A skincare and / or makeup composition comprising a polyphenol, a compound capable of reacting by hydrogen bonds with the polyphenol, a monoalcohol, and an antioxidant agent

Abstract

A skincare and / or makeup composition comprising a polyphenol, a compound capable of reacting by hydrogen bonds with the polyphenol, a monoalcohol, and an antioxidant. The present invention relates to a composition comprising, in particular in a physiologically acceptable medium: (1) at least one polyphenol X comprising at least two different phenol groups; and (2) at least one compound Y comprising at least two identical or different Gy functional groups capable of forming at least two hydrogen bonds with said phenol groups of polyphenol X; (3) at least one monoalcohol having from 2 to 8 carbon atoms; and (4) at least one antioxidant. It also relates to a method for coating keratinous materials, in particular skin, keratinous fibers such as eyelashes and / or eyebrows, comprising a step of applying at least one composition as defined above to said keratinous materials.

Description

Title of the invention: Care and / or makeup composition comprising a polyphenol, a compound capable of reacting by hydrogen bonds with the polyphenol, a monoalcohol and an antioxidant agent

[0001] The present invention relates to the field of care and / or makeup of keratin materials, and aims to propose compositions more particularly dedicated to makeup of the skin, in particular of the face, the eye contour, the eyelashes or the eyebrows.

[0002] Compositions dedicated to care and / or makeup are commonly used to provide beautification and / or aesthetic color to keratin materials such as the skin and areas of the face, eyelashes, eyebrows and nails.

[0003] Consumers are looking for care and / or makeup products that are stable over time and that produce, after application to the keratin material, a homogeneous deposit, pleasant sensory properties such as the perception of a very thin film and having good durability over time of the care and / or makeup effect obtained after application. The presence of polyphenols and in particular those of natural origin is particularly sought after for their beneficial properties for keratin materials such as the skin or keratin fibers such as eyelashes or eyebrows. Compositions comprising polyphenols do not give complete satisfaction in terms of stability over time because they tend to yellow or darken over time, probably due to a phenomenon of oxidation of the polyphenol.

[0004] There therefore remains a need to find new compositions for caring for and / or making up keratin materials based on polyphenols which are stable over time, produce after application to the keratin material a homogeneous deposit and pleasant sensory properties such as the perception of a very thin film, as well as good durability over time of the caring and / or make-up effect obtained after application without the disadvantages of yellowing or darkening mentioned above.

[0005] Unexpectedly, the inventors found that it is possible to achieve these objectives by using a composition comprising, in particular in a physiologically acceptable medium: 1) at least one polyphenol X comprising at least two different phenol groups, and 2) at least one non-ionic compound Y comprising at least two groups functional groups Gy, identical or different, capable of forming at least two hydrogen bonds with said phenol groups of polyphenol X; and (3) at least one mono-alcohol having from 2 to 8 carbon atoms at contents ranging from 40% to 90% by weight relative to the total weight of the composition; and (4) at least one antioxidant agent in a total amount ranging from 0.1 to 10% by weight relative to the total weight of the composition; said antioxidant agent being chosen from ascorbic acid, sodium metabisulfite, erythorbic acid, and mixtures thereof; and (5) water in an amount less than or equal to 30% by weight relative to the total weight of the composition.

[0006] The inventors have in fact discovered that the compositions of the invention were not only stable over time without observing any yellowing or darkening phenomenon but that they also produced, after application to the keratin material, a homogeneous deposit thanks to the formation of a coating agent resulting from the interaction by hydrogen bonds, at room temperature and atmospheric pressure, between the polyphenol X and the compound Y. This coating agent allowed excellent durability of the expected cosmetic effects on keratin materials, which could range from the day involving makeup removal at the end of the day, to durability over several days which is resistant to mechanical friction, water, sebum, oil, cleaning products such as shower gels, shampoos, bi-phasic products and certain micellar waters.

[0007] This discovery is the basis of the invention. Objects of the invention

[0008] Thus, a first object of the present invention is a composition comprising, preferably in a physiologically acceptable medium: ( 1) at least one polyphenol X comprising at least two different phenol groups, and 2) at least one non-ionic compound Y comprising at least two functional groups Gy, identical or different, capable of forming at least two hydrogen bonds with said phenol groups of polyphenol X; and (3) at least one mono-alcohol having from 2 to 8 carbon atoms at contents ranging from 40% to 90% by weight relative to the total weight of the composition; and (4) at least one antioxidant agent in a total amount ranging from 0.1 to 10% by weight relative to the total weight of the composition; said antioxidant agent being chosen from ascorbic acid, sodium metabisulfite, erythorbic acid, and mixtures thereof; and (5) water in an amount less than or equal to 30% by weight relative to the total weight of the composition.

[0009] A second subject of the present invention is a process for coating keratin materials comprising a step of applying to said keratin materials at least one composition as defined above. Definitions

[0010] In the context of the present invention, the term "keratin material" is understood to mean in particular skin such as the face, body, hands, cheeks, eyelids, the contour of the eyes, keratin fibers such as eyelashes, eyebrows, hairs such as those of the beard, nails. This term "keratin materials", within the meaning of the present invention, also extends to synthetic false eyelashes and false eyebrows.

[0011] By "physiologically acceptable" is meant compatible with the skin and / or its appendages, which has a pleasant color, odor and feel and which does not generate unacceptable discomfort (tingling, tightness), likely to deter the consumer from using this composition.

[0012] For the purposes of the invention, the term "hydrogen bond" means an interaction involving a hydrogen atom of one of the two reactants and an electronegative heteroatom of the other reactant such as oxygen, nitrogen, sulfur and fluorine. In the context of the invention, the hydrogen bonds are made between the hydroxyl (OH) functions of the reactive phenol groups of polyphenol X and the reactive Gy functional groups containing these electronegative heteroatoms and capable of forming hydrogen bonds with said phenol groups of polyphenol X.

[0013] By “room temperature” we mean 25°C.

[0014] By “atmospheric pressure” we mean 760 mm of Hg or 101,325 Pascals. Polyphenol

[0015] The polyphenols X which can be used according to the present invention comprise at least two different phenol groups in their structure.

[0016] By “polyphenol” is meant any compound having in its chemical structure at least two, preferably at least three phenol groups.

[0017] By "polyphenol" is meant any compound having in its chemical structure at least two benzene compounds, in free or condensed form, each benzene compound comprising at least one hydroxyl group (OH), preferably at least 2 hydroxyl groups, or even 3 hydroxyl groups.

