Display device

Abstract

Display device with a transparent colored glass ceramic, which has a front display side and a rear illumination side, wherein at least one luminaire element is arranged in the area of ​​the illumination side, characterized by that a light compensation filter in the form of a color layer is indirectly applied to the glass ceramic, or that a light compensation filter in the form of a color layer, comprising a color matrix of organic and / or inorganic components, is applied directly to the glass ceramic, that the light compensation filter compensates for the shift in the color point of the light source due to the colored glass ceramic, or that the color point of the light source on the display side is shifted to a desired color point that is different from the original color point of the light source, and that the glass ceramic has an average transmission of >0.2% for each of the spectral ranges 420 nm to 500 nm, 500 nm to 620 nm and 550 nm to 640 nm,

Description

[0001] To improve user guidance, modern glass ceramic cooktops are equipped with indicator lights or 7-segment displays. The cooking surface itself consists of a transparent, tinted glass ceramic panel (substrate) that appears black when viewed from above. The indicator lights provide the user with information about the on state of the cooktop or individual cooking zones, the control setting, and whether the cooking zone is still hot after being switched off. LEDs are typically used as lighting.

[0002] Due to the coloring of the glass ceramic cooktop and the very limited selection of colored LED displays, the available color spectrum for user information is very limited. These displays are usually red or orange, which is also due to the coloring of the glass ceramic cooktop. DE 100 52 370 A1 describes the transmission curve for a glass ceramic cooktop, which, in particular, also allows for the transmission of blue light at approximately 450 nm, thus enabling expanded color display capabilities. DE 10 2009 013 127 A1 describes various display options based on this glass ceramic.By expanding the transmission spectrum to include the blue wavelength range, the color range of the displays has been expanded. However, due to the small number of differently colored LED displays, the number of colors visible to the user is limited even with this glass ceramic cooktop. A white LED, for example, would be perceived by the user as having a distinct yellow tint due to the transmission profile of the cooktop. DE 10 2010 061 123 A1 proposes avoiding this deficiency by using RGB LEDs. An LED lamp consists of three LEDs in the primary colors red, green, and blue. The intensity of the three-color LEDs is adjusted according to the transmission of the glass ceramic cooktop so that the overall color impression of the light signal is white for the observer. This technology requires three LEDs and the associated controls.Due to the different aging of the different colored LEDs, color shifts may occur over longer periods of use.

[0003] US 2007 / 0 108 184 A1 discloses an illuminated cooking surface using a fluorescent display as the light source. The cooking surface comprises a colorless glass-ceramic panel, the back of which is printed with a sputtered, translucent metal layer.

[0004] DE 103 09 225 A1 discloses a household appliance with a display. Facing the viewer, the household appliance has a translucent glass panel, which is provided on the rear with an opaque cover. The opaque cover has translucent cutouts, for example, in the form of display symbols. A lighting component in the form of an LED is also arranged on the rear at a distance from the translucent cover. A dark-colored film is provided between the LED and the translucent cover to change the color impression of the LED.

[0005] US 2010 / 0 193 496 A1 discloses another household appliance in which a display is designed using a fluorescent light source.

[0006] The object of the invention is therefore to create an inexpensive and robust display device with transparent colored glass ceramic in order to realize any desired and predeterminable color impressions for the user.

[0007] This problem is solved in a surprisingly simple way by placing a compensation filter in the form of a colored layer between the glass-ceramic cooking surface and the light source, corresponding to the desired color impression. The shift in the color coordinates of the light source caused by the filter properties of the glass-ceramic is corrected to a desired color coordinate by combining the glass-ceramic with such a compensation filter.

[0008] The total transmittance of the substrate τ ges (λ) is composed of the transmissions of the glass ceramic τ GK (λ) and the compensation filter τ KF (λ) together (Eq. 1).

[0009] The intensity distribution i LE(λ) of the luminous element is determined by the total transmission spectrum τ ges (λ) to the intensity distribution i A (λ) of the display (Eq. 2), which an observer perceives on the display side (Eq. 2). τtotal(λ)=τKF(λ)⋅τA(λ) iA(λ)=τtotal(λ)⋅iLE(λ)

