Hydrolysis-resistant borosilicate glass

By adopting a multi-layer combined borosilicate glass design, using a connecting layer with a high content of SiO2 and a specific chemical composition, combined with the colloidal connection of silicone glue and polyurethane glue, the problem of hydrolysis reaction of existing glass in a humid environment is solved, achieving Provides higher hydrolysis resistance and wider application areas.

CN222387764UActive Publication Date: 2025-01-24山东鲁玻玻璃科技有限公司
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Patent Information

Application Number
CN202421173993.8
Authority / Receiving Office
CN · China
Patent Type
Utility models(China)
Current Assignee / Owner
Filing Date
2024-05-28
Publication Date
2025-01-24
Estimated Expiration
2034-05-28

AI Technical Summary

Technical Problem

Existing glasses are prone to hydrolysis in humid environments, resulting in cracks, discoloration or loss of transparency on the surface, affecting their service life and performance.

Method used

The multi -layer combined borosilicon glass is adopted, where the upper surface is high -content SIO2, the connection layer consists of SiO2, B2O3, and NA2O, and is fixed with the upper surface and the lower surface layer through silicone glue and polyurethane glue.

Benefits of technology

Effectively prevent the glass of hydrolysis in the humid environment, improve the hydrolysis performance of glass, and make it more extensive in the application of chemistry and medical fields.

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Abstract

The utility model discloses hydrolysis-resistant borosilicate glass, and relates to the technical field of borosilicate glass, the hydrolysis-resistant borosilicate glass comprises a glass body, the glass body comprises an upper surface layer, a silica sand layer, a connecting layer and a lower surface layer, the surface of the upper surface layer is provided with a placing area and a label area, so that a user can place experimental samples and marks conveniently, and through the upper, middle and lower multi-layer structural design, the hydrolysis-resistant borosilicate glass is convenient to use. The glass body is stable in chemical property, so that the glass body can be used in the chemical and medical fields, the upper surface of the glass body can be suitable for the inner walls of sample bottles, conduits and experimental containers, the glass body is effectively prevented from being hydrolyzed when used in a humid environment, and the glass body is prevented from being damaged due to the connectivity and light transmission of the silicone adhesive and polyurethane adhesive mixed colloid. The upper surface layer and the lower surface layer are adhered on the basis of not influencing the transparent condition of the glass, so that when the glass body falls off or is damaged, the glass body cracks, and broken glass is still connected and cannot be broken.
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Description

Technical Field

[0001] The utility model relates to the technical field of borosilicate glass, in particular to a hydrolysis-resistant borosilicate glass. Background Art

[0002] In the pharmaceutical field, glass is widely used as a packaging material. In particular, its special material properties, such as high transparency, mechanical resistance, low permeability and high chemical stability, are critical to maintaining the quality and even the efficacy of pharmaceutical substances. Pharmaceutical glass containers or primary packaging are usually in direct contact with the contained pharmaceutical substances and therefore must follow strict requirements. They must be able to take out the contents in a suitable manner while minimizing the loss and change of the contents. High borosilicate glass (also known as hard glass) is made by using the conductive properties of glass at high temperatures, heating the glass inside to achieve glass melting, and processing through advanced production processes.

[0003] Some existing glasses are prone to hydrolysis in humid environments, resulting in cracks, discoloration or loss of transparency on the glass surface, affecting its service life and performance. In addition, due to the limitations of its chemical or physical properties, glass can only be used in specific fields or environments and cannot meet a wider range of application needs. In view of this, we provide a hydrolysis-resistant borosilicate glass. Utility Model Content

[0004] The purpose of the utility model is to make up for the deficiencies of the prior art and provide a borosilicate glass with hydrolysis resistance.

[0005] To achieve the above-mentioned purpose, the utility model provides the following technical solutions: a hydrolysis-resistant borosilicate glass, comprising a glass body, wherein the glass body comprises an upper surface layer, a silica sand layer, a connecting layer and a lower surface layer, wherein a placement area and a label area are provided on the surface of the upper surface layer, and the connecting layer is fixedly connected to the bottom of the upper surface layer, one end of the connecting layer is fixedly connected to a contact plate, and the bottom of the connecting layer is fixedly connected to the lower surface layer, and the silica sand layer is coated on the edges of the upper surface layer, the connecting layer and the lower surface layer.