[0018] The polyphenols that can be used according to the invention can be synthetic or natural. They can be in the isolated state or contained in a mixture, in particular contained in a plant extract. Polyphenols are phenols comprising at least two phenolic groups differently substituted on the aromatic ring.

[0019] The two classes of polyphenols are flavonoids and non-flavonoids.

[0020] Examples of flavonoids include chalcones such as phloretin, phloridzin, aspalathin or neohesperidin; flavanols such as catechin, fisetin, kaempferol, myricetin, quercetin, rutin, procyanidins, proanthocyanidins, pyroanthocyanidins, theaflavins or thearubigins (or thearubrins); dihydroflavonols such as astilbin, dihydroquercetin (taxifolin), or silibinin; flavanones such as hesperidin, neohesperidin, hesperetin, naringenin, naringin; anthocyanins such as cyanidin, delphinidin, malvidin, peonidin or petunidin; catechin tannins such as tannic acid; isoflavonoids such as daidzein, or genistein; neo-flavanoids; lignans such as pyroresorcinol; and mixtures thereof.

[0021] Among the natural polyphenols that can be used according to the invention, mention may also be made of lignins.

[0022] Examples of non-flavonoids include curcuminoids such as curcumin or tetrahydrocurcumin; stilbenoids such as astringin, resveratrol or rhaponticin; aurones such as aureusidin; and mixtures thereof.

[0023] As polyphenols which can be used according to the invention, mention may also be made of chlorogenic acid, verbascoside; coumarins substituted by phenols

[0024] According to a particular embodiment of the invention, the polyphenol will be selected from catechic tannins such as gallotannins selected from tannic acid; ellagitannins such as epigallocatechin, epigallocatechin gallate, castalagin, vescalagin, vescalin, castaline, casuarictin, castanopsins, excoecarinins, grandinin, gradin, roburines, pterocarine, telligranine, tellimane sanguiine, potentillin, pedunculin, geraniin, che-bulagic acid, sprendisinic acid, ascorgeranine, stachyurin, casuarinin, casuarinin, punicacortein, coriarin, cameliatannine, isodes, dehydrogenyl, dehydroyl galloyl, l punicalagine, les rhoipteleanines..

[0025] According to a particular embodiment of the invention, the polyphenol is epigallocatechin, in particular a green tea extract with the INCI name GREEN TEA EXTRACT, in particular comprising at least 45% of epigallocatechin relative to the total weight of said extract such as the commercial product sold under the name DERMOFEEL PHENON 90 MC® sold by the company Evonik Nutrition & Care or the commercial product sold under the name TEA POLYPHENOLS GREEN TEA EXTRACT® by the company Tayo Green Power.

[0026] According to a particular embodiment of the invention, the polyphenol is a procyanidin or a mixture of procyanidins, in particular an extract of maritime pine bark with the INCI name PINUS PINASTER BARK / BUD EXTRACT, in particular comprising at least 65% by weight of procyanidins relative to the total weight of said extract such as the commercial product sold under the name PYCNOGENOL® sold by the company BIOLANDES AROMAS.

[0027] Tannic acid will be used more particularly as polyphenol.

[0028] According to a particular embodiment, the polyphenol(s) of the invention is (are) present in an amount greater than or equal to 0.8% by weight, preferably greater than or equal to 1.0% by weight, and more particularly greater than or equal to 2.0% by weight relative to the total weight of the composition.

[0029] According to a particular embodiment, the polyphenol(s) of the invention are present in an amount ranging from 1.0 to 30.0% by weight, and more particularly ranging from 2.0 to 30% by weight relative to the total weight of the composition. Compound Y

[0030] The non-ionic Y compounds which can be used according to the invention comprise in their chemical structure at least two functional groups Gy, identical or different, capable of forming at least two hydrogen bonds with the phenol groups of the polyphenol X comprising at least two different phenols.

[0031] The non-ionic Y compounds that can be used according to the invention comprise at least two functional groups, identical or different, chosen from hydroxyl (OH), acid anhydride (R-CO-O-CO-R), ether (RrO-R2), amino (NHRiR2R3), amide (ROCNR'R”), carbamate, urethane (R-HN-(C=O) O-R'), carbamide, urea (CO(NH2)2), thiol (RSH), glyceryl, acrylate, acrylamide, vinylpyrrolidone, vinyl alcohol, vi-nylamine, vinylformamide, and mixtures thereof.

[0032] In a preferred embodiment, the molar mass of compound Y is greater than 200 g / mol, or even greater than 350 g / mol.

[0033] According to a particular embodiment, the non-ionic compound(s) Y, in the medium of the composition containing them, do not comprise an anionic group in their chemical structure.

[0034] As examples of non-ionic compounds Y capable of reacting with polyphenols X such as those indicated above, mention may be made of

[0035] (1) Glycerolated alkyl ethers such as Glyceryl Lauryl Ether.

[0036] (2) Modified or unmodified polysaccharides, preferably non-ionic. Polysaccharides The polysaccharides suitable for the invention may be homopolysaccharides such as fructans, glucans, galactans and mannans or heteropolysaccharides such as hemicellulose. They may be starchy like native or modified starches. The non-starchy polysaccharides may be chosen from polysaccharides produced by microorganisms; polysaccharides isolated from algae, polysaccharides from higher plants, such as homogeneous polysaccharides, in particular celluloses and its derivatives or fructoses, heterogeneous polysaccharides such as galactomannans, glucomannans, pectins, and their derivatives; and mixtures thereof. In particular, the polysaccharides may be chosen from fructans, glucans, amylose, amylopectin, glycogen, modified or unmodified pullulans, dextrans, celluloses and their derivatives, in particular methyl celluloses, hydroxyalkylcelluloses, ethylhydroxyethylcelluloses, cetyl hydroxyethylcelluloses, mannans, xylans, arabans, galactans, galacturonans, chitin, chitosans, glucoronoxylans, arabinoxylans, xyloglucans, glucomannans, arabinogalactans, agars, Karaya gums (acid about 40%), locust bean gums, guar gums and their non-ionic derivatives, in particular hydroxypropyl guar, biopolysaccharide gums of microbial origin, in particular scleroglucan gums. They are more particularly chosen from celluloses such as cetyl hydroxyethylcelluloses; guar gums, particularly modified ones such as hydroxypropyl guars, agarose; pullulans, inulins, starches.