[0010] The resulting shift in the color coordinate system can be represented in the CIE standard color space CIExyY (CIE - Commission Internationale de l'Eclaireage). (For the following description and its examples, the CIExyY 1931 version with a 2° observer is used in this document.) The human eye is not a spectrally continuous light sensor, but is composed of color receptors for limited red, green, and blue spectral ranges. Accordingly, the sensory perception of the L, M, and K cones is determined by sensitivities in the red, green, and blue light spectrum. Based on test series with test subjects, tristimulus functions x, y, and z and their integrals X, Y, and Z were defined in the CIE formalism. These tristimulus functions, as a triplet of artificial primary colors, can, when combined, reproduce the entire perceptible color space of our eyes. The x and z functions only approximately correspond to the L and K cone sensitivity.The y function is constructed to simulate the perception of brightness during the day and nearly corresponds to M-cone sensitivity. Using Equations 3 and 4, the perceived color coordinate is uniquely described by the standardized values ​​x and y, with Y being a measure of brightness. The CIExyY formalism describes self-luminous objects, optionally illuminating through absorbing media, whose light spectrum entering the eye is transformed into the standardized X, Y, Z CIE coordinates, which then describe the color coordinate and brightness of the self-luminous object. A=1N∫a¯(λ)⋅τ(λ)⋅i(λ)⋅dλwith A=X,Y,Z and a¯=x¯,y¯,z¯with N=∫y¯(λ)⋅i(λ)⋅dλ x=XS,y=YS,z=1−x−ywithS=X+Y+Z

[0011] The prerequisite for achieving a desired display color location in the red to blue spectral range for an observer using a compensation filter and preferably a commercially available and cost-effective display light element is minimum transmission values ​​of the substrate in the spectral range of all three L, M, K cones, or all three x, y, z CIE primary spectra. Fig. Figure 1 shows typical transmission spectra of various glass ceramic types (classes) commonly used for cooking surfaces. These include the currently most widely used vanadium (V) colored glass ceramics type A (e.g. CERAN SUPREMA ®, CERAN HIGHTRANS ®, KeraBlack®), glass ceramics colored with Co, Fe, Ni (type B, e.g. CERAN COLOR ®), with V, As and Fe (type C, China), with V, Fe (type D, e.g. CERAN HIGHTRANS eco ®), and those colored with Ti 3+by means of reducing refining (e.g. ZnS refining), type E.

[0012] In order to produce sufficiently bright color impressions in the blue to red spectral range through the glass ceramic on the display side using commercially available light sources (e.g. LEDs), glass ceramics are required that have an average transmission of >0.2%, preferably >0.4%, for each of the spectral ranges of 420-500nm, 500-620nm, and 550-640nm. As described in Fig. 1, the newer glass ceramic classes D and E meet this requirement, and with restrictions also class C. The previously widely used glass ceramic class A does not meet this requirement. With this glass ceramic, even the inventive color shifts across the entire visible spectral range are impossible with conventional lamps and filters, and in particular, white compensation is not possible. On the other hand, the spectral transmission must not be too high to prevent a view into the interior structure of the cooktops without additional aids, such as light-tight underside coatings, and to present an aesthetically preferred, color-uniform, non-transparent cooking surface. We define this maximum transmission as < 40%, preferably < 25% at 400nm and 700nm, and additionally an average of < 4% between 450-600nm. As in Fig. As can be seen from Figure 1, this second condition is met by all glass ceramic classes shown, except for Class C, which in practice appears too transparent to prevent a view into the inner workings of a cooktop. A further, third condition arises from the feasibility of a color shift to a white color impression of a commercially available light source through a glass ceramic cooktop and a not too complex compensation filter. For this to be possible, the transmission differences in the three spectral sensory ranges must not be too great. This is explained in Fig. 2. The color coordinates of standard illumination through glass ceramics according to the invention should lie within a limit curve G1, preferably a limit curve G2. The corner coordinates for the limit curves G1 and G2 are listed in Table 2.

[0013] If an observer perceives a light stimulus consisting of two light signals that are spatially adjacent to each other but do not appear to be spatially resolvable to the eye, and that are described by the intensity distribution of the light elements and by filter transmissions, the perceived sensory stimulus adds up linearly (Eq. 5), and the summary color location (x, y) lies in the chromaticity diagram CIExyY on a straight line between the color locations (x1, y1 ) and (x2, y2) of the two light signals (Eq. 6). In the special case of equal intensities (Eq. 7), (x, y) lies midway between the color coordinates of the two light signals (Eq. 8). A=1N∫a¯(λ)⋅(τ1(λ)⋅i1(λ)+τ2(λ)⋅i2(λ))⋯dλ=A1(τ1,k1i)+A1(τ2,k2i)miti1=k1⋅ii2=k2⋅ik1+k2=1 x=k1x1+k2x2with xi=f(τ,i), y,z accordingly. k1=k2=12 x=x1+x22,y=y1+y22,z=z1+z22=1−x−y.

