Novel heteroaryl-triazole compounds as pesticides

Abstract

To provide heteroaryl-triazole compounds as crop protection compositions or veterinary ectoparasiticides.SOLUTION: The present invention relates to: novel heteroaryl-triazole and heteroaryl-tetrazole compounds of the general formula (I); formulations and compositions comprising such compounds; their use in the control of animal pests including arthropods and insects in plant protection; and their use for the control of ectoparasites on animals.SELECTED DRAWING: None

Description

Technical Field

[0001] The present invention relates to novel heteroaryl triazole compounds, formulations and compositions containing such compounds, and their use in controlling pests such as arthropods and insects in plant protection, and their use for controlling external parasites on animals.

[0002] Certain heteroaryl-triazole compounds are disclosed in WO2017 / 192385 for use in controlling external parasites on animals, and in WO2019 / 170626 and WO2019 / 215198 for use in controlling pests such as arthropods and insects in the field of plant protection. Further, patent applications WO2019 / 197468, WO20 19 / 201835, WO2019 / 202077, and WO2019 / 206799 disclose certain heteroaryl- triazole compounds for use in controlling external parasites on animals and for controlling pests such as arthropods and insects in the field of plant protection. WO2020 / 002563, WO2020 / 053364, WO2020 / 05 3365, WO2020 / 079198, WO2020 / 094363 all describe azole-amide compounds that can be used as insecticides.

Prior Art Documents

Patent Documents

[0003]

Patent Document 1

Patent Document 2

Patent Document 3

Patent Document 4

Patent Document 5

Patent Document 6

Patent Document 7

Patent Document 8

Patent Document 9

Patent Document 10

Patent Document 11

Patent Document 12

Summary of the Invention

Problems to be Solved by the Invention

[0004] Modern plant protection products and external parasite repellents for animals must meet many requirements, for example, with respect to efficacy, persistence, spectrum and resistance-breaking properties. Doubts regarding toxicity, the possibility of combination with other active compounds or formulation adjuvants become important, and furthermore doubts regarding the costs required for the synthesis of active compounds become important. Furthermore, there is a possibility of resistance occurring for all these reasons, it cannot be considered that the search for new crop protection compositions or external parasite repellents for animals is complete, and new compounds having improved properties with respect to at least individual aspects are always needed compared to known compounds. The object of the present invention was to provide compounds that broaden the spectrum of pesticides in various aspects.

[0005] . [Means for solving the problem]

[0006] The present invention provides a compound of the following general formula (I): [ka]

[0007] In the formula (configuration 1-1), R 1 is hydrogen; R 2 is phenyl, where the phenyl is substituted with a total of 1 to 2 substituents provided that the substituent is not on any carbon adjacent to the carbon bonded to C=O, and The substituents are Cyclopropyl, methylsulfonyl, ethylsulfonyl, isopropylsulfonyl, Cyclopropylsulfonyl, difluoromethylsulfonyl, trifluoroethylsulfonyl The group consisting of -SF5, -SF6, -SF7, -SF8, -SF9, -SF10, -SF11, -SF12, -SF13, -SF14, -SF15, -SF16, -SF17, -SF18, -SF19, -SF20 Selected from A; The other substituents are independently Selected from group B consisting of chlorine, trifluoromethyl and trifluoromethoxy; teeth R 2 teeth, one substituent selected from the group consisting of fluorine, chlorine, bromine and trifluoromethyl; or R 2 teeth, 1 to 3 selected from the group consisting of fluorine, chlorine, bromine, methyl and trifluoromethyl. a pyrazole optionally substituted by two substituents; R 3 is C1-C3 alkyl; R 4is pyridine, pyrimidine or pyrazine, where pyridine, pyrimidine or pyrazine is optionally substituted by one substituent selected from the group consisting of chlorine and -CN; ; R 5 is ethyl, n-propyl, iso-propyl, difluoromethyl, cyclopropyl, methoxy, ethoxy, iso-propoxy or halogen.

[0008] The compounds of formula (I) likewise include all diastereomers or enantiomers present, and E / Z isomers, as well as salts and N-oxides of the compounds of formula (I), and their use for the control of pathogenic animals.

[0009] Definitions of preferred groups for the formulas specified above and below are provided below.

[0010] The present invention further relates to (Configuration 1-2): R 1 is hydrogen; R 2 is phenyl, where phenyl is substituted by a total of 1 to 2 substituents, provided that none of the substituents is on a carbon adjacent to the carbon to which any C=O is attached, and one substituent is selected from group A consisting of methylsulfonyl, ethylsulfonyl, isopropylsulfonyl, cyclopropylsulfonyl, difluoromethylsulfonyl, trifluoroethylsulfonyl, trifluoromethylsulfonyl and -SF5 and cyclopropyl, where the cyclopropyl is optionally substituted by 1 to 2 substituents selected from the group consisting of halogen, -CN, methyl, difluoromethyl and trifluoromethyl; and the other substituents are independently ; ; Fluorine, chlorine, bromine, iodine, -CN, difluoromethyl, trifluoromethyl, di selected from Group B consisting of difluoromethoxy, trifluoromethoxy and cyclopropyl , wherein said cyclopropyl may be substituted by 1 to 2 substituents selected from the group consisting of halogen, -CN, methyl, difluoromethyl and trifluoro methyl; or R 2 is thiophene which may be substituted by 1 substituent selected from the group consisting of fluorine, chlorine, bromine and trifluoromethyl ; or R 2 is pyrazole which may be substituted by 1 to 2 substituents selected from the group consisting of fluorine, chlorine, bromine, methyl and trifluoromethyl; R 3 is C1-C3 alkyl; R 4 is pyridine, pyrimidine or pyrazine, wherein pyridine, pyrimidine or pyrazine may be substituted by 1 substituent selected from the group consisting of chlorine and -CN ; R 5 is ethyl, n-propyl, iso-propyl, difluoromethyl, cyclopropyl , methoxy, ethoxy, iso-propoxy or halogen, and provides a compound of general formula (I). Provided is.

[0011] Preferred (Constitution 2-1) is R 1 is hydrogen; R 2 is 3-chloro-5-cyclopropylphenyl, 3-chloro-5-methylsulfonyl phenyl, 5-chloro-3-thienyl, 3-chloro-5-(2,2,2-trifluoro (Ethylsulfonyl)phenyl, 3-chloro-5-isopropylsulfonylphenyl, 3- Cyclopropylsulfonyl-5-(trifluoromethyl)phenyl, 3-chloro-5-e thylsulfonylphenyl, 3-chloro-5-cyclopropylsulfonylphenyl, 3-e thylsulfonyl-5-(trifluoromethyl)phenyl, 3-cyclopropyl-5-(tr ifluoromethoxy)phenyl, 3-chloro-5-(difluoromethylsulfonyl)p henyl, 3-methylsulfonyl-5-(trifluoromethyl)phenyl, 1-methyl-5- (trifluoromethyl)-1H-pyrazol-3-yl, 3-chloro-5-(pentaflu oro-λ6-sulfanyl)phenyl, 3-chloro-5-(1-cyanocyclopropyl) phenyl, or 3-chloro-5-(trifluoromethylsulfonyl)phenyl; R 3 is methyl; R 4 is 5-cyanopyridin-2-yl, pyrimidin-2-yl, 5-chloropyrimid in-2-yl or 5-chloropyridin-2-yl; R 5 is ethyl, n-propyl, iso-propyl, difluoromethyl, cyclopropyl , methoxy, ethoxy, iso-propoxy, iodine, bromine or chlorine, a compound of formula (I).

[0012] Preferred (Constitution 2-2) includes R 1 is hydrogen; R 2 is 3-chloro-5-cyclopropylphenyl, 3-chloro-5-methylsulfony lphenyl, 5-chloro-3-thienyl, 3-chloro-5-(2,2,2-trifluoro ethylsulfonyl)phenyl, 3-chloro-5-isopropylsulfonylphenyl, 3-​ Cyclopropylsulfonyl-5-(trifluoromethyl)phenyl, 3-chloro-5-ethyl sulfonylphenyl, 3-chloro-5-cyclopropylsulfonylphenyl, 3-ethyl sulfonyl-5-(trifluoromethyl)phenyl, 3-cyclopropyl-5-(trifluoro methoxy)phenyl, 3-chloro-5-(difluoromethylsulfonyl)phenyl, 3-methylsulfonyl-5-(trifluoromethyl)phenyl, 1-methyl-5- (trifluoromethyl)-1H-pyrazol-3-yl, 3-chloro-5-(pentafluoro λ6-sulfanyl)phenyl, 3-chloro-5-(1-cyanocyclopropyl) phenyl, 3-chloro-5-(trifluoromethylsulfonyl)phenyl, 3-bromo- 5-[1-(trifluoromethyl)cyclopropyl]phenyl, 3-cyclopropyl-5 -methylsulfonylphenyl, 3-(difluoromethyl)-5-methylsulfonylphenyl , 3-cyclopropyl-5-cyclopropylsulfonylphenyl, 3-fluoro-5- methylsulfonylphenyl, 3-(difluoromethoxy)-5-methylsulfonylphenyl , 3-methylsulfonyl-5-(trifluoromethoxy)phenyl, 3-cyclopropyl -5-(difluoromethyl)phenyl, 3-bromo-5-(1-fluorocyclopropyl yl)phenyl, 3-bromo-5-(2,2-difluorocyclopropyl)phenyl, 3- cyclopropyl-5-(difluoromethoxy)phenyl, 3-cyclopropylsulfonyl -5-(difluoromethoxy)phenyl, 3-cyclopropylsulfonyl-5-(trifluoro methoxy)phenyl, or 3-cyclopropylsulfonyl-5-(difluoromethyl yl)phenyl; R R 3is methyl; R 4 is 5-cyanopyridin-2-yl, pyrimidin-2-yl, 5-chloropyrimid in-2-yl or 5-chloropyridin-2-yl; R 5 is ethyl, n-propyl, iso-propyl, difluoromethyl, cyclopropyl , methoxy, ethoxy, iso-propoxy, iodine, bromine or chlorine, of formula (I) compounds are also available.

[0013] In a further preferred embodiment, the present invention relates to a compound of formula (I′) in which R 3 is C1-C3 alkyl, particularly preferably Me.

Chemical formula

[0014] wherein structural element R 1 , R 2 , R 4 and R 5 have the meanings provided by configuration (1-1) or configuration (2-1) or configuration ( 1-2) or configuration (2-2).

[0015] In a further preferred embodiment, the present invention relates to a compound of formula (I″) in which R 3 is C1-C3 alkyl, particularly preferably Me.

Chemical formula

[0016] wherein structural element R 2 , R 4 and R 5 have the meanings provided by configuration (1-1) or configuration (2-1) or configuration (1-2 ). or configuration (2-2).

[0017] According to a further aspect, the present invention encompasses intermediate compounds useful for the production of the compounds of the general formula (I). In particular, the present invention encompasses intermediate compounds of the general formula (e),

[0018] wherein the structural elements R

Chemical formula

[0019] in the formula, the structural elements R 3 , R 4 and R 5 have the meanings provided by configuration (1-1) or configuration (2-1) or configuration (1-2 ) or configuration (2-2), for example, intermediate compounds INT-1 to INT-8 , INT-10 to INT-12, INT-18, INT-20, INT-22, INT- 24, INT-25 and INT-26, and in the case of their salts and amine hydrochlorides, the free amine : INT-1: 6-[5-[(1S)-1-aminoethyl]-3-ethyl-1,2,4- triazol-1-yl]pyridine-3-carbonitrile hydrochloride, INT-2: 6-[5-[(1S)-1-aminoethyl]-3-isopropyl-1,2 ,4-triazol-1-yl]pyridine-3-carbonitrile, INT-3: 6-[5-[(1S)-1-aminoethyl]-3-cyclopropyl-1, 2,4-triazol-1-yl]pyridine-3-carbonitrile hydrochloride, INT-4: 6-[5-(1-aminoethyl)-3-(difluoromethyl)-1,2, 4-triazol-1-yl]pyridine-3-carbonitrile, INT-5: 6-[5-[(1S)-1-aminoethyl]-3-methoxy-1,2,4 -triazol-1-yl]pyridine-3-carbonitrile, INT-6: 6-[5-[(1S)-1-aminoethyl]-3-ethoxy-1,2,4 -triazol-1-yl]pyridine-3-carbonitrile, INT-7: 6-[5-[(1S)-1-aminoethyl]-3-isopropoxy-1, 2,4-triazol-1-yl]pyridine-3-carbonitrile, INT-8: (1S)-1-[1-(5-chloropyrimidin-2-yl)-3-cyclo propyl-1H-1,2,4-triazol-5-yl]ethanamine hydrochloride, INT-10: 1-[3-chloro-1-(pyrimidin-2-yl)-1H-1,2,4 -triazol-5-yl]ethanamine, INT-11: 1-[3-bromo-1-(pyrimidin-2-yl)-1H-1,2,4 -triazol-5-yl]ethanamine, INT-12: 1-[3-iodo-1-(pyrimidin-2-yl)-1H-1,2,4 -triazol-5-yl]ethanamine, INT-18: (1S)-1-[1-(5-chloropyridin-2-yl)-3-methoxy -1H-1,2,4-triazol-5-yl]ethanamine, INT-20: (1S)-1-[1-(5-chloropyridin-2-yl)-3-cyclo propyl-1H-1,2,4-triazol-5-yl]ethanamine hydrochloride, INT-22: (1S)-1-[1-(5-chloropyrimidin-2-yl)-3-methoxy -1H-1,2,4-triazol-5-yl]ethanamine, INT-24: 6-[5-(1-aminoethyl)-3-iodo-1H-1,2,4-tri azol-1-yl]nicotinonitrile, INT-25: 6-[5-(1-aminoethyl)-3-bromo-1,2,4-triazolo -1-yl]pyridine-3-carbonitrile, INT-26: 6-[5-(1-aminoethyl)-3-chloro-1,2,4-triaz -ol-1-yl]pyridine-3-carbonitrile is included.

[0020] The present invention also includes the intermediate 3-chloro-5-[(difluoromethyl)sulfanyl]benzoic acid ( INT-9), 3-cyclopropyl-5-(difluoromethyl)benzoic acid (INT-13 ), 3-cyclopropyl-5-iodobenzoic acid (INT-14), 3-chloro-5-[( (difluoromethyl)sulfonyl]benzoic acid (INT-16), 3-cyano-5-cyclop ropylbenzoic acid (INT-15), 3-cyclopropyl-5-methylsulfonyl-benzo ic acid (INT-17), 3-cyclopropyl-5-cyclopropylsulfonyl-benzoic acid ( INT-19) and 3-fluoro-5-methylsulfonyl-benzoic acid (INT-21) and their salts.

[0021] The present invention also includes the intermediate compound of the following general formula (yf′),

Chemical formula

[0022] In the formula, E′ is hydrogen, chlorine or -CN, A is N or CH, and its salts are included. Preferred ones are hydrochloride salts, for example INT-23: 5-[(1S)-1-aminoethyl]-1-(pyrimidin-2-yl) -1H-1,2,4-triazole-3-amine hydrochloride.

[0023] The compound of formula (I) may also exist in the form of stereoisomers, i.e., geometric It may be in the form of an isomer and / or an optical isomer or a mixture of isomers of various compositions. In this specification Even for only the compounds of formula (I) discussed herein, the present invention provides both pure stereoisomers and any desired mixtures of these isomers.

[0024] However, according to the present invention, it is preferable to use the optically active stereoisomeric forms of the compounds of formula (I) and their salts.

[0025] Therefore, the present invention relates to both pure enantiomers and diastereomers, and mixtures thereof, for controlling pest animals including arthropods, especially insects.

[0026] Where appropriate, the compounds of formula (I) may exist in various polymorphic forms or as mixtures of various polymorphic forms. Both pure polymorphs and polymorph mixtures are provided by the present invention and can be used in accordance with the present invention.

DETAILED DESCRIPTION OF THE INVENTION

[0027] Definitions To those skilled in the art, when not explicitly stated, the expressions "a" or " an" used in this application may, depending on the context, mean "1", "1 or more" or "at least 1" as can be understood.

[0028] In all structures described herein, such as ring systems and groups, adjacent atoms shall not be -O-O- or -O-S-.

[0029] Structures having possible carbon atoms (C atoms) for variables are, in this application, C 炭素原子の下 限 -C 炭素原子の上限 structure (C LL -C​UL is called a "(structure)", and by doing so, more specific can be defined. Example: An alkyl group can consist of 3 to 10 carbon atoms, and in that case, it corresponds to C3-C 10 alkyl. A ring structure composed of carbon atoms and heteroatoms may be called an " L-~UL-member" structure. An example of a 6-membered ring structure is toluene (a 6-membered ring structure substituted by a methyl group).

[0030] A general term for substituents, for example, C LL -C UL alkyl, when at the end of a complex substituent such as, for example, C LL -C UL cyclo alkyl-C LL -C UL alkyl, the components at the beginning of the complex substituent, for example, C -C LL -C UL cycloalkyl, can be mono-substituted or multi- substituted, either identically or differently, and independently, by the latter substituent, for example, -C LL -C UL alkyl. All general terms used in this application for chemical groups, ring systems, and cyclic groups can be more specifically defined by adding " LL C~C UL " or "LL-~UL-member". can be 。 In the definitions of the symbols given in the above formula, generally, the following collective terms representing substituents are used.

[0031] Halogens are elements of Group 7, preferably fluorine, chlorine, bromine, and iodine, more preferably fluorine, chlorine, and bromine, and even more preferably fluorine and chlorine.

[0032] Examples of heteroatoms are N, O, S, P, B, Si. Preferably, "heteroatom" and The term relates to N, S and O.

[0033] According to the present invention, "alkyl", by itself or as part of a chemical group, preferably represents a straight-chain or branched hydrocarbon having 1 to 6 carbon atoms, such as methyl, ethyl, n-prop yl, isopropyl, n-butyl, isobutyl, s-butyl, t-butyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,2-dimethylpropyl, 1,1-dimethylpropyl, 2,2-dimethylpropyl, 1-ethylpropyl, hexyl , 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl , 1,2-dimethylpropyl, 1,3-dimethylbutyl, 1,4-dimethylbutyl, 2, 3-dimethylbutyl, 1,1-dimethylbutyl, 2,2-dimethylbutyl, 3,3-dime thylbutyl, 1,1,2-trimethylpropyl, 1,2,2-trimethylpropyl, 1- ethylbutyl and 2-ethylbutyl. Preferred are alkyls having 1 to 4 carbon atoms , especially for example methyl, ethyl, ethyl, n-propyl, isoprop yl, n-butyl, isobutyl, s-butyl or t-butyl. The alkyl of the present invention may be substituted with one or more identical or different groups.

