A Ru-W / ZrO2 composite catalyst based on carrier morphology regulation, a preparation method and application thereof

By loading Ru and W onto a ZrO2 support to form amorphous WOx and solid solution structures, the problem of insufficient activity and stability of the catalyst in high humidity environments is solved, and the effect of efficient catalytic oxidation of CVOCs is achieved.

CN122399804APending Publication Date: 2026-07-17INST OF URBAN ENVIRONMENT CHINESE ACAD OF SCI

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
INST OF URBAN ENVIRONMENT CHINESE ACAD OF SCI
Filing Date
2026-05-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing catalysts have insufficient catalytic activity and stability in high humidity environments, resulting in low efficiency and safety risks in the catalytic oxidation of CVOCs.

Method used

By loading Ru and W onto ZrO2 supports with different morphologies, amorphous WOx species and solid solution structures are formed, enhancing interfacial electronic coupling and charge transfer, regulating the electronic structure of the active component Ru, and improving catalytic activity and water resistance.

Benefits of technology

It significantly improves the catalytic activity and stability of the catalyst, effectively treating CVOCs containing water vapor, and reducing operating costs and safety risks.

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Abstract

本发明涉及一种基于载体形貌调控的Ru‑W / ZrO2复合催化剂及其制备方法和应用。基于载体形貌调控的Ru‑W / ZrO2复合催化剂包括活性组分Ru、载体ZrO2和助剂W;载体ZrO2的形貌为棒状和 / 或球状;助剂W的存在形式包括非晶态WOx存在于载体ZrO2表面。本发明通过在不同形貌的载体ZrO2上负载活性组分Ru和助剂W,有利于在载体ZrO2表面形成高度分散的非晶态WOx物种,并构建出稳定的W‑O‑Zr界面结构,形成丰富的界面活性位点,增强界面电子耦合与促进界面电荷转移,进而调控活性组分Ru的电子结构,显著增强活性组分Ru与载体ZrO2之间的EMSI,从而显著提升催化活性、抗水性能和稳定性。
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