Modified manganese slag low-carbon cement, and preparation method and application thereof

By designing modifiers loaded with binary polymer copolymers and small molecule organic additives, the activity of manganese slag was stimulated, heavy metals were solidified, and the microstructure of cement was optimized. This solved the problems of low hydration activity and easy leaching of heavy metals in electrolytic manganese slag, while reducing the amount of cement clinker and carbon emissions, thus realizing the preparation of low-carbon cement.

CN122403799APending Publication Date: 2026-07-17HUNAN NINGYING NEW MATERIAL TECH CO LTD
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Patent Information

Application Number
CN202610797898.2
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-06-04
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies suffer from problems such as low hydration activity of electrolytic manganese slag, easy leaching of heavy metals, negative impact on cement setting and hardening, and high carbon emissions from traditional cement clinker.

Method used

A specific binary polymer copolymer is loaded onto the surface of nano-silica as a modifier, and small molecule organic additives are added. By designing the copolymerization of ester monomers and double-terminated polyether monomers, a comb-shaped polymer structure is formed. Combined with nano-silica particles, the activity of manganese slag is activated, heavy metals are solidified, and the microstructure of cement is optimized.

Benefits of technology

It significantly improves the hydration activity of manganese slag, reduces the risk of heavy metal leaching, reduces the amount of cement clinker used, reduces carbon emissions, and improves the mechanical properties and environmental safety of cement.

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Abstract

本发明提供了一种改性锰渣低碳水泥及其制备方法与应用。所述一种改性锰渣低碳水泥包括:水泥熟料30‑50份,电解锰渣40‑60份,改性剂1‑5份,小分子有机辅料0.5‑2份,石膏2‑9份;所述改性剂为负载有二元高分子共聚物的纳米二氧化硅颗粒;所述二元高分子共聚物由酯类单体与双封端聚醚单体聚合而成,所述二元高分子共聚物的平均分子量为2000‑4000,且与纳米二氧化硅表面的活性羟基结合;所述小分子有机辅料为N,N‑二(2‑羟乙基)甘氨酸单钠盐。本发明能够极大提高锰渣的潜在水化活性,有效吸附并固化重金属离子,显著减少水泥熟料用量,从而大幅降低水泥生产成本与碳排放,在绿色建材领域具有广阔的应用潜力。
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