Hydraulic binder compositions for flooring applications

Abstract

The invention a hydraulic binder composition comprising: Component a) Between 0,5 weight% and 5 weight% of Portland cement; Component b) Between 5 weight% and 30 weight% of aluminate cement; Component c) Between 5 weight% and 15 weight% of a sulfate source; Component d) Between 35 weight% and 88.5 weight% of ground granulated blast furnace slag having a d50 between 7.5 µm and 12 µm and a d85 between 19 µm and 29 µm.

Description

DescriptionTitle: HYDRAULIC BINDER COMPOSITIONS FOR FLOORING APPLICATIONSTechnical Field

[0001] This disclosure pertains to the field of hydraulic binder compositions comprising Ground Granulated Blast Furnace Slag (GGBS) for preparing industrial mortars. In particular, the technical field of the invention relates to hydraulic mineral binders including Ground Granulated Blast Furnace Slag (GGBS or slag), which are used in compositions able to set and harden, such as mortar and more specifically mortars for flooring applications like self levelling underlayment (SLU) and screed.Background Art

[0002] In order to be usable forflooring application a mortar has to harden and dry quickly. Indeed, flooring product, like SLU and screed are intended to be covered with a floor covering product such as tiles or wooden floor and workers should be able to walk on the floor to pursuit construction or renovation. In addition, to be covered with a floor covering product, the moisture level should be low.

[0003] Moreover, flooring product need to be resistant to heat, especially when an underfloor heating system is present.

[0004] To the knowledge of the applicants, industrial mortars forflooring applications commercially available comprise, as the binder, Portland cement, combined with rapid cement, like aluminate and sulphoaluminate cement and a calcium sulfate source for fulfilling the requirement of quick hardening and quick drying.

[0005] Even if these industrial mortars give satisfaction, it is a major issue to limit the emission of carbon dioxide. For instance, Portland cement production has a strong and negative impact on the environment due to the emissions of large quantities of carbon dioxide. The production of cement inherently generates CO2 during the calcination of the raw materials at very high temperature (1450°C) in a kiln through decarbonation of the limestone (Eq. (1)):CaCO3(s) — > CaO (s) + CO2(g) (Eq. (1))

[0006] In addition, carbon dioxide is released as a result of the combustion of the fossil fuels needed to heat the cement kiln. By adding the additional emissions of grinding, almost one ton of CO2 per ton of Portland cement is obtained. Overall, the cement industry is responsible for about 7 to 9% of the global carbon dioxide emissions.

[0007] Hydraulic binder compositions having low carbon impact, have been developed by replacing at least a part of Portland cement with Ground Granulated Blast Furnace Slag (GGBS), as disclosed for instance in documents WO 2017 / 198930 or WO 2019 / 110134.

[0008] However, in the field of industrial mortars for flooring application the quick drying is brought by the aluminate cement part, which also generate emission of carbon dioxide. Thus, there is a need to develop industrial mortars for flooring application in which Portland cement and aluminate cement are, at least partially, replaced by a binder having a lower carbon dioxide impact.

[0009] In this context, the invention aims at addressing at least one of the above problems and / or needs, through fulfilling at least one of the following objectives:-O1- Providing a GGBS-based binder or a mortar composition including said GGBS-based binder, which is attractive substitute to Ordinary Portland Cement (OPC) and allow to reduce aluminate cement-based in flooring compositions.-02- Providing a slag-based binder or a mortar composition including said GGBS-based binder, which is environmentally friendly.-03- Providing a slag-based binder or a mortar composition including said GGBS-based binder, which gives rise to wet formulations with appropriate rheological properties, i.e stable rheology (good workability) during the usual setting time (e.g. from some minutes to several hours) required by the users of said wet formulation.Summary

[0010] At least one of the above objectives is reached thanks to a hydraulic binder composition comprising:Component a) Between 0,5 weight% and 5 weight% of Portland cement;Component b) Between 5 weight% and 30 weight% of aluminate cement;Component c) Between 5 weight% and 15 weight% of a sulfate source;Component d) Between 35 weight% and 88.5 weight% of ground granulated blast furnace slag having a dso between 7.5 pm and 12 pm and a das between 19 pm and 29 pm.

