An in-situ hydrogenation reaction temperature distribution monitoring method and system suitable for a nuclear magnetic resonance imaging device

By combining nuclear magnetic resonance imaging with a multimodal monitoring method using catalyst support and external temperature-sensitive substances, the problem of continuous and non-invasive monitoring of temperature distribution in hydrogenation reactions has been solved, achieving high spatial resolution and real-time temperature warning, thus improving the safety and optimization capabilities of hydrogenation reactions.

CN122408991APending Publication Date: 2026-07-17INSTITUTE OF PROCESS ENGINEERING CHINESE ACADEMY OF SCIENCES

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
INSTITUTE OF PROCESS ENGINEERING CHINESE ACADEMY OF SCIENCES
Filing Date
2026-05-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies cannot achieve continuous, non-invasive, high spatial resolution monitoring of catalyst bed temperature distribution in hydrogenation reactions, which poses safety hazards, especially under high pressure conditions, and lacks the ability to dynamically track rapid temperature changes and provide early warning of temperature spikes.

Method used

By employing nuclear magnetic resonance imaging (NMR) devices, a quantitative correlation between NMR signal parameters and catalyst bed temperature is established. Combined with the intrinsic NMR signal of the catalyst support and the added temperature-sensitive material, non-invasive, high spatial resolution in-situ real-time monitoring of the catalyst bed is achieved, and time-domain analysis is performed for early warning of temperature spikes.

Benefits of technology

It enables non-invasive, high spatial resolution in-situ real-time monitoring of catalyst bed temperature, identifies hotspot locations and temperature gradients, provides multi-physics correlation analysis, and improves reaction safety and process optimization capabilities.

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Abstract

本发明公开了一种适用于核磁共振成像装置的原位加氢反应温度分布监测方法及系统,涉及催化反应过程监测与磁共振技术交叉领域。本发明首先,建立核磁共振可测参数与催化剂床层温度之间的定量对应关系;然后,在加氢反应过程中,利用核磁共振成像装置对反应器内的催化剂床层施加空间编码,采集反映温度分布信息的核磁共振信号参数的空间分布数据;最后,利用定量对应关系,将空间分布数据转换为催化剂床层的二维或三维温度分布信息。本发明利用催化剂载体本身或外加温度敏感物质作为核磁共振测温探针,实现了非侵入式、高空间分辨率的原位实时温度分布监测,对加氢反应的飞温预警和反应器优化具有重要意义。
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