A method for preparing a polymeric 2,6-naphtalenediol material

By using air oxidative coupling of 2,6-naphthol with copper compounds in an alcohol solvent, polynaphthol materials were synthesized, solving the problem of high-temperature coupling generating dimers in existing technologies. This provides a high-yield and low-cost method for preparing polynaphthol materials, which is suitable for optoelectronic functional materials, pharmaceuticals, and corrosion prevention.

CN122404677APending Publication Date: 2026-07-17CHONGQING UNIV
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Patent Information

Application Number
CN202610284411.0
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-03-03
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing technologies, the coupling reaction of naphthol requires a high temperature and can only generate dimers through bimolecular coupling, lacking the phenomenon of polymerization.

Method used

Using 2,6-naphthol as a raw material, copper compounds as catalysts, and alcohols as solvents, poly-2,6-naphthol material is generated through air oxidative coupling. The reaction conditions are mild, carried out at room temperature, and the process involves simple steps and product purification.

Benefits of technology

The synthesis of polynatrol materials has been achieved. The raw materials are inexpensive and readily available, the yield is high, the process is simple, and the safety is high. It is suitable for industrial production, and the product can be widely used in optoelectronic functional materials, medicine, and corrosion prevention.

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Abstract

本发明提供了一种多聚2,6‑萘二酚材料的制备方法,用于制备轴联共轭多羟基功能材料。该方法以2,6‑萘二酚为原料,铜化合物为催化剂,醇做溶剂,空气氧化一步偶联,经抽滤、酸处理、真空干燥得多聚2,6‑萘二酚材料。本方法具有方法简单,操作简便,反应条件温和,便于推广等特点。本发明方法原料、催化剂、溶剂便宜易得,可广泛应用于多聚2,6‑萘二酚材料的工业化生产。采用本发明方法制备出的多聚2,6‑萘二酚材料可在光电功能材料、医药、化学分析、防腐等多领域广泛应用,满足市场面广量大的需求。
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Citation Information

Patent Citations

  • Method for efficiently preparing binaphthol through liquid ligand assisted catalysis

    CN112479827A