COMPOSITIONS CONTAINING PYRIDINE CARBOXYLATE HERBICIDES WITH ACETOLACTATE SYNTHASE (ALS) INHIBITOR HERBICIDES

Description

FIELD OF THE DISCLOSURE

[0001] The present disclosure includes compositions comprising (a) a pyridine carboxylate herbicide which is cyanomethyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate or propargyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate or an agriculturally acceptable N-oxide, or salt, thereof, (b) an acetolactate synthase (ALS) inhibitor or an agriculturally acceptable salt or ester thereof, and (c) a safener. The present disclosure also relates to methods of controlling undesirable vegetation using the same.

[0002] Pyridine carboxylate herbicides and compositions comprising them are disclosed, for instance, in application WO 2016 / 044285 A1.BACKGROUND

[0003] Many recurring problems in agriculture involve controlling the growth of undesirable vegetation that can, for instance, negatively affect the growth of desirable vegetation. To help control undesirable vegetation, researchers have produced a variety of chemicals and chemical formulations effective in controlling such unwanted growth. However, there exists a need for new herbicides compositions and methods to control the growth of undesirable vegetation.SUMMARY OF THE DISCLOSURE

[0004] Disclosed herein are compositions that may be used as herbicides, for example, in crops. The compositions contain (a) a pyridine carboxylate herbicide which is cyanomethyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate or propargyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate or agriculturally acceptable N-oxide, or salt thereof, (b) an acetolactate synthase inhibitor ("ALS inhibitor") or an agriculturally acceptable salt or ester thereof, and (c) a safener. The weight ratio of (a) to (b) can be from 1:3400 to 1200:1 (e.g., from 1:1700 to 600:1, from 1:280 to 160:1, from 1:10 to 16:1, from 1:14 to 10:1, or from 1:5 to 5:1).

[0005] In some aspects, the composition comprises: (a) the pyridine carboxylate herbicide compound cyanomethyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate, referred to hereinafter as Compound A: or an agriculturally acceptable N-oxide, or salt thereof; (b) an ALS inhibitor or an agriculturally acceptable salt or ester thereof; and (c) a safener.

[0006] In some aspects, the composition comprises: (a) the pyridine carboxylate herbicide compound propargyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate, referred to hereinafter as Compound B: or an agriculturally acceptable N-oxide, or salt thereof; (b) an ALS inhibitor or an agriculturally acceptable salt or ester thereof; and (c) a safener.

[0007] In some aspects, (b) can comprise a triazolopyrimidine sulfonamide herbicide. In some aspects, (b) can include florasulam, cloransulam, diclosulam, flumetsulam, metosulam, penoxsulam, or pyroxsulam, agriculturally acceptable salts or esters thereof, or combinations thereof.

[0008] In some aspects, (b) can comprise an imidazolinone herbicide. In some aspects, (b) can include imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, or imazethapyr, agriculturally acceptable salts or esters thereof, or combinations thereof.

[0009] In some aspects, (b) can comprise a pyrimidinyl oxybenzoate herbicide. In some aspects, (b) can include bispyribac, pyribenzoxim, pyriftalid, pyriminobac, pyrimisulfan, or pyrithiobac, agriculturally acceptable salts or esters thereof, or combinations thereof.

[0010] In some aspects, (b) can comprise a sulfonylaminocarbonyl triazolinone herbicide. In some aspects, (b) can include flucarbazone, propoxycarbazone, or thiencarbazone, agriculturally acceptable salts or esters thereof, or combinations thereof.

[0011] In some aspects, (b) can comprise a sulfonylurea herbicide. In some aspects, (b) can include amidosulfuron, azimsulfuron, bensulfuron, chlorimuron, chlorsulfuron, cinosulfuron, cyclosulfamuron, ethametsulfuron, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron, foramsulfuron, halosulfuron, imazosulfuron, iodosulfuron, iofensulfuron, mesosulfuron, metazosulfuron, metsulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, primisulfuron, propyrisulfuron, prosulfuron, pyrazosulfuron, rimsulfuron, sulfometuron, sulfosulfuron, triasulfuron, tribenuron, thifensulfuron, trifloxysulfuron, or tritosulfuron, agriculturally acceptable salts or esters thereof, or combinations thereof.

[0012] In some aspects, the composition can further comprise an agriculturally acceptable adjuvant or carrier, an additional pesticide, or combinations thereof. In some aspects, the composition can be provided as a herbicidal concentrate.

[0013] Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation, to an area adjacent the vegetation, or to soil or water to control the emergence or growth of vegetation, a composition comprising: (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof; (b) an ALS inhibitor or an agriculturally acceptable salt or ester thereof; and (c) a safener. In some aspects, (a) and (b) are applied pre-emergence of the undesirable vegetation. In some aspects, (a) and (b) are applied post-emergence of the undesirable vegetation. In some aspects, the undesirable vegetation is in cereals. In some aspects, the undesirable vegetation is in maize, wheat, barley, rice, sorghum, millet, or oats. In some aspects, the undesirable vegetation is in broadleaf crops. In some aspects, the undesirable vegetation is in canola, flax, sunflower, soy, or cotton.

[0014] In some aspects, the pyridine carboxylate herbicide (a) can be applied in an amount of from 0.5 gram acid equivalent per hectare (g ae / ha) to 300 g ae / ha (e.g., from 30 g ae / ha to 40 g ae / ha). In some cases, the ALS inhibitor (b) can be applied in an amount of from 0.25 g ai / ha to 1000 g ai / ha (e.g., from 3 g ai / ha to 40 g ai / ha). In some cases, (a) and (b) can be applied in a weight ratio of from 1:3400 to 1200:1 (e.g., from 1:1700 to 600:1, from 1:280 to 160:1, from 1:10 to 16:1, from 1:14 to 10:1, or from 1:5 to 5:1).

[0015] The description below sets forth details of one or more aspect of the present disclosure. Other features, objects, and advantages will be apparent from the description and from the claims.DETAILED DESCRIPTION

[0016] The present disclosure includes compositions comprising: (a) a pyridine carboxylate herbicide which is cyanomethyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate or propargyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate or an agriculturally acceptable N-oxide, or salt thereof, (b) an ALS inhibitor or an agriculturally acceptable salt or ester thereof, and (c) a safener. The present disclosure also includes methods for controlling undesirable vegetation. In some aspects, the undesirable vegetation is in cereals. In some aspects, the undesirable vegetation is in maize, wheat, barley, rice, sorghum, millet, or oats. In some aspects, the undesirable vegetation is in broadleaf crops. In some aspects, the undesirable vegetation is in canola, flax, sunflower, soy, or cotton.I. Definitions

[0017] Terms used herein will have their customary meaning in the art unless specified otherwise. The singular forms "a" and "the" include plural references unless stated otherwise. To the extent that the term "or" is employed (e.g., A or B) it is intended to mean "A or B or both." If this disclosure intends to indicate "only A or B but not both" then the term "only A or B but not both" will be employed. Thus, use of the term "or" herein is the inclusive and not the exclusive use.

[0018] The prefix C n -C m preceding a group or moiety indicates, in each case, the possible number of carbon atoms in the group or moiety that follows.

[0019] As used herein, the terms "herbicide" and "herbicidal active ingredient" may be understood to include an active ingredient that kills, controls, or otherwise adversely modifies the growth of vegetation, particularly undesirable vegetation such as weed species, when applied in an appropriate amount.

[0020] As used herein, the term "herbicidal effect" may be understood to include an adversely modifying effect of an active ingredient on vegetation, including, for example, a deviation from natural growth or development, killing, regulation, desiccation, growth inhibition, growth reduction, and retardation. The term "herbicidal activity" refers generally to herbicidal effects of an active ingredient. As used herein, the term "prevents" or similar terms such as "preventing" may be understood by a person of ordinary skill to include any combination that shows herbicidal effect or reduces the competitive capability of the weed with respect to a crop.

[0021] As used herein, "applying" a herbicide or herbicidal composition refers to delivering it directly to the targeted vegetation or to the locus thereof or to the area where control of undesirable vegetation is desired. Methods of application include, but are not limited to, pre-emergently contacting soil or water, post-emergently contacting the undesirable vegetation, or contacting the area adjacent to the undesirable vegetation.

[0022] As used herein, the term "vegetation" can include, for instance, dormant seeds, germinating seeds, emerging seedlings, plants propagating from vegetative propagules, immature vegetation, and established vegetation.

[0023] As used herein, the term "crop" refers to desired vegetation, for instance, plants that are grown to provide food, shelter, pasture, erosion control, etc. Example crops include cereals, legumes, vegetables, orchard and timber trees, grapevines, etc. Preferably, herbicides or herbicidal compositions have zero or minimal herbicidal effect on crops.

[0024] As used herein, the term "undesirable vegetation" refers to vegetation that is not wanted in a given area, for instance, weed species. Herbicides or herbicidal compositions are used to control undesirable vegetation. Preferably, herbicides or herbicidal compositions have a large or complete herbicidal effect on undesirable vegetation.

[0025] As used herein, "active ingredient" or "ai" may be understood to include a chemical compound or composition that has an effect on vegetation, for example, a herbicidal effect or a safening effect on the vegetation.

[0026] As used herein, "acid equivalent" or "ae" may be understood to include the amount of the acid form of an active ingredient that is calculated from the amount of a salt or ester form of that active ingredient. For example, if the acid form of an active ingredient "Z" has a molecular weight of 100 Dalton, and the salt form of Z has a molecular weight of 130 Dalton, an application of 130 g ai / ha of the Z salt would be equal to applying 100 g ae / ha of the acid form of Z : 130 g ai / ha Z salt * 100 Da Z acid / 130 Da Z salt = 100 g ae / ha Z acid .

[0027] As used herein, unless otherwise specified, the term "acyl" may be understood to include a group of formula -C(O)R, where "C(O)" is short-hand notation for C=O. In the acyl group, the R may be alkyl (e.g., C 1 -C 6 alkyl), haloalkyl (e.g., C 1 -C 6 haloalkyl), alkenyl (e.g., C 2 -C 6 alkenyl), haloalkenyl (e.g., C 2 -C 6 haloalkenyl), alkynyl (e.g., C 2 -C 6 alkynyl), aryl or heteroaryl, or arylalkyl (e.g., C 7 -C 10 arylalkyl).

[0028] As used herein, the term "alkyl" may be understood to include saturated, straight-chained, or branched saturated hydrocarbon moieties. Unless otherwise specified, C 1 -C 20 (e.g., C 1 -C 12 , C 1 -C 10 , C 1 -C 8 , C 1 -C 6 , or C 1 -C 4 ) alkyl groups are intended. Examples of alkyl groups include methyl, ethyl, propyl, cyclopropyl, 1-methyl-ethyl, butyl, cyclobutyl, 1-methyl-propyl, 2-methyl-propyl, 1,1-dimethyl-ethyl, pentyl, cyclopentyl, 1-methyl-butyl, 2-methyl-butyl, 3-methyl-butyl, 2,2-dimethyl-propyl, 1-ethyl-propyl, hexyl, cyclohexyl, 1,1-dimethyl-propyl, 1,2-dimethyl-propyl, 1-methyl-pentyl, 2-methyl-pentyl, 3-methyl-pentyl, 4-methyl-pentyl, 1,1-dimethyl-butyl, 1,2-dimethyl-butyl, 1,3-dimethyl-butyl, 2,2-dimethyl-butyl, 2,3-dimethyl-butyl, 3,3-dimethyl-butyl, 1-ethyl-butyl, 2-ethyl-butyl, 1,1,2-trimethyl-propyl, 1,2,2-trimethyl-propyl, 1-ethyl-1-methyl-propyl, and 1-ethyl-2-methyl-propyl. Alkyl substituents may also be substituted with one or more chemical moieties. Examples of suitable substituents include, for example, hydroxy, nitro, cyano, formyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, C 1 -C 6 acyl, C 1 -C 6 alkylthio, C 1 -C 6 haloalkylthio, C 1 -C 6 alkylsulfinyl, C 1 -C 6 haloalkylsulfinyl, C 1 -C 6 alkylsulfonyl, C 1 -C 6 haloalkylsulfonyl, C 1 -C 6 alkoxycarbonyl, C 1 -C 6 haloalkoxycarbonyl, C 1 -C 6 carbamoyl, C 1 -C 6 halocarbamoyl, hydroxycarbonyl, C 1 -C 6 alkylcarbonyl, C 1 -C 6 haloalkylcarbonyl, aminocarbonyl, C 1 -C 6 alkylaminocarbonyl, haloalkylaminocarbonyl, C 1 -C 6 dialkylaminocarbonyl, and C 1 -C 6 dihaloalkylaminocarbonyl, provided that the substituents are sterically compatible and the rules of chemical bonding and strain energy are satisfied. Preferred substituents include cyano and C 1 -C 6 alkoxy.

[0029] As used herein, the term "haloalkyl" may be understood to include straight-chained or branched alkyl groups, wherein the hydrogen atoms may partially or entirely be substituted with halogen atoms. Unless otherwise specified, C 1 -C 20 (e.g., C 1 -C 12 , C 1 -C 10 , C 1 -C 8 , C 1 -C 6 , or C 1 -C 4 ) alkyl groups are intended. Examples include chloromethyl, bromomethyl, dichloromethyl, trichloromethyl, fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl, chlorodifluoromethyl, 1-chloroethyl, 1-bromoethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl, 2,2-dichloro-2-fluoroethyl, 2,2,2-trichloroethyl, pentafluoroethyl, and 1,1,1-trifluoroprop-2-yl. Haloalkyl substituents may also be substituted with one or more chemical moieties. Examples of suitable substituents include, for example, hydroxy, nitro, cyano, formyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, C 1 -C 6 acyl, C 1 -C 6 alkylthio, C 1 -C 6 haloalkylthio, C 1 -C 6 alkylsulfinyl, C 1 -C 6 haloalkylsulfinyl, C 1 -C 6 alkylsulfonyl, C 1 -C 6 haloalkylsulfonyl, C 1 -C 6 alkoxycarbonyl, C 1 -C 6 haloalkoxycarbonyl, C 1 -C 6 carbamoyl, C 1 -C 6 halocarbamoyl, hydroxycarbonyl, C 1 -C 6 alkylcarbonyl, C 1 -C 6 haloalkylcarbonyl, aminocarbonyl, C 1 -C 6 alkylaminocarbonyl, haloalkylaminocarbonyl, C 1 -C 6 dialkylaminocarbonyl, and C 1 -C 6 dihaloalkylaminocarbonyl, provided that the substituents are sterically compatible and the rules of chemical bonding and strain energy are satisfied. Preferred substituents include cyano and C 1 -C 6 alkoxy.

[0030] As used herein, the term "alkoxy" may be understood to include a group of the formula R-O-, where R is unsubstituted or substituted alkyl as defined above. Unless otherwise specified, alkoxy groups wherein R is a C 1 -C 20 (e.g., C 1 -C 12 , C 1 -C 10 , C 1 -C 8 , C 1 -C 6 , or C 1 -C 4 ) alkyl group are intended. Examples include methoxy, ethoxy, propoxy, 1-methyl-ethoxy, butoxy, 1-methyl-propoxy, 2-methyl-propoxy, 1,1-dimethyl-ethoxy, pentoxy, 1-methyl-butyloxy, 2-methyl-butoxy, 3-methyl-butoxy, 2,2-dimethyl-propoxy, 1-ethyl-propoxy, hexoxy, 1,1-dimethyl-propoxy, 1,2-dimethyl-propoxy, 1-methyl-pentoxy, 2-methyl-pentoxy, 3-methyl-pentoxy, 4-methyl-penoxy, 1,1-dimethyl-butoxy, 1,2-dimethyl-butoxy, 1,3-dimethyl-butoxy, 2,2-dimethyl-butoxy, 2,3-dimethyl-butoxy, 3,3-dimethyl-butoxy, 1-ethyl-butoxy, 2-ethylbutoxy, 1,1,2-trimethyl-propoxy, 1,2,2-trimethyl-propoxy, 1-ethyl-1-methyl-propoxy, and 1-ethyl-2-methyl-propoxy.

[0031] As used herein, the term "alkoxycarbonyl" may be understood to include a group of the formula -C(O)OR, where R is an unsubstituted or substituted alkyl as defined above. Unless otherwise specified, alkoxycarbonyl groups wherein R is a C 1 -C 20 (e.g., C 1 -C 12 , C 1 -C 10 , C 1 -C 8 , C 1 -C 6 , or C 1 -C 4 ) alkyl group are intended. Examples include methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl, 1-methyl-ethoxycarbonyl, butoxycarbonyl, 1-methyl-propoxycarbonyl, 2-methyl-propoxycarbonyl, 1,1-dimethyl-ethoxycarbonyl, pentoxycarbonyl, 1-methyl-butoxycarbonyl, 2-methyl-butoxycarbonyl, 3-methyl-butoxycarbonyl, 2,2-dimethyl-propoxycarbonyl, 1-ethyl-propoxycarbonyl, hexoxycarbonyl, 1,1-dimethyl-propoxycarbonyl, 1,2-dimethyl-propoxycarbonyl, 1-methyl-pentoxycarbonyl, 2-methyl-pentoxycarbonyl, 3-methyl-pentoxycarbonyl, 4-methyl-penoxycarbonyl, 1,1-dimethyl-butoxycarbonyl, 1,2-dimethyl-butoxycarbonyl, 1,3-dimethyl-butoxycarbonyl, 2,2-dimethyl-butoxycarbonyl, 2,3-dimethyl-butoxycarbonyl, 3,3-dimethyl-butoxycarbonyl, 1-ethyl-butoxycarbonyl, 2-ethylbutoxycarbonyl, 1,1,2-trimethyl-propoxycarbonyl, 1,2,2-trimethyl-propoxycarbonyl, 1-ethyl-1-methyl-propoxycarbonyl, and 1-ethyl-2-methyl-propoxycarbonyl.

[0032] As used herein, the term "haloalkoxy" may be understood to include a group of the formula R-O-, where R is unsubstituted or substituted haloalkyl as defined above. Unless otherwise specified, haloalkoxy groups wherein R is a C 1 -C 20 (e.g., C 1 -C 12 , C 1 -C 10 , C 1 -C 8 , C 1 -C 6 , or C 1 -C 4 ) alkyl group are intended. Examples include chloromethoxy, bromomethoxy, dichloromethoxy, trichloromethoxy, fluoromethoxy, difluoromethoxy, trifluoromethoxy, chlorofluoromethoxy, dichlorofluoromethoxy, chlorodifluoromethoxy, 1-chloroethoxy, 1-bromoethoxy, 1-fluoroethoxy, 2-fluoroethoxy, 2,2-difluoroethoxy, 2,2,2-trifluoroethoxy, 2-chloro-2-fluoroethoxy, 2-chloro-2,2-difluoroethoxy, 2,2-dichloro-2-fluoroethoxy, 2,2,2-trichloroethoxy, pentafluoroethoxy, and 1,1,1-trifluoroprop-2-oxy.

[0033] As used herein, the term "aryl," as well as derivative terms such as aryloxy, may be understood to include groups that include a monovalent aromatic carbocyclic group of from 6 to 14 carbon atoms. Aryl groups can include a single ring or multiple condensed rings. In some aspects, aryl groups include C 6 -C 10 aryl groups. Examples of aryl groups include, but are not limited to, phenyl, biphenyl, naphthyl, tetrahydronaphthyl, phenylcyclopropyl, and indanyl. In some aspects, the aryl group can be a phenyl, indanyl or naphthyl group.

[0034] As used herein, the term "heteroaryl," as well as derivative terms such as "heteroaryloxy," may be understood to include a 5- or 6-membered aromatic ring containing one or more heteroatoms, for example, N, O or S. Heteroaryl rings may be fused to other aromatic systems. The aryl or heteroaryl substituents may also be substituted with one or more chemical moieties. Examples of suitable substituents include, for example, hydroxy, nitro, cyano, formyl, C 1 -C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkyl, C 1 -C 6 haloalkoxy, C 1 -C 6 acyl, C 1 -C 6 alkylthio, C 1 -C 6 alkylsulfinyl, C 1 -C 6 alkylsulfonyl, C 1 -C 6 alkoxycarbonyl, C 1 -C 6 carbamoyl, hydroxycarbonyl, C 1 -C 6 alkylcarbonyl, aminocarbonyl, C 1 -C 6 alkylaminocarbonyl, C 1 -C 6 dialkylaminocarbonyl, provided that the substituents are sterically compatible and the rules of chemical bonding and strain energy are satisfied. Preferred substituents include halogen, C 1 -C 4 alkyl and C 1 -C 4 haloalkyl.

[0035] As used herein, the term "halogen," including derivative terms such as "halo," refers to fluorine, chlorine, bromine and iodine.

[0036] As used herein, agriculturally acceptable salts and esters may be understood to include salts and esters that exhibit herbicidal activity, or that are or can be converted in plants, water, or soil to the referenced herbicide. Exemplary agriculturally acceptable esters are those that are or can be hydrolyzed, oxidized, metabolized, or otherwise converted, e.g., in plants, water, or soil, to the corresponding carboxylic acid which, depending on the pH, may be in the dissociated or undissociated form.

[0037] Compounds described herein can include N-oxides. Pyridine N-oxides can be obtained by oxidation of the corresponding pyridines. Suitable oxidation methods are described, for example, in Houben-Weyl, Methoden der organischen Chemie [Methods in organic chemistry], expanded and subsequent volumes to the 4th edition, volume E 7b, p. 565 f.II. Pyridine Carboxylate Herbicides

[0038] Compositions and methods of the present disclosure include a composition comprising (a) a pyridine carboxylate herbicide which is cyanomethyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate or propargyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate or an agriculturally acceptable N-oxide, or salt thereof; (b) an ALS inhibitor or an agriculturally acceptable salt or ester thereof; and (c) a safener.

[0039] In some aspects, compositions and methods of the present disclosure include the composition comprising (a) the pyridine carboxylate herbicide cyanomethyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate, Compound A: or an agriculturally acceptable N-oxide, or salt thereof, (b) an ALS inhibitor or an agriculturally acceptable salt or ester thereof, and (c) a safener.

[0040] In some aspects, compositions and methods of the present disclosure include the composition comprising (a) the pyridine carboxylate herbicide propargyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate, Compound B: or an agriculturally acceptable N-oxide, or salt thereof, (b) an ALS inhibitor or an agriculturally acceptable salt or ester thereof, and (c) a safener.

[0041] The above pyridine carboxylate herbicides, as well as methods of making these pyridine carboxylate herbicides, are disclosed in application WO 2018 / 208582 A1.

[0042] In some aspects, the pyridine carboxylate herbicide can be provided as an agriculturally acceptable salt. Exemplary agriculturally acceptable salts of the pyridine carboxylate herbicides include, but are not limited to: sodium salts; potassium salts; ammonium salts or substituted ammonium salts, in particular mono-, di- and tri-C 1 -C 8 -alkylammonium salts such as methyl ammonium, dimethylammonium and isopropylammonium; mono-, di- and tri-hydroxy-C 2 -C 8 -alkylammonium salts such as hydroxyethylammonium, di(hydroxyethyl)ammonium, tri(hydroxyethyl)ammonium, hydroxypropylammonium, di(hydroxypropyl)ammonium and tri(hydroxypropyl)ammonium salts; olamine salts; diglycolamine salts; choline salts; and quaternary ammonium salts such as those represented by the formula R 9< R 10< R 11< R 12< N +< and wherein R 9< , R 10< , R 11< and R 12< (e.g., R 9< -R 12< ) each independently can represent hydrogen, C 1 -C 10 alkyl, C 2 -C 8 alkenyl, C 2 -C 8 alkynyl, C 1 -C 8 alkoxy, C 1 -C 8 alkylthio, or aryl groups, provided that R 9< -R 12< are sterically compatible.

[0043] The pyridine carboxylate herbicide, or an agriculturally acceptable N-oxide, or saltthereof, can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, the pyridine carboxylate herbicide, or an agriculturally acceptable N-oxide, or salt thereof, is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 0.1 grams acid equivalent per hectare (g ae / ha) or greater, such as 0.2 g ae / ha or greater, 0.3 g ae / ha or greater, 0.4 g ae / ha or greater, 0.5 g ae / ha or greater, 0.6 g ae / ha or greater, 0.7 g ae / ha or greater, 0.8 g ae / ha or greater, 0.9 g ae / ha or greater, 1 g ae / ha or greater, 1.1 g ae / ha or greater, 1.2 g ae / ha or greater, 1.3 g ae / ha or greater, 1.4 g ae / ha or greater, 1.5 g ae / ha or greater, 1.6 g ae / ha or greater, 1.7 g ae / ha or greater, 1.8 g ae / ha or greater, 1.9 g ae / ha or greater, 2 g ae / ha or greater, 2.25 g ae / ha or greater, 2.5 g ae / ha or greater, 2.75 g ae / ha or greater, 3 g ae / ha or greater, 4 g ae / ha or greater, 5 g ae / ha or greater, 6 g ae / ha or greater, 7 g ae / ha or greater, 8 g ae / ha or greater, 9 g ae / ha or greater, 10 g ae / ha or greater, 11 g ae / ha or greater, 12 g ae / ha or greater, 13 g ae / ha or greater, 14 g ae / ha or greater, 15 g ae / ha or greater, 16 g ae / ha or greater, 17 g ae / ha or greater, 18 g ae / ha or greater, 19 g ae / ha or greater, 20 g ae / ha or greater, 22 g ae / ha or greater, 24 g ae / ha or greater, 25 g ae / ha or greater, 26 g ae / ha or greater, 28 g ae / ha or greater, 30 g ae / ha or greater, 32 g ae / ha or greater, 34 g ae / ha or greater, 35 g ae / ha or greater, 36 g ae / ha or greater, 38 g ae / ha or greater, 40 g ae / ha or greater, 42.5 g ae / ha or greater, 45 g ae / ha or greater, 47.5 g ae / ha or greater, 50 g ae / ha or greater, 52.5 g ae / ha or greater, 55 g ae / ha or greater, 57.5 g ae / ha or greater, 60 g ae / ha or greater, 65 g ae / ha or greater, 70 g ae / ha or greater, 75 g ae / ha or greater, 80 g ae / ha or greater, 85 g ae / ha or greater, 90 g ae / ha or greater, 95 g ae / ha or greater, 100 g ae / ha or greater, 110 g ae / ha or greater, 120 g ae / ha or greater, 130 g ae / ha or greater, 140 g ae / ha or greater, 150 g ae / ha or greater, 160 g ae / ha or greater, 170 g ae / ha or greater, 180 g ae / ha or greater, 190 g ae / ha or greater, 200 g ae / ha or greater, 210 g ae / ha or greater, 220 g ae / ha or greater, 230 g ae / ha or greater, 240 g ae / ha or greater, 250 g ae / ha or greater, 260 g ae / ha or greater, 270 g ae / ha or greater, 280 g ae / ha or greater, or 290 g ae / ha or greater; in an amount of 300 g ae / ha or less, such as 290 g ae / ha or less, 280 g ae / ha or less, 270 g ae / ha or less, 260 g ae / ha or less, 250 g ae / ha or less, 240 g ae / ha or less, 230 g ae / ha or less, 220 g ae / ha or less, 210 g ae / ha or less, 200 g ae / ha or less, 190 g ae / ha or less, 180 g ae / ha or less, 170 g ae / ha or less, 160 g ae / ha or less, 150 g ae / ha or less, 140 g ae / ha or less, 130 g ae / ha or less, 120 g ae / ha or less, 110 g ae / ha or less, 100 g ae / ha or less, 95 g ae / ha or less, 90 g ae / ha or less, 85 g ae / ha or less, 80 g ae / ha or less, 75 g ae / ha or less, 70 g ae / ha or less, 65 g ae / ha or less, 60 g ae / ha or less, 57.5 g ae / ha or less, 55 g ae / ha or less, 52.5 g ae / ha or less, 50 g ae / ha or less, 47.5 g ae / ha or less, 45 g ae / ha or less, 42.5 g ae / ha or less, 40 g ae / ha or less, 38 g ae / ha or less, 36 g ae / ha or less, 35 g ae / ha or less, 34 g ae / ha or less, 32 g ae / ha or less, 30 g ae / ha or less, 28 g ae / ha or less, 26 g ae / ha or less, 25 g ae / ha or less, 24 g ae / ha or less, 22 g ae / ha or less, 20 g ae / ha or less, 19 g ae / ha or less, 18 g ae / ha or less, 17 g ae / ha or less, 16 g ae / ha or less, 15 g ae / ha or less, 14 g ae / ha or less, 13 g ae / ha or less, 12 g ae / ha or less, 11 g ae / ha or less, 10 g ae / ha or less, 9 g ae / ha or less, 8 g ae / ha or less, 7 g ae / ha or less, 6 g ae / ha or less, 5 g ae / ha or less, 4 g ae / ha or less, 3 g ae / ha or less, 2.75 g ae / ha or less, 2.5 g ae / ha or less, 2.25 g ae / ha or less, 2 g ae / ha or less, 1.9 g ae / ha or less, 1.8 g ae / ha or less, 1.7 g ae / ha or less, 1.6 g ae / ha or less, 1.5 g ae / ha or less, 1.4 g ae / ha or less, 1.3 g ae / ha or less, 1.2 g ae / ha or less, 1.1 g ae / ha or less, 1 g ae / ha or less, 0.9 g ae / ha or less, 0.8 g ae / ha or less, 0.7 g ae / ha or less, 0.6 g ae / ha or less, 0.5 g ae / ha or less, 0.4 g ae / ha or less, 0.3 g ae / ha or less, or 0.2 g ae / ha or less; or in an amount within any range defined between any pair of the preceding values, such as 0.1-300 g ae / ha, 1-150 g ae / ha, 10-200 g ae / ha, 25 g ae / ha-75 g ae / ha, or 40-100 g ae / ha.III. ALS Inhibitors

[0044] In addition to the pyridine carboxylate herbicide or agriculturally acceptable N-oxide, or salt thereof, the compositions include an acetolactate synthase (ALS) inhibitor. ALS inhibitors disrupt the production of amino acids in the plant, which eventually leads to inhibition of DNA synthesis. Examples of ALS inhibitors include sulfonylureas, imidazolinones, triazolopyrimidine sulfonamides, pyrimidinyl oxybenzoates and sulfonylaminocarbonyl triazolinones. In some aspects, the ALS inhibitor can contain a triazolopyrimidine sulfonamide herbicide. In some aspects, the ALS inhibitor can contain an imidazolinone herbicide. In some aspects, the ALS inhibitor can contain a pyrimidinyl oxybenzoate herbicide. In some aspects, the ALS inhibitor can contain a sulfonylaminocarbonyl triazolinone herbicide. In some aspects, the ALS inhibitor can contain a sulfonylurea herbicide.

[0045] In some aspects, the composition can include an ALS inhibitor selected from the group of imidazolinones, triazolopyrimidine sulfonamides, pyrimidinyl oxybenzoates, sulfonylaminocarbonyl triazolinones, sulfonylureas, and combinations thereof. In some cases, the composition can include amidosulfuron, azimsulfuron, bispyribac, bensulfuron, chlorimuron, chlorsulfuron, cinosulfuron, cloransulam, cyclosulfamuron, diclosulam, ethametsulfuron, ethoxysulfuron, flazasulfuron, florasulam, flucarbazone, flucetosulfuron, flumetsulam, flupyrsulfuron, foramsulfuron, halosulfuron, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, imazosulfuron, iodosulfuron, iofensulfuron, mesosulfuron, metazosulfuron, metosulam, metsulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, penoxsulam, primisulfuron, propoxycarbazone, propyrisulfuron, prosulfuron, pyrazosulfuron, pyribenzoxim, pyriftalid, pyriminobac, pyrimisulfan, pyrithiobac, pyroxsulam, rimsulfuron, sulfometuron, sulfosulfuron, thiencarbazone, thifensulfuron, triasulfuron, tribenuron, trifloxysulfuron, triflusulfuron, tritosulfuron, agriculturally acceptable salts and esters thereof, and combinations thereof.

[0046] The ALS inhibitor or agriculturally acceptable salt or ester thereof can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, the ALS inhibitor or agriculturally acceptable salt or ester thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 0.25 grams active ingredient per hectare (g ai / ha) or more, such as 0.3 g ai / ha or more, 0.4 g ai / ha or more, 0.5 g ai / ha or more, 0.6 g ai / ha or more, 0.7 g ai / ha or more, 0.8 g ai / ha or more, 0.9 g ai / ha or more, 1 g ai / ha or more, 1.5 g ai / ha or more, 2 g ai / ha or more, 2.5 g ai / ha or more, 3 g ai / ha or more, 3.5 g ai / ha or more, 4 g ai / ha or more, 4.5 g ai / ha or more, 5 g ai / ha or more, 6 g ai / ha or more, 7 g ai / ha or more, 8 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 15 g ai / ha or more, 20 g ai / ha or more, 25 g ai / ha or more, 30 g ai / ha or more, 35 g ai / ha or more, 40 g ai / ha or more, 45 g ai / ha or more, 50 g ai / ha or more, 55 g ai / ha or more, 60 g ai / ha or more, 65 g ai / ha or more, 70 g ai / ha or more, 75 g ai / ha or more, 80 g ai / ha or more, 85 g ai / ha or more, 90 g ai / ha or more, 95 g ai / ha or more, 100 g ai / ha or more, 110 g ai / ha or more, 120 g ai / ha or more, 130 g ai / ha or more, 140 g ai / ha or more, 150 g ai / ha or more, 160 g ai / ha or more, 170 g ai / ha or more, 180 g ai / ha or more, 190 g ai / ha or more, 200 g ai / ha or more, 220 g ai / ha or more, 240 g ai / ha or more, 250 g ai / ha or more, 260 g ai / ha or more, 280 g ai / ha or more, 300 g ai / ha or more, 320 g ai / ha or more, 340 g ai / ha or more, 350 g ai / ha or more, 360 g ai / ha or more, 380 g ai / ha or more, 400 g ai / ha or more, 420 g ai / ha or more, 440 g ai / ha or more, 460 g ai / ha or more, 480 g ai / ha or more, 500 g ai / ha or more, 520 g ai / ha or more, 540 g ai / ha or more, 560 g ai / ha or more, 580 g ai / ha or more, 600 g ai / ha or more, 625 g ai / ha or more, 650 g ai / ha or more, 675 g ai / ha or more, 700 g ai / ha or more, 725 g ai / ha or more, 750 g ai / ha or more, 775 g ai / ha or more, 800 g ai / ha or more, 825 g ai / ha or more, 850 g ai / ha or more, 875 g ai / ha or more, 900 g ai / ha or more, 925 g ai / ha or more, 950 g ai / ha or more, 975 g ai / ha or more, 1000 g ai / ha or more, 1050 g ai / ha or more, 1100 g ai / ha or more, 1150 g ai / ha or more, 1200 g ai / ha or more, 1250 g ai / ha or more, 1300 g ai / ha or more, 1350 g ai / ha or more, 1400 g ai / ha or more, 1450 g ai / ha or more, 1500 g ai / ha or more, 1550 g ai / ha or more, 1600 g ai / ha or more, 1650 g ai / ha or more, 1675 g ai / ha or more, 1680 g ai / ha or more, or 1690 g ai / ha or more; in an amount of 1700 g ai / ha or less, such as 1690 g ai / ha or less, 1680 g ai / ha or less, 1675 g ai / ha or less, 1650 g ai / ha or less, 1600 g ai / ha or less, 1550 g ai / ha or less, 1500 g ai / ha or less, 1450 g ai / ha or less, 1400 g ai / ha or less, 1350 g ai / ha or less, 1300 g ai / ha or less, 1250 g ai / ha or less, 1200 g ai / ha or less, 1150 g ai / ha or less, 1100 g ai / ha or less, 1050 g ai / ha or less, 1000 g ai / ha or less, 975 g ai / ha or less, 950 g ai / ha or less, 925 g ai / ha or less, 900 g ai / ha or less, 875 g ai / ha or less, 850 g ai / ha or less, 825 g ai / ha or less, 800 g ai / ha or less, 775 g ai / ha or less, 750 g ai / ha or less, 725 g ai / ha or less, 700 g ai / ha or less, 675 g ai / ha or less, 650 g ai / ha or less, 625 g ai / ha or less, 600 g ai / ha or less, 580 g ai / ha or less, 560 g ai / ha or less, 540 g ai / ha or less, 520 g ai / ha or less, 500 g ai / ha or less, 480 g ai / ha or less, 460 g ai / ha or less, 440 g ai / ha or less, 420 g ai / ha or less, 400 g ai / ha or less, 380 g ai / ha or less, 360 g ai / ha or less, 350 g ai / ha or less, 340 g ai / ha or less, 320 g ai / ha or less, 300 g ai / ha or less, 280 g ai / ha or less, 260 g ai / ha or less, 250 g ai / ha or less, 240 g ai / ha or less, 220 g ai / ha or less, 200 g ai / ha or less, 190 g ai / ha or less, 180 g ai / ha or less, 170 g ai / ha or less, 160 g ai / ha or less, 150 g ai / ha or less, 140 g ai / ha or less, 130 g ai / ha or less, 120 g ai / ha or less, 110 g ai / ha or less, 100 g ai / ha or less, 95 g ai / ha or less, 90 g ai / ha or less, 85 g ai / ha or less, 80 g ai / ha or less, 75 g ai / ha or less, 70 g ai / ha or less, 65 g ai / ha or less, 60 g ai / ha or less, 55 g ai / ha or less, 50 g ai / ha or less, 45 g ai / ha or less, 40 g ai / ha or less, 35 g ai / ha or less, 30 g ai / ha or less, 25 g ai / ha or less, 20 g ai / ha or less, 15 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7 g ai / ha or less, 6 g ai / ha or less, 5 g ai / ha or less, 4.5 g ai / ha or less, 4 g ai / ha or less, 3.5 g ai / ha or less, 3 g ai / ha or less, 2.5 g ai / ha or less, 2 g ai / ha or less, 1.5 g ai / ha or less, 1 g ai / ha or less, 0.9 g ai / ha or less, 0.8 g ai / ha or less, 0.7 g ai / ha or less, 0.6 g ai / ha or less, 0.5 g ai / ha or less, 0.4 g ai / ha or less, or 0.3 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.25-1700 g ai / ha, 0.25-1250 g ai / ha, 0.5-150 g ai / ha, 2-90 g ai / ha, 2.5-200 g ai / ha, 3-900 g ai / ha, 5-260 g ai / ha, 5-750 g ai / ha, 5-1000 g ai / ha, 6-280 g ai / ha, 7-100 g ai / ha, 10-560 g ai / ha, 10-1600 g ai / ha, 20-500 g ai / ha, 25-140 g ai / ha, 30-480 g ai / ha, 40-400 g ai / ha, 50-320 g ai / ha, 60-300 g ai / ha, 70-1250 g ai / ha, 100-140 g ai / ha, 140-520 g ai / ha, or 250-1700 g ai / ha.A. Triazolopyrimidine Sulfonamide Herbicides

[0047] In some aspects, the composition contains a herbicidally effective amount of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof, and (b) florasulam, cloransulam, diclosulam, flumetsulam, metosulam, penoxsulam, or pyroxsulam, or agriculturally acceptable salts or esters thereof.Florasulam

[0048] Compositions and methods of the present disclosure can include florasulam or an agriculturally acceptable salt or ester thereof. Florasulam, shown below, is a triazolopyrimidine sulfonamide that provides broad-spectrum control of many broad-leaved weeds in cereals and maize. Florasulam, as well as methods of preparing florasulam, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Sixteenth Edition, 2012.

