Low-magnetic foreign matter spherical lithium iron phosphate positive electrode material, preparation method thereof and lithium ion battery

By preparing spherical lithium iron phosphate cathode materials with low magnetic foreign matter content through spherical forming and gradient sintering processes, the problems of low material compaction density, high magnetic foreign matter content and unstable crystal form in energy storage scenarios are solved, and lithium-ion batteries with high energy density and long cycle life are realized.

CN122417879APending Publication Date: 2026-07-17HUNAN CHANGYUAN LICO NEW ENERGY CO LTD +2

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
HUNAN CHANGYUAN LICO NEW ENERGY CO LTD
Filing Date
2026-06-09
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies make it difficult to prepare spherical lithium iron phosphate cathode materials with high real density, low magnetic foreign matter content and stable crystal form in energy storage scenarios, resulting in low cell volumetric energy density, poor safety and short cycle life.

Method used

A spherical lithium iron phosphate cathode material with low magnetic foreign matter was prepared by using a spherical forming process and a three-stage gradient sintering process through spray drying and gradient sintering. The process includes low-temperature pre-sintering, medium-temperature crystallization and high-temperature densification steps, combined with airflow deagglomeration and sieving demagnetization to control particle morphology and the generation of magnetic materials.

Benefits of technology

It achieves high solid density (≥2.55 g/cm³), low magnetic foreign matter content (≤50 ppb) and stable crystal structure, improving battery safety and cycle life, while also possessing excellent rate performance and processing performance.

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Abstract

本申请涉及锂离子电池技术领域,并提供了一种低磁性异物球形磷酸铁锂正极材料及其制备方法和锂离子电池。该低磁性异物球形磷酸铁锂正极材料为二次球形颗粒,颗粒球形度≥90%,压实密度≥2.55 g / cm³,磁性异物总含量≤50 ppb。其制备方法包括:将原料与水混合后进行喷雾干燥,然后置于惰性气氛中,进行梯度烧结,接着进行气流解聚处理、二次烧结处理,最后经气流解聚,筛分除磁,得到磷酸铁锂正极材料。并公开了包括该正极材料的锂离子电池。本发明在极低磁性异物的基础上,同步实现了球形形貌的完整保留与颗粒高致密度,最终产物压实密度可达2.55g / cm3以上,大幅提升了磷酸铁锂正极的体积能量密度。
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