[0011] The invention also concerns a dry industrial mortar composition, in particular mortars for flooring application, especially screed and self levelling underlayment (SLU) comprising at least one aggregate and the hydraulic binder composition mentioned above.

[0012] The invention is also directed to a wet industrial mortar formulation, in particular mortars for floor covering, especially self levelling underlayment (SLU) comprising at least one aggregate, hydraulic binder composition mentioned above and water.

[0013] The invention further concerns a hardened industrial mortar product obtained from the wet industrial mortar formulation mentioned above.

[0014] The invention is in addition directed to a process for preparing the wet industrial mortar formulation mentioned above comprising a step of mixing with water, at least one aggregate and the hydraulic binder composition mentioned above, the hydraulic binder composition being prepared before the mixing step or in situ during the mixing step from at least some of the different components of the hydraulic binder composition taken separately and / or under the form of premix(es).Definitions

[0015] According to the terminology of this text, the following non limitative definitions have to be taken into consideration:

[0016] “binder” refers to “hydraulic binder” meaning any material that hardens just by adding water, like cement.

[0017] "cement" is understood as meaning a powdery substance made for use in making mortar or concrete. They are mineral binders, possibly free from any organic compound. It refers to any ordinary cement and it includes Ordinary Portland Cement, blends of Ordinary Portland Cement, Pozzolanic materials and / or Filler and alkali-activated based cements.

[0018] “clinker” is understood as the main constituent phase of Ordinary Portland Cement obtained from the co-calcination of limestone and an aluminosilicate source.

[0019] "mortar" refers to a material composed of binder(s), aggregates such as filler, sand and other components, like admixtures.

[0020] "Dry industrial mortar composition" refers to a material composed of binder(s), aggregates such as sand and gravel and other components, like admixtures.

[0021] “Wet industrial mortar formulation” refers to a material composed of binder(s), aggregates such as sand and gravel and other components, like admixtures and water.

[0022] “Hardened industrial mortar product” refers to the hardened product obtained from wet industrial mortar composition after reaction and evaporation of the water.

[0023] "dio" gives the median size of the granulometric distribution of material’s particles (usually in micrometers for cementation materials). It means that 10% of the particles have a size less than the dio number and 90% of the particles have a size greater than the dio number. The measurement of dio is done by Laser diffraction analysis, also known as Laser diffraction spectroscopy, by means of Laser diffraction analyzer such as "SYMPATEC" and commercialized by the SYMPATEC company, with the dry way method.

[0024] "d5o" gives the median size of the granulometric distribution of material’s particles (usually in micrometers for cementation materials). It means that 50% of the particles have a size less than the dso number and 50% of the particles have a size greater than the dso number. The measurement of dso is done by Laser diffraction analysis, also known as Laser diffraction spectroscopy, by means of Laser diffraction analyzer such as "SYMPATEC" and commercialized by the SYMPATEC company, with the dry way method.

[0025] "dss" gives the median size of the granulometric distribution of material’s particles (usually in micrometers for cementation materials). It means that 85% of the particles have a size less than the das number and 15% of the particles have a size greater than the dss number. The measurement of das is done by Laser diffraction analysis, also known as Laser diffraction spectroscopy, by means of Laser diffraction analyzer such as " SYMPATEC " and commercialized by the SYMPATEC company, with the dry way method.