[0049] Florasulam can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, florasulam is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 0.25 g ai / ha or more, such as 0.3 g ai / ha or more, 0.4 g ai / ha or more, 0.5 g ai / ha or more, 0.6 g ai / ha or more, 0.7 g ai / ha or more, 0.8 g ai / ha or more, 0.9 g ai / ha or more, 1 g ai / ha or more, 1.1 g ai / ha or more, 1.25 g ai / ha or more, 1.5 g ai / ha or more, 1.75 g ai / ha or more, 2 g ai / ha or more, 2.25 g ai / ha or more, 2.5 g ai / ha or more, 2.75 g ai / ha or more, 3 g ai / ha or more, 3.25 g ai / ha or more, 3.5 g ai / ha or more, 3.75 g ai / ha or more, 4 g ai / ha or more, 4.25 g ai / ha or more, 4.5 g ai / ha or more, 4.75 g ai / ha or more, 5 g ai / ha or more, 5.25 g ai / ha or more, 5.5 g ai / ha or more, 5.75 g ai / ha or more, 6 g ai / ha or more, 6.25 g ai / ha or more, 6.5 g ai / ha or more, 6.75 g ai / ha or more, 7 g ai / ha or more, 7.25 g ai / ha or more, 7.5 g ai / ha or more, 8 g ai / ha or more, 8.5 g ai / ha or more, 9 g ai / ha or more, or 9.5 g ai / ha, or more; in an amount of 10 g ai / ha or less, such as 9.5 g ai / ha or less, 9 g ai / ha or less, 8.5 g ai / ha or less, 8 g ai / ha or less 7.5 g ai / ha or less, 7.25 g ai / ha or less, 7 g ai / ha or less, 6.75 g ai / ha or less, 6.5 g ai / ha or less, 6.25 g ai / ha or less, 6 g ai / ha or less, 5.75 g ai / ha or less, 5.5 g ai / ha or less, 5.25 g ai / ha or less, 5 g ai / ha or less, 4.75 g ai / ha or less, 4.5 g ai / ha or less, 4.25 g ai / ha or less, 4 g ai / ha or less, 3.75 g ai / ha or less, 3.5 g ai / ha or less, 3.25 g ai / ha or less, 3 g ai / ha or less, 2.75 g ai / ha or less, 2.5 g ai / ha or less, 2.25 g ai / ha or less, 2 g ai / ha or less, 1.75 g ai / ha or less, 1.5 g ai / ha or less, 1.25 g ai / ha or less, 1 g ai / ha or less, 0.9 g ai / ha or less, 0.8 g ai / ha or less, 0.7 g ai / ha or less, 0.6 g ai / ha or less, 0.5 g ai / ha or less, 0.4 g ai / ha or less, or 0.3 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.25-10 g ai / ha, 0.25-7 g ai / ha, 0.4-6.5 g ai / ha, 0.5-6 g ai / ha, 0.6-9 g ai / ha, 0.7-8.5 g ai / ha, 0.8-4.5 g ai / ha, 1-4 g ai / ha, 1.1-7.5 g ai / ha, 1.5-5.75 g ai / ha, 2-7.25 g ai / ha, 2.25-10 g ai / ha, 3-8.5 g ai / ha, or 3.5-9.5 g ai / ha.Cloransulam

[0050] Compositions and methods of the present disclosure can include cloransulam or an agriculturally acceptable salt or ester thereof. Cloransulam, as well as methods of preparing cloransulam, are known in the art. In some aspects, cloransulam can be provided as an agriculturally acceptable ester of cloransulam. Cloransulam-methyl, shown below, is a triazolopyrimidine sulfonamide that provides broad-spectrum control of many broadleaf weeds in soybeans and other broadleaf crops. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0051] Cloransulam can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, cloransulam is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2.18 g ai / ha or more, such as 2.25 g ai / ha or more, 2.5 g ai / ha or more, 2.75 g ai / ha or more, 3 g ai / ha or more, 3.25 g ai / ha or more, 3.5 g ai / ha or more, 3.75 g ai / ha or more, 4 g ai / ha or more, 4.5 g ai / ha or more, 5 g ai / ha or more, 6 g ai / ha or more, 7 g ai / ha or more, 8 g ai / ha or more, 9g ai / ha or more, 10 g ai / ha or more, 12 g ai / ha or more, 14 g ai / ha or more, 16 g ai / ha or more, 18 g ai / ha or more, 20 g ai / ha or more, 25 g ai / ha or more, 30 g ai / ha or more, 35 g ai / ha or more, 36 g ai / ha or more, 38 g ai / ha or more, 40 g ai / ha or more, 42 g ai / ha or more, 44 g ai / ha or more, 46 g ai / ha or more, 48 g ai / ha or more, 50 g ai / ha or more, 51 g ai / ha or more, 52 g ai / ha or more, 53 g ai / ha or more, 54 g ai / ha or more, 55 g ai / ha or more, 56 g ai / ha or more, 57 g ai / ha or more, 58 g ai / ha or more, or 59 g ai / ha or more; in an amount of 61 g ai / ha or less, such as 60 g ai / ha or less, 59 g ai / ha or less, 58 g ai / ha or less, 57 g ai / ha or less, 56 g ai / ha or less, 55 g ai / ha or less, 54 g ai / ha or less, 53 g ai / ha or less, 52 g ai / ha or less, 51 g ai / ha or less, 50 g ai / ha or less, 48 g ai / ha or less, 46 g ai / ha or less, 44 g ai / ha or less, 42 g ai / ha or less, 40 g ai / ha or less, 38 g ai / ha or less, 36 g ai / ha or less, 35 g ai / ha or less, 30 g ai / ha or less, 25 g ai / ha or less, 20 g ai / ha or less, 18 g ai / ha or less, 16 g ai / ha or less, 14 g ai / ha or less, 12 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7 g ai / ha or less, 6 g ai / ha or less, 5 g ai / ha or less, 4.5 g ai / ha or less, 4 g ai / ha or less, 3.75 g ai / ha or less, 3.5 g ai / ha or less, 3.25 g ai / ha or less, 3 g ai / ha or less, 2.75 g ai / ha or less, 2.5 g ai / ha or less, or 2.25 g ai / ha or less; or

[0052] in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2.18-61 g ai / ha, 2.5-60 g ai / ha, 2.75-44 g ai / ha, 3-59 g ai / ha, 3.25-60 g ai / ha, 3.5-40 g ai / ha, 3.75-18 g ai / ha, 3.75-50 g ai / ha, 4-60 g ai / ha, 4-52 g ai / ha, 4.25-30 g ai / ha, 4.25-55 g ai / ha, 4.5-51 g ai / ha, or 5-38 g ai / ha.Diclosulam

[0053] Compositions and methods of the present disclosure can include diclosulam or an agriculturally acceptable salt or ester thereof. Diclosulam, shown below, is a triazolopyrimidine sulfonamide that provides broad-spectrum control of many broadleaf weeds in soybeans and peanuts. Diclosulam, as well as methods of preparing diclosulam, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0054] Diclosulam can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, diclosulam is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2.18 g ai / ha or more, such as 2.25 g ai / ha or more, 2.5 g ai / ha or more, 2.75 g ai / ha or more, 3 g ai / ha or more, 3.25 g ai / ha or more, 3.5 g ai / ha or more, 4 g ai / ha or more, 4.5 g ai / ha or more, 5 g ai / ha or more, 6 g ai / ha or more, 7 g ai / ha or more, 8 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 12 g ai / ha or more, 14 g ai / ha or more, 16 g ai / ha or more, 18 g ai / ha or more, 20 g ai / ha or more, 22 g ai / ha or more, 24 g ai / ha or more, 26 g ai / ha or more, 27 g ai / ha or more, 28 g ai / ha or more, 29 g ai / ha or more, 30 g ai / ha or more, 31g ai / ha or more, 31.5 g ai / ha or more, 32 g ai / ha or more, 32.5 g ai / ha or more, 33 g ai / ha or more, 33.5 g ai / ha or more, 34 g ai / ha or more, 34.5 g ai / ha or more, or 34.75 g ai / ha or more; in an amount of 35 g ai / ha or less, such as 34.5 g ai / ha or less, 34 g ai / ha or less, 33.5 g ai / ha or less, 33 g ai / ha or less, 32.5 g ai / ha or less, 32 g ai / ha or less, 31.5 g ai / ha or less, 31 g ai / ha or less, 30 g ai / ha or less, 29 g ai / ha or less, 28 g ai / ha or less, 27 g ai / ha or less, 26 g ai / ha or less, 24 g ai / ha or less, 22 g ai / ha or less, 20 g ai / ha or less, 18 g ai / ha or less, 16 g ai / ha or less, 14 g ai / ha or less, 12 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7 g ai / ha or less, 6 g ai / ha or less, 5 g ai / ha or less, 4.5 g ai / ha or less, 4 g ai / ha or less, 3.5 g ai / ha or less, 2.75 g ai / ha or less, 2.5 g ai / ha or less, 2.25 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2.18-35 g ai / ha, 2.5-34 g ai / ha, 2.75-22 g ai / ha, 3-29 g ai / ha, 3.25-34 g ai / ha, 3.25-32 g ai / ha, 3.5-30 g ai / ha, 3.75-27 g ai / ha, 4-35 g ai / ha, 4-30 g ai / ha, 4.5-18 g ai / ha, 4.5-33.5 g ai / ha, 5-32 g ai / ha, or 6-33 g ai / ha.Flumetsulam

[0055] Compositions and methods of the present disclosure can include flumetsulam or an agriculturally acceptable salt or ester thereof. Flumetsulam, shown below, is a triazolopyrimidine sulfonamide that provides control of broadleaf weeds and greens in soybeans, field peas, and maize. Flumetsulam, as well as methods of preparing flumetsulam, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0056] Flumetsulam can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, flumetsulam is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2.18 g ai / ha or more, such as 2.5 g ai / ha or more, 2.75 g ai / ha or more, 3 g ai / ha or more, 3.5 g ai / ha or more, 4 g ai / ha or more, 4.5 g ai / ha or more, 5 g ai / ha or more, 7 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 15 g ai / ha or more, 20 g ai / ha or more, 25 g ai / ha or more, 30 g ai / ha or more, 35 g ai / ha or more, 36 g ai / ha or more, 37 g ai / ha or more, 38 g ai / ha or more, 39 g ai / ha or more, 40 g ai / ha or more, 41 g ai / ha or more, 42 g ai / ha or more, 44 g ai / ha or more, 46 g ai / ha or more, 48 g ai / ha or more, 50 g ai / ha or more, 52 g ai / ha or more, 54 g ai / ha or more, 56 g ai / ha or more, 58 g ai / ha or more, 60 g ai / ha or more, 62 g ai / ha or more, 64 g ai / ha or more, 66 g ai / ha or more, 68 g ai / ha or more, 70 g ai / ha or more, 72 g ai / ha or more, 74 g ai / ha or more, or 77 g ai / ha or more; in an amount of 78 g ai / ha or less, such as 77 g ai / ha or less, 75 g ai / ha or less, 74 g ai / ha or less, 72 g ai / ha or less, 70 g ai / ha or less, 68 g ai / ha or less, 66 g ai / ha or less, 64 g ai / ha or less, 62 g ai / ha or less, 60 g ai / ha or less, 58 g ai / ha or less, 56 g ai / ha or less, 54 g ai / ha or less, 52 g ai / ha or less, 50 g ai / ha or less, 48 g ai / ha or less, 46 g ai / ha or less, 44 g ai / ha or less, 42 g ai / ha or less, 41 g ai / ha or less, 40 g ai / ha or less, 39 g ai / ha or less, 38 g ai / ha or less, 37 g ai / ha or less, 36 g ai / ha or less, 35 g ai / ha or less, 30 g ai / ha or less, 25 g ai / ha or less, 20 g ai / ha or less, 15 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 7 g ai / ha or less, 5 g ai / ha or less, 4.5 g ai / ha or less, 4 g ai / ha or less, 3.5 g ai / ha or less, 3 g ai / ha or less, 2.75 g ai / ha or less, 2.5 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2.18-78 g ai / ha, 2.5-75 g ai / ha, 2.75-54 g ai / ha, 3-46 g ai / ha, 3-78 g ai / ha, 3.5-39 g ai / ha, 3.5-72 g ai / ha, 4-60 g ai / ha, 4-75 g ai / ha, 4.5-25 g ai / ha, 4.5-66 g ai / ha, 5-58 g ai / ha, or 9-62 g ai / ha.Penoxsulam

[0057] Compositions and methods of the present disclosure can include penoxsulam or an agriculturally acceptable salt or ester thereof. Penoxsulam, shown below, is a triazolopyrimidine sulfonamide that provides control of Echinochloa spp., as well as many broadleaf, sedge, and aquatic weeds in rice. Penoxsulam, as well as methods of preparing penoxsulam, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0058] Penoxsulam can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, penoxsulam is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2.5 g ai / ha or more, such as 2.75 g ai / ha or more, 3 g ai / ha or more, 3.5 g ai / ha or more, 4 g ai / ha or more, 4.5 g ai / ha or more, 5 g ai / ha or more, 6 g ai / ha or more, 7 g ai / ha or more, 8 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 12 g ai / ha or more, 14 g ai / ha or more, 16 g ai / ha or more, 18 g ai / ha or more, 20 g ai / ha or more, 22 g ai / ha or more, 24 g ai / ha or more, 26 g ai / ha or more, 28 g ai / ha or more, 30 g ai / ha or more, 32 g ai / ha or more, 34 g ai / ha or more, 36 g ai / ha or more, 38 g ai / ha or more, 40 g ai / ha or more, 41 g ai / ha or more, 42 g ai / ha or more, 43 g ai / ha or more, 44 g ai / ha or more, 45 g ai / ha or more, 46 g ai / ha or more, 47 g ai / ha or more, 48 g ai / ha or more, or 49 g ai / ha or more; in an amount of 50 g ai / ha or less, such as 49 g ai / ha or less, 48 g ai / ha or less, 47 g ai / ha or less, 46 g ai / ha or less, 45 g ai / ha or less, 44 g ai / ha or less, 43 g ai / ha or less, 42 g ai / ha or less, 41 g ai / ha or less, 40 g ai / ha or less, 38 g ai / ha or less, 36 g ai / ha or less, 34 g ai / ha or less, 32 g ai / ha or less, 30 g ai / ha or less, 28 g ai / ha or less, 26 g ai / ha or less, 24 g ai / ha or less, 22 g ai / ha or less, 20 g ai / ha or less, 18 g ai / ha or less, 16 g ai / ha or less, 14 g ai / ha or less, 12 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7 g ai / ha or less, 6 g ai / ha or less, 5 g ai / ha or less, 4.75 g ai / ha or less, 4.5 g ai / ha or less, 4.25 g ai / ha or less, 4 g ai / ha or less, 3.5 g ai / ha or less, 3 g ai / ha or less, or 2.75 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2.5-50 g ai / ha, 3-28 g ai / ha, 3.5-40 g ai / ha, 4-34 g ai / ha, 4.25-50 g ai / ha, 4.5-47 g ai / ha, 5-45 g ai / ha, 6-36 g ai / ha, 8-22 g ai / ha, or 10-49 g ai / ha.Pyroxsulam

[0059] Compositions and methods of the present disclosure can include pyroxsulam or an agriculturally acceptable salt or ester thereof. Pyroxsulam, shown below, is a triazolopyrimidine sulfonamide that provides broad spectrum post-emergence annual grass and broadleaf weeds control in cereals. Pyroxsulam, as well as methods of preparing pyroxsulam, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0060] Pyroxsulam can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pyroxsulam is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1.9 g ai / ha or more, such as 2 g ai / ha or more, 2.25 g ai / ha or more, 2.5 g ai / ha or more, 2.75 g ai / ha or more, 3 g ai / ha or more, 3.25 g ai / ha or more, 3.5 g ai / ha or more, 3.75 g ai / ha or more, 4 g ai / ha or more, 4.5 g ai / ha or more, 5 g ai / ha or more, 6 g ai / ha or more, 7 g ai / ha or more, 8 g ai / ha or more, 9 g ai / ha or more, 9.5 g ai / ha or more, 10 g ai / ha or more, 10.5 g ai / ha or more, 11 g ai / ha or more, 11.5 g ai / ha or more, 12 g ai / ha or more, 12.5 g ai / ha or more, 13 g ai / ha or more, 13.5 g ai / ha or more, 14 g ai / ha or more, 14.5 g ai / ha or more, 15 g ai / ha or more, 15.25 g ai / ha or more, 15.5 g ai / ha or more, 15.75 g ai / ha or more, 16 g ai / ha or more, 16.25 g ai / ha or more, 16.5 g ai / ha or more, 16.75 g ai / ha or more, 17 g ai / ha or more, 17.25 g ai / ha or more, 17.5 g ai / ha or more, 17.75 g ai / ha or more, 18 g ai / ha or more, 18.25 g ai / ha or more, or 18.5 g ai / ha or more; in an amount of 18.75 g ai / ha or less, such as 18.5 g ai / ha or less, 18.25 g ai / ha or less, 18 g ai / ha or less, 17.75 g ai / ha or less, 17.5 g ai / ha or less, 17.25 g ai / ha or less, 17 g ai / ha or less, 16.75 g ai / ha or less, 16.5 g ai / ha or less, 16.25 g ai / ha or less, 16 g ai / ha or less, 15.75 g ai / ha or less, 15.5 g ai / ha or less, 15.25 g ai / ha or less, 15 g ai / ha or less, 14.5 g ai / ha or less, 14 g ai / ha or less, 13.5 g ai / ha or less, 13 g ai / ha or less, 12.5 g ai / ha or less, 12 g ai / ha or less, 11.5 g ai / ha or less, 11 g ai / ha or less, 10.5 g ai / ha or less, 10 g ai / ha or less, 9.5 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7 g ai / ha or less, 6 g ai / ha or less, 5 g ai / ha or less, 4.5 g ai / ha or less, 4 g ai / ha or less, 3.5 g ai / ha or less, 3.25 g ai / ha or less, 3 g ai / ha or less, 2.75 g ai / ha or less, 2.5 g ai / ha or less, or 2.25 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1.9-18.75 g ai / ha, 2.25-18 g ai / ha, 2.5-14.5 g ai / ha, 2.75-12.5 g ai / ha, 2.75-18.5 g ai / ha, 3-13 g ai / ha, 3.25-10.5 g ai / ha, 3.5-16 g ai / ha, 4-15.25 g ai / ha, 5-18 g ai / ha, 6-17.75 g ai / ha, 8-16 g ai / ha, 9-18 g ai / ha, or 10-14.5 g ai / ha.B. Imidazolinone Herbicides

[0061] In some aspects, the composition contains a herbicidally effective amount of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof, and (b) imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, or agriculturally acceptable salts or esters thereof, or combinations thereof.Imazamethabenz

[0062] Compositions and methods of the present disclosure can include imazamethabenz or an agriculturally acceptable salt or ester thereof. Imazamethabenz, shown below, is a mixture of isomers and an imidazolinone that provides post-emergence control of Avena species, Alopecurus myosuroides, Apera spica-venti and dicotyledonous weeds in wheat, barley, rye and sunflowers. Imazamethabenz, as well as methods of preparing imazamethabenz, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0063] Imazamethabenz can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, imazamethabenz is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai / ha or more, such as 55 g ai / ha or more, 60 g ai / ha or more, 65 g ai / ha or more, 70 g ai / ha or more, 75 g ai / ha or more, 80 g ai / ha or more, 90 g ai / ha or more, 95 g ai / ha or more, 100 g ai / ha or more, 110 g ai / ha or more, 120 g ai / ha or more, 130 g ai / ha or more, 140 g ai / ha or more, 150 g ai / ha or more, 160 g ai / ha or more, 170 g ai / ha or more, 180 g ai / ha or more, 190 g ai / ha or more, 200 g ai / ha or more, 220 g ai / ha or more, 240 g ai / ha or more, 260 g ai / ha or more, 280 g ai / ha or more, 300 g ai / ha or more, 320 g ai / ha or more, 340 g ai / ha or more, 360 g ai / ha or more, 380 g ai / ha or more, 400 g ai / ha or more, 420 g ai / ha or more, 440 g ai / ha or more, 460 g ai / ha or more, 480 g ai / ha or more, 500 g ai / ha or more, 520 g ai / ha or more, 540 g ai / ha or more, 560 g ai / ha or more, 580 g ai / ha or more, 600 g ai / ha or more, 620 g ai / ha or more, 640 g ai / ha or more, 650 g ai / ha or more, 660 g ai / ha or more, 670 g ai / ha or more, 680 g ai / ha or more, or 690 g ai / ha or more; in an amount of 700 g ai / ha or less, such as 690 g ai / ha or less, 680 g ai / ha or less, 670 g ai / ha or less, 660 g ai / ha or less, 650 g ai / ha or less, 640 g ai / ha or less, 620 g ai / ha or less, 600 g ai / ha or less, 580 g ai / ha or less, 560 g ai / ha or less, 540 g ai / ha or less, 520 g ai / ha or less, 500 g ai / ha or less, 480 g ai / ha or less, 460 g ai / ha or less, 440 g ai / ha or less, 420 g ai / ha or less, 400 g ai / ha or less, 380 g ai / ha or less, 360 g ai / ha or less, 340 g ai / ha or less, 320 g ai / ha or less, 300 g ai / ha or less, 280 g ai / ha or less, 260 g ai / ha or less, 240 g ai / ha or less, 220 g ai / ha or less, 200 g ai / ha or less, 190 g ai / ha or less, 180 g ai / ha or less, 170 g ai / ha or less, 160 g ai / ha or less, 150 g ai / ha or less, 140 g ai / ha or less, 130 g ai / ha or less, 120 g ai / ha or less, 110 g ai / ha or less, 100 g ai / ha or less, 95 g ai / ha or less, 90 g ai / ha or less, 85 g ai / ha or less, 80 g ai / ha or less, 75 g ai / ha or less, 70 g ai / ha or less, 65 g ai / ha or less, 60 g ai / ha or less, or 55 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50-700 g ai / ha, 55-400 g ai / ha, 60-650 g ai / ha, 75-520 g ai / ha, 80-400 g ai / ha, 85-500 g ai / ha, 90-220 g ai / ha, 100-700 g ai / ha, 100-500 g ai / ha, 110-640 g ai / ha, 120-420 g ai / ha, 120-500 g ai / ha, 140-670 g ai / ha, or 150-580 g ai / ha.Imazamox

[0064] Compositions and methods of the present disclosure can include imazamox or an agriculturally acceptable salt or ester thereof. Imazamox, shown below, is an imidazolinone that provides pre- and post-emergence control of broadleaf and grass weeds, e.g., in rice, maize, rape, alfalfa, peas and beans. Imazamox, as well as methods of preparing imazamox, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0065] Imazamox can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, imazamox is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 5 g ai / ha or more, such as 6 g ai / ha or more, 7 g ai / ha or more, 8 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 11 g ai / ha or more, 12 g ai / ha or more, 13 g ai / ha or more, 14 g ai / ha or more, 15 g ai / ha or more, 16 g ai / ha or more, 17 g ai / ha or more, 18 g ai / ha or more, 19 g ai / ha or more, 20 g ai / ha or more, 21 g ai / ha or more, 22 g ai / ha or more, 23 g ai / ha or more, 24 g ai / ha or more, 25 g ai / ha or more, 26 g ai / ha or more, 27 g ai / ha or more, 28 g ai / ha or more, 29 g ai / ha or more, 30 g ai / ha or more, 32 g ai / ha or more, 34 g ai / ha or more, 36 g ai / ha or more, 38 g ai / ha or more, 40 g ai / ha or more, 44 g ai / ha or more, 46 g ai / ha or more, 48 g ai / ha or more, 50 g ai / ha or more, 52 g ai / ha or more, 54 g ai / ha or more, 56 g ai / ha or more, or 58 g ai / ha or more; in an amount of 60 g ai / ha or less, such as 58 g ai / ha or less, 56 g ai / ha or less, 54 g ai / ha or less, 52 g ai / ha or less, 50 g ai / ha or less, 48 g ai / ha or less, 46 g ai / ha or less, 44 g ai / ha or less, 42 g ai / ha or less, 40 g ai / ha or less, 38 g ai / ha or less, 36 g ai / ha or less, 34 g ai / ha or less, 32 g ai / ha or less, 30 g ai / ha or less, 29 g ai / ha or less, 28 g ai / ha or less, 27 g ai / ha or less, 26 g ai / ha or less, 25 g ai / ha or less, 24 g ai / ha or less, 23 g ai / ha or less, 22 g ai / ha or less, 21 g ai / ha or less, 20 g ai / ha or less, 19 g ai / ha or less, 18 g ai / ha or less, 17 g ai / ha or less, 16 g ai / ha or less, 15 g ai / ha or less, 14 g ai / ha or less, 13 g ai / ha or less, 12 g ai / ha or less, 11 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7 g ai / ha or less, or 6 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 5-60 g ai / ha, 5-52 g ai / ha, 6-46 g ai / ha, 6-54 g ai / ha, 7-38 g ai / ha, 7-50 g ai / ha, 8-48 g ai / ha, 9-45 g ai / ha, 10-40 g ai / ha, 10-58 g ai / ha, 11-36 g ai / ha, 12-54 g ai / ha, 13-60 g ai / ha, or 15-48 g ai / ha.Imazapic

[0066] Compositions and methods of the present disclosure can include imazapic or an agriculturally acceptable salt or ester thereof. Imazapic, shown below, is an imidazolinone that provides pre- and post-emergence control of a wide range of annual and perennial weeds in pasture, rangeland and non-cropland areas. Imazapic, as well as methods of preparing imazapic, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0067] Imazapic can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, imazapic is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 17.5 g ai / ha or more, such as 18 g ai / ha or more, 19 g ai / ha or more, 20 g ai / ha or more, 22 g ai / ha or more, 24 g ai / ha or more, 26 g ai / ha or more, 28 g ai / ha or more, 30 g ai / ha or more, 35 g ai / ha or more, 40 g ai / ha or more, 45 g ai / ha or more, 50 g ai / ha or more, 45 g ai / ha or more, 50 g ai / ha or more, 60 g ai / ha or more, 70 g ai / ha or more, 80 g ai / ha or more, 90 g ai / ha or more, 100 g ai / ha or more, 110 g ai / ha or more, 120 g ai / ha or more, 130 g ai / ha or more, 140 g ai / ha or more, 150 g ai / ha or more, 155 g ai / ha or more, 160 g ai / ha or more, 165 g ai / ha or more, 170 g ai / ha or more, 175 g ai / ha or more, 180 g ai / ha or more, 185 g ai / ha or more, 190 g ai / ha or more, 195 g ai / ha or more, 200 g ai / ha or more, 205 g ai / ha or more, 210 g ai / ha or more, or 215 g ai / ha or more; in an amount of 220 g ai / ha or less, such as 215 g ai / ha or less, 210 g ai / ha or less, 205 g ai / ha or less, 200 g ai / ha or less, 195 g ai / ha or less, 190 g ai / ha or less, 185 g ai / ha or less, 180 g ai / ha or less, 175 g ai / ha or less, 170 g ai / ha or less, 165 g ai / ha or less, 160 g ai / ha or less, 155 g ai / ha or less, 150 g ai / ha or less, 140 g ai / ha or less, 130 g ai / ha or less, 120 g ai / ha or less, 110 g ai / ha or less, 100 g ai / ha or less, 90 g ai / ha or less, 80 g ai / ha or less, 70 g ai / ha or less, 60 g ai / ha or less, 50 g ai / ha or less, 45 g ai / ha or less, 40 g ai / ha or less, 35 g ai / ha or less, 30 g ai / ha or less, 28 g ai / ha or less, 26 g ai / ha or less, 24 g ai / ha or less, 22 g ai / ha or less, 20 g ai / ha or less, 19 g ai / ha or less, or 18 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 17.5-220 g ai / ha, 17.5-210 g ai / ha, 18-200 g ai / ha, 19-120 g ai / ha, 20-210 g ai / ha, 20-170 g ai / ha, 22-190 g ai / ha, 24-175 g ai / ha, 26-210 g ai / ha, 26-160 g ai / ha, 30-190 g ai / ha, 30-140 g ai / ha, 35-220 g ai / ha, or 45-215 g ai / ha.Imazapyr

[0068] Compositions and methods of the present disclosure can include imazapyr or an agriculturally acceptable salt or ester thereof. Imazapyr, shown below, is an imidazolinone that provides pre- and post-emergence control of annual and perennial grasses, broadleaf weeds, brush and trees. Imazapyr, as well as methods of preparing imazapyr, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0069] Imazapyr can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, imazapyr is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 100 g ai / ha or more, such as 120 g ai / ha or more, 125 g ai / ha or more, 130 g ai / ha or more, 140 g ai / ha or more, 150 g ai / ha or more, 160 g ai / ha or more, 170 g ai / ha or more, 180 g ai / ha or more, 190 g ai / ha or more, 200 g ai / ha or more, 225 g ai / ha or more, 250 g ai / ha or more, 275 g ai / ha or more, 300 g ai / ha or more, 325 g ai / ha or more, 350 g ai / ha or more, 375 g ai / ha or more, 400 g ai / ha or more, 425 g ai / ha or more, 450 g ai / ha or more, 475 g ai / ha or more, 500 g ai / ha or more, 600 g ai / ha or more, 700 g ai / ha or more, 800 g ai / ha or more, 900 g ai / ha or more, 1000 g ai / ha or more, 1050 g ai / ha or more, 1100 g ai / ha or more, 1150 g ai / ha or more, 1200 g ai / ha or more, 1250 g ai / ha or more, 1300 g ai / ha or more, 1350 g ai / ha or more, 1400 g ai / ha or more, 1450 g ai / ha or more, 1500 g ai / ha or more, 1550 g ai / ha or more, 1600 g ai / ha or more, 1620 g ai / ha or more, 1640 g ai / ha or more, 1660 g ai / ha or more, or 1680 g ai / ha or more; in an amount of 1700 g ai / ha or less (e.g., 1680 g ai / ha or less, 1660 g ai / ha or less, 1640 g ai / ha or less, 1620 g ai / ha or less, 1600 g ai / ha or less, 1550 g ai / ha or less, 1500 g ai / ha or less, 1450 g ai / ha or less, 1400 g ai / ha or less, 1350 g ai / ha or less, 1300 g ai / ha or less, 1250 g ai / ha or less, 1200 g ai / ha or less, 1150 g ai / ha or less, 1100 g ai / ha or less, 1050 g ai / ha or less, 1000 g ai / ha or less, 900 g ai / ha or less, 800 g ai / ha or less, 700 g ai / ha or less, 600 g ai / ha or less, 500 g ai / ha or less, 475 g ai / ha or less, 450 g ai / ha or less, 425 g ai / ha or less, 400 g ai / ha or less, 375 g ai / ha or less, 350 g ai / ha or less, 325 g ai / ha or less, 300 g ai / ha or less, 275 g ai / ha or less, 250 g ai / ha or less, 225 g ai / ha or less, 200 g ai / ha or less, 190 g ai / ha or less, 180 g ai / ha or less, 170 g ai / ha or less, 160 g ai / ha or less, 150 g ai / ha or less, 140 g ai / ha or less, 130 g ai / ha or less, 125 g ai / ha or less, 120 g ai / ha or less, or 110 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 100-1700 g ai / ha, 125-850 g ai / ha, 130-700 g ai / ha, 150-1000 g ai / ha, 160-475 g ai / ha, 170-1660 g ai / ha, 180-1500 g ai / ha, 190-1050 g ai / ha, 200-700 g ai / ha, 250-1500 g ai / ha, 325-1200 g ai / ha, 450-1500 g ai / ha, 500-900 g ai / ha, or 110-1000 g ai / ha.Imazethapyr

[0070] Compositions and methods of the present disclosure can include imazethapyr or an agriculturally acceptable salt or ester thereof. Imazethapyr, shown below, is an imidazolinone that controls many major annual and perennial grass and broadleaf weeds in most major crops. Imazethapyr, as well as methods of preparing imazethapyr, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0071] Imazethapyr can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, imazethapyr is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 8.75 g ai / ha or more, such as 9 g ai / ha or more, 10 g ai / ha or more, 11 g ai / ha or more, 12 g ai / ha or more, 13 g ai / ha or more, 14 g ai / ha or more, 15 g ai / ha or more, 16 g ai / ha or more, 18 g ai / ha or more, 20 g ai / ha or more, 25 g ai / ha or more, 30 g ai / ha or more, 35 g ai / ha or more, 40 g ai / ha or more, 45 g ai / ha or more, 50 g ai / ha or more, 60 g ai / ha or more, 70 g ai / ha or more, 80 g ai / ha or more, 90 g ai / ha or more, 100 g ai / ha or more, 120 g ai / ha or more, 130 g ai / ha or more, 140 g ai / ha or more, 150 g ai / ha or more, 160 g ai / ha or more, 170 g ai / ha or more, 180 g ai / ha or more, 190 g ai / ha or more, 200 g ai / ha or more, 210 g ai / ha or more, 220 g ai / ha or more, 230 g ai / ha or more, 240 g ai / ha or more, 250 g ai / ha or more, 260 g ai / ha or more, 270 g ai / ha or more, 272 g ai / ha or more, 274 g ai / ha or more, 276 g ai / ha or more, or 278 g ai / ha or more; in an amount of 280 g ai / ha or less, such as 278 g ai / ha or less, 276 g ai / ha or less, 274 g ai / ha or less, 272 g ai / ha or less, 270 g ai / ha or less, 260 g ai / ha or less, 250 g ai / ha or less, 240 g ai / ha or less, 230 g ai / ha or less, 220 g ai / ha or less, 210 g ai / ha or less, 200 g ai / ha or less, 190 g ai / ha or less, 180 g ai / ha or less, 170 g ai / ha or less, 160 g ai / ha or less, 150 g ai / ha or less, 140 g ai / ha or less, 130 g ai / ha or less, 120 g ai / ha or less, 110 g ai / ha or less, 100 g ai / ha or less, 90 g ai / ha or less, 80 g ai / ha or less, 70 g ai / ha or less, 60 g ai / ha or less, 50 g ai / ha or less, 45 g ai / ha or less, 40 g ai / ha or less, 35 g ai / ha or less, 30 g ai / ha or less, 25 g ai / ha or less, 20 g ai / ha or less, 18 g ai / ha or less, 16 g ai / ha or less, 15 g ai / ha or less, 14 g ai / ha or less, 13 g ai / ha or less, 12 g ai / ha or less, 11 g ai / ha or less, 10 g ai / ha or less, or 9 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 8.75-280 g ai / ha, 8.75-170 g ai / ha, 9-220 g ai / ha, 10-260 g ai / ha, 10-150 g ai / ha, 11-220 g ai / ha, 12-200 g ai / ha, 13-274 g ai / ha, 15-230 g ai / ha, 16-160 g ai / ha, 18-280 g ai / ha, 20-210 g ai / ha, 20-190 g ai / ha, or 25-272 g ai / ha.C. Pyrimidinyl Oxybenzoate Herbicides

[0072] In some aspects, the composition contains a herbicidally effective amount of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof, and (b) bispyribac, pyribenzoxim, pyriftalid, pyriminobac, pyrimisulfan, pyrithiobac, or agriculturally acceptable salts or esters thereof, or combinations thereof.Bispyribac

[0073] Compositions and methods of the present disclosure can include bispyribac or an agriculturally acceptable salt or ester thereof. Bispyribac-sodium, shown below, is a pyrimidinyl oxybenzoate that provides control of grasses, sedges and broadleaf weeds, e.g., in direct-seeded and water-seeded rice and in turf. Bispyribac-sodium, as well as methods of preparing bispyribac-sodium, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0074] Bispyribac can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, bispyribac is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 5 g ai / ha or more, such as 7.5 g ai / ha or more, 10 g ai / ha or more, 12.5 g ai / ha or more, 15 g ai / ha or more, 17.5 g ai / ha or more, 20 g ai / ha or more, 22.5 g ai / ha or more, 25 g ai / ha or more, 27.5 g ai / ha or more, 30 g ai / ha or more, 32.5 g ai / ha or more, 35 g ai / ha or more, 37.5 g ai / ha or more, 40 g ai / ha or more, 42.5 g ai / ha or more, 45 g ai / ha or more, 47.5 g ai / ha or more, 50 g ai / ha or more, 52.5 g ai / ha or more, 55 g ai / ha or more, 57.5 g ai / ha or more, 60 g ai / ha or more, 62.5 g ai / ha or more, 65 g ai / ha or more, 67.5 g ai / ha or more, 70 g ai / ha or more, 72.5 g ai / ha or more, 75 g ai / ha or more, 77.5 g ai / ha or more, 80 g ai / ha or more, 82.5 g ai / ha or more, 85 g ai / ha or more, 87.5 g ai / ha or more, 90 g ai / ha or more, 92.5 g ai / ha or more, 95 g ai / ha or more, 97.5 g ai / ha or more; in an amount of 100 g ai / ha or less, such as 97.5 g ai / ha or less, 95 g ai / ha or less, 92.5 g ai / ha or less, 90 g ai / ha or less, 87.5 g ai / ha or less, 85 g ai / ha or less, 82.5 g ai / ha or less, 80 g ai / ha or less, 77.5 g ai / ha or less, 75 g ai / ha or less, 72.5 g ai / ha or less, 70 g ai / ha or less, 67.5 g ai / ha or less, 65 g ai / ha or less, 62.5 g ai / ha or less, 60 g ai / ha or less, 57.5 g ai / ha or less, 55 g ai / ha or less, 52.5 g ai / ha or less, 50 g ai / ha or less, 47.5 g ai / ha or less, 45 g ai / ha or less, 42.5 g ai / ha or less, 40 g ai / ha or less, 37.5 g ai / ha or less, 35 g ai / ha or less, 32.5 g ai / ha or less, 30 g ai / ha or less, 27.5 g ai / ha or less, 25 g ai / ha or less, 22.5 g ai / ha or less, 20 g ai / ha or less, 17.5 g ai / ha or less, 15 g ai / ha or less, 12.5 g ai / ha or less, 10 g ai / ha or less, or 7.5 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 5-100 g ai / ha, 5-90 g ai / ha, 7.5-45 g ai / ha, 10-55 g ai / ha, 15-90 g ai / ha, 20-50 g ai / ha, 22.5-90 g ai / ha, 25-52.5 g ai / ha, 25-80 g ai / ha, 25-65 g ai / ha, 27.5-60 g ai / ha, 27.5-47.5 g ai / ha, 30-85 g ai / ha, or 40-95 g ai / ha.Pyribenzoxim

[0075] Compositions and methods of the present disclosure can include pyribenzoxim or an agriculturally acceptable salt or ester thereof. Pyribenzoxim, shown below, is a pyrimidinyl oxybenzoate that provides post-emergence control of barnyard grass, blackgrass and Polygonum species in rice, wheat and zoysiagrass. Pyribenzoxim, as well as methods of preparing pyribenzoxim, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016.

