Preparation method and application of a molecular sieve loaded metal oxide photocatalyst

By preparing an In2O3/TS-1 composite photocatalyst by loading metal oxides onto molecular sieves and combining it with potassium persulfate, the problems of weak adsorption and limited catalytic activity of existing photocatalysts in PFOA degradation were solved, achieving efficient and economical PFOA degradation.

CN122399889APending Publication Date: 2026-07-17NANJING UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
NANJING UNIV
Filing Date
2026-05-14
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing photocatalysts have limitations in degrading perfluorooctanoic acid (PFOA), including weak adsorption, high recombination rate of photogenerated carriers, limited catalytic activity, complex synthesis process, and high energy consumption, making them difficult to apply effectively under real sunlight.

Method used

A molecular sieve-supported metal oxide composite photocatalyst was used. Indium nitrate solution was added to titanium silicate-1 zeolite, the pH value was controlled and calcined, and In2O3/TS-1 composite material was prepared. Combined with potassium persulfate, it was used for photocatalytic degradation of PFOA under a light source.

Benefits of technology

It efficiently degrades PFOA under simulated and real sunlight, with degradation rates exceeding 90% and 70%, respectively, and maintains activity over a wide pH range, reducing the amount of oxidant required and simplifying the preparation process.

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Abstract

本发明公开了一种分子筛负载金属氧化物复合光催化剂的制备方法及应用。该制法为:向含有钛硅酸盐‑1沸石的硝酸溶液中加入硝酸铟溶液,滴加第一浓度的氢氧化钠溶液至第一pH、滴加第二浓度的氢氧化钠溶液至第二pH,使氢氧化铟完全沉淀,去除上清液,将固体产物洗涤、干燥,煅烧,得到复合光催化剂。将该复合光催化应用于降解水中全氟辛酸,在模拟日光 / 真实日光照射下能够有效激发过硫酸钾从而光催化降解PFOA,并且可在较宽的pH范围进行反应,极大改善了PFOA的光催化降解条件,有利于实际废水中PFOA的去除;在350W氙灯照射24小时后能够降解超过90%的PFOA,在真实日光照射24h后能够降解约70%的PFOA。
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