[0006] As mentioned above, the upper surface layer is made of SiO2, and the thickness of the upper surface layer is 2 mm.

[0007] As mentioned above, the upper surface layer is located on the upper surface of the glass body, and a connecting layer is fixedly connected to the center of the glass body. The connecting layer consists of three parts: upper, middle and lower. The upper surface and lower surface of the connecting layer are evenly melted with colloid.

[0008] As mentioned above, the upper surface and the lower surface of the connection layer are fixedly connected to the upper surface layer and the lower surface layer through colloid.

[0009] As mentioned above, the central part of the connecting layer adopts B2O3, and the thickness of the connecting layer is 3mm.

[0010] As mentioned above, the lower surface layer is made of Na2O, and the thickness of the lower surface layer is 2 mm.

[0011] As mentioned above, the contact plate is located at one end of the glass body, and a curved bump is fixedly connected to one end of the contact plate close to the connection layer, and stripes are provided on both the upper surface and the lower surface of the contact plate.

[0012] As mentioned above, the silica sand layer is made of silica sand glass, and the silica sand layer is entirely covered at the edge of the glass body, and the inner wall of the silica sand layer is fixedly connected to the upper surface layer, the connecting layer and the lower surface layer respectively.

[0013] Compared with the prior art, the hydrolysis-resistant borosilicate glass has the following beneficial effects:

[0014] 1. The upper surface of the utility model is provided with a placement area and a label area, which is convenient for users to place experimental samples and labels.

[0015] 2. The utility model adopts a multi-layer structure design with upper, middle and lower layers, and the upper surface layer, as the side with the most contact surface, adopts a large content of SiO2 and has stable chemical properties, so that the glass body can be used in the chemical and medical fields. The upper surface of the glass body can be suitable for the inner wall of sample bottles, catheters and experimental containers, effectively preventing the glass body from being easily hydrolyzed when used in a humid environment.

[0016] 3. The utility model is fixedly connected to the upper surface layer and the lower surface layer by a mixed colloid of silicone glue and polyurethane glue, and utilizes the connectivity and light transmittance of the mixed colloid of silicone glue and polyurethane glue to adhere the upper surface layer and the lower surface layer without affecting the transparency of the glass itself, so that when the glass body falls or is damaged, cracks will appear on the glass body, and the broken glass will still be connected without breaking.

[0017] Other advantages, objectives and features of the present invention will be described in the following description to some extent, and will be apparent to those skilled in the art based on the following examination and study, or may be taught from the practice of the present invention to some extent. BRIEF DESCRIPTION OF THE DRAWINGS

[0018] Figure 1 It is a three-dimensional structural schematic diagram of the utility model;

[0019] Figure 2 It is a schematic diagram of the three-dimensional split structure of the utility model;

[0020] Figure 3 It is a schematic diagram of the cross-sectional structure of the utility model;

[0021] Figure 4 For the utility model Figure 3Schematic diagram of the locally enlarged structure of A in the middle.

[0022] In the figure: 1, glass body; 2, upper surface layer; 201, placement area; 202, label area; 3, silica sand layer; 4, connection layer; 401, contact plate; 5, lower surface layer. DETAILED DESCRIPTION

[0023] The following will be combined with the drawings in the embodiments of the utility model to clearly and completely describe the technical solutions in the embodiments of the utility model. Obviously, the described embodiments are only part of the embodiments of the utility model, not all of the embodiments. Based on the embodiments in the utility model, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the utility model.

[0024] like Figure 1-4 As shown, the utility model provides a technical solution: a hydrolysis-resistant borosilicate glass, comprising a glass body 1, the glass body 1 comprising an upper surface layer 2, a silica sand layer 3, a connecting layer 4 and a lower surface layer 5, a placement area 201 and a label area 202 are provided on the surface of the upper surface layer 2, and the connecting layer 4 is fixedly connected to the bottom of the upper surface layer 2, one end of the connecting layer 4 is fixedly connected to a contact plate 401, and the bottom of the connecting layer 4 is fixedly connected to the lower surface layer 5, and the silica sand layer 3 is coated on the edges of the upper surface layer 2, the connecting layer 4 and the lower surface layer 5.