[0037] According to a particular embodiment, the non-ionic polysaccharides in accordance with the invention will be different from the sugars derived from fruits or vegetables, in particular simple sugars such as glucose, sucrose, fructose and sorbitol.

[0038] (3) Non-ionic polyglycerolated alkyl ether surfactants, in particular chosen among Polyglyceryl-2-Oleyl Ether, Polyglyceryl-4-Oleyl Ether.

[0039] (4) Esters of glycerol or polyglycerol and fatty acid, optionally polyhy- droxylated, in particular chosen from Polyglyceryl-3 Polyricinoleate, Poly-glyceryl-2 Diisostearate, Polyglyceryl-4 Diisostearate, Polyglyceryl-4 Caprate, Polyglyceryl-2 Stearate, Polyglyceryl-3 Dicitrate / Stearate, Polyglyceryl-10 Dioleate, Polyglyceryl-3 Diisostearate, Polyglyceryl-2 Triisostearate, Poly-glyceryl-10 Laurate, Glyceryl Stearate Citrate, Polyglyceryl-2 Dipolyhy-droxystearate.

[0040] (5) Polyoxyethylenated or polyglycerolated waxes, in particular chosen from polyoxyethylenated ester waxes such as polyoxyethylene jojoba wax (120 EO) (INCI name: Jojoba Wax PEG-120 Esters), PEG-8 Beeswax, PEG-60 Lanolin, PEG-75 Lanolin, PPG-12-PEG-50 Lanolin, Polyglyceryl-3 Beeswax.

[0041] (5) Polyethylene glycols of the H(O-CH2-CH2)n-OH type in particular chosen from PEG-6, PEG-8, PEG-14M, PEG-20, PEG-45M, PEG-90, PEG-90M, PEG-150, PEG-180, PEG-220.

[0042] (6) Poloxamers of type HO-(CH2-CH2-O)n-(CHCH3-CH2-O)O-(CH2-CH2-O)pH, in particular chosen from Poloxamer 124, Poloxamer 184, Poloxamer 338, Poloxamer 124, Poloxamer 184, Poloxamer 184, Poloxamer 338.

[0043] (7) Polypropylene glycols alkyl ethers of type: CnH2n+1-(OC(CH3)H-CH2)o-(O-CH2-CH2)p-OH in particular chosen from PPG-26-Buteth-26, PPG-5-Ceteth-20, PPG- 6-Decyltetradeceth-30.

[0044] (8) Compounds of the type: H(OC(CnH2n+1)-CH2)o-(CH2-CH2-O)p-(CH2-C(CqH2q+1)HO)rH in particular PEG-45 / Dodecyl Glycol Copolymer.

[0045] (9) Compounds of the type: CnH2n+1-(O-CH2-CH2)oO-CH2-C(CpH2p+1)HOH in particular Ceteareth-60 Myristyl Glycol.

[0046] (10) Polyoxyethylenated glycerins, in particular oxyethylenated glycerin 26 OE (Glycereth-26).

[0047] (11) Alkyl polyethylene glycols of the CnH2n+r(O-CH2-CH2)o-OH type, in particular chosen from Ceteth-2, Ceteth-10, Ceteth-20, Ceteth-25, Isoceteth-20, Laureth-2, Laureth-3, Laureth-4, Laureth-12, Laureth-23, Oleth-2, Oleth-5, rOleth-10, Oleth-20, Oleth-25, Deceth-3, Deceth-5, Beheneth-10, Steareth-2, Steareth-10, Steareth-20, Steareth-21, Steareth-100, Ceteareth-12, Ceteareth-15, Ceteareth-20, Ceteareth-25, Ceteareth-30, Ceteareth-33, Coceth-7, the Trideceth-12.

[0048] (12) Polyoxyethylenated alkylphosphates and polyoxyalkylphosphates- propylene, in particular chosen from Trilaureth-4 Phosphate, Ceteth-10 Phosphate, Oleth-10 Phosphate, PPG-5-Ceteth-10 Phosphate.

[0049] (13) Polyoxyethylenated alkylamines of the type CH3-(CH2)n-(CH=CH)o-(CH)pN((CH2-CH2-O)H)q((CH2-CH2-O)rH), in particular: PEG-2-01eamine.

[0050] (14) Polyoxyethylenated amide compounds of the type: [0051 ] R-CO-N((O-CH2-CH2)nO-SO3 M+) CH2-CH2-N((O-CH2-CH2)nO-SO3 M+)-C0-R or of the type CnH2n+r(O-CH2-CH2) oO-CH2-CO-NH-(CH2-CH2-O)pH, in particular chosen from Disodium Ethylene Dicocamide PEG-15 Disulfate, Trideceth-2-Carboxamide MEA.

[0052] (15) Esters of polyethylene glycol and fatty acid of type CnH2n+1-(CH=CH2)o-CpH2p-CO-(O-CH2-CH2)n-OH or CnH2n+1-(CH=CH)o-CpH2p-CO-(O-CH2-CH2)qO-CO-CrH2r+1or CnH2n+1-(CH=CH)o-CO-(O-CH2-CH2)qO-CnH2n+1or CnH2n+iO-CH(alkyl)-(CH2)p-(O-CH2-CH2)qO-CO-CrH2r+i in particular chosen from PEG-6 Isostearate, PEG-6 Stearate, PEG-8 Stearate, PEG-8 Isostearate, PEG-20 Stearate, PEG-30 Stearate, PEG-32 Stearate, PEG-40 Stearate, PEG-75 Stearate, PEG-100 Stearate, PEG-8 Distearate, PEG-150 Distearate, Mereth-3 Myristate, PEG-4 Olivate, Propy-leneglycol Ceteth-3 Acetate, PEG-30 Dipolyhydroxystearate.

[0053] (16) Polyoxyethylenated carboxylic acids of type CnH2n+i-(O-CH2-CH2)o-COOH, in particular chosen from PEG-7 Capric Acid, PEG-6 Caprylic Acid, PEG-7 Caprylic Acid, Laureth-5 Carboxylic Acid, Laureth-11 Carboxylic Acid, Laureth-12 Carboxylic Acid.

[0054] (17) Polyoxyethylenated alkylglycerides, in particular chosen from PEG-6 Caprylic / Capric Glycerides, PEG-60 Almond Glycerides, PEG-10 Olive Glycerides, PEG-45 Palm Kernel Glycerides,

[0055] (18) Polyoxyethylenated alkylglucoses, in particular chosen from Methyl- Gluceth-10, Methyl-Gluceth-20.