[0034] According to the present invention, "alkenyl", by itself or as part of a chemical group, preferably represents a straight-chain or branched hydrocarbon having 2 to 6 carbon atoms and at least one double bond , such as vinyl, 2-propenyl, 2-butenyl, 3-butenyl, 1-methyl-2-pro penyl, 2-methyl-2-propenyl, 2-pentenyl, 3-pentenyl, 4-pentenyl Ru, 1-methyl-2-butenyl, 2-methyl-2-butenyl, 3-methyl-2-butenyl , 1-methyl-3-butenyl, 2-methyl-3-butenyl, 3-methyl-3-butenyl, 1,1-dimethyl-2-propenyl, 1,2-dimethyl-2-propenyl, 1-ethyl- 2-propenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl, 1-methyl-2-pentenyl, 2-methyl-2-pentenyl, 3-methyl-2-penten yl, 4-methyl-2-pentenyl, 3-methyl-3-pentenyl, 4-methyl-3-pen tenyl, 1-methyl-4-pentenyl, 2-methyl-4-pentenyl, 3-methyl-4- pentenyl, 4-methyl-4-pentenyl, 1,1-dimethyl-2-butenyl, 1,1- dimethyl-3-butenyl, 1,2-dimethyl-2-butenyl, 1,2-dimethyl-3-b tenyl, 1,3-dimethyl-2-butenyl, 2,2-dimethyl-3-butenyl, 2,3- dimethyl-2-butenyl, 2,3-dimethyl-3-butenyl, 1-ethyl-2-butenyl , 1-ethyl-3-butenyl, 2-ethyl-2-butenyl, 2-ethyl-3-butenyl, 1,1,2-trimethyl-2-propenyl, 1-ethyl-1-methyl-2-propenyl and 1-ethyl-2-methyl-2-propenyl. Preferred are alkenyls having 2 to 4 carbon atoms, and particularly, for example, 2-propenyl, 2-butenyl or 1 -methyl-2-propenyl. The alkenyl of the present invention may be substituted with one or more identical or different groups.

[0035] According to the present invention, "alkynyl" represents, by itself or as part of a chemical group, preferably a straight-chain or branched hydrocarbon having 2 to 6 carbon atoms and at least one triple bond. , for example, 2-propynyl, 2-butynyl, 3-butynyl, 1-methyl-2-propynyl, 2-pentynyl, 3-pentynyl, 4-pentynyl, 1-methyl-3-butynyl, 2-me thyl-3-butynyl, 1-methyl-2-butynyl, 1,1-dimethyl-2-propynyl, 1-ethyl-2-propynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, 5- hexynyl, 1-methyl-2-pentynyl, 1-methyl-3-pentynyl, 1-methyl- 4-pentynyl, 2-methyl-3-pentynyl, 2-methyl-4-pentynyl, 3-meth yl-4-pentynyl, 4-methyl-2-pentynyl, 1,1-dimethyl-3-butynyl, 1,2-dimethyl-3-butynyl, 2,2-dimethyl-3-butynyl, 1-ethyl-3- butynyl, 2-ethyl-3-butynyl, 1-ethyl-1-methyl-2-propynyl and 2 ,5-hexadiynyl. Preferably, there are also alkynyls having 2 to 4 carbon atoms, especially, for example, ethynyl, 2-propynyl or 2-butynyl-2-propenyl yl. The alkynyl of the present invention may be substituted with one or more identical or different groups.

[0036] According to the present invention, "cycloalkyl" represents, by itself or as part of a chemical group, preferably a monocyclic, bicyclic or tricyclic hydrocarbon having 3 to 10 carbons, for example, cyclo propyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclo octyl, bicyclo[2.2.1]heptyl, bicyclo[2.2.2]octyl or adamantyl yl. Preferably, there are also alkenyls having 3, 4, 5, 6 or 7 carbon atoms, especially, for example, cyclopropyl or cyclobutyl. The cycloalkyl of the present invention The "kill" may be substituted with one or more identical or different groups.

[0037] According to the present invention, "alkylcycloalkyl" preferably represents a monocyclic, bicyclic or tricyclic alkylcycloalkyl having 4 to 10 or 4 to 7 carbon atoms, such as methylcyclopropyl, ethylcyclopropyl, isopropylcyclobutyl, 3-methylcyclopentyl and 4-methylcyclohexyl. Preferred are also alkylcycloalkyls having 4, 5 or 7 carbon atoms, especially, for example, ethylcyclopropyl or 4-methylcyclohexyl. The alkylcycloalkyl of the present invention may be substituted with one or more identical or different groups.

[0038] According to the present invention, "cycloalkylalkyl" preferably represents a monocyclic, bicyclic or tricyclic cycloalkylalkyl having 4 to 10 or 4 to 7 carbon atoms, such as cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, cyclohexylmethyl and cyclopentylethyl. Preferred are also cycloalkylalkyls having 4, 5 or 7 carbon atoms such as, especially, cyclopropylmethyl or cyclobutylmethyl. The cycloalkylalkyl of the present invention may be substituted with one or more identical or different groups.

[0039] According to the present invention, "hydroxyalkyl" preferably represents a straight-chain or branched alcohol having 1 to 6 carbon atoms such as, for example, methanol, ethanol, n-propanol, isopropanol, n-butanol, isobutanol, s-butanol and t-butanol is. Preferably, a hydroxyalkyl group having 1 to 4 carbon atoms is also present. The hydroxyalkyl group of the present invention may be substituted by one or more identical or different groups and may be.

[0040] According to the present invention, "alkoxy" preferably represents a linear or branched O-alkyl having 1 to 6 carbon atoms, for example, methoxy, ethoxy, n-propoxy, isopropoxy , n-butoxy, isobutoxy, s-butoxy and t-butoxy. Preferably There is also an alkoxy group having 1 to 4 carbon atoms. The alkoxy group of the present invention may be substituted by one or more identical or different groups. and may be.

[0041] According to the present invention, "alkylthio" or "alkylsulfanyl" preferably represents a linear or branched S-alkyl having 1 to 6 carbon atoms, for example, methylthio, ethylthio , n-propylthio, isopropylthio, n-butylthio, isobutylthio, s-butylthio , t-butylthio and t-butylthio. Preferably, there is also an alkylthio group having 1 to 4 carbon atoms. The alkylthio group of the present invention may be substituted by one or more identical or different groups and may be. and may be.

[0042] According to the present invention, "alkylsulfinyl" preferably represents a linear or branched alkylsulfinyl having 1 to 6 carbon atoms, for example, methylsulfinyl, ethyl sulfinyl, n-propylsulfinyl, isopropylsulfinyl, n-butylsulfinyl , isobutylsulfinyl, s-butylsulfinyl and t-butylsulfinyl . Preferably, there is an alkylsulfinyl group having 1 to 4 carbon atoms and may be. There is also. The alkylsulfinyl group of the present invention may be substituted by one or more identical or different groups and includes both enantiomers.

[0043] According to the present invention, "alkylsulfonyl" preferably represents a linear or branched alkylsulfonyl having 1 to 6 carbon atoms, such as methylsulfonyl, ethylsulfonyl, n-propylsulfonyl, isopropylsulfonyl, n-butylsulfonyl, isobutyl sulfonyl, s-butylsulfonyl and t-butylsulfonyl. Preferably, there is also an alkylsulfonyl group having 1 to 4 carbon atoms. The alkylsulfonyl group of the present invention may be substituted by one or more identical or different groups.

[0044] According to the present invention, "cycloalkylthio" or "cycloalkylsulfanyl" preferably represents -S-cycloalkyl having 3 to 6 carbon atoms, such as cyclopropyl thio, cyclobutylthio, cyclopentylthio, cyclohexylthio. Preferably, there is also a cycloalkylthio group having 3 to 5 carbon atoms. The cycloalkylthio group of the present invention may be substituted by one or more identical or different groups.

[0045] According to the present invention, "cycloalkylsulfinyl" preferably represents -S(O)-cycloalkyl having 3 to 6 carbon atoms, such as cyclopropylsulfinyl, cyclobutylsulfinyl, cyclopentylsulfinyl, cyclohexylsulfinyl. Preferably, there is also a cycloalkylsulfinyl group having 3 to 5 carbon atoms. There is also a basis. The cycloalkylsulfinyl group of the present invention may be substituted by one or more identical or different groups and includes both enantiomers.

[0046] According to the present invention, "cycloalkylsulfonyl" preferably represents -SO2-cycloalkyl having 3 to 6 carbon atoms, for example, cyclopropylsulfonyl, cyclobutylsulfonyl, cyclopentylsulfonyl, cyclohexylsulfonyl. Preferably, there is also a cycloalkylsulfonyl group having 3 to 5 carbon atoms. The cycloalkylsulfonyl group of the present invention may be substituted by one or more identical or different groups.

[0047] According to the present invention, "phenylthio" or "phenylsulfanyl" represents -S-phenyl, for example, phenylthio. The phenylthio group of the present invention may be substituted by one or more identical or different groups.

[0048] According to the present invention, "phenylsulfinyl" represents -S(O)-phenyl, for example, phenylsulfinyl. The phenylsulfinyl group of the present invention may be substituted by one or more identical or different groups and includes both enantiomers.

[0049] According to the present invention, "phenylsulfonyl" represents -SO2-phenyl, for example, phenylsulfonyl. The phenylsulfonyl group of the present invention may be substituted by one or more identical or different groups.

[0050] According to the present invention, "alkylcarbonyl" preferably has 2 to 7 carbon atoms. represents a straight or branched alkyl-C(=O), such as methylcarbonyl, ethylcarbonyl, etc. , n-propyl carbonyl, isopropyl carbonyl, s-butyl carbonyl and t-butyl Preferred are alkylcarbonyl having 1 to 4 carbon atoms. The alkylcarbonyl of the present invention is substituted with one or more identical or different groups. It may be replaced.

[0051] According to the present invention, "alkoxycarbonyl" alone or as a component of a chemical group means: Preferably, the alkoxy moiety is a straight-chain or represents a branched alkoxycarbonyl, such as methoxycarbonyl, ethoxycarbonyl, n-propoxycarbonyl, isopropoxycarbonyl, s-butoxycarbonyl and t The alkoxycarbonyl group of the present invention is one or more of the same or different It may be substituted by a group.

[0052] According to the present invention, "alkylaminocarbonyl" preferably has 1 to 6 alkyl groups in the alkyl portion. A straight or branched alkylaminocarbonyl group having 1 to 4 carbon atoms. For example, methylaminocarbonyl, ethylaminocarbonyl, n-propylaminocarbonyl, aminocarbonyl, isopropylaminocarbonyl, s-butylaminocarbonyl and t- The alkylaminocarbonyl group of the present invention is one or more identical Or it may be substituted with a different group.

[0053] According to the present invention, "N,N-dialkylaminocarbonyl" preferably comprises an alkyl moiety. Straight-chain or branched N,N-dialkylamine having 1 to 6 carbon atoms or 1 to 4 carbon atoms in a moiety represents a kill amino carbonyl, for example, N,N-dimethylamino carbonyl, N,N-di ethylamino carbonyl, N,N-di(n-propylamino)carbonyl, N,N-di(i sopropylamino)carbonyl and N,N-di-(s-butylamino)carbonyl. The N,N-dialkylamino carbonyl group of the present invention may be substituted by one or more identical or different groups.

[0054] According to the present invention, "aryl" preferably represents a monocyclic, bicyclic or polycyclic aromatic system having 6 to 14, particularly 6 to 10 ring carbon atoms, for example, phenyl, naphthyl, anth ryl, phenanthrenyl, preferably phenyl. Further, aryl also represents polycyclic systems such as tetrahydronaphthyl, indenyl, indanyl, fluorenyl, biphenyl, etc., and the bonding site is on the aromatic system. The aryl group of the present invention may be substituted by one or more identical or different groups.

[0055] Examples of substituted aryl are arylalkyl, which can be similarly substituted by one or more identical or different groups in the C1-C4 alkyl and / or the C6-C aryl moiety. Examples of such arylalkyl include benzyl and phenyl-1-ethyl. 14

[0056] According to the present invention, "heterocyclic ring", "heterocyclic ring system" or "heterocyclic ring system" means that at least one carbon atom is replaced by a heteroatom, preferably a heteroatom from the group consisting of N, O, S, P, B, Si, Se, and is saturated, unsaturated or heteroaromatic, and may or may not be substituted, and the bonding site is on the ring atom, at least ​​​​​​​​​​It represents a carbocyclic system having one ring. Unless otherwise defined, the heterocyclic ring preferably has 3 ~9 ring atoms, particularly 3~6 ring atoms, and contains one or more, preferably 1 ~4, particularly 1, 2 or 3 heteroatoms from the group consisting of N, O and S, but two oxygen atoms must not be directly adjacent. The heterocyclic ring usually contains 4 or fewer nitrogen atoms and / or or 2 or fewer oxygen atoms and / or 2 or fewer sulfur atoms. If the heterocyclic group or heterocyclic ring may be substituted, it may be condensed with another carbocyclic or heterocyclic ring. In the case of a heterocyclic ring that may be substituted, the present invention also includes polycyclic systems, such as 8-azabicyclo[3.2 .1]octanyl or 1-azabicyclo[2.2.1]heptyl. In the case of a heterocyclic ring that may be substituted, the present invention also includes spiro ring systems, such as 1-oxa-5-azaspiro 2.3]hexyl. . The heterocyclic groups of the present invention are, for example, piperidinyl, piperazinyl, morpholinyl, thiomorph olinyl, dihydropyranyl, tetrahydropyranyl, dioxanyl, pyrrolinyl, pyr

[0057] rolyl, imidazolinyl, imidazolidinyl, thiazolidinyl, oxazolidinyl, di oxolanyl, dioxolyl, pyrazolidinyl, tetrahydrofuranyl, dihydrofuranyl l, oxetanyl, oxiranyl, azetidinyl, aziridinyl, oxazetidinyl, o xaziridinyl, oxazepanyl, oxazinanyl, azepanyl, oxopyrrolidinyl, dioxopyrrolidinyl, oxomorpholinyl, oxopiperazinyl and oxazepanyl. Particularly important is heteroaryl, i.e., a heteroaromatic system. According to the present invention, .

[0058] ... The term "heteroaryl" refers to a heteroaromatic compound, i.e., a fully unsaturated aromatic heterocyclic compound that meets the above definition of a heterocycle. Preferred are 5- to 7-membered rings having 1 to 3, preferably 1 or 2, identical or different heteroatoms from the above group. The heteroaryl of the present invention is, for example, furyl, thienyl, pyrazolyl, imidazolyl, 1,2 ,3- and 1,2,4-triazolyl, isoxazolyl, thiazolyl, isothiazolyl , 1,2,3-, 1,3,4-, 1,2,4- and 1,2,5-oxadiazolyl, azepinyl, pyrrolyl, pyridyl, pyridazinyl, pyrimidinyl, pyrazinyl, 1,3,5- , 1,2,4- and 1,2,3-triazinyl, 1,2,4-, 1,3,2-, 1,3, 6- and 1,2,6-oxazinyl, oxepinyl, thiepinyl, 1,2,4-triazolonyl and 1,2,4-diazepinyl. The heteroaryl group of the present invention may be substituted by one or more identical or different groups. The term "optionally substituted in each case" means that a group / substituent such as an alkyl, alkenyl, alkynyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, cycloalkyl, aryl, phenyl, benzyl, heterocycle and heteroaryl group is substituted, which means that, for example, a substituent, for example one substituent or a plurality of substituents, preferably 1, 2, 3, 4, 5, 6 or 7 substituents, is amino, hydroxy syl, halogen, nitro, cyano, isocyano, mercapto, isothiocyanato, C1- C4 carboxyl, carbonamide, SF5, aminosulfonyl, C1-C4 alkyl, C1-C4 haloalkyl, C3-C4 cycloalkyl, C2-C4 alkenyl, C5-C The heteroaryl of the present invention is, for example, furyl, thienyl, pyrazolyl, imidazolyl, 1,2 or 2, identical or different heteroatoms from the above group. The heteroaryl group of the present invention may be substituted by one or more identical or different groups.

[0059] The term "optionally substituted in each case" means that a group / substituent such as an alkyl, alkenyl, alkynyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, cycloalkyl, aryl, phenyl, benzyl, heterocycle and heteroaryl group is substituted, which means that, for example, a substituent, for example one substituent or a plurality of substituents, preferably 1, 2, 3, 4, 5, 6 or 7 substituents, is amino, hydroxy syl, halogen, nitro, cyano, isocyano, mercapto, isothiocyanato, C1- C4 carboxyl, carbonamide, SF5, aminosulfonyl, C1-C4 alkyl, C1-C4 haloalkyl, C3-C4 cycloalkyl, C2-C4 alkenyl, C5-C substituents, preferably 1, 2, 3, 4, 5, 6 or 7 substituents, is amino, hydroxy syl, halogen, nitro, cyano, isocyano, mercapto, isothiocyanato, C1- C4 carboxyl, carbonamide, SF5, aminosulfonyl, C1-C4 alkyl, C1-C4 haloalkyl, C3-C4 cycloalkyl, C2-C4 alkenyl, C5-C 6-cycloalkenyl, C2-C4 alkynyl, N-mono-C1-C4 alkylamino, N ,N-di-C1-C4 alkylamino, N-C1-C4 alkanoylamino, C1-C4 alkoxy, C1-C4 haloalkoxy, C2-C4 alkenyloxy, C2-C4 al kynyloxy, C3-C4 cycloalkoxy, C5-C6 cycloalkenyloxy, C1 -C4 alkoxycarbonyl, C2-C4 alkenyloxycarbonyl, C2-C4 al kynyloxycarbonyl, C6-,C 10 ,C 14 -aryloxycarbonyl, C1 -C4 alkanoyl, C2-C4 alkenylcarbonyl, C2-C4 alkynylcarbonyl , C6-,C 10 ,C 14 -arylcarbonyl, C1-C4 alkylthio, C1- C4 haloalkylthio, C3-C4 cycloalkylthio, C2-C4 alkenylthio, C 5-C6 cycloalkenylthio, C2-C4 alkynylthio, C1-C4 alkylsulf inyl (including both enantiomers of the C1-C4 alkylsulfinyl group), C1-C 4 haloalkylsulfinyl (including both enantiomers of the C1-C4 haloalkylsulfinyl group), C1-C4 alkylsulfonyl, C1-C4 haloalkylsulfonyl, N-mono-C1-C4 alkylaminosulfonyl, N,N-di-C1-C4 alkylami nosulfonyl, C1-C4 alkylphosphinyl, C1-C4 alkylphosphonyl (C1 -C4 alkylphosphinyl and both enantiomers of C1-C4 alkylphosphonyl), N-C1-C4 alkylaminocarbonyl, N,N-di-C1-C4 alkyl aminocarbonyl, N-C1-C4 alkanoylaminocarbonyl, N-C1-C4 al 4 alkylaminocarbonyl, N,N-di-C1-C4 alkyl aminocarbonyl, N-C1-C4 alkanoylaminocarbonyl, N-C1-C4 al Canoil-N-C1-C4 alkylaminocarbonyl, C6-, C 10 -, C 14 -aryl -yl, C6-, C 10 -, C 14 -aryloxy, benzyl, benzyloxy, benzy lthio, C6-, C 10 -, C 14 -arylthio, C6-, C 10 -, C 14 -ary lamino, benzylamino, heterocycle and trialkylsilyl, bonded via a double bond substituents, such as C1-C4 alkylidene (e.g., methylidene or ethylidene), oxo groups, imino groups and substituted imino groups, selected from the group consisting of, unsubstituted basic structures derived from substituted groups. When two or more groups form one or more rings, these can be carbocyclic, heterocyclic, saturated, partially saturated, unsaturated, for example aromatic rings exist, and are further substituted. The substituents mentioned by way of example ("first substituent level") are when they contain a hydrocarbonaceous component, for example each independently halogen, hydroxyl, amino, nitro, cyano, isocyano, azide, acylamino, oxo groups and imino groups selected from one or more of the substituents, further substitution therewith ("second substituent level") may have. The term "substituted (optionally substituted)" group preferably includes only one or two substituent levels.

