A near-infrared luminescent material which can be excited by ambient light, and a preparation method and application thereof

By preparing A2BaGa4-xCO12:xCr3+ near-infrared luminescent materials, the dependence on a dedicated excitation light source was solved, and efficient and stable near-infrared luminescence under ambient light was achieved, which is suitable for information encryption and biological monitoring.

CN122405271APending Publication Date: 2026-07-17XINJIANG NORMAL UNIVERSITY
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
XINJIANG NORMAL UNIVERSITY
Filing Date
2026-05-06
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing near-infrared luminescent materials are highly dependent on dedicated excitation light sources, making it difficult to meet the needs for long-term, dynamic, and non-invasive real-time monitoring, and they also pose phototoxicity risks in biomedicine.

Method used

A near-infrared luminescent material that can be excited by ambient light was developed. The chemical structure is A2BaGa4-xCO12:xCr3+. By replacing the A-site ion with Lu, La or Gd and the C-site ion with Si or Ge, and controlling the doping ratio x between 0.01 and 1, a garnet structure was formed, achieving high fluorescence quantum yield and excellent thermal and chemical stability.

Benefits of technology

The material can be excited under ambient light of 400~700nm without the need for a dedicated light source, has an internal quantum yield of 99%, and possesses high thermal and chemical stability, making it suitable for information encryption and biological monitoring.

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Abstract

传统近红外发光材料依赖蓝光(450~485nm)或高能量光源激发,存在隐蔽性差、激发设备复杂、器件老化等局限。针对此问题,本发明提出一种可被环境光激发的近红外发光材料,化学通式为A2BaGa4‑xCO12:xCr3+,A为Lu、La或Gd,C为Ge或Si,Cr3+掺杂浓度x为0.01~1,其激发光谱覆盖400~700nm可见光区,可利用日常环境光(手机背景光、室内灯光、汽车前大灯光)激发,实现无特殊光源的“无源化”近红外发光。该材料的内量子产率达99%,且热、化学稳定性优异。本发明从材料本征属性上摆脱了对专用激发光源的依赖,为信息加密、隐蔽式安防与生物监测技术等应用提供了可靠的核心材料支撑。
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