[0056] (19) Polyoxyethylene sugar esters such as PEG-120 Methyl Glucose Dioleate, PEG-20 Methyl Glucose Sesquistearate.

[0057] (20) Polyoxyalkylenated alkyl glycol ethers such as PPG-1-PEG-9 Lauryl Glycol Ether.

[0058] (21) Polyoxyethylenated or polyglycerolated pentaerythritol esters and ethers, in particular chosen from PEG-150 Pentaerythrityl Tetrastearate.

[0059] (22) Polysorbates, in particular chosen from Polysorbate-20, Polysorbate- 21, Polysorbate-60, Polysorbate-61, Polysorbate-80, Polysorbate-85.

[0060] (23) Polyoxyethylenated polyamines, in particular PEG-15 Cocopolyamine.

[0061] (24) Polyoxyethylenated dihydrocholesteryl esters of structure: in particular Dihydrocholeth-30.

[0062] (25) Optionally hydrogenated esters of glycerol and polyoxylated fatty acid ethylenediamines chosen from PEG-7 Glyceryl Cocoate, PEG-30 Glyceryl Cocoate, PEG-200 Glyceryl Stearate, PEG-200 Hydrogenated Glyceryl Palmitate.

[0063] (26) Polyoxyethylenated hydrogenated castor oils such as PEG-40 Hy drogenated Castor Oil, PEG-60 Hydrogenated Castor Oil, (27) Polyethylene glycol ethers of fatty acid ester and propylene glycol such as PEG-55 Propylene Glycol Oleate.

[0064] (26) Polyoxyethylene butters, in particular polyoxyethylene shea butter oxyethylenated.

[0065] (27) Polyoxyalkylenated or polyglycerolated silicones, in particular chosen among PEG / PPG-17 / 18 Dimethicone, PEG / PPG-18 / 18 Dimethicone, Trideceth-9 PG-Amodimethicone, PEG / PPG-22 / 24 Dimethicone.

[0066] (28) Polyoxyalkylenated or polyglycerolated silanes, in particular chosen from Bis-PEG-18 Methyl Ether Dimethyl Silane, Bis-PEG-18 Methyl ether Dimethyl Silane.

[0067] (29) Polyoxyethylenated or polyglycerolated acrylate copolymers, in particular copolymer with INCI name: Acrylate / Palmeth-25 Acrylate Copolymer

[0068] (30) Proteins, in particular proteins of plant origin, modified or not, hydrolyzed or not such as silk proteins, keratins, soy proteins, wheat proteins, corn proteins, lupin proteins, hazelnut proteins, conchiolin proteins, oat proteins, rice proteins, sweet almond proteins.

[0069] (31) Polyoxyalkylenated alkanediols such as PEG-8 Caprylyl Glycol.

[0070] (32) polyoxyethylenated rapeseed amides and sterols, in particular chosen from PEG-4 Rapeseed Amide, PEG-5 Rapeseed Sterol.

[0071] (33) polyoxyethylenated lanolins such as Laneth-15.

[0072] (34) Polyoxyethylene fatty acid sorbitol esters such as PEG-40 Sorbitan Peroleate.

[0073] (35) Polyoxyethylenated glycerolated esters such as Glycereth-25 PCA Isostearate.

[0074] (36) Polyvinyl alcohols such as those with the following INCI names: ALLYL STEARATE / VINYL ALCOHOL COPOLYMER, ETHYLENE / VINYL ALCOHOL COPOLYMER, POLYVINYL ALCOHOL, VINYL ALCOHOL / CROTONATES COPOLYMER, VINYL ALCOHOL / CROTONATES / VINYL NEODECANOATE COPOLYMER.

[0075] (37) Vinyl pyrrolidone copolymers such as those with the following INCI names: POLYVINYL PYRROLIDONE / VINYL ALCOHOL, VINYL PYRROLIDONE / EICOSENE COPOLYMER, VINYL PYRROLIDONE / HEXADECENE COPOLYMER, VINYL PYRROLIDONE / DIMETHYLAMINOPROPYLACRYL AMIDE ACRYLATES COPOLYMER, HY-DROLYZED WHEAT PROTEIN / VINYL PYRROLIDONE CROSSPOLYMER, VINYL PYRROLIDONE / METHACRYLAMIDE / VINYL IMIDAZOLE COPOLYMER, AMMONIUM ACRYLOYLDIMETHYL TAURATE / VINYL PYRROLIDONE COPOLYMER, VINYL PYRROLIDONE / ACRYLATES / LAURYL METHACRYLATE COPOLYMER, SODIUM ACRYLOYLDIMETHYLTAURATE / VINYL PYRROLIDONE CROSSPOLYMER,VINYL CAPROLACTAM / VP / DIMETHYLAMINOETHYL METHACRYLATE COPOLYMER, VINYL PYR-ROLIDONE / DIMETHYLAMINOETHYLMETHACRYLATE COPOLYMER, VINYL PYRROLIDONE / POLYCARBAMYL POLYGLYCOL ESTER.

[0076] (38) Les polymères et les copolymères de caprolactame tels que les polyvinylcapro- lactames, les polymères de nom INCI : VINYL CAPROLACTAM / VINYL PYR-ROLIDONE / DIMETHYLAMINOETHYL METHACRYLATE COPOLYMER.

[0077] (39) leurs mélanges.

[0078] According to a preferred embodiment, the compound(s) Y will be chosen from non-ionic compounds.

[0079] According to a preferred embodiment, the compound(s) Y will be chosen from pullulans; celluloses such as Cetyl Hydroxyethyl cellulose; modified guar gums, in particular hydroxypropyl guar; polyglycerol and fatty acid esters, in particular Polyglyceryl-10 Caprate, Polyglyceryl-10 Laurate; polyethylene glycols such as PEG-180; PEG-40 Hydrogenated Castor Oil; polysorbates, in particular Polysorbate 80; polyoxyalkylenated ester waxes such as polyoxyethylenated jojoba wax (120 EO); and mixtures thereof.

[0080] According to a preferred embodiment of the invention, the molar ratio of the reactive hydroxyl groups (OH) of the polyphenol(s) X to the reactive functional groups Gy of the compound(s) Y with said hydroxyl groups, preferably varies from 1 / 3 to 20, more preferably from 1 / 2 to 15, and more particularly from 3 / 4 to 3. Mono-alcohol

[0081] The composition according to the invention comprises at least one mono-alcohol comprising from 2 to 8 carbon atoms, in particular from 2 to 6 carbon atoms, and in particular from 2 to 4 carbon atoms such as ethanol, isopropanol, propanol or butanol, and mixtures thereof, and more particularly ethanol.