[0060] The halogen-substituted chemical groups or halogenated groups (e.g., alkyl or alkoxy silyl) of the present invention are mono-substituted or polysubstituted up to the maximum number of possible substituents by halogen. Such groups are also referred to as halo groups (e.g., haloalkyl). Polysubstitution by halogen In this case, the halogen atoms may be the same or different, and all may be bonded to one carbon atom, or may be bonded to a plurality of carbon atoms. Halogen is particularly fluorine, chlorine, bromine or iodine, preferably fluorine, chlorine or bromine, more preferably fluorine. Specifically, the halogen-substituted group is monohalocycloalkyl, such as 1-fluorocyclopropyl, 2-fluorocyclopropyl or 1-fluorocyclobutyl, monohaloalkyl, such as 2-chloroethyl, 2-fluoroethyl, 1-chloroethyl, 1-fluoroethyl, chloromethyl, or fluoromethyl; perhaloalkyl, such as trichloromethyl or trifluoromethyl or CF2CF3, polyhaloalkyl, such as difluoromethyl, 2-fluoro-2-chloroethyl, dichloromethyl, 1,1,2,2-tetrafluoroethyl or 2,2,2-trifluoroethyl. Further examples of haloalkyl are trichloromethyl, chlorodifluoromethyl, dichlorofluoromethyl, chloromethyl, bromomethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2,2,2-trichloroethyl, 2-chloro-2,2-difluoroethyl, pentafluoroethyl, 3,3,3-trifluoropropyl and pentafluoro-t-butyl. Preferred are haloalkyls having 1 to 4 carbon atoms and 1 to 9, preferably 1 to 5, identical or different halogen atoms selected from fluorine, chlorine and bromine. Particularly preferred are those having 1 or 2 carbon atoms and 1 to 5 identical or different halogen atoms selected from fluorine and chlorine. is a haloalkyl, especially difluoromethyl, trifluoromethyl or 2,2-dif luoroethyl. Further examples of halogen-substituted compounds are haloalkoxy, e.g. OCF3, OCHF2, OCH2F, OCF2CF3, OCH2CF3, OCH2CH F2 and OCH2CH2Cl, haloalkylsulfanyl, e.g. difluoromethylthio , trifluoromethylthio, olichloromethylthio, chlorodifluoromethylthio, 1- fluoroethylthio, 2-fluoroethylthio, 2,2-difluoroethylthio, 1,1 ,2,2-tetrafluoroethylthio, 2,2,2-trifluoroethylthio or 2-ch loro-1,1,2-trifluoroethylthio, haloalkylsulfinyl, e.g. diflu oromethylsulfinyl, trifluoromethylsulfinyl, olichloromethylsulfinyl , chlorodifluoromethylsulfinyl, 1-fluoroethylsulfinyl, 2-fluoroethylsulfinyl , 2,2-difluoroethylsulfinyl, 1,1,2,2- tetrafluoroethylsulfinyl, 2,2,2-trifluoroethylsulfinyl and 2-chloro-1,1,2-trifluoroethylsulfinyl, haloalkylsulfonyl , e.g. difluoromethylsulfonyl, trifluoromethylsulfonyl, olichloromethylsulfonyl , chlorodifluoromethylsulfonyl, 1-fluoroethylsulfonyl, 2-fluoroethylsulfonyl , 2,2-difluoroethylsulfonyl, 1 ,1,2,2-tetrafluoroethylsulfonyl, 2,2,2-trifluoroethylsulfonyl and 2-chloro-1,1,2-trifluoroethylsulfonyl, haloalkylsulfonyl groups, e.g. difluoromethylsulfonyl, trifluoromethylsulfonyl, O-chloromethylsulfonyl, chlorodifluoromethylsulfonyl, 1-fluoroethyl sulfonyl, 2-fluoroethylsulfonyl, 2,2-difluoroethylsulfonyl, 1 ,1,2,2-tetrafluoroethylsulfonyl, 2,2,2-trifluoroethylsulf onyl and 2-chloro-1,1,2-trifluoroethylsulfonyl.

[0061] In the case of a group having a carbon atom, a group having 1 to 4 carbon atoms, particularly 1 or 2 carbon atoms is preferred. Preferred are usually substituents from the group of halogen, for example fluorine and chlorine, (C 1-C4)alkyl, preferably methyl or ethyl, (C1-C4)haloalkyl, preferably trifluoromethyl, (C1-C4)alkoxy, preferably methoxy or ethoxy , (C1-C4)haloalkoxy, nitro and cyano. Here , particularly preferred are the substituents methyl, methoxy, fluorine and chlorine.

[0062] Substituted aminos such as mono-substituted amino or di-substituted amino are, for example, alkyl, hydro xy, amino, alkoxy, acyl and aryl; preferably N-mono- and N,N-di alkylamino, (for example, methylamino, ethylamino, N,N-dimethylamino, N ,N-diethylamino, N,N-di-n-propylamino, N,N-diisopropylamino no or N,N-dibutylamino), N-mono- or N,N-dialkoxyalkylamino groups (for example N-methoxymethylamino, N-methoxyethylamino, N,N-di(methoxy methyl)amino or N,N-di(methoxyethyl)amino), N-mono- and N,N- diarylamino, for example optionally substituted anilines, acylamino, N,N-di Acylamino, N-alkyl-N-aryl amino, N-alkyl-N-acyl amino, further N-substituted by one or two identical or different groups from the group of saturated N-heterocycles means a group from the group of substituted amino groups, where preferably an alkyl group having 1 to 4 carbon atoms; here, aryl is preferably phenyl or substituted phenyl; for acyl, the definition further provided below applies, preferably (C1-C4)-alkanoyl. The same applies to substituted hydroxyl amino or hydrazino.

[0063] Substituted amino includes quaternary ammonium compounds (salts) having four organic substituents on the nitrogen atom .

[0064] Optionally substituted phenyl is preferably unsubstituted or halogen, (C 1-C4) alkyl, (C1-C4) alkoxy, (C1-C4) alkoxy-(C1- C4) alkoxy, (C1-C4) alkoxy-(C1-C4) alkyl, (C1-C4 ) haloalkyl, (C1-C4) haloalkoxy, (C1-C4) alkylthio, (C1 -C4) haloalkylthio, (C1-C4) alkylsulfinyl (C1-C4) haloalkylsulfinyl, (C1-C4) alkylsulfonyl (C1-C4) haloalkylsulfonyl, cyano, isocyano and nitro, for example o-, m- and p-tolyl, dimethyl phenyls, 2-, 3- and 4-chlorophenyl, 2-, 3- and 4-fluorophenyl , 2-, 3- and 4-trifluoromethyl- and 4-olichloromethylphenyl, 2,4 -, 3,5-, 2,5- and 2,3-dichlorophenyl, o-, m- and p-methoxyp henyl, etc. monosubstituted or polysubstituted, preferably trisubstituted, by the same or different groups from the group of phenyl, 4-heptafluorophenyl is phenyl.

[0065] Optionally substituted cycloalkyl is preferably unsubstituted or mono- or polysubstituted, preferably trisubstituted, by the same or different groups from the group of halogen, cyano, (C1-C4)alkyl, (C1-C4)alkoxy, (C1-C4)alk oxy-(C1-C4)alkoxy, (C1-C4)alkoxy-(C1-C4)alkyl , (C1-C4)haloalkyl and (C1-C4)haloalkoxy, especially by the same or different groups from the group of one or two (C1-C4)alkyl groups. is cycloalkyl.

[0066] The compounds of the invention can occur in preferred embodiments. The individual embodiments described herein can be combined with each other. Combinations that violate the laws of nature and would thus be excluded by a person skilled in the art based on their expertise are not included. For example, a ring structure having three or more adjacent oxygen atoms is excluded.

[0067] Isomers Depending on the nature of the substituents, the compounds of formula (I) can be in the form of geometric isomers and / or optically active isomers or corresponding isomer mixtures in different compositions. These stereoisomers are, for example, enantiomers, diastereomers, atropisomers or geometric isomers. Thus, the invention encompasses both pure stereoisomers and any mixtures of these isomers. .

[0068] Methods and uses The present invention relates to a method for controlling pest animals, which comprises applying a compound of formula (I) to the pest animals and / or their habitats. Such control of pest animals is preferably carried out in agriculture and forestry, as well as in the protection of materials. Preferably, surgical treatment or therapeutic treatment methods of the human or animal body, as well as diagnostic methods carried out on the human or animal body, are excluded therefrom.

[0069] The present invention further relates to the use of a compound of formula (I) as a crop protection agent, in particular as a pesticide.

[0070] In the context of the present application, the term "pesticide" always includes, in each case, the term "crop protection agent".

[0071] Compounds of formula (I) having good plant tolerance have a desirable degree of toxicity to warm-blooded animals, exhibit good environmental compatibility, are suitable for protecting plants and plant organs against biotic stress factors and abiotic stress factors, are suitable for increasing the yield, are suitable for improving the quality of the harvested product, and are also suitable for controlling pests encountered in agriculture, horticulture, animal husbandry, hydroponics, forests, gardens and leisure facilities, the protection of stored products and materials, and in the field of hygiene, in particular insects, arachnids, worms, in particular nematodes and molluscs. In the context of the present patent application, the term "hygiene" means all means, procedures and practices which serve the purpose of preventing diseases, in particular infectious diseases, and of protecting the health of humans and animals and / or of protecting the environment and / or of maintaining cleanliness.

[0072] It is understood. According to the present invention, this particularly includes, for example, textile or hard surfaces, especially glass, wood, concrete, porcelain, ceramic, plastic surfaces, or metal surfaces, and means for cleaning, disinfecting and sterilizing them to keep them free of sanitary pests and / or their excreta. Preferably, in this context, surgical or therapeutic procedures that can be performed on the human or animal body, and diagnostic procedures performed on the human or animal body are excluded from the scope of the present invention.

[0073] Accordingly, the term "sanitary sector" includes, for example, all areas, technical fields and industrial applications where these sanitary means, procedures and practices are important in relation to hygiene in kitchens, bakeries, airports, bathrooms, swimming pools, department stores, hotels, hospitals, livestock houses, livestock farming, etc.

[0074] Therefore, the term "sanitary pest" is understood to mean one or more pest animals that are particularly problematic in the sanitary sector for health reasons. Therefore, the main purpose is to avoid or minimize the presence and / or exposure to sanitary pests in the sanitary sector This can be achieved, in particular, by applying pesticides that can be used both to prevent entry and to deal with existing infestations. Agents that avoid or reduce exposure to pest organisms can also be used. Sanitary pest insects include, for example, the following organisms.

[0075] Therefore, the term "sanitary protection" encompasses all activities for maintaining and / or improving these sanitary means, procedures and practices.

[0076] ​​​​​​​​​The compounds of formula (I) can preferably be used as pesticides. They are active against susceptible and resistant species and at all or some stages of development . The above-mentioned pest organisms are as follows.