[0076] Pyribenzoxim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pyribenzoxim is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 7.5 g ai / ha or more, such as 8 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 11 g ai / ha or more, 12 g ai / ha or more, 13 g ai / ha or more, 14 g ai / ha or more, 15 g ai / ha or more, 16 g ai / ha or more, 17 g ai / ha or more, 18 g ai / ha or more, 19 g ai / ha or more, 20 g ai / ha or more, 22 g ai / ha or more, 24 g ai / ha or more, 26 g ai / ha or more, 28 g ai / ha or more, 30 g ai / ha or more, 32 g ai / ha or more, 34 g ai / ha or more, 36 g ai / ha or more, 38 g ai / ha or more, 40 g ai / ha or more, 42 g ai / ha or more, 44 g ai / ha or more, 46 g ai / ha or more, 48 g ai / ha or more, 50 g ai / ha or more, 52 g ai / ha or more, 54 g ai / ha or more, 56 g ai / ha or more, 58 g ai / ha or more, 60 g ai / ha or more, 62 g ai / ha or more, 64 g ai / ha or more, 66 g ai / ha or more, 68 g ai / ha or more, or 69 g ai / ha or more; in an amount of 70 g ai / ha or less, such as 69 g ai / ha or less, 68 g ai / ha or less, 66 g ai / ha or less, 64 g ai / ha or less, 62 g ai / ha or less, 60 g ai / ha or less, 58 g ai / ha or less, 56 g ai / ha or less, 54 g ai / ha or less, 52 g ai / ha or less, 50 g ai / ha or less, 48 g ai / ha or less, 46 g ai / ha or less, 44 g ai / ha or less, 42 g ai / ha or less, 40 g ai / ha or less, 38 g ai / ha or less, 36 g ai / ha or less, 34 g ai / ha or less, 32 g ai / ha or less, 30 g ai / ha or less, 28 g ai / ha or less, 26 g ai / ha or less, 24 g ai / ha or less, 22 g ai / ha or less, 20 g ai / ha or less, 19 g ai / ha or less, 18 g ai / ha or less, 17 g ai / ha or less, 16 g ai / ha or less, 15 g ai / ha or less, 14 g ai / ha or less, 13 g ai / ha or less, 12 g ai / ha or less, 11 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, or 8 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 7.5-70 g ai / ha, 7.5-68 g ai / ha, 7.5-52 g ai / ha, 8-60 g ai / ha, 9-38 g ai / ha, 9-64 g ai / ha, 10-66 g ai / ha, 10-44 g ai / ha, 10-40 g ai / ha, 11-62 g ai / ha, 12-46 g ai / ha, 13-70 g ai / ha, 15-54 g ai / ha, or 20-64 g ai / ha.Pyriftalid

[0077] Compositions and methods of the present disclosure can include pyriftalid or an agriculturally acceptable salt or ester thereof. Pyriftalid, shown below, is a pyrimidinyl oxybenzoate that provides control of grass weeds in rice. Pyriftalid, as well as methods of preparing pyriftalid, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016.

[0078] Pyriftalid can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pyriftalid is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 20 g ai / ha or more, such as 22 g ai / ha or more, 25 g ai / ha or more, 30 g ai / ha or more, 35 g ai / ha or more, 40 g ai / ha or more, 45 g ai / ha or more, 50 g ai / ha or more, 55 g ai / ha or more, 60 g ai / ha or more, 70 g ai / ha or more, 80 g ai / ha or more, 90 g ai / ha or more, 100 g ai / ha or more, 120 g ai / ha or more, 130 g ai / ha or more, 140 g ai / ha or more, 150 g ai / ha or more, 160 g ai / ha or more, 170 g ai / ha or more, 180 g ai / ha or more, 190 g ai / ha or more, 200 g ai / ha or more, 210 g ai / ha or more, 220 g ai / ha or more, 230 g ai / ha or more, 240 g ai / ha or more, 250 g ai / ha or more, 260 g ai / ha or more, 270 g ai / ha or more, 280 g ai / ha or more, 290 g ai / ha or more, 300 g ai / ha or more, 310 g ai / ha or more, 320 g ai / ha or more, 330 g ai / ha or more, 340 g ai / ha or more, or 345 g ai / ha or more; in an amount of 350 g ai / ha or less, such as 345 g ai / ha or less, 340 g ai / ha or less, 330 g ai / ha or less, 320 g ai / ha or less, 310 g ai / ha or less, 300 g ai / ha or less, 290 g ai / ha or less, 280 g ai / ha or less, 270 g ai / ha or less, 260 g ai / ha or less, 250 g ai / ha or less, 240 g ai / ha or less, 230 g ai / ha or less, 220 g ai / ha or less, 210 g ai / ha or less, 200 g ai / ha or less, 190 g ai / ha or less, 180 g ai / ha or less, 170 g ai / ha or less, 160 g ai / ha or less, 150 g ai / ha or less, 140 g ai / ha or less, 130 g ai / ha or less, 120 g ai / ha or less, 110 g ai / ha or less, 100 g ai / ha or less, 90 g ai / ha or less, 80 g ai / ha or less, 70 g ai / ha or less, 60 g ai / ha or less, 55 g ai / ha or less, 50 g ai / ha or less, 45 g ai / ha or less, 40 g ai / ha or less, 35 g ai / ha or less, 30 g ai / ha or less, 25 g ai / ha or less, or 22 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 20-350 g ai / ha, 55-170 g ai / ha, 22-220 g ai / ha, 70-260 g ai / ha, 30-250 g ai / ha, 45-220 g ai / ha, 80-200 g ai / ha, 130-270 g ai / ha, 150-330 g ai / ha, 60-160 g ai / ha, 180-345 g ai / ha, 210-310 g ai / ha, 90-190 g ai / ha, or 22-340 g ai / ha.Pyriminobac

[0079] Compositions and methods of the present disclosure can include pyriminobac or an agriculturally acceptable salt or ester thereof. Pyriminobac, shown below, is a pyrimidinyl oxybenzoate that provides post-emergence control of Echinochloa spp., in paddy rice. Pyriminobac, as well as methods of preparing pyriminobac, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016.

[0080] Pyriminobac can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pyriminobac is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 20 g ai / ha or more, such as 22 g ai / ha or more, 25 g ai / ha or more, 30 g ai / ha or more, 35 g ai / ha or more, 40 g ai / ha or more, 45 g ai / ha or more, 50 g ai / ha or more, 60 g ai / ha or more, 70 g ai / ha or more, 80 g ai / ha or more, 90 g ai / ha or more, 100 g ai / ha or more, 120 g ai / ha or more, 130 g ai / ha or more, 140 g ai / ha or more, 150 g ai / ha or more, 160 g ai / ha or more, or 170 g ai / ha or more; in an amount of 175 g ai / ha or less, such as 170 g ai / ha or less, 160 g ai / ha or less, 150 g ai / ha or less, 140 g ai / ha or less, 130 g ai / ha or less, 120 g ai / ha or less, 110 g ai / ha or less, 100 g ai / ha or less, 90 g ai / ha or less, 80 g ai / ha or less, 70 g ai / ha or less, 60 g ai / ha or less, 50 g ai / ha or less, 45 g ai / ha or less, 40 g ai / ha or less, 35 g ai / ha or less, 30 g ai / ha or less, 25 g ai / ha or less, or 22 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 20-175 g ai / ha, 22-170 g ai / ha, 35-120 g ai / ha, 100-160 g ai / ha, 40-150 g ai / ha, 80-120 g ai / ha, 25-110 g ai / ha, 90-150 g ai / ha, 45-130 g ai / ha, 60-160 g ai / ha, 30-120 g ai / ha, 20-160 g ai / ha, or 22-100 g ai / ha.D. Sulfonylaminocarbonyl Triazolinone Herbicides

[0081] In some aspects, the composition contains a herbicidally effective amount of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof, and (b) flucarbazone, propoxycarbazone, thiencarbazone, or agriculturally acceptable salts or esters thereof, or combinations thereof.Flucarbazone

[0082] Compositions and methods of the present disclosure can include flucarbazone or an agriculturally acceptable salt or ester thereof. Flucarbazone, shown below, is a sulfonylaminocarbonyl triazolinone that provides post-emergence control of annual grass weeds and some perennial grass weeds and some broad-leaved weeds. Flucarbazone, as well as methods of preparing flucarbazone, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0083] Flucarbazone can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, flucarbazone is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 3.75 g ai / ha or more, such as 4 g ai / ha or more, 4.25 g ai / ha or more, 4.5 g ai / ha or more, 4.75 g ai / ha or more, 5 g ai / ha or more, 5.25 g ai / ha or more, 5.5 g ai / ha or more, 5.75 g ai / ha or more, 6 g ai / ha or more, 7 g ai / ha or more, 7.5 g ai / ha or more, 8 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 11 g ai / ha or more, 12 g ai / ha or more, 13 g ai / ha or more, 14 g ai / ha or more, 15 g ai / ha or more, 16 g ai / ha or more, 17 g ai / ha or more, 18 g ai / ha or more, 19 g ai / ha or more, 20 g ai / ha or more, 21 g ai / ha or more, 22 g ai / ha or more, 23 g ai / ha or more, 24 g ai / ha or more, 25 g ai / ha or more, 25.5 g ai / ha or more, 26 g ai / ha or more, 26.5 g ai / ha or more, 27 g ai / ha or more, 27.5 g ai / ha or more, 28 g ai / ha or more, 28.5 g ai / ha or more, 29 g ai / ha or more, 29.25 g ai / ha or more, 29.5 g ai / ha or more, or 29.75 g ai / ha or more; in an amount of 30 g ai / ha or less, such as 29.75 g ai / ha or less, 29.5 g ai / ha or less, 29.25 g ai / ha or less, 29 g ai / ha or less, 28.5 g ai / ha or less, 28 g ai / ha or less, 27.5 g ai / ha or less, 27 g ai / ha or less, 26.5 g ai / ha or less, 26 g ai / ha or less, 25 g ai / ha or less, 24 g ai / ha or less, 23 g ai / ha or less, 22 g ai / ha or less, 21 g ai / ha or less, 20 g ai / ha or less, 19 g ai / ha or less, 18 g ai / ha or less, 17 g ai / ha or less, 16 g ai / ha or less, 15 g ai / ha or less, 14 g ai / ha or less, 13 g ai / ha or less, 12 g ai / ha or less, 11 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7.5 g ai / ha or less, 7 g ai / ha or less, 6 g ai / ha or less, 5.75 g ai / ha or less, 5.5 g ai / ha or less, 5.25 g ai / ha or less, 5 g ai / ha or less, 4.75 g ai / ha or less, 4.5 g ai / ha or less, 4.25 g ai / ha or less, or 4 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 3.75-30 g ai / ha, 3.75-27 g ai / ha, 4-28 g ai / ha, 4-20 g ai / ha, 5-29.5 g ai / ha, 5-21 g ai / ha, 5.5-28 g ai / ha, 6-26 g ai / ha, 7-25 g ai / ha, 7.5-30 g ai / ha, 7.5-21 g ai / ha, 8-25 g ai / ha, 9-19 g ai / ha, or 10-28.5 g ai / ha.Propoxycarbazone

[0084] Compositions and methods of the present disclosure can include propoxycarbazone or an agriculturally acceptable salt or ester thereof. Propoxycarbazone, shown below, is a sulfonylaminocarbonyl triazolinone that provides post-emergence control of grass weeds and some broad-leaved weeds. Propoxycarbazone, as well as methods of preparing propoxycarbazone, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0085] Propoxycarbazone can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, propoxycarbazone is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 3.75 g ai / ha or more, such as 4 g ai / ha or more, 4.25 g ai / ha or more, 4.5 g ai / ha or more, 4.75 g ai / ha or more, 5 g ai / ha or more, 6 g ai / ha or more, 7 g ai / ha or more, 8 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 12 g ai / ha or more, 14 g ai / ha or more, 16 g ai / ha or more, 18 g ai / ha or more, 20 g ai / ha or more, 22 g ai / ha or more, 24 g ai / ha or more, 26 g ai / ha or more, 28 g ai / ha or more, 30 g ai / ha or more, 32 g ai / ha or more, 34 g ai / ha or more, 36 g ai / ha or more, 38 g ai / ha or more, 40 g ai / ha or more, 42 g ai / ha or more, 44 g ai / ha or more, 46 g ai / ha or more, 48 g ai / ha or more, 50 g ai / ha or more, 52 g ai / ha or more, 54 g ai / ha or more, 56 g ai / ha or more, 58 g ai / ha or more, 60 g ai / ha or more, 61 g ai / ha or more, 62 g ai / ha or more, 63 g ai / ha or more, 64 g ai / ha or more, 65 g ai / ha or more, 66 g ai / ha or more, 67 g ai / ha or more, 68 g ai / ha or more, or 69 g ai / ha or more; in an amount of 70 g ai / ha or less, such as 69 g ai / ha or less, 68 g ai / ha or less, 67 g ai / ha or less, 66 g ai / ha or less, 65 g ai / ha or less, 64 g ai / ha or less, 63 g ai / ha or less, 62 g ai / ha or less, 61 g ai / ha or less, 60 g ai / ha or less, 58 g ai / ha or less, 56 g ai / ha or less, 54 g ai / ha or less, 52 g ai / ha or less, 50 g ai / ha or less, 48 g ai / ha or less, 46 g ai / ha or less, 44 g ai / ha or less, 42 g ai / ha or less, 40 g ai / ha or less, 38 g ai / ha or less, 36 g ai / ha or less, 34 g ai / ha or less, 32 g ai / ha or less, 30 g ai / ha or less, 28 g ai / ha or less, 26 g ai / ha or less, 24 g ai / ha or less, 22 g ai / ha or less, 20 g ai / ha or less, 28 g ai / ha or less, 16 g ai / ha or less, 14 g ai / ha or less, 12 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7 g ai / ha or less, 6 g ai / ha or less, 5 g ai / ha or less, 4.75 g ai / ha or less, 4.5 g ai / ha or less, 4.25 g ai / ha or less, or 4 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 3.75-70 g ai / ha, 4-68 g ai / ha, 4.25-56 g ai / ha, 4.5-28 g ai / ha, 5-62 g ai / ha, 5-38 g ai / ha, 7-70 g ai / ha, 8-52 g ai / ha, 9-40 g ai / ha, 10-70 g ai / ha, 10-24 g ai / ha, 12-69 g ai / ha, 14-65 g ai / ha, or 20-58 g ai / ha.Thiencarbazone

[0086] Compositions and methods of the present disclosure can include thiencarbazone or an agriculturally acceptable salt or ester thereof. Thiencarbazone-methyl, shown below, is a sulfonylaminocarbonyl triazolinone that provides post-emergence control of grass weeds and some broad-leaved weeds. Thiencarbazone, as well as methods of preparing thiencarbazone, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0087] Thiencarbazone can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, thiencarbazone is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2.5 g ai / ha or more, such as 2.75 g ai / ha or more, 3 g ai / ha or more, 3.25 g ai / ha or more, 3.5 g ai / ha or more, 3.75 g ai / ha or more, 4 g ai / ha or more, 4.25 g ai / ha or more, 4.5 g ai / ha or more, 4.75 g ai / ha or more, 5 g ai / ha or more, 6 g ai / ha or more, 7 g ai / ha or more, 8 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 12 g ai / ha or more, 14 g ai / ha or more, 16 g ai / ha or more, 18 g ai / ha or more, 20 g ai / ha or more, 22 g ai / ha or more, 24 g ai / ha or more, 26 g ai / ha or more, 28 g ai / ha or more, 30 g ai / ha or more, 31 g ai / ha or more, 32 g ai / ha or more, 33 g ai / ha or more, 34 g ai / ha or more, 35 g ai / ha or more, 36 g ai / ha or more, 37 g ai / ha or more, 38 g ai / ha or more, 39 g ai / ha or more, 40 g ai / ha or more, 41 g ai / ha or more, 42 g ai / ha or more, 43 g ai / ha or more, or 44 g ai / ha or more; in an amount of 45 g ai / ha or less, such as 44 g ai / ha or less, 43 g ai / ha or less, 42 g ai / ha or less, 41 g ai / ha or less, 40 g ai / ha or less, 39 g ai / ha or less, 38 g ai / ha or less, 37 g ai / ha or less, 36 g ai / ha or less, 35 g ai / ha or less, 34 g ai / ha or less, 33 g ai / ha or less, 32 g ai / ha or less, 31 g ai / ha or less, 30 g ai / ha or less, 28 g ai / ha or less, 26 g ai / ha or less, 24 g ai / ha or less, 22 g ai / ha or less, 20 g ai / ha or less, 18 g ai / ha or less, 16 g ai / ha or less, 14 g ai / ha or less, 12 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7 g ai / ha or less, 6 g ai / ha or less, 5 g ai / ha or less, 4.75 g ai / ha or less, 4.5 g ai / ha or less, 4.25 g ai / ha or less, 4 g ai / ha or less, 3.75 g ai / ha or less, 3.5 g ai / ha or less, 3.25 g ai / ha or less, 3 g ai / ha or less, or 2.75 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2.5-45 g ai / ha, 2.5-41 g ai / ha, 2.75-39 g ai / ha, 2.75-37 g ai / ha, 3-40 g ai / ha, 3-33 g ai / ha, 3.25-28 g ai / ha, 3.5-45 g ai / ha, 3.75-45 g ai / ha, 4-39 g ai / ha, 4.5-31 g ai / ha, 5-45 g ai / ha, 5-37 g ai / ha, or 8-36 g ai / ha.E. Sulfonylurea Herbicides

[0088] In some aspects, the composition contains a herbicidally effective amount of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof, and (b) amidosulfuron, azimsulfuron, bensulfuron, chlorimuron, chlorsulfuron, cinosulfuron, cyclosulfamuron, ethametsulfuron, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron, foramsulfuron, halosulfuron, imazosulfuron, iodosulfuron, iofensulfuron, mesosulfuron, metazosulfuron, metsulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, primisulfuron, propyrisulfuron, prosulfuron, pyrazosulfuron, rimsulfuron, sulfometuron, sulfosulfuron, triasulfuron, tribenuron, thifensulfuron, trifloxysulfuron, triflusulfuron, tritosulfuron, or agriculturally acceptable salts or esters thereof, or combinations thereof.Amidosulfuron

[0089] Compositions and methods of the present disclosure can include amidosulfuron or an agriculturally acceptable salt or ester thereof. Amidosulfuron, shown below, is a sulfonylurea that provides post-emergence control of a wide range of broadleaf weeds, e.g., cleavers, in winter wheat, durum wheat, barley, rye, triticale and oats. Amidosulfuron, as well as methods of preparing amidosulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0090] Amidosulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, amidosulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 3.75 g ai / ha or more, such as 4 g ai / ha or more, 4.25 g ai / ha or more, 4.5 g ai / ha or more, 4.75 g ai / ha or more, 5 g ai / ha or more, 6 g ai / ha or more, 7 g ai / ha or more, 8 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 11 g ai / ha or more, 12 g ai / ha or more, 13 g ai / ha or more, 14 g ai / ha or more, 15 g ai / ha or more, 16 g ai / ha or more, 17 g ai / ha or more, 18 g ai / ha or more, 19 g ai / ha or more, 20 g ai / ha or more, 22 g ai / ha or more, 24 g ai / ha or more, 26 g ai / ha or more, 28 g ai / ha or more, 30 g ai / ha or more, 32 g ai / ha or more, 34 g ai / ha or more, 36 g ai / ha or more, 38 g ai / ha or more, 40 g ai / ha or more, 42 g ai / ha or more, 44 g ai / ha or more, 46 g ai / ha or more, 48 g ai / ha or more, 50 g ai / ha or more, 51 g ai / ha or more, 52 g ai / ha or more, 53 g ai / ha or more, 54 g ai / ha or more, 55 g ai / ha or more, 56 g ai / ha or more, 57 g ai / ha or more, 58 g ai / ha or more, or 59 g ai / ha or more; in an amount of 60 g ai / ha or less, such as 59 g ai / ha or less, 58 g ai / ha or less, 57 g ai / ha or less, 56 g ai / ha or less, 55 g ai / ha or less, 54 g ai / ha or less, 53 g ai / ha or less, 52 g ai / ha or less, 51 g ai / ha or less, 50 g ai / ha or less, 48 g ai / ha or less, 46 g ai / ha or less, 44 g ai / ha or less, 42 g ai / ha or less, 40 g ai / ha or less, 38 g ai / ha or less, 36 g ai / ha or less, 34 g ai / ha or less, 32 g ai / ha or less, 30 g ai / ha or less, 28 g ai / ha or less, 26 g ai / ha or less, 24 g ai / ha or less, 22 g ai / ha or less, 20 g ai / ha or less, 19 g ai / ha or less, 18 g ai / ha or less, 17 g ai / ha or less, 16 g ai / ha or less, 15 g ai / ha or less, 14 g ai / ha or less, 13 g ai / ha or less, 12 g ai / ha or less, 11 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7 g ai / ha or less, 6 g ai / ha or less, 5 g ai / ha or less, 4.75 g ai / ha or less, 4.5 g ai / ha or less, or 4.25 g ai / ha or less, or 4 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 3.75-60 g ai / ha, 4-58 g ai / ha, 4.5-51 g ai / ha, 5-57 g ai / ha, 5-30 g ai / ha, 6-42 g ai / ha, 8-50 g ai / ha, 9-32 g ai / ha, 10-53 g ai / ha, 12-30 g ai / ha, or 13-40 g ai / ha.Azimsulfuron

[0091] Compositions and methods of the present disclosure can include azimsulfuron or an agriculturally acceptable salt or ester thereof. Azimsulfuron, shown below, is a sulfonylurea that provides e.g., post-emergence control of annual and perennial broadleaf and sedge weeds in rice. Azimsulfuron, as well as methods of preparing azimsulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0092] Azimsulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, azimsulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 3.125 g ai / ha or more, such as 3.25 g ai / ha or more, 3.5 g ai / ha or more, 3.75 g ai / ha or more, 4 g ai / ha or more, 4.25 g ai / ha or more, 4.5 g ai / ha or more, 4.75 g ai / ha or more, 5 g ai / ha or more, 5.5 g ai / ha or more, 6 g ai / ha or more, 6.5 g ai / ha or more, 7 g ai / ha or more, 7.5 g ai / ha or more, 8 g ai / ha or more, 8.5 g ai / ha or more, 9 g ai / ha or more, 9.5 g ai / ha or more, 10 g ai / ha or more, 11 g ai / ha or more, 12 g ai / ha or more, 13 g ai / ha or more, 14 g ai / ha or more, 15 g ai / ha or more, 16 g ai / ha or more, 17 g ai / ha or more, 18 g ai / ha or more, 19 g ai / ha or more, 20 g ai / ha or more, 20.5 g ai / ha or more, 21 g ai / ha or more, 21.5 g ai / ha or more, 22 g ai / ha or more, 22.5 g ai / ha or more, 22.75 g ai / ha or more, 23 g ai / ha or more, 23.25 g ai / ha or more, 23.5 g ai / ha or more, 23.75 g ai / ha or more, 24 g ai / ha or more, 24.25 g ai / ha or more, 24.5 g ai / ha or more, or 24.75 g ai / ha or more; in an amount of 25 g ai / ha or less, such as 24.75 g ai / ha or less, 24.5 g ai / ha or less, 24.25 g ai / ha or less, 24 g ai / ha or less, 23.75 g ai / ha or less, 23.5 g ai / ha or less, 23.25 g ai / ha or less, 23 g ai / ha or less, 22.75 g ai / ha or less, 22.5 g ai / ha or less, 22 g ai / ha or less, 21.5 g ai / ha or less, 21 g ai / ha or less, 20.5 g ai / ha or less, 20 g ai / ha or less, 19 g ai / ha or less, 18 g ai / ha or less, 17 g ai / ha or less, 16 g ai / ha or less, 15 g ai / ha or less, 14 g ai / ha or less, 13 g ai / ha or less, 12 g ai / ha or less, 11 g ai / ha or less, 10 g ai / ha or less, 9.5 g ai / ha or less, 9 g ai / ha or less, 8.5 g ai / ha or less, 8 g ai / ha or less, 7.5 g ai / ha or less, 7 g ai / ha or less, 6.5 g ai / ha or less, 6 g ai / ha or less, 5.5 g ai / ha or less, 5 g ai / ha or less, 4.75 g ai / ha or less, 4.5 g ai / ha or less, 4.25 g ai / ha or less, 4 g ai / ha or less, 3.75 g ai / ha or less, 3.5 g ai / ha or less, or 3.25 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 3.125-25 g ai / ha, 3.125-23.5 g ai / ha, 3.125-19 g ai / ha, 3.25-22 g ai / ha, 3.5-24.5 g ai / ha, 3.5-19 g ai / ha, 3.75-22 g ai / ha, 4-25 g ai / ha, 4-23.25 g ai / ha, 4.25-20 g ai / ha, 4.5-18 g ai / ha, 4.75-22.75 g ai / ha, or 5-24 g ai / ha.Bensulfuron

[0093] Compositions and methods of the present disclosure can include bensulfuron or an agriculturally acceptable salt or ester thereof. Bensulfuron-methyl, shown below, is a sulfonylurea that provides e.g., pre- and post-emergence control of annual and perennial broadleaf weeds and sedges in rice. Bensulfuron, as well as methods of preparing bensulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0094] Bensulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, bensulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 8.75 g ai / ha or more, such as 9 g ai / ha or more, 10 g ai / ha or more, 11 g ai / ha or more, 12 g ai / ha or more, 13 g ai / ha or more, 14 g ai / ha or more, 15 g ai / ha or more, 16 g ai / ha or more, 17 g ai / ha or more, 18 g ai / ha or more, 19 g ai / ha or more, 20 g ai / ha or more, 22 g ai / ha or more, 24 g ai / ha or more, 26 g ai / ha or more, 28 g ai / ha or more, 30 g ai / ha or more, 32 g ai / ha or more, 34 g ai / ha or more, 36 g ai / ha or more, 38 g ai / ha or more, 40 g ai / ha or more, 42 g ai / ha or more, 44 g ai / ha or more, 46 g ai / ha or more, 48 g ai / ha or more, 50 g ai / ha or more, 52 g ai / ha or more, 54 g ai / ha or more, 56 g ai / ha or more, 58 g ai / ha or more, 60 g ai / ha or more, 62 g ai / ha or more, 64 g ai / ha or more, 66 g ai / ha or more, 68 g ai / ha or more, or 69 g ai / ha or more; in an amount of 70 g ai / ha or less, such as 69 g ai / ha or less, 68 g ai / ha or less, 66 g ai / ha or less, 64 g ai / ha or less, 62 g ai / ha or less, 60 g ai / ha or less, 58 g ai / ha or less, 56 g ai / ha or less, 54 g ai / ha or less, 52 g ai / ha or less, 50 g ai / ha or less, 48 g ai / ha or less, 46 g ai / ha or less, 44 g ai / ha or less, 42 g ai / ha or less, 40 g ai / ha or less, 38 g ai / ha or less, 36 g ai / ha or less, 34 g ai / ha or less, 32 g ai / ha or less, 30 g ai / ha or less, 28 g ai / ha or less, 26 g ai / ha or less, 24 g ai / ha or less, 22 g ai / ha or less, 20 g ai / ha or less, 19 g ai / ha or less, 18 g ai / ha or less, 17 g ai / ha or less, 16 g ai / ha or less, 15 g ai / ha or less, 14 g ai / ha or less, 13 g ai / ha or less, 12 g ai / ha or less, 11 g ai / ha or less, 10 g ai / ha or less, or 9 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 8.75-70 g ai / ha, 9-60 g ai / ha, 10-65 g ai / ha, 10-40 g ai / ha, 10-28 g ai / ha, 11-68 g ai / ha, 11-54 g ai / ha, 12-60 g ai / ha, 12-42 g ai / ha, 13-69 g ai / ha, 14-56 g ai / ha, 15-40 g ai / ha, 20-46 g ai / ha, or 20-69 g ai / ha.Chlorsulfuron

[0095] Compositions and methods of the present disclosure can include chlorsulfuron or an agriculturally acceptable salt or ester thereof. Chlorsulfuron, shown below, is a sulfonylurea that provides control of e.g., broadleaf weeds and annual grasses in wheat, barley, oats, rye, triticale, flax and on non-crop land. Chlorsulfuron, as well as methods of preparing chlorsulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0096] Chlorsulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, chlorsulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1.1 g ai / ha or more, such as 1.25 g ai / ha or more, ., 1.5 g ai / ha or more, 1.75 g ai / ha or more, 2 g ai / ha or more, 2.25 g ai / ha or more, 2.5 g ai / ha or more, 2.75 g ai / ha or more, 3 g ai / ha or more, 3.25 g ai / ha or more, 3.5 g ai / ha or more, 3.75 g ai / ha or more, 4 g ai / ha or more, 4.25 g ai / ha or more, 4.5 g ai / ha or more, 4.75 g ai / ha or more, 5 g ai / ha or more, 6 g ai / ha or more, 7 g ai / ha or more, 8 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 11 g ai / ha or more, 12 g ai / ha or more, 13 g ai / ha or more, 14 g ai / ha or more, 15 g ai / ha or more, 16 g ai / ha or more, 17 g ai / ha or more, 18 g ai / ha or more, 19 g ai / ha or more, 20 g ai / ha or more, 22 g ai / ha or more, 24 g ai / ha or more, 26 g ai / ha or more, 28 g ai / ha or more, 30 g ai / ha or more, 32 g ai / ha or more, 34 g ai / ha or more, 36 g ai / ha or more, 38 g ai / ha or more, 40 g ai / ha or more, 42 g ai / ha or more, 44 g ai / ha or more, 46 g ai / ha or more, 47 g ai / ha or more, 48 g ai / ha or more, 49 g ai / ha or more, 50 g ai / ha or more, 51 g ai / ha or more, or 51.5 g ai / ha or more; in an amount of 52 g ai / ha or less, such as 51.5 g ai / ha or less, 51 g ai / ha or less, 50 g ai / ha or less, 49 g ai / ha or less, 48 g ai / ha or less, 47 g ai / ha or less, 46 g ai / ha or less, 44 g ai / ha or less, 42 g ai / ha or less, 40 g ai / ha or less, 38 g ai / ha or less, 36 g ai / ha or less, 34 g ai / ha or less, 32 g ai / ha or less, 30 g ai / ha or less, 28 g ai / ha or less, 26 g ai / ha or less, 24 g ai / ha or less, 22 g ai / ha or less, 20 g ai / ha or less, 19 g ai / ha or less, 18 g ai / ha or less, 17 g ai / ha or less, 16 g ai / ha or less, 15 g ai / ha or less, 14 g ai / ha or less, 13 g ai / ha or less, 12 g ai / ha or less, 11 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7 g ai / ha or less, 6 g ai / ha or less, 5 g ai / ha or less, 4.75 g ai / ha or less, 4.5 g ai / ha or less, or 4.25 g ai / ha or less, ai / ha or less, 4 g ai / ha or less, 3.75 g ai / ha or less, 3.5 g ai / ha or less, 3.25 g ai / ha or less, 3 g ai / ha or less, 2.75 g ai / ha or less, 2.5 g ai / ha or less, 2.25 g ai / ha or less, 2 g ai / ha or less, 1.75 g ai / ha or less, 1.5 g ai / ha or less, or 1.25 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1.1-52 g ai / ha,1.25-51.5 g ai / ha, 1.5-30 g ai / ha, 1.75-47 g ai / ha, 2-26 g ai / ha, 3-50 g ai / ha, 4-38 g ai / ha, 4.5-42 g ai / ha, 5-51 g ai / ha, 7-49 g ai / ha, 9-32 g ai / ha, 10-45 g ai / ha, 12-52 g ai / ha, or 15-48 g ai / ha.Ethoxysulfuron

[0097] Compositions and methods of the present disclosure can include ethoxysulfuron or an agriculturally acceptable salt or ester thereof. Ethoxysulfuron, shown below, is a sulfonylurea that provides e.g., control of broadleaf and sedge weeds in cereals, rice and sugar cane. Ethoxysulfuron, as well as methods of preparing ethoxysulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0098] Ethoxysulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, ethoxysulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 5 g ai / ha or more, such as 6 g ai / ha or more, 7 g ai / ha or more, 8 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 11 g ai / ha or more, 12 g ai / ha or more, 13 g ai / ha or more, 14 g ai / ha or more, 15 g ai / ha or more, 16 g ai / ha or more, 17 g ai / ha or more, 18 g ai / ha or more, 19 g ai / ha or more, 20 g ai / ha or more, 22 g ai / ha or more, 24 g ai / ha or more, 26 g ai / ha or more, 28 g ai / ha or more, 30 g ai / ha or more, 32 g ai / ha or more, 34 g ai / ha or more, 36 g ai / ha or more, 38 g ai / ha or more, 40 g ai / ha or more, 45 g ai / ha or more, 50 g ai / ha or more, 55 g ai / ha or more, 60 g ai / ha or more, 65 g ai / ha or more, 70 g ai / ha or more, 75 g ai / ha or more, 80 g ai / ha or more, 85 g ai / ha or more, 90 g ai / ha or more, 95 g ai / ha or more, 100 g ai / ha or more, 101 g ai / ha or more, 102 g ai / ha or more, 103 g ai / ha or more, 104 g ai / ha or more, 105 g ai / ha or more, 106 g ai / ha or more, 107 g ai / ha or more, 108 g ai / ha or more, 109 g ai / ha or more, 110 g ai / ha or more, 111 g ai / ha or more, 112 g ai / ha or more, 113 g ai / ha or more, 114 g ai / ha or more, 115 g ai / ha or more, 116 g ai / ha or more, 117 g ai / ha or more, 118 g ai / ha or more, or 119 g ai / ha or more; in an amount of 120 g ai / ha or less, such as 119 g ai / ha or less, 118 g ai / ha or less, 117 g ai / ha or less, 116 g ai / ha or less, 115 g ai / ha or less, 114 g ai / ha or less, 113g ai / ha or less, 112 g ai / ha or less, 111 g ai / ha or less, 110 g ai / ha or less, 109 g ai / ha or less, 108 g ai / ha or less, 107 g ai / ha or less, 106 g ai / ha or less, 105 g ai / ha or less, 104 g ai / ha or less, 103 g ai / ha or less, 102 g ai / ha or less, 101 g ai / ha or less, 100 g ai / ha or less, 95 g ai / ha or less, 90 g ai / ha or less, 85 g ai / ha or less, 80 g ai / ha or less, 75 g ai / ha or less, 70 g ai / ha or less, 65 g ai / ha or less, 60 g ai / ha or less, 55 g ai / ha or less, 50 g ai / ha or less, 45 g ai / ha or less, 40 g ai / ha or less, 38 g ai / ha or less, 36 g ai / ha or less, 34 g ai / ha or less, 32 g ai / ha or less, 30 g ai / ha or less, 28 g ai / ha or less, 26 g ai / ha or less, 24 g ai / ha or less, 22 g ai / ha or less, 20 g ai / ha or less, 19 g ai / ha or less, 18 g ai / ha or less, 17 g ai / ha or less, 16 g ai / ha or less, 15 g ai / ha or less, 14 g ai / ha or less, 13 g ai / ha or less, 12 g ai / ha or less, 11 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7 g ai / ha or less, or 6 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 5-120 g ai / ha, 5-90 g ai / ha, 5-75 g ai / ha, 6-114 g ai / ha, 8-108 g ai / ha, 9-113 g ai / ha, 10-80 g ai / ha, 10-55 g ai / ha, 12-112 g ai / ha, 13-85 g ai / ha, 15-106 g ai / ha, 20-100 g ai / ha, 24-105 g ai / ha, or 28-115 g ai / ha.Flupyrsulfuron

[0099] Compositions and methods of the present disclosure can include flupyrsulfuron or an agriculturally acceptable salt or ester thereof. Flupyrsulfuron-methyl sodium, shown below, is a sulfonylurea that is used, e.g., for post-emergent control of grass and broadleaf weeds in cereals. Flupyrsulfuron, as well as methods of preparing flupyrsulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0100] Flupyrsulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, flupyrsulfuron thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2.5 g ai / ha or more, such as 2.6 g ai / ha or more, 2.7 g ai / ha or more, 2.8 g ai / ha or more, 2.9 g ai / ha or more, 3.0 g ai / ha or more, 3.2 g ai / ha or more, 3.4 g ai / ha or more, 3.6 g ai / ha or more, 3.8 g ai / ha or more, 4 g ai / ha or more, 4.2 g ai / ha or more, 4.4 g ai / ha or more, 4.6 g ai / ha or more, 4.8 g ai / ha or more, 5 g ai / ha or more, 5.2 g ai / ha or more, 5.4 g ai / ha or more, 5.6 g ai / ha or more, 5.8 g ai / ha or more, 6 g ai / ha or more, 6.2 g ai / ha or more, 6.4 g ai / ha or more, 6.6 g ai / ha or more, 6.8 g ai / ha or more, 7 g ai / ha or more, 7.2 ai / ha or more, 7.4 g ai / ha or more, 7.6 g ai / ha or more, 8 g ai / ha or more, 8.2 g ai / ha or more, 8.4 ai / ha or more, 8.6 g ai / ha or more, 8.8 g ai / ha or more, 9 g ai / ha or more, 9.1 g ai / ha or more, 9.2 g ai / ha or more,9.3 g ai / ha or more, 9.4 g ai / ha or more, 9.5 g ai / ha or more, 9.6 g ai / ha or more, 9.7 g ai / ha or more, 9.8 g ai / ha or more, or 9.9 g ai / ha or more; in an amount of 10 g ai / ha or less, such as 9.9 g ai / ha or less, 9.8 g ai / ha or less, 9.7 g ai / ha or less, 9.6 g ai / ha or less, 9.5 g ai / ha or less, 9.4 g ai / ha or less, 9.3 g ai / ha or less, 9.2 g ai / ha or less, 9.1 g ai / ha or less, 9 g ai / ha or less, 8.8 g ai / ha or less, 8.6 g ai / ha or less, 8.4 g ai / ha or less, 8.2 g ai / ha or less, 8 g ai / ha or less, 7.8 g ai / ha or less, 7.6 g ai / ha or less, 7.4 g ai / ha or less, 7.2 g ai / ha or less, 7 g ai / ha or less, 6.8 g ai / ha or less, 6.6 g ai / ha or less, 6.4 g ai / ha or less, 6.2 g ai / ha or less, 6 g ai / ha or less, 5.8 g ai / ha or less, 5.6 g ai / ha or less, 5.4 g ai / ha or less, 5.2 g ai / ha or less, 5 g ai / ha or less, 4.8 g ai / ha or less, 4.6 g ai / ha or less, 4.4 g ai / ha or less, 4.2 g ai / ha or less, 4 g ai / ha or less, 3.8 g ai / ha or less, 3.6 g ai / ha or less, 3.4 g ai / ha or less, 3.2 g ai / ha or less, 3 g ai / ha or less, 2.9 g ai / ha or less, 2.8 g ai / ha or less, 2.7 g ai / ha or less, or 2.6 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2.5-10 g ai / ha, 2.5-9.4 g ai / ha, 2.6-9 g ai / ha, 2.7-10 g ai / ha, 2.8-9.4 g ai / ha, 3-8.8 g ai / ha, 3.2-7.2 g ai / ha, 3.4-8.6 g ai / ha, 3.6-10 g ai / ha, 3.8-9.5 g ai / ha, 4-8.8 g ai / ha, 4.4-7 g ai / ha, 4.6-6.8 g ai / ha, or 5-9.5 g ai / ha.Foramsulfuron