[0014] This linear relationship is also known from color diagrams, for example, for image displays such as CRT or LCD monitors, where possible perceivable color locations in the CIE diagram lie in a triangle between the color locations of the display device's three primary colors, generally an RGB color space, or in a color polygon with more than three primary colors. Here, the color location is calculated from the linear combination of three or more primary intensities according to (Eq. 6).

[0015] In the inventive application of two filters arranged one behind the other, a substrate (for example glass ceramic) and a compensation filter, the relationship is no longer linear as illustrated in Equation 9 in comparison to Equation 5. In Equation 9, for τ1(λ) and τ2(λ), for example, the transmission spectra of the glass ceramic τ GK (λ) and the compensation filter τ KF (λ) can be used. A12=1N∫a¯(λ)⋅τ1(λ)⋅τ2(λ)⋅i(λ)⋯d(λ)

[0016] The color coordinate of the luminous element through the consecutively arranged filters no longer necessarily lies on a straight line between the color coordinates of the luminous element through the individual filters. Conversely, this leads to the phenomenon that the same common, inventively compensated color coordinate of a luminous element can be achieved through a glass ceramic with different compensation filters, whereby the color coordinate of the luminous element through the individual compensation filters need not be identical depending on the spectral distribution. Fig. 3, the color coordinates of the standard light E are individually separated by a type D glass ceramic and individually by various color filters B1-B7, which, when combined with the glass ceramic, make the standard light appear at the same overall color coordinate. In the example shown, the color filters are designed so that the overall color coordinate for the observer lies at the achromatic point E (gray or white point E).

[0017] With a color filter according to the invention, as described, it is thus possible to compensate for the shift of the original color location of the light source by the colored substrate, specifically to a white color location. A further application according to the invention is to shift the color location of the light source on the display side of the substrate to a desired color location that is different from the original color location of the light source. The combined shift of the color location by the substrate and the filter is intentionally not compensated for. This can be used to create color locations that cannot be represented, for example, by the available, fixed wavelengths of commercially available LEDs, for example a color location that lies between that of a yellow and orange LED. This is advantageous, for example, for the identification, differentiation and marketing of product lines.On the other hand, lighting elements can be constructed uniformly and thus cost-effectively using a single type of non-monochromatic, but rather spectrally broad-emitting, colored light source (e.g., white LEDs, fluorescent tubes). By applying various color filters according to the invention, different color coordinates can be created for different product lines or the same color coordinates of a product line combined with differently colored substrates. Color coordinate shifts and compensations are particularly applicable for spectrally broadband light sources, such as white LEDs, fluorescent tubes, or mixed colors of combined single-color LEDs, for example, RGB LEDs. Single-color, nearly monochromatic light sources, such as red, blue, or green LEDs, generally do not experience any noticeable color coordinate shift due to filters when used as a single color.

[0018] Compensating the color coordinate of a light source to white according to the invention does not mean precisely hitting the achromatic point E. Instead, the eye tolerates a wide color coordinate range as a white impression. This depends, among other things, on the color coordinates of the surrounding surfaces, such as a red-black cooktop surface. The goal is therefore, for the white compensation of any light element, to achieve a color coordinate that lies within the boundaries of the white range W1, preferably the white range W2. The white range W2 encompasses the ANSI-defined white fields (ANSI binning) 1A, ..., 1D, ..., 8D, which are typically used by LED manufacturers to characterize the color coordinates of their white LEDs. This range corresponds to color temperatures from 2580K to 7040K (CCT, color correlated temperature), corresponding to a white impression from cool white to warm white. The corner points of the white ranges W1 and W2 defined according to the invention in Fig. 3 are listed in Table 1.

[0019] According to the invention, the color coordinate compensation is not limited to the example coatings 1-4 or the standard light source E. Commercially available and cost-effective light sources, for example white LEDs, are preferably used in one application. Other colored, non-monochromatic light sources, such as fluorescent tubes or, for example, a combination of blue, green, and red LEDs (RGB light sources), which are set to a fixed color coordinate, for example as backlighting for LCD displays or control a color representation of the display, can also be used to compensate for the original color coordinate of the light sources by means of appropriately constructed compensation filters on the display side of the hob, or to create a white color impression or any desired color impression.

[0020] According to the invention, color location compensation is not limited to a white color location. Any desired color location can be set using a corresponding compensation filter, for example, brand-specific colors for displays or company logos, or different color locations for user-friendly differentiation of warning messages, instructions, or user aids, or different color locations for different power levels in cooking appliances. This can be used in a variety of examples, including easier user guidance, status displays, or different ambiences for decorative lighting.