[0082] The mono-alcohol(s) comprising from 2 to 8 carbon atoms is (are) then preferably present at contents ranging from 40% to 90% by weight, more preferably ranging from 40 to 80% by weight, and more particularly ranging from 45 to 65% by weight relative to the total weight of the composition. Antioxidant agent

[0083] The composition according to the invention also comprises at least one antioxidant agent.

[0084] For the purposes of the present invention, the term “antioxidant agent” means a compound which slows down or prevents the oxidation of other compounds.

[0085] The antioxidant agents according to the invention can be chosen from all the compounds known for their antioxidant activity.

[0086] In particular, the antioxidant agents may be chosen from sodium sulfite; sodium metabisulfite; tocopherol and its esters, in particular tocopherol acetate; ascorbic acid and its derivatives, in particular palmitate ascorbyl, ascorbyl magnesium phosphate and ascorbyl glucoside, erythorbic acid, melatonin; pidolates; glutathione; tris(tetramethylhydroxypiperidinol) citrate; and mixtures thereof.

[0087] According to a particular embodiment, the antioxidant agents may be chosen from 2,6-di-tert-butyl-4-methylphenol (BHT), tert-butyl-4-hydroxyanisole (BHA), N,N'-bis(3,4,5-trimethoxybenzyl) ethylenediamine and its salts; idebenone; and mixtures thereof.

[0088] According to a particular embodiment, the antioxidant agent is chosen from those of the following formula (I) or (II):

[0089] [Chem.l] ALK' (I)

[0090] or

[0091] [Chem.2] (II)

[0092] in which: - ALK' represents a saturated, linear or branched hydrocarbon chain in C1-C4, in particular in C1-C2; in particular methyl or ethyl; - ALK, identical or different, represents a hydrocarbon chain, saturated or unsaturated, linear or branched, cyclic or acyclic, C1-C8; and - R is an OH, SH or NH2 group.

[0093] Preferably, ALK represents a hydrocarbon chain, identical or different, in C3-C4, saturated or unsaturated, linear or branched, cyclic or acyclic; in particular ALK represents a hydrocarbon chain in C3-C4, saturated, linear or branched, acyclic; in particular tert-butyl.

[0094] Preferably, R is an OH group.

[0095] Preferably, at least one antioxidant agent corresponds to formula (II) and even better at least one antioxidant agent is pentaerythrityl tetra-di-t-butyl hydroxyhydrocinnamate.

[0096] Examples of compounds of formula (I) include 2,6-di-tert-butyl-4-methylphenol (INCI name: BHT). Commercial products include the product sold under the trade name AGIDOL 1 CRYSTAL® by the company STERLITAMAK PETROCHEMICAL PLANT, IONOL CP® by the company OXIRIS CHEMICALS, NIPANOX BHT by the company CLARIANT, or PUROLAN BHT® by LANXESS.

[0097] According to a preferred embodiment of the invention, the antioxidant agent is chosen from ascorbic acid, sodium metabisulfite, erythorbic acid, and mixtures thereof.

[0098] The composition according to the invention preferably comprises the antioxidant agent(s) in a total amount ranging from 0.1 to 10% by weight, in particular ranging from 0.2 to 8% by weight, better still ranging from 0.3 to 5% by weight and preferentially ranging from 0.3 to 3% by weight relative to the total weight of the composition. Aqueous phase

[0099] According to a particular embodiment, the composition of the invention may additionally comprise water.

[0100] The composition of the invention may in particular contain demineralized water, or even floral water such as cornflower water and / or mineral water such as VITTEL water, LUCAS water or LA ROCHE POSAY water and / or thermal water.

[0101] The pH of the composition is preferably less than 6, more preferably between 2 and 6 and more particularly between 2 and 5.

[0102] The quantity of water is preferably less than or equal to 30% by weight, and more preferably varies from 5 to 30% by weight, and more particularly from 8 to 25% relative to the total weight of the composition.

[0103] The composition may additionally contain solvents and ingredients soluble or miscible in water (miscibility in water greater than 50% by weight at 25°C such as polyols having 3 to 8 carbon atoms such as propylene glycol, 1,3-butylene glycol, caprylyl glycol, pentylene glycol, glycerin, dipropylene glycol; C3-C4 ketones, C2-C4 aldehydes. Oily phase

[0104] According to a particular embodiment, the composition of the invention may additionally comprise an oily phase;

[0105] The term “oily phase” means a liquid phase at room temperature (25°C) and atmospheric pressure comprising oils, waxes, pasty bodies and possibly all organic solvents and ingredients which are soluble or miscible in said phase.

[0106] The oil or oils may be chosen from mineral, animal, vegetable, synthetic oils, in particular chosen from hydrocarbon and / or silicone and / or fluorinated oils, volatile or non-volatile, and mixtures thereof.

[0107] By "oil" is meant a fatty substance that is liquid at room temperature (25°C) and atmospheric pressure (760mm Hg or 105 Pa). The oil may be volatile or non-volatile.

[0108] For the purposes of the present invention, the term “silicone oil” means an oil comprising at least one Si-O group, and more particularly an organopolysiloxane.

[0109] The term “fluorinated oil” means an oil comprising at least one fluorine atom.

[0110] The term “hydrocarbon oil” means an oil containing mainly hydrogen and carbon atoms and optionally one or more functions chosen from hydroxyl, ester, ether, carboxylic functions.

[0111] For the purposes of the invention, the term "volatile oil" means any oil capable of evaporating on contact with the skin in less than one hour, at room temperature and atmospheric pressure. Volatile oil is a volatile cosmetic compound, liquid at room temperature, having in particular a non-zero vapor pressure, at room temperature and atmospheric pressure, in particular having a vapor pressure ranging from 2.66 Pa to 40,000 Pa, in particular ranging from 2.66 Pa to 13,000 Pa, and more particularly ranging from 2.66 Pa to 1,300 Pa.