[0101] Compositions and methods of the present disclosure can include foramsulfuron or an agriculturally acceptable salt or ester thereof. Foramsulfuron, shown below, is a sulfonylurea that provides e.g., post-emergence control of grass and broadleaf weeds in maize. Foramsulfuron, as well as methods of preparing foramsulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0102] Foramsulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, foramsulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 22.5 g ai / ha or more, such as 23 g ai / ha or more, 24 g ai / ha or more, 25 g ai / ha or more, 26 g ai / ha or more, 28 g ai / ha or more, 30 g ai / ha or more, 32 g ai / ha or more, 34 g ai / ha or more, 35 g ai / ha or more, 36 g ai / ha or more, 38 g ai / ha or more, 40 g ai / ha or more, 42 g ai / ha or more, 44 g ai / ha or more, 46 g ai / ha or more, 48 g ai / ha or more, 50 g ai / ha or more, 51 g ai / ha or more, 52 g ai / ha or more, 53 g ai / ha or more, 54 g ai / ha or more, 55 g ai / ha or more, 56 g ai / ha or more, 57 g ai / ha or more, or 58 g ai / ha or more; in an amount of 59 g ai / ha or less, such as 58 g ai / ha or less, 57 g ai / ha or less, 56 g ai / ha or less, 55 g ai / ha or less, 54 g ai / ha or less, 53 g ai / ha or less, 52 g ai / ha or less, 51 g ai / ha or less, 50 g ai / ha or less, 48 g ai / ha or less, 46 g ai / ha or less, 44 g ai / ha or less, 42 g ai / ha or less, 40 g ai / ha or less, 38 g ai / ha or less, 36 g ai / ha or less, 35 g ai / ha or less 34 g ai / ha or less, 32 g ai / ha or less, 30 g ai / ha or less, 28 g ai / ha or less, 26 g ai / ha or less, 25 g ai / ha or less, 24 g ai / ha or less, or 23 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 22.5-59 g ai / ha, 23-51 g ai / ha, 25-38 g ai / ha, 26-57 g ai / ha, 28-48 g ai / ha, 30-58 g ai / ha, 30-50 g ai / ha, 32-55 g ai / ha, 34-57 g ai / ha, or 35-58 g ai / ha.Halosulfuron

[0103] Compositions and methods of the present disclosure can include halosulfuron or an agriculturally acceptable salt or ester thereof. Halosulfuron-methyl, shown below, is a sulfonylurea that has demonstrated activity for the control of annual broadleaf weeds and nutsedge species, in maize, sugar cane, rice, sorghum, nuts, and turf. Halosulfuron, as well as methods of preparing halosulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0104] Halosulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, halosulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 4.375 g ai / ha or more, such as 4.75 g ai / ha or more, 5 g ai / ha or more, 6 g ai / ha or more, 7 g ai / ha or more, 8 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 15 g ai / ha or more, 20 g ai / ha or more, 25 g ai / ha or more, 30 g ai / ha or more, 35 g ai / ha or more, 40 g ai / ha or more, 45 g ai / ha or more, 50 g ai / ha or more, 55 g ai / ha or more, 60 g ai / ha or more, 65 g ai / ha or more, 70 g ai / ha or more, 75 g ai / ha or more, 80 g ai / ha or more, 85 g ai / ha or more, 90 g ai / ha or more, 95 g ai / ha or more, 100 g ai / ha or more, 105 g ai / ha or more, 110 g ai / ha or more, 115 g ai / ha or more, 120 g ai / ha or more, 122 g ai / ha or more, 124 g ai / ha or more, 126 g ai / ha or more, 128 g ai / ha or more, 130 g ai / ha or more, 131 g ai / ha or more, 132 g ai / ha or more, 133 g ai / ha or more, 134 g ai / ha or more, 135 g ai / ha or more, 136 g ai / ha or more, 137 g ai / ha or more, 138 g ai / ha or more, or 139 g ai / ha or more; in an amount of 139 g ai / ha or less, such as 138 g ai / ha or less, 137 g ai / ha or less, 136 g ai / ha or less, 135 g ai / ha or less, 134 g ai / ha or less, 133 g ai / ha or less, 132 g ai / ha or less, 131 g ai / ha or less, 130 g ai / ha or less, 129 g ai / ha or less, 128 g ai / ha or less, 126 g ai / ha or less, 124 g ai / ha or less, 122 g ai / ha or less, 120 g ai / ha or less, 115 g ai / ha or less, 110 g ai / ha or less, 105 g ai / ha or less, 100 g ai / ha or less, 95 g ai / ha or less, 90 g ai / ha or less, 85 g ai / ha or less, 80 g ai / ha or less, 75 g ai / ha or less, 70 g ai / ha or less, 65 g ai / ha or less, 60 g ai / ha or less, 55 g ai / ha or less, 50 g ai / ha or less, 45 g ai / ha or less, 40 g ai / ha or less, 35 g ai / ha or less, 30 g ai / ha or less, 25 g ai / ha or less, 20 g ai / ha or less, 15 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7 g ai / ha or less, 6 g ai / ha or less, 5 g ai / ha or less, 4.75 g ai / ha or less, or 4.5 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 4.375-140 g ai / ha, 4.5-120 g ai / ha, 4.75-100 g ai / ha, 5-95 g ai / ha, 5-131 g ai / ha, 6-80 g ai / ha, 7-130 g ai / ha, 8-122 g ai / ha, 9-75 g ai / ha, 10-139 g ai / ha, 15-90 g ai / ha, 20-124 g ai / ha, 25-110 g ai / ha, or 25-75 g ai / ha.Iodosulfuron

[0105] Compositions and methods of the present disclosure can include iodosulfuron or an agriculturally acceptable salt or ester thereof. Iodosulfuron-methyl-sodium, shown below, is a sulfonylurea that provides, e.g., post-emergence control of grass and broadleaf weeds in winter, spring and durum wheat, triticale, rye and spring barley. Iodosulfuron, as well as methods of preparing iodosulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0106] Iodosulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, iodosulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 0.1 g ai / ha or more, such as 0.2 g ai / ha or greater, 0.3 g ai / ha or greater, 0.4 g ai / ha or greater, 0.5 g ai / ha or greater, 0.6 g ai / ha or greater, 0.7 g ai / ha or greater, 0.8 g ai / ha or greater, 0.9 g ai / ha or greater, 1 g ai / ha or greater, 1.1 g ai / ha or greater, 1.2 g ai / ha or greater, 1.3 g ai / ha or greater, 1.4 g ai / ha or more, 1.5 g ai / ha or more, 1.6 g ai / ha or more, 1.7 g ai / ha or more, 1.8 g ai / ha or more, 1.9 g ai / ha or more, 2.0 g ai / ha or more, 2.1 g ai / ha or more, 2.2 g ai / ha or more, 2.3 g ai / ha or more, 2.3 g ai / ha or more, 2.4 g ai / ha or more, 2.5 g ai / ha or more, 2.6 g ai / ha or more, 2.7 g ai / ha or more, 2.8 g ai / ha or more, 2.9 g ai / ha or more, 3.0 g ai / ha or more, 3.2 g ai / ha or more, 3.4 g ai / ha or more, 3.6 g ai / ha or more, 3.8 g ai / ha or more, 4 g ai / ha or more, 4.2 g ai / ha or more, 4.4 g ai / ha or more, 4.6 g ai / ha or more, 4.8 g ai / ha or more, 5 g ai / ha or more, 5.2 g ai / ha or more, 5.4 g ai / ha or more, 5.6 g ai / ha or more, 5.8 g ai / ha or more, 6 g ai / ha or more, 6.2 g ai / ha or more, 6.4 g ai / ha or more, 6.6 g ai / ha or more, 6.8 g ai / ha or more, 7 g ai / ha or more, 7.2 ai / ha or more, 7.4 g ai / ha or more, 7.6 g ai / ha or more, 8 g ai / ha or more, 8.2 g ai / ha or more, 8.4 ai / ha or more, 8.6 g ai / ha or more, 8.8 g ai / ha or more, 9 g ai / ha or more, 9.1 g ai / ha or more, 9.2 g ai / ha or more, 9.3 g ai / ha or more, 9.4 g ai / ha or more, 9.5 g ai / ha or more, 9.6 g ai / ha or more, 9.7 g ai / ha or more, 9.8 g ai / ha or more, or 9.9 g ai / ha or more; in an amount of 10 g ai / ha or less, such as 9.9 g ai / ha or less, 9.8 g ai / ha or less, 9.7 g ai / ha or less, 9.6 g ai / ha or less, 9.5 g ai / ha or less, 9.4 g ai / ha or less, 9.3 g ai / ha or less, 9.2 g ai / ha or less, 9.1 g ai / ha or less, 9 g ai / ha or less, 8.8 g ai / ha or less, 8.6 g ai / ha or less, 8.4 g ai / ha or less, 8.2 g ai / ha or less, 8 g ai / ha or less, 7.8 g ai / ha or less, 7.6 g ai / ha or less, 7.4 g ai / ha or less, 7.2 g ai / ha or less, 7 g ai / ha or less, 6.8 g ai / ha or less, 6.6 g ai / ha or less, 6.4 g ai / ha or less, 6.2 g ai / ha or less, 6 g ai / ha or less, 5.8 g ai / ha or less, 5.6 g ai / ha or less, 5.4 g ai / ha or less, 5.2 g ai / ha or less, 5 g ai / ha or less, 4.8 g ai / ha or less, 4.6 g ai / ha or less, 4.4 g ai / ha or less, 4.2 g ai / ha or less, 4 g ai / ha or less, 3.8 g ai / ha or less, 3.6 g ai / ha or less, 3.4 g ai / ha or less, 3.2 g ai / ha or less, 3 g ai / ha or less, 2.9 g ai / ha or less, 2.8 g ai / ha or less, 2.7 g ai / ha or less, 2.6 g ai / ha or less, 2.5 g ai / ha or less, 2.4 g ai / ha or less, 2.3 g ai / ha or less, 2.2 g ai / ha or less, 2.1 g ai / ha or less, 2.0 g ai / ha or less, 1.9 g ai / ha or less, 1.8 g ai / ha or less, 1.7 g ai / ha or less, 1.6 g ai / ha or less, 1.5 g ai / ha or less, 1.4 g ai / ha or less, 1.3 g ai / ha or less, 1.2 g ai / ha or less, 1.1 g ai / ha or less, 1 g ai / ha or less, 0.9 g ai / ha or less, 0.8 g ai / ha or less, 0.7 g ai / ha or less, 0.6 g ai / ha or less, 0.5 g ai / ha or less, 0.4 g ai / ha or less, 0.3 g ai / ha or less, or 0.2 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.1-10 g ai / ha, 0.4-8.8 g ai / ha, 1.1-6.2 g ai / ha, 1.7-7.5 g ai / ha, 1.8-9.2 g ai / ha, 1.9-9 g ai / ha, 2-6.8 g ai / ha, 2.2-9.5 g ai / ha, 2.5-10 g ai / ha, 2.8-7.6 g ai / ha, 3-9.4 g ai / ha, 3.2-7.2 g ai / ha, 3.4-10 g ai / ha, or 3.6-8 g ai / ha.Mesosulfuron

[0107] Compositions and methods of the present disclosure can include mesosulfuron or an agriculturally acceptable salt or ester thereof. Mesosulfuron-methyl, shown below, is a sulfonylurea that provides, e.g., early- to mid-post-emergence control of grass and some broadleaf weeds in winter, spring and durum wheat, triticale and rye. Mesosulfuron, as well as methods of preparing mesosulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0108] Mesosulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, mesosulfuron thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1.5 g ai / ha or more, such as 1.6 g ai / ha or more, 1.7 g ai / ha or more, 1.8 g ai / ha or more, 1.9 g ai / ha or more, 2 g ai / ha or more, 2.1 g ai / ha or more, 2.25 g ai / ha or more, 2.5 g ai / ha or more, 2.75 g ai / ha or more, 3 g ai / ha or more, 3.25 g ai / ha or more, 3.5 g ai / ha or more, 3.75 g ai / ha or more, 4 g ai / ha or more, 4.25 g ai / ha or more, 4.5 g ai / ha or more, 4.75 g ai / ha or more, 5 g ai / ha or more, 6 g ai / ha or more, 7 g ai / ha or more, 8 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 12 g ai / ha or more, 14 g ai / ha or more, 16 g ai / ha or more, 18 g ai / ha or more, 20 g ai / ha or more, 22 g ai / ha or more, 24 g ai / ha or more, 26 g ai / ha or more, 28 g ai / ha or more, 30 g ai / ha or more, 31 g ai / ha or more, 32 g ai / ha or more, 33 g ai / ha or more, 34 g ai / ha or more, 35 g ai / ha or more, 36 g ai / ha or more, 37 g ai / ha or more, 38 g ai / ha or more, 39 g ai / ha or more, 40 g ai / ha or more, 41 g ai / ha or more, 42 g ai / ha or more, 43 g ai / ha or more, or 44 g ai / ha or more; in an amount of 45 g ai / ha or less, such as 44 g ai / ha or less, 43 g ai / ha or less, 42 g ai / ha or less, 41 g ai / ha or less, 40 g ai / ha or less, 39 g ai / ha or less, 38 g ai / ha or less, 37 g ai / ha or less, 36 g ai / ha or less, 35 g ai / ha or less, 34 g ai / ha or less, 33 g ai / ha or less, 32 g ai / ha or less, 31 g ai / ha or less, 30 g ai / ha or less, 28 g ai / ha or less, 26 g ai / ha or less, 24 g ai / ha or less, 22 g ai / ha or less, 20 g ai / ha or less, 18 g ai / ha or less, 16 g ai / ha or less, 14 g ai / ha or less, 12 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7 g ai / ha or less, 6 g ai / ha or less, 5 g ai / ha or less, 4.75 g ai / ha or less, 4.5 g ai / ha or less, 4.25 g ai / ha or less, 4 g ai / ha or less, 3.75 g ai / ha or less, 3.5 g ai / ha or less, 3.25 g ai / ha or less, 3 g ai / ha or less, 2.75 g ai / ha or less, 2.5 g ai / ha or less, 2.25 g ai / ha or less, 2.1 g ai / ha or less, 2 g ai / ha or less, 1.9 g ai / ha or less, 1.8 g ai / ha or less, 1.7 g ai / ha or less, 1.6 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1.5-45 g ai / ha, 1.6-42 g ai / ha, 1.5-40 g ai / ha, 1.7-43 g ai / ha, 1.8-35 g ai / ha, 2-37 g ai / ha, 2.25-41 g ai / ha, 2.5-32 g ai / ha, 2.75-45 g ai / ha, 3-40 g ai / ha, 3-33 g ai / ha, 3-24 g ai / ha, 3.5-45 g ai / ha, or 4-39 g ai / ha.Metsulfuron

[0109] Compositions and methods of the present disclosure can include metsulfuron or an agriculturally acceptable salt or ester thereof. Metsulfuron-methyl, shown below, is a sulfonylurea that controls, e.g., grass and broadleaf weeds in wheat, barley, rice, oats and triticale. Metsulfuron, as well as methods of preparing metsulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0110] Metsulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, metsulfuron thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai / ha or more, such as 1.1 g ai / ha or more, 1.2 g ai / ha or more, 1.25 g ai / ha or more, 1.3 g ai / ha or more, 1.4 g ai / ha or more, 1.5 g ai / ha or more, 1.6 g ai / ha or more, 1.7 g ai / ha or more, 1.8 g ai / ha or more, 1.9 g ai / ha or more, 2 g ai / ha or more, 2.1 g ai / ha or more, 2.2 g ai / ha or more, 2.3 g ai / ha or more, 2.3 g ai / ha or more, 2.4 g ai / ha or more, 2.5 g ai / ha or more, 2.6 g ai / ha or more, 2.7 g ai / ha or more, 2.8 g ai / ha or more, 2.9 g ai / ha or more, 3 g ai / ha or more, 3.2 g ai / ha or more, 3.4 g ai / ha or more, 3.6 g ai / ha or more, 3.8 g ai / ha or more, 4 g ai / ha or more, 4.2 g ai / ha or more, 4.4 g ai / ha or more, 4.6 g ai / ha or more, 4.8 g ai / ha or more, 5 g ai / ha or more, 5.2 g ai / ha or more, 5.4 g ai / ha or more, 5.6 g ai / ha or more, 5.8 g ai / ha or more, 6 g ai / ha or more, 6.2 g ai / ha or more, 6.4 g ai / ha or more, 6.6 g ai / ha or more, 6.8 g ai / ha or more, 7 g ai / ha or more, 7.2 ai / ha or more, 7.4 g ai / ha or more, 7.6 g ai / ha or more, 7.8 g ai / ha or more, 8 g ai / ha or more, 8.2 g ai / ha or more, 8.4 ai / ha or more, 8.6 g ai / ha or more, 8.8 g ai / ha or more, 9 g ai / ha or more, 9.2 g ai / ha or more, 9.4 g ai / ha or more, 9.6 g ai / ha or more, 9.8 g ai / ha or more, 10 g ai / ha or more, 10.2 g ai / ha or more, 10.4 g ai / ha or more, 10.6 g ai / ha or more, 10.8 g ai / ha or more, 11 g ai / ha or more, 11.1 g ai / ha or more, 11.2 g ai / ha or more, 11.3 g ai / ha or more, 11.4 g ai / ha or more, 11.5 g ai / ha or more, 11.6 g ai / ha or more, 11.7 g ai / ha or more, 11.8 g ai / ha or more, or 11.9 g ai / ha or more; in an amount of 12 g ai / ha or less, such as 11.9 g ai / ha or less, 11.8 g ai / ha or less, 11.7 g ai / ha or less, 11.6 g ai / ha or less, 11.5 g ai / ha or less, 11.4 g ai / ha or less, 11.3 g ai / ha or less, 11.2 g ai / ha or less, 11.1 g ai / ha or less, 11 g ai / ha or less, 10.8 g ai / ha or less, 10.6 g ai / ha or less, 10.4 g ai / ha or less, 10.2 g ai / ha or less, 10 g ai / ha or less, 9.8 g ai / ha or less, 9.6 g ai / ha or less, 9.4 g ai / ha or less, 9.2 g ai / ha or less, 9 g ai / ha or less, 8.8 g ai / ha or less, 8.6 g ai / ha or less, 8.4 g ai / ha or less, 8.2 g ai / ha or less, 8 g ai / ha or less, 7.8 g ai / ha or less, 7.6 g ai / ha or less, 7.4 g ai / ha or less, 7.2 g ai / ha or less, 7 g ai / ha or less, 6.8 g ai / ha or less, 6.6 g ai / ha or less, 6.4 g ai / ha or less, 6.2 g ai / ha or less, 6 g ai / ha or less, 5.8 g ai / ha or less, 5.6 g ai / ha or less, 5.4 g ai / ha or less, 5.2 g ai / ha or less, 5 g ai / ha or less, 4.8 g ai / ha or less, 4.6 g ai / ha or less, 4.4 g ai / ha or less, 4.2 g ai / ha or less, 4 g ai / ha or less, 3.8 g ai / ha or less, 3.6 g ai / ha or less, 3.4 g ai / ha or less, 3.2 g ai / ha or less, 3 g ai / ha or less, 2.9 g ai / ha or less, 2.8 g ai / ha or less, 2.7 g ai / ha or less, 2.6 g ai / ha or less, 2.5 g ai / ha or less, 2.4 g ai / ha or less, 2.3 g ai / ha or less, 2.2 g ai / ha or less, 2.1 g ai / ha or less, 2 g ai / ha or less, 1.9 g ai / ha or less, 1.8 g ai / ha, 1.7 g ai / ha or less, 1.6 g ai / ha or less, 1.5 g ai / ha or less, 1.4 g ai / ha or less, 1.3 g ai / ha or less, 1.25 g ai / ha or less, 1.2 g ai / ha or less, or 1.1 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1-12 g ai / ha, 1-10 g ai / ha, 1.1-9.4 g ai / ha, 1.25-8.2 g ai / ha, 1.25-11 g ai / ha, 1.3-7 g ai / ha, 1.4-5.8 g ai / ha, 1.5-12 g ai / ha, 1.5-10.4 g ai / ha, 1.5-8.8 g ai / ha, 2-11.7 g ai / ha, 2.2-6.4 g ai / ha, 2.5-7.6 g ai / ha, 2.8-12 g ai / ha, or 3-8 g ai / ha.Nicosulfuron

[0111] Compositions and methods of the present disclosure can include nicosulfuron or an agriculturally acceptable salt or ester thereof. Nicosulfuron, shown below, is a sulfonylurea that provides e.g., selective post-emergence control in maize of annual grass weeds, including Setaria, Echinochloa, Digitaria, Panicum, Lolium and Avena spp., broadleaf weeds, including Amaranthus spp. and Cruciferae, and perennials such as Sorghum halepense and Agropyron repens. Nicosulfuron, as well as methods of preparing nicosulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0112] Nicosulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, nicosulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 8.75 g ai / ha or more, such as 9 g ai / ha or more, 10 g ai / ha or more, 11 g ai / ha or more, 12 g ai / ha or more, 13 g ai / ha or more, 14 g ai / ha or more, 15 g ai / ha or more, 16 g ai / ha or more, 17 g ai / ha or more, 18 g ai / ha or more, 19 g ai / ha or more, 20 g ai / ha or more, 22 g ai / ha or more, 24 g ai / ha or more, 26 g ai / ha or more, 28 g ai / ha or more, 30 g ai / ha or more, 32 g ai / ha or more, 34 g ai / ha or more, 36 g ai / ha or more, 38 g ai / ha or more, 40 g ai / ha or more, 42 g ai / ha or more, 44 g ai / ha or more, 46 g ai / ha or more, 48 g ai / ha or more, 50 g ai / ha or more, 52 g ai / ha or more, 54 g ai / ha or more, 56 g ai / ha or more, 58 g ai / ha or more, 60 g ai / ha or more, 62 g ai / ha or more, 64 g ai / ha or more, 66 g ai / ha or more, 68 g ai / ha or more, or 69 g ai / ha or more; in an amount of 70 g ai / ha or less, such as 69 g ai / ha or less, 68 g ai / ha or less, 66 g ai / ha or less, 64 g ai / ha or less, 62 g ai / ha or less, 60 g ai / ha or less, 58 g ai / ha or less, 56 g ai / ha or less, 54 g ai / ha or less, 52 g ai / ha or less, 50 g ai / ha or less, 48 g ai / ha or less, 46 g ai / ha or less, 44 g ai / ha or less, 42 g ai / ha or less, 40 g ai / ha or less, 38 g ai / ha or less, 36 g ai / ha or less, 34 g ai / ha or less, 32 g ai / ha or less, 30 g ai / ha or less, 28 g ai / ha or less, 26 g ai / ha or less, 24 g ai / ha or less, 22 g ai / ha or less, 20 g ai / ha or less, 19 g ai / ha or less, 18 g ai / ha or less, 17 g ai / ha or less, 16 g ai / ha or less, 15 g ai / ha or less, 14 g ai / ha or less, 13 g ai / ha or less, 12 g ai / ha or less, 11 g ai / ha or less, 10 g ai / ha or less, or 9 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 8.75-70 g ai / ha, 9-68 g ai / ha, 10-50 g ai / ha, 12-66 g ai / ha, 14-44 g ai / ha, 15-58 g ai / ha, 18-65 g ai / ha, 20-45 g ai / ha, 22-60 g ai / ha, 26-56 g ai / ha, or 30-70 g ai / ha.Orthosulfamuron

[0113] Compositions and methods of the present disclosure can include orthosulfamuron or an agriculturally acceptable salt or ester thereof. Orthosulfamuron, shown below, is a sulfonylurea that provides e.g., early post-emergence control of annual and perennial broadleaf weeds and sedges in rice, cereals, pastures and sugar cane. Orthosulfamuron, as well as methods of preparing orthosulfamuron, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016.

[0114] Orthosulfamuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, orthosulfamuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 7.5 g ai / ha or more, such as 8 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 11 g ai / ha or more, 12 g ai / ha or more, 13 g ai / ha or more, 14 g ai / ha or more, 15 g ai / ha or more, 16 g ai / ha or more, 17 g ai / ha or more, 18 g ai / ha or more, 19 g ai / ha or more, 20 g ai / ha or more, 22 g ai / ha or more, 24 g ai / ha or more, 26 g ai / ha or more, 28 g ai / ha or more, 30 g ai / ha or more, 32 g ai / ha or more, 34 g ai / ha or more, 36 g ai / ha or more, 38 g ai / ha or more, 40 g ai / ha or more, 42 g ai / ha or more, 44 g ai / ha or more, 46 g ai / ha or more, 48 g ai / ha or more, 50 g ai / ha or more, 52 g ai / ha or more, 54 g ai / ha or more, 56 g ai / ha or more, 58 g ai / ha or more, 60 g ai / ha or more, 62 g ai / ha or more, 64 g ai / ha or more, 66 g ai / ha or more, 68 g ai / ha or more, 70 g ai / ha or more, 71 g ai / ha or more, 72 g ai / ha or more, 73 g ai / ha or more, or 74 g ai / ha or more; in an amount of 75 g ai / ha or less, such as 74 g ai / ha or less, 72 g ai / ha or less, 70 g ai / ha or less, 68 g ai / ha or less, 66 g ai / ha or less, 64 g ai / ha or less, 62 g ai / ha or less, 60 g ai / ha or less, 58 g ai / ha or less, 56 g ai / ha or less, 54 g ai / ha or less, 52 g ai / ha or less, 50 g ai / ha or less, 48 g ai / ha or less, 46 g ai / ha or less, 44 g ai / ha or less, 42 g ai / ha or less, 40 g ai / ha or less, 38 g ai / ha or less, 36 g ai / ha or less, 34 g ai / ha or less, 32 g ai / ha or less, 30 g ai / ha or less, 28 g ai / ha or less, 26 g ai / ha or less, 24 g ai / ha or less, 22 g ai / ha or less, 20 g ai / ha or less, 19 g ai / ha or less, 18 g ai / ha or less, 17 g ai / ha or less, 16 g ai / ha or less, 15 g ai / ha or less, 14 g ai / ha or less, 13 g ai / ha or less, 12 g ai / ha or less, 11 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, or 8 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 7.5-75 g ai / ha, 7.5-60 g ai / ha, 8-58 g ai / ha, 9-42 g ai / ha, 10-70 g ai / ha, 10-56 g ai / ha, 11-40 g ai / ha, 13-64 g ai / ha, 15-75 g ai / ha, 17-46 g ai / ha, 20-65 g ai / ha, 20-52 g ai / ha, 22-48 g ai / ha, or 24-74 g ai / ha.Rimsulfuron

[0115] Compositions and methods of the present disclosure can include rimsulfuron or an agriculturally acceptable salt or ester thereof. Rimsulfuron, shown below, is a sulfonylurea that provides post-emergence control of most annual and perennial grass weeds and several broad-leaved weeds in maize, tomatoes and potatoes, at 15 g / ha. Rimsulfuron, as well as methods of preparing rimsulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0116] Rimsulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, rimsulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 5 g ai / ha or more, such as 5.5 g ai / ha or more, 6 g ai / ha or more, 7 g ai / ha or more, 7.5 g ai / ha or more, 8 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 12 g ai / ha or more, 14 g ai / ha or more, 16 g ai / ha or more, 18 g ai / ha or more, 20 g ai / ha or more, 22 g ai / ha or more, 24 g ai / ha or more, 26 g ai / ha or more, 27 g ai / ha or more, 28 g ai / ha or more, 30 g ai / ha or more, 32 g ai / ha or more, 34 g ai / ha or more, 36 g ai / ha or more, 38 g ai / ha or more, 40 g ai / ha or more, 42 g ai / ha or more, 44 g ai / ha or more, 46 g ai / ha or more, 48 g ai / ha or more, 50 g ai / ha or more, 52 g ai / ha or more, 54 g ai / ha or more, 56 g ai / ha or more, 58 g ai / ha or more, 60 g ai / ha or more, 62 g ai / ha or more, 64 g ai / ha or more, 66 g ai / ha or more, 68 g ai / ha or more, 69 g ai / ha or more, 70 g ai / ha or more, 71 g ai / ha or more, 72 g ai / ha or more, 73 g ai / ha or more, or 74 g ai / ha or more; in an amount of 75 g ai / ha or less, such as 74 g ai / ha or less, 73 g ai / ha or less, 72 g ai / ha or less, 71 g ai / ha or less, 70 g ai / ha or less, 69 g ai / ha or less, 68 g ai / ha or less, 66 g ai / ha or less, 64 g ai / ha or less, 62 g ai / ha or less, 60 g ai / ha or less, 58 g ai / ha or less, 56 g ai / ha or less, 54 g ai / ha or less, 52 g ai / ha or less, 50 g ai / ha or less, 48 g ai / ha or less, 46 g ai / ha or less, 44 g ai / ha or less, 42 g ai / ha or less, 40 g ai / ha or less, 38 g ai / ha or less, 36 g ai / ha or less, 34 g ai / ha or less, 32 g ai / ha or less, 30 g ai / ha or less, 28 g ai / ha or less, 27 g ai / ha or less, 26 g ai / ha or less, 24 g ai / ha or less, 22 g ai / ha or less, 20 g ai / ha or less, 18 g ai / ha or less, 16 g ai / ha or less, 14 g ai / ha or less, 12 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7.5 g ai / ha or less, 7 g ai / ha or less, 6 g ai / ha or less, 5.5 g ai / ha or less, or 5 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 5-75 g ai / ha, 7.5-70 g ai / ha, 9-64 g ai / ha, 18-69 g ai / ha, 27-36 g ai / ha, 5.5-66 g ai / ha, 14-18 g ai / ha, 27-69 g ai / ha, 7-38 g ai / ha, 12-52 g ai / ha, 9-44 g ai / ha, 10-38 g ai / ha, 16-75 g ai / ha, or 20-48 g ai / ha.Sulfosulfuron

[0117] Compositions and methods of the present disclosure can include sulfosulfuron or an agriculturally acceptable salt or ester thereof. Sulfosulfuron, shown below, is a sulfonylurea that provides e.g., control of annual broadleaf weeds and grass weeds in cereals. Sulfosulfuron, as well as methods of preparing sulfosulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0118] Sulfosulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, sulfosulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 4.375 g ai / ha or more, such as 4.75 g ai / ha or more, 5 g ai / ha or more, 6 g ai / ha or more, 7 g ai / ha or more, 8 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 12 g ai / ha or more, 14 g ai / ha or more, 16 g ai / ha or more, 18 g ai / ha or more, 20 g ai / ha or more, 22 g ai / ha or more, 24 g ai / ha or more, 26 g ai / ha or more, 28 g ai / ha or more, 30 g ai / ha or more, 32 g ai / ha or more, 34 g ai / ha or more, 36 g ai / ha or more, 38 g ai / ha or more, 40 g ai / ha or more, 42 g ai / ha or more, 44 g ai / ha or more, 46 g ai / ha or more, 48 g ai / ha or more, 50 g ai / ha or more, 52 g ai / ha or more, 54 g ai / ha or more, 56 g ai / ha or more, 58 g ai / ha or more, 60 g ai / ha or more, 62 g ai / ha or more, 64 g ai / ha or more, 66 g ai / ha or more, 68 g ai / ha or more, 70 g ai / ha or more, 71 g ai / ha or more, 72 g ai / ha or more, 73 g ai / ha or more, or 74 g ai / ha or more; in an amount of 75 g ai / ha or less, such as 74 g ai / ha or less, 73 g ai / ha or less, 72 g ai / ha or less, 71 g ai / ha or less, 70 g ai / ha or less, 68 g ai / ha or less, 66 g ai / ha or less, 64 g ai / ha or less, 62 g ai / ha or less, 60 g ai / ha or less, 58 g ai / ha or less, 56 g ai / ha or less, 54 g ai / ha or less, 52 g ai / ha or less, 50 g ai / ha or less, 48 g ai / ha or less, 46 g ai / ha or less, 44 g ai / ha or less, 42 g ai / ha or less, 40 g ai / ha or less, 38 g ai / ha or less, 36 g ai / ha or less, 34 g ai / ha or less, 32 g ai / ha or less, 30 g ai / ha or less, 28 g ai / ha or less, 26 g ai / ha or less, 24 g ai / ha or less, 22 g ai / ha or less, 20 g ai / ha or less, 18 g ai / ha or less, 16 g ai / ha or less, 14 g ai / ha or less, 12 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7 g ai / ha or less, 6 g ai / ha or less, 5 g ai / ha or less, or 4.75 g ai / ha or less, or 4.5 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above such as 4.375-75 g ai / ha, 4.5-70 g ai / ha, 4.75-64 g ai / ha, 5-75 g ai / ha, 5-73 g ai / ha, 5-66 g ai / ha, 5-40 g ai / ha, 6-75 g ai / ha, 7-68 g ai / ha, 7-52 g ai / ha, 9-44 g ai / ha, 10-50 g ai / ha, 16-75 g ai / ha, or 20-60 g ai / ha.Thifensulfuron

[0119] Compositions and methods of the present disclosure can include thifensulfuron or an agriculturally acceptable salt or ester thereof. Thifensulfuron-methyl, shown below, is a sulfonylurea that provides e.g., control of annual weeds in cereals, maize and pasture. Thifensulfuron, as well as methods of preparing thifensulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0120] Thifensulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, thifensulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 4.4 g ai / ha or more, such as 4.5 g ai / ha or more, 4.6 g ai / ha or more, 4.7 g ai / ha or more, 4.8 g ai / ha or more, 4.9 g ai / ha or more, 5 g ai / ha or more, 5.2 g ai / ha or more, 5.4 g ai / ha or more, 5.6 g ai / ha or more, 5.8 g ai / ha or more, 6 g ai / ha or more, 6.2 g ai / ha or more, 6.4 g ai / ha or more, 6.6 g ai / ha or more, 6.8 g ai / ha or more, 7 g ai / ha or more, 7.2 g ai / ha or more, 7.4 g ai / ha or more, 7.6 g ai / ha or more, 7.8 g ai / ha or more, 8 g ai / ha or more, 8.2 g ai / ha or more, 8.4 g ai / ha or more, 8.6 g ai / ha or more, 8.8 g ai / ha or more, 9 g ai / ha or more, 9.2 g ai / ha or more, 9.4 g ai / ha or more, 9.6 g ai / ha or more, 9.8 g ai / ha or more, 10 g ai / ha or more, 11 g ai / ha or more, 12 g ai / ha or more, 13 g ai / ha or more, 14 g ai / ha or more, 15 g ai / ha or more, 16 g ai / ha or more, 16.2 g ai / ha or more, 16.4 g ai / ha or more, 16.6 g ai / ha or more, 16.8 g ai / ha or more, 17 g ai / ha or more, 17.1 g ai / ha or more, 17.2 g ai / ha or more, 17.3 g ai / ha or more, or 17.4 g ai / ha or more; in an amount of 17.5 g ai / ha or less, such as 17.4 g ai / ha or less, 17.3 g ai / ha or less, 17.2 g ai / ha or less, 17.1 g ai / ha or less, 17 g ai / ha or less, 16.8 g ai / ha or less, 16.6 g ai / ha or less, 16.4 g ai / ha or less, 16.2 g ai / ha or less, 16 g ai / ha or less, 15 g ai / ha or less, 14 g ai / ha or less, 13 g ai / ha or less, 12 g ai / ha or less, 11 g ai / ha or less, 10 g ai / ha or less, 9.8 g ai / ha or less, 9.6 g ai / ha or less, 9.4 g ai / ha or less, 9.2 g ai / ha or less, 9 g ai / ha or less, 8.8 g ai / ha or less, 8.6 g ai / ha or less, 8.4 g ai / ha or less, 8.2 g ai / ha or less, 8 g ai / ha or less, 7.8 g ai / ha or less, 7.6 g ai / ha or less, 7.4 g ai / ha or less, 7.2 g ai / ha or less, 7 g ai / ha or less, 6.8 g ai / ha or less, 6.6 g ai / ha or less, 6.4 g ai / ha or less, 6.2 g ai / ha or less, 6 g ai / ha or less, 5.8 g ai / ha or less, 5.6 g ai / ha or less, 5.4 g ai / ha or less, 5.2 g ai / ha or less, 5 g ai / ha or less, 4.9 g ai / ha or less, 4.8 g ai / ha or less, 4.7 g ai / ha or less, 4.6 g ai / ha or less, 4.5 g ai / ha or less, or 4.4 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 4.4-17.5 g ai / ha, 4.5-16 g ai / ha, 4.8-11 g ai / ha, 5-17.3 g ai / ha, 5-16.2 g ai / ha, 5.4-13 g ai / ha, 5.8-10 g ai / ha, 6-12 g ai / ha, 6-16 g ai / ha, 7.4-16.4 g ai / ha, 7.8-15 g ai / ha, 8-15 g ai / ha, or 8-17.1 g ai / ha.Tribenuron

[0121] Compositions and methods of the present disclosure can include tribenuron or an agriculturally acceptable salt or ester thereof. Tribenuron-methyl, shown below, is a sulfonylurea that provides e.g., post-emergence control of broadleaf weeds in cereal crops, including wheat, barley, oats, rye and triticale. Tribenuron, as well as methods of preparing tribenuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016.