[0021] The color layer allows for a sharp delineation of the signal field and shielding from stray light using various coating processes, such as screen printing. It also allows characters, symbols or lettering to be displayed that are visible to the user when the lighting is on and not perceptible when it is off. Even the position of these markings / logos is not visible when the lighting is off, so the user retains the monochrome, elegant appearance of the glass ceramic surface. This effect is known as the deadfront effect and is often desired by designers as it significantly enhances the overall aesthetic of the cooking appliance. This deadfront effect is only possible with the transparent glass ceramic cooking surfaces, which are particularly popular in Japan, with considerable additional effort. Due to the high transparency of these cooking surfaces, displays or lights are directly or indirectly visible.clearly visible, which is sometimes perceived as distracting. In contrast to these transparent cooking surfaces, the dark-colored cooking surfaces can still be combined with powerful radiant heaters, which significantly enhances the user experience of glass ceramic cooking appliances with radiant heaters or halogen heaters with the proposed method.

[0022] The sharp image of fine lines and lettering on the top side is possible without visually disturbing distortions when using glass ceramic cooktops that are usually dimpled on the underside. This is achieved by applying a compensation layer with a refractive index adjustment to the dimples. This is a further clear advantage over the printed masking on a dimpled underside described in US patent US 6 369 365 B1. Direct printing on the dimpled underside results in highly disturbing distortions, which means that only very large, coarse windows and symbols can be displayed. The cooktop thickness is usually 4 mm, but in commercial applications up to 6 mm. To increase color intensity or luminosity, it is also conceivable to use cooktops with a reduced thickness of, for example, 3 mm.

[0023] In addition to the main application areas outlined here for lighting with individual LEDs or 7-segment displays, this system is of course also suitable for any other light source and display format. For example, halogen lamps, light bars, fiber optics, or fluorescent tubes can also be used as light sources. In addition to illuminated dots or 7-segment displays, bar displays or illuminated markings for cooking zone identification or marking are also conceivable, or for illuminating larger cooking zone areas or borders. Furthermore, color locus compensations or shifts according to the invention can also be used for background lighting of alphanumeric or graphic displays, for example LCD displays. In addition to its preferred use in glass ceramic cooking appliances, this system can also be used in the panel area of ​​ovens or domino cooking appliances, including griddles.Glass ceramic fireplace surrounds are also well known, for example. These fireplace surrounds can also be illuminated using the proposed system to improve user comfort. The cooking surface can be flat, curved, or complexly shaped. Gas burners, induction coils, radiant heaters, or halogen heaters are all conceivable for heating the cooking zones.

[0024] Crucial to the desired overall color impression is a corresponding transmission curve, which results from the transmission curves of the substrate and the color filter (color layer). Since the transmission curve of the substrate is "predetermined," correction can only be made via the color layer.

[0025] The correction filter effect of the color layers is determined by the respective transmission curve in the visible range, by the following essential parameters: • Location of the transmission maximum • Width of the transmission maximum • Intensity of the transmission maximum •

[0026] The position and width of the transmission maximum is determined by the color composition, in particular by the coloring pigments.

[0027] The intensity, on the other hand, is determined by the layer thickness of the color and the concentration of the dye or color pigment in the color matrix.

[0028] So in Fig. 4 and Fig. 5 different dye concentrations depending on the transmission ( Fig. 4) and the color location ( Fig. 5), where Fig. 4 the spectra B1 to B4 optimized to compensate the standard light source E for the glass ceramic type D and in Fig. 5 shows the concentration curves B1 to B4. By carefully selecting the dye and / or pigment concentration, the color coordinate can be adjusted to the desired range.

[0029] The color layer with 1% and 0.8% heliogen blue (B1 and B2, respectively) lies at the edge of the white range W1. In contrast, B3 with 0.6% heliogen blue in the color matrix lies at the upper end of the white range W2, and B4 with 0.4% of the same blue pigment lies below W1. Due to the position of points B1-B4 in the color coordinate graph ( Fig. ) shows that the desired color coordinate can be achieved by specifically adjusting the pigment concentration. The dye or pigment concentration in the finished baked ink layer can be adjusted to the respective substrate by changing the layer thickness and / or the dye and / or pigment concentration in the ink matrix.

[0030] The color layer can be made from various color systems. Organic color systems are suitable for low-temperature applications, for example, while inorganic color systems, or mixtures thereof, are also suitable for high-temperature applications.