[0077] Pests of the phylum Arthropoda, in particular of the class Arachnida, such as species of the genus Acarus ( Acarus spp.), such as Acarus siro, Aceria kuko, Aceria she ldoni, species of the genus Aculops, species of the genus Acul us spp.), such as Aculus fockeui , Aculus schlechtendali, species of the genus Amblyomma, Amphitetranychus viennensis , species of the genus Argas, species of the genus Boophilus, Brevipal pus spp.), such as Brevipalpus phoenicis , Bryobia graminum, Bryobia praet iosa, species of the genus Centruroides, species of the genus Chorioptes, Dermanyssus gallinae , Brevipalpus phoenicis, Bryobia graminum, Bryobia praetiosa , Dermatophagoides pteronyssinus, Dermatophagoides far , Dermatophagoides pteronyssinus, Dermatophagoides farinae , species of the genus Centruroides, species of the genus Chorioptes, Dermanyssus gallinae , species of the genus Chorioptes, Dermanyssus gallinae, Dermatophagoides pteronyssinus , Dermatophagoides pteronyssinus, Dermatophagoides farinae inae, etc. Dermatophagoides farinae, Dermacentor spp. , Eotetranychus spp., for example, Eotetranychus hicoriae , Epitrimerus pyri , Eutetranychus spp., for example, Eutetranychus banksi , Eriophyes spp., for example, Eriophyes pyri , Glycyphagus domesticus , Halotydeus destructor , Hemitarsonemus spp., for example, Hemitarsonemus latus (= Polyphagotarsonemus latus) , Hyalomma spp., Ixodes spp., Latrodectus spp., Loxosceles spp., Neutrombicula autumnalis , Nuphersa spp., Oligonychus spp., for example, Oligonychus coffeae, Oligonychus con , etc. , etc. , etc. , etc. , etc. , etc. , etc. ​Oligonychus coniferarum, Oligonychus ilicis Oligonychus ilicis, Oligonychus indicus Oligonychus indicus, Oligonychus mangiferus Oligonychus mangiferus, Oligonychus pratensis Oligonychus pratensis, Oligonychus punicae Oligonychus punicae, Oligonychus yothersi ) Ornithodorus spp., Ornithonyssus spp (Ornithonyssus spp.), Panonychus spp ), e.g., Panonychus citri (=Metatetranychus citri) ), Panonychus ulmi (=Metatetranychus ulmi) (Metatetranychus ulmi)), Phyllocoptruta oleivora (Phyllocoptruta oleivora), Platytetranychus multidigituli (Platytetranychus multidigituli), Polyphagotarsonemus latus (Polyphagotarsonemus latus), Psoroptes spp (Psoroptes spp.), Rhipicephalus spp (Rhipicephalus spp.), Rhizoglyphus spp (Rhizoglyphus spp.), Sarcoptes spp (Sarcoptes spp.), Scorpio maurus ), Steneotarsonemus sp p.), Steneotarsonemus spin nki), Tarsonemus spp., e.g., Tarsonem us confusus, Tarsonemus pallidus (Tarsonemus pallidus), Tetranychus spp. us spp.), e.g., Tetranychus canadensis (Tetranychus canadensis), Tetranychus cinnabarinus (Tetranychus cinnabarinus), Tetranychus turkestani (Tetranychus turkestani), Tetranychus urticae (Tetranychus urticae), Trombicula alfreddugesi (Trombicula alfreddugesi), Vaejovis spp., Vasates lycopersici (Vasates lycopersici); Of Chilopoda, e.g., Geophilus spp. (Geophilus spp.), Scutigera spp.; Of Collembola or Collembola, e.g., e.g., Onychiurus armatus (Onychiurus armatus); Sminthurus viridis (Sminthurus viridis); Of Diplopoda, e.g., Blaniulus guttulatus (Blaniulus guttulatus); Of Insecta, e.g., of Blattodea, e.g , Blatta orientalis, Blattela a Blattella asahinai, Blattella germanica Leucophaea maderae Loboptera decipiens Neostylopyga rhombifolia Panchlora spp., Parcoblatta spp., Periplaneta spp., for example, Periplaneta americana, Periplaneta australasiae, Pycnoscelus surinamensis, Supella longipalpa (Parcoblatta spp.), Periplaneta spp. spp.), for example, Periplaneta americana Periplaneta australasiae Pycnoscelus surinamensis Supella longipalpa ; Coleoptera, for example, Acalymma vittatum, Acanthoscelides obtectus, Adoretus spp., Aethina tumida, Agelastica alni, Agrilus spp., for example, Agrilus planipennis, Agrilus coxalis, Agrilus bilineatus, Agrilus anxius (Acanthoscelides obtectus), Adoretus spp., Aethina tumida, Agelastica alni Agrilus spp., for example, Agrilus planipennis Agrilus coxalis Agrilus bilineatus Agrilus anxius (us), Agriotes spp., e.g., Agriotes linneatus, Agriotes mancus, Agriotes obscurus, Alphitobius diaperinus, Amphimallon solstitialis, Anobium punctatum, Anomala dubia, Anoplophora spp., e.g., Anoplophora glabripennis, Anthonomus spp., e.g., Anthonomus grandis, Anthrenus spp., Apion spp., Apogonia spp., Athous haemorrhoidales, Atomaria spp., e.g., Atomaria linearis, Attagenus spp., Baris caerulescens, Bruchidius obtectus, Bruchus spp., e.g., Bruchus pisorum, Bruchus rufimanus, Cassida spp., Cero nneatus, Agriotes mancus, Ag riotes mancus), Agriotes obscurus), Alphitobius diaperinus), Amphimallon solstitialis), Anobium punctatum), Anomala dubia), Anoplophora spp.), e.g., Anoplophora glabripennis), Anthonomus spp.), e.g., Anthonomus grandis), Anthrenus spp.), Apion spp.), Apogonia spp.), Athous haemorrhoidales), Atomaria spp.), e.g., Atomaria linearis), Attagenus spp.), Baris caerulescens), Bruchidius obtectus), Bruchus spp.), e.g., Bruchus pisorum), Bruchus rufimanus), Cassida spp.), Cero scurus), Alphitobius diaperinus), Amphimallon solstitialis), Anobium punctatum), Anomala dubia), Anoplophora spp.), e.g., Anoplophora glabripennis), Anthonomus spp.), e.g., Anthonomus grandis), Anthrenus spp.), Apion spp.), Apogonia spp.), Athous haemorrhoidales), Atomaria spp.), e.g., Atomaria linearis), Attagenus spp.), Baris caerulescens), Bruchidius obtectus), Bruchus spp.), e.g., Bruchus pisorum), Bruchus rufimanus), Cassida spp.), Cero stitialis), Anobium punctatum), Anomala dubia), Anoplophora spp.), e.g., Anoplophora glabripennis), Anthonomus spp.), e.g., Anthonomus grandis), Anthrenus spp.), Apion spp.), Apogonia spp.), Athous haemorrhoidales), Atomaria spp.), e.g., Atomaria linearis), Attagenus spp.), Baris caerulescens), Bruchidius obtectus), Bruchus spp.), e.g., Bruchus pisorum), Bruchus rufimanus), Cassida spp.), Cero stitialis), Anobium punctatum), Anomala dubia), Anoplophora spp.), e.g., Anoplophora glabripennis), Anthonomus spp.), e.g., Anthonomus grandis), Anthrenus spp.), Apion spp.), Apogonia spp.), Athous haemorrhoidales), Atomaria spp.), e.g., Atomaria linearis), Attagenus spp.), Baris caerulescens), Bruchidius obtectus), Bruchus spp.), e.g., Bruchus pisorum), Bruchus rufimanus), Cassida spp.), Cero m), Anomala dubia), Anoplophora spp.), e.g., Anoplophora glabripennis), Anthonomus spp.), e.g., Anthonomus grandis), Anthrenus spp.), Apion spp.), Apogonia spp.), Athous haemorrhoidales), Atomaria spp.), e.g., Atomaria linearis), Attagenus spp.), Baris caerulescens), Bruchidius obtectus), Bruchus spp.), e.g., Bruchus pisorum), Bruchus rufimanus), Cassida spp.), Cero plophora spp.), e.g., Anoplophora glabripennis), Anthonomus spp.), e.g., Anthonomus grandis), Anthrenus spp.), Apion spp.), Apogonia spp.), Athous haemorrhoidales), Atomaria spp.), e.g., Atomaria linearis), Attagenus spp.), Baris caerulescens), Bruchidius obtectus), Bruchus spp.), e.g., Bruchus pisorum), Bruchus rufimanus), Cassida spp.), Cero hora glabripennis), Anthonomus spp.), e.g., Anthonomus grandis), Anthrenus spp.), Apion spp.), Apogonia spp.), Athous haemorrhoidales), Atomaria spp.), e.g., Atomaria linearis), Attagenus spp.), Baris caerulescens), Bruchidius obtectus), Bruchus spp.), e.g., Bruchus pisorum), Bruchus rufimanus), Cassida spp.), Cero pp.), e.g., Anthonomus grandis), Anthrenus spp.), Apion spp.), Apogonia spp.), Athous haemorrhoidales), Atomaria spp.), e.g., Atomaria linearis), Attagenus spp.), Baris caerulescens), Bruchidius obtectus), Bruchus spp.), e.g., Bruchus pisorum), Bruchus rufimanus), Cassida spp.), Cero ), Anthrenus spp.), Apion spp.), Apogonia spp.), Athous haemorrhoidales), Atomaria spp.), e.g., Atomaria linearis), Attagenus spp.), Baris caerulescens), Bruchidius obtectus), Bruchus spp.), e.g., Bruchus pisorum), Bruchus rufimanus), Cassida spp.), Cero spp.), Apogonia spp.), Athous haemorrhoidales), Atomaria spp.), e.g., Atomaria linearis), Attagenus spp.), Baris caerulescens), Bruchidius obtectus), Bruchus spp.), e.g., Bruchus pisorum), Bruchus rufimanus), Cassida spp.), Cero ス(Athous haemorrhoidales), Atomaria spp.), e.g., Atomaria linearis), Attagenus spp.), Baris caerulescens), Bruchidius obtectus), Bruchus spp.), e.g., Bruchus pisorum), Bruchus rufimanus), Cassida spp.), Cero ia spp.), e.g., Atomaria linearis), Attagenus spp.), Baris caerulescens), Bruchidius obtectus), Bruchus spp.), e.g., Bruchus pisorum), Bruchus rufimanus), Cassida spp.), Cero s), Attagenus spp.), Baris caerulescens), Bruchidius obtectus), Bruchus spp.), e.g., Bruchus pisorum), Bruchus rufimanus), Cassida spp.), Cero aris caerulescens), Bruchidius obtectus), Bruchus spp.), e.g., Bruchus pisorum), Bruchus rufimanus), Cassida spp.), Cero ius obtectus), Bruchus spp.), e.g., Bruchus pisorum), Bruchus rufimanus), Cassida spp.), Cero ルクス·ピソルム(Bruchus pisorum), Bruchus rufimanus), Cassida spp.), Cero uchus rufimanus), Cassida spp.), Cero Cerotoma trifurcata, Ceutorrhynchus spp. (Ceutorrhynchus spp.), for example, Ceutorrhynchus assimilis Ceutorrhynchus assimilis, Ceutorrhynchus quadridens Ceutorrhynchus quadridens, Ceutorrhynchus rapae (Ceutorrhynchus rapae), Chaetocnema spp. (Chaetocnema spp.), for example, Chaetocnema confinis Chaetocnema confinis, Chaetocnema denticulata Chaetocnema denticulata, Chaetocnema ectypa Cleonus mendicus, Conoderus spp. Conoderus spp., Cosmopolites spp. (Cosmopolites spp.), for example, Cosmopolites sordidus Cosmopolites sordidus, Costelytra zealandica Costelytra zealandica, Ctenicera spp., Curculio spp. (Curculio spp.), for example, Curculio caryae Curculio caryae, Curculio caryatrypes, Curculio obtusus Curculio obtusus, Curculio sayi, Cryptolestes ferrugineus Cryptolestes ferrugineus, Cryptolestes pusillus Cryptolestes pusillus s pusillus), Cryptorhynchus lapathi, Cryptorhynchus mangiferae, Cylindrocopturus spp., Cylindrocopturus adspersus, Cylindrocopturus furnissi, Dendroctonus spp., e.g., Dendroctonus ponderosae, Dermestes spp., Diabrotica spp., e.g., Diabrotica balteata, Diabrotica barberi, Diabrotica undecimpunctata howardi, Diabrotica undecimpunctata undecimpunctata, Diabrotica virgifera virgifera, Diabrotica virgifera zeae, Dichocrocis spp., Dicladispa armigera, Diloboderus spp., Epicaerus spp., Epirak lapathi), Cryptorhynchus mangiferae mangiferae), Cylindrocopturus spp. us spp.), Cylindrocopturus adspersus urus adspersus), Cylindrocopturus furnissi copturus furnissi), Dendroctonus spp. us spp.), e.g., Dendroctonus ponderosae ponderosae), Dermestes spp. rotica spp.), e.g., Diabrotica balteata Diabrotica balteata), Diabrotica barberi ica barberi), Diabrotica undecimpunctata howardi rotica undecimpunctata howardi), Diabrotica undecimp unctata undecimpunctata), Diabrotica virgifera virgifera unctata undecimpunctata), Diabrotica virgifera virgifera virgifera virgifera), Diabrotica virgifera zeae virgifera zeae), Dichocrocis spp. e), Dichocrocis spp., Dicladispa armigera Dicladispa armigera), Diloboderus spp. erus spp.), Epicaerus spp., Epirak Epilachna spp., e.g., Epilachna borealis, Epilachna varivestis, Epitrix spp., e.g., Epitrix cucumeris, Epitrix fuscula, Epitrix hirtipennis, Epitrix sub crinita, Epitrix tuberis, Faustinus spp., Gibbium psylloides, Gnathocerus cornutus, Hellula undalis, Heteronychus arator, Heteronyx spp., Hoplia argentaea, Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypomeces squamosus, Hypothenemus spp., e.g., Hypothenemus hampei, Hypothenemus obscurus, Hypothenemus p ​​​​​​​​Hypothenemus pubescens, Lachnosterna consanguinea Lachnosterna consanguinea, Lasioderma serricorne, Latheticus oryzae Latheticus oryzae, Lathridius spp. Lema spp., Leptinotarsa decemlineata Leptinotarsa decemlineata, Leucoptera spp. For example, Leucoptera coffeella Limonius ectypus, Lissorhoptrus oryzophilus Lissorhoptrus oryzophilus, Listronotus(=Hyperodes s)) spp., Lixus spp., Lupoderes spp. Lupoderes spp., Luperomorpha xanthodera Luperomorpha xanthodera, Lyctus spp., Megacyllene spp., For example, Megacyllene robiniae Megacyllene robiniae, Megascelis spp., Melanotus spp., For example, Melanotus longulus oregonensis Melanotus longulus oregonensis, Meligethes aeneus Meligethes aeneus, Melolontha spp., For example, Melolontha melolontha Melolontha melolontha ha melolontha), Migdolus spp., Mono Monochamus spp., Nauupactus xanthographus (N aupactus xanthographus), Necrobia spp spp.), Neogalerucella spp., Nip tus hololeucus, Oryctes rhinoceros (Oryctes rhinoceros), Orzaephilus surinamensis (Or yzaephilus surinamensis), Orzaephagus oryzae (Or yzaphagus oryzae), Otiorhynchus spp spp.), e.g., Otiorhynchus cribricollis (Otiorhynchus cribricollis), Otiorhynchus ligustici (Otiorhynchus ligustici), Otiorhynchus ov atus, Otiorhynchus rug osostriarus, Otiorhynchus sulcatus (Otiorhynchus sulcatus), Oulema spp., e.g., Oulema mela nopus (Oulema melanopus), Oulema oryzae (Oulema o ryzae), Oxycetonia jucunda ), Phaedon cochleariae, Philo Phyllophaga spp., Phyllophaga helleri (Phyll ophaga helleri), Phyllotreta spp .), for example, Phyllotreta armora ciae, Phyllotreta pusilla, Phyllotreta ramosa, Phyllotreta striolata, Popillia japonica, Premnotrypes spp., Prostephanus truncatus, Psylliodes spp., for example, Psylliodes affinis, Psylliodes chrysocephala, Psylliodes punctulata, Ptinus spp., Rhizobius ventralis, Rhizopertha dominica, Rhynchophorus spp., Rhynchophorus ferrugineus, Rhynchophorus palmarum, Scolytus spp., for example, Scolytus multistriatus, Sinoxylon perforans, Sitophilus spp., for example, Sitophilus and so on, Rhynchophorus palmarum, Scolytus spp., for example, Scolytus multistriatus, Sinoxylon perforans, Sitophilus spp., for example, Sitophilus and so on, Scolytus multistriatus, Sinoxylon perforans, Sitophilus spp., for example, Sitophilus and so on, Sinoxylon perforans, Sitophilus spp., for example, Sitophilus Sitophilus granarius, Sitophilus linearis, Sitophilus oryzae, Sitophilus zeamais, Sphenophorus spp., Stegobium paniceum, Sternechus spp., for example, Sternechus paludatus, Symphyletes spp., Tanymecus spp., for example, Tanymecus dilaticollis, Tanymecus indicus, Tanymecus palliatus, Tenebrio molitor, Tenebrioides mauretanius, Tribolium spp., for example, Tribolium audax, Tribolium castaneum, Tribolium confusum, Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp., for example, Zabrus tenebrioides; Sitophilus linearis, Sitophilus oryzae, Si tophilus oryzae, Sitophilus zeamais, Sitophilus zeamais, Sphenophorus spp., S tegobium paniceum, Sternechus spp. (Sternechus spp.), for example, Stern echus paludatus, Symphyletes s pp., Tanymecus spp., for example, Tanymec us dilaticollis, Tanymecus indic us, Tanymecus palliatus, Tenebrio molito r, Tenebrioides maureta nicus, Tribolium spp., for example, Tribol ium spp., for example, Tribol ium audax, Tribolium castaneum( Tribolium castaneum), Tribolium confusum(Tribol ium confusum), Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp., for example, Zabrus ten ebrioides); Of the order Dermaptera, such as Anisola bis maritime, Forficula auricularia, Labidura riparia ; Of the order Diptera, such as species of the genus Aedes, for example Aedes aegypti, Aedes albopictus (Aedes albopictus), Aedes sti cticus, Aedes vexans, species of the genus Agromyza (Agromyza spp.), for example, Agromyza frontella, Agromyza parvi cornis, species of the genus Anastrepha, species of the genus Anopheles (Anopheles spp.), for example, Anopheles quadrimaculatus (Anopheles quadrimaculatus), Anopheles gambiae (Anopheles gambiae), species of the genus Asphondyli a spp., species of the genus Bactrocera, for example, Bac trocera cucurbitae, Bactrocera dorsalis, Bactrocera oleae (Bactrocera oleae), Bibio hort ulanus, Calliphora erythro cephala), Calliphora vicina, Cerat itis capitata, Chir onomus spp., Chrysomya spp., Chry sops spp., Chrysomyia pluvialis , Cochliomya spp. , Contarinia spp., e.g., Contarinia john soni, Contarinia nasturtii , Contarinia pyrivora, Contarinia sch ulzi, Contarinia sorghicola , Contarinia tritici, Cordylobia anthropophaga, Cricotopus sylvestris, Culex spp., e.g., Culex pipien s, Culex quinquefasciatus , Culicoides spp., Culiceta spp., Cuterebra spp., Dacus oleae, Dasineura spp. , e.g., Dasineura brassicae, De ​​​ Delia spp., such as Delia antiqua, Delia coarctata, Delia florilega, Delia platura, Delia radicum, Dermatobia hominis, Drosophila spp., such as Drosophila melanogaster, Drosophila suzukii, Echinocnemus spp., Euleia heraclei, Fannia spp., Gasterophilus spp., Glossina spp., Haematopota spp., Hydrellia spp., Hydrellia griseola, Hylemya spp., Hippobosca spp., Hypoderma spp., Liriomyza spp., such as Liriomyza brassicae, Liriomyza huidobrensis, Liriomyza sativae, Lucilia spp. iqua), Delia coarctata, Delia flo rileaga), Delia platura, Delia radicum, Dermatobia hominis, Drosophila spp., such as Drosophila mela nogaster), Drosophila suzukii (Dermatobia hominis), Drosophila spp. spp.), such as Drosophila melanogaster ), Drosophila suzukii ), Echinocnemus spp., Euleia heraclei, Fannia spp., Gasterophilus spp., Glossina spp., Haematopota spp. (Euleia heraclei), Fannia spp. , Gasterophilus spp., Glossina spp., Haematopota spp. (Glossina spp.), Haematopota spp. ), Hydrellia spp., Hydrellia griseola, Hylemya spp., Hippobosca spp., Hypoderma spp., Liriomyza spp. (Hydrellia griseola), Hylemya spp., Hippobosca spp., Hypoderma spp., Liriomyza spp. (Hylemya spp.), Hippobosca spp., Hypoderma spp., Liriomyza spp. (Hippobosca spp.), Hypoderma spp., Liriomyza spp., such as Liriomyza brassicae (Liriomyza brassicae), Liriomyza huidobrensis (Liriomyza huidobrensis), Liriomyza sativae (Liriomyza sativae), Lucilia spp. For example, Lucilia cuprina, Lutzomyia spp., Mansonia spp., Musca spp., such as Musca domestica, Musca domestica vicina, Oestrus spp., Oscinella frit, Paratanytarsus spp., Paralauterborniella subcincta, Pegomya or Pegomyia spp., such as Pegomya betae, Pegomya hyoscyami, Pegomya rubivora, Phlebotomus spp., Phorbia spp., Phormia spp., Piophila casei, Platyparea poeciloptera, Prodiplosis spp., Psila rosae, Rhagoletis spp., such as Rhagoletis cingulata, Rhagoletis completa, Rhagoletis fausta, Rhagoletis indifferens Lutzomyia spp.) Musca spp., for example, Musca domestica Musca domestica vicina Oestrus spp., Oscinella frit Paratanytarsus spp., Paralauterborniella subcincta Pegomya or Pegomyia spp., for example, Pegomya betae Pegomya hyoscyami Pegomya rubivora Phlebotomus spp., Phorbia spp., Phormia spp., fferens), Rhagoletis mendax, Rhagoletis pomonella, Sarcophaga spp. (Sarcophaga spp.), Simulium spp. ), e.g., Simulium meridionale , Stomoxys spp., Tabanus spp. pp.), Tetanops spp., Tipula spp. ), e.g., Tipula paludosa, Tipula simplex , Toxotrypana curvicauda; Of Hemiptera, e.g., Acizzia acaciaebaileyanae (Acizzia acaciaebaileyanae), Acizzia dodonaeae (Acizzia dodonaeae), Acizzia uncatoides (Acizzia uncatoides), Acrida turrita, Acyrthosipon spp. , e.g., Acyrthosiphon pisum, Acrogonia spp. (Acrogonia spp.), Aeneolamia spp., Agonoscena spp. (Agonoscena spp.), Aleurocanthus spp., Aleyrodes proletella (Aleyrodes proletella), Aleurolobus barodensis (Aleurolobus barodensis) sis), Aleurothrixus flocco sus), Allocaridara malayen sis), Amrasca spp., for example, Amrasca bigutulla la), Amrasca devastans i), Anuraphis cardu i), Aonidiella spp., for example, (Aonidi ella aurantii), (Aonidiella citrina), Aonidi ella inornata, Aphanostigma piri ), Aphis spp., for example, Aphis citricola, Aphis craccivora ), Aphis fabae ), Aphis forbesi, Aphis glycines ), Aphis gossypii ), Aphis hederae, Aphis illinoisensis (Aphis illinoisensis), Aphis middletoni ), Aphis nasturtii ), Aphis nerii, Aphis pomi ), Aphis spiraecola, Aphis viburniphila apicalis(Ar boridia apicalis), species of Arytainilla s pp.), species of Aspidiella spp., species of Aspidiotus (Aspidiotus spp.), for example, Aspidiotus nerii otus nerii), species of Atanus spp., Aulacorthum solani Aulacorthum solani), Bemisia tabaci Bemisia tabaci), Blastopsylla occidentalis Blastopsylla occidentalis), Boreioglycaspis melaleucae Boreioglycaspis melaleucae), Brachycaudus helichrysi Brachycaudus helichrysi), species of Brachycolus s pp.), Brevicoryne brassicae ), species of Cacopsylla spp., for example, Cacopsylla pyricola (Cacopsylla pyricola), Calligypona marginata Calligypona marginata), species of Capulinia spp. ), Carneocephala fulgida, Ceratovacuna lanigera Ceratovacuna lanigera), Cercopidae (Cercopidae), species of Ceroplastes spp., Chaetosiphon fragaefolii Chaetosiphon fragaefolii), Chionaspis tegalensis, Chlorita onukii, Condracris rosea, Chromaph is juglandicola, Chrysomp halus aonidum, Chrysomphal us ficus, Cicadulina mbila, Coc comytilus halli, Coccus spp., e.g., Coccus hesperi dum, Coccus longulus, Coccus pse udomagnoliarum, Coccus