[0122] Tribenuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, tribenuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 3.75 g ai / ha or more, such as 4 g ai / ha or more, 4.25 g ai / ha or more, 4.5 g ai / ha or more, 4.75 g ai / ha or more, 5 g ai / ha or more, 5.25 g ai / ha or more, 5.5 g ai / ha or more, 5.75 g ai / ha or more, 6 g ai / ha or more, 7 g ai / ha or more, 7.5 g ai / ha or more, 8 g ai / ha or more, 9 g ai / ha or more, 10 g ai / ha or more, 11 g ai / ha or more, 12 g ai / ha or more, 13 g ai / ha or more, 14 g ai / ha or more, 15 g ai / ha or more, 16 g ai / ha or more, 17 g ai / ha or more, 18 g ai / ha or more, 19 g ai / ha or more, 20 g ai / ha or more, 21 g ai / ha or more, 22 g ai / ha or more, 23 g ai / ha or more, 24 g ai / ha or more, 25 g ai / ha or more, 25.5 g ai / ha or more, 26 g ai / ha or more, 26.5 g ai / ha or more, 27 g ai / ha or more, 27.5 g ai / ha or more, 28 g ai / ha or more, 28.5 g ai / ha or more, 29 g ai / ha or more, 29.25 g ai / ha or more, 29.5 g ai / ha or more, or 29.75 g ai / ha or more; in an amount of 30 g ai / ha or less, such as 29.75 g ai / ha or less, 29.5 g ai / ha or less, 29.25 g ai / ha or less, 29 g ai / ha or less, 28.5 g ai / ha or less, 28 g ai / ha or less, 27.5 g ai / ha or less, 27 g ai / ha or less, 26.5 g ai / ha or less, 26 g ai / ha or less, 25 g ai / ha or less, 24 g ai / ha or less, 23 g ai / ha or less, 22 g ai / ha or less, 21 g ai / ha or less, 20 g ai / ha or less, 19 g ai / ha or less, 18 g ai / ha or less, 17 g ai / ha or less, 16 g ai / ha or less, 15 g ai / ha or less, 14 g ai / ha or less, 13 g ai / ha or less, 12 g ai / ha or less, 11 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7.5 g ai / ha or less, 7 g ai / ha or less, 6 g ai / ha or less, 5.75 g ai / ha or less, 5.5 g ai / ha or less, 5.25 g ai / ha or less, 5 g ai / ha or less, 4.75 g ai / ha or less, 4.5 g ai / ha or less, 4.25 g ai / ha or less, or 4 g ai / ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above such as 3.75-30 g ai / ha, 4-27.5 g ai / ha, 4.25-23 g ai / ha, 4.5-17 g ai / ha, 5-25 g ai / ha, 6-29.5 g ai / ha, 7-28 g ai / ha, 7.5-23 g ai / ha, 7.5-20 g ai / ha, 9-30 g ai / ha, 10-19 g ai / ha, or 10-27.5 g ai / ha.IV. Compositions

[0123] In some aspects, (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide or salt thereof and (b) the ALS inhibitor or an agriculturally acceptable salt or ester thereof are used in an amount sufficient to induce an unexpectedly enhanced herbicidal effect (e.g., increased damage or injury to undesirable vegetation) while still showing good crop compatibility (e.g., no increased damage to crops) when compared to the individual application of the herbicidal compounds (a) or (b). In some aspects, the damage or injury to undesirable vegetation caused by the compositions and methods disclosed herein is evaluated using a scale from 0% to 100%, when compared with the untreated control vegetation, wherein 0% indicates no damage to the undesirable vegetation and 100% indicates complete destruction of the undesirable vegetation.

[0124] In some aspects, the joint action of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof and (b) the ALS inhibitor or an agriculturally acceptable salt or ester thereof results in unexpectedly enhanced herbicidal effect against undesirable vegetation, even at application rates below those typically used for the herbicide to have a herbicidal effect on its own. In some aspects, the compositions and methods disclosed herein can, based on the individual components, be used at lower application rates to achieve a herbicidal effect comparable to the effect produced by the individual components at normal application rates.

[0125] In some aspects, the weight ratio of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof (in g ae / ha) to (b) the ALS inhibitor or an agriculturally acceptable salt or ester thereof (in g ai / ha) is 1:3400 or more, such as 1: 3200 or more, 1:3000 or more, 1:2800 or more, 1:2600 or more, 1:2400 or more, 1:2200 or more, 1:2000 or more, 1:1800 or more, 1:1600 or more, 1:1400 or more, 1:1200 or more, 1:1000 or more, 1: 900 or more, 1:800 or more, 1:700 or more, 1:600 or more, 1:500 or more, 1:400 or more, 1:300 or more, 1:200 or more, 1:100 or more, 1:90 or more, 1:80 or more, 1:70 or more, 1:60 or more, 1:50 or more, 1:40 or more, 1:30 or more, 1:20 or more, 1:10 or more, 1:9 or more, 1:8 or more, 1:7 or more, 1:6 or more, 1:5 or more, 1:4 or more, 1:3 or more, 1:2 or more, 1:1.9 or more, 1:1.8 or more, 1:1.7 or more, 1:1.6 or more, 1:1.5 or more, 1:1.4 or more, 1:1.3 or more, 1:1.2 or more, 1:1.1 or more, 1:1 or more, 1.1:1 or more, 1.2:1 or more, 1.3:1 or more, 1.4:1 or more, 1.5:1 or more, 1.6:1 or more, 1.7:1 or more, 1.8:1 or more, 1.9:1 or more, 2:1 or more, 3:1 or more, 4:1 or more, 5:1 or more, 6:1 or more, 7:1 or more, 8:1 or more, 9:1 or more, 10:1 or more, 20:1 or more, 30:1 or more, 40:1 or more, 50:1 or more, 60:1 or more, 70:1 or more, 80:1 or more, 90:1 or more, 100:1 or more, 200:1 or more, 300:1 or more, 400:1 or more, 500:1 or more, 600:1 or more, 700:1 or more, 800:1 or more, 900:1 or more, 1000:1 or more, or 1100:1 or more; the weight ratio of (a) to (b) is 1200:1 or less, such as 1100:1 or less, 1000:1 or less, 900:1 or less, 800:1 or less, 700:1 or less, 600:1 or less, 500:1 or less, 400:1 or less, 300:1 or less, 200:1 or less, 100:1 or less, 90:1 or less, 80:1 or less, 70:1 or less, 60:1 or less, 50:1 or less, 40:1 or less, 30:1 or less, 20:1 or less, 10:1 or less, 9:1 or less, 8:1 or less, 7:1 or less, 6:1 or less, 5:1 or less, 4:1 or less, 3:1 or less, 2:1 or less, 1.9:1 or less, 1.8:1 or less, 1.7:1 or less, 1.6:1 or less, 1.5:1 or less, 1.4:1 or less, 1.3:1 or less, 1.2:1 or less, 1.1:1 or less, 1:1 or less, 1:1.1 or less, 1:1.2 or less, 1:1.3 or less, 1:1.4 or less, 1:1.5 or less, 1:1.6 or less, 1:1.7 or less, 1:1.8 or less, 1:1.9 or less, 1:2 or less, 1:3 or less, 1:4 or less, 1:5 or less, 1:6 or less, 1:7 or less, 1:8 or less, 1:9 or less, 1:10 or less, 1:20 or less, 1:30 or less, 1:40 or less, 1:50 or less, 1:60 or less, 1:70 or less, 1:80 or less, 1:90 or less, 1:100 or less, 1:200 or less, 1:300 or less, 1:400 or less, 1:500 or less, 1:600 or less, 1:700 or less, 1:800 or less, 1:900 or less, 1:1000 or less, 1:1200 or less, 1:1400 or less, 1:1600 or less, 1:1800 or less, 1:2000 or less, 1:2200 or less, 1:2400 or less, 1:2600 or less, 1:2800 or less, 1:3000 or less, or 1:3200 or less; or the weight ratio of (a) to (b) can range from any of the minimum ratios to any of the maximum ratios provided above, such as from 1:1700 to 600:1, from 1:280 to 160:1, from 1:10 to 16:1, from 1:14 to 10:1, or from 1:5 to 5:1.

[0126] In some aspects, (b) includes a triazolopyrimidine sulfonamide or an agriculturally acceptable salt or ester thereof. In some aspects, the weight ratio of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof (in g ae / ha) to (b) a triazolopyrimidine sulfonamide or an agriculturally acceptable salt or ester thereof (in g ai / ha) is 1:2000 or more, such as 1:1900 or more, 1:1800 or more, 1:1700 or more, 1:1600 or more, 1:1500 or more, 1:1400 or more, 1:1300 or more, 1:1200 or more, 1:1100 or more, 1:1000 or more, 1:900 or more, 1:800 or more, 1:700 or more, 1:600 or more, 1:500 or more, 1:400 or more, 1:300 or more, 1:200 or more, 1:100 or more, 1:90 or more, 1:80 or more, 1:70 or more, 1:60 or more, 1:50 or more, 1:40 or more, 1:30 or more, 1:20 or more, 1:10 or more, 1:9 or more, 1:8 or more, 1:7 or more, 1:6 or more, 1:5 or more, 1:4 or more, 1:3 or more, 1:2 or more, 1:1.9 or more, 1:1.8 or more, 1:1.7 or more, 1:1.6 or more, 1:1.5 or more, 1:1.4 or more, 1:1.3 or more, 1:1.2 or more, 1:1.1 or more, 1:1 or more, 1.1:1 or more, 1.2:1 or more, 1.3:1 or more, 1.4:1 or more, 1.5:1 or more, 1.6:1 or more, 1.7:1 or more, 1.8:1 or more, 1.9:1 or more, 2:1 or more, 3:1 or more, 4:1 or more, 5:1 or more, 6:1 or more, 7:1 or more, 8:1 or more, 9:1 or more, 10:1 or more, 20:1 or more, 30:1 or more, 40:1 or more, 50:1 or more, 60:1 or more, 70:1 or more, 80:1 or more, 90:1 or more, 100:1 or more, 200:1 or more, 300:1 or more, 400:1 or more, 500:1 or more, 600:1 or more, 700:1 or more, 800:1 or more, 900:1 or more, 1000:1 or more, or 1100:1 or more; the weight ratio of (a) to (b) is 1200:1 or less, such as 1100:1 or less, 1000:1 or less, 900:1 or less, 800:1 or less, 700:1 or less, 600:1 or less, 500:1 or less, 400:1 or less, 300:1 or less, 200:1 or less, 100:1 or less, 90:1 or less, 80:1 or less, 70:1 or less, 60:1 or less, 50:1 or less, 40:1 or less, 30:1 or less, 20:1 or less, 10:1 or less, 9:1 or less, 8:1 or less, 7:1 or less, 6:1 or less, 5:1 or less, 4:1 or less, 3:1 or less, 2:1 or less, 1.9:1 or less, 1.8:1 or less, 1.7:1 or less, 1.6:1 or less, 1.5:1 or less, 1.4:1 or less, 1.3:1 or less, 1.2:1 or less, 1.1:1 or less, 1:1 or less, 1:1.1 or less, 1:1.2 or less, 1:1.3 or less, 1:1.4 or less, 1:1.5 or less, 1:1.6 or less, 1:1.7 or less, 1:1.8 or less, 1:1.9 or less, 1:2 or less, 1:3 or less, 1:4 or less, 1:5 or less, 1:6 or less, 1:7 or less, 1:8 or less, 1:9 or less, 1:10 or less, 1:20 or less, 1:30 or less, 1:40 or less, 1:50 or less, 1:60 or less, 1:70 or less, 1:80 or less, 1:90 or less, 1:100 or less, 1:200 or less, 1:300 or less, 1:400 or less, 1:500 or less, 1:600 or less, 1:700 or less, 1:800 or less, 1:900 or less, 1:1000 or less, 1:1100 or less, 1:1200 or less, 1:1300 or less, 1:1400 or less, 1:1500 or less, 1:1600 or less, 1:1700 or less, 1:1800 or less, or 1:1900 or less; or the weight ratio of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof (in g ae / ha) to (b) a triazolopyrimidine sulfonamide or an agriculturally acceptable salt or ester thereof (in g ai / ha) can range from any of the minimum ratios described above to any of the maximum values described above, such as from 1:2000 to 1200:1, from 1:2000 to 1000:1, from 1:2000 to 800:1, from 1:2000 to 600:1, from 1:1000 to 400:1, from 1:500 to 200:1, from 1:400 to 190:1, from 1:300 to 180:1, from 1:200 to 170:1, from 1:50 to 120:1, from 1:1.5 to 150:1, from 1:1.5 to 100:1, from 1:1.5 to 50:1, from 1:10 to 16:1, or from 1:1.5 to 40:1. In some aspects, the weight ratio of (a) to (b) is from 1:3.8 to 16:1, or from 1:5 to 6:1.

[0127] In some aspects, (b) includes an imidazolinone or an agriculturally acceptable salt or ester thereof. In some aspects, the weight ratio of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof (in g ae / ha) to (b) imidazolinone or an agriculturally acceptable salt or ester thereof (in g ai / ha) is 1:3400 or more, such as 1: 3200 or more, 1:3000 or more, 1:2800 or more, 1:2600 or more, 1:2400 or more, 1:2200 or more, 1:2000 or more, 1:1800 or more, 1:1600 or more, 1:1400 or more, 1:1200 or more, 1:1000 or more, 1: 900 or more, 1:800 or more, 1:700 or more, 1:600 or more, 1:500 or more, 1:400 or more, 1:300 or more, 1:200 or more, 1:100 or more, 1:90 or more, 1:80 or more, 1:70 or more, 1:60 or more, 1:50 or more, 1:40 or more, 1:30 or more, 1:20 or more, 1:10 or more, 1:9 or more, 1:8 or more, 1:7 or more, 1:6 or more, 1:5 or more, 1:4 or more, 1:3 or more, 1:2 or more, 1:1.9 or more, 1:1.8 or more, 1:1.7 or more, 1:1.6 or more, 1:1.5 or more, 1:1.4 or more, 1:1.3 or more, 1:1.2 or more, 1:1.1 or more, 1:1 or more, 1.1:1 or more, 1.2:1 or more, 1.3:1 or more, 1.4:1 or more, 1.5:1 or more, 1.6:1 or more, 1.7:1 or more, 1.8:1 or more, 1.9:1 or more, 2:1 or more, 3:1 or more, 4:1 or more, 5:1 or more, 6:1 or more, 7:1 or more, 8:1 or more, 9:1 or more, 10:1 or more, 15:1 or more, 20:1 or more, 25:1 or more, 30:1 or more, 35:1 or more, 40:1 or more, 45:1 or more, 50:1 or more, 51:1 or more, 52:1 or more, 53:1 or more, 54:1 or more, 55:1 or more, 56:1 or more, 57:1 or more, 58:1 or more, or 59:1 or more; the weight ratio of (a) to (b) is 60:1 or less, such as 59:1 or less, 58:1 or less, 57:1 or less, 56:1 or less, 55:1 or less, 54:1 or less, 53:1 or less, 52:1 or less, 51:1 or less, 50:1 or less, 45:1 or less, 40:1 or less, 35:1 or less, 30:1 or less, 25:1 or less, 20:1 or less, 15:1 or less, 10:1 or less, 9:1 or less, 8:1 or less, 7:1 or less, 6:1 or less, 5:1 or less, 4:1 or less, 3:1 or less, 2:1 or less, 1.9:1 or less, 1.8:1 or less, 1.7:1 or less, 1.6:1 or less, 1.5:1 or less, 1.4:1 or less, 1.3:1 or less, 1.2:1 or less, 1.1:1 or less, 1:1 or less, 1:1.1 or less, 1:1.2 or less, 1:1.3 or less, 1:1.4 or less, 1:1.5 or less, 1:1.6 or less, 1:1.7 or less, 1:1.8 or less, 1:1.9 or less, 1:2 or less, 1:3 or less, 1:4 or less, 1:5 or less, 1:6 or less, 1:7 or less, 1:8 or less, 1:9 or less, 1:10 or less, 1:20 or less, 1:30 or less, 1:40 or less, 1:50 or less, 1:60 or less, 1:70 or less, 1:80 or less, 1:90 or less, 1:100 or less, 1:200 or less, 1:300 or less, 1:400 or less, 1:500 or less, 1:600 or less, 1:700 or less, 1:800 or less, 1:900 or less, 1:1000 or less, 1:1200 or less, 1:1400 or less, 1:1600 or less, 1:1800 or less, 1:2000 or less, 1:2200 or less, 1:2400 or less, 1:2600 or less, 1:2800 or less, 1:3000 or less, or 1:3200 or less; or the weight ratio of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof (in g ae / ha) to (b) imidazolinone or an agriculturally acceptable salt or ester thereof (in g ai / ha) can range from any of the minimum ratios described above to any of the maximum values described above, such as from 1:3400 to 60:1, from 1:3000 to 60:1, from 1:2500 to 50:1, from 1:2000 to 50:1, from 1:1400 to 60:1, from 1:1500 to 50:1, from 1:1000 to 40:1, from 1:750 to 50:1, from 1:440 to 30:1, from 1:280 to 17:1, from 1:100 to 15:1, from 1:50 to 10:1, or from 1:50 to 7:1. In some aspects, the weight ratio of (a) to (b) is from 1:10 to 5:1, or from 1:10 to 1:6.

[0128] In some aspects, (b) includes pyrimidinyl oxybenzoate or an agriculturally acceptable salt or ester thereof. In some aspects, the weight ratio of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof (in g ae / ha) to (b) pyrimidinyl oxybenzoate or an agriculturally acceptable salt or ester thereof (in g ai / ha) is 1:600 or more, such as 1:590 or more, 1:580 or more, 1:570 or more, 1:560 or more, 1:550 or more, 1:500 or more, 1:450 or more, 1:400 or more, 1:350 or more, 1:300 or more, 1:250 or more, 1:225 or more, 1:200 or more, 1:175 or more, 1:150 or more, 1:125 or more, 1:100 or more, 1:90 or more, 1:80 or more, 1:70 or more, 1:60 or more, 1:50 or more, 1:40 or more, 1:30 or more, 1:20 or more, 1:15 or more, 1:10 or more, 1:5 or more, 1:2.5 or more, 1:1.25 or more, 1:1.1 or more, 1:1 or more, 1.1:1 or more, 1.25:1 or more, 1.5:1 or more, 2:1 or more, 3:1 or more, 4:1 or more, 5:1 or more, 6:1 or more, 7:1 or more, 8:1 or more, 9:1 or more, 10:1 or more, 12:1 or more, 14:1 or more, 16:1 or more, 18:1 or more, 20:1 or more, 22:1 or more, 24:1 or more, 26:1 or more, 28:1 or more, 30:1 or more, 32:1 or more, 34:1 or more, 36:1 or more, 38:1 or more, 40:1 or more, 42:1 or more, 44:1 or more, 46:1 or more, 48:1 or more, 50:1 or more, 51:1 or more, 52:1 or more, 53:1 or more, 54:1 or more, 55:1 or more, 56:1 or more, 58:1 or more, or 59:1 or more; the weight ratio of (a) to (b) is 60:1 or less, such as 59:1 or less, 58:1 or less, 57:1 or less, 56:1 or less, 55:1 or less, 54:1 or less, 53:1 or less, 52:1 or less, 51:1 or less, 50:1 or less, 48:1 or less, 46:1 or less, 44:1 or less, 42:1 or less, 40:1 or less, 38:1 or less, 36:1 or less, 34:1 or less, 32:1 or less, 30:1 or less, 28:1 or less, 26:1 or less, 24:1 or less, 22:1 or less, 20:1 or less, 18:1 or less, 16:1 or less, 14:1 or less, 12:1 or less, 10:1 or less, 9:1 or less, 8:1 or less, 7:1 or less, 6:1 or less, 5:1 or less, 4:1 or less, 3:1 or less, 2:1 or less, 1.5:1 or less, 1.25:1 or less, 1.1:1 or less, 1:1 or less, 1:1.1 or less, 1:1.25 or less, 1:2.5 or less, 1:5 or less, 1:10 or less, 1:15 or less, 1:20 or less, 1:30 or less, 1:40 or less, 1:50 or less, 1:60 or less, 1:70 or less, 1:80 or less, 1:90 or less, 1:100 or less, 1:125 or less, 1:150 or less, 1:175 or less, 1:200 or less, 1:225 or less, 1:250 or less, 1:300 or less, 1:350 or less, 1:400 or less, 1:450 or less, 1:500 or less, 1:550 or less, 1:560 or less, 1:570 or less, 1:580 or less, or 1:590 or less; or the weight ratio of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof (in g ae / ha) to (b) pyrimidinyl oxybenzoate or an agriculturally acceptable salt or ester thereof (in g ai / ha) can range from any of the minimum ratios described above to any of the maximum values described above, such as from 1:600 to 60:1, from 1:500 to 60:1, from 1:500 to 55:1, from 1:400 to 52:1, from 1:400 to 50:1, from 1:300 to 47:1, from 1:250 to 45:1, from 1:200 to 42:1, from 1:140 to 40:1, from 1:130 to 30:1, 1:120 to 20:1 or from 1:100 to 10:1. In some aspects, the weight ratio of (a) to (b) is from 1:15 to 5:1, or from 1:10 to 5:1.

[0129] In some aspects, (b) includes a sulfonylaminocarbonyl triazolinone or an agriculturally acceptable salt or ester thereof. In some aspects, the weight ratio of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof (in g ae / ha) to (b) sulfonylaminocarbonyl triazolinone or an agriculturally acceptable salt or ester thereof (in g ai / ha) is 1:600 or more, such as 1:590 or more, 1:580 or more, 1:570 or more, 1:560 or more, 1:550 or more, 1:500 or more, 1:450 or more, 1:400 or more, 1:350 or more, 1:300 or more, 1:250 or more, 1:225 or more, 1:200 or more, 1:175 or more, 1:150 or more, 1:125 or more, 1:100 or more, 1:90 or more, 1:80 or more, 1:70 or more, 1:60 or more, 1:50 or more, 1:40 or more, 1:30 or more, 1:20 or more, 1:15 or more, 1:10 or more, 1:5 or more, 1:2.5 or more, 1:1.25 or more, 1:1.1 or more, 1:1 or more, 1.1:1 or more, 1.25:1 or more, 1.5:1 or more, 2:1 or more, 3:1 or more, 4:1 or more, 5:1 or more, 6:1 or more, 7:1 or more, 8:1 or more, 9:1 or more, 10:1 or more, 12:1 or more, 14:1 or more, 16:1 or more, 18:1 or more, 20:1 or more, 25:1 or more, 30:1 or more, 35:1 or more, 40:1 or more, 45:1 or more, 50:1 or more, 55:1 or more, 60:1 or more, 65:1 or more, 70:1 or more, 75:1 or more, 80:1 or more, 85:1 or more, 90:1 or more, 95:1 or more, 100:1 or more, 105:1 or more, 110:1 or more, 112:1 or more, 114:1 or more, 116:1 or more, 117:1 or more, 118:1 or more, or 119:1 or more; the weight ratio of (a) to (b) is 120:1 or less, such as 119:1 or less, 118:1 or less, 117:1 or less, 116:1 or less, 114:1 or less, 112:1 or less, 110:1 or less, 105:1 or less, 100:1 or less, 95:1 or less, 90:1 or less, 85:1 or less, 80:1 or less, 75:1 or less, 70:1 or less, 65:1 or less, 60:1 or less, 55:1 or less, 50:1 or less, 45:1 or less, 40:1 or less, 35:1 or less, 30:1 or less, 25:1 or less, 20:1 or less, 18:1 or less, 16:1 or less, 14:1 or less, 12:1 or less, 10:1 or less, 9:1 or less, 8:1 or less, 7:1 or less, 6:1 or less, 5:1 or less, 4:1 or less, 3:1 or less, 2:1 or less, 1.5:1 or less, 1.25:1 or less, 1.1:1 or less, 1:1 or less, 1:1.1 or less, 1:1.25 or less, 1:2.5 or less, 1:5 or less, 1:10 or less, 1:15 or less, 1:20 or less, 1:30 or less, 1:40 or less, 1:50 or less, 1:60 or less, 1:70 or less, 1:80 or less, 1:90 or less, 1:100 or less, 1:125 or less, 1:150 or less, 1:175 or less, 1:200 or less, 1:225 or less, 1:250 or less, 1:300 or less, 1:350 or less, 1:400 or less, 1:450 or less, 1:500 or less, 1:550 or less, 1:560 or less, 1:570 or less, 1:580 or less, or 1:590 or less; or the weight ratio of (a) to (b) can range from any of the minimum ratios described above to any of the maximum values described above, such as from 1:600 to 120:1, from 1:500 to 120:1, from 1:500 to 100:1, from 1:400 to 100:1, from 1:400 to 80:1, from 1:300 to 120:1, from 1:300 to 100:1, from 1:250 to 120:1, from 1:200 to 100:1, from 1:175 to 85:1, from 1:150 to 80:1, from 1:140 to 80:1, from 1:130 to 50:1, or from 1:100 to 25:1. In some aspects, the weight ratio of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof to (b) sulfonylaminocarbonyl triazolinone or an agriculturally acceptable salt or ester thereof is from 1:7.5 to 10:1, or from 1:5 to 1:1.

[0130] In some aspects, (b) includes sulfonylurea or an agriculturally acceptable salt or ester thereof. In some aspects, the weight ratio of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof (in g ae / ha) to (b) a sulfonylurea or an agriculturally acceptable salt or ester thereof (in g ai / ha) is 1:400 or more, such as 1:390 or more, 1:380 or more, 1:360 or more, 1:360 or more, 1:350 or more, 1:340 or more, 1:330 or more, 1:320 or more, 1:310 or more, 1:300 or more, 1:250 or more, 1:225 or more, 1:200 or more, 1:175 or more, 1:150 or more, 1:125 or more, 1:100 or more, 1:90 or more, 1:80 or more, 1:70 or more, 1:60 or more, 1:50 or more, 1:40 or more, 1:30 or more, 1:20 or more, 1:15 or more, 1:10 or more, 1:5 or more, 1:2.5 or more, 1:1.25 or more, 1:1.1 or more, 1:1 or more, 1.1:1 or more, 1.25:1 or more, 2.5:1 or more, 5:1 or more, 10:1 or more, 15:1 or more, 20:1 or more, 30:1 or more, 40:1 or more, 50:1 or more, 60:1 or more, 70:1 or more, 80:1 or more, 90:1 or more, 100:1 or more, 125:1 or more, 150:1 or more, 175:1 or more, 200:1 or more, 225:1 or more, 250:1 or more, 300:1 or more, 310:1 or more, 320:1 or more, 330:1 or more, 340:1 or more, 350:1 or more, 360:1 or more, 380:1 or more, 385:1 or more, 390:1 or more, 392:1 or more, 394:1 or more, 396:1 or more, 397:1 or more, 398:1 or more, or 399:1 or more; the weight ratio of (a) to (b) is 400:1 or less, such as 390:1 or less, 380:1 or less, 370:1 or less, 360:1 or less, 350:1 or less, 340:1 or less, 330:1 or less, 320:1 or less, 310:1 or less, 300:1 or less, 250:1 or less, 225:1 or less, 200:1 or less, 175:1 or less, 150:1 or less, 125:1 or less, 100:1 or less, 90:1 or less, 80:1 or less, 70:1 or less, 60:1 or less, 50:1 or less, 40:1 or less, 30:1 or less, 20:1 or less, 15:1 or less, 10:1 or less, 5:1 or less, 2.5:1 or less, 1.25:1 or less, 1.1:1 or less, 1:1 or less, 1:1.1 or less, 1:1.25 or less, 1:2.5 or less, 1:5 or less, 1:10 or less, 1:15 or less, 1:20 or less, 1:30 or less, 1:40 or less, 1:50 or less, 1:60 or less, 1:70 or less, 1:80 or less, 1:90 or less, 1:100 or less, 1:125 or less, 1:150 or less, 1:175 or less, 1:200 or less, 1:225 or less, 1:250 or less, 1:300 or less, 1:310 or less, 1:320 or less, 1:330 or less, 1:340 or less, 1:350 or less, 1:360 or less, or 1:390 or less; or the weight ratio of (a) to (b) can range from any of the minimum ratios described above to any of the maximum values described above, such as from 1:400 to 400:1, from 1:300 to 300:1, from 1:250 to 250:1, from 1:200 to 200:1, from 1:175 to 175:1, from 1:150 to 150:1, from 1:125 to 125:1, from 1:100 to 100:1, from 1:75 to 75:1, from 1:50 to 50:1, from 1:40 to 40:1, from 1:30 to 30:1, from 1:25 to 25:1, or from 1:20 to 20:1. In some aspects, the weight ratio of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof to (b) pyroxsulam or an agriculturally acceptable salt or ester thereof is from 1:10 to 5:1, or from 1:8.75 to 2:1.

[0131] In some aspects, (a) and (b), independently, can be employed in a purity of from 90% to 100% (e.g., from 95% to 100%) according to nuclear magnetic resonance (NMR) spectroscopy.V. Formulations

[0132] The present disclosure also includes formulations of the compositions and methods disclosed herein.A. Additives

[0133] The compositions and methods disclosed herein can also be mixed with or applied with an additive. In some aspects, the additive is added sequentially. In some aspects, the additive is added simultaneously. In some aspects, the additive is premixed with the pyridine carboxylate herbicide or agriculturally acceptable N-oxide, or salt thereof.1. Other Pesticides

[0134] Some aspects of the described herbicidal compositions includes adding one or more additional pesticide active ingredients to the solid herbicidal compositions. These pesticide active ingredients may include one or more of an herbicide, an insecticide, a fungicide, a nematocide, a miticide, a arthropodicide, a bactericide, a plant growth regulator, or combinations thereof that are compatible with the compositions of the present disclosure.

[0135] In some aspects, the additive is an additional herbicide. For example, the compositions described herein can be applied in conjunction with one or more additional herbicides to control undesirable vegetation. The composition can be formulated with the one or more additional herbicides, tank mixed with the one or more additional herbicides, or applied sequentially with the one or more additional herbicides. Exemplary additional herbicides include, but are not limited to: 4-CPA; 4-CPB; 4-CPP; 2;4-D; 2;4-D choline salt; 2,4-D salts, esters and amines; 2,4-DB; 3,4-DA; 3,4-DB; 2,4-DEB; 2,4-DEP; 2,4-DP; 3,4-DP; 2,3,6-TBA; 2,4,5-T; 2,4,5-TB; acetochlor; acifluorfen; aclonifen; acrolein; alachlor; allidochlor; alloxydim; allyl alcohol; alorac; ametridione; ametryne; amibuzin; amicarbazone; aminocyclopyrachlor; 4-aminopicolinic acid based herbicides, such as halauxifen, halauxifen-methyl, florpyrauxifen, and those described in U.S. Patent Nos. 7,314,849 and 7,432,227 to Balko, et al.; aminopyralid; amiprofos-methyl; amitrole; ammonium sulfamate; anilofos; anisuron; asulam; atraton; atrazine; azafenidin; azimsulfuron; aziprotryne; barban; BCPC; beflubutamid; benazolin; bencarbazone; benfluralin; benfuresate; bensulide; benthiocarb; bentazone; benzadox; benzfendizone; benzipram; benzobicyclon; benzofenap; benzofluor; benzoylprop; benzthiazuron; bialaphos; bicyclopyrone; bifenox; bilanafos; borax; bromacil; bromobonil; bromobutide; bromofenoxim; bromoxynil; brompyrazon; butachlor; butafenacil; butamifos; butenachlor; buthidazole; buthiuron; butralin; butroxydim; buturon; butylate; cacodylic acid; cafenstrole; calcium chlorate; calcium cyanamide; cambendichlor; carbasulam; carbetamide; carboxazole; chlorprocarb; carfentrazone-ethyl; CDEA; CEPC; chlomethoxyfen; chloramben; chloranocryl; chlorazifop; chlorazine; chlorobromuron; chlorbufam; chloreturon; chlorfenac; chlorfenprop; chlorflurazole; chlorflurenol; chloridazon; chlornitrofen; chloropon; chlorotoluron; chloroxuron; chloroxynil; chlorpropham; chlorthal; chlorthiamid; cinidon-ethyl; cinmethylin; cisanilide; clacyfos; clethodim; cliodinate; clodinafop-propargyl; clofop; clomazone; clomeprop; cloprop; cloproxydim; clopyralid; CMA; copper sulfate; CPMF; CPPC; credazine; cresol; cumyluron; cyanatryn; cyanazine; cycloate; cyclopyrimorate; cycloxydim; cycluron; cyhalofop-butyl; cyperquat; cyprazine; cyprazole; cypromid; daimuron; dalapon; dazomet; delachlor; desmedipham; desmetryn; di-allate; dicamba; dichlobenil; dichloralurea; dichlormate; dichlorprop; dichlorprop-P; diclofop-methyl; diethamquat; diethatyl; difenopenten; difenoxuron; difenzoquat; diflufenican; diflufenzopyr; dimefuron; dimepiperate; dimethachlor; dimethametryn; dimethenamid; dimethenamid-P; dimexano; dimidazon; dinitramine; dinofenate; dinoprop; dinosam; dinoseb; dinoterb; diphenamid; dipropetryn; diquat; disul; dithiopyr; diuron; DMPA; DNOC; DSMA; EBEP; eglinazine; endothal; epronaz; EPTC; erbon; esprocarb; ethalfluralin; ethbenzamide; ethidimuron; ethiolate; ethobenzamid; ethofumesate; ethoxyfen; etinofen; etnipromid; etobenzanid; EXD; fenasulam; fenoprop; fenoxaprop; fenoxaprop-P-ethyl; fenoxaprop-P-ethyl + isoxadifen-ethyl; fenoxasulfone; fenquinotrione; fenteracol; fenthiaprop; fentrazamide; fenuron; ferrous sulfate; flamprop; flamprop-M; fluazifop; fluazifop-P-butyl; fluazolate; fluchloralin; flufenacet; flufenican; flufenpyr-ethyl; flumezin; flumiclorac-pentyl; flumioxazin; flumipropyn; fluometuron; fluorodifen; fluoroglycofen; fluoromidine; fluoronitrofen; fluothiuron; flupoxam; flupropacil; flupropanate; fluridone; flurochloridone; fluroxypyr; fluroxypyr-meptyl; flurtamone; fluthiacet; fomesafen; fosamine; fumiclorac; furyloxyfen; glufosinate; glufosinate-ammonium; glufosinate-P-ammonium; glyphosate salts and esters; halosafen;haloxydine; haloxyfop; hexachloroacetone; hexaflurate; hexazinone; indanofan; indaziflam; iodobonil; iodomethane; iodosulfuron-ethyl-sodium; ioxynil; ipazine; ipfencarbazone; iprymidam; isocarbamid; isocil; isomethiozin; isonoruron; isopolinate; isopropalin; isoproturon; isouron; isoxaben; isoxachlortole; isoxaflutole; isoxapyrifop; karbutilate; ketospiradox; lactofen; lenacil; linuron; MAA; MAMA; MCPA esters and amines; MCPA-thioethyl; MCPB; mecoprop; mecoprop-P; medinoterb; mefenacet; mefluidide; mesoprazine; mesotrione; metam; metamifop; metamitron; metazachlor; metflurazon; methabenzthiazuron; methalpropalin; methazole; methiobencarb; methiozolin; methiuron; methometon; methoprotryne; methyl bromide; methyl isothiocyanate; methyldymron; metobenzuron; metobromuron; metolachlor; metoxuron; metribuzin; molinate; monalide; monisouron; monochloroacetic acid; monolinuron; monuron; morfamquat; MSMA; naproanilide; napropamide; napropamide-M; naptalam; neburon; nipyraclofen; nitralin; nitrofen; nitrofluorfen; norflurazon; noruron; OCH; orbencarb; ortho-dichlorobenzene; oryzalin; oxadiargyl; oxadiazon; oxapyrazon; oxaziclomefone; oxyfluorfen; paraflufen-ethyl; parafluron; paraquat; pebulate; pelargonic acid; pendimethalin; pentachlorophenol; pentanochlor; pentoxazone; perfluidone; pethoxamid; phenisopham; phenmedipham; phenmedipham-ethyl; phenobenzuron; phenylmercury acetate; picloram; picolinafen; pinoxaden; piperophos; potassium arsenite; potassium azide; potassium cyanate; pretilachlor; procyazine; prodiamine; profluazol; profluralin; profoxydim; proglinazine; prohexadione-calcium; prometon; prometryne; pronamide; propachlor; propanil; propaquizafop; propazine; propham; propisochlor; propyzamide; prosulfalin; prosulfocarb; proxan; prynachlor; pydanon; pyraclonil; pyraflufen; pyrasulfotole; pyrazogyl; pyrazone; pyrazolynate; pyrazoxyfen; pyributicarb; pyriclor; pyridafol; pyridate; pyroxasulfone; quinclorac; quinmerac; quinoclamine; quinonamid; quizalofop; quizalofop-P-ethyl; quizalofop-P-tefuryl; rhodethanil; saflufenacil; S-metolachlor; sebuthylazine; secbumeton; sethoxydim; siduron; simazine; simeton; simetryn; SMA; sodium arsenite; sodium azide; sodium chlorate; sulcotrione; sulfallate; sulfentrazone; sulfosate; sulfuric acid; sulglycapin; swep; TCA; tebutam; tebuthiuron; tefuryltrione; tembotrione; tepraloxydim; terbacil; terbucarb; terbuchlor; terbumeton; terbuthylazine; terbutryne; tetrafluron; thenylchlor; thiameturon; thiazafluron; thiazopyr; thidiazimin; thidiazuron; thiobencarb; tiafenacil; tiocarbazil; tioclorim; tolpyralate; topramezone; tralkoxydim; tri-allate; triafamone; triaziflam; tribenuron; tricamba; triclopyr choline salt; triclopyr esters and amines; tridiphane; trietazine; trifludimoxazin; trifluralin; triflusulfuron; trifop; trifopsime; trihydroxytriazine; trimeturon; tripropindan; tritac; vernolate; xylachlor; and salts, esters, optically active isomers, and mixtures thereof.

[0136] In some aspects, the additional pesticide or an agriculturally acceptable salt or ester thereof is provided in a premixed formulation with (a), (b), or combinations thereof. In some aspects, the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof is provided in a premixed formulation with an additional pesticide. In some aspects, the ALS inhibitor or an agriculturally acceptable salt or ester thereof is provided in a premixed formulation with an additional pesticide.