[0031] As explained above, the adapted transmission profile can be achieved through color layers consisting of a color matrix and / or dyes and / or pigments. Organic and inorganic dyes and / or pigments are used as dyes / pigments, preferably absorbing organic and inorganic dyes / pigments, particularly preferably blue, green and blue-green dyes / pigments. Of the blue-green dyes / pigments, those dyes / pigments whose transmission maximum is in the range of 400-600 nm, particularly preferably in the range 450-550 nm are preferred. Examples of dyes used include iron cyanide complexes, indanthrone, indigo, copper phthalocyanines, preferably the β-form of copper phthalocyanines, chromium chelates, preferably Cr3+ with ligands from the azo and azomethine series, e.g. Heliogen Blue 23050.

[0032] Examples of color pigments used are cobalt-tin oxide compounds (mixed oxides), aluminum silicates, preferably sulfur-containing aluminum silicates (e.g. ultramarine blue, green), zirconium silicates, preferably with added vanadium, particularly preferably with 1.5% added vanadium, zirconium silicate-vanadium oxides, calcium copper silicates, preferably CaCuSi4O10, copper carbonate compounds 2CuCO3*Cu(OH)2, cobalt-aluminum oxide compounds, preferably as cobalt aluminate (cobalt-aluminum spinel; Color Index Blue 28), and cobalt-chromium oxide compounds, preferably as cobalt chromite (cobalt-chromium spinel; Color Index Blue 36).

[0033] These pigments are preferably used as nanoparticles. In a special version, these pigments can also be applied as scattering particles.

[0034] The ink matrix can consist of organic and / or inorganic components, with the inorganic matrix being preferred, particularly for applications in the higher temperature range. An inorganic ink matrix generally consists of a glass powder and a medium with which the processability / printability, etc. can be adjusted. The organic ink matrix consists of a binder, solvent, and additives such as hardeners, crosslinkers, leveling agents, additives, defoamers, acidic and / or basic and / or cationic and / or anionic and / or radical polymerization initiators. Binders that can be used include rubber, polyurethane resins, silicones (organic and / or inorganic crosslinking), sol-gel compounds, hybrid polymers, acrylate-based systems, preferably methacrylates, epoxies, polyamides, polyimide, and mixtures thereof. These binders can be used with or without nanoparticles.

[0035] In particular, the coating composition may comprise sol-gel precursors of silicon, titanium, zirconium, aluminum, zinc, magnesium, calcium, tin, or mixtures thereof. The sol-gel precursors are particularly preferred: SiORxRy, TiORxXy, ZrORxXy, AlORxXy, ZnORxXy, MgORxXy, CaORxXy, and SnORxXy.

[0036] In one embodiment, the particle size of the sol-gel precursor and / or organometallic and / or inorganic nanoparticles is in a range from 0.05 to 200 nm, particularly preferably from 1 to 100 nm. The particle shape can be, in particular, spherical, irregular, or chain-like.

[0037] In a particularly preferred embodiment, the coating composition comprises a UV-curable and / or thermally curable hybrid polymer, hydrolyzed and condensed alkoxysilane precursor, in particular glycidylpropyloxyltriethoxysilane and / or methacryloxypropyloxytrimethoxysilane, which can be further functionalized with polysiloxanes. Methyl and / or phenyl-functionalized polysiloxanes are preferably used. The sol-gel layer on the glass-ceramic therefore preferably comprises the reaction products of the sol-gel precursors described herein with the polysiloxanes described herein.

[0038] In a particular embodiment of the invention, the coating contains inorganic nanoparticles. The nanoparticles improve, for example, the scratch resistance of the coating.

[0039] In this particular embodiment, inorganic nanoparticles are added to the coating solution. The volume fraction of the nanoparticles in the coating composition is preferably more than 10%, more preferably more than 20%. The nanoparticles are preferably added as an alcoholic dispersion.

[0040] The coating composition preferably also comprises nanoparticles in the form of amorphous or nanocrystalline metal oxides. Preferred metal oxides are silicon oxide (SiO2), titanium dioxide (TiO2), zirconium dioxide (ZrO2), Y2O3-stabilized zirconium oxide, aluminum oxide (Al2O3), zinc oxide (ZnO), and indium tin oxide (ITO). Hybrid polymer derivatives or compounds thereof can also preferably be used. The metal oxides can be in the form of particles and / or organometallic polymers.