viridis, Cryptomyzus ribis, Cryptoneossa spp. (Cryptoneossa ribis), Ctenarytaina spp., Dalbulus spp. (Cryptoneossa ribis), Ctenarytaina spp., Dalbulus spp. Dialeurodes chittendeni, Dialeurodes ci tri, Diaphorina citri, Diaspis spp. (Diaspis spp.), Diuraphis spp., Doralis spp., Drosicha spp .), Dysaphis spp., e.g., Dysaphis apiifolia ria, Dysaphis plantaginea, Dys​​​ Aphis plantaginea), Dysaphis tulipe ae), Dysmicoccus spp., Empoasca spp., for example, Empoasca abrupta ), Empoasca fabae ), Empoasca maligna, Empoasca solana), Empoasca stevensi ), Eriosoma spp., for example, Eriosoma americanum, Eriosoma lanigerum, Eriosoma pyricola ), Erythroneura spp. ), Eucalyptolyma spp., Euphyllura spp., Euscelis bilobatus ), Ferrisia spp., Fiorinia spp., Furcaspis oceanica ), Geococcus coffeae ), Glycaspis spp., Heteropsylla cubana ), Heteropsylla spinulosa ), Homalodisca coagulata isca coagulata), Hyalopterus arundinis, Hyalopter us arundinis, Hyalopterus pr uni, Icerya spp., for example, Icerya purchasi, Idiocerus spp. cerya purchasi, Idiocerus spp. , Idioscopus spp., Laodelphax striatellus, Lec anium spp., for example, Lecanium corni anium spp., for example, Lecanium corni (= Parthenolecanium corni) ), Lepidosaphes spp., for example, Lepidosaphes ulmi, Lip aphis erysimi, Lopholeucaspis japonica, Lycorma delica tula, Macrosiphum spp., for example, Macrosiphum euphorbiae, Mac rosiphum lilii, Macrosiphum rosae, Macroster les facifrons, Mahanarva spp., Mel anaphis sacchari, Metcalfiella spp., Metca rosiphum lilii, Macrosiphum rosae, Macroster rosiphum rosae, Macrosteres facifrons, Mahanarva spp., Mel anaphis sacchari, Metcalfiella spp., Metca anaphis sacchari, Melanaphis sacchari, Metcalfiella spp., Metca lfiella spp., Metcalfa pruinosa lfa pruinosa), Metopolophium dirhodum, Monellia costalis ), Monelliopsis pecanis, Myzus spp., e.g., Myzus ascalonicus ), Myzus cerasi, Myzus ligustri, Myzus ornatus ), Myzus persicae, Myzus nicotianae, Nasonovia ribisnigri ), Neomaskellia spp., Nephotettix spp., e.g., Nephotettix cincticeps ), Nephotettix nigropictus, Nettigoniclla spectra, Nilaparvata lugens ), Oncometopia spp., Orthezia praelonga, Oxya chinensis ), Pachypsylla spp., Parabemisia myricae, Paratrioza spp., e.g., ), Nephotettix spp., e.g., Nephotettix cincticeps ), Nephotettix nigropictus, Nettigoniclla spectra, Nilaparvata lugens ), Nephotettix nigropictus, Nettigoniclla spectra, Nilaparvata lugens ), Nettigoniclla spectra, Nilaparvata lugens, Oncometopia spp., Orthezia praelonga ), Oncometopia spp., Orthezia praelonga, Oxya chinensis ), Orthezia praelonga, Oxya chinensis, Pachypsylla spp., Parabemisia myricae ), Oxya chinensis, Pachypsylla spp., Parabemisia myricae, Paratrioza spp., e.g., ), Parabemisia myricae, Paratrioza spp., e.g., ​​, Paratrioza cockerelli, Parlatoria spp., Pemphigus spp., e.g., Pemphigus burs arius, Pemphigus populiven ae, Peregrinus maidis, Perkinsi ella spp., Phenacoccus spp., e.g., Phenacoccus madeirensis, Phloeomyzus passerinii, Phorodon humuli , Phylloxera spp., e.g., Phylloxera devastatrix, Phylloxera notabilis, Pinnaspis aspidistrae, Planococcus spp., e.g., Planococcus citri, Prosopidopsylla flava, Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus sp ., e.g., Phenacoccus madeirensis c us madeirensis, Phloeomyzus passerinii, Phorodon humuli , Phylloxera spp., e.g., Phylloxera devastatrix ., Phylloxera notabilis, Pinnaspis aspidistrae, Planococcus spp., e.g., Planococcus citri, Prosopidopsylla flava, Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus sp ., Phylloxera notabilis, Pinnaspis aspidistrae, Planococcus spp., e.g., Planococcus citri, Prosopidopsylla flava, Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus sp ., Pinnaspis aspidistrae, Planococcus spp., e.g., Planococcus citri, Prosopidopsylla flava, Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus sp ., e.g., Planococcus citri ., Planococcus citri, Prosopidopsylla flava, Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus sp ., Prosopidopsylla flava, Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus sp ., Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus sp ., Pseudaulacaspis pentagona, Pseudococcus sp p.), for example, Pseudococcus calceolariae, Pseudococcus comstocki, Pseudococcus longispinus, Pseudococcus maritimus, Pseudococcus viburni, Psyllopsis spp., Psylla spp., for example, Psylla buxi, Psylla mali, Psylla pyri, Pteromalus spp., Pulvinaria spp., Pyrilla spp., Quadraspidiotus spp., for example, Quadraspidiotus juglansregiae, Quadraspidiotus ostreaeformis, Quadraspidiotus perniciosus, Quaesada gigas, Rastrococcus spp., Rhopalosiphum spp., for example, Rhopalosiphum maidis, Rhopalosiphum oxyacanthae, Rhopalosiphum...paji alceolariae), Pseudococcus comstocki s comstocki), Pseudococcus longispinus us longispinus), Pseudococcus maritimus cus maritimus), Pseudococcus viburni s viburni), Psyllopsis spp., Psylla spp., for example, Psylla buxi s buxi), Psylla mali, Psylla pyri s mali), Psylla pyri s pyri), Pteromalus spp., Pulvinaria spp., Pyrilla spp., Quadraspidiotus spp., for example, Quadraspidiotus juglansregiae inaria spp.), Pyrilla spp., Quadraspidiotus spp., for example, Quadraspidiotus juglansregiae us spp.), for example, Quadraspidiotus juglansregiae iae), Quadraspidiotus ostreaeformis us ostreaeformis), Quadraspidiotus perniciosus us ostreaeformis), Quadraspidiotus perniciosus us perniciosus), Quaesada gigas da gigas), Rastrococcus spp., spp.), Rhopalosiphum spp., for example, Rhopalosiphum... maidis), Rhopalosiphum oxyacanthae acanthae), Rhopalosiphum...paji (Rhopalosiphum padi), Rhopalosiphum rufiabdominale (Rh opalosiphum rufiabdominale), Saissetia spp., for example, Saissetia coffeae (Saissetia co ffeae), Saissetia miranda, Saissetia neglecta, Saissetia oleae ( Saissetia oleae), Scaphoideus titanus (Scaphoideu s titanus), Schizaphis graminum (Schizaphis grami num), Selenaspidus articulatus (Selenaspidus articu latus), Sipha flava, Sitobion avenae (S itobion avenae), Sogatella spp., Sogatella furcifera ( Sogatella furcifera), Sogatodes spp., Stictocephala festina (Stictocephala festina), Siphoninus phillyreae (Siphoninus philly reae), Tenalaphara malayensis (Tenalaphara malayen sis), Tetragonocephela spp., Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., for example, Toxoptera aurantii (Toxoptera aura ntii), Tinocallis caryaefoliae), Tomaspis spp., Toxoptera spp., For example, Toxoptera aurantii (Toxoptera aura ntii), Toxoptera citricidus ), Trialeurodes vaporari orum), Trioza spp., for example, Trioza diospyri (Trioza diospyri), Typhlocyba spp .), Unaspis spp., Viteus vitifolii (Viteus vitifolii), Zygina spp.; Of the Heteroptera, for example, Aelia s pp.), Anasa tristis, Antestiopsis spp (Antestiopsis spp.), Boisea spp , Blissus spp., Calocoris spp.), Campylomma livida, Cavelerius spp.), Cimex spp , for example, Cimex adjunctus, Cimex · hemipterus, Cimex lectularius (C imex lectularius), Cimex pilos ellus), Collaria spp., Creontiades dilutus (Creontiades dilutus), Dasynu s piperis), Dichelops furcatu (Dichelops furcatus), Diconocoris hewetti, Disde Dysdercus spp., Euschistus spp., for example, Euschistus hero s, Euschistus servus, Euschistus tristigmus, Euschistus variolarius, Eurydema spp., Eurygaster sp p., Halyomorpha halys, Heliopeltis spp., Horcias nobilellus, Leptocorisa spp. ), Leptocorisa varicornis, Leptoglossus occidentalis ), Leptoglossus phyllopus, Lygocoris spp., for example, Lygocoris pabulinus ), Lygus spp., for example, Lygus elisus, Lygus hesperus, Lygus lineolaris ), Macropes excavatus, Megacopta cribraria, Miridae, Monalonion atratum, Nezara ​​​​​​​​​​​​ Genus Nezara spp., e.g., Nezara vir idula, Genus Nysius spp., Genus Oebal us spp., Pentomidae (Pentomidae), Piesma quad rata, Genus Piezodorus spp ., e.g., Piezodorus guild inii, Genus Psallus spp., Pseudacysta persea , Genus Rhodnius spp ., Sahlbergella singularis , Scaptocoris castanea, Genus Scotinophora spp , Stephanitis nashi , Genus Tibraca spp., Tri atoma spp.; Of the order Hymenoptera, e.g., Genus Acromy rmex spp., Genus Athalia spp., e.g., Athalia ·rosae, Genus Atta spp., Genus Camponotus spp , Genus Dolicho vespula spp., Genus Diprion spp., e.g., Diprion similis, Genus Hoplocampa spp , e.g., Hoplocampa coo cookei), Hoplocampa testud inea), Lasius spp., Linepithema humile ), Monomorium pharaonis ), Paratrechina spp., Paravespula spp., Plagiolepis spp., Sirex spp., e.g., Sirex noctilio ), Solenopsis invicta ), Tapinoma spp., Technomyrmex albipes, Urocerus spp., Vespa spp., e.g., Vespa crabro, Wasmannia auropunctata ), Xeris spp .); From the order Isopoda, e.g., Armadillidium vulgare ), Oniscus asellus ), Porcellio scaber; From the order Isoptera, e.g., Coptotermes spp ), e.g., Coptotermes formosanus ), Cornitermes cumulans ), Cryptotermes spp., Incisitermes spp., Kalotermes spp., Microtermes obesi, Nasutitermes spp., Odontotermes spp., Porotermes spp., Reticulitermes spp., e.g., Reticulitermes flavipes, Reticulitermes hesperus; Lepidoptera, e.g., Achroia grisella, Acronicta major, Adoxophyes spp., e.g., Adoxophyes orana, Aedia leucomelas, Agrotis spp., e.g., Agrotis segetum, Agrotis ipsilon, Alabama spp., e.g., Alabama argillacea, Amyelois transitella, Anarsia spp., Anticarsia spp., e.g., Anticarsia gemmatalis ​​​​​​​​​​​)、Argyroploce spp., Autographa spp. (Autographa spp.), Barathra brassicae , Blastodacna atra, Borbo cinnara, Bucculatrix thurberiella , Bupalus piniarius, Busseola spp. , Cacoecia spp., Caloptilia theivora , Capua reticulana , Carpocapsa pomonella, Carposina niponensis , Cheimatobia brumata, Chilo spp. (e.g., Chilo plejadellus, Chilo suppressalis) , Choreutis pariana, Choristoneura spp. , Chrysodeixis chalcites , Clysia ambiguella, Cnaphalocerus spp. , Cnaphalocrocis medinalis, Cnephasia spp. , Conopomorpha spp. p. p.), Conotrachelus spp., Copitarsia spp., Cydia spp., for example, Cydia nigricana, Cydia pomonella, Dalaca noctuid es, Diaphania spp., Diapopsis spp., Diatraea saccharalis, Dioryctria spp., for example, Dioryctria zimmermani, Earias spp., Ecdytoipha aurantium, Elasmopalpus lignosellus, Eldana saccharina, Ephestia spp., for example, Ephestia elutella, Ephestia kuehniella, Epinotia spp., Epiphyas postvittana, Erannis spp., Erschoviella musculana, Etiella spp., Eudocima spp., Eulia spp., Ecdytoipha aurantium, Elasmopalpus lignosellus, Eldana saccharina, Ephestia spp., for example, Ephestia elutella, Ephestia kuehniella, Epinotia spp., Epiphyas postvittana, Erannis spp., Erschoviella musculana, Etiella spp., Eudocima spp., Eulia spp., Ecdytoipha aurantium, Elasmopalpus lignosellus, Eldana saccharina, Ephestia spp., for example, Ephestia elutella, Ephestia kuehniella, Epinotia spp., Epiphyas postvittana, Erannis spp., Erschoviella musculana, Etiella spp., Eudocima a spp.), Eupoecilia ambigu ella), Euproctis spp., for example, Eupro ctis chrysorrhoea), Euxoa spp., Feltia spp., Galleria mellonella), Gracillaria spp., Grapholitha spp., for example, Grapholita molesta, Grapholita prunivora), Hedylepta spp., Helicoverpa spp., for example, Helicoverpa armigera, He licoverpa zea), Heliothis spp., for example, Heliothis vire scens), Hepialus spp., for example, Hepialus humuli ), Hofmannophila pseudospretella), Homoeosoma spp., Homona spp., Hyponomeuta padella), Kakivoria flavofasciata), Lampides spp., Laphygma spp., Laspeyresia ), for example, Heliothis virescens), Hepialus spp., for example, Hepialus humuli ), Hofmannophila pseudospretella), Homoeosoma spp., Homona spp., Hyponomeuta padella), Kakivoria flavofasciata), Lampides spp., Laphygma spp., Laspeyresia ), Hofmannophila pseudospretella), Homoeosoma spp., Homona spp., Hyponomeuta omoeosoma spp.), Homona spp., Hyponomeuta padella), Kakivoria flavofasciata), Lampides spp., Laphygma spp., Laspeyresia ), Lampides spp., Laphygma spp., Laspeyresia spp.), Laphygma spp., Laspeyresia Laspeyresia molesta, Leucinoides orbonaris (Leucinodes orbonalis), Leucoptera species ra spp., e.g. Leucoptera cophaera feella), Lithocolletis spp., e.g. , Lithocolletis blancardel la), Lithophane antennata, Lobesia spp., e.g. Lobesia botola a botrana, Loxagrotis albicosta icosta), Lymantria spp., e.g. Lymantria dispar, Lyonetia species tia spp., e.g., Lyonetia clerkella ella), Malacosoma neustria, Maruca testulalis, Mamestra brassica Mamestra brassicae, Melanitis reda leda, Mocis spp., Monopis obviella pis obviella), Mythimna separat a), Nemapogon cloacellus, Nim Nymphula spp., Oiketicus spp. pp.), Omphisa spp., Oper ophtera spp., Oria spp., Or thaga spp., Ostrinia spp., for example, Ostrinia nubilalis, Panolis flammea , Parnara spp. , Pectinophora spp., for example, Pectinophora ·gossypiella, Perileucoptera spp., Phtho rimaea spp., for example, Phthorima ea operculella, Phyllocnistis citrella , Phyllonorycter spp., for example, Phyllonorycter ·blancardella, Phyllonorycter crataegella , Pieris spp., for example, Pieris rapae, Platynota stultana , Plodia interpunctella, Plusia spp., Plutella ·xylostella (= Plutella maculipennis ), Podesia spp., , Plutella xylostella (= Plutella maculipennis ), Plutella xylostella (= Plutella maculipennis ), Podesia spp., ia spp.), for example, Podesia syringae, Prays spp., Prodenia spp. ), Protoparce spp., Pseudaletia spp. eudaletia spp.), for example, Pseudaletia unipuncta, Pseudoplusia includens, Pyrausta nubilalis, Rachiplusia nu, Schoenobius spp.), for example, Schoenobius bipunctifer, Scirpophaga spp.), for example, Scirpophaga innotata, Scotia segetum, ), Sesamia spp.), for example, Sesamia inferens, Sparganothis spp.), Spodoptera spp.), for example, Spodoptera eradiana, Spodoptera exigua, Spodoptera frugiperda, Spodoptera praefica, Stathmopoda spp. ), ) Stenoma spp., Stomopteryx subsecivella, Synant hedon spp., Tecia solanivora, Thaumetopoea spp., Thermesia gemmatalis, Tinea cloacella, Tinea pellionella, Tineola bisselliella, Tortrix spp., Trichophaga tapetzella, Trichoplusia spp., e.g., Trichoplusia ni, Tryporyza incertulas, Tu ta absoluta, Virachola spp.; Orthoptera or Saltatoria, e.g., Acheta domesticus, Dichroplus spp., Gryllotalpa spp., e.g., Gryllotalpa gryllotalpa, Hieroglyphus spp., Locusta spp., e.g., Locusta migratoria, Melanoplus spp., e.g., Mel anoplus anoplus​​​​ Melanoplus devastator, Paratrat nicus ussuriensis, Schistocerca gregaria; from the order Phthiraptera, for example, species of Damalin ia spp., Haematopinus spp., Linognathus spp., Pedicul us spp., Phylloxera vastatrix, Phthirus pubis, Trichodectes spp. ; from the order Psocoptera, for example, species of Lepino tus spp., Liposcelis spp.; from the order Siphonaptera, for example, species of Cerato phyllus spp., Ctenocephalide s spp., for example, Ctenocephalide s canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenops ylla cheopis; from the order Thysanoptera, for example, Anaphothrips obscurus, B aliothrips bihorrnnis (B ); from the order Thysanoptera, for example, Anaphothrips obscurus, B aliothrips bihorrnnis (B Aliothrips biformis), Chaetanaphothrips leeuweni Chaetanaphothrips leeuweni), Drepanothrips reuteri Drepanothrips reuteri), Enneothrips flavens Enneothrips flavens), Franklinella spp. Franklinella spp.), for example, Franklinella fusca Franklinella fusca), Franklinella occidentalis Franklinella occidentalis), Franklinella schultzei Franklinella schultzei), Franklinella tritici Franklinella tritici), Franklinella vaccinii Franklinella vaccinii), Franklinella williamsi Franklinella williamsi), Haplothrips spp. Haplothrips spp.), Heliothrips spp.), Hercinothrips femoralis Hercinothrips femoralis), Kakothrips spp. Kakothrips spp.), Rhipiphorothrips cruentatus Rhipiphorothrips cruentatus), Scirtothrips spp. Scirtothrips spp.), Taeniothrips cardamomi Taeniothrips cardamomi), Thrips spp. Thrips spp.), for example, Thrips palmi, Thrips tabaci; Pests of Zygentoma(=Thysanura), for example, Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus, Thermobia domestica; Pests of Symphyla, for example, Scutigerella spp., for example, Scutigerella immaculata; Pests of Mollusca, for example, pests of Bivalvia such as Dreissena spp.; and further, pests of Gastropoda such as Arion spp., for example, Arion ater rufus, Biompha laria spp., Bulinus spp., Deroceras spp., for example, Deroceras laeve, Galba spp., Lymnaea spp., Oncomelania spp., Pomacea spp., Succinea spp.; Plant pests of Nematoda, namely, plant - parasitic nematodes, especially Aglenchus spp., for example, Aglenchus agricola ; ; ; ; ; ; ; Aglenchus agricola), Anguina spp. ), for example, Anguina tritici, Aphelench oides spp.), for example, Aphelenchoides arachidis, Aphelenchoides fragariae, Belonolaimus spp. ), for example, Belonolaimus gracilis, Belonolaimus longicaudatus, Belonolaimus nortoni, Bursaphelenchus spp. ), for example, Bursaphelenchus cocophilus, Bursaphelenchus eremus, Bursaphelenchus xylophilus, Cacopaurus spp.), for example, Cacopaurus pestis, Criconemella spp .), for example, Criconemella curvata , Criconemella onoensis, Criconemella ornata, Criconemella rusium, Criconemella xenoplax(C , Criconemella onoensis, Criconemella ornata, Criconemella rusium, Criconemella rusium, Criconemella xenoplax(C riconemella xenoplax)(= Mesocriconema xenoplax (M esocriconema xenoplax)), Criconemoides spp. (Crico nemoides spp.), for example, Criconemoides ferniae (Crico nemoides ferniae), Criconemoides onoense (Cricone moides onoense), Criconemoides ornatum (Criconemo ides ornatum), Ditylenchus spp. , for example, Ditylenchus dipsaci, Dory dorus spp., Globodera spp. , for example, Globodera pallida (Globodera pallid a), Globodera rostochiensis (Globodera rostochiensi s), Helicotylenchus spp., for example, Helicotylenchus dihystera (Helicotylenchus dihystera ), Hemicriconemoides spp., He micycliophora spp., Heterodera spp. , for example, Heterodera avenae (Heterode ra avenae), Heterodera glycines (Heterodera glycin es), Heterodera schachtii, Hir schmaniella spp., Hoplolaimus spp. Hoplolaimus spp., Longidorus sp p., for example, Longidorus africanus us, Meloidogyne spp., for example, Meloidogyne chitwoodi, Meloidogyne fallax, Meloidogyne hapla , Meloidogyne incognita, Meloinema spp., Nacobbus spp., Neotylenchu s spp., Paralongidorus spp., Paraphelenchus spp., Paratrichodorus spp., for example, Paratrichodorus minor , Paratylenchus spp., Pratylenchus sp p., for example, Pratylenchus penetrans , Pseudohalenchus spp., Psilenchus spp., Punctodera spp , Quinisulcius spp., Radopholus spp., for example, Radopholus citrophilus , Radopholus similis , Pratylenchus penetrans, Pseudohalenchus spp , Psilenchus spp., Punctodera spp., Quinisulcius spp ., Radopholus spp., for example, Radopholus citrophilus , Radopholus similis , Quinisulcius spp., Radopholus spp., for example, Radopholus citrophilus .), Radopholus spp., for example, Radopholus citrophilus Radopholus similis (Radopholus similis), Rotylenchulus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp., for example, Trichodorus obtusus, Trichodorus primitivus, Tylenchorhynchus spp., for example, Tylenchorhynchus annulatus, Tylenchulus spp., for example, Tylenchulus semipenetrans, Xiphinema spp., for example, Xiphinema index. ulus spp.), Rotylenchus spp., Scut ellonema spp.), Subanguina spp.), Trichodorus spp.), for example, Trichodorus obtusus, Trichodorus primitivus, Tylenchorhynchus spp.), for example, Tylenchorhynchus annulatus, Tylenchulus spp.), for example, Tylenchulus semipenetrans, Xiphinema spp.), for example, Xiphinema index. guina spp.), Trichodorus spp.), for example, Trichodorus obtusus, Trichodorus primitivus, Tylenchorhynchus spp.), for example, Tylenchorhynchus annulatus, Tylenchulus spp.), for example, Tylenchulus semipenetrans, Xiphinema spp.), for example, Xiphinema index. For example, Trichodorus obtusus, Trichodorus primitivus, Tylenchorhynchus spp.), for example, Tylenchorhynchus annulatus, Tylenchulus spp.), for example, Tylenchulus semipenetrans, Xiphinema spp.), for example, Xiphinema index. For example, Trichodorus obtusus, Trichodorus primitivus, Tylenchorhynchus spp.), for example, Tylenchorhynchus annulatus, Tylenchulus spp.), for example, Tylenchulus semipenetrans, Xiphinema spp.), for example, Xiphinema index. ynchus spp.), for example, Tylenchorhynchus annulatus, Tylenchulus spp.), for example, Tylenchulus semipenetrans, Xiphinema spp.), for example, Xiphinema index. For example, Tylenchorhynchus annulatus, Tylenchulus spp.), for example, Tylenchulus semipenetrans, Xiphinema spp.), for example, Xiphinema index. For example, Tylenchulus semipenetrans, Xiphinema spp.), for example, Xiphinema index. For example, Tylenchulus semipenetrans, Xiphinema spp.), for example, Xiphinema index. Xiphinema spp.), for example, Xiphinema index. Xiphinema index).

