Preparation method of anti-radiation nano-anion material

By using rare earth ion coordination modification of tourmaline and covalent grafting of bismuth oxide, combined with mechanochemical impact composite treatment, the problems of sedimentation separation and spontaneous polarization effect of bismuth oxide and tourmaline during melt blending were solved, achieving highly efficient synergistic performance of radiation-resistant nano-negative ion materials suitable for eye care products.

CN122404874APending Publication Date: 2026-07-17K LINK OPTICAL TECH GUANGZHOU CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-06-12
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the existing technology, bismuth oxide and tourmaline are prone to sedimentation and separation during melt blending. Radiation-resistant fillers block the negative ion release channels, and the spontaneous polarization effect of tourmaline decays during processing, resulting in uneven performance and decreased mechanical properties of the composite material.

Method used

By modifying tourmaline with rare earth ions, grafting bismuth oxide with covalent bonds, and combining mechanical and chemical impact composite treatment, a non-continuous island-shaped composite functional filler is constructed, and a polydopamine interface bonding layer is formed on the surface of the matrix resin to ensure the synergistic coexistence of tourmaline negative ion release channels and radiation protection performance.

Benefits of technology

It achieves efficient synergy between X-ray attenuation and negative ion release, with a negative ion release of over 2000 per cubic centimeter. It also exhibits excellent far-infrared radiation performance and improved material mechanical properties, making it suitable for eye care products to relieve eye fatigue.

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Abstract

本发明涉及高分子复合材料技术领域,公开了一种防辐射纳米负离子材料的制备方法,包括:将纳米电气石粉体与稀土盐溶液混合反应,得到稀土改性电气石粉体;将纳米氧化铋粉体与有机膦酸化合物混合反应,得到膦酸改性氧化铋粉体;将稀土改性电气石粉体与膦酸改性氧化铋粉体混合,通过机械化学冲击复合处理,得到复合功能填料;将基体树脂与多巴胺盐酸盐在碱性条件下反应,得到多巴胺改性基体树脂;将多巴胺改性基体树脂、复合功能填料、相容剂和加工助剂混合,得到防辐射纳米负离子材料。本发明实现了防辐射性能与负离子释放性能的协同共存,所得材料可应用于眼部护理产品,有助于缓解眼疲劳和改善眼部舒适度。
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