A modified polyamide nanofiltration membrane of methiocarb and a preparation method and application thereof

By introducing fenitrothion as an aqueous phase additive during the interfacial polymerization process, a fenitrothion-modified polyamide nanofiltration membrane was prepared. This solved the problem of sacrificing water flux when improving the rejection rate of traditional nanofiltration membranes, achieving a synergistic improvement in water flux and rejection rate, as well as enhanced antifouling performance, making it suitable for water treatment and desalination.

CN122399600APending Publication Date: 2026-07-17NORTH CHINA ELECTRIC POWER UNIV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
NORTH CHINA ELECTRIC POWER UNIV
Filing Date
2026-06-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional polyamide nanofiltration membranes often sacrifice water flux when improving retention rate, and their antifouling ability and long-term operational stability are insufficient, resulting in bottlenecks in practical applications.

Method used

The preparation method of polyamide nanofiltration membrane modified with pyridinium involves introducing pyridinium as an aqueous phase additive during the interfacial polymerization process. By utilizing its dicarboxylic acid sulfide group to covalently crosslink with pyromellitic tricarboxylic acid chloride, the diffusion rate of piperazine is controlled, forming a uniform crosslinked separation layer, thereby enhancing the hydrophilicity and antifouling ability of the membrane.

Benefits of technology

It significantly improves water flux and salt rejection rate, enhances the membrane's antifouling performance and long-term operational stability, breaks the traditional nanofiltration membrane permeability-selectivity trade-off effect, and provides a new type of membrane material that combines high flux and high selectivity.

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Abstract

本发明公开了一种杀螟丹改性聚酰胺纳滤膜及其制备方法和应用,属于水处理膜分离技术领域。本发明在制备杀螟丹改性聚酰胺纳滤膜时,通过杀螟丹改性实现聚酰胺纳滤膜通量与截留率协同提升,打破传统trade‑off效应。本发明提供的杀螟丹改性聚酰胺纳滤膜的功能面具有超亲水性,该聚酰胺纳滤膜的结构致密均匀,抗污染性强且易清洗,且长期运行稳定,在水处理、脱盐领域应用前景广阔。
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