[0078] The compound of formula (I) may optionally be used, at a specific concentration or specific application rate, as a herbicide, phytotoxicity reducer, growth regulator or agent for improving plant characteristics, or as a microbicide or gametocide, for example, as a fungicide, antimycotic, bactericide or virucide (which also includes agents against viroids), or as an agent against MLO (mycoplasma-like organisms) and RLO (rickettsia-like organisms). If appropriate, they are used for synthesizing other active compounds (microbicide) or gametocide, for example, as a fungicide, antimycotic, bactericide or virucide (which also includes agents against viroids), or as an agent against MLO (mycoplasma-like organisms) and RLO (rickettsia-like organisms). If appropriate, they are used for synthesizing other active compounds for example, as a fungicide, antimycotic, bactericide or virucide (which also includes agents against viroids), or as an agent against MLO (mycoplasma-like organisms) and RLO (rickettsia-like organisms). If appropriate, they are used for synthesizing other active compounds for synthesizing other active compounds They can also be used as intermediates or precursors for the

[0079] Formulation / Use The invention further relates to formulations, in particular formulations for controlling unwanted pests. The agents may be applied to the pests and / or their habitat.

[0080] The formulations of the present invention can be provided to the end user in a "ready to use" form, That is, the formulation is applied directly to the plants or seeds by a suitable device, such as a spray device or a dusting device. Alternatively, the formulation must be diluted, preferably with water, before use. Therefore, unless otherwise specified, The term "preparation" refers to such a concentrate, while the term "use form" refers to a final The “ready-to-use” solution for the end user, i.e., the most commonly used dilute formulation, It means the end user.

[0081] The formulations of the present invention can be prepared in a conventional manner, for example by incorporating the compounds of the present invention as disclosed herein. The composition can be prepared by mixing with one or more suitable auxiliary agents such as:

[0082] The formulations comprise at least one compound of the invention and at least one agriculturally suitable adjuvant. , for example, a carrier and / or a surfactant.

[0083] Carriers are usually inert solid or liquid natural or synthetic organic or inorganic substances. A carrier is usually a compound that improves the application of the compound to, for example, a plant, plant part, or seed. Examples of suitable solid supports include ammonium salts, especially ammonium sulfates, phosphorus Acid dark gatemium and ammonium nitrate, natural rock powder, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite and diatomaceous earth, silica gel and synthetic rock powder, such as finely ground silica, alumina and silicates, etc., but not limited to these. Examples of solid carriers usually useful for manufacturing granules include crushed and fractionated natural rocks , such as calcite, marble, pumice, sepiolite and dolomite, synthetic granules of inorganic and organic powders and paper, , sawdust, coconut shells, corn cobs and granules of organic materials such as tobacco stems, etc., but not limited to these. Examples of suitable liquid carriers include organic solvents and their combinations , etc., but not limited to these. Examples of suitable solvents include, for example, aromatic and non-aromatic hydrocarbons (such as cyclohexane, paraffins, alkylbenzenes , xylene, toluene, tetrahydronaphthalene, alkylnaphthalenes, chlorinated aromatic or chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride), alcohols and polyhydric alcohols (which may be substituted, etherified and / or esterified; for example, ethanol, propanol, butanol, benzyl alcohol , cyclohexanol or glycol), ketones (such as acetone, methyl ethyl ketone, methyl isobutyl ketone, acetophenone or cyclohexanone), esters (including fats and oils) and (poly)ethers, unsubstituted and substituted amines, amides (such as dimethylformamide or / fatty acid amides) and their esters, lactams (such as N-alkylpyrrolidones, especially N-methylpyrrolid one) and lactones, sulfones and sulfoxides (such as dimethyl sulfoxide) ), esters (including fats and oils) and (poly)ethers, unsubstituted and substituted amines, amides (such as dimethylformamide or / fatty acid amides) and their esters, lactams (such as N-alkylpyrrolidones, especially N-methylpyrrolid one) and lactones, sulfones and sulfoxides (such as dimethyl sulfoxide) ), sulfones and sulfoxides (such as dimethyl sulfoxide) and polar and nonpolar organic chemical liquids from the group consisting of oils of plant or animal origin, nitriles (alkyl nitriles such as acetonitrile, propionitrile, butyronitrile, or aromatic nitriles such as benzonitrile), carbonic esters (cyclic carbonic esters such as ethylene carbonate, propylene carbonate, butylene carbonate, or dialkyl carbonic esters such as dimethyl carbonate, diethyl carbonate, dipropyl carbonate, dibutyl carbonate, dioctyl carbonate). The carrier can also be a liquefied gas diluent, i.e., a liquid that is a gas at normal temperature and pressure, such as a hydrocarbon, butane, propane, nitrogen, and carbon dioxide, which are aerosol propellants.

[0084] Preferred solid carriers are selected from clays, talc, and silica.

[0085] Preferred liquid carriers are selected from water, fatty acid amides and their esters, aromatic and non-aromatic hydrocarbons, lactams, lactones, carbonic esters, ketones, (poly)ethers.

[0086] The amount of the carrier is typically in the range of 1 to 99.99% by weight, preferably 5 to 99.9%, more preferably 10 to 99.5% by weight, and most preferably 20 to 99% by weight of the formulation.

[0087] The liquid carrier is typically present in the range of 20 to 90% by weight, for example 30 to 80% by weight of the formulation.

[0088] The solid carrier is typically present in the range of 0 to 50% by weight, preferably 5 to 45% by weight, for example 10 to 30% by weight of the formulation.

[0089] When the formulation contains two or more carriers, the ranges outlined refer to the total amount of the carriers.

[0090] The surfactant can be an ionic (cationic or anionic), amphoteric or non-ionic surfactant, such as an ionic or non-ionic emulsifier, foaming agent, dispersant, wetting agent, penetration promoter and mixtures thereof. Examples of suitable surfactants include salts of polyacrylic acid, ethoxylated poly(α-substituted) acrylate derivatives, salts of lignosulfonic acid (e.g., sodium lignosulfonate), salts of phenolsulfonic acid or naphthalenesulfonic acid, polycondensates of ethylene oxide and / or propylene oxide with alcohols or without alcohols, fatty acids or aliphatic amines (e.g., polyoxyethylene fatty acid esters such as castor oil ethoxylate, polyoxyethylene fatty alcohol ethers such as alkylaryl polyglycol ethers), substituted phenols (preferably alkylphenols or arylphenols), salts of sulfosuccinic acid esters, taurine derivatives (preferably alkyltaurates), phosphate esters of polyethoxylated alcohols or phenols, fatty esters of polyhydric alcohols (such as fatty acid esters of glycerol, sorbitol or sucrose), sulfates (such as alkyl sulfates and alkyl ether sulfates), sulfonates (e.g., alkyl sulfonates, aryl sulfonates and alkylbenzene sulfonates), sulfonated polymers of naphthalene / formaldehyde, phosphate esters, protein hydrolysates, lignosulfite waste liquors and methylcellulose, including but not limited to these. The reference to salts in this paragraph preferably refers to the respective alkali salts, alkaline earth salts, and ammonium salts.

[0091] Preferred surfactants are ethoxylated poly(α-substituted) acrylate derivatives, alcohol condensation polymers of ethylene oxide and / or propylene oxide, polyoxyethylene fatty acid esters, alkylbenzene sulfonates, sulfonated polymers of naphthalene / formaldehyde, castor oil ethoxylate, sodium lignosulfonate, and polyoxyethylene fatty acid esters such as arylphenol ethoxylate.

[0092] The amount of surfactant is typically in the range of 5 to 40 wt%, for example 10 to 20 wt%, of the formulation.

[0093] Further examples of suitable adjuvants include water repellents, desiccants, binders (adhesives, tackifiers, fixatives, such as carboxymethyl cellulose, natural and synthetic polymers in the form of powders, granules or latexes, such as gum arabic, polyvinyl alcohol and polyvinyl acetate, natural phospholipids such as cephalins and lecithins and synthetic phospholipids, polyvinyl pyrrolidone and tyrosin), thickeners and secondary thickeners (cellulose ethers, acrylic acid derivatives, xanthan gum, modified clays, such as products available under the name Bentone, and finely divided silica), stabilizers (e.g. cryostabilizers, preservatives (e.g. dichlorophen, benzylalcohol hemiformal, 1,2-benzisothiazolin-3-one, 2-methyl-4-isothiazolin-3-one), antioxidants, light stabilizers, especially UV stabilizers, or other agents which improve cyanine dyes), antifoaming agents (e.g., silicone-based antifoaming agents and magnesium stearate) , antifreezing agents, spreading agents, gibberellins and processing aids, mineral oils and vegetable oils, fragrances, waxes, nutrients elements (e.g., micronutrients, e.g., salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc), protective colloids, thixotropic substances, penetrants, sequestering agents and complexing agents.

[0094] The choice of adjuvant depends on the intended application form of the compounds of the invention and / or the physical properties of the compounds. Furthermore, the adjuvants can be selected to provide specific properties (technical, physical and / or physiological properties) to the formulation or the form of use produced therefrom. The adjuvants can be selected to customize the formulation for specific needs.

[0095] The formulations contain an insecticidally / acaricidally / nematicidally effective amount of a compound of the invention. The term "effective amount" means an amount sufficient to control harmful insects / mites / nematodes on cultivated plants or to protect materials and which causes little damage to the plants being treated. Such an amount can vary widely and depends on various factors such as the insect / mite / nematode species to be controlled, the cultivated plant or material being treated, the climatic conditions, and the specific compound of the invention being used. Usually, the formulations according to the invention contain 0.01 to 99% by weight, preferably 0.05 to 98% by weight, more preferably 0.1 to 95% by weight, even more preferably 0.5 to 90 % by weight, most preferably 1 to 80% by weight of a compound of the invention. Formulation I can contain two or more compounds of the invention. In such a case, the ranges outlined refer to the total amount of the compounds of the invention.

[0096] The formulations of the present invention can be any conventional formulation type such as a liquid formulation (e.g., an aqueous solution), an emulsion, a water- and oil-based suspension, a powder ( e.g., a wettable powder, a soluble powder), a dust, a paste, a granule (e.g., a soluble granule, a spreading granule), a suspoemulsion formulation, a natural or synthetic product impregnated with the compound of the present invention, a fertilizer, and microencapsulation in a polymeric substance. The compound of the present invention can exist in a suspended form, an emulsified form or a dissolved form. Examples of particularly preferred formulation types are a liquid formulation, a water-soluble concentrate (e.g., SL, LS), a dispersible concentrate (DC) , a suspension and a suspension concentrate (e.g., SC, OD, OF, FS), an emulsifiable concentrate (e.g., EC), an emulsion (e.g., EW, EO, ES, ME, SE), a capsule (such as CS, ZC ), a paste, a troche, a wettable powder or a dust (e.g., WP, SP, WS, DP, D S), a compress (e.g., BR, TB, DT), a granule (e.g., WG, SG, GR, FG, GG, MG), an insecticide (e.g., LN), and a gel formulation (e.g., GW, GF) for the treatment of plant propagation materials such as seeds. These and other formulation types are defined by the Food and Agriculture Organization of the United Nations (FAO). An overview can be found in ″Catalogue of p esticide formulation types and internati onal coding system″, Technical Monograph No. 2, 6th Ed. May 2008, Croplife Internat ional. Preferably, the formulation of the present invention is of the following types: EC, SC, FS, SE, OD, WG, W P, CS, more preferably in one of the forms of EC, SC, OD, WG, CS.

[0097] ​

[0098] Details of the types of formulations and examples of their preparation are provided below. When two or more compounds of the present invention are present, the amounts of the compounds of the present invention outlined refer to the total amount of the compounds of the present invention. This applies mutatis mutandis to any further components of the formulation, when two or more representatives of such components are present, for example, wetting agents, binders. When there are two or more representatives of such components, for example, wetting agents, binders, the amounts of the compounds of the present invention outlined refer to the total amount of the compounds of the present invention. This applies mutatis mutandis to any further components of the formulation. When there are two or more representatives of such components, for example, wetting agents, binders, this applies mutatis mutandis to any further components of the formulation.

[0099] i) Water-soluble concentrates (SL, LS) 10 to 60% by weight of at least one compound of the present invention and 5 to 15% by weight of a surfactant (for example, a polycondensate of ethylene oxide and / or propylene oxide with an alcohol) are dissolved in water and / or a water-soluble solvent (for example, an alcohol such as propylene glycol or a carbonic acid ester such as propylene carbonate) in such an amount that the total amount is 100% by weight. Before application, the concentrate is diluted with water. are dissolved in water and / or a water-soluble solvent (for example, an alcohol such as propylene glycol or a carbonic acid ester such as propylene carbonate) in such an amount that the total amount is 100% by weight. Before application, the concentrate is diluted with water.

[0100] ii) Dispersible concentrates (DC) 5 to 25% by weight of at least one compound of the present invention and 1 to 10% by weight of a surfactant and / or binder (for example, polyvinylpyrrolidone) are dissolved in an organic solvent (for example, cyclohexanone) in such an amount that the total amount is 100% by weight. Dilute with water to obtain a dispersion. are dissolved in an organic solvent (for example, cyclohexanone) in such an amount that the total amount is 100% by weight. Dilute with water to obtain a dispersion.

[0101] iii) Emulsifiable concentrates (EC) 15 to 70% by weight of at least one compound of the present invention and 5 to 10% by weight of a surfactant (for example, a mixture of calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolved in a water-insoluble organic solvent (for example, an aromatic hydrocarbon or a fatty acid amide) and, if necessary, an additional water-soluble solvent in such an amount that the total amount is 100% by weight. Dilute with water to obtain an emulsion. are dissolved in a water-insoluble organic solvent (for example, an aromatic hydrocarbon or a fatty acid amide) and, if necessary, an additional water-soluble solvent in such an amount that the total amount is 100% by weight. Dilute with water to obtain an emulsion. ​​​

[0102] iv) Emulsions (EW, EO, ES) 5 to 40% by weight of at least one compound of the present invention and 1 to 10% by weight of a surfactant ( for example, a mixture of calcium dodecylbenzenesulfonate and castor oil ethoxylate, or a polycondensate of ethylene oxide and / or propylene oxide with or without alcohol) is dissolved in 20 to 40% by weight of a water-insoluble organic solvent (for example, an aromatic hydrocarbon). This mixture is added to water in an amount such that the total amount is 100% by weight using an emulsifier. The resulting formulation is a homogeneous emulsion. Before application, the emulsion can be further diluted with water. This mixture is added to water in an amount such that the total amount is 100% by weight using an emulsifier. The resulting formulation is a homogeneous emulsion. Before application, the emulsion can be further diluted with water. The resulting formulation is a homogeneous emulsion. Before application, the emulsion can be further diluted with water. is possible.

[0103] v) Suspensions and suspension concentrates v-1) Aqueous systems (SC, FS) Using a suitable grinding device, for example, a stirred ball mill, 20 to 60% by weight of at least one compound of the present invention is ground by adding 2 to 10% by weight of a surfactant (for example, sodium lignosulfonate and polyoxyethylene fatty alcohol ether), 0.1 to 2% by weight of a thickener (for example, xanthan gum) and water to obtain a fine active substance suspension. The water is added in an amount such that the total amount is 100% by weight. By diluting with water, a stable suspension of the active substance is obtained. In the case of FS type formulations, up to 40% by weight of a binder (for example, polyvinyl alcohol) is added. is added. The water is added in an amount such that the total amount is 100% by weight. By diluting with water, a stable suspension of the active substance is obtained. In the case of FS type formulations, up to 40% by weight of a binder (for example, polyvinyl alcohol) is added. is added. By diluting with water, a stable suspension of the active substance is obtained. is obtained. In the case of FS type formulations, up to 40% by weight of a binder (for example, polyvinyl alcohol) is added. is added.