[0025] According to the overall structure of the device, a placement area 201 and a label area 202 are respectively provided on the upper surface of the glass body 1. The placement area 201 is located at one end of the upper surface of the glass body 1 and can be used to place test samples, while the label area 202 can be used to attach labels. The label area 202 neither affects the sample placement position nor blocks the label when the device is taken, which greatly facilitates the device to perform sample experimental detection. At the same time, a contact plate 401 is provided at one end of the glass body 1 to increase the fulcrum of the glass body 1, making the glass body 1 easier to pick up and use. The glass body 1 adopts a multi-layer combination type, which is composed of a variety of material layers. Among them, the upper surface layer 2 of the glass body 1 adopts SiO2, which has a large proportion. The chemical properties of SiO2 are stable, so that the glass body 1 can be used in the chemical and medical fields. Among them, the upper surface 2 of the glass body 1 can be suitable for the inner wall of sample bottles, catheters and experimental containers, which effectively prevents the glass body 1 from being easily hydrolyzed when used in a humid environment.

[0026] like Figure 1-4As shown, the upper surface layer 2 is made of SiO2, the thickness of the upper surface layer 2 is 2mm, the upper surface layer 2 is located on the upper surface of the glass body 1, and the inner center of the glass body 1 is fixedly connected with a connecting layer 4, the connecting layer 4 is composed of three parts, the upper, middle and lower parts, the upper surface and the lower surface of the connecting layer 4 are uniformly melted with colloid, the upper surface and the lower surface of the connecting layer 4 are fixedly connected to the upper surface layer 2 and the lower surface layer 5 through the colloid, the central part of the connecting layer 4 is made of B2O3, the thickness of the connecting layer 4 is preferably 3mm, the lower surface layer 5 is made of Na2O, the thickness of the lower surface layer 5 is 2mm, the contact plate 401 is located at one end of the glass body 1, and the contact plate 401 is fixedly connected with a curved protrusion near one end of the connecting layer 4, the upper surface and the lower surface of the contact plate 401 are both provided with stripes, the silica sand layer 3 is made of silica sand glass, and the silica sand layer 3 is entirely coated on the edge of the glass body 1, and the inner wall of the silica sand layer 3 is fixedly connected to the upper surface layer 2, the connecting layer 4 and the lower surface 5 respectively.

[0027] The upper surface layer 2 is used as the contact surface of the glass body 1, and is made of glass material with a high SiO2 content. The chemical properties of SiO2 are stable, so that the glass body 1 can be used in the chemical and medical fields. The upper surface 2 of the glass body 1 can be used for the inner wall of sample bottles, catheters and experimental containers, which effectively prevents the glass body 1 from being easily hydrolyzed when used in a humid environment.

[0028] The upper surface and the lower surface of the connecting layer 4 are fixedly connected to the upper surface layer 2 and the lower surface layer 5 by a mixed colloid of silicone adhesive and polyurethane adhesive. The upper surface layer 2 and the lower surface layer 5 are adhered to each other without affecting the transparency of the glass itself by utilizing the connectivity and light transmittance of the mixed colloid of silicone adhesive and polyurethane adhesive, so that when the glass body 1 is dropped or damaged, cracks appear on the glass body 1, and the broken glass remains connected without breaking.

[0029] The lower surface layer 5 and the connecting layer 4 have a relatively small proportion of B2O3 and Na2O, which does not affect the proportion of SiO2. Through the design of combination and structure, the anti-hydrolysis effect of the device is further improved.

