A catalytic coal spontaneous combustion inhibitor and a preparation method and use method thereof

The synergistic composite system formed by potassium formate and surfactant catalyzes the self-decomposition of coal molecules to release carbon dioxide and form a physical barrier, solving the problems of environmental pollution and insufficient timeliness of traditional flame retardants, and achieving a highly efficient, safe and environmentally friendly coal spontaneous combustion inhibition effect.

CN122399892APending Publication Date: 2026-07-17TAIYUAN UNIVERSITY OF TECHNOLOGY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
TAIYUAN UNIVERSITY OF TECHNOLOGY
Filing Date
2026-05-13
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing flame retardants have problems with environmental pollution and insufficient timeliness in suppressing spontaneous combustion of coal. Traditional flame retardants may cause environmental pollution during use and their suppression effect is not long-lasting.

Method used

A synergistic composite system formed by potassium formate and surfactants (such as CTAB, SDBS, and SLS) is used to uniformly load the coal surface through supramolecular interactions, catalyze the self-decomposition of oxygen-containing groups in coal molecules, release carbon dioxide, dilute the concentration of combustible gases, and form a dense film for physical barrier, thereby achieving multi-stage synergistic inhibition of coal spontaneous combustion.

Benefits of technology

It improves flame retardant efficiency, enhances the effect of suppressing coal spontaneous combustion, reduces environmental impact, and has the characteristics of high efficiency, safety, and environmental protection. It can significantly extend the coal spontaneous combustion suppression time.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明提供了一种催化阻化协同抑制煤自燃阻化剂及其制备方法和使用方法,属于煤矿阻燃技术领域。本发明所述催化阻化协同抑制煤自燃阻化剂为甲酸钾或甲酸钾复合物;所述甲酸钾复合物包含表面活性剂和甲酸钾;表面活性剂包含木质素磺酸钠、十二烷基苯磺酸钠和十六烷基三甲基溴化铵中的一种或几种;所述表面活性剂和甲酸钾的质量比为1:7~24。本发明基于甲酸钾协同抑制煤自燃的水热反应,利用甲酸钾与表面活性剂(如SLS、SDBS、CTAB等)协同作用,对甲酸钾进行改性,使其在煤炭自燃过程中通过催化自身含氧基团自裂解,释放大量二氧化碳,从而稀释可燃气体浓度,同时借助改性后形成的异质结的作用,达到高效抑制煤自燃的效果。
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