[0112] By "non-volatile oil" is meant an oil remaining on the skin or keratin fiber at room temperature and atmospheric pressure for at least several hours and having in particular a vapor pressure of less than 2.66 Pa, preferably less than 0.13 Pa. For example, the vapor pressure can be measured according to the static method or by the isothermal thermogravimetry effusion method, according to the vapor pressure (OECD standard 104). Volatile hydrocarbon oils

[0113] As an example of volatile hydrocarbon oil that can be used in the invention, mention may be made of: - hydrocarbon oils with 8 to 16 carbon atoms, and in particular C8-C16 isoalkanes of petroleum origin (also called isoparaffins) such as isododecane (also called 2,2,4,4,6-pentamethylheptane), isododecane, isohexadecane, and for example oils sold under the trade names Isopars® or Permetyls®, branched C8-Ci6 esters, isohexyl neopentanoate, and mixtures thereof. Other volatile hydrocarbon oils such as petroleum distillates, in particular those sold under the name Shell or by the company SHELL, may also be used; volatile linear alkanes such as those described in the patent application of the company Cognis DE10 2008 012 457 and such as that sold under the trade name CETIOL ULTIMATE® by the company BASF. We can also mention the dodecane / tetradecane mixture in the weight ratio 85 / 15 marketed by the company BIOSYNTHIS under the reference VEGELIGHT 1214® as well as the mixture of volatile linear alkanes in C9-C12-with INCI name: C9-12 ALKANE such as the product marketed by the company BIOSYNTHIS under the reference VEGELIGHT SILK®. Non-volatile hydrocarbon oils

[0114] As an example of non-volatile hydrocarbon oil that can be used in the invention, mention may be made of: - linear or branched hydrocarbons, of mineral or synthetic origin such as paraffin oils and their derivatives, petroleum jelly, polydecenes, polybutenes, polyisobutenes, hydrogenated or not such as Parleam, squalane; - synthetic ethers having 10 to 40 carbon atoms such as dicaprylyl ether; - triglycerides consisting of esters of fatty acids and glycerol, in particular the fatty acids of which may have chain lengths varying from C4 to C36, and in particular from C18 to C36, these oils being able to be linear or branched, saturated or unsaturated; these oils may in particular be heptanoic or octanoic triglycerides, wheat germ oils, sunflower oils, grape seed oils, sesame (820.6 g / mol), corn oils, apricot oils, castor oil, shea oil, avocado oil, olive oil, soybean oil, sweet almond oil, palm oil, rapeseed oil, cotton oil, hazelnut oil, macadamia oil, jojoba oil, alfalfa oil, poppy oil, pumpkin oil, squash oil, blackcurrant oil, evening primrose oil, millet oil, barley oil, quinoa oil, rye oil, safflower oil, candlenut oil, passionflower oil, musk rose oil; shea oil; or caprylic / capric acid triglycerides such as those sold by the company Stéarineries Dubois or those sold under the names Miglyol 810®, 812® and 818® by the company Dynamit Nobel - linear aliphatic hydrocarbon esters of formula RCOOR' in which RCOO represents a carboxylic acid residue containing from 2 to 40 carbon atoms, and R' represents a hydrocarbon chain containing from 1 to 40 carbon atoms, such as cetostearyl octanoate, esters of isopropyl alcohol such as isopropyl myristate, isopropyl palmitate, ethyl palmitate, palmitate of 2-ethylhexyl, isopropyl stearate or isostearate, isostearyl isostearate, octyl stearate, diisopropyl adipate, heptanoates, and in particular isostearyl heptanoate, octanoates, decanoates or ricinoleates of alcohols or polyalcohols such as propylene glycol dioctanoate, cetyl octanoate, tridecyl octanoate, 4-diheptanoate and ethyl 2-hexyl palmitate, alkyl benzoate, hexyl laurate, esters of neopentanoic acid such as isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, octyl-2-docecyl neopentanoate, isononanoic acid esters such as isononyl isononanoate, isotridecyl isononanoate, octyl isononanoate, oleyl erucate; lauroyl isopropyl sarcosinate, diisopropyl sebacate, isocetyl stearate, isodecyl neopentanoate, isostearyl behenate; - polyesters obtained by condensation of dimer and / or trimer of unsaturated fatty acid and diol such as those described in patent application FR 0 853 634, such as in particular dilinoleic acid and 1,4-butanediol. In this respect, we may notably mention the polymer marketed by Biosynthis under the name Viscoplast 14436H® (INCI name: Dilinoleic Acid / Butane diol Copolymer), or copolymers of polyols and diacid dimers, and their esters, such as Hailuscent ISDA®, - di-alkyl carbonates, the 2 alkyl chains being able to be identical or different, such as dicaprylyl carbonate marketed under the name Cetiol CC®, by Cognis; - linear fatty acid esters having a total carbon number ranging from 35 to 70 such as pentaerythrityl tetrapelargonate, - aromatic esters such as tridecyl trimellitate, C12-C15 alcohol benzoate, 2-phenyl ethyl ester of benzoic acid, butyl octyl salicylate, - esters and polyesters of dimer diol and mono- or dicarboxylic acid, such as esters of dimer diol and fatty acid and esters of dimer diols and dimer dicarboxylic acid, such as Lusplan DD-DA5® and Lusplan DD-DA7® marketed by the company NIPPON FINE CHEMICAL and described in application US 2004-175338, the content of which is incorporated into the present application by reference; - fatty alcohols having from 12 to 26 carbon atoms such as octyldodecanol, 2-butyloctanol, 2-hexyl decanol, 2-undecyl pentadecanol, oleyl alcohol; - di-alkyl carbonates, the 2 alkyl chains being able to be identical or different, such as dicaprylyl carbonate marketed under the name Cetiol CC®, by Cognis; and - and their mixtures. Non-volatile silicone oils

[0115] Among the non-volatile silicone oils, mention may be made of silicone oils such as non-volatile polydimethylsiloxanes (PDMS); phenyl silicones such as phenyl trimethicones, phenyl dimethicones, diphenyl dimethicones, trimethyl pentaphenyl trisiloxane, tetramethyl tetraphenyl trisiloxane, trimethyl-siloxyphenyl dimethicone, diphenylsiloxy phenyl trimethicone, as well as mixtures thereof.

[0116] Volatile, linear or cyclic silicone oils

[0117] As linear volatile silicone oils, mention may be made of octamethyltrisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, and mixtures thereof.

[0118] As cyclic volatile silicone oils, mention may be made of octamethyl cyclotetrasiloxane, decamethyl cyclopentasiloxane, dodecamethyl cyclohexasiloxane and mixtures thereof.

[0119] According to a preferred embodiment of the invention, the total quantity of non-volatile oil(s) is less than or equal to 10% by weight, more preferably, in particular less than or equal to 5.0% by weight, or even less than 2.0% by weight, relative to the total weight of the composition.