[0030] Working principle: A placement area 201 and a label area 202 are respectively provided on the upper surface of the glass body 1. The placement area 201 is located at one end of the upper surface of the glass body 1 and can be used to place experimental samples, while the label area 202 can be used to attach labels. The label area 202 neither affects the sample placement position nor blocks the label when the device is taken, which greatly facilitates the device to perform sample experimental detection. At the same time, a contact plate 401 is provided at one end of the glass body 1 to increase the fulcrum of the glass body 1, making the glass body 1 easier to pick up and use. The glass body 1 adopts a multi-layer combination type, which is composed of a variety of material layers. Among them, the upper surface layer 2 of the glass body 1 adopts SiO2, which has a large proportion. The chemical properties of SiO2 are stable, so that the glass body 1 can be used in the chemical and medical fields. Among them, the upper surface 2 of the glass body 1 can be suitable for the inner wall of sample bottles, catheters and experimental containers, which effectively prevents the glass body 1 from being easily hydrolyzed when used in a humid environment.

[0031] It should be noted that, in this article, the orientation or position relationship indicated by the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inside", "outside", etc. is based on the orientation or position relationship shown in the drawings, which is only for the convenience of describing the utility model and simplifying the description, and does not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be understood as a limitation on the utility model; the terms "first", "second", and "third" are only used for descriptive purposes and cannot be understood as indicating or implying relative importance. In addition, unless otherwise clearly specified and limited, the terms "fixed", "installed", "connected", and "connected" should be understood in a broad sense. For example, "installed" can be a fixed connection, a detachable connection, or an integral connection; "connected" can be a mechanical connection or an electrical connection; "connected" can be a direct connection, an indirect connection through an intermediate medium, or a connection between two elements. For ordinary technicians in this field, the specific meanings of the above terms in the utility model can be understood according to specific circumstances.

[0032] Although the embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions and variations may be made to the embodiments without departing from the principles and spirit of the present invention, and that the scope of the present invention is defined by the appended claims and their equivalents.

Claims

1. A hydrolysis-resistant borosilicate glass, comprising a glass body (1), characterized in that: The glass body (1) comprises an upper surface layer (2), a silica sand layer (3), a connecting layer (4) and a lower surface layer (5); a placement area (201) and a label area (202) are provided on the surface of the upper surface layer (2); the connecting layer (4) is fixedly connected to the bottom of the upper surface layer (2); one end of the connecting layer (4) is fixedly connected to a contact plate (401); and the bottom of the connecting layer (4) is fixedly connected to the lower surface layer (5); the silica sand layer (3) is coated on the edges of the upper surface layer (2), the connecting layer (4) and the lower surface layer (5); the upper surface layer (2) is made of SiO2; and the thickness of the upper surface layer (2) is 2 mm.

2. The hydrolysis-resistant borosilicate glass according to claim 1, characterized in that: The upper surface layer (2) is located on the upper surface of the glass body (1), and a connecting layer (4) is fixedly connected to the center of the interior of the glass body (1), the connecting layer (4) is composed of three parts: upper, middle and lower, and the upper surface and the lower surface of the connecting layer (4) are evenly melted with colloid.

3. The hydrolysis-resistant borosilicate glass according to claim 2, characterized in that: The upper surface and the lower surface of the connecting layer (4) are fixedly connected to the upper surface layer (2) and the lower surface layer (5) via colloid.

4. The hydrolysis-resistant borosilicate glass according to claim 1, characterized in that: The central part of the connecting layer (4) is made of B2O3, and the thickness of the connecting layer (4) is 3 mm.

5. The hydrolysis-resistant borosilicate glass according to claim 1, characterized in that: The lower surface layer (5) is made of Na2O, and the thickness of the lower surface layer (5) is 2 mm.

6. The hydrolysis-resistant borosilicate glass according to claim 1, characterized in that: The contact plate (401) is located at one end of the glass body (1), and a curved bump is fixedly connected to one end of the contact plate (401) close to the connection layer (4), and stripes are provided on both the upper surface and the lower surface of the contact plate (401).

7. The hydrolysis-resistant borosilicate glass according to claim 1, characterized in that: The silica sand layer (3) is made of silica sand glass, and the silica sand layer (3) is entirely coated on the edge of the glass body (1), and the inner wall of the silica sand layer (3) is respectively fixedly connected to the upper surface layer (2), the connecting layer (4) and the lower surface layer (5).