Ag modified Bi2Mo2O4 / WS2 heterojunction composite material, preparation method thereof and application thereof in trace detection of organic pollutants

By preparing Ag-modified Bi2Mo2O9/WS2 heterojunction composite materials, and combining Z-type heterojunctions and surface plasmon resonance effects, the sensitivity and stability problems of existing SERS substrates were solved, and high-sensitivity and stable detection of organic pollutants was achieved.

CN122409622APending Publication Date: 2026-07-17LIAONING UNIVERSITY
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Patent Information

Application Number
CN202610864264.4
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-06-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing SERS substrates suffer from insufficient sensitivity, poor stability, and narrow spectral response range in the detection of organic pollutants. Traditional noble metal nanomaterials are costly and lack stability, while metal oxide/sulfide substrates have limited spectral response.

Method used

Bi2Mo2O9/WS2 heterojunctions were prepared by a one-step hydrothermal method and Ag nanoparticles were loaded by chemical reduction to form a multi-interface coupling structure. Combined with the dual charge separation mechanism of the Z-type heterojunction, the detection performance was improved.

Benefits of technology

It significantly improves the sensitivity and stability of SERS detection, broadens the spectral response range, and enables ultra-trace detection of organic pollutants.

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Abstract

本发明涉及SERS检测领域,涉及一种Ag修饰的Bi2Mo2O4 / WS2异质结复合材料及其制备方法和在有机污染物痕量检测中的应用。将硝酸铋用稀硝酸溶解后搅拌至澄清,加入硝酸钨与硫脲搅拌,缓慢滴入钼酸钠溶液利用一步水热法合成Bi2Mo2O9 / WS2异质结,通过化学还原法使Ag复合在Bi2Mo2O9 / WS2异质结表面,干燥得到Ag修饰的Bi2Mo2O9 / WS2异质结复合材料。区别于主流Bi2MoO6钼酸铋物相,本发明采用Bi2Mo2O9与WS2形成Z型异质结。该材料形成多重界面耦合结构,兼具等离子体增强效应与双重电荷分离机制,有效拓宽光谱响应区间、增多反应活性位点、提升结构稳定性与反应活性等特性。
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