Preparation of functional master batch for polyester film by in-situ polymerization and preparation process and application

Functional masterbatch for polyester film was prepared by in-situ polymerization. Using terephthalic acid, ethylene glycol, 1,4-cyclohexanediethanol and modified silica, a shell with a certain degree of toughness was formed, which solved the problem of large surface roughness of PET film and achieved a balance between flatness and anti-blocking performance of high-end MLCC release film.

CN122404682APending Publication Date: 2026-07-17ZHEJIANG JIANXING TECH CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
ZHEJIANG JIANXING TECH CO LTD
Filing Date
2026-04-25
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing PET films, while maintaining anti-blocking properties, have relatively large surface roughness, making it difficult to meet the high-end requirements of MLCC release films.

Method used

Functional masterbatch for polyester film was prepared by in-situ polymerization. Terephthalic acid and ethylene glycol were used as the main polymerization monomers, 1,4-cyclohexanediethanol was used as the copolymerization modification monomer, and modified silica was used as the functional filler to form a shell with a certain toughness, achieving uniform dispersion at the nanoscale and forming a uniform micro-protrusion structure.

Benefits of technology

While maintaining anti-blocking properties, it significantly reduces surface roughness and improves surface smoothness, meeting the stringent requirements of release films for high-end MLCCs.

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Abstract

本申请公开了一种原位聚合法制备聚酯薄膜用功能母粒及制备工艺和应用,涉及离型膜领域。原位聚合法制备聚酯薄膜用功能母粒,包括以下重量份数的原料:对苯二甲酸85~87份,乙二醇40~50份,1,4‑环己烷二甲醇3~10份,改性二氧化硅0.1~0.6份,催化剂0.005~0.2份,热稳定剂0.005~0.05份;改性二氧化硅的制备原料包括乙烯基三乙氧基硅烷、丙烯酸缩水甘油酯、甲基丙烯酸甲酯、间苯二胺和纳米二氧化硅。1,4‑环己烷二甲醇与改性二氧化硅相协同,使薄膜在保持防粘连性能的同时,实现较低的表面粗糙度,保持较高的表面平整度,满足高端MLCC用离型基膜的严苛要求。
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