[0026] "dgo" gives the median size of the granulometric distribution of material’s particles (usually in micrometers for cementation materials). It means that 90% of the particles have a size less than the dgo number and 10% of the particles have a size greater than the dgo number. The measurementof dgo is done by Laser diffraction analysis, also known as Laser diffraction spectroscopy, by means of Laser diffraction analyzer such as " SYMPATEC " and commercialized by the SYMPATEC company, with the dry way method.Brief Description of DrawingsFig. 1

[0027] [Fig. 1] is a graphic representing the granulometric distribution of a GGBS used in the hydraulic binder of the invention.Detailed descriptionThe hydraulic binder composition

[0028] As mentioned above, in a first aspect, the invention concerns a hydraulic binder composition comprising:Component a) Between 0.5 weight% and 5 weight% of Portland cement;Component b) Between 5 weight% and 30 weight% of aluminate cement;Component c) Between 5 weight% and 15 weight% of a sulfate source;Component d) Between 35 weight% and 88.5 weight% of ground granulated blast furnace slag having a dso between 7.5 pm and 12 pm and a ds5 between 19 pm and 29 pm.The Portland cement

[0029] The hydraulic binder composition according to the invention comprises a component a) which is Portland cement in an amount of between 0.5 weight% and 5 weight %.

[0030] In an embodiment, the Portland cement is Ordinary Portland Cement (OPC) according to standard EN 197-1

[0031] Advantageously, the hydraulic binder composition comprises between 1 weight% and 4 weight% of Portland cement, preferably between 1 .5 weight% and 3.5 weight% and more preferably between 2 weight% and 3 weight%.The aluminate Cement

[0032] The hydraulic binder composition according to the invention comprises a component b) which is an aluminate cement in an amount of between 5 weight% and 30 weight%. Preferably, the aluminate cement is selected in the group comprising, preferably consisting of, calcium aluminate cement (CAC), calcium sulfoaluminate cement (CSA), Belite-Ye'elimite-Ferritecement (BYF) and mixtures thereof.

[0033] The calcium aluminate cement may be composed by at least one of the following crystalline form: monocalcium aluminate (CaO.ALOs), monocalcium dialuminate (CaO.2 AI2O3), monocalcium hexa-aluminate (CaO.SAhOs), dicalcium alumina silicate (2CaO.AI2O3.SiO2), tricalcium aluminate (SCaO.ALOs), dodecacalcium hepta-aluminate (12CaO. 7AI2O3), ye’elimite (4CaO.3Al2O3 SO3), calcium aluminoferrite (4CaO Al2O3 Fe2O3).

[0034] Advantageously, the hydraulic binder composition comprises between 7.5 weight% and 25 weight% of aluminate cement, preferably between 10 weight% and 20 weight%, more preferably between 12.5 weight% and 17.5 weight%.The sulfate source

[0035] The hydraulic binder composition according to the invention comprises a component c) which is a sulfate source in an amount of between 5 weight % and 15 weight %.

[0036] Preferably, the sulfate source is selected from the group comprising, preferably consisting of, calcium sulfate (CaSC ), sodium sulfate (NagSC ), potassium sulfate (K2SO4), lithium sulfate (IJ2SO4) and mixtures thereof.

[0037] When the sulfate source is calcium sulfate, it may be anhydrite, hemihydrate or dihydrate, the difference resides in molecule(s) of water bounded to calcium sulfate: anhydrite no water (CaSC ), hemihydrate contains half molecule of water (CaSC . % H2O), dihydrate, also known as gypsum, contains 2 molecules of water (CaSC . 2 H2O). According to the invention, the calcium sulfate is anhydrite calcium sulfate.

[0038] Advantageously, the hydraulic binder composition comprises between 8 weight% and 12 weight% of a sulfate source, preferably between 9 weight% and 1 1 weight%.The ground granulated blast furnace slag

[0039] The hydraulic binder composition according to the invention comprises between 35 weight% and 88.5 weight% of a component d) which is ground granulated blast furnace slag having a dso between 7.5 pm and 12 pm and a das between 19 pm and 29 pm.

[0040] Advantageously, the hydraulic binder composition comprises between 50 weight% and 80 weight% of component d), preferably between 60 weight% and 75 weight%.

[0041] In an embodiment the ground granulated blast furnace slag according to the invention has a dio between 0.5 pm and 1.7 pm.

[0042] In a preferred embodiment, the ground granulated blast furnace slag further has a dgo between 25 pm and 32 pm.

