High-toughness gas shielded welding wire and preparation method thereof

By constructing a multi-layered composite shell and a fine composite inclusion design, the problem of boron being easily oxidized in high-temperature environments was solved, which improved the tensile strength and low-temperature toughness of the weld metal of the high-strength and tough gas-shielded welding wire, achieving a balance between high strength and low-temperature toughness.

CN122165091AActive Publication Date: 2026-06-09SICHUAN XIYE NEW MATERIAL
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Patent Information

Application Number
CN202610648036.3
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-05-12
Publication Date
2026-06-09
Estimated Expiration
2046-05-12

AI Technical Summary

Technical Problem

In existing high-strength and high-toughness gas-shielded welding wires, boron is easily oxidized and nitrided in high-temperature, high-oxygen, and high-nitrogen environments, resulting in coarse borides that affect the strength and low-temperature toughness of the weld. Furthermore, traditional inclusion control methods are insufficient to effectively improve the weld's resistance to cold cracking.

Method used

Using calcium-enriched low-polymer borosilicate as the core, a multi-layered composite shell is constructed through a time-sequence modification method of first hydrolyzing and sealing with a reactive aluminum source and then embedding framework-type alumina nanoparticles. Combined with the preferential distribution of cerium element at defect oxygen and residual hydroxyl sites in the outer layer, fine composite inclusions are formed, which improves the low-temperature toughness and cold crack resistance of the weld.

Benefits of technology

The synergistic design of stable boron release and fine inclusions improves the tensile strength, low-temperature impact toughness and cold crack resistance of the weld metal, ensuring a balance between high strength and low-temperature toughness in the weld.

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Abstract

The invention relates to the technical field of welding materials, in particular to a high-toughness gas shielded welding wire and a preparation method thereof. The welding wire comprises a low-carbon steel strip sheath and flux core powder, wherein the flux core powder comprises reduced iron powder, manganese powder, carbonyl nickel powder, molybdenum powder, titanium powder, silicon powder, graphite powder, rutile titanium dioxide, calcium fluoride, potassium fluotitanate and cerium-aluminum co-doped particle powder; the cerium-aluminum co-doped particle powder takes calcium-enriched borosilicate as an inner core, and is prepared by aluminum isopropoxide hydrolytic polycondensation sealing, aluminum oxide nano-particle enhancement, aluminum nitrate-colloidal silicon dioxide bridging and cerium nitrate outer layer treatment; the welding wire is suitable for multi-layer and multi-channel gas shielded welding of high-strength steel thick plates, and the low-temperature impact toughness can be improved and inclusions can be refined while high deposited metal strength is kept.
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