination of the above, or any other possible beneficial effects.

[0086] The basic concepts have been described above. Obviously, for those skilled in the art, the detailed disclosure above is merely illustrative and does not constitute a limitation of this specification. Although not explicitly stated herein, those skilled in the art may make various modifications, improvements, and corrections to this specification. Such modifications, improvements, and corrections are suggested in this specification and therefore remain within the spirit and scope of the exemplary embodiments described herein.

[0087] Furthermore, this specification uses specific terms to describe embodiments thereof. For example, "an embodiment," "one embodiment," and / or "some embodiments" refer to a particular feature, structure, or characteristic associated with at least one embodiment of this specification. Therefore, it should be emphasized and noted that references to "an embodiment," "one embodiment," or "an alternative embodiment" in different locations throughout this specification do not necessarily refer to the same embodiment. Moreover, certain features, structures, or characteristics in one or more embodiments of this specification can be appropriately combined.

[0088] Furthermore, unless expressly stated in the claims, the order of processing elements and sequences, the use of numbers and letters, or other names described in this specification are not intended to limit the order of the processes and methods described herein. Although some inventive embodiments that are currently considered useful have been discussed by way of various examples in the foregoing disclosure, it should be understood that such details are for illustrative purposes only, and the appended claims are not limited to the disclosed embodiments. Rather, the claims are intended to cover all modifications and equivalent combinations that conform to the substance and scope of the embodiments described herein.

[0089] Similarly, it should be noted that, in order to simplify the description disclosed herein and thus aid in the understanding of one or more embodiments of the invention, the foregoing description of embodiments in this specification may sometimes combine multiple features into a single embodiment, drawing, or description thereof. However, this method of disclosure does not imply that the subject matter of this specification requires more features than those mentioned in the claims. In fact, the embodiments contain fewer features than all the features of a single embodiment disclosed above.

[0090] In some embodiments, numbers describing the quantity of components and attributes are used. It should be understood that such numbers used in the description of embodiments are modified in some examples with the terms "approximately," "approximately," or "generally." Unless otherwise stated, "approximately," "approximately," or "generally" indicates that the numbers are allowed to vary by ±20%. Accordingly, in some embodiments, the numerical parameters used in the specification and claims are approximate values, which may be changed depending on the characteristics required by individual embodiments. In some embodiments, numerical parameters should take into account specified significant digits and employ a general method of digit reservation. Although the numerical ranges and parameters used to confirm their breadth of range in some embodiments of this specification are approximate values, in specific embodiments, such values ​​are set as precisely as feasible.

[0091] For each patent, patent application, patent application publication, and other material, such as articles, books, specifications, publications, and documents, referenced in this specification, the entire contents of which are incorporated herein by reference. This excludes historical application documents that are inconsistent with or conflict with the content of this specification, as well as documents that limit the broadest scope of the claims in this specification (currently or subsequently appended to this specification). It should be noted that in the event of any inconsistency or conflict between the descriptions, definitions, and / or terminology used in the supplementary materials to this specification and the content of this specification, the descriptions, definitions, and / or terminology used in this specification shall prevail.

[0092] Finally, it should be understood that the embodiments described in this specification are merely illustrative of the principles of the embodiments described herein. Other variations may also fall within the scope of this specification. Therefore, alternative configurations of the embodiments described herein are intended to be illustrative rather than limiting, and should be considered consistent with the teachings of this specification. Accordingly, the embodiments described herein are not limited to those explicitly introduced and described herein.

Claims

1. A vinyl resin electrolytic cell, characterized in that, The vinyl resin electrolytic cell includes an electrolytic cell body, which includes at least a casting layer. The casting layer is formed by mixing and curing aggregates and binders. The aggregates include barium sulfate, wherein the amount of barium sulfate is 85%-90% of the weight of the casting layer.

2. The vinyl resin electrolytic cell according to claim 1, characterized in that, The aggregate comprises barium sulfate of the following mesh sizes by weight percentage: 6-8 mesh 20%-40%, 10-20 mesh 20%-30%, 30-70 mesh 5%-15%, 70-140 mesh 5%-15%, and 200-300 mesh 5%-10%.

3. The vinyl resin electrolytic cell according to claim 1, characterized in that, The adhesive comprises the following components by weight percentage: 90%-95% vinyl resin, 3%-10% diluent, 1%-5% curing agent, and 0.1%-2% accelerator.

4. The vinyl resin electrolytic cell according to claim 1, characterized in that, The electrolytic cell also includes an inner anti-corrosion layer and an outer anti-corrosion layer. The inner anti-corrosion layer is located inside the casting layer, and the outer anti-corrosion layer is located outside the casting layer.

5. The vinyl resin electrolytic cell according to claim 4, characterized in that, The inner anti-corrosion layer is made of polyester surface felt and vinyl resin. The manufacturing process includes mixing the polyester surface felt and the vinyl resin by hand application and then curing them. The amount of polyester surface felt is 15%-30% of the weight of the inner anti-corrosion layer, and the amount of vinyl resin is 70%-85% of the weight of the inner anti-corrosion layer.

6. The vinyl resin electrolytic cell according to claim 4, characterized in that, The outer anti-corrosion layer is made of polyester surface felt and vinyl resin. The manufacturing process includes mixing the polyester surface felt and the vinyl resin by hand application and then curing them. The amount of polyester surface felt is 15%-30% of the weight of the inner anti-corrosion layer, and the amount of vinyl resin is 70%-85% of the weight of the inner anti-corrosion layer.

7. The vinyl resin electrolytic cell according to claim 1, characterized in that, The vinyl resin electrolytic cell also includes a slag discharge hole and a liquid discharge hole, both of which are located at the bottom of the electrolytic cell body, and connecting parts are pre-embedded on the slag discharge hole and / or the liquid discharge hole.

8. A method for manufacturing a vinyl resin electrolytic cell, characterized in that, include: A steel mold is made by applying polyester surface felt to the surface of the steel mold using vinyl ester resin and then assembling the steel mold to obtain the assembled steel mold. An adhesive is prepared, and aggregate is added to the adhesive and mixed to obtain a casting layer raw material; wherein the aggregate includes barium sulfate, and the amount of barium sulfate is 85%-90% of the weight of the casting layer raw material; The casting layer material is poured into the assembled steel mold, and connectors are pre-embedded. After vibration and curing treatment, a vinyl resin electrolytic cell is obtained.

9. The method for manufacturing a vinyl resin electrolytic cell according to claim 8, characterized in that, The aggregate comprises barium sulfate of the following mesh sizes by weight percentage: 6-8 mesh 20%-40%, 10-20 mesh 20%-30%, 30-70 mesh 5%-15%, 70-140 mesh 5%-15%, and 200-300 mesh 5%-10%.

10. The method for manufacturing a vinyl resin electrolytic cell according to claim 8, characterized in that, The adhesive comprises the following components by weight percentage: 90%-95% vinyl resin, 3%-10% diluent, 1%-5% curing agent, and 0.1%-2% accelerator.

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