[0137] In some aspects, the compositions may exclude one or more herbicidal active ingredients specified above.2. Adjuvants

[0138] In some aspects, the additive includes an agriculturally acceptable adjuvant. Exemplary agriculturally acceptable adjuvants include, but are not limited to, antifreeze agents, antifoam agents, compatibilizing agents, sequestering agents, neutralizing agents and buffers, corrosion inhibitors, colorants, odorants, penetration aids, wetting agents, spreading agents, dispersing agents, thickening agents, freeze point depressants, antimicrobial agents, crop oil, adhesives (for instance, for use in seed formulations), surfactants, protective colloids, emulsifiers, tackifiers, and mixtures thereof.

[0139] Exemplary agriculturally acceptable adjuvants include, but are not limited to, crop oil concentrates (e.g., 85% mineral oil + 15% emulsifiers); nonylphenol ethoxylates; benzylcocoalkyldimethyl quaternary ammonium salts; blends of petroleum hydrocarbon, alkyl esters, organic acids, and anionic surfactants; C 9 -C 11 alkylpolyglycoside; phosphate alcohol ethoxylates; natural primary alcohol (C 12 -C 16 ) ethoxylate; di-sec-butylphenol EO-PO block copolymers; polysiloxane-methyl cap; nonylphenol ethoxylate+urea ammonium nitrates; emulsified methylated seed oils; tridecyl alcohol (synthetic) ethoxylates (e.g., 8 EO); tallow amine ethoxylates (e.g., 15 EO); and PEG(400) dioleate-99.

[0140] Exemplary surfactants (e.g., wetting agents, tackifiers, dispersants, emulsifiers) include, but are not limited to: the alkali metal salts, alkaline earth metal salts and ammonium salts of fatty acids or of aromatic sulfonic acids (e.g., lignosulfonic acids, phenolsulfonic acids, naphthalenesulfonic acids, and dibutylnaphthalenesulfonic acid); alkyl- and alkylarylsulfonates; alkyl sulfates, lauryl ether sulfates and fatty alcohol sulfates; salts of sulfated hexa-, hepta- and octadecanols; salts of fatty alcohol glycol ethers; condensates of sulfonated naphthalene and its derivatives with formaldehyde; condensates of naphthalene or of the naphthalene sulfonic acids with phenol and formaldehyde; polyoxyethylene octylphenol ether; ethoxylated isooctyl-, octyl- or nonylphenol, alkylphenyl or tributylphenyl polyglycol ether; alkyl aryl polyether alcohols; isotridecyl alcohol; fatty alcohol / ethylene oxide condensates; ethoxylated castor oil; polyoxyethylene alkyl ethers or polyoxypropylene alkyl ethers; lauryl alcohol polyglycol ether acetate; sorbitol esters; lignosulfite waste liquors and proteins; denatured proteins, polysaccharides (e.g., methylcellulose); hydrophobically modified starches; and polyvinyl alcohol, polycarboxylates, polyalkoxylates, polyvinyl amine, polyethyleneimine, polyvinylpyrrolidone, and copolymers thereof.

[0141] Exemplary thickeners include, but are not limited to, polysaccharides (e.g., xanthan gum), organic and inorganic sheet minerals, and mixtures thereof.

[0142] Exemplary antifoam agents include, but are not limited to, silicone emulsions, long-chain alcohols, fatty acids, fatty acid salts, organofluorine compounds, and mixtures thereof.

[0143] Exemplary antimicrobial agents include, but are not limited to: bactericides based on dichlorophen and benzyl alcohol hemiformal; isothiazolinone derivatives, such as alkylisothiazolinones and benzisothiazolinones; and mixtures thereof.

[0144] Exemplary antifreeze agents, include, but are not limited to ethylene glycol, propylene glycol, urea, glycerol, and mixtures thereof.

[0145] Exemplary colorants include, but are not limited to, the dyes known under the names Rhodamine B, pigment blue 15:4, pigment blue 15:3, pigment blue 15:2, pigment blue 15:1, pigment blue 80, pigment yellow 1, pigment yellow 13, pigment red 112, pigment red 48:2, pigment red 48:1, pigment red 57:1, pigment red 53:1, pigment orange 43, pigment orange 34, pigment orange 5, pigment green 36, pigment green 7, pigment white 6, pigment brown 25, basic violet 10, basic violet 49, acid red 51, acid red 52, acid red 14, acid blue 9, acid yellow 23, basic red 10, basic red 108, and mixtures thereof.

[0146] Exemplary adhesives include, but are not limited to, polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, tylose, and mixtures thereof.3. Safeners

[0147] is the composition comprises a safener. Safeners are compounds leading to better crop plant compatibility when applied with a herbicide. In some aspects, the safener itself is herbicidally active. In some aspects, the safener acts as an antidote or antagonist in the crop plants and can protect the crop plants from damage that might otherwise occur from an applied herbicide. Exemplary safeners include, but are not limited to, AD-67 (MON 4660), benoxacor, benthiocarb, brassinolide, cloquintocet, cloquintocet-mexyl, cyometrinil, cyprosulfamide, daimuron, dichlormid, dicyclonon, dietholate, dimepiperate, disulfoton, fenchlorazole, fenchlorazole-ethyl, fenclorim, flurazole, fluxofenim, furilazole, harpin proteins, isoxadifen-ethyl, jiecaowan, jiecaoxi, mefenpyr, mefenpyr-diethyl, mephenate, naphthalic anhydride, 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine, 4-(dichloroacetyl)-1-oxa-4-azaspiro [4.5]decane, oxabetrinil, R29148, and N-phenyl-sulfonylbenzoic acid amides, as well as thereof agriculturally acceptable salts and, provided they have a carboxyl group, their agriculturally acceptable derivatives. In some aspects, the safener can be cloquintocet or an ester or salt thereof, such as cloquintocet-mexyl. In some aspects, the safener can be mefenpyr or an ester or salt thereof, such as mefenpyr-diethyl. In some aspects, the safener is employed in rice, cereal, or maize. For example, mefenpyr or cloquintocet can be used to antagonize harmful effects of the compositions on rice, row crops, and cereals.4. Carriers

[0148] In some aspects, the additive includes a carrier. In some aspects, the additive includes a liquid or solid carrier. In some aspects, the additive includes an organic or inorganic carrier. Exemplary liquid carriers include, but are not limited to: water; petroleum fractions or hydrocarbons such as mineral oil, aromatic solvents, paraffinic oils, and the like; vegetable oils such as soybean oil, rapeseed oil, olive oil, castor oil, sunflower seed oil, coconut oil, corn oil, cottonseed oil, linseed oil, palm oil, peanut oil, safflower oil, sesame oil, tung oil and the like; esters of the above vegetable oils; esters of monoalcohols or dihydric, trihydric, or other lower polyalcohols (4-6 hydroxy containing), such as 2-ethyl hexyl stearate, n-butyl oleate, isopropyl myristate, propylene glycol dioleate, di-octyl succinate, di-butyl adipate, di-octyl phthalate and the like; esters of mono, di and polycarboxylic acids and the like; toluene; xylene; petroleum naphtha; crop oil; acetone; methyl ethyl ketone; cyclohexanone; trichloroethylene; perchloroethylene; ethyl acetate; amyl acetate; butyl acetate; propylene glycol monomethyl ether and diethylene glycol monomethyl ether; methyl alcohol; ethyl alcohol; isopropyl alcohol; amyl alcohol; ethylene glycol; propylene glycol; glycerine; N-methyl-2-pyrrolidinone; N;N-dimethyl alkylamides; dimethyl sulfoxide; and liquid fertilizers, as well as mixtures thereof. Exemplary solid carriers include, but are not limited to: silicas, silica gels, silicates, talc, kaolin, limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, pyrophyllite clay, attapulgus clay, kieselguhr, calcium carbonate, bentonite clay, Fuller's earth, cottonseed hulls, wheat flour, soybean flour, pumice, wood flour, walnut shell flour, lignin, ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, cereal meal, tree bark meal, wood meal and nutshell meal, cellulose powders, and mixtures thereof.B. Physical States

[0149] In some aspects, the formulation of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, or salt thereof and (b) the ALS inhibitor or an agriculturally acceptable salt or ester thereof may be present in suspended, emulsified, dissolved, or solid form. Exemplary formulations include, but are not limited to, aqueous solutions, aqueous suspensions, aqueous dispersions, aqueous emulsions, aqueous microemulsions, aqueous suspo-emulsions, oil solutions, oil suspensions, oil dispersions, oil emulsions, oil microemulsions, oil suspo-emulsions, self-emulsifying formulations, pastes, powders, dusts, granules, and materials for spreading.

[0150] In some aspects, (a) and (b) are aqueous solutions that can be diluted before use. In various aspects, (a) or (b) may be provided as a high-strength formulation such as a concentrate. In some aspects, the concentrate is stable and retains potency during storage and shipping. In various aspects, the concentrate is a clear, homogeneous liquid that is stable at temperatures of 54 °C or greater. In some aspects, the concentrate does not exhibit any precipitation of solids at temperatures of -10 °C or higher. In some aspects, the concentrate does not exhibit separation, precipitation, or crystallization of any components at low temperatures. For example, the concentrate remains a clear solution at temperatures below 0 °C (e.g., below -5 °C, below -10°C, below -15 °C). In some aspects, the concentrate exhibits a viscosity of less than 50 centipoise (50 megapascals), even at temperatures as low as 5 °C. In some aspects, the concentrate does not exhibit separation, precipitation, or crystallization of any components during storage for a period of 2 weeks or greater (e.g., 4 weeks, 6 weeks, 8 weeks, 3 months, 6 months, 9 months, or 12 months or greater).

[0151] In some aspects, emulsions, pastes, or oil dispersions can be prepared by homogenizing (a) and (b) in water with a wetting agent, tackifier, dispersant, or emulsifier. In some aspects, concentrates suitable for dilution with water can be prepared, comprising (a), (b), a wetting agent, a tackifier, and a dispersant or emulsifier.

[0152] In some aspects, powders, materials for spreading, or dusts can be prepared by mixing or concomitant grinding of (a) and (b) and optionally other additives with a solid carrier.

[0153] In some aspects, granules (e.g., coated granules, impregnated granules and homogeneous granules) can be prepared by binding the (a) and (b) to solid carriers.

[0154] In some aspects, the formulations comprise, by total weight of (a) and (b), from 1% to 99% of (a) and 1% to 99% of (b) (e.g., 95% of (a) and 5% of (b); 70% of (a) and 30% of (b); or 40% of (a) and 60% of (b)). In formulations designed to be employed as concentrates, the total amount of (a) and (b) can be present in a concentration of from about 0.1 to about 98 weight percent (wt. %), based on the total weight of the formulation For example, the total amount of (a) and (b) can be present in a concentration as little as about 1 wt. %, about 2.5 wt. %, about 5 wt. %, about 7.5 wt. %, about 10 wt. %, about 15wt. %, about 20 wt. %, about 25 wt. %, about 30 wt. %, about 35 wt. %, about 40 wt. %, about 45 wt. %, as high as about 50 wt. %, about 55 wt. %, about 60 wt. %, about 65 wt. %, about 70 wt. %, about 75 wt. %, about 80 wt. %, about 85 wt. %, about 90 wt. %, about 95 wt. %, about 97 wt. %, or within any range defined between any two of the forgoing values, such as between about 1 wt. % to about 97 wt. %, between about 10 wt. % to about 90 wt. %, between about 20 wt. % to about 45 wt. %, and about 25 wt. % to about 50 wt. % based on the total weight of the formulation. Concentrates can be diluted with an inert carrier, such as water, prior to application. The diluted formulations applied to undesirable vegetation or the locus of undesirable vegetation can contain from 0.0006 to 8.0 wt. % of the total amount of (a) and (b) (e.g., from 0.001 to 5.0 wt. %), based on the total weight of the diluted formulation.C. Packaging

[0155] In some aspects, the formulation can be in the form of a single package formulation including both (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide or salt thereof and (b) the ALS inhibitor or an agriculturally acceptable salt or ester thereof, and further including at least one safener as an additive. In some aspects, the formulation can be in the form of a multi-package formulation, such as a two-package formulation, wherein one package contains (a) and optionally at least one additive while the other package contains (b) and optionally at least one additive, provided that at least one package comprises the safener. In some aspects of the two-package formulation, the formulation including (a) and optionally at least one additive and the formulation including (b) and optionally at least one additive are mixed before application and then applied simultaneously. In some aspects, the mixing is performed as a tank mix (e.g., the formulations are mixed immediately before or upon dilution with water).VI. Methods of Use

[0156] The compositions disclosed herein can be applied in any known technique for applying herbicides. Exemplary application techniques include, but are not limited to, spraying, atomizing, dusting, spreading, or direct application into water. The method of application can vary depending on the intended purpose. In some aspects, the method of application can be chosen to ensure the finest possible distribution of the compositions disclosed herein.

[0157] In some aspects, a method of controlling undesirable vegetation which comprises contacting the vegetation or the locus thereof with or applying to the soil or water to prevent the emergence or growth of vegetation any of the compositions is disclosed herein.

[0158] The compositions disclosed herein can be applied pre-emergence (before the emergence of undesirable vegetation) or post-emergence (e.g., during and / or after emergence of the undesirable vegetation). In some aspects, the composition is applied post-emergence to the undesirable vegetation.

[0159] When the compositions are used in crops, the compositions can be applied after seeding and before or after the emergence of the crop plants. In some aspects, the compositions disclosed herein show good crop tolerance even when the crop has already emerged and can be applied during or after the emergence of the crop plants. In some aspects, when the compositions are used in crops, the compositions can be applied before seeding of the crop plants.

[0160] In some aspects, the compositions disclosed herein are applied to vegetation or an area adjacent the vegetation or applying to soil or water to prevent the emergence or growth of vegetation by spraying (e.g., foliar spraying). In some aspects, the spraying techniques use, for example, water as carrier and spray volume rates of from 2 liters per hectare (L / ha) to 2000 L / ha (e.g., from 10-1000 L / ha or from 50-500 L / ha). In some aspects, the compositions disclosed herein are applied by the low-volume or the ultra-low-volume method, wherein the application is in the form of micro granules. In some aspects, wherein the compositions disclosed herein are less well tolerated by certain crop plants, the compositions can be applied with the aid of the spray apparatus in such a way that they come into little contact, if any, with the leaves of the sensitive crop plants while reaching the leaves of undesirable vegetation that grows underneath or on the bare soil (e.g., post-directed or lay-by). In some aspects, the compositions disclosed herein can be applied as dry formulations (e.g., granules, powders, or dusts).

[0161] In some aspects, wherein the undesirable vegetation is treated post-emergence, the compositions disclosed herein are applied by foliar application. In some aspects, herbicidal activity is exhibited by the compounds of the mixture when they are applied directly to the plant or to the locus of the plant at any stage of growth or before planting or emergence. The effect observed can depend upon the type of undesirable vegetation to be controlled, the stage of growth of the undesirable vegetation, the application parameters of dilution and spray drop size, the particle size of solid components, the environmental conditions at the time of use, the specific compound employed, the specific adjuvants and carriers employed, the soil type, and the like, as well as the amount of chemical applied. In some aspects, these and other factors can be adjusted to promote non-selective or selective herbicidal action.

[0162] The compositions and methods disclosed herein can be used to control undesirable vegetation in a variety of applications. The compositions and methods disclosed herein can be used for controlling undesirable vegetation in areas including, but not limited to, farmland, turfgrass, pastures, grasslands, rangelands, fallow land, rights-of-way, aquatic settings, tree and vine, wildlife management areas, or rangeland. In some aspects, the undesirable vegetation is controlled in a row crop. Exemplary crops include, but are not limited to, wheat, barley, triticale, rye, teff, oats, maize, cotton, soy, sorghum, rice, millet, sugarcane and range land (e.g., pasture grasses). In some aspects, the compositions and methods disclosed herein can be used for controlling undesirable vegetation in maize, wheat, barley, rice, sorghum, millet, oats, or a combination thereof. In some aspects, the compositions and methods disclosed herein can be used for controlling undesirable vegetation in broadleaf crops. In some aspects, the compositions and methods disclosed herein can be used for controlling undesirable vegetation in canola, flax, sunflower, soy, or cotton. In some aspects, the compositions and methods disclosed herein can be used in industrial vegetation management (IVM) or for utility, pipeline, roadside, and railroad rights-of-way applications. In some aspects, the compositions and methods disclosed herein can also be used in forestry (e.g., for site preparation or for combating undesirable vegetation in plantation forests). In some aspects, the compositions and methods disclosed herein can be used to control undesirable vegetation in conservation reserve program lands (CRP), trees, vines, grasslands, and grasses grown for seeds. In some aspects, the compositions and methods disclosed herein can be used on lawns (e.g., residential, industrial, and institutional), golf courses, parks, cemeteries, athletic fields, and sod farms.

[0163] The compositions and methods disclosed herein can also be used in crop plants that are resistant to, for instance, herbicides, pathogens, and / or insects. In some aspects, the compositions and methods disclosed herein can be used in crop plants that are resistant to one or more herbicides because of genetic engineering or breeding. In some aspects, the compositions and methods disclosed herein can be used in crop plants that are resistant to one or more pathogens such as plant pathogenic fungi owing to genetic engineering or breeding. In some aspects, the compositions and methods disclosed herein can be used in crop plants that are resistant to attack by insects owing to genetic engineering or breeding. Exemplary resistant crops include, but are not limited to, crops that are resistant to photosystem II inhibitors, or crop plants that, owing to introduction of the gene for Bacillus thuringiensis (or Bt) toxin by genetic modification, are resistant to attack by certain insects. In some aspects, the compositions and methods described herein can be used in conjunction with glyphosate, glufosinate, dicamba, phenoxy auxins, pyridyloxy auxins, aryloxyphenoxypropionates, acetyl CoA carboxylase (ACCase) inhibitors, imidazolinones, acetolactate synthase (ALS) inhibitors, 4-hydroxyphenyl-pyruvate dioxygenase (HPPD) inhibitors, protoporphyrinogen oxidase (PPO) inhibitors, triazines, and bromoxynil to control vegetation in crops tolerant to glyphosate, glufosinate, dicamba, phenoxy auxins, pyridyloxy auxins, aryloxyphenoxypropionates, ACCase inhibitors, imidazolinones, ALS inhibitors, HPPD inhibitors, PPO inhibitors, triazines, bromoxynil, or combinations thereof. In some aspects, the undesirable vegetation is controlled in glyphosate, glufosinate, dicamba, phenoxy auxins, pyridyloxy auxins, aryloxyphenoxypropionates, ACCase inhibitors, ALS inhibitors, HPPD inhibitors, PPO inhibitors, triazines, and bromoxynil tolerant crops possessing single, multiple or stacked traits conferring tolerance to single or multiple chemistries and / or multiple modes of action. In some aspects, the undesirable vegetation can be controlled in a crop that is ACCase-tolerant, ALS-tolerant, or a combination thereof. The combination of (a) and (b) can be used in combination with one or more herbicides that are selective for the crop being treated and which complement the spectrum of weeds controlled by these compounds at the application rate employed. In some aspects, the compositions described herein and other complementary herbicides are applied at the same time, either as a combination formulation or as a tank mix, or as sequential applications. The compositions and methods may be used in controlling undesirable vegetation in crops possessing agronomic stress tolerance (including but not limited to drought, cold, heat, salt, water, nutrient, fertility, pH), pest tolerance (including but not limited to insects, fungi and pathogens), and crop improvement traits (including but not limited to yield; protein, carbohydrate, or oil content; protein, carbohydrate, or oil composition; plant stature and plant architecture).

[0164] In some aspects, the compositions disclosed herein can be used for controlling undesirable vegetation including grasses, broadleaf weeds, sedge weeds, and combinations thereof. In some aspects, the compositions disclosed herein can be used for controlling undesirable vegetation including, but not limited to, Polygonum species, Amaranthus species, Chenopodium species, Sida species, Ambrosia species, Cyperus species, Setaria species, Sorghum species, Acanthospermum species, Anthemis species, Atriplex species, Brassica species, Cirsium species, Convolvulus species, Conyza species, Cassia species, Commelina species, Datura species, Euphorbia species, Geranium species, Galinsoga species, Ipomea species, Lamium species, Lolium species, Malva species, Matricaria species, Prosopis species, Rumex species, Sisymbrium species, Solanum species, Trifolium species, Xanthium species, Veronica species, and Viola species. In some aspects, the undesired vegetation includes common chickweed (Stellaria media), velvetleaf (Abutilon theophrasti), hemp sesbania (Sesbania exaltata Cory), Anoda cristata, Bidens pilosa, Brassica kaber, shepherd's purse (Capsella bursa-pastoris), cornflower (Centaurea cyanus or Cyanus segetum), hempnettle (Galeopsis tetrahit), cleavers (Galium aparine), common sunflower (Helianthus annuus), Desmodium tortuosum, Italian ryegrass (Lolium multiflorum), kochia (Kochia scoparia), Medicago arabica, Mercurialis annua, Myosotis arvensis, common poppy (Papaver rhoeas), Raphanus raphanistrum, broad-leaf dock (Rumex obtusifolius), Russian thistle (Salsola kali), wild mustard (Sinapis arvensis), Sonchus arvensis, Thlaspi arvense, Tagetes minuta, Richardia brasiliensis, Plantago major, Plantago lanceolata, bird's-eye speedwell (Veronica persica), pigweed (Amaranthus retroflexus), winter rape (Brassica napus), lambsquarters (Chenopodium album), Canadian thistle (Cirsium arvense), nutsedge (Cyperus esculentus), poinsettia (Euphorbiaheterophylla), prickly lettuce (Lactuca serriola), purple deadnettle (Lamium purpureum), wild chamomile (Matricaria chamomilla), false chamomile (Matricaria inodora), field chamomile (Anthemis arvensis), common buckwheat (Fagopyrum esculentum), wild buckwheat (Polygonum convulvus), giant foxtail (Setaria faberi), green foxtail (Setaria viridis), common sorghum (Sorghum vulgare), wild pansy (Viola tricolor), or a combination thereof.

[0165] The compositions described herein can be used to control herbicide resistant or tolerant weeds. The methods employing the compositions described herein may also be employed to control herbicide resistant or tolerant weeds. Exemplary resistant or tolerant weeds include, but are not limited to, biotypes resistant or tolerant to acetolactate synthase (ALS) or acetohydroxy acid synthase (AHAS) inhibitors (e.g., imidazolinones, sulfonylureas, pyrimidinylthiobenzoates, triazolopyrimidines, sulfonylaminocarbonyltriazolinones), photosystem II inhibitors (e.g., phenylcarbamates, pyridazinones, triazines, triazinones, uracils, amides, ureas, benzothiadiazinones, nitriles, phenylpyridazines), acetyl CoA carboxylase (ACCase) inhibitors (e.g., aryloxyphenoxypropionates, cyclohexanediones, phenylpyrazolines), synthetic auxins (e.g., benzoic acids, phenoxycarboxylic acids, pyridine carboxylates, quinoline carboxylic acids), auxin transport inhibitors (e.g., phthalamates, semicarbazones), photosystem I inhibitors (e.g., bipyridyliums), 5-enolpyruvylshikimate-3-phosphate (EPSP) synthase inhibitors (e.g., glyphosate), glutamine synthetase inhibitors (e.g., glufosinate, bialaphos), microtubule assembly inhibitors (e.g., benzamides, benzoic acids, dinitroanilines, phosphoramidates, pyridines), mitosis inhibitors (e.g., carbamates), very long chain fatty acid (VLCFA) inhibitors (e.g., acetamides, chloroacetamides, oxyacetamides, tetrazolinones), fatty acid and lipid synthesis inhibitors (e.g., phosphorodithioates, thiocarbamates, benzofuranes, chlorocarbonic acids), protoporphyrinogen oxidase (PPO) inhibitors (e.g., diphenylethers, N-phenylphthalimides, oxadiazoles, oxazolidinediones, phenylpyrazoles, pyrimidindiones, thiadiazoles, triazolinones), carotenoid biosynthesis inhibitors (e.g., clomazone, amitrole, aclonifen), phytoene desaturase (PDS) inhibitors (e.g., amides, anilidex, furanones, phenoxybutan-amides, pyridiazinones, pyridines), 4-hydroxyphenyl-pyruvate-dioxygenase (HPPD) inhibitors (e.g., callistemones, isoxazoles, pyrazoles, triketones), cellulose biosynthesis inhibitors (e.g., nitriles, benzamides, quinclorac, triazolocarboxamides), herbicides with multiple modes of action such as quinclorac, and unclassified herbicides such as arylaminopropionic acids, difenzoquat, endothall, and organoarsenicals. Exemplary resistant or tolerant weeds include, but are not limited to, biotypes with resistance or tolerance to multiple herbicides, biotypes with resistance or tolerance to multiple chemical classes, biotypes with resistance or tolerance to multiple herbicide modes of action, and biotypes with multiple resistance or tolerance mechanisms (e.g., target site resistance or metabolic resistance).

[0166] By way of illustration, examples of some aspects of the present disclosure are given below. Parts and percentages are on a per weight basis unless otherwise indicated.Examples Greenhouse Trial Methodology - Evaluation of Postemergence Herbicidal Effect

[0167] Seeds of the desired test plant species were planted in a 90:10 % v / v (volume / volume) mixture of PRO-MIX ®< BX (Premier Tech Horticulture, Quakertown, PA, USA) and PROFILE ®< GREENS GRADE ™< (Profile Products LLC, Buffalo Grove, IL, USA) planting mixture, which typically has a pH of 5.2 to 6.2 and an organic matter content of at least 50 percent, in plastic pots with a surface area of 103.2 square centimeters (cm 2< ). In some aspects, to ensure good germination and healthy plants, a fungicide treatment and / or other chemical or physical treatment was applied. The plants were grown for 7-36 days (d) in a greenhouse with an approximate 14-hour (h) photoperiod which was maintained at about 23 °C during the day and 22 °C during the night. Nutrients and water were added on a regular basis and supplemental lighting was provided with overhead metal halide 1000-Watt lamps as necessary. The plants were employed for testing when they reached the second or third true leaf stage.

[0168] Emulsifiable concentrates of each of each pyridine carboxylate herbicide (Compound A or Compound B) were prepared at 100 grams acid equivalent per liter (g ae / L). The emulsifiable concentrates also included a safener, cloquintocet-mexyl, at 120 grams active ingredient per liter (g ai / L), unless otherwise noted below. An aliquot of each emulsifiable concentrate was placed in a 25 mL glass vial and diluted with an aqueous mixture of 1.25% (v / v) ACTIROB ®< B esterified rapeseed oil (Bayer Crop Science, Research Triangle Park, NC, USA) or MSO ®< Concentrate with LECI-TECH ®< methylated soybean oil (Loveland Products, Loveland, CO, USA) to obtain concentrated stock solutions at the highest application rate for each herbicide, based upon a 12 milliliter (mL) application volume at a rate of 187 liters per hectare (L / ha). The concentrated stock solutions were further diluted with an aqueous mixture of 1.25% v / v ACTIROB ®< B or MSO ®< Concentrate with LECI-TECH ®< to obtain stock solutions at reduced application rates for each herbicide. Spray solutions of the herbicide combinations (Compound A or Compound B plus ALS herbicide) were prepared by adding weighed amounts or aliquots of the ALS herbicides to the stock solutions of Compound A or Compound B to form 12-mL spray solutions in two- or three-way combinations.

[0169] The spray solutions were applied to the plant material with an overhead Mandel track sprayer equipped with 8002E nozzles calibrated to deliver 187 L / ha over an application area of 0.503 square meters (m 2< ) at a spray height of 18 inches (43 centimeters (cm)) above the average plant canopy. Control plants were sprayed in the same manner with the solvent blank. All pyridine carboxylate herbicide (component a) application rates are given as "g ae / ha" and all ALS inhibitor (component b) application rates are given as "g ai / ha."

[0170] The treated plants and control plants were placed in a greenhouse as described above and watered by sub-irrigation to prevent wash-off of the test compounds. After 20-22 d, the condition of the test plants as compared with that of the control plants was determined visually and scored on a scale of 0 to 100 percent where 0 corresponds to no injury and 100 corresponds to complete kill.

[0171] The details of the compositions and the crops tested are specified in the following Examples.Example 1

[0172] Compositions comprising Compound A and florasulam were tested on undesirable vegetation species, including winter rape (BRSNW, Brassica napus), wild buckwheat (POLCO, Polygonum convolvulus), wild mustard (SINAR, Sinapis arvensis), Russian thistle (SASKR, Salsola kali), kochia (KCHSC, Kochia scoparia), cornflower (CENCY, Cyanus segetum), field violet (VIOAR, Viola arvensis), cleavers (GALAP, Galium aparine), purple deadnettle (LAMPU, Lamium purpureum), ivyleaf speedwell (VERHE, Veronica hederifolia), corn poppy (PAPRH, Papaver rhoeas), bird's-eye speedwell (VERPE, Veronica persica), wild pansy (VIOTR, Viola tricolor), shepherd's purse (CAPBP, Capsella bursa-pastoris), chickweed (STEME, Stellaria media), field chamomile (ANTAR, Anthemis arvensis), wild chamomile (MATCH, Matricaria chamomilla), pineapple weed (MATMT, Matricaria discoidea), false chamomile (MATIN, Matricaria inodora), and Canadian thistle (CIRAR, Cirsium arvense), to determine the efficacy of the compositions on these undesirable vegetation species. The compositions were also tested on spring wheat (TRZAS), winter wheat (TRZAW), spring barley (HORVS), and winter barley (HORVW), and the phytotoxicity of the compositions on each crop was measured.

[0173] The results are summarized in Table 1 below. Table 1. Herbicidal Effects (% visual injury) of Compound A and Florasulam on weed and grain crops. Application rate (g / ha) Compound A7.5101507.51015Florasulam0005555BRSNW 70757597979799POLCO 90959787909093SINAR 97959795100100100SASKR 70707585909090KCHSC 70757595959799CENCY 95939570939797VIOAR 55510101010GALAP 252535959797100LAMPU 70757510758585VERHE 7580805656565PAPRH 851001009710097100VERPE 90939510959397R-PAPRH 959393759797100VIOTR 5101010151520CAPBP 75708080858580STEME 70100100100100100100ANTAR 809095701009595MATCH 20405085959397MATMT 10153095979393MATIN 971001001009799100CIRAR 40406575939595TRZAW 0000000TRZAS 0000000HORVS 0000000HORVW 0000000g / ha = grams per hectare BRSNW = Brassica napus (winter rape) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) SASKR = Salsola kali (Russian thistle) KCHSC = Kochia scoparia (kochia) CENCY = Cyanus segetum (cornflower) VIOAR = Viola arvensis (field violet) GALAP = Galium aparine (cleavers) LAMPU = Lamium purpureum (purple deadnettle) VERHE = Veronica hederifolia (ivyleaf speedwell) PAPRH = Papaver rhoeas (corn poppy) VERPE = Veronica persica (bird's-eye speedwell) R-PAPRH = Papaver rhoeas (corn poppy), herbicide-resistant VIOTR = Viola tricolor (wild pansy) CAPBP = Capsella bursa-pastoris (shepherd's purse) STEME = Stellaria media (chickweed) ANTAR = Anthemis arvensis (field chamomile) MATCH = Matricaria chamomilla (wild chamomile) MATMT = Matricaria discoidea (pineapple weed) MATIN = Matricaria inodora (false chamomile) CIRAR = Cirsium arvense (Canadian thistle) TRZAW = Triticum aestivum (winter wheat) TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) HORVW = Hordeum vulgare (winter barley) Example 2

[0174] Compositions comprising Compound A and pyroxsulam were tested to determine the efficacy of the compositions on undesirable vegetation species, including winter rape (BRSNW, Brassica napus), wild buckwheat (POLCO, Polygonum convolvulus), wild mustard (SINAR, Sinapis arvensis), Russian thistle (SASKR, Salsola kali), kochia (KCHSC, Kochia scoparia), cornflower (CENCY, Cyanus segetum), field violet (VIOAR, Viola arvensis), cleavers (GALAP, Galium aparine), purple deadnettle (LAMPU, Lamium purpureum), ivyleaf speedwell (VERHE, Veronica hederifolia), corn poppy (PAPRH, Papaver rhoeas), bird's-eye speedwell (VERPE, Veronica persica), wild pansy (VIOTR, Viola tricolor), shepherd's purse (CAPBP, Capsella bursa-pastoris), chickweed (STEME, Stellaria media), field chamomile (ANTAR, Anthemis arvensis), wild chamomile (MATCH, Matricaria chamomilla), pineapple weed (MATMT, Matricaria discoidea), false chamomile (MATIN, Matricaria inodora), and Canadian Canadian thistle (CIRAR, Cirsium arvense). The compositions were also tested on spring wheat (TRZAS), winter wheat (TRZAW), spring barley (HORVS), and winter barley (HORVW), and the phytotoxicity of the compositions on each crop was measured.

[0175] The results are summarized in Table 2 below. Table 2. Herbicidal Effects (% visual injury) of Compound A and Pyroxsulam on weed and grain crops. Application rate (g / ha) Compound A7.5101507.51015Pyroxsulam00010101010BRSNW 70757599999799POLCO 90959793939595SINAR 97959799100100100SASKR 70707510097100100KCHSC 70757530858593CENCY 959395709999100VIOAR 55580939595GALAP 252535601009595LAMPU 707575508510090VERHE 75808070858085PAPRH 851001005959597VERPE 90939575909393R-PAPRH 95939310939595VIOTR 5101085859093CAPBP 75708090939590STEME 70100100100858595ANTAR 80909560658085MATCH 20405060656560MATMT 10153050707575MATIN 9710010065708085CIRAR 40406575707580TRZAW 0000000TRZAS 0000000HORVS 0000000HORVW 0000000g / ha = grams per hectareBRSNW = Brassica napus (winter rape) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) SASKR = Salsola kali (Russian thistle) KCHSC = Kochia scoparia (kochia) CENCY = Cyanus segetum (cornflower) VIOAR = Viola arvensis (field violet) GALAP = Galium aparine (cleavers) LAMPU = Lamium purpureum (purple deadnettle) VERHE = Veronica hederifolia (ivyleaf speedwell) PAPRH = Papaver rhoeas (corn poppy) VERPE = Veronica persica (bird's-eye speedwell) R-PAPRH = Papaver rhoeas (corn poppy), herbicide-resistant VIOTR = Viola tricolor (wild pansy) CAPBP = Capsella bursa-pastoris (shepherd's purse) STEME = Stellaria media (chickweed) ANTAR = Anthemis arvensis (field chamomile) MATCH = Matricaria chamomilla (wild chamomile) MATMT = Matricaria discoidea (pineapple weed) MATIN = Matricaria inodora (false chamomile) CIRAR = Cirsium arvense (Canadian thistle) TRZAW = Triticum aestivum (winter wheat) TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) HORVW = Hordeum vulgare (winter barley) Example 3

[0176] Compositions comprising Compound A and imazamethabenz were tested to determine the efficacy of the compositions on undesirable vegetation species, including winter rape (BRSNW, Brassica napus), wild buckwheat (POLCO, Polygonum convolvulus), wild mustard (SINAR, Sinapis arvensis), Russian thistle (SASKR, Salsola kali), kochia (KCHSC, Kochia scoparia), common lambsquarters (CHEAL, Chenopodium album L.), pigweed (AMARE, Amaranthus retroflexus), wild chamomile (MATCH, Matricaria chamomilla), and Canadian Canadian thistle (CIRAR, Cirsium arvense). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0177] The results are summarized in Table 3 below. Table 3. Herbicidal Effects (% visual injury) of Compound A and Imazamethabenz on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Imazamethabenz00100100100TRZAS 00000HORVS 00000BRSNW 3543358395POLCO 7893708495SINAR 889068100100SASKR 606307070KCHSC 636306570CHEAL 889308988AMARE 787308585MATCH 203004540CIRAR 304006568g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) BRSNW = Brassica napus (winter rape) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) SASKR = Salsola kali (Russian thistle) KCHSC = Kochia scoparia (kochia) CHEAL = Chenopodium album L. (common lambsquarters) AMARE = Amaranthus retroflexus (pigweed) MATCH = Matricaria chamomilla (wild chamomile) CIRAR = Cirsium arvense (Canadian thistle) Example 4

[0178] Compositions comprising Compound A and bispyribac were tested to determine the efficacy of the compositions on undesirable vegetation species, including poinsettia (EPHHL, Euphorbia heterophylla), Canadian thistle (CIRAR, Cirsium arvense), spring rape (BRSNN, Brassica napus), grain sorghum (SORVU, Sorghum vulgare), nutsedge (CYPES, Cyperus esculentus), ivyleaf morningglory (IPOHE, Ipomoea hederacea), and common sunflower (HELAN, Helianthus annuus). The compositions were also tested on spring wheat (TRZAS), and the phytotoxicity of the compositions on this crop was measured.

[0179] The results are summarized in Table 4 below. Table 4. Herbicidal Effects (% visual injury) of Compound A and Bispyribac on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Bispyribac00909090EPHHL 9797959093CIRAR 4060909385BRSNN 6565888890SORVU 00736355CYPES 308204045IPOHE 2025708083HELAN 9089979997TRZAS 531883g / ha = grams per hectare EPHHL = Euphorbia heterophylla (poinsettia) CIRAR = Cirsium arvense (Canadian thistle) BRSNN = Brassica napus (spring rape) SORVU = Sorghum vulgare (grain sorghum) CYPES = Cyperus esculentus (nutsedge) IPOHE = Ipomoea hederacea (ivyleaf morningglory) HELAN = Helianthus annuus (common sunflower) TRZAS = Triticum aestivum (spring wheat) Example 5

[0180] Compositions comprising Compound A and pyribenzoxim were tested to determine the efficacy of the compositions on undesirable vegetation species, including poinsettia (EPHHL, Euphorbia heterophylla), Canadian thistle (CIRAR, Cirsium arvense), spring rape (BRSNN, Brassica napus), grain sorghum (SORVU, Sorghum vulgare), nutsedge (CYPES, Cyperus esculentus), ivyleaf morningglory (IPOHE, Ipomoea hederacea), and common sunflower (HELAN, Helianthus annuus). The compositions were also tested on spring wheat (TRZAS), and the phytotoxicity of the compositions on this crop was measured.

