Hydrophobically modified coix seed starch-quercetin composite emulsifier, and preparation method and application thereof

By combining coix seed starch with quercetin, an emulsifier with a dual physical-chemical barrier mechanism was constructed, which solved the problems of insufficient density of the modified starch interfacial film and easy precipitation of quercetin, and achieved long-term antioxidant and stability of highly unsaturated oils such as walnut oil.

CN122397902APending Publication Date: 2026-07-17KUNMING UNIV OF SCI & TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
KUNMING UNIV OF SCI & TECH
Filing Date
2026-05-09
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing modified starch interfacial films have insufficient density, making it difficult to effectively inhibit the oxidation of oils rich in polyunsaturated fatty acids. Quercetin has poor water solubility and is prone to precipitation, resulting in a high risk of lipid oxidation in emulsions during long-term storage.

Method used

A composite emulsifier combining coix seed starch and quercetin is used to form a physical-chemical dual barrier mechanism through interfacial molecular self-assembly. By utilizing the microscopic geometric structure and chemical binding advantages of coix seed starch, quercetin is precisely anchored to build a highly dense defense system.

Benefits of technology

It achieves excellent physical stability and long-lasting antioxidant capacity of the emulsion, significantly extends the shelf life of the oil, and the stabilization and encapsulation of quercetin improves its bioavailability.

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Abstract

本发明公开了一种疏水改性薏米淀粉‑槲皮素复合乳化剂及其制备方法和应用,属于食品加工技术领域。本发明利用具有小颗粒尺寸和高支链比例的薏米淀粉作为改性基质,通过酯化改性及界面激活热处理,利用薏米淀粉特定的理化结构提升辛烯基琥珀酸基团的结合效率与分布均匀性,并作为化学锚点通过强疏水相互作用驱动槲皮素分子的原位负载与自组装,构建高致密复合界面防御体系。该复合乳化剂在保护核桃油时发挥协同增效作用,一方面通过物理拦截致密度以阻断氧气渗透;另一方面通过原位化学淬灭作用高效清除自由基,解决了槲皮素稳态化递送难题,显著提升了核桃油乳液的物理稳定性与长效防氧化能力,在功能性油脂保护领域具有显著应用价值。
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