[0043] In an embodiment the ground granulated blast furnace slag has a dso between 8 pm and 10 pm.

[0044] In an embodiment the ground granulated blast furnace slag has a das between 21 pm and 25 pm.

[0045] In an embodiment the ground granulated blast furnace slag has a dgo between 27 pm and 30 pm.The dry industrial mortar composition

[0046] As mentioned above, the invention concerns in a second aspect a dry industrial mortar composition, in particular mortars for flooring application, especially screed and self levellingunderlayment (SLU) comprising at least one aggregate and the hydraulic binder composition mentioned above.

[0047] According to the invention, “dry” concrete composition or “dry” industrial mortar composition refers to composition that are in the form of powder and ready to be mixed with water. In other words, the dry concrete composition or dry industrial mortar composition of the invention may content some moisture, but it essentially contains solid components which are intended to be mixed with water before its application.

[0048] Aggregates comprise a large category of particulate material used in construction, including fillers, sands, gravels, crushed stones, slag (not-granulated), recycled concrete and geosynthetic aggregates. They serve as reinforcement to add strength to the overall composite material.

[0049] Advantageously, said dry concrete composition or dry industrial mortar composition can also include, apart from aggregates, one or several ingredients, especially functional admixtures, additions and fibres, which can be the other optional component mentioned below.Optional other components

[0050] The binder composition is advantageously enriched with one or several other components which are ingredients, notably functional additives preferably selected in the following list:• Water retention agent.

[0051] A water retention agent has the property to keep the water of mixing before the setting. The water is so trapped in the wet formulation paste which improves its bond. To some extent, the water is less absorbed by the support.

[0052] The water retentive agent is preferably chosen in the group comprising: modified celluloses, modified guars, modified cellulose ethers and / or guar ether and their mixes, more preferably consisting of: methylcelluloses, methylhydroxypropylcelluloses, methylhydroxyethyl-celluloses and their mixes.• Rheological agent

[0053] The possible rheological agent (also named a "thickener") is preferably chosen in the group comprising, more preferably consisting of: starch ethers, cellulose ethers and / or gums (e.g. Welan guar xanthane, succinoglycans), modified polysaccharides -preferably among modified starch ethers-, polyvinylic alcohols, polyacrylamides, sepiolites, and their mixes.• Defoamer / Antifoams

[0054] The possible defoamer is preferably chosen in the group comprising, more preferably consisting of: polyether polyols and mixes thereof.Biocide

[0055] The possible biocide is preferably chosen in the group comprising, more preferably consisting of: mineral oxides like zinc oxide and mixes thereof.• Pigment

[0056] The possible pigment is preferably chosen in the group comprising, more preferably consisting of: TiC>2, iron oxide and mixes thereof.• Flame retardant

[0057] Flame retardant (or flame proof agent) makes it possible to increase the fire resistance and / or to shrink the speed of flame spreading of the composition.• Air-entraining agents

[0058] Air-entraining agents (surfactants) are advantageously chosen in the group comprising, more preferably consisting of, natural resins, sulfated or sulfonated compounds, synthetic detergents, organic fatty acids and their mixes, preferably in the group comprising, more preferably consisting in the lignosulfonates, the basic soaps of fatty acids and their mixes, and, more preferably in the group comprising, more preferably consisting of, the sulfonate olefins, the sodium lauryl sulfate and their mixes.• Retarders

[0059] Retarders are advantageously chosen in the group comprising, more preferably consisting of, tartric acid and its salts: sodium or potassium salts, citric acid and its salts: sodium (trisodic citrate) and their mixes.• Accelerators

[0060] Accelerators are advantageously chosen in the group comprising, alkaline metal salts more preferably consisting of, , sodium and potassium carbonates, sodium chloride, or calcium formate, or lithium salts

[0061] In addition, other components may be:• Plasticizers• Fibres• Dispersion powders• Polymeric resins• Complexing agents• Drying shrinkage reducing agents based on polyols.