[0041] Examples of solvents used include terpene, n-butyl acetate, carbitol, carbitol acetate, ethylene glycol monoethyl ether, and mixtures thereof. Ink matrices particularly suitable for screen printing require high-boiling solvents with a vapor pressure of < 5 hPa, preferably < 2 hPa, and particularly preferably < 1 hPa. Additionally, hardeners can be added, for example, to increase the layer hardness / scratch resistance, such as nanoparticles or bisepoxides. Depending on the coating process, various leveling agents can also be added, such as PEG, BYK 302, or BYK 306, to achieve homogeneous layer thicknesses. Especially when printing on non-smooth surfaces, such as dimpled surfaces, a wetting agent / leveling agent is added to allow the dimples to be reproduced.

[0042] The components of the color matrix and the dyes and / or pigments are homogenized, preferably using Dispermat (Ultraturax) or a three-roll mill.

[0043] Various coating processes are used, including printing processes such as inkjet printing, offset printing, pad printing, roll coating, and preferably screen printing; dipping, spin coating, and spraying. For these coating processes, the viscosity of the ink matrix must be adapted to processability / printability, particularly for the preferred screen printing process, the thixotropic behavior. For this purpose, organic thickeners such as cellulose compounds, polyvinylpyrimidone, polyethylene glycol, and block copolymers are used. Inorganic thickeners such as aerosils, flame-pyrolytic SiOx or AlOy particles produced by precipitation are used.

[0044] After coating, the color layers are thermally cured and / or UV cured; in the case of inorganic paint (ceramic paint), the color layer is fired at temperatures above 500°C, preferably > 700°C.

[0045] The filter effect of the inventive color layers requires homogeneous layer thicknesses, so that the fluctuations in the layer thickness are < 3 µm, preferably < 1 µm, most preferably < 0.5 µm. Therefore, smooth surfaces on both sides are preferred. "Smooth" in this context means that the top and bottom sides have approximately the same surface geometries, and the bottom side does not have the usual dimpled structure.

[0046] For non-smooth surfaces, such as dimpled surfaces, a refractive index-matched leveling layer can be applied directly to the surface. These can be made of polyurethane resins, silicones (organic and / or inorganic crosslinking), sol-gel compounds, hybrid polymers, acrylate-based systems, preferably methacrylates, epoxies, polyamides, polyimide, and mixtures thereof. This leveling layer can be used with or without nanoparticles. The previously described color layer is then applied to this leveling layer. Example 1: dark glass ceramic with smooth underside Production of binder A

[0047] 0.08 mol of GPTES (glycidyloxypropyltriethoxysilane) is hydrolyzed with 0.02 mol of TEOS (tetraethoxysilane) in water containing 0.125 mol of paratoluene acid. The solvent is then removed using a rotary evaporator, yielding 22.6 g of binder. Production of Binder B

[0048] 0.04 mol of MPTMS (methacryloxypropyltrimethoxysilane) is hydrolyzed with 0.02 mol of TEOS (tetraethoxysilane) and 0.04 mol of MTEOS (methyltriethoxysilane) in water containing 0.125 mol of paratoluic acid. The solvent is then removed using a rotary evaporator.

[0049] A commercially available dispersion of 15 nm SiO2 particles in diethylene glycol monopropyl ether is used as the nanoparticle-containing solution.

[0050] The starter solution contains 50 mass-% of thermally activated starter methylimidazole in ethylene glycol monopropyl ether.

[0051] The dark glass ceramic, which is smooth on both sides and made of a glass ceramic material equivalent to a glass ceramic of the CERAN HIGHTRANS eco® type and has a thickness of 4 mm, was screen-printed with a colour consisting of the following components on the underside: 30 mass-% binder A 65 mass-% nanoparticle-containing sol-gel solution 2 mass-% starter solution 3 mass % Heliogen Blue 23050

[0052] This ink was printed using two different mesh thicknesses and then cured for 3 minutes using a Dymax 500 UV lamp. With the 100-40 mesh thickness, the layer thickness was 4.9 µm, the layer was cracked, and the overall color impression was bluish when illuminated by a white LED.

[0053] With a 140-31 mesh, however, a layer thickness of 2.8 µm was achieved, exhibiting a closed, homogeneous surface structure. Using the same backlighting, a white overall impression was achieved. Example 2: dark glass ceramic with dimpled underside

[0054] A polyurethane resin leveling layer was screen-printed onto a dimpled, dark CERAN HIGHTRANS eco® glass-ceramic and then thermally cured. The layer thickness variation was < 3 µm. A color consisting of the following components was screen-printed onto this leveling layer: 32% Binder A 60% nanoparticle-containing sol-gel solution 2% starter solution 6% Spirit Blue 94030

[0055] Drying was carried out under UV radiation for 3 minutes.