[0104] v-2) Oil-based systems (OD, OF) Using a suitable grinding device, for example, a stirred ball mill, 20 to 60% by weight of at least one compound of the present invention is ground by adding 2 to 10% by weight of a surfactant (for example, sodium lignosulfonate and polyoxyethylene fatty alcohol ether), 0.1 to 2% by weight of a thickener (for example, xanthan gum) and water to obtain a fine active substance suspension. The water is added in an amount such that the total amount (Polyoxyethylene fatty alcohol ether), 0.1 to 2% by weight of a thickener (e.g., modified quality clay, especially Bentone, or silica) and an organic carrier are added and ground to obtain a fine active substance oil suspension. The organic carrier is added in an amount such that the total amount is 100% by weight. Water is diluted to obtain a stable dispersion of the active substance.

[0105] vi) Granular wettable powders and water-soluble granules (WG, SG) 1 to 90% by weight, preferably 20 to 80% by weight, most preferably 50 to 80% by weight of at least one compound of the present invention, a surfactant (e.g., sodium lignosulfonate and sodium alkylnaphthalenesulfonate) and a potential carrier material are added and finely ground, and then extruded, spray-dried, fluidized bed granulated, etc. by typical technical equipment to convert them into granular wettable powders or water-soluble granules. The surfactant and the carrier material are used in amounts such that the total amount is 100% by weight. Water is diluted to obtain a stable dispersion or solution of the active substance.

[0106] vii) Wettable powders and water-soluble powders (WP, SP, WS) 50 to 80% by weight of at least one compound of the present invention, 1 to 20% by weight of a surfactant (e.g., sodium lignosulfonate, sodium alkylnaphthalenesulfonate) and a solid carrier, such as silica gel, in an amount such that the total amount is 100% by weight, are added and ground with a rotor-stator mill. Water is diluted to obtain a stable dispersion or solution of the active substance.

[0107] viii) Gels (GW, GF) In a stirred ball mill, 5 to 25% by weight of at least one compound of the present invention, 3 to 10% by weight of a surfactant (e.g., sodium lignosulfonate), 1 to 5% by weight of a binder (e.g. For example, carboxymethyl cellulose) and water in an amount such that the total amount is 100% by weight are added and then pulverized. Thereby, a fine suspension of the active substance is obtained. Dilute with water to obtain a stable suspension of the active substance.

[0108] ix) Microemulsion (ME) 5 to 20% by weight of at least one compound of the present invention is added to 5 to 30% by weight of an organic solvent mixture (for example, fatty acid dimethylamide and cyclohexanone), 10 to 25% by weight of a surfactant mixture (for example, polyoxyethylene fatty alcohol ether and arylphenol ethoxylate), and water in an amount such that the total amount is 100% by weight. By stirring this mixture for 1 hour, a thermodynamically stable microemulsion is spontaneously formed.

[0109] x) Microcapsule (CS) An oil phase containing 5 to 50% by weight of at least one compound of the present invention, 0 to 40% by weight of a water-insoluble organic solvent (for example, aromatic hydrocarbon), 2 to 15% by weight of an acrylic monomer (for example, methyl meth acrylate, methacrylic acid, and di- or triacrylate) is dispersed in an aqueous solution of a protective colloid (for example, polyvinyl alcohol). Poly(meth)acrylate microcapsules are formed by radical polymerization initiated by a radical initiator . Alternatively, an oil phase containing 5 to 50% by weight of at least one compound of the present invention, 0 to 40% by weight of a water-insoluble organic solvent (for example, aromatic hydrocarbon), and an isocyanate monomer (for example, diphenylmethane-4,4'-diisocyanate) is dispersed in an aqueous solution of a protective colloid (for example, polyvinyl alcohol), whereby polyurea microcapsules are formed. enylmethane-4,4'-diisocyanate) is dispersed in an aqueous solution of a protective colloid (for example, poly vinyl alcohol), and thereby, polyurea microcapsules are formed. is formed. Optionally, the addition of a polyamine (e.g., hexamethylenediamine) is also used to form poly urea microcapsules. The monomer amounts to 1 to 10% by weight of the total amount of the CS formulation.

[0110] xi) Dustable powder (DP, DS) At least one compound of the present invention in an amount of 1 to 10% by weight is finely pulverized and thoroughly admixed with a solid carrier, such as finely pulverized kaolin, in such an amount that the total amount is 100% by weight ..

[0111] xii) Granules (GR, FG) At least one compound of the present invention in an amount of 0.5 to 30% by weight is finely pulverized and combined with a solid carrier (e.g., silicate) in such an amount that the total amount is 100% by weight ..

[0112] xiii) Ultra-low volume liquid (UL) At least one compound of the present invention in an amount of 1 to 50% by weight is dissolved in an organic solvent, such as an aromatic hydrocarbon, in such an amount that the total amount is 100% by weight ..

[0113] The formulations of types i) to xiii) may optionally further contain auxiliary agents, such as 0.1 to 1% by weight of a preservative, 0.1 to 1% by weight of an antifoaming agent, 0.1 to 1% by weight of a dye and / or pigment, and 5 to 10% by weight of an antifreezing agent.

[0114] Mixture The compound of formula (I) can, for example, expand the spectrum of action, extend the duration of action, increase the rate of action, prevent repulsion, or prevent the development of resistance, in order to prevent the development of resistance, or in combination with one or more suitable fungicides, bactericides, acaricides, molluscicides, nematicides, insecticides, microbicides, beneficial species, herbicides, fertilizers, bird repellents, phytot reinforcing agents, insecticides, pesticides, microbial agents, beneficial species, herbicides, fertilizers, bird repellents, plant fortifying agents (phytot as a mixture with an ionic compound, a contraceptive, a phytotoxicity reducing agent, an infochemical and / or a plant growth regulator It is also possible to use it as such. Furthermore, such combinations of active compounds can improve plant growth and / or increase tolerance to abiotic factors (such as high or low temperature), tolerance to drought, or tolerance to an increase in the salt content in water or soil. Furthermore, it is also possible to improve the flowering and fruiting performance, optimize the germination ability and root development, facilitate harvesting, increase the yield, affect maturity, improve the quality and / or nutritional value of the harvested product, lengthen the shelf life of the harvested product, and / or improve the processability of the harvested product.

[0115] Furthermore, the compound of formula (I) can be present in a mixture with another active compound or infochemical (such as an attractant, and / or a bird repellent, and / or a plant activator, and / or a growth regulator, and / or a fertilizer). Similarly, it is also possible to improve plant characteristics (such as growth, yield and quality of the harvested product) using the compound of formula (I).

[0116] In certain embodiments according to the invention, the compound of formula (I) is present in a formulation or in a use form prepared from such a formulation in a mixture with a further compound (preferably a compound described below ).

[0117] If one of the compounds described below can exist in various tautomeric forms , and their forms are also included even if not explicitly mentioned in each case. Further, all of the mixed counterparts named may form salts with suitable bases or acids, if possible, by their functional groups.

[0118] Insecticide / acaricide / nematicide The active compounds specified by the general names in this specification are known, and , for example, are described in the Pesticide Manual (″The Pesticide Manual″ 16th Ed., British Crop Protection Council 2 012), or can be found on the Internet (for example, ″http: / / www.alanwood.net / pesticides″). The classification is based on the IRAC Mode of Action Classification Scheme as of the filing date of this patent application.

[0119] (1) Acetylcholinesterase (AChE) inhibitors, preferably selected from aldicarb, aldicarb, beniodicarb, benfuracarb, butocarboxim, butoxycarboxim, carbaryl, carbofuran, carbosulfan, ethiofencarb, fenobucarb, formetanate, flucarb, isoprocarb, methiocarb, methomyl, metolcarb, oxamyl, pirimicarb, propoxur, thiodicarb, thiofanox, triazamate, trimethacarb, XMC, and xylylcarb; or acephate, azamethiphos, azinphos-ethyl, azinphos-methyl, cadusafos, chlorethoxyfos, chlorfenvinphos, chlorfenphos, Rupirifos-methyl, Coumaphos, Cyanophos, Dimethon-S-methyl, Diazinon, Di Chlorpyrifos / DDVP, Dichlorvos, Dimethoate, Dimethylvinphos, Disulfoton , EPN, Ethion, Ethoprophos, Famphur, Fenamiphos, Fenitrothion , Fenthion, Phosphazate, Heptenophos, Imicyafos, Isofenphos, O- (Methoxyaminothiophosphoryl) salicylic acid isopropyl ester, Isoxathion, Malathion , Carbaryl, Methamidophos, Methidathion, Mevinphos, Monocrotophos, Naled, Omethoate, Oxydimethon-methyl, Parathion-methyl, Phenthoate, Phosalone , Phosmet, Phosphamidon, HCH, Pirimiphos-methyl, Profenofos , Propetamphos, Prothiofos, Pyraclofos, Pyridaphenthion, Quinalphos , Sulfotep, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphos, Thiometon , Triazophos, Trichlorfon, and organophosphorus acid esters selected from vamidothion .

[0120] (2) GABA-dependent chloride channel blockers, preferably cyclodiene organochlorines selected from chlordane and endosulfan; or phenylpyrazoles (fiproles) selected from ethiprole and fipronil .

[0121] (3) Sodium channel regulators, preferably acrinathrin, allethrin, d-cis -trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin s-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cy Fluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cy halothrin, permethrin, alpha-cypermethrin, beta-cypermethrin, cy -permethrin, zeta-cypermethrin, cyphenothrin [(1R)-trans isomer], deltamethrin, empenthrin [(EZ)-(1R) isomer], esfen valerate, etofenprox, fenpropathrin, fenvalerate, flucythr inate, flumethrin, tau-fluvalinate, halfenprox, imiprothr in, kadethrin, monofluorothrin, permethrin, phenothrin [(1R)-trans isomer], prallethrin, pyrethrins (pyrethrum), resmethr in, silafluofen, tefluthrin, tetramethrin, tetramethrin [(1R) is omer], tralomethrin, and transfluthrin, or DDT or methoxychlor or pyrethroids selected therefrom.

[0122] (4) Nicotinic acetylcholine receptor (nAChR) competitive modulators, preferably ace tamprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiac loprid, and thiamethoxam; or neonicotinoids selected from nicotine; or sulfoximines selected from sulfoxaflor; or butenolides selected from flupyradifurone; or mesoionic compounds selected from triflumizopyrim.

[0123] (5) Nicotinic acetylcholine receptor (nAChR) allosteric modulators (site I ), preferably spinosins selected from spinetoram and spinosad.

[0124] (6) Glutamate-dependent chloride channel (GluCl) allosteric regulators , preferably abamectin, emamectin benzoate, lepimectin, and milbemectin selected from the avermectins / milbemycins.

[0125] (7) Juvenile hormone mimics, preferably hydroprene, kinoprene and methoprene or juvenile hormone analogs selected from fenoxycarb or pyriproxyfen.

[0126] (8) Various non-specific (multi-site) inhibitors, preferably methyl bromide and another halogenated al kyl selected from chloropicrin or sulfuryl fluoride or borax or tartar emetic or methyl isocyanate generators selected from dazomet and metam.

[0127] (9) Chordotonal organ TRPV channel regulators, preferably pyridine azomethanes selected from pimetrozine and pyrifluquinazon, or pyropenes selected from afidopyropen.

[0128] (10) Acaricide growth inhibitors that affect CHS1 selected from clofentezine, hexythiazox, diflovidazin and etoxazole.

[0129] (11) Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies aizawai (Bacillus aizawai), Bacillus thuringiensis subspecies kurstaki (Bacillus thuringiensis subspecies kurst aki), Bacillus thuringiensis subspecies tenebrionis selected from the microbial disruptors of the insect intestinal membrane, and the Bt plant proteins selected from Cry1Ab, Cry1Ac, Cry1 Fa, Cry1A.105, Cry2Ab, Vip3A, mCry3A, Cry3Ab, Cry3Bb and Cry34 / 35Ab1.

[0130] (12) Inhibitors of mitochondrial ATP synthase, preferably ATP disruptors selected from diafenthiuron or organic tin compounds selected from azocyclotin, cyhexatin and fenbutatin oxide or propargite or tetradifon. (13) Uncouplers of oxidative phosphorylation by disrupting the proton gradient, selected from chlorfenapyr, DNOC and sulfuryl fluoride.

[0131] (14) Nicotinic acetylcholine receptor channel blockers selected from bensultap, cartap hydrochloride, thiram and thiosultap-sodium.

[0132] (15) Inhibitors of chitin biosynthesis that affect CHS1, preferably benzoyl ureas selected from bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexythiazox, lufenuron, novaluron, noviflumuron, teflubenzuron, and triflumuron.

[0133] (16) An inhibitor of chitin biosynthesis selected from buprofezin, type 1.

[0134] (17) A molting disruptor selected from silafluofen (especially in the case of Diptera, i.e., Diptera species).

[0135] (18) An ecdysone receptor agonist, preferably a diacylhydrazine selected from chromafenozide, halofenozide, me toxifenozide and tebufenozide.

[0136] (19) An octopamine receptor agonist selected from amitraz.

[0137] (20) A mitochondrial complex III electron transport inhibitor selected from hydramethylnon, acequinocyl, fluacrypyrim and bifenazate and selected.

[0138] (21) A mitochondrial complex I electron transport inhibitor, preferably a METI acaricide and insecticide selected from phenazakine, fen pyroximate, pyrimidifen, pyridaben, tebufenpyrad and tolfenpyrad or rotenone (Derris).

[0139] (22) A voltage-dependent sodium channel blocker, preferably an oxadiazone selected from indoxacarb or a semicarbazone selected from metaflumizone.

[0140] (23) An inhibitor of acetyl-CoA carboxylase, preferably a tetronic acid derivative and a tetramic acid derivative selected from spirodiclofen, spirotetramat, spirobifen and spirodiclofen selected.

[0141] (24) A mitochondrial complex IV electron transport inhibitor, preferably aluminum phosphide, Phosphides selected from calcium phosphide, phosphine, and zinc phosphide; or cyanides selected from calcium cyanide, potassium cyanide, and sodium cyanide.

[0142] (25) Mitochondrial complex II electron transport inhibitors, preferably β-ketonitrile derivatives selected from cyanopyrafen and siflumetofen, or carboxyanilides selected from piflubumide.

[0143] (28) Ryanodine receptor regulators, preferably diamides selected from chlorantraniliprole, cyantraniliprole, cyclaniliprole, flubendiamide, and tetraniliprole.

[0144] (29) A chordotonal organ regulator (target site undefined) selected from flonicamid.

[0145] (30) GABA-dependent chloride channel allosteric regulators, preferably metadiamides selected from broflanilide, or isoxazoles selected from flumetramide.

[0146] (31) Baculoviruses, preferably granuloviruses (GV) selected from Cydia pomonella GV and Thaumatotibia leucotreta (GV), or nucleopolyhedroviruses (NPV) selected from Anticarsia gemmatalis MNPV and Helicoverpa armigera NPV.

[0147] (32) A nicotinic acetylcholine receptor allosteric modulator (site II) selected from GS-omega / kappa HXTX-Hv1a peptide.