[0120] According to a particular embodiment of the invention, the composition of the invention may be free of non-volatile oil.

[0121] According to a preferred embodiment of the invention, the total quantity of volatile oil(s) is less than or equal to 10% by weight, more preferably, in particular less than or equal to 5.0% by weight relative to the total weight of the composition.

[0122] According to a particular embodiment of the invention, the composition of the invention may be free of volatile oil. Pigment

[0123] According to a particular embodiment, the composition according to the invention additionally comprises at least one pigment of the iron oxide type (INCI Name Iron Oxide).

[0124] The term “pigment” means particles insoluble in an aqueous medium, intended to color and / or opacify the composition and / or the resulting deposit.

[0125] By “uncoated pigment” is meant any pigment not treated with a surface agent covering it partially or totally by being absorbed, adsorbed or grafted onto said pigment.

[0126] According to a preferred embodiment, the pigment(s) are present in an amount of up to 35.0% by weight, more preferably up to 25.0% by weight and more particularly from 4 to 25% by weight relative to the total weight of the composition.

[0127] According to a particular embodiment, the pigments used according to the invention are chosen from yellow iron oxides (CI 77492), red iron oxides, black iron oxides (CI 77499) and mixtures thereof.

[0128] The size of the pigment useful in the context of the present invention is generally greater than 100 nm and can range up to 10 qm, preferably from 200 nm to 5 qm, and more. preferentially from 300 nm to 1 pm.

[0129] According to a particular form of the invention, the pigments have a size characterized by a D

[50] greater than 100 nm and which can range up to 10 pm, preferably from 200 nm to 5 pm, and more preferably from 300 nm to 1 pm.

[0130] The sizes are measured by static light scattering using a commercial granulometer of the MasterSizer 3000® type from Malvem, making it possible to understand the particle size distribution of all the particles over a wide range from 0.01 pm to 1000 pm. The data are processed on the basis of the classical Mie scattering theory. This theory is the most suitable for size distributions ranging from submicron to multi-micron, it makes it possible to determine an “effective” particle diameter. This theory is notably described in the work of Van de Hulst, HC, “Light Scattering by Small Particles”, Chapters 9 and 10, Wiley, New York, 1957.

[0131] D

[50] represents the maximum size that 50% by volume of the particles has.

[0132] In the context of the present invention, the pigments are more particularly black iron oxides (CI 77499). Cosmetic additives

[0133] The compositions of the invention may contain additives commonly used in cosmetics. Mention may be made in particular of neutralizers, cosmetic active ingredients such as, for example, emollients, moisturizers, vitamins, sunscreens, and mixtures thereof.

[0134] Of course, those skilled in the art will take care to choose any additional additives and / or their quantity in such a way that the advantageous properties of the compositions according to the invention are not, or not substantially, altered by the envisaged addition.

[0135] The compositions of the invention can be manufactured by known methods, generally used in the cosmetic field.

[0136] The compositions used according to the invention may be care products for keratin materials such as the skin such as the face, cheeks, eyelids, eye contour, eyelashes, eyebrows and nails.

[0137] The compositions used according to the invention may be makeup products for keratin materials such as the skin such as the face, cheeks, eyelids, eye contour, eyelashes, eyebrows and nails such as foundations, eye shadows, mascaras, eyeliners, nail polishes, primers or finishers.

[0138] Packaging and application assembly or kit

[0139] The present invention also relates to a set, or kit, for packaging and applying a cosmetic composition for coating keratin materials. Unique including: - a packaging device comprising the cosmetic composition for coating keratin materials as previously described, - an applicator of said composition.

[0140] Said applicator may be integral with a gripping member forming a cover for said packaging device. In other words, said applicator may be mounted in a removable position on said device between a closed position and a position clear of a dispensing opening of the packaging device for said composition.

[0141] A keratin material coating assembly suitable for the invention may comprise an applicator configured to apply said cosmetic composition for coating keratin materials, and where appropriate a packaging device suitable for receiving said composition. Packaging device

[0142] The packaging device comprises a container intended to house the coating composition for keratin materials. This composition can then be taken from the container by immersing the applicator therein.

[0143] This applicator may be integral with a closure element of the container. This closure element may form a gripping member of the applicator. This gripping member may form a cover to be removably mounted on said container by any suitable means such as screwing, snap-fastening, fitting or other. Such a container may therefore reversibly house said applicator.

[0144] This container may optionally be equipped with a wringer suitable for removing excess product taken up by the applicator.

[0145] A method of applying the composition according to the invention to the eyelashes or eyebrows may also comprise the following steps: - form a deposit of the cosmetic composition on the keratin materials., - leave the deposit on the keratin materials, the deposit may dry.

[0146] It should be noted that according to another embodiment the applicator can form a product container. In such a case a container can for example be provided in the gripping member and an internal channel can internally connect this gripping member to the raised application elements.

[0147] Finally, it should be noted that the packaging and application assembly may be presented in the form of a kit, the applicator and the packaging device being able to be housed separately in the same packaging article.

[0148] The expressions "between ... and..." and "ranging from ... to ..." must be understood inclusively, unless otherwise specified. In the description and examples, unless otherwise indicated, the percentages are percentages by weight. The percentages are therefore expressed by weight relative to the total weight of the composition. The ingredients are mixed, in the order and under the conditions easily determined by those skilled in the art.

[0149] The invention will now be described by means of examples which are presented for illustrative purposes only and should not be interpreted as limiting examples of the invention.

[0150] Examples 1 to 6 (invention) and examples A and B (outside the invention)

[0151] Examples 1 to 6 of the invention and Examples A and B outside the invention were prepared. without antioxidant.

[0152] .[Tables 1] Ingredients Exl Ex2 Ex3 Ex4 Ex5 Ex6 ExA ExB Tannic Acid 5 5 5 5 5 5 5 5 Polysorbate-80 (TWEEN-80-LQ® from CRODA)a 5 5 5 - - - 5 - Polyglyceryl-10 Laurate (DERMOFEELG10 L® from DR STRAETMANS) 5 5 5 5 Ascorbic Acid 0.5 0.5 Sodium Meta-bisulfite 0.5 0.5 Erythorbic Acid 0.5 0.5 Water 10 10 10 10 10 10 10 10 Ethanol qsp 100 qsp 100 qsp 100 qsp 100 qsp 100 qsp 100 qsp 100 Preparation protocol

[0153] Tannic acid (polyphenol X) and the non-ionic surfactant (compound Y): Polysorbate-80 or Polyglyceryl-10 Laurate were dispersed in ethanol. Once the mixture was homogeneous, the preparation containing the antioxidant previously dissolved in water was added for Examples 1 to 6 of the invention with stirring.

