A bio-based polyhydroxyalkanoate pressure sensitive adhesive as well as a preparation method and application thereof

By modifying the side chains of polyhydroxyalkanoates, a bio-based polyhydroxyalkanoate pressure-sensitive adhesive was prepared, which solved the environmental protection and adhesion problems of existing pressure-sensitive adhesives, expanded the application range, met the comprehensive performance requirements of adhesion and cohesion, and met the needs of sustainable development.

CN122104118APending Publication Date: 2026-05-29NANJING UNIV +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
NANJING UNIV
Filing Date
2026-02-11
Publication Date
2026-05-29

AI Technical Summary

Technical Problem

Existing pressure-sensitive adhesives are mainly derived from petrochemical resources, which have problems such as non-renewability, high carbon emissions, and non-degradability. Furthermore, polyhydroxyalkanoates, as thermoplastic polymers, lack viscoelastic balance and surface adhesion, making them difficult to directly apply to the preparation of pressure-sensitive adhesives.

Method used

By modifying the side chains of polyhydroxy fatty acid esters and introducing carboxyl groups or carboxyl groups and vinyl groups to form coordination bonds or free radical polymerization crosslinking, bio-based polyhydroxy fatty acid ester pressure-sensitive adhesives can be prepared, improving adhesion and cohesion.

Benefits of technology

It broadens the sources of materials, improves adhesion and cohesion, meets the comprehensive performance requirements of pressure-sensitive adhesives, is environmentally friendly and sustainable, and is suitable for labels, medical patches and electronic devices.

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Abstract

The application discloses a kind of bio-based polyhydroxyaliphatic acid ester pressure sensitive adhesive and its preparation method and application.The preparation method: polyhydroxyaliphatic acid ester with terminal double bond in side chain is synthesized by biological fermentation method, and polyhydroxyaliphatic acid ester is modified by click reaction, and the modified polyhydroxyaliphatic acid ester can be crosslinked by two ways of coordination bond or free radical polymerization.The bio-based polyhydroxyaliphatic acid ester pressure sensitive adhesive of the application includes the following components by mass: modified polyhydroxyaliphatic acid ester 20-40 parts;Solvent ethyl acetate 60-80 parts;Crosslinking agent aluminum acetylacetone 0.3-2 parts;Initiator benzoyl peroxide 0.1-1 part.The bio-based polyhydroxyaliphatic acid ester pressure sensitive adhesive of the application realizes, and expands the material source of pressure sensitive adhesive.
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