[0056] The layer thickness variation was < 3µm; the light of a white LED was displayed as homogeneous white. Example 3: dark glass ceramic with dimpled underside

[0057] A polyurethane resin leveling layer was screen-printed onto a dimpled, dark CERAN HIGHTRANS eco® glass-ceramic and then thermally cured. The layer thickness variation was < 3 µm. A color consisting of the following components was screen-printed onto this leveling layer: 32% Binder B 60% nanoparticle-containing sol-gel solution 2% starter solution 6% Spirit Blue 94030

[0058] Drying was carried out using 60 min IR radiation combined with circulating air.

[0059] The layer thickness variation was < 3µm; the light of a white LED was displayed as homogeneous white. Example 4: dark glass ceramic with ceramic color layer

[0060] A ceramic ink was screen-printed onto a 4mm-thick, double-sided, smooth glass-ceramic sheet (a corresponding material such as CERAN HIGHTRANS eco®). The ink consisted of a borosilicate glass powder (40%), screen-printing medium (50%), and a blue pigment (10%) of CI Class 36 (cobalt aluminum oxide), which was homogenized in a three-roll mill.

[0061] This paint was fired in the oven at temperatures > 500°.

[0062] The layer thickness was 4µm, with a variation of <1µm. The color impression with a white LED backlight was white with a slight reddish tinge.

Claims

[1] Display device with a transparent colored glass ceramic, which has a front display side and a rear illumination side, wherein at least one luminous element is arranged in the region of the illumination side, characterized by , that a light compensation filter in the form of a colour layer is indirectly applied to the glass ceramic, or that a light compensation filter in the form of a colour layer comprising a colour matrix of organic and / or inorganic components is applied directly to the glass ceramic, that the light compensation filter compensates for the shift in the color location of the lamp caused by the colored glass ceramic or the color location of the lamp on the display side is shifted to a desired color location that is different from the original color location of the lamp, and that the glass-ceramic has an average transmission of >0.2% for each of the spectral ranges 420 nm to 500 nm, 500 nm to 620 nm and 550 nm to 640 nm, [2] Display device according to claim 1, characterized by that the color layer is applied as a paint application. [3] Display device according to claim 1 or 2, characterized by that the color layer is arranged on the illumination side. [4] Display device according to one of claims 1 to 3, characterized by that the color layer contains organic and / or inorganic dyes and / or color pigments, preferably blue, green and / or blue-green dyes and / or color pigments. [5] Display device according to claim 4, characterized by that the color pigments or at least some of the color pigments have a transmission maximum in the range from 400nm to 600nm, preferably in the range from 450nm to 550nm. [6] Display device according to one of claims 4 or 5, characterized by that at least some of the dye pigments consist of iron cyanide complexes, imdanthrone, indigo, copper phthalocyanine, preferably in the β-form of the copper phthalocyanines, chromium chelate, preferably Cr3+, with ligands from the azo or azomethine series, for example Heliogen Blue 23050, color pigments such as cobalt-tin oxide compounds (mixed oxides), aluminum silicates, preferably sulfur-containing aluminum silicates, zirconium silicates, preferably with added vanadium, particularly preferably with 1.5% added vanadium, zirconium silicate-vanadium oxide compounds, calcium-copper silicates, preferably CaCuSi4O10, copper carbonate compounds 2CuCo3*Cu(OH)2, cobalt-aluminum oxide compounds, preferably as cobalt aluminate (Cobalt-aluminium spinel; Colour Index Blue 28), and / or cobalt-chromium oxide compounds, preferably as cobalt-chromite (cobalt-chromium spinel; Colour Index Blue 36). [7] Display device according to one of claims 4 to 6, characterized by that at least part of the color pigments is formed by nanoparticles. [8] Display device according to one of claims 4 to 7, characterized by that the color pigments are applied as scattering particles on the color layer. [9] Display device according to one of claims 1 to 8, characterized by that the color layer applied indirectly to the glass ceramic has a color matrix of organic and / or inorganic components. [10] Display device according to claim 9, characterized by that the inorganic color matrix consists of glass powder. [11] Display device according to claim 9 or 10, characterized by that the organic color matrix contains binders, solvents and additives such as hardeners, leveling agents and additives. [12] Display device according to claim 11, characterized bythat the binder comprises rubber, polyurethane resins, silicones (organic and / or inorganic crosslinking), sol-gel compounds, hybrid polymers, acrylate-based systems, preferably methacrylates, epoxies, polyamides and / or polyimide. [13] Display device according to claims 9 to 12, characterized by that terpeniol, n-butyl acetate, carbitol, carbitol acetate, ethylene glycol monoethyl ether and / or high-boiling solvents with a vapor pressure < 5 hPa, preferably < 2 hPa, particularly preferably < 1 hPa, are used as solvents. [14] Display device according to one of claims 9 to 13, characterized by that nanoparticles and / or bis-epoxides are used as hardeners. [15] Display device according to one of claims 9 to 14, characterized by that PEG, BYK302 and / or BYK306 is used as leveling agent. [16] Display device according to one of claims 9 to 15, characterized bythat organic thickeners in the form of cellulose compounds, polyvinylpyrimidone, polyethylene glycol, block copolymers, aerosils, and / or flame-pyrolytic or precipitation-produced SiOx or AlxOy particles are used as additives. [17] Display device according to one of claims 1 to 16, characterized by that the color layer is burned into the surface of the glass ceramic or thermally and / or UV-cured. [18] Display device according to one of claims 1 to 17, characterized by that the variations in the thickness of the paint layer are < 3µm, preferably <1µm. [19] Display device according to one of claims 1 to 18, characterized by that a leveling layer is arranged between the glass ceramic and the color layer. [20] Display device according to claim 19, characterized by that the refractive index of the compensation layer differs from the refractive index of the glass ceramic by a maximum of 0.2, preferably less than 0.

