A catalyst for preparing succinic anhydride by hydrogenating maleic anhydride and a preparation method thereof

CN122164413APending Publication Date: 2026-06-09CHINA PETROLEUM & CHEMICAL CORP +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
CHINA PETROLEUM & CHEMICAL CORP
Filing Date
2024-12-06
Publication Date
2026-06-09

AI Technical Summary

Technical Problem

Existing nickel-based catalysts are prone to sintering growth and loss of active components in the hydrogenation reaction of maleic anhydride, resulting in decreased catalyst stability and activity, making it difficult to meet the requirements for efficient preparation of succinic anhydride.

Method used

A composite support of alumina and titanium dioxide of different crystal phases (rutile and anatase) is used. By selecting appropriate calcination and reduction temperatures, a stable catalyst structure is formed. Nickel particles are uniformly dispersed and coated with an oxide film, reducing the nickel loading to improve catalytic activity and stability.

Benefits of technology

The catalyst achieved efficient conversion of maleic anhydride to succinic anhydride with low nickel loading, exhibiting good stability and activity, and significantly improving catalytic performance.

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Abstract

A method for preparing a catalyst for the hydrogenation of maleic anhydride to succinic anhydride includes: adding a mixture of alumina, rutile, and anatase as a composite support to an aqueous solution of a nickel precursor, rotary evaporation to dryness, drying the resulting solid to obtain a catalyst precursor; calcination and reduction at 400-600℃ to obtain the catalyst; the nickel weight percentage is 3-20 wt%. By selecting appropriate calcination and reduction temperatures, the degree of interaction between the composite support and metallic nickel can be controlled in this process, resulting in a catalyst with a more stable structure, effective control of nickel sintering and loss, high dispersion of active components, high hydrogenation activity, and the ability to achieve the effect of a high-load catalyst with a lower nickel loading.
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