[0154] The appearance of each composition was observed after two months of storage at room temperature (25°C).

[0155] After two months at room temperature, compositions A and B without antioxidant darkened unlike examples 1 to 6 of the invention comprising an antioxidant agent.

Claims

Claims

1. Composition comprising, in particular in a physiologically acceptable medium: (1) at least one polyphenol X comprising at least two different phenol groups, and 2) at least one non-ionic compound Y comprising at least two functional groups Gy, identical or different, capable of forming at least two hydrogen bonds with said phenol groups of polyphenol X; and (3) at least one mono-alcohol having from 2 to 8 carbon atoms at contents ranging from 40% to 90% by weight relative to the total weight of the composition; (4) at least one antioxidant agent in a total amount ranging from 0.1 to 10% by weight relative to the total weight of the composition; said antioxidant agent being chosen from ascorbic acid, sodium meta-bisulfite, erythorbic acid, and mixtures thereof; and (5) water in an amount less than or equal to 30% by weight relative to the total weight of the composition.

2. Composition according to claim 1, where the polyphenol is chosen from catechol tannins, in particular chosen from gallotannins and ellagitannins.

3. A composition according to claim 1 or 2, wherein the polyphenol is epigallocatechin, in particular a green tea extract comprising at least 45% by weight of epigallocatechin relative to the weight of said extract.

4. Composition according to claim 1, wherein the polyphenol is a procyanidin or a mixture of procyanidins, in particular an extract of maritime pine bark, in particular comprising at least 65% by weight of procyanidins relative to the total weight of said extract.

5. A composition according to claim 1 or 2, wherein the polyphenol is tannic acid.

6. Composition according to any one of the preceding claims, where the polyphenol(s) are present in an amount greater than or equal to 0.8% by weight, preferably greater than or equal to 1.0% by weight, and more particularly greater than or equal to 2.0% by weight relative to the total weight of the composition.

7. A composition according to any preceding claim, wherein the polyphenol(s) is (are) present in an amount ranging from 1.0 to 30.0% by weight, and more particularly ranging from 2.0 to 30% by weight relative to the total weight of the composition.

8. Composition according to any one of the preceding claims, wherein the compound Y comprises at least two functional groups Gy, identical or different, chosen from hydroxyl, acid anhydride, amine, amide, carbamate, urethane, carbamide, urea, thiol, glyceryl, acrylate, acrylamide, vinylpyrrolidone, vinyl alcohol, vinylamine, vi-nylformamide, and mixtures thereof.

9. Composition according to any one of the preceding claims, wherein the molar mass of compound Y is greater than 200 g / mol, or even greater than 350 g / mol.

10. Composition according to any one of the preceding claims, wherein the non-ionic compound(s) Y are chosen from pullulans; celluloses such as Cetyl Hydroxyethyl cellulose; modified guar gums, in particular hydroxypropyl guar; polyglycerol fatty acid esters, in particular Polyglyceryl-10 Laurate; polyethylene glycols such as PEG-180; PEG-40 Hydrogenated Castor Oil; polysorbates, in particular Polysorbate 80; polyoxyalkylenated ester waxes such as polyoxyethylenated jojoba wax (120 EO); and mixtures thereof.

11. Composition according to any one of the preceding claims, wherein the molar ratio of the reactive hydroxyl groups (OH) of the polyphenol X to the reactive functional group(s) Gy of the compound Y varies from 1 / 3 to 20, more preferably from 1 / 2 to 15, more particularly from 3 / 4 to 3.

12. Composition according to any one of the preceding claims, wherein the mono-alcohol comprising from 2 to 8 carbon atoms is chosen from ethanol, isopropanol, propanol or butanol, and mixtures thereof, and more particularly is ethanol.

13. Composition according to any one of the preceding claims, where the mono-alcohol(s) comprising from 2 to 8 carbon atoms is (are) present at contents ranging from 40% to 90% by weight, more preferably, ranging from 40 to 80% by weight, and more particularly ranging from 45 to 65% by weight relative to the total weight of the composition.

14. Composition according to any one of the preceding claims wherein the antioxidant agent(s) is (are) present in a total amount ranging from 0.1 to 10% by weight, in particular ranging from 0.2 to 8% by weight, better ranging from 0.3 to 5% by weight and preferably ranging from 0.3 to 3% by weight relative to the total weight of the composition.

15. Composition according to any one of the preceding claims, further comprising at least one pigment of the uncoated iron oxide type, and preferably at least one uncoated black iron oxide.

16. A composition according to claim 19, wherein the uncoated iron oxide(s) is (are) present in an amount of up to 35.0% by weight, more preferably up to 25.0% by weight and more particularly from 4 to 25% by weight relative to the total weight of the composition.

17. Composition according to claim 21, where the quantity of water is less than or equal to 30% by weight, and more preferably varies from 5 to 30% by weight, and more particularly from 8 to 25% relative to the total weight of the composition.

18. A composition according to any preceding claim, further comprising an oily phase.

19. Composition according to claim 18, wherein the total quantity of non-volatile oil(s) is less than or equal to 10% by weight, more preferably, in particular less than or equal to 5.0% by weight, or even less than 2.0% by weight, or even free of non-volatile oil relative to the total weight of the composition.

20. Composition according to claim 18, wherein the total amount of volatile oil(s) is less than or equal to 10% by weight, more preferably, in particular less than or equal to 5.0% by weight relative to the total weight of the composition.

21. Composition according to any one of the preceding claims, in the form of a product for caring for keratin materials such as the skin such as the face, cheeks, eyelids, eye contour, eyelashes, eyebrows and nails.

22. Composition according to any one of the preceding claims, in the form of a makeup product for keratin materials such as the face, the eyes, the eyelids, the eye contour, the eyelashes, the eyebrows and the nails.

23. Assembly, or kit, for packaging and applying a cosmetic composition for coating keratin fibers comprising: - a packaging device comprising the composition as defined in any one of the preceding claims; - an applicator of said composition.

24. Process for coating keratin materials, in particular the skin, keratin fibers such as the eyelashes and / or eyebrows, comprising a step of applying to said keratin materials at least one composition as defined according to any one of claims 1 to 23.