[0148] (33) Acinonapil, afoxolena, azadirachtin, benclothiaz, ben zoximate, benzpyramoxan, bromopropylate, chinomethionate, chlorop rallethrin, cryolite, cyclobutrifluram, cycloxaprid, cyetpyrafen, cyhalodiamide, cyprofuranilide (CAS23 75110-88-4), dichloromezothiaz, dicofol, dimipropyridaz, ε-meth fluthrin, ε-momfluorothrin, flometokine, fluaazaindoline, fluensul hon, flufenirim, flufenoxystrobin, flufiprole, flufexahone (Fluhexafon), fluopyram, flupyrimidine, fluralaner, fufenozide (Fufenozide), flupenthiophenox, guazipyr, heptafluthrin , imidaclothiz, iprodione, isocycloseram, κ-bifenthrin, κ-tefl thrin, lotilaner, meperfluthrin, nicofluprole (CA S1771741-86-6), oxazosulfyl, paichongding , pyridalyl, pyrifluquinazone, pyriminostrobin, sarolaner, spidoxamat, spirobudiclofen, tetram thylfluthrin, tetrachlorantraniliprole , thigolaner, thioxazafen, thiofluoximate (Thi fluoximate), chloropyrazoflor, iodomethane; furthermore, Bacillus firmus-based preparations (I-1582, Votivo) and azadirachtin (BioNeem); furthermore, the following compounds: 1-{2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}-3-(trifluoromethyl)-1H-1,2,4-triazol-5-amine (known from WO2006 / 043635) (CAS 885026-50-6), 2-chloro-N-[2-{1-[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]piperidin-4-yl}-4-(trifluoromethyl)phenyl]isonicotinamide (known from WO2006 / 003494) (CAS 872999-66-1), 3-(4-chloro-2,6-dimethylphenyl)-4-hydroxy-8-methoxy-1,8-diazaspiro[4.5]deca-3-en-2-one (known from WO2010052161) (CAS 1225292-17-0), 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-2-oxo-1,8-diazaspiro[4.5]deca-3-en-4-yl ethyl carbonate (known from EP2647626) (CAS-1440516-42-6), PF1364 (known from JP2010 / 018586) (CAS 1204776-60-2), (3E)-3-[1-[(6-chloro-3-pyridyl)methyl]-2-pyridylidene]-1,1,1-trifluoropropan-2-one (known from WO2013 / 144213) (CAS 1461743-15-6), N-[3-(benzylcarbamoyl)-4-chlorophenyl]-1-methyl derived active compound; furthermore, preparations based on Bacillus firmus (I-1582, Votivo) and azadirachtin (BioNeem); furthermore, the following compounds: 1-{2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}-3-(trifluoromethyl)-1H-1,2 ,4-triazole-5-amine (known from WO2006 / 043635) (CAS 8 85026-50-6), 2-chloro-N-[2-{1-[(2E)-3-(4-chloro phenyl)prop-2-en-1-yl]piperidin-4-yl}-4-(trifluoromethyl phenyl]isonicotinamide (known from WO2006 / 003494) (CA S 872999-66-1), 3-(4-chloro-2,6-dimethylphenyl)-4- hydroxy-8-methoxy-1,8-diazaspiro[4.5]deca-3-en-2-one (known from WO2010052161) (CAS 1225292-17-0), 3-( 4-chloro-2,6-dimethylphenyl)-8-methoxy-2-oxo-1,8-diaza spiro[4.5]deca-3-en-4-yl ethyl carbonate (EP2647626 known) (CAS-1440516-42-6), PF1364 (JP2010 / 018 586 known) (CAS 1204776-60-2), (3E)-3-[1-[(6 chloro-3-pyridyl)methyl]-2-pyridylidene]-1,1,1-trifluoroprop an-2-one (known from WO2013 / 144213) (CAS 1461743- 15-6), N-[3-(benzylcarbamoyl)-4-chlorophenyl]-1-methyl derived active compound; furthermore, preparations based on Bacillus firmus (I-1582, Votivo) and azadirachtin (BioNeem); furthermore, the following compounds: 1-{2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}-3-(trifluoromethyl)-1H-1,2 ,4-triazole-5-amine (known from WO2006 / 043635) (CAS 8 85026-50-6), 2-chloro-N-[2-{1-[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]piperidin-4-yl}-4-(trifluoromethyl)phenyl]isonicotinamide (known from WO2006 / 003494) (CAS 872999-66-1), 3-(4-chloro-2,6-dimethylphenyl)-4-hydroxy-8-methoxy-1,8-diazaspiro[4.5]deca-3-en-2-one (known from WO2010052161) (CAS 1225292-17-0), 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-2-oxo-1,8-diazaspiro[4.5]deca-3-en-4-yl ethyl carbonate (known from EP2647626) (CAS-1440516-42-6), PF1364 (known from JP2010 / 018586) (CAS 1204776-60-2), (3E)-3-[1-[(6-chloro-3-pyridyl)methyl]-2-pyridylidene]-1,1,1-trifluoropropan-2-one (known from WO2013 / 144213) (CAS 1461743-15-6), N-[3-(benzylcarbamoyl)-4-chlorophenyl]-1-methyl -3-(Pentafluoroethyl)-4-(trifluoromethyl)-1H-pyrazole-5 -carboxamide (known from WO2010 / 051926) (CAS 1226889- 14-0), 5-bromo-4-chloro-N-[4-chloro-2-methyl-6-(methylcarb amoyl)phenyl]-2-(3-chloro-2-pyridyl)pyrazole-3-carbox amide (known from CN103232431) (CAS 1449220-44-3), 4 -[5-(3,5-dichlorophenyl)-4,5-dihydro-5-(trifluoromethyl )-3-isoxazolyl]-2-methyl-N-(cis-1-oxide-3-thietanyl )-benzamide, 4-[5-(3,5-dichlorophenyl)-4,5-dihydro-5- (trifluoromethyl)-3-isoxazolyl]-2-methyl-N-(trans-1- oxide-3-thietanyl)-benzamide and 4-[(5S)-5-(3,5-dichloro phenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl -2-methyl-N-(cis-1-oxide-3-thietanyl)benzamide (known from WO20 13 / 050317A1) (CAS 1332628-83-7), N-[3- chloro-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3- (3,3,3-trifluoropropyl)sulfinyl]-propanamide, (+)-N- [3-chloro-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl- 3-[(3,3,3-trifluoropropyl)sulfinyl]-propanamide and (- )-N-[3-chloro-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N- Ethyl 3-[(3,3,3-trifluoropropyl)sulfinyl]propanamide (Known from WO2013 / 162715A2, WO2013 / 162716A2, US2014 / 0213448A1) (CAS 1477923-37-7), 5-[[(2E )-3-chloro-2-propen-1-yl]amino]-1-[2,6-dichloro-4-( trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H -pyrazole-3-carbonitrile (known from CN101337937A) (CAS 1 105672-77-2), 3-bromo-N-[4-chloro-2-methyl-6-[(methyl amino)thiomethyl]phenyl]-1-(3-chloro-2-pyridinyl)-1H- pyrazole-5-carboxamide, (Liudaibenjiaxuanan, known from CN10 3109816A) (CAS 1232543-85-9); N-[4-chloro -2-[[(1,1-dimethylethyl)amino]carbonyl]-6-methylphenyl]- 1-(3-chloro-2-pyridinyl)-3-(fluoromethoxy)-1H-pyrazole- 5-carboxamide (known from WO2012 / 034403A1) (CAS 12682 77-22-0), N-[2-(5-amino-1,3,4-thiadiazol-2-yl) -4-chloro-6-methylphenyl]-3-bromo-1-(3-chloro-2-pyridinyl )-1H-pyrazole-5-carboxamide (known from WO2011 / 085575A1 )(CAS 1233882-22-8), 4-[3-[2,6-dichloro-4-[(3 ,3-dichloro-2-propen-1-yl)oxy]phenoxy]propoxy]-2-me thoxy-6-(trifluoromethyl)-pyrimidine (known from CN101337940A )(CAS 1108184-52-6); (2E)-and 2(Z)-2-[2-(4- cyanophenyl)-1-[3-(trifluoromethyl)phenyl]ethylidene]-N- 4-(difluoromethoxy)phenyl]-hydrazinecarboxamide (known from CN101715 774A) (CAS 1232543-85-9); 3-(2,2-dichloroeth enyl)-2,2-dimethyl-4-(1H-benzimidazol-2-yl)phenyl- cyclopropanecarboxylate (known from CN103524422A) (CAS 1 542271-46-4); (4aS)-7-chloro-2,5-dihydro-2-[[(me thoxycarbonyl)[4-[(trifluoromethyl)thio]phenyl]amino]carbonyl -indeno[1,2-e][1,3,4]oxadiazine-4a(3H)-carboxylic acid methyl ester (known from CN102391261A) (CAS 1370358-6 9-2); 6-deoxy-3-O-ethyl-2,4-di-O-methyl-1-[N-[4- [1-[4-(1,1,2,2,2-pentafluoroethoxy)phenyl]-1H-1, 2,4-triazol-3-yl]phenyl]carbamate]-α-L-mannopyrano se (known from US2014 / 0275503A1) (CAS 1181213-14-8 ); 8-(2-cyclopropylmethoxy-4-trifluoromethyl-phenoxy)-3- (6-trifluoromethyl-pyridazin-3-yl)-3-aza-bicyclo[3.2.1 octane (CAS 1253850-56-4), (8-anti)-8-(2-cyclo propylmethoxy-4-trifluoromethyl-phenoxy)-3-(6-trifluorometh (2-Chloro-pyridazin-3-yl)-3-aza-bicyclo[3.2.1]octane (CAS 933798-27-7), (8-cis)-8-(2-cyclopropylmethoxy-4-tr ifluoromethylphenoxy)-3-(6-trifluoromethylpyridazin-3-yl) -3-azabicyclo[3.2.1]octane (known from WO2007040280A1, WO20 07040282A1) (CAS 934001-66-8), N-[4-(ami nothiomethyl)-2-methyl-6-[(methylamino)carbonyl]phenyl]- 3-bromo-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxa mide (known from CN 103265527A) (CAS1452877-50-7), 3 -(4-chloro-2,6-dimethylphenyl)-8-methoxy-1-methyl-1,8-di azaspiro[4.5]decane-2,4-dione (known from WO2014 / 187846A1) (CAS1638765-58-8), 3-(4-chloro-2,6-dimethylpheny l)-8-methoxy-1-methyl-2-oxo-1,8-diazaspiro[4.5]deca- 3-en-4-yl-ethyl carbonate (known from WO2010 / 066780A1, WO20 11151146A1) (CAS1229023-00-0), N-[1-(2 ,6-difluorophenyl)-1H-pyrazole-3-yl]-2-(trifluoromethy l)benzamide (known from WO2014 / 053450A1) (CAS1594624 -87-9), N-[2-(2,6-difluorophenyl)-2H-1,2,3-tri azole-4-yl]-2-(trifluoromethyl)benzamide (known from WO2014 / 053 450A1) (CAS1594637-65-6), N-[1-(3,5-dif [[3-[(2-chloro-5-thiazolyl)-2,3-dihydro-8-methyl-5,7-dioxo-6-phenyl-5H-thiazolo[3,2-a]pyrimidinium-3-yl]-1H-pyrazol-4-yl]methyl]carbamate )(known from WO2014 / 053450A1) (CAS1594626- 19-3), (3R)-3-(2-chloro-5-thiazolyl)-2,3-dihydro-8- methyl-5,7-dioxo-6-phenyl-5H-thiazolo[3,2-a]pyrimidinium inner salt (known from WO2018 / 177970A1) (CAS2246757-58-2 ); 3-(2-chloro-5-thiazolyl)-2,3-dihydro-8-methyl-5,7-di oxo-6-phenyl-5H-thiazolo[3,2-a]pyrimidinium inner salt (WO201 8 / 177970A1) (CAS2246757-56-0); N-[3-chloro -1-(3-pyridinyl)-1H-pyrazol-4-yl]-2-(methylsulfonyl )-propanamide (known from WO2019 / 236274A1) (CAS239674 7-83-2), N-[2-bromo-4-[1,2,2,2-tetrafluoro-1-(tr ifluoromethyl)ethyl]-6-(trifluoromethyl)phenyl]-2-fluoro- 3-[(4-fluorobenzoyl)amino]-benzamide (WO2019059412 A1) (CAS1207977-87-4).

[0149] Fungicide The active ingredients specified by the common name in this specification are known and described, for example, in the Pesticide Manual (16 th Ed. British Crop Protection Council) or can be searched on the Internet (for example, ). www.alanwood.n et / pesticides )

[0150] All the listed fungicide mixing partners in Classifications (1) to (15) can optionally form salts with suitable bases or acids, if possible, by virtue of their functional groups. All the listed mixing partners in Classifications (1) to (15) can include tautomers, where applicable.

[0151] 1) Inhibitors of ergosterol biosynthesis, for example, (1.001) cyproconazole, ( 1.002) difenoconazole, (1.003) epoxyconazole, (1.004) fenhexamid, (1.005) fenpropimorph, (1.006) fenpropidin mol, (1.007) fenpyrazamine, (1.008) fluquinconazole, (1.00 9) flutriafol, (1.010) imazalil, (1.011) imazalil sulfate, ( 1.012) ipconazole, (1.013) metconazole, (1.014) myclob tanil, (1.015) paclobutrazol, (1.016) procraz, (1.01 7) propiconazole, (1.018) prothioconazole, (1.019) pyrisoxa zol, (1.020) spiroxamine, (1.021) tebuconazole, (1.022 ) tetraconazole, (1.023) triadimenol, (1.024) tridemorph, (1.025) triticonazole, (1.026) (1R,2S,5S)-5-(4-ch lorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-tri azol-1-ylmethyl)cyclopentanol, (1.027) (1S,2R,5R)- 5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2 ,4-triazol-1-ylmethyl)cyclopentanol, (1.028) (2R)- ​​2-(1-Chlorocyclopropyl)-4-[(1R)-2,2-dichlorocyclopropyl -1-(1H-1,2,4-triazol-1-yl)butan-2-ol (1.02 9)(2R)-2-(1-Chlorocyclopropyl)-4-[(1S)-2,2-dichloro cyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol -ol, (1.030)(2R)-2-[4-(4-Chlorophenoxy)-2-(trifluoro methyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan -2-ol, (1.031)(2S)-2-(1-Chlorocyclopropyl)-4-[( (1R)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazol- 1-yl)butan-2-ol, (1.032)(2S)-2-(1-Chlorocyclopropyl yl)-4-[(1S)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4 -triazol-1-yl)butan-2-ol, (1.033)(2S)-2-[4- (4-Chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1, 2,4-triazol-1-yl)propan-2-ol, (1.034)(R)-[3 -(4-Chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1, 2-oxazol-4-yl](pyridin-3-yl)methanol, (1.035)(S )-[3-(4-Chloro-2-fluorophenyl)-5-(2,4-difluorophenyl )-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.03 6)[3-(4-Chloro-2-fluorophenyl)-5-(2,4-difluorophenyl )-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.03 7) 1-({(2R,4S)-2-[2-chloro-4-(4-chlorophenoxy)phenyl -4-methyl-1,3-dioxolan-2-yl}methyl)-1H-1,2,4-tri azole, (1.038) 1-({(2S,4S)-2-[2-chloro-4-(4-ch lorophenoxy)phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl) -1H-1,2,4-triazole, (1.039) 1-{[3-(2-chlorophenyl )-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1, 2,4-triazole-5-yl thiocyanate, (1.040) 1-{[rel(2R ,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxir ane-2-yl]methyl}-1H-1,2,4-triazole-5-yl thiocyanate, (1.041) 1-{[rel(2R,3S)-3-(2-chlorophenyl)-2-(2 ,4-difluorophenyl)oxirane-2-yl]methyl}-1H-1,2,4-tri azole-5-yl thiocyanate, (1.042) 2-[(2R,4R,5R)-1- (2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4 -yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.0 43) 2-[(2R,4R,5S)-1-(2,4-dichlorophenyl)-5-hydroxy -2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2, 4-triazole-3-thione, (1.044) 2-[(2R,4S,5R)-1-(2 ,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl L]-2,4-Dihydro-3H-1,2,4-triazole-3-thione, (1.045 )2-[(2R,4S,5S)-1-(2,4-Dichlorophenyl)-5-hydroxy- 2,6,6-Trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4- triazole-3-thione, (1.046)2-[(2S,4R,5R)-1-(2,4 -Dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.047)2 -[(2S,4R,5S)-1-(2,4-Dichlorophenyl)-5-hydroxy-2, 6,6-Trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-tri azole-3-thione, (1.048)2-[(2S,4S,5R)-1-(2,4-di chlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2 ,4-dihydro-3H-1,2,4-triazole-3-thione, (1.049)2- (2S,4S,5S)-1-(2,4-Dichlorophenyl)-5-hydroxy-2,6, 6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole -3-thione, (1.050)2-[1-(2,4-Dichlorophenyl)-5-hyd roxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1, 2,4-triazole-3-thione, (1.051)2-[2-Chloro-4-(2,4- dichlorophenoxy)phenyl]-1-(1H-1,2,4-triazol-1-yl) propan-2-ol, (1.052)2-[2-Chloro-4-(4-chlorophenoxy )phenyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol , (1.053)2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.054)2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)pentan-2-ol, (1 .055) mefenoxazol, (1.056) 2-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4 -dihydro-3H-1,2,4-triazole-3-thione, (1.057) 2-{[rel(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl )oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.058) 2-{[rel(2R,3S)-3-(2-chlorophenyl )-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4 -dihydro-3H-1,2,4-triazole-3-thione, (1.059) 5-(4 -chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol, (1.060) 5-(allylsulfanyl )-1-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxyiran-2-yl]methyl}-1H-1,2,4-triazole, (1.061) 5- (allylsulfanyl)-1-{[rel(2R,3R)-3-(2-chlorophenyl) -2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2 -4-triazole, (1.061) 5- (allylsulfanyl)-1-{[rel(2R,3R)-3-(2-chlorophenyl) -2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazole, (1.061) 5- (allylsulfanyl)-1-{[rel(2R,3R)-3-(2-chlorophenyl) -2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazole, (1.061) 5- (allylsulfanyl)-1-{[rel(2R,3R)-3-(2-chlorophenyl) -2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2 , 4 - Triazole, (1.062) 5 - (allylsulfanyl) - 1 - {[rel(2 R,3S) - 3 - (2 - chlorophenyl) - 2 - (2,4 - difluorophenyl) oxy lan - 2 - yl] methyl} - 1H - 1,2,4 - triazole, (1.063) N′ - ( 2,5 - dimethyl - 4 - {[3 - (1,1,2,2 - tetrafluoroethoxy)phenyl sulfanyl} phenyl) - N - ethyl - N - methylimidohydroformamide, (1.06 4) N′ - (2,5 - dimethyl - 4 - {[3 - (2,2,2 - trifluoroethoxy) f enyl] sulfanyl} phenyl) - N - ethyl - N - methylimidohydroformamide, (1 .065) N′ - (2,5 - dimethyl - 4 - {[3 - (2,2,3,3 - tetrafluoro propoxy) phenyl] sulfanyl} phenyl) - N - ethyl - N - methylimidohor mamide, (1.066) N′ - (2,5 - dimethyl - 4 - {[3 - (pentafluoroeth oxy) phenyl] sulfanyl} phenyl) - N - ethyl - N - methylimidohydro mide, (1.067) N′ - (2,5 - dimethyl - 4 - {3 - [(1,1,2,2 - tet rafluoroethyl) sulfanyl] phenoxy} phenyl) - N - ethyl - N - methyli midohydroformamide, (1.068) N′ - (2,5 - dimethyl - 4 - {3 - [(2,2, 2 - trifluoroethyl) sulfanyl] phenoxy} phenyl) - N - ethyl - N - me thylimidohydroformamide, (1.069) N′ - (2,5 - dimethyl - 4 - {3 - [(2 ,2,3,3 - tetrafluoropropyl) sulfanyl] phenoxy} phenyl) - N - ethyl - N - methylimidohydroformamide, (1.070) N′ - (2,5 - dimethyl - 4 - {3 - [(pentafluoroethyl) sulfanyl] phenoxy} phenyl) - N - ethy N-methylimidohydroxamic acid, (1.071) N′-(2,5-dimethyl-4- phenoxyphenyl)-N-ethyl-N-methylimidohydroxamic acid, (1.072) N′ -(4-{[3-(difluoromethoxy)phenyl]sulfanyl}-2,5-dimethyl phenyl)-N-ethyl-N-methylimidohydroxamic acid, (1.073) N′-(4- {3-[(difluoromethyl)sulfanyl]phenoxy}-2,5-dimethylphenyl )-N-ethyl-N-methylimidohydroxamic acid, (1.074) N′-[5-bromo- 6-(2,3-dihydro-1H-inden-2-yloxy)-2-methylpyridin-3 -yl]-N-ethyl-N-methylimidohydroxamic acid, (1.075) N′-{4- (4,5-dichloro-1,3-thiazol-2-yl)oxy]-2,5-dimethylphe nyl}-N-ethyl-N-methylimidohydroxamic acid, (1.076) N′-{5-bro mo-6-[(1R)-1-(3,5-difluorophenyl)ethoxy]-2-methylpyr din-3-yl}-N-ethyl-N-methylimidohydroxamic acid, (1.077) N′- {5-bromo-6-[(1S)-1-(3,5-difluorophenyl)ethoxy]-2- methylpyridin-3-yl}-N-ethyl-N-methylimidohydroxamic acid, (1.07 8) N′-{5-bromo-6-[(cis-4-isopropylcyclohexyl)oxy]- 2-methylpyridin-3-yl}-N-ethyl-N-methylimidohydroxamic acid, (1. 079) N′-{5-bromo-6-[(trans-4-isopropylcyclohexyl)o xy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidohydroxamic acid , (1.080) N′-{5-bromo-6-[1-(3,5-difluorophenyl)eth oxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidohydroformamide , (1.081) ipfentrifluconazole, (1.082) 2-[4-(4-chloro phenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-tri azole-1-yl)propan-2-ol, (1.083) 2-[6-(4-bromof enoxy)-2-(trifluoromethyl)-3-pyridyl]-1-(1,2,4-tri azole-1-yl)propan-2-ol, (1.084) 2-[6-(4-chlorophen oxy)-2-(trifluoromethyl)-3-pyridyl]-1-(1,2,4-triaz ole-1-yl)propan-2-ol, (1.085) 3-[2-(1-chlorocyclo propyl)-3-(3-chloro-2-fluoro-phenyl)-2-hydroxy-propyl imidazole-4-carbonitrile and (1.086) 4-[[6-[rac-(2R )-2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3- (5-thioxo-4H-1,2,4-triazol-1-yl)propyl]-3-pyrid yl]oxy]benzonitrile.

[0152] 2) Inhibitors of the respiratory chain in Complex I or Complex II, for example, (2.001) benzovin difuril, (2.002) bixafen, (2.003) boscalid, (2.004) carboxin, (2.005) fluopyram, (2.006) flutolanil, (2.00 7) fluxapyroxad, (2.008) flutriafol, (2.009) isophytamide , (2.010) Isopyrazam (anti-epimeric enantiomer 1R,4S,9S) , (2.011) Isopyrazam (anti-epimeric enantiomer 1S,4R,9R) , (2.012) Isopyrazam (anti-epimeric racemate 1RS,4SR,9SR) , (2.013) Isopyrazam (syn-epimeric racemate (