Super long cycle electrolyte for supercapacitor based on ionic liquid and ethylene carbonate synergistically regulated stable CEI membrane

By synergistically regulating the CEI membrane with acetonitrile and ethylene carbonate, the problem of insufficient stability of supercapacitor electrolyte under high voltage is solved, achieving long cycle life and high performance under high temperature and high pressure, which is suitable for new energy vehicles and grid energy storage.

CN122202070APending Publication Date: 2026-06-12ZHEJIANG UNIV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-04-16
Publication Date
2026-06-12

AI Technical Summary

Technical Problem

Existing supercapacitor electrolytes lack stability under high voltage, resulting in low energy density and insufficient energy storage capacity. Furthermore, pure ionic liquids have high viscosity and high cost, limiting their application in high-power characteristics and long cycle life.

Method used

Acetonitrile, 1-n-butyl-1-methylpyrrolidine di(trifluoromethanesulfonyl)imide (PYR14-TFSI), and ethylene carbonate were used to synergistically regulate and stabilize the CEI film, forming a dense and uniform CEI film. The high electrochemical stability of the ionic liquid and the film-forming aid properties of ethylene carbonate were used to optimize the interfacial stability and ion transport.

Benefits of technology

It achieves an ultra-long cycle life under high temperature and high pressure, combines high ionic conductivity and low cost, adapts to electrolytes with a wide temperature range, and improves the energy density and power density of supercapacitors, making it suitable for new energy vehicles, grid energy storage and portable electronic devices.

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Abstract

The application discloses a supercapacitor long-cycle electrolyte based on ionic liquid and ethylene carbonate synergistically regulating stable CEI membrane, and the electrolyte comprises a composite solvent and an electrolyte salt, wherein the composite solvent comprises acetonitrile, 1-n-butyl-1-methylpyrrolidine di(trifluoromethylsulfonyl) imide (PYR 14 -TFSI) and ethylene carbonate. The application further discloses application of the electrolyte in a supercapacitor. The electrolyte realizes uniform formation and long-term stability of the CEI membrane through synergistic effect of the ionic liquid, the ethylene carbonate and the base solvent, and meanwhile, excellent ion transmission kinetics and electrochemical performance are ensured.
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