[0062] The total content of these optional other components in the dry concrete composition or dry industrial mortar composition is preferably comprised between 0.1% and 10% by weight of the total weight of the dry concrete composition or dry industrial mortar composition.The wet industrial mortar formulation

[0063] As mentioned above, the invention concerns in a third aspect a wet industrial mortar formulation, in particular mortars for floor covering, especially self levelling underlayment (SLU) comprising at least one aggregate, hydraulic binder composition mentioned above and water.The hardened industrial mortar product

[0064] As mentioned above, the invention concerns in a fourth aspect a hardened industrial mortar product obtained from the wet industrial mortar formulation mentioned above.

[0065] The wet is applied and dry and hardenThe process for preparing the wet industrial mortar formulation

[0066] As mentioned above, the invention concerns in a fifth aspect a process for preparing the wet industrial mortar formulation mentioned above comprising a step of mixing with water, at least one aggregate and the hydraulic binder composition mentioned above, the hydraulic binder composition being prepared before the mixing step or in situ during the mixing step from at least some of the different components of the hydraulic binder composition taken separately and / or under the form of premix(es).

[0067] In other words, wet concrete composition or wet industrial mortar composition could be prepared by two distinct methods.

[0068] In a first method, the binder composition is prepared, and then mixed with the at least one aggregate. The dry concrete composition or dry mortar composition is thereafter mixed with water.

[0069] In a second method, the wet concrete composition or wet industrial mortar composition is prepared by mixing in water each component of the binder composition and the aggregates.

[0070] According to the present disclosure, the term "mixing" has to be understood as any form of mixing.

[0071] In a preferred embodiment a part of the binder composition and at least a part of the water are mixed together prior to the mixing with the aggregate.

[0072] In a preferred embodiment, the process is implemented with a ratio water to binder composition comprised between 0.1 and 1.2, advantageously between 0.15 and 0.45, and more advantageously between 0.2 and 0.4.The use of the hydraulic binder composition

[0073] The invention is also directed to the use of the binder composition described above for improving the fresh state rheology, for instance fresh state yield stress and fresh state viscosity, of wet industrial mortar composition in particular for floor covering.

[0074] Advantageously, for the use according to the invention, the mortar fresh state yield stress is comprised between 0 Pa and 200 Pa, advantageously between 5 Pa and 100 Pa and more advantageously between 30 Pa and 60 Pa.

[0075] Advantageously, for the use according to the invention, the paste fresh state viscosity is comprised between 0 Pa.s and 50 Pa.s, advantageously between 15 Pa.s and 35 Pa.s and more advantageously between 20 Pa.s and 30 Pa.s.ExamplesExample 1 : Preparation of a hydraulic binder composition according to the invention and of a mortar comprising the same

[0076] A hydraulic binder composition has been prepared by mixing the different component of the same. The components and their proportions are listed in table 1 below.

[0077] [Table 1]

[0078] The GGBS used has the granulometric distribution represented at figure 1 .

[0079] This hydraulic binder composition has then been mixed with sand and filler in a proportion of 52.39 dry weight % of hydraulic binder and 47.61 dry weight % of sand. The resulting mixture has then been mixed with water at a ratio water to binder of 0.34.Example 2: adhesion and shrinkage test

[0080] The mortar obtained at example 1 has been stored at 23°C under a relative humidity of 50% for 28 days. The adhesion resistance and the shrinkage have been measured according to the standard NF EN 13813. The adhesion force measured is egual to 1 .07 MPa which is higher than the specification being 1 MPa, according to CSTB (Centre Scientifigue et Technigue du Batiment) document QB11-02 published on March 14, 2022(https: / / evaluation.cstb.fr / doc / certification / certificats / gb11 -02 / qb11-02-document-technigue-11-02-enduits-de-sol-rev01-140322.pdf). The shrinkage is of -50|jm / m which is very low, according to the standard and technical recommendations.Example 3: variation of the ratio water to binder

[0081] A hydraulic binder has been prepared in the same manner than in Example 1 , except that the water to binder ratio was 0.43. The adhesion resistance has been measured according to the standard NF EN 13813. The adhesion force measured is equal to 1.03 MPaExample 4: variation of the adhesion under different storage conditions

[0082] The mortar obtained at example 1 has been stored at 45°C, 60°C on a wet support or with a moisture recovery for 28 days according to CSTB document QB11 -02 published on March 14, 2022. In these conditions, the specification set a level of 0.8Mpa. The adhesion forces obtained are reported in table 2 below.