[0181] The results are summarized in Table 5 below. Table 5. Herbicidal Effects (% visual injury) of Compound A and Pyribenzoxim on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Pyribenzoxim00101010EPHHL 97971009494CIRAR 4060909398BRSNN 6565908893SORVU 00738080CYPES 30806373IPOHE 2025788883HELAN 9089989899TRZAS 531355g / ha = grams per hectare EPHHL = Euphorbia heterophylla (poinsettia) CIRAR = Cirsium arvense (Canadian thistle) BRSNN = Brassica napus (spring rape) SORVU = Sorghum vulgare (grain sorghum) CYPES = Cyperus esculentus (nutsedge) IPOHE = Ipomoea hederacea (ivyleaf morningglory) HELAN = Helianthus annuus (common sunflower) TRZAS = Triticum aestivum (spring wheat) Example 6

[0182] Compositions comprising Compound A and flucarbazone were tested to determine the efficacy of the compositions on undesirable vegetation species, including winter rape (BRSNW, Brassica napus), wild buckwheat (POLCO, Polygonum convolvulus), wild mustard (SINAR, Sinapis arvensis), Russian thistle (SASKR, Salsola kali), kochia (KCHSC, Kochia scoparia), common lambsquarters (CHEAL, Chenopodium album L.), pigweed (AMARE, Amaranthus retroflexus), wild chamomile (MATCH, Matricaria chamomilla), and Canadian thistle (CIRAR, Cirsium arvense). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0183] The results are summarized in Table 6 below. Table 6. Herbicidal Effects (% visual injury) of Compound A and Flucarbazone on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Flucarbazone007.57.57.5TRZAS 00000HORVS 0023130BRSNW 3543839293POLCO 7893688795SINAR 889095100100SASKR 6063627070KCHSC 6363156563CHEAL 8893138591AMARE 7873709380MATCH 233003040CIRAR 3040105563g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) BRSNW = Brassica napus (winter rape) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) SASKR = Salsola kali (Russian thistle) KCHSC = Kochia scoparia (kochia) CHEAL = Chenopodium album L. (common lambsquarters) AMARE = Amaranthus retroflexus (pigweed) MATCH = Matricaria chamomilla (wild chamomile) CIRAR = Cirsium arvense (Canadian thistle) Example 7

[0184] Compositions comprising Compound A and thiencarbazone were tested to determine the efficacy of the compositions on undesirable vegetation species, including winter rape (BRSNW, Brassica napus), wild buckwheat (POLCO, Polygonum convolvulus), wild mustard (SINAR, Sinapis arvensis), Russian thistle (SASKR, Salsola kali), kochia (KCHSC, Kochia scoparia), common lambsquarters (CHEAL, Chenopodium album L.), pigweed (AMARE, Amaranthus retroflexus), wild chamomile (MATCH, Matricaria chamomilla), and Canadian thistle (CIRAR, Cirsium arvense). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0185] The results are summarized in Table 7 below. Table 7. Herbicidal Effects (% visual injury) of Compound A and Thiencarbazone on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Thiencarbazone00555TRZAS 00000HORVS 000510BRSNW 3543979998POLCO 7893899293SINAR 889095100100SASKR 6063537070KCHSC 6363257578CHEAL 8893608590AMARE 7873839595MATCH 2330556355CIRAR 3040106868g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) BRSNW = Brassica napus (winter rape) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) SASKR = Salsola kali (Russian thistle) KCHSC = Kochia scoparia (kochia) CHEAL = Chenopodium album L. (common lambsquarters) AMARE = Amaranthus retroflexus (pigweed) MATCH = Matricaria chamomilla (wild chamomile) CIRAR = Cirsium arvense (Canadian thistle) Example 8

[0186] Compositions comprising Compound A and iodosulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including winter rape (BRSNW, Brassica napus), wild buckwheat (POLCO, Polygonum convolvulus), wild mustard (SINAR, Sinapis arvensis), Russian thistle (SASKR, Salsola kali), kochia (KCHSC, Kochia scoparia), common lambsquarters (CHEAL, Chenopodium album L.), pigweed (AMARE, Amaranthus retroflexus), wild chamomile (MATCH, Matricaria chamomilla), and Canadian thistle (CIRAR, Cirsium arvense). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0187] The results are summarized in Table 8 below. Table 8. Herbicidal Effects (% visual injury) of Compound A and Iodosulfuron on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Iodosulfuron002.52.52.5TRZAS 00000HORVS 00003BRSNW 35439999100POLCO 7893637880SINAR 8890100100100SASKR 6063858890KCHSC 6363409380CHEAL 8893758883AMARE 78737010098MATCH 2030687875CIRAR 3040788389g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) BRSNW = Brassica napus (winter rape) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) SASKR = Salsola kali (Russian thistle) KCHSC = Kochia scoparia (kochia) CHEAL = Chenopodium album L. (common lambsquarters) AMARE = Amaranthus retroflexus (pigweed) MATCH = Matricaria chamomilla (wild chamomile) CIRAR = Cirsium arvense (Canadian thistle) Example 9

[0188] Compositions comprising Compound A and mesosulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including winter rape (BRSNW, Brassica napus), wild buckwheat (POLCO, Polygonum convolvulus), wild mustard (SINAR, Sinapis arvensis), Russian thistle (SASKR, Salsola kali), kochia (KCHSC, Kochia scoparia), common lambsquarters (CHEAL, Chenopodium album L.), pigweed (AMARE, Amaranthus retroflexus), wild chamomile (MATCH, Matricaria chamomilla), and Canadian thistle (CIRAR, Cirsium arvense). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0189] The results are summarized in Table 9 below. Table 9. Herbicidal Effects (% visual injury) of Compound A and Mesosulfuron on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Mesosulfuron00333TRZAS 00000HORVS 00181518BRSNW 35431009899POLCO 7893208083SINAR 889098100100SASKR 6063156870KCHSC 636306563CHEAL 8893309188AMARE 7873789395MATCH 2030153545CIRAR 3040788081g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) BRSNW = Brassica napus (winter rape) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) SASKR = Salsola kali (Russian thistle) KCHSC = Kochia scoparia (kochia) CHEAL = Chenopodium album L. (common lambsquarters) AMARE = Amaranthus retroflexus (pigweed) MATCH = Matricaria chamomilla (wild chamomile) CIRAR = Cirsium arvense (Canadian thistle) Example 10

[0190] Compositions comprising Compound A and metsulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including winter rape (BRSNW, Brassica napus), wild buckwheat (POLCO, Polygonum convolvulus), wild mustard (SINAR, Sinapis arvensis), Russian thistle (SASKR, Salsola kali), kochia (KCHSC, Kochia scoparia), common lambsquarters (CHEAL, Chenopodium album L.), pigweed (AMARE, Amaranthus retroflexus), wild chamomile (MATCH, Matricaria chamomilla), and Canadian thistle (CIRAR, Cirsium arvense). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0191] The results are summarized in Table 10 below. Table 10. Herbicidal Effects (% visual injury) of Compound A and Metsulfuron on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Metsulfuron001.51.51.5TRZAS 00000HORVS 00050BRSNW 354399100100POLCO 7893788490SINAR 889099100100SASKR 6063989599KCHSC 6363588290CHEAL 889393100100AMARE 787398100100MATCH 2030789090CIRAR 3040859798g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) BRSNW = Brassica napus (winter rape) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) SASKR = Salsola kali (Russian thistle) KCHSC = Kochia scoparia (kochia) CHEAL = Chenopodium album L. (common lambsquarters) AMARE = Amaranthus retroflexus (pigweed) MATCH = Matricaria chamomilla (wild chamomile) CIRAR = Cirsium arvense (Canadian thistle) Example 11

[0192] Compositions comprising Compound A and tribenuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including winter rape (BRSNW, Brassica napus), wild buckwheat (POLCO, Polygonum convolvulus), wild mustard (SINAR, Sinapis arvensis), Russian thistle (SASKR, Salsola kali), kochia (KCHSC, Kochia scoparia), common lambsquarters (CHEAL, Chenopodium album L.), pigweed (AMARE, Amaranthus retroflexus), wild chamomile (MATCH, Matricaria chamomilla), and Canadian thistle (CIRAR, Cirsium arvense). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0193] The results are summarized in Table 11 below. Table 11. Herbicidal Effects (% visual injury) of Compound A and Tribenuron on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Tribenuron007.57.57.5TRZAS 00000HORVS 00000BRSNW 3543909797POLCO 7893658075SINAR 88909396100SASKR 6063989395KCHSC 6363788889CHEAL 8893959799AMARE 7873508898MATCH 2030788390CIRAR 3040889292g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) BRSNW = Brassica napus (winter rape) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) SASKR = Salsola kali (Russian thistle) KCHSC = Kochia scoparia (kochia) CHEAL = Chenopodium album L. (common lambsquarters) AMARE = Amaranthus retroflexus (pigweed) MATCH = Matricaria chamomilla (wild chamomile) CIRAR = Cirsium arvense (Canadian thistle) Example 12

[0194] Compositions comprising Compound A and halosulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), winter rape (BRSNW, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring barley (HORVS) and spring wheat (TRZAS), and the phytotoxicity of the compositions on each crop was measured.

[0195] The results are summarized in Table 12 below. Table 12. Herbicidal Effects (% visual injury) of Compound A and Halosulfuron on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Halosulfuron008.758.758.75AMARE Obs7090959696Exp---99100△-3-4BRSNW Obs636888100100Exp---9596△54CHEAL Obs7078109590Exp---7380△2210CIRAR Obs1830407075Exp---5158△2017KCHSC Obs6570157080Exp---7075△06MATCH Obs1830788888Exp---8184△63POLCO Obs6070637883Exp---8589Δ-8-6SINAR Obs8588959810Exp---9999△-21HORVS Obs00005Exp---00△05TRZAS Obs00000Exp---00△00g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNW = Brassica napus (winter rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) HORVS = Hordeum vulgare (spring barley) TRZAS = Triticum aestivum (spring wheat) Example 13

[0196] Compositions comprising Compound A and sulfosulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), winter rape (BRSNW, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring barley (HORVS) and spring wheat (TRZAS), and the phytotoxicity of the compositions on each crop was measured.

[0197] The results are summarized in Table 13 below. Table 13. Herbicidal Effects (% visual injury) of Compound A and Sulfosulfuron on weed and grain crops. Compound A7.51007.510Application rate (g / ha) Sulfosulfuron00140140140AMARE Obs70908888100Exp---9699△-91BRSNW Obs636898100100Exp---9999△11CHEAL Obs7078439088Exp---8387△70CIRAR Obs1830457375Exp---5562△1814KCHSC Obs657088083Exp---6872△1210MATCH Obs1830738083Exp---7781△32POLCO Obs6070838883Exp---9395△-6-12SINARObs858899100100Exp---100100△00HORVS Obs002880Exp---2828△-20-28TRZAS Obs00000Exp---00△00g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNW = Brassica napus (winter rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) HORVS = Hordeum vulgare (spring barley) TRZAS = Triticum aestivum (spring wheat) Example 14

[0198] Compositions comprising Compound A and amidosulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), winter rape (BRSNW, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0199] The results are summarized in Table 14 below. Table 14. Herbicidal Effects (% visual injury) of Compound A and Amidosulfuron on weed and grain crops. Application rate (g / ha) Compound A7.5101507.51015Amidosulfuron00045454545AMARE Obs73758010010010098Exp----100100100△00-3BRSNW Obs63457398989593Exp----999999△-2-4-7CHEAL Obs78788525838580Exp----838389△-12-9CIRAR Obs25335518637373Exp----384463△242810KCHSC Obs6868685757880Exp----696969△6811MATCH Obs20454550506075Exp----607373△-10-133POLCO Obs88988855738585Exp----949994△-22-14-9SINAR Obs93939382989998Exp----999999△-10-1TRZAS Obs0000000Exp----000△000HORVS Obs0000000Exp----000△000g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNW = Brassica napus (winter rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) Example 15

[0200] Compositions comprising Compound A and iodosulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), winter rape (BRSNW, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0201] The results are summarized in Table 15 below. Table 15. Herbicidal Effects (% visual injury) of Compound A and Iodosulfuron on weed and grain crops. Application rate (g / ha) Compound A7.5101507.51015Iodosulfuron0003.753.753.753.75AMARE Obs737580989898100Exp----9999100△-2-20BRSNW Obs63457398969699Exp----999999△-3-3-1CHEAL Obs78788590939189Exp----989899△-5-7-10CIRAR Obs25335585959697Exp----899093△664KCHSC Obs68686870889085Exp----909090△-30-5MATCH Obs20454585889093Exp----889292△-1-21POLCO Obs88988885958394Exp----9810098△-3-17-4SINAR Obs9393931001096100Exp----100100100△0-40TRZAS Obs0000000Exp----000△000HORVS Obs0000000Exp----000△000g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNW = Brassica napus (winter rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) Example 16

[0202] Compositions comprising Compound A and mesosulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), winter rape (BRSNW, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0203] The results are summarized in Table 16 below. Table 16. Herbicidal Effects (% visual injury) of Compound A and Mesosulfuron on weed and grain crops. Application rate (g / ha) Compound A7.5101507.51015Mesosulfuron0009999AMARE Obs737580100989598Exp----100100100△-3-5-3BRSNW Obs63457395969999Exp----989799△-210CHEAL Obs78788548858385Exp----888892Δ-3-6-7CIRAR Obs25335573859393Exp----798188△6115KCHSC Obs68686813737373Exp----727272△111MATCH Obs20454545352535Exp----567070△-21-45-35POLCO Obs88988828969695Exp----919891△5-24SINAR Obs9393939410010098Exp----100100100△00-2TRZAS Obs0000000Exp----000△000HORVS Obs00010131318Exp----101010△338g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNW = Brassica napus (winter rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) Example 17

[0204] Compositions comprising Compound A and metsulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), winter rape (BRSNW, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0205] The results are summarized in Table 17 below. Table 17. Herbicidal Effects (% visual injury) of Compound A and Metsulfuron on weed and grain crops. Application rate (g / ha) Compound A7.5101507.51015Metsulfuron0003333AMARE Obs73758010098100100Exp----100100100Δ-300BRSNW Obs634573909990100Exp----969597△2-53CHEAL Obs78788598989595Exp----9999100△-2-4-5CIRAR Obs25335585969696Exp----899093△763KCHSC Obs68686875888892Exp----929292△-4-40MATCH Obs20454596958595Exp----979898△-2-13-3POLCO Obs88988885939090Exp----9810098△-6-10-8SINAR Obs939393881009898Exp----999999△1-2-2TRZAS Obs0000000Exp----000△000HORVS Obs0000005Exp----000△005g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNW = Brassica napus (winter rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) Example 18

[0206] Compositions comprising Compound A and tribenuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), winter rape (BRSNW, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0207] The results are summarized in Table 18 below. Table 18. Herbicidal Effects (% visual injury) of Compound A and Tribenuron on weed and grain crops. Application rate (g / ha) Compound A7.5101507.51015Tribenuron00015151515AMARE Obs7375801001008893Exp----100100100△0-13-8BRSNW Obs63457399949797Exp----9999100Δ-6-2-3CHEAL Obs787885969799100Exp----999999△-2-11CIRAR Obs25335589889490Exp----929395△-41-5KCHSC Obs68686850849895Exp----848484△01411MATCH Obs20454587899588Exp----899393△02-5POLCO Obs88988878909593Exp----979997△-7-4-5SINAR Obs93939395989999Exp----100100100△-2-1-1TRZAS Obs0003000Exp----333△-3-3-3HORVS Obs0000000Exp----000△000g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNW = Brassica napus (winter rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) Example 19

[0208] Compositions comprising Compound A and propoxycarbazone were tested to determine the efficacy of the compositions on undesirable vegetation species, including spring rape (BRSNN, Brassica napus), wild buckwheat (POLCO, Polygonum convolvulus), Russian thistle (SASKR, Salsola kali), kochia (KCHSC, Kochia scoparia), common lambsquarters (CHEAL, Chenopodium album L.), and wild chamomile (MATCH, Matricaria chamomilla). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0209] The results are summarized in Table 19 below. Table 19. Herbicidal Effects (% visual injury) of Compound A and Propoxycarbazone on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Propoxycarbazone00202020TRZAS Obs00000Exp---00△00HORVS Obs80485553Exp---5148△45BRSNN Obs556096100100Exp---9898△22POLCO Obs70780100100Exp---7078△3023SASKR Obs4560208583Exp---5668△2915KCHSC Obs5058137883Exp---5663△2120CHEAL Obs7083108588Exp---7384△123MATCH Obs131553850Exp---1719△2131g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) BRSNN = Brassica napus (spring rape) POLCO = Polygonum convolvulus (wild buckwheat) SASKR = Salsola kali (Russian thistle) KCHSC = Kochia scoparia (kochia) CHEAL = Chenopodium album L. (common lambsquarters) MATCH = Matricaria chamomilla (wild chamomile) Example 20

[0210] Compositions comprising Compound A and flurcarbazone were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), winter rape (BRSNW, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0211] The results are summarized in Table 20 below. Table 20. Herbicidal Effects (% visual injury) of Compound A and Flurcarbazone on weed and grain crops. Application rate (g / ha) Compound A7.5101507.51015Flurcarbazone00030303030AMARE Obs73758098939095Exp----9999100△-7-9-5BRSNW Obs63457383949193Exp----939095△01-3CHEAL Obs78788510787883Exp----808087△-2-2-4CIRAR Obs25335528486868Exp----465167△2160KCHSC Obs68686825757578Exp----767676△-1-12MATCH Obs20454518101830Exp----345555△-24-37-25POLCO Obs88988888919593Exp----9810098△-7-5-6SINAR Obs939393889410097Exp----999999△-61-2TRZAS Obs000010310Exp----000△10310HORVS Obs00020403843Exp----202020△201823g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNW = Brassica napus (winter rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) Example 21

[0212] Compositions comprising Compound A and propoxycarbazone were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), winter rape (BRSNW, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0213] The results are summarized in Table 21 below. Table 21. Herbicidal Effects (% visual injury) of Compound A and Propoxycarbazone on weed and grain crops. Application rate (g / ha) Compound A7.5101507.51015Propoxycarbazone00040404040AMARE Obs73758095919599Exp----999999△-8-4-1BRSNW Obs6345731001009999Exp----100100100△0-2-2CHEAL Obs78788538738078Exp----868691△-13-6-13CIRAR Obs25335568657383Exp----767885△-11-6-3KCHSC Obs68686818908083Exp----737373△1779MATCH Obs20454528153535Exp----426060△-27-25-25POLCO Obs889888893100100Exp----889888△4212SINAR Obs9393939696100100Exp----100100100△-400TRZAS Obs0008000Exp----888△-8-8-8HORVS Obs00090589058Exp----909090△-33-30-33g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNW = Brassica napus (winter rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) Example 22

[0214] Compositions comprising Compound A and thiencarbazone were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), winter rape (BRSNW, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0215] The results are summarized in Table 22 below. Table 22. Herbicidal Effects (% visual injury) of Compound A and Thiencarbazone on weed and grain crops. Application rate (g / ha) Compound A7.5101507.51015Thiencarbazone00010101010AMARE Obs7375809810010098Exp----9999100△11-2BRSNW Obs634573989810099Exp----999999△-21-1CHEAL Obs78788583858588Exp----969697△-11-11-10CIRAR Obs25335545657075Exp----596375△670KCHSC Obs68686845838385Exp----828282△003MATCH Obs20454580808890Exp----848989△-4-21POLCO Obs88988895969896Exp----9910099△-3-2-3SINAR Obs9393939010010093Exp----999999△11-7TRZAS Obs0000000Exp----000△000HORVS Obs0008101310Exp----888△353g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNW = Brassica napus (winter rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) Example 23

[0216] Compositions comprising Compound A and cloransulam were tested to determine the efficacy of the compositions on undesirable vegetation species, including spring rape (BRSNN, Brassica napus), wild buckwheat (POLCO, Polygonum convolvulus), wild mustard (SINAR, Sinapis arvensis), Russian thistle (SASKR, Salsola kali), kochia (KCHSC, Kochia scoparia), pigweed (AMARE, Amaranthus retroflexus), common lambsquarters (CHEAL, Chenopodium album L.), and wild chamomile (MATCH, Matricaria chamomilla). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0217] The results are summarized in Table 23 below. Table 23. Herbicidal Effects (% visual injury) of Compound A and Cloransulam on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Cloransulam0017.517.517.5TRZAS Obs00000Exp---00△00HORVS Obs8015258Exp---2115△4-8BRSNN Obs5560100100100Exp---100100△00POLCO Obs70788098100Exp---9496△45SINAR Obs889297100100Exp100100△00SASKR Obs4560257373Exp---5970△143KCHSC Obs505806368Exp---5058△1310AMARE Obs1001001593100Exp100100△-80CHEAL Obs708308389Exp---7083△137MATCH Obs1315405363Exp---4849△514g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) BRSNN = Brassica napus (spring rape) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) SASKR = Salsola kali (Russian thistle) KCHSC = Kochia scoparia (kochia) AMARE = Amaranthus retroflexus (pigweed) CHEAL = Chenopodium album L. (common lambsquarters) MATCH = Matricaria chamomilla (wild chamomile) Example 24

[0218] Compositions comprising Compound A and diclosulam were tested to determine the efficacy of the compositions on undesirable vegetation species, including spring rape (BRSNN, Brassica napus), wild buckwheat (POLCO, Polygonum convolvulus), wild mustard (SINAR, Sinapis arvensis), Russian thistle (SASKR, Salsola kali), kochia (KCHSC, Kochia scoparia), pigweed (AMARE, Amaranthus retroflexus), common lambsquarters (CHEAL, Chenopodium album L.), and wild chamomile (MATCH, Matricaria chamomilla). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0219] The results are summarized in Table 24 below. Table 24. Herbicidal Effects (% visual injury) of Compound A and Diclosulam on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Diclosulam0017.517.517.5TRZAS Obs00000Exp---00△00HORVS Obs80503Exp---125△-12-3BRSNN Obs5560100100100Exp---100100△00POLCO Obs7078989395Exp---9999△-7-4SINAR Obs8892100100100Exp100100△00SASKR Obs4560256573Exp---5970△63KCHSC Obs505807580Exp---5058△2523AMARE Obs10010085100100Exp100100△00CHEAL Obs708308588Exp---7083△155MATCH Obs1315684785Exp---7272△-2513g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) BRSNN = Brassica napus (spring rape) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) SASKR = Salsola kali (Russian thistle) KCHSC = Kochia scoparia (kochia) AMARE = Amaranthus retroflexus (pigweed) CHEAL = Chenopodium album L. (common lambsquarters) MATCH = Matricaria chamomilla (wild chamomile) Example 25

[0220] Compositions comprising Compound A and penoxsulam were tested to determine the efficacy of the compositions on undesirable vegetation species, including barnyard grass (ECHCG, Echinochloa crus-galli), small-flower flatsedge (CYPDI, Cyperus difformis), and broadleaf signalgrass (BRAPP, Brachiaria platyphylla).

[0221] The results are summarized in Table 25 below. Table 25. Herbicidal Effects (% visual injury) of Compound A and Penoxsulam on weeds. Application rate (g / ha) Compound A7.51007.510Penoxsulam00202020ECHCG Obs8085608783Exp---9294△-5-11CYPDI Obs6072175775Exp---6776△-10-1BRAPP Obs4368328793Exp---6178△2515g / ha = grams per hectare ECHCG = Echinochloa crus-galli (bamyardgrass) CYPDI = Cyperus difformis (small-flower flatsedge) BRAPP = Brachiaria platyphylla (broadleaf signalgrass) Example 26

[0222] Compositions comprising Compound A and florasulam were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), winter rape (BRSNW, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0223] The results are summarized in Table 26 below. Table 26. Herbicidal Effects (% visual injury) of Compound A and Florasulam on weed and grain crops. Application rate (g / ha) Compound A7.5101507.51015Florasulam0003.753.753.753.75AMARE Obs7375801001009598Exp----100100100△0-5-3BRSNW Obs63457395949696Exp----989799△-5-1-3CHEAL Obs7878850787883Exp----787885△00-3CIRAR Obs25335568757894Exp----767885△-1-19KCHSC Obs68686870757883Exp----909090△-15-13-8MATCH Obs20454585909393Exp----889292△211POLCO Obs88988890969696Exp----9910099△-3-4-3SINAR Obs939393859510098Exp----999999△-41-1TRZAS Obs0000000Exp----000△000HORVS Obs0000000Exp----000△000g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNW = Brassica napus (winter rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) Example 27

[0224] Compositions comprising Compound A and pyroxsulam were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), winter rape (BRSNW, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0225] The results are summarized in Table 27 below. Table 27. Herbicidal Effects (% visual injury) of Compound A and Pyroxsulam on weed and grain crops. Application rate (g / ha) Compound A7.5101507.51015Pyroxsulam00015151515AMARE Obs7375809810098100Exp----9999100△1-21BRSNW Obs63457368939395Exp----888291△5104CHEAL Obs78788573807585Exp----949496△-14-19-11CIRAR Obs25335548706873Exp----616576△93-4KCHSC Obs68686855787878Exp----858585△-8-8-8MATCH Obs20454553483343Exp----627474△-15-41-31POLCO Obs88988894979797Exp----9910099△-2-3-2SINAR Obs939393731009896Exp----989898△20-2TRZAS Obs0000000Exp----000△000HORVS Obs0000380Exp----000△380g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNW = Brassica napus (winter rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) Example 28

[0226] Compositions comprising Compound A and flumetsulam were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), winter rape (BRSNW, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), Russian thistle (SASKR, Salsola kali), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0227] The results are summarized in Table 28 below. Table 28. Herbicidal Effects (% visual injury) of Compound A and Flumetsulam on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Flumetsulam004.3754.3754.375AMARE Obs9085989898Exp---100100△-2-2BRSNW Obs3540406875Exp---6164△711CHEAL Obs7580458380Exp---8689△-4-9CIRAR Obs405556565Exp---4357△228KCHSC Obs707058083Exp---7272△911MATCH Obs1020838588Exp---8486△12POLCO Obs304356065Exp---3445△2720SASKR Obs606307073Exp---6063△1010SINAR Obs8388508893Exp---9194△-4-1TRZAS Obs00000Exp---00△00HORVS Obs00000Exp---00△00g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNW = Brassica napus (winter rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SASKR = Salsola kali (Russian thistle) SINAR = Sinapis arvensis (wild mustard) TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) Example 29

[0228] Compositions comprising Compound A and bispyribac were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), winter rape (BRSNW, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0229] The results are summarized in Table 29 below. Table 29. Herbicidal Effects (% visual injury) of Compound A and Pyroxsulam on weed and grain crops. Application rate (g / ha) Compound A7.5101507.51015Bispyrabac00020202020AMARE Obs7375801009596100Exp----100100100△-5-40BRSNW Obs634573100999999Exp----100100100△-2-2-2CHEAL Obs7878850788085Exp----787885△030CIRAR Obs25335568949594Exp----767885△18179KCHSC Obs68686810707578Exp----717171△-147MATCH Obs20454523152565Exp----385757△-23-328POLCO Obs88988896999799Exp----100100100△-1-3-1SINAR Obs93939396100100100Exp----100100100△000TRZAS Obs0000000Exp----000△000HORVS Obs00013050Exp----131313△-13-8-13g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNW = Brassica napus (winter rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) Example 30

[0230] Compositions comprising Compound A and imazamethabenz were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), winter rape (BRSNW, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0231] The results are summarized in Table 30 below. Table 30. Herbicidal Effects (% visual injury) of Compound A and Imazamethabenz on weed and grain crops. Application rate (g / ha) Compound A7.5101507.51015Imazamethabenz000200200200200AMARE Obs7375805787073Exp----747681△4-6-9BRSNW Obs63457353858896Exp----827487△3149CHEAL Obs7878850758078Exp----787885△-33-8CIRAR Obs2533555636573Exp----293657△342915KCHSC Obs6868680707373Exp----686868△355MATCH Obs2045455202058Exp----244848△-4-2810POLCO Obs88988888959699Exp----9810098△-3-40SINAR Obs93939375959589Exp----989898△-3-3-10TRZAS Obs0000000Exp----000△000HORVS Obs0000000Exp----000△000g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNW = Brassica napus (winter rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) Example 31

[0232] Compositions comprising Compound A and imazapic were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), winter rape (BRSNW, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), Russian thistle (SASKR, Salsola kali), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0233] The results are summarized in Table 31 below. Table 31. Herbicidal Effects (% visual injury) of Compound A and Imazapic on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Imazapic00353535AMARE Obs9085100100100Exp---100100△00BRSNW Obs3540989898Exp---9899△-1-1CHEAL Obs7580789095Exp---9496△-4-1CIRAR Obs4055687378Exp---8185△-8-8KCHSC Obs7070809696Exp---9494△22MATCH Obs1020688580Exp---7174△146POLCO Obs3043636575Exp---7478△-9-3SASKR Obs6063359390Exp---7476△1914SINAR Obs8388919898Exp---9899△-1-1TRZAS Obs00906368Exp---9090△-28-23HORVS Obs00908088Exp---9090△-10-3g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNW = Brassica napus (winter rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SASKR = Salsola kali (Russian thistle) SINAR = Sinapis arvensis (wild mustard) TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) Example 32

[0234] Compositions comprising Compound B and florasulam were tested to determine the efficacy of the compositions on undesirable vegetation species, including winter rape (BRSNW, Brassica napus), turnip (BRSRR, Brassica rapa), wild chamomile (MATCH, Matricaria chamomilla), and pineapple weed (MATMT, Matricaria discoidea).

[0235] The results are summarized in Table 32 below. Table 32. Herbicidal Effects (% visual injury) of Compound B and Florasulam on weeds. Application rate (g / ha) Compound B10001010Florasulam02.552.55BRSNW Obs93303510099Exp---9595△54BRSRR Obs857095100100Exp---9699△51MATCH Obs20302070100Exp---4436△2664MATMT Obs207565100100Exp---8072△2028g / ha = grams per hectare BRSNW = Brassica napus (winter rape) BRSRR = Brassica rapa (turnip) MATCH = Matricaria chamomilla (wild chamomile) MATMT = Matricaria discoidea (pineapple weed) Example 34

[0236] Compositions comprising Compound B and iodosulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including kochia (KCHSC, Kochia scoparia) and pigweed (AMARE, Amaranthus retroflexus). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0237] The results are summarized in Table 34 below. Table 34. Herbicidal Effects (% visual injury) of Compound B and Iodosulfuron on weed and grain crops. Application rate (g / ha) Compound B7.51007.510Iodosulfuron002.52.52.5TRZAS Obs00000Exp---00△00HORVS Obs00000Exp---00△00KCHSC Obs6365208391Exp---7072△1319AMARE Obs758485100100Exp---9698△42g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) KCHSC = Kochia scoparia (kochia) AMARE = Amaranthus retroflexus (pigweed) Example 35

[0238] Compositions comprising Compound B and mesosulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including wild buckwheat (POLCO, Polygonum convolvulus) and wild chamomile (MATCH, Matricaria chamomilla). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0239] The results are summarized in Table 35 below. Table 35. Herbicidal Effects (% visual injury) of Compound B and Mesosulfuron on weed and grain crops. Application rate (g / ha) Compound B7.51007.510Mesosulfuron00333TRZAS Obs00000Exp---00△00HORVS Obs0015188Exp---1515△3-8POLCO Obs709738378Exp---7197△12-20MATCH Obs2018102343Exp---2826△-617g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) POLCO = Polygonum convolvulus (wild buckwheat) MATCH = Matricaria chamomilla (wild chamomile) Example 36

[0240] Compositions comprising Compound B and imazamethabenz were tested to determine the efficacy of the compositions on undesirable vegetation species, including Canadian thistle (CIRAR, Cirsium arvense), Russian thistle (SASKR, Salsola kali), and common lambsquarters (CHEAL, Chenopodium album L). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0241] The results are summarized in Table 36 below. Table 36. Herbicidal Effects (% visual injury) of Compound B and Imazamethabenz on weed and grain crops. Application rate (g / ha) Compound B7.51007.510Imazamethabenz00100100100TRZAS Obs00000Exp---00△00HORVS Obs80005Exp---00△05CIRAR Obs182552828Exp---2229△6-1SASKR Obs5363136565Exp---5867△7-2CHEAL Obs859409590Exp---8594△10-4g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) CIRAR = Cirsium arvense (Canadian thistle) SASKR = Salsola kali (Russian thistle) CHEAL = Chenopodium album L. (common lambsquarters) Example 37

[0242] Compositions comprising Compound B and bensulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), kochia (KCHSC, Kochia scoparia), chickweed (STEME, Stellaria media), wild pansy (VIOTR, Viola tricolor), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), large crabgrass (DIGSA, Digitaria sanguinalis), wild buckwheat (POLCO, Polygonum convolvulus), and broad-leaf dock (RUMOB, Rumex obtusifolius). The compositions were also tested on spring wheat (TRZAS), and the phytotoxicity of the compositions on this crop was measured.

[0243] The results are summarized in Table 37 below. Table 37. Herbicidal Effects (% visual injury) of Compound B and Bensulfuron on weed and grain crops. Application rate (g / ha) Compound B5100510Bensulfuron00161616AMARE Obs939420100100Exp---9495△65KCHSC Obs6065206570Exp---6872△-3-2STEME Obs8595898100Exp---8695△115VIOTR Obs201881310Exp---2624△-14-14CHEAL Obs9696109095Exp---9696△-6-1CIRAR Obs5060205555Exp---6068△-5-13DIGSA Obs506303545Exp---5063△-15-18POLCO Obs8887808390Exp---9897△-15-7RUMOB Obs2318606870Exp---6967△-23TRZAS Obs13208020Exp---1926△-19-6g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) KCHSC = Kochia scoparia (kochia) STEME = Stellaria media (chickweed) VIOTR = Viola tricolor (wild pansy) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) DIGSA = Digitaria sanguinalis (large crabgrass) POLCO = Polygonum convolvulus (wild buckwheat) RUMOB = Rumex obtusifolius (broad-leaf dock) TRZAS = Triticum aestivum (spring wheat) Example 38

[0244] Compositions comprising Compound B and flupyrsulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), kochia (KCHSC, Kochia scoparia), chickweed (STEME, Stellaria media), wild pansy (VIOTR, Viola tricolor), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), large crabgrass (DIGSA, Digitaria sanguinalis), wild buckwheat (POLCO, Polygonum convolvulus), and broad-leaf dock (RUMOB, Rumex obtusifolius). The compositions were also tested on spring wheat (TRZAS), and the phytotoxicity of the compositions on this crop was measured.

[0245] The results are summarized in Table 38 below. Table 38. Herbicidal Effects (% visual injury) of Compound B and Flupyrsulfuron on weed and grain crops. Application rate (g / ha) Compound B5100510Flupyrsulfuron00101010AMARE Obs939497100100Exp---100100△00KCHSC Obs6065308085Exp---7276△810STEME Obs85958010099Exp---9799△3-1VIOTR Obs201882530Exp---2624△-16CHEAL Obs9696639591Exp---9999△-4-8CIRAR Obs5060849085Exp---9294△-2-9DIGSA Obs5063058Exp---5063△-45-55POLCO Obs8887919485Exp---9999△-5-14RUMOB Obs2318706870Exp---7775△-9-5TRZAS Obs132015230Exp---2632△-3-32g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) KCHSC = Kochia scoparia (kochia) STEME = Stellaria media (chickweed) VIOTR = Viola tricolor (wild pansy) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) DIGSA = Digitaria sanguinalis (large crabgrass) POLCO = Polygonum convolvulus (wild buckwheat) RUMOB = Rumex obtusifolius (broad-leaf dock) TRZAS = Triticum aestivum (spring wheat) Example 39

[0246] Compositions comprising Compound B and propoxycarbazone were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), kochia (KCHSC, Kochia scoparia), chickweed (STEME, Stellaria media), wild pansy (VIOTR, Viola tricolor), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), large crabgrass (DIGSA, Digitaria sanguinalis), wild buckwheat (POLCO, Polygonum convolvulus), and broad-leaf dock (RUMOB, Rumex obtusifolius). The compositions were also tested on spring wheat (TRZAS), and the phytotoxicity of the compositions on this crop was measured.

[0247] The results are summarized in Table 39 below. Table 39. Herbicidal Effects (% visual injury) of Compound B and Propoxycarbazone on weed and grain crops. Application rate (g / ha) Compound B5100510Propoxycarbazone00202020AMARE Obs93949093100Exp---9999△-61KCHSC Obs6065608085Exp---8486△-4-1STEME Obs85958810097Exp---9899△2-3VIOTR Obs2018152030Exp---3230△-120CHEAL Obs9696809683Exp---9999△-3-17CIRAR Obs5060686870Exp---8487△-16-17DIGSA Obs50630515Exp---5063△-45-48POLCO Obs888709395Exp---8887△59RUMOB Obs2318737065Exp---7977△-9-12TRZAS Obs1320353828Exp---4348△-6-21g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) KCHSC = Kochia scoparia (kochia) STEME = Stellaria media (chickweed) VIOTR = Viola tricolor (wild pansy) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) DIGSA = Digitaria sanguinalis (large crabgrass) POLCO = Polygonum convolvulus (wild buckwheat) RUMOB = Rumex obtusifolius (broad-leaf dock) TRZAS = Triticum aestivum (spring wheat) Example 40

[0248] Compositions comprising Compound B and pyriminobac methyl were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), kochia (KCHSC, Kochia scoparia), chickweed (STEME, Stellaria media), wild pansy (VIOTR, Viola tricolor), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), large crabgrass (DIGSA, Digitaria sanguinalis), wild buckwheat (POLCO, Polygonum convolvulus), and broad-leaf dock (RUMOB, Rumex obtusifolius). The compositions were also tested on spring wheat (TRZAS), and the phytotoxicity of the compositions on this crop was measured.

[0249] The results are summarized in Table 40 below. Table 40. Herbicidal Effects (% visual injury) of Compound B and Pyriminobac methyl on weed and grain crops. Application rate (g / ha) Compound B5100510Pyriminobac methyl00303030AMARE Obs93949310097Exp---99100△1-3KCHSC Obs6065337885Exp---7376△5-1STEME Obs85951510099Exp---8796△133VIOTR Obs201852818Exp---2422△4-4CHEAL Obs9696209694Exp---9797△-1-3CIRAR Obs506086065Exp---5463△62DIGSA Obs506306063Exp---5063△101POLCO Obs8887808893Exp---9897△-10-5RUMOB Obs2318656365Exp---7371△-10-6TRZAS Obs132001315Exp---1320△0-5g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) KCHSC = Kochia scoparia (kochia) STEME = Stellaria media (chickweed) VIOTR = Viola tricolor (wild pansy) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) DIGSA = Digitaria sanguinalis (large crabgrass) POLCO = Polygonum convolvulus (wild buckwheat) RUMOB = Rumex obtusifolius (broad-leaf dock) TRZAS = Triticum aestivum (spring wheat) Example 41

[0250] Compositions comprising Compound B and halosulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including velvetleaf (ABUTH, Abutilon theophrasti), pigweed (AMARE, Amaranthus retroflexus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), soybean (GLXMA, Glycine max), common sunflower (HELAN, Helianthus annuus), ivyleaf morningglory (IPOHE, Ipomoea hederacea), kochia (KCHSC, Kochia scoparia), wild buckwheat (POLCO, Polygonum convolvulus), broad-leaf dock (RUMOB, Rumex obtusifolius), chickweed (STEME, Stellaria media), and wild pansy (VIOTR, Viola tricolor).

