Systems and methods for disproportionation of silicon oxide for anode material

By using disproportionated silica particles to form a coating layer by reacting alkali metal salts with silica at high temperatures, the low coulombic efficiency of silica anode materials in lithium-ion batteries is solved, thereby improving the initial charge-discharge efficiency and energy density of the battery.

CN122422992APending Publication Date: 2026-07-17ALBEMARLE CORP

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
ALBEMARLE CORP
Filing Date
2024-12-10
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

When silicon oxide is used as the anode material in existing lithium-ion batteries, there is an irreversible loss of active lithium, resulting in low initial coulombic efficiency and affecting battery performance.

Method used

By reacting alkali metal salts and/or alkaline earth metal salts with silica particles at high temperatures, disproportionated silica particles containing alkali metal and/or alkaline earth metal coatings are formed. The disproportionation process of silica to silica and elemental silicon is controlled, and silica particles with high crystalline phase content are produced.

Benefits of technology

It significantly improves the first-cycle coulombic efficiency of lithium-ion batteries, enhances the performance of anode materials, reduces silicon grain size, and increases battery energy density.

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Abstract

This disclosure relates to systems and methods for producing disproportionated silica composite particles. The disproportionated silica composite particles can be produced by mixing an alkali metal salt and / or an alkaline earth metal salt, a carbon precursor, a liquid medium, and silica particles to form a precursor suspension. This precursor suspension can be heated to form a powder containing disproportionated silica particles having a coating layer comprising an alkali metal and / or an alkaline earth metal, wherein the disproportionation of the silica is at least 30%.
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