1. [21] Display device according to claim 19 or 20, characterized by that the leveling layer comprises polyurethane resins, silicones (organic and / or inorganic crosslinking), sol-gel compounds, hybrid polymers, acrylate-based systems, preferably methacrylates, epoxies, polyamides and / or polyimide. [22] Display device according to one of claims 1 to 21, characterized by that the glass-ceramic has an average transmission of > 0.4% for each of the spectral ranges 420nm to 500nm, 500nm to 620nm and 550nm to 640nm. [23] Display device according to one of claims 1 to 22, characterized by that the maximum transmission is < 40%, preferably < 25%, at 400nm and 700nm, and on average < 4% between 450nm and 600nm. [24] Display device according to one of claims 1 to 23, characterized bythat the color location of the normal illumination through the glass ceramic is arranged within a limit curve, which is determined in the chromaticity diagram CIExyY-2° by the following corner coordination: Limit curve G1 x y 0,71 0,27 0,17 0,02 0,12 0,08 0,05 0,30 0,01 0,60 0,08 0,81 0,28 0,70 0,71 0,27 , preferably determined by the following corner coordination: Limit curve G2 x y 0,64 0,28 0,20 0,07 0,17 0,09 0,10 0,30 0,08 0,56 0,12 0,70 0,26 0,65 0,64 0,28 [25] Display device according to one of claims 1 to 24, characterized by that the light emitted on the display side is located within the limit curve, which is determined in the chromaticity diagram CIExyY-2° by the following corner coordinates: W1 x y 0,3 0,25 0,26 0,32 0,37 0,43 0,51 0,48 0,48 0,35 0,35 0,3 , preferably determined by the following corner coordinates: W2 x y 0,3068 0,3113 0,3028 0,3304 0,3205 0,3481 0,3207 0,3462 0,3376 0,3616 0,3551 0,376 0,3548 0,3736 0,3736 0,3874 0,4006 0,4044 0,3996 0,4015 0,4299 0,4165 0,4562 0,426 0,4813 0,4319 0,4593 0,3944 0,4147 0,3814 0,3889 0,369 0,3898 0,3716 0,367 0,3578 0,3512 0,3465 0,3515 0,3487 0,3366 0,3369 0,3222 0,3243 0,3221 0,3261 [26] Display device according to one of claims 1 to 25, characterized by that the glass ceramic has a thickness between the display side and the illumination side in the range between 2 and 6 mm. [27] Display device according to one of claims 1 to 26, characterized by that the glass ceramic is smooth on both sides. [28] Display device according to one of claims 1 to 27, characterized by that a white LED, an RGB light source and / or a non-monochromatic light source is arranged in the area of ​​the lighting side. [29] Display device according to one of claims 1 to 28, characterized by that the layer thickness of the paint layer is in the range between 30 - 1µm, preferably 10 - 2µm. [30] Display device according to one of claims 1 to 29, characterized by that the concentration of the dyes and / or color pigments of the color layer is in the range between 4 and 0.1 wt%, preferably between 2 and 0.4 wt%. [31] Display device according to one of claims 1 to 30, characterized by that the concentration of color pigments in the inorganic color layer is in the range between 40 and 1 wt%, preferably between 20 and 2 wt%, particularly preferably between 10 and 5 wt%.

Images