[0083] [Table 2]

[0084] It can be seen from table 2 that adhesion forces are all above the 0.8 MPa specification as recommended in CSTB document QB11-02 published on March 14, 2022.

Claims

Claims

1. Hydraulic binder composition comprising:Component a) Between 0,5 weight% and 5 weight% of Portland cement;Component b) Between 5 weight% and 30 weight% of aluminate cement;Component c) Between 5 weight% and 15 weight% of a sulfate source;Component d) Between 35 weight% and 88.5 weight% of ground granulated blast furnace slag having a dgo between 7.5 pm and 12 pm and a das between 19 pm and 29 pm.

2. Hydraulic binder composition according to claim 1 , wherein it comprises between 1 weight% and 4 weight% of Portland cement, preferably between 1 .5 weight% and 3.5 weight% and more preferably between 2 weight% and 3 weight%.

3. Hydraulic binder composition according to any one of the preceding claims, wherein it comprises between 7.5 weight% and 25 weight% of aluminate cement, preferably between 10 weight% and 20 weight%, more preferably between 12.5 weight% and 17.5 weight%.

4. Hydraulic binder composition according to any one of the preceding claims, wherein the aluminate cement is selected in the group comprising, preferably consisting of, calcium aluminate cement (CAC), calcium sulfoaluminate cement (CSA), Belite-Ye'elimite-Ferritecement (BYF) and mixtures thereof.

5. Hydraulic binder composition according to any one of the preceding claims, wherein it comprises between 8 weight% and 12 weight% of a sulfate source, preferably between 9 weight% and 11 weight%.

6. Hydraulic binder composition according to any one of the preceding claims, wherein the sulfate source is selected in the group comprising, preferably consisting of, calcium sulfate (CaSC ), sodium sulfate (NaoSC ), potassium sulfate (K2SO4), lithium sulfate (IJ2SO4) and mixtures thereof.

7. Hydraulic binder composition according to any one of the preceding claims, wherein it comprises between 50 weight% and 80 weight% of ground granulated blast furnace slag, preferably between 60 weight% and 75 weight%.

8. Hydraulic binder composition according to any one of the preceding claims, wherein component d) has, further has a dgo between 25 pm and 32 pm, preferably a dgo between 27 pm and 30 pm.

9. Hydraulic binder composition according to any one of the preceding claims, wherein component d) has a dgo between 8 pm and 10 pm.

10. Hydraulic binder composition according to any one of the preceding claims, wherein component d) has a das between 21 pm and 25 pm.

11. Dry industrial mortar composition, in particular mortars for flooring application, especially screed and self levelling underlayment (SLU) comprising at least one aggregate and the hydraulic binder composition according to any one of claims 1 to 10.

12. Wet industrial mortar formulation, in particular mortars for floor covering, especially self levelling underlayment (SLU) comprising at least one aggregate, the hydraulic binder composition according to any one of claims 1 to 10 and water.

13. Hardened industrial mortar product obtained from the wet industrial mortar formulation according to claim 12.

14. Process for preparing the wet industrial mortar formulation according to claim 12 comprising a step of mixing with water, at least one aggregate and the hydraulic binder composition according to any one of claims 1 to 10, the hydraulic binder composition being prepared before the mixing step or in situ during the mixing step from the different components of the hydraulic binder composition taken separately and / or under the form of premix(es).

15. Process according to claim 14, wherein the ratio water to binder composition comprised between 0.1 and 1.2, advantageously between 0.15 and 0.45, and more advantageously between 0.2 and 0.4.

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