[0251] The results are summarized in Table 41 below. Table 41. Herbicidal Effects (% visual injury) of Compound B and Halosulfuron on weeds. Application rate (g / ha) Compound B7.51007.510Halosulfuron008.758.758.75ABUTH Obs4568959395Exp---9798△-5-3AMARE Obs6073407888Exp---7684△24CHEAL Obs809309893Exp---8093△180CIRAR Obs1855103870Exp---2660△1211GLXMA Obs6873788595Exp---9394△-81HELAN Obs98100100100100Exp---100100△00IPOHE Obs00000Exp---00△00KCHSC Obs657308390Exp---6573△1818POLCO Obs759059395Exp---7691△165RUMOB Obs101501335Exp---1015△320STEME Obs589005588Exp---5890△-3-3VIOTR Obs38152020Exp---1721△3-1g / ha = grams per hectare ABUTH = Abutilon theophrasti (velvetleaf) AMARE = Amaranthus retroflexus (pigweed) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) GLXMA = Glycine max (soybean)KCHSC = Kochia scoparia (kochia) HELAN = Helianthus annuus (common sunflower) IPOHE = Ipomoea hederacea (ivyleaf morningglory) KCHSC = Kochia scoparia (kochia) POLCO = Polygonum convolvulus (wild buckwheat) RUMOB = Rumex obtusifolius (broad-leaf dock) STEME = Stellaria media (chickweed) VIOTR = Viola tricolor (wild pansy) Example 42

[0252] Compositions comprising Compound B and sulfosulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including velvetleaf (ABUTH, Abutilon theophrasti), pigweed (AMARE, Amaranthus retroflexus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), soybean (GLXMA, Glycine max), common sunflower (HELAN, Helianthus annuus), ivyleaf morningglory (IPOHE, Ipomoea hederacea), kochia (KCHSC, Kochia scoparia), wild buckwheat (POLCO, Polygonum convolvulus), broad-leaf dock (RUMOB, Rumex obtusifolius), chickweed (STEME, Stellaria media), and wild pansy (VIOTR, Viola tricolor).

[0253] The results are summarized in Table 42 below. Table 42. Herbicidal Effects (% visual injury) of Compound B and Sulfosulfuron on weeds. Application rate (g / ha) Compound B7.51007.510Sulfosulfuron008.758.758.75ABUTH Obs4568305360Exp---6277△-9-17AMARE Obs6073409098Exp---7684△1414CHEAL Obs809308385Exp---8093△3-8CIRAR Obs185555575Exp---2257△3318GLXMA Obs6873859590Exp---9596△0-6HELAN Obs9810010010090Exp---100100△0-10IPOHE Obs007898100Exp---7878△2023KCHSC Obs657308888Exp---6573△2315POLCO Obs759059395Exp---7691△165RUMOB Obs101501010Exp---1015△0-5STEME Obs589053100100Exp---8095△205VIOTR Obs38553860Exp---5658△-192g / ha = grams per hectare ABUTH = Abutilon theophrasti (velvetleaf) AMARE = Amaranthus retroflexus (pigweed) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) GLXMA = Glycine max (soybean)KCHSC = Kochia scoparia (kochia) HELAN = Helianthus annuus (common sunflower) IPOHE = Ipomoea hederacea (ivyleaf morningglory) KCHSC = Kochia scoparia (kochia) POLCO = Polygonum convolvulus (wild buckwheat) RUMOB = Rumex obtusifolius (broad-leaf dock) STEME = Stellaria media (chickweed) VIOTR = Viola tricolor (wild pansy) Example 43

[0254] Compositions comprising Compound A and amidosulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including spring rape (BRSNN, Brassica napus), wild pansy (VIOTR, Viola tricolor), kochia (KCHSC, Kochia scoparia and Canadian thistle (CIRAR, Cirsium arvense). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0255] The results are summarized in Table 43 below. Table 43. Herbicidal Effects (% visual injury) of Compound A and Amidosulfuron on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Amidosulfuron0022.522.522.5TRZAS Obs00000Exp---00△00HORVS Obs00000Exp---00△00BRSNN Obs557398100100Exp---9999△11VIOTR Obs1523183050Exp---3036△014KCHSC Obs6068156580Exp---6672△-18CIRAR Obs1543154063Exp---2851△1211g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) BRSNN = Brassica napus (spring rape) VIOTR = Viola tricolor (wild pansy) KCHSC = Kochia scoparia (kochia) CIRAR = Cirsium arvense (Canadian thistle) Example 44

[0256] Compositions comprising Compound A and bensulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including Russian thistle (SASKR, Salsola kali), kochia (KCHSC, Kochia scoparia), common lambsquarters (CHEAL, Chenopodium album L.), and wild chamomile (MATCH, Matricaria chamomilla). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0257] The results are summarized in Table 44 below. Table 44. Herbicidal Effects (% visual injury) of Compound A and Bensulfuron on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Bensulfuron00161616TRZAS Obs00000Exp---00△00HORVS Obs80850Exp---148△-9-8SASKR Obs456006870Exp---4560△2310KCHSC Obs505857578Exp---5360△2318CHEAL Obs7083108388Exp---7384△103MATCH Obs1315385348Exp---4547△71g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) SASKR = Salsola kali (Russian thistle) KCHSC = Kochia scoparia (kochia) CHEAL = Chenopodium album L. (common lambsquarters) MATCH = Matricaria chamomilla (wild chamomile) Example 45

[0258] Compositions comprising Compound A and flupyrsulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including Russian thistle (SASKR, Salsola kali), kochia (KCHSC, Kochia scoparia), common lambsquarters (CHEAL, Chenopodium album L.), and wild chamomile (MATCH, Matricaria chamomilla). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0259] The results are summarized in Table 45 below. Table 45. Herbicidal Effects (% visual injury) of Compound A and Flupyrsulfuron on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Flupyrsulfuron00101010TRZAS Obs00000Exp---00△00HORVS Obs808015Exp---148△-148SASKR Obs4560458085Exp---7078△107KCHSC Obs5058159490Exp---5864△3726CHEAL Obs7083759695Exp---9396△4-1MATCH Obs1315839094Exp---8585△59g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) SASKR = Salsola kali (Russian thistle) KCHSC = Kochia scoparia (kochia) CHEAL = Chenopodium album L. (common lambsquarters) MATCH = Matricaria chamomilla (wild chamomile) Example 46

[0260] Compositions comprising Compound A and nicosulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including large crabgrass (DIGSA, Digitaria sanguinalis), wild oat (AVEFA, Avena fatua), annual ryegrass (LOLMG = Lolium multiflorum subsp. gaudini), giant foxtail (SETFA, Setaria faberi), and nutsedge (CYPES, Cyperus esculentus).

[0261] The results are summarized in Table 46 below. Table 46. Herbicidal Effects (% visual injury) of Compound A and Nicosulfuron on weeds. Application rate (g / ha) Compound A7.51007.510Nicosulfuron00202020DIGSA Obs00658083Exp---6565△1518AVEFA Obs00969999Exp---66△33LOLMG Obs0396100100Exp---9696△44SETFA Obs0010010099Exp---100100△0-2CYPES Obs4045407068Exp---6467△61g / ha = grams per hectare DIGSA = Digitaria sanguinalis (large crabgrass) AVEFA = Avena fatua (wild oat) LOLMG = Lolium multiflorum subsp. gaudini (annual ryegrass) SETFA = Setaria faberi (giant foxtail) CYPES = Cyperus esculentus (nutsedge) Example 47

[0262] Compositions comprising Compound A and imazamox were tested to determine the efficacy of the compositions on undesirable vegetation species, including wild pansy (VIOTR, Viola tricolor) and Canadian thistle (CIRAR, Cirsium arvense).

[0263] The results are summarized in Table 47 below. Table 47. Herbicidal Effects (% visual injury) of Compound A and Imazamox on weeds. Application rate (g / ha) Compound A7.51007.510Imazamox0017.517.517.5VIOTR Obs1523758085Exp---7981△14CIRAR Obs1543638893Exp---6878△1914g / ha = grams per hectare VIOTR = Viola tricolor (wild pansy) CIRAR = Cirsium arvense (Canadian thistle) Example 48

[0264] Compositions comprising Compound A and imazapyr were tested to determine the efficacy of the compositions on undesirable vegetation species, including wild pansy (VIOTR, Viola tricolor), kochia (KCHSC, Kochia scoparia), and Canadian thistle (CIRAR, Cirsium arvense).

[0265] The results are summarized in Table 48 below. Table 48. Herbicidal Effects (% visual injury) of Compound A and Imazapyr on weeds. Application rate (g / ha) Compound A7.51007.510Imazapyr00140140140VIOTR Obs1523637383Exp---6871△412KCHSC Obs6068549999Exp---8185△1714CIRAR Obs1543808589Exp---8389△20g / ha = grams per hectare VIOTR = Viola tricolor (wild pansy) KCHSC = Kochia scoparia (kochia) CIRAR = Cirsium arvense (Canadian thistle) Example 49

[0266] Compositions comprising Compound A and imazethapyr were tested to determine the efficacy of the compositions on undesirable vegetation species, including kochia (KCHSC, Kochia scoparia), Russian thistle (SASKR, Salsola kali), common lambsquarters (CHEAL, Chenopodium album L.), wild chamomile (MATCH, Matricaria chamomilla), and Canadian thistle (CIRAR, Cirsium arvense).

[0267] The results are summarized in Table 49 below. Table 49. Herbicidal Effects (% visual injury) of Compound A and Imazethapyr on weeds. Application rate (g / ha) Compound A7.51007.510Imazethapyr00353535KCHSC Obs5055538089Exp---7679△410SASKR Obs3863408885Exp---6378△258CHEAL Obs6090288993Exp---7193△180MATCH Obs033186360Exp---1844△4516CIRAR Obs1023406055Exp---4654△142g / ha = grams per hectare KCHSC = Kochia scoparia (kochia) SASKR = Salsola kali (Russian thistle) CHEAL = Chenopodium album L. (common lambsquarters) MATCH = Matricaria chamomilla (wild chamomile) CIRAR = Cirsium arvense (Canadian thistle) Example 50

[0268] Compositions comprising Compound A and pyriminobac were tested to determine the efficacy of the compositions on undesirable vegetation species, including spring rape (BRSNN, Brassica napus), wild mustard (SINAR, Sinapis arvensis), kochia (KCHSC, Kochia scoparia), Russian thistle (SASKR, Salsola kali), common lambsquarters (CHEAL, Chenopodium album L.), wild chamomile (MATCH, Matricaria chamomilla), and Canadian thistle (CIRAR, Cirsium arvense). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0269] The results are summarized in Table 50 below. Table 50. Herbicidal Effects (% visual injury) of Compound A and Pyriminobac on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Pyriminobac0017.517.517.5TRZAS Obs00000Exp---00△00HORVS Obs00000Exp---00△00BRSNN Obs557008083Exp---5570△2513SINAR Obs85905100100Exp---8691△1410KCHSC Obs505506565Exp5055△1510SASKR Obs386307580Exp---3863△3818CHEAL Obs609059093Exp---6291△282MATCH Obs03357981Exp536△7445CIRAR Obs102305050Exp---1023△4028g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) BRSNN = Brassica napus (spring rape) SINAR = Sinapis arvensis (wild mustard) KCHSC = Kochia scoparia (kochia) SASKR = Salsola kali (Russian thistle) CHEAL = Chenopodium album L. (common lambsquarters) MATCH = Matricaria chamomilla (wild chamomile) CIRAR = Cirsium arvense (Canadian thistle) Example 51

[0270] Compositions comprising Compound A and pyriftalid were tested to determine the efficacy of the compositions on undesirable vegetation species, including spring rape (BRSNN, Brassica napus), wild mustard (SINAR, Sinapis arvensis), Russian thistle (SASKR, Salsola kali), kochia (KCHSC, Kochia scoparia), and wild chamomile (MATCH, Matricaria chamomilla). The compositions were also tested on spring wheat (TRZAS) and spring barley (HORVS), and the phytotoxicity of the compositions on each crop was measured.

[0271] The results are summarized in Table 51 below. Table 51. Herbicidal Effects (% visual injury) of Compound A and Pyriftalid on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Pyriftalid00303030TRZAS Obs00000Exp---00△00HORVS Obs805813Exp---125△-58BRSNN Obs5560187370Exp---6367△103SINAR Obs8892239798Exp---9093△74SASKR Obs456006568Exp---4560△208KCHSC Obs505806570Exp---5058△1513MATCH Obs131503045Exp1315△1830g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) BRSNN = Brassica napus (spring rape) SINAR = Sinapis arvensis (wild mustard) SASKR = Salsola kali (Russian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) Example 52

[0272] Compositions comprising Compound A, mesosulfuron, and iodosulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including large crabgrass (DIGSA, Digitaria sanguinalis), annual ryegrass (LOLMG = Lolium multiflorum subsp. gaudini), and giant foxtail (SETFA, Setaria faberi).

[0273] The results are summarized in Table 52 below. Table 52. Herbicidal Effects (% visual injury) of Compound A, Mesosulfuron, and Iodosulfuron on weeds. Application rate (g / ha) Compound A7.51007.510Mesosulfuron002.12.12.1Iodosulfuron000.40.40.4DIGSA Obs000200Exp---00△200LOLMG Obs03889096Exp---8888△38SETFA Obs00638589Exp---6363△2327g / ha = grams per hectare DIGSA = Digitaria sanguinalis (large crabgrass) LOLMG = Lolium multiflorum subsp. gaudini (annual ryegrass) SETFA = Setaria faberi (giant foxtail) Example 53

[0274] Compositions comprising Compound A, mesosulfuron, and iodosulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including velvetleaf (ABUTH, Abutilon theophrasti), wild buckwheat (POLCO, Polygonum convolvulus), poinsettia (EPHHL, Euphorbia heterophylla), and kochia (KCHSC, Kochia scoparia).

[0275] The results are summarized in Table 53 below. Table 53. Herbicidal Effects (% visual injury) of Compound A, Mesosulfuron, and Iodosulfuron on weeds. Application rate (g / ha) Compound A7.51007.510Mesosulfuron002.12.12.1Iodosulfuron000.40.40.4ABUTH Obs4048738091Exp---8486△-45POLCO Obs687006080Exp---6870△-810EPHHL Obs9183609397Exp---9693△-44KCHSC Obs636558585Exp---6467△2118g / ha = grams per hectare ABUTH = Abutilon theophrasti (velvetleaf) POLCO = Polygonum convolvulus (wild buckwheat) EPHHL = Euphorbia heterophylla (poinsettia) KCHSC = Kochia scoparia (kochia) Example 54

[0276] Compositions comprising Compound A, florasulam, and pyroxsulam were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), winter rape (BRSNW, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring barley (HORVS) and spring wheat (TRZAS), and the phytotoxicity of the compositions on each crop was measured.

[0277] The results are summarized in Table 54 below. In the table, an application rate of "X+Y" indicates that the application rate of florasulam is "X" and pyroxsulam is "Y." Table 54. Herbicidal Effects (% visual injury) of Compound A and Florasulam + Pyroxsulam on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Florasulam + Pyroxsulam003.75 + 103.75 + 103.75 + 10AMARE Obs7090100100100Exp---100100△00BRSNW Obs6368100100100Exp---100100△00CHEAL Obs7078969698Exp---9999△-3-2CIRAR Obs1830689093Exp---7377△1715KCHSC Obs6570739595Exp---9092△53MATCH Obs1830789094Exp---8184△910POLCO Obs6070889393Exp---9596△-3-4SINAR Obs8588989999Exp---100100△-1-1HORVS Obs00435068Exp---4343△825TRZAS Obs00000Exp---00△00g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNW = Brassica napus (winter rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SINAR = Sinapis arvensis (wild mustard) TRZAS = Triticum aestivum (spring wheat) HORVS = Hordeum vulgare (spring barley) Example 55

[0278] Compositions comprising Compound A, florasulam, and pyroxsulam were tested to determine the efficacy of the compositions on undesirable vegetation species, including pigweed (AMARE, Amaranthus retroflexus), spring rape (BRSNN, Brassica napus), common lambsquarters (CHEAL, Chenopodium album L.), Canadian thistle (CIRAR, Cirsium arvense), kochia (KCHSC, Kochia scoparia), wild chamomile (MATCH, Matricaria chamomilla), wild buckwheat (POLCO, Polygonum convolvulus), Russian thistle (SASKR, Salsola kali), and wild mustard (SINAR, Sinapis arvensis). The compositions were also tested on spring barley (HORVS) and spring wheat (TRZAS), and the phytotoxicity of the compositions on each crop was measured.

[0279] The results are summarized in Table 55 below. In the table, an application rate of "X+Y" indicates that the application rate of florasulam is "X" and pyroxsulam is "Y." Table 55. Herbicidal Effects (% visual injury) of Compound A and Florasulam + Pyroxsulam on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Florasulam + Pyroxsulam003.75 + 103.75 + 103.75 + 10AMARE Obs100100100100100Exp---100100△00BRSNN Obs5555100100100Exp---100100△00CHEAL Obs8388809496Exp---9798△-3-2CIRAR Obs1820839093Exp---8686△47KCHSC Obs55651810098Exp---6371△3727MATCH Obs2013708393Exp---7674△719POLCO Obs939110010099Exp---100100△0-2SASKR Obs63659699100Exp---9999△01SINAR Obs100100100100100Exp---100100△00HORVS Obs00354025Exp---3535△5-10TRZAS Obs00000Exp---00△00g / ha = grams per hectare AMARE = Amaranthus retroflexus (pigweed) BRSNN = Brassica napus (spring rape) CHEAL = Chenopodium album L. (common lambsquarters) CIRAR = Cirsium arvense (Canadian thistle) KCHSC = Kochia scoparia (kochia) MATCH = Matricaria chamomilla (wild chamomile) POLCO = Polygonum convolvulus (wild buckwheat) SASKR = Salsola kali (Russian thistle) SINAR = Sinapis arvensis (wild mustard) HORVS = Hordeum vulgare (spring barley) TRZAS = Triticum aestivum (spring wheat) Example 56

[0280] Compositions comprising Compound A (with the safener mefenpyr-diethyl instead of cloquintocet-mexyl), mesosulfuron, iodosulfuron, and thiencarbazone were tested to determine the efficacy of the compositions on undesirable vegetation species, including wild pansy (VIOTR, Viola tricolor), chickweed (STEME, Stellaria media), Canadian thistle (CIRAR, Cirsium arvense), broad-leaf dock (RUMOB, Rumex obtusifolius), spring rape (BRSNN, Brassica napus), kochia (KCHSC, Kochia scoparia), common sunflower (HELAN, Helianthus annuus), soybean (GLXMA, Glycine max), common lambsquarters (CHEAL, Chenopodium album L.), ivyleaf morningglory (IPOHE, Ipomoea hederacea), velvetleaf (ABUTH, Abutilon theophrasti), wild buckwheat (POLCO, Polygonum convolvulus), pigweed (AMARE, Amaranthus retroflexus), large crabgrass (DIGSA, Digitaria sanguinalis), giant foxtail (SETFA, Setaria faberi), blackgrass (ALOMY, Alopecurus myosuroides), Italian ryegrass (LOLMU, Lolium multiflorum), nutsedge (CYPES, Cyperus esculentus), grain sorghum (SORVU, Sorghum vulgare), wild oat (AVEFA, Avena fatua), and barnyard grass (ECHCG, Echinochloa crus-galli),. The compositions were also tested on rice (ORYSA, Oryza sativa), spring wheat (TRZAS), and maize (ZEAMX, Zea mays), and the phytotoxicity of the compositions on each crop was measured

[0281] The results are summarized in Table 56 below. In the table, an application rate of "X+Y+Z" indicates that the application rate of mesosulfuron is "X," iodosulfuron is "Y," and thiencarbazone is "Z." Table 56. Herbicidal Effects (% visual injury) of Compound A and Mesosulfuron + Iodosulfuron + Thiencarbazone on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Mesosulfuron + Iodosulfuron + Thiencarbazone009 + 9 + 7.59+9 + 7.59+9 + 7.5VIOTR Obs1018859393Exp---8788△65STEME Obs8883100100100Exp---100100△00CIRAR Obs28438399100Exp---8790△1110RUMOB Obs2020100100100Exp---100100△00BRSNN Obs7078100100100Exp---100100△00KCHSC Obs6870858596Exp---9596△-101HELAN Obs10098100100100Exp---100100△00GLXMA Obs959597100100Exp---100100△00CHEAL Obs1001001009999Exp---100100△-2-2IPOHE Obs859910098Exp---9999△1-1ABUTH Obs6873959696Exp---9899△-2-3POLCO Obs1001007098100Exp---100100△-30AMARE Obs9398100100100Exp---100100△00DIGSA Obs1310819395Exp---8383△912SETFA Obs7880959796Exp---9999△-2-3ALOMY Obs013979899Exp---9797△11LOLMU Obs510100100100Exp---100100△00CYPES Obs1528658378Exp---7075△123SORVU Obs51098100100Exp---9898△22AVEFA Obs009810099Exp---9898△21ECHCG Obs8885959899Exp---9999△-2-1ORYSA Obs35508080Exp---5153△2928TRZAS Obs03005Exp---03△03ZEAMX Obs05888588Exp---8888△-3-1g / ha = grams per hectare VIOTR = Viola tricolor (wild pansy) STEME = Stellaria media (chickweed) CIRAR = Cirsium arvense (Canadian thistle) RUMOB = Rumex obtusifolius (broad-leaf dock) BRSNN = Brassica napus (spring rape) KCHSC = Kochia scoparia (kochia) HELAN = Helianthus annuus (common sunflower) GLXMA = Glycine max (soybean) CHEAL = Chenopodium album L. (common lambsquarters) IPOHE = Ipomoea hederacea (ivyleaf morningglory) ABUTH = Abutilon theophrasti (velvetleaf) POLCO = Polygonum convolvulus (wild buckwheat) AMARE = Amaranthus retroflexus (pigweed) DIGSA = Digitaria sanguinalis (large crabgrass) SETFA = Setaria faberi (giant foxtail) ALOMY = Alopecurus myosuroides (blackgrass) LOLMU = Lolium multiflorum (Italian ryegrass) CYPES = Cyperus esculentus (nutsedge) SORVU = Sorghum vulgare (grain sorghum) AVEFA = Avena fatua (wild oat) ECHCG = Echinochloa crus-galli (barnyardgrass) ORYSA = Oryza sativa (common rice) TRZAS = Triticum aestivum (spring wheat) ZEAMX = Zea mays (maize) Example 57

[0282] Compositions comprising Compound A (with the safener mefenpyr-diethyl instead of cloquintocet-mexyl), amidosulfuron, and iodosulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including wild pansy (VIOTR, Viola tricolor), chickweed (STEME, Stellaria media), Canadian thistle (CIRAR, Cirsium arvense), broad-leaf dock (RUMOB, Rumex obtusifolius), spring rape (BRSNN, Brassica napus), kochia (KCHSC, Kochia scoparia), common sunflower (HELAN, Helianthus annuus), soybean (GLXMA, Glycine max), common lambsquarters (CHEAL, Chenopodium album L.), ivyleaf morningglory (IPOHE, Ipomoea hederacea), velvetleaf (ABUTH, Abutilon theophrasti), wild buckwheat (POLCO, Polygonum convolvulus), pigweed (AMARE, Amaranthus retroflexus), large crabgrass (DIGSA, Digitaria sanguinalis), giant foxtail (SETFA, Setaria faberi), blackgrass (ALOMY, Alopecurus myosuroides), Italian ryegrass (LOLMU, Lolium multiflorum), nutsedge (CYPES, Cyperus esculentus), grain sorghum (SORVU, Sorghum vulgare), wild oat (AVEFA, Avena fatua), and barnyard grass (ECHCG, Echinochloa crus-galli),. The compositions were also tested on rice (ORYSA, Oryza sativa), spring wheat (TRZAS), and maize (ZEAMX, Zea mays), and the phytotoxicity of the compositions on each crop was measured

[0283] The results are summarized in Table 57 below. In the table, an application rate of "X+Y" indicates that the application rate of amidosulfuron is "X" and iodosulfuron is "Y." Table 57. Herbicidal Effects (% visual injury) of Compound A and Amidosulfuron + Iodosulfuron on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Amidosulfuron + Iodosulfuron0025 + 2525 + 2525 + 25VIOTR Obs1018737870Exp---7577△2-7STEME Obs8883100100100Exp---100100△-10CIRAR Obs2843689590Exp---7681△199RUMOB Obs2020909898Exp---9292△66BRSNN Obs70789899100Exp---9999△-11KCHSC Obs6870308888Exp---7779△109HELAN Obs1009899100100Exp---100100△00GLXMA Obs959595100100Exp---100100△00CHEAL Obs1001008810093Exp---100100△0-8IPOHE Obs85839391Exp---8483△98ABUTH Obs6873889595Exp---9697△-1-2POLCO Obs100100738893Exp---100100△-13-8AMARE Obs939898100100Exp---100100△00DIGSA Obs13100105Exp---1310△-3-5SETFA Obs788008085Exp---7880△35ALOMY Obs013000Exp---013△0-13LOLMU Obs510637583Exp---6466△1116CYPES Obs1528606858Exp---6671△2-14SORVU Obs510088Exp---510△3-3AVEFA Obs00050Exp---00△50ECHCG Obs888507085Exp---8885△-180ORYSA Obs35055Exp---35△30TRZAS Obs03000Exp---03△0-3ZEAMX Obs05000Exp---05△0-5g / ha = grams per hectare VIOTR = Viola tricolor (wild pansy) STEME = Stellaria media (chickweed) CIRAR = Cirsium arvense (Canadian thistle) RUMOB = Rumex obtusifolius (broad-leaf dock) BRSNN = Brassica napus (spring rape) KCHSC = Kochia scoparia (kochia) HELAN = Helianthus annuus (common sunflower) GLXMA = Glycine max (soybean) CHEAL = Chenopodium album L. (common lambsquarters) IPOHE = Ipomoea hederacea (ivyleaf morningglory) ABUTH = Abutilon theophrasti (velvetleaf) POLCO = Polygonum convolvulus (wild buckwheat) AMARE = Amaranthus retroflexus (pigweed) DIGSA = Digitaria sanguinalis (large crabgrass) SETFA = Setaria faberi (giant foxtail) ALOMY = Alopecurus myosuroides (blackgrass) LOLMU = Lolium multiflorum (Italian ryegrass) CYPES = Cyperus esculentus (nutsedge) SORVU = Sorghum vulgare (grain sorghum) AVEFA = Avena fatua (wild oat) ECHCG = Echinochloa crus-galli (bamyardgrass) ORYSA = Oryza sativa (common rice) TRZAS = Triticum aestivum (spring wheat) ZEAMX = Zea mays (maize) Example 58

[0284] Compositions comprising Compound A (with the safener mefenpyr-diethyl instead of cloquintocet-mexyl), mesosulfuron, iodosulfuron, and amidosulfuron were tested to determine the efficacy of the compositions on undesirable vegetation species, including wild pansy (VIOTR, Viola tricolor), chickweed (STEME, Stellaria media), Canadian thistle (CIRAR, Cirsium arvense), broad-leaf dock (RUMOB, Rumex obtusifolius), spring rape (BRSNN, Brassica napus), kochia (KCHSC, Kochia scoparia), common sunflower (HELAN, Helianthus annuus), soybean (GLXMA, Glycine max), common lambsquarters (CHEAL, Chenopodium album L.), ivyleaf morningglory (IPOHE, Ipomoea hederacea), velvetleaf (ABUTH, Abutilon theophrasti), wild buckwheat (POLCO, Polygonum convolvulus), pigweed (AMARE, Amaranthus retroflexus), large crabgrass (DIGSA, Digitaria sanguinalis), giant foxtail (SETFA, Setaria faberi), blackgrass (ALOMY, Alopecurus myosuroides), Italian ryegrass (LOLMU, Lolium multiflorum), nutsedge (CYPES, Cyperus esculentus), grain sorghum (SORVU, Sorghum vulgare), wild oat (AVEFA, Avena fatua), and barnyard grass (ECHCG, Echinochloa crus-galli),. The compositions were also tested on rice (ORYSA, Oryza sativa), spring wheat (TRZAS), and maize (ZEAMX, Zea mays), and the phytotoxicity of the compositions on each crop was measured

[0285] The results are summarized in Table 58 below. In the table, an application rate of "X+Y+Z" indicates that the application rate of mesosulfuron is "X," iodosulfuron is "Y," and amidosulfurone is "Z." Table 58. Herbicidal Effects (% visual injury) of Compound A and Mesosulfuron + Iodosulfuron + Amidosulfuron on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Mesosulfuron + Iodosulfuron + Amidosulfurone009+3 + 159+3 + 159+3 + 15VIOTR Obs1018808889Exp---8284△66STEME Obs888310098100Exp---100100△-3-1CIRAR Obs2843809996Exp---8689△138RUMOB Obs202010010098Exp---100100△0-3BRSNN Obs7078100100100Exp---100100△00KCHSC Obs6870788996Exp---9393△-43HELAN Obs10098100100100Exp---100100△00GLXMA Obs959596100100Exp---100100△00CHEAL Obs1001009910098Exp---100100△0-3IPOHE Obs8588100100Exp---8888△1212ABUTH Obs6873989896Exp---9999△-1-3POLCO Obs100100789893Exp---100100△-3-8AMARE Obs93989399100Exp---99100△-10DIGSA Obs131002023Exp---1310△813SETFA Obs7880909385Exp---9898△-5-13ALOMY Obs013969699Exp---9697△02LOLMU Obs510969799Exp---9696△12CYPES Obs1528638078Exp---6873△125SORVU Obs51096100100Exp---9696△44AVEFA Obs0096100100Exp---9696△44ECHCG Obs8885458378Exp---9392△-11-14ORYSA Obs35404525Exp---4243△4-18TRZAS Obs03000Exp---03△0-3ZEAMX Obs05758585Exp---7576△109g / ha = grams per hectare VIOTR = Viola tricolor (wild pansy) STEME = Stellaria media (chickweed) CIRAR = Cirsium arvense (Canadian thistle) RUMOB = Rumex obtusifolius (broad-leaf dock) BRSNN = Brassica napus (spring rape) KCHSC = Kochia scoparia (kochia) HELAN = Helianthus annuus (common sunflower) GLXMA = Glycine max (soybean) CHEAL = Chenopodium album L. (common lambsquarters) IPOHE = Ipomoea hederacea (ivyleaf morningglory) ABUTH = Abutilon theophrasti (velvetleaf) POLCO = Polygonum convolvulus (wild buckwheat) AMARE = Amaranthus retroflexus (pigweed) DIGSA = Digitaria sanguinalis (large crabgrass) SETFA = Setaria faberi (giant foxtail) ALOMY = Alopecurus myosuroides (blackgrass) LOLMU = Lolium multiflorum (Italian ryegrass) CYPES = Cyperus esculentus (nutsedge) SORVU = Sorghum vulgare (grain sorghum) AVEFA = Avena fatua (wild oat) ECHCG = Echinochloa crus-galli (bamyardgrass) ORYSA = Oryza sativa (common rice) TRZAS = Triticum aestivum (spring wheat) ZEAMX = Zea mays (maize) Example 59

[0286] Compositions comprising Compound A (with the safener mefenpyr-diethyl instead of cloquintocet-mexyl), iodosulfuron, and propoxycarbazone were tested to determine the efficacy of the compositions on undesirable vegetation species, including wild pansy (VIOTR, Viola tricolor), chickweed (STEME, Stellaria media), Canadian thistle (CIRAR, Cirsium arvense), broad-leaf dock (RUMOB, Rumex obtusifolius), spring rape (BRSNN, Brassica napus), kochia (KCHSC, Kochia scoparia), common sunflower (HELAN, Helianthus annuus), soybean (GLXMA, Glycine max), common lambsquarters (CHEAL, Chenopodium album L.), ivyleaf morningglory (IPOHE, Ipomoea hederacea), velvetleaf (ABUTH, Abutilon theophrasti), wild buckwheat (POLCO, Polygonum convolvulus), pigweed (AMARE, Amaranthus retroflexus), large crabgrass (DIGSA, Digitaria sanguinalis), giant foxtail (SETFA, Setaria faberi), blackgrass (ALOMY, Alopecurus myosuroides), Italian ryegrass (LOLMU, Lolium multiflorum), nutsedge (CYPES, Cyperus esculentus), grain sorghum (SORVU, Sorghum vulgare), wild oat (AVEFA, Avena fatua), and barnyard grass (ECHCG, Echinochloa crus-galli),. The compositions were also tested on rice (ORYSA, Oryza sativa), spring wheat (TRZAS), and maize (ZEAMX, Zea mays), and the phytotoxicity of the compositions on each crop was measured

[0287] The results are summarized in Table 59 below. In the table, an application rate of "X+Y" indicates that the application rate of iodosulfuron is "X" and propoxycarbazone is "Y." Table 59. Herbicidal Effects (% visual injury) of Compound A and Iodosulfuron + Propoxycarbazone on weed and grain crops. Application rate (g / ha) Compound A7.51007.510Iodosulfuron + Propoxycarbazone003 + 50.43+ 50.43+ 50.4VIOTR Obs1018787880Exp---8081△-2-1STEME Obs88839898100Exp---100100△-20CIRAR Obs2843989595Exp---9899△-3-4RUMOB Obs20209294100Exp---9494△06BRSNN Obs707810010098Exp---100100△0-3KCHSC Obs6870489396Exp---8384△1012HELAN Obs10098100100100Exp---100100△00GLXMA Obs959595100100Exp---100100△00CHEAL Obs1001009295100Exp---100100△-50IPOHE Obs8594100100Exp---9494△66ABUTH Obs6873859396Exp---959...

Claims

1. A composition, comprising: (a) a pyridine carboxylate herbicide which is cyanomethyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate: or propargyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate: or an agriculturally acceptable N-oxide, or salt thereof; (b) an acetolactate synthase (ALS) inhibitor or an agriculturally acceptable salt or ester thereof; and (c) a safener.

2. The composition of claim 1, wherein the ALS inhibitor is selected from the group consisting of triazolopyrimidines sulfonamide herbicides, imidazolinone herbicides, pyrimidinyl oxybenzoate herbicides, sulfonylaminocarbonyl triazolinone herbicides, sulfonylurea herbicides, and combinations thereof.

3. The composition of claim 2, wherein the ALS inhibitor is selected from the group consisting of amidosulfuron, azimsulfuron, bispyribac, bensulfuron, chlorimuron, chlorsulfuron, cinosulfuron, cloransulam, cyclosulfamuron, diclosulam, ethametsulfuron, ethoxysulfuron, flazasulfuron, florasulam, flucarbazone, flucetosulfuron, flumetsulam, flupyrsulfuron, foramsulfuron, halosulfuron, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, imazosulfuron, iodosulfuron, iofensulfuron, mesosulfuron, metazosulfuron, metosulam, metsulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, penoxsulam, primisulfuron, propoxycarbazone, propyrisulfuron, prosulfuron, pyrazosulfuron, pyribenzoxim, pyriftalid, pyriminobac, pyrimisulfan, pyrithiobac, pyroxsulam, rimsulfuron, sulfometuron, sulfosulfuron, thiencarbazone, thifensulfuron, triasulfuron, tribenuron, trifloxysulfuron, triflusulfuron, tritosulfuron, agriculturally acceptable salts and esters thereof, and combinations thereof.

4. The composition of any one of claims 1-3, wherein the weight ratio of the pyridine carboxylate herbicide (in g ae / ha) to the ALS inhibitor (in g ai / ha) is from about 1:3400 to about 1200:1.

5. The composition of any one of claims 1-4, further comprising an additional pesticide.

6. The composition of any one of claims 1-4, wherein the composition does not include a herbicidal active ingredient in addition to (a) and (b).

7. A method of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying to soil or water to limit the emergence or growth of vegetation a composition, comprising: (a) a pyridine carboxylate herbicide which is cyanomethyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate: or propargyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate: or an agriculturally acceptable N-oxide, or salt thereof; (b) an acetolactate synthase (ALS) inhibitor or an agriculturally acceptable salt or ester thereof; and (c) a safener; wherein the pyridine carboxylate herbicide is applied in an amount of at least 0.1 g ae / ha; and wherein the ALS inhibitor is applied in an amount of at least 0.1 g ai / ha.

8. The method of claim 7, wherein the ALS inhibitor is selected from the group consisting of triazolopyrimidines sulfonamide herbicides, imidazolinone herbicides, pyrimidinyl oxybenzoate herbicides, sulfonylaminocarbonyl triazolinone herbicides, sulfonylurea herbicides, and combinations thereof, preferably selected from the group consisting of amidosulfuron, azimsulfuron, bispyribac, bensulfuron, chlorimuron, chlorsulfuron, cinosulfuron, cloransulam, cyclosulfamuron, diclosulam, ethametsulfuron, ethoxysulfuron, flazasulfuron, florasulam, flucarbazone, flucetosulfuron, flumetsulam, flupyrsulfuron, foramsulfuron, halosulfuron, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, imazosulfuron, iodosulfuron, iofensulfuron, mesosulfuron, metazosulfuron, metosulam, metsulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, penoxsulam, primisulfuron, propoxycarbazone, propyrisulfuron, prosulfuron, pyrazosulfuron, pyribenzoxim, pyriftalid, pyriminobac, pyrimisulfan, pyrithiobac, pyroxsulam, rimsulfuron, sulfometuron, sulfosulfuron, thiencarbazone, thifensulfuron, triasulfuron, tribenuron, trifloxysulfuron, triflusulfuron, tritosulfuron, agriculturally acceptable salts and esters thereof, and combinations thereof.

9. The method of any one of claims 7-8, wherein the pyridine carboxylate herbicide is provided in amount of 0.1 g ae / ha to 300 g ae / ha.

10. The method of any one of claims 7-9, wherein weight ratio of the pyridine carboxylate herbicide (in g ae / ha) to the ALS inhibitor (in g ai / ha) is from about 1:3400 to about 1200:1.

11. The method of any one of claims 7-10, further comprising applying an additional pesticide.

12. The method of any one of claims 7-10, wherein the composition does not include a herbicidal active ingredient in addition to (a) and (b).