Modified pvdf nanofiber piezoelectric sensing film and preparation method and application thereof

CN122406459APending Publication Date: 2026-07-17NANJING TECH UNIV
View PDF 0 Cites 0 Cited by

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
NANJING TECH UNIV
Filing Date
2026-03-25
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional fiber-reinforced polymer composites (FRPs) suffer from poor impact resistance and low damage tolerance in damage detection. Furthermore, existing embedded sensors may compromise structural integrity or require external power, making it difficult to achieve real-time and accurate damage monitoring.

Method used

A modified PVDF nanofiber piezoelectric sensing membrane was prepared by using a composite spinning solution modified with hydroxylated barium titanate and multi-walled carbon nanotubes. The membrane was then prepared by electrospinning and hot-pressed with glass fiber prepreg to form a self-powered embedded sensing unit. Damage monitoring was achieved by combining this unit with electrical impedance tomography (EIT) technology.

Benefits of technology

It enables real-time, in-situ, and visualized damage monitoring of FRP structures, improves sensing sensitivity and signal accuracy, has self-powered characteristics, does not weaken the structural mechanical properties, and is suitable for aerospace, automotive, and marine engineering.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure CN122406459A_ABST
    Figure CN122406459A_ABST
Patent Text Reader

Abstract

本发明公开了一种改性 PVDF 纳米纤维压电传感膜及其制备方法和应用,属于柔性压电传感材料与复合材料结构健康监测技术领域。本发明先对钛酸钡纳米颗粒和多壁碳纳米管进行羟基化改性,再与 PVDF‑HFP 共混制备纺丝液,通过静电纺丝技术制备得到 PVDF‑HFP / BaTiO₃‑h / MWCNTs‑h 复合压电传感膜;将该传感膜作为嵌入式传感单元,与玻璃纤维预浸料通过热压工艺一体化成型,制备得到内置自供电传感单元的 GFRP 复合材料层合板。本发明制备的改性 PVDF 纳米纤维压电传感膜压电输出性能优异、与复合材料基体相容性好,嵌入后不削弱层合板的力学性能,反而实现拉伸强度与模量的小幅提升,同时本发明具备自供电特性,可广泛应用于航空航天、汽车、海洋工程等领域的纤维增强复合材料结构健康监测。
Need to check novelty before this filing date? Find Prior Art