Preparation method of environment-friendly negative oxygen ion waterproof latex paint

By combining tourmaline@ZIF-8 core-shell structure with silicone-acrylic block copolymer emulsion, the problems of performance degradation and construction defects of negative ion coatings in high humidity environments are solved, achieving a synergistic unity of waterproof performance and release performance of negative ion coatings.

CN122127885AInactive Publication Date: 2026-06-02BEIJING SENHAI OXYGEN TECH CO LTD
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Patent Information

Application Number
CN202610579390.5
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-04-29
Publication Date
2026-06-02
Estimated Expiration
Not applicable · inactive patent

AI Technical Summary

Technical Problem

In existing technologies, the release performance of negative ion coatings decreases sharply in high humidity environments, the waterproof function and the negative ion release function are difficult to be compatible, and pinholes and blistering defects are easily generated when applying to high humidity walls.

Method used

By combining tourmaline powder with a ZIF-8 core-shell structure, the hydrophobic channels of ZIF-8 are used to protect the surface of tourmaline. A silicone-acrylic block copolymer emulsion is prepared by combining reversible addition-fragmentation chain transfer polymerization technology to form a hydrophobic-hydrophilic dual continuous network structure. With the help of a closed isocyanate crosslinking agent, the synergistic effect of negative oxygen ion release and waterproof performance is achieved.

Benefits of technology

It maintains a stable and efficient negative oxygen ion release capacity in high humidity environments, possesses excellent waterproof performance, and solves the problems of pinholes and blistering during construction on high humidity walls, achieving a synergistic unity between waterproof and negative ion release functions.

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Abstract

The invention relates to the technical field of coating preparation, in particular to a preparation method of environment-friendly negative oxygen ion waterproof latex paint, which comprises the following steps: preparing tourmaline ZIF-8 core-shell structure powder, dynamically adjusting the molar ratio based on a particle size-time growth curve, and accurately controlling the shell thickness of 20-100nm; the preparation method comprises the following steps: synthesizing a polymethyl methacrylate-b-polydimethylsiloxane-b-polyacrylic acid triblock copolymer by adopting an RAFT (Reversible Addition-Fragmentation Chain Transfer) polymerization method to form a hydrophobic sea + hydrophilic island microphase separation structure; the preparation method comprises the following steps: compounding blocked isocyanate and modified phosphate according to a ratio of (2-5): 1 to prepare a latent curing cross-linking agent dispersion liquid; performing paint mixing in a layered charging sequence; the three technical problems of negative ion release attenuation in a high-humidity environment, contradiction between water resistance and release and foaming in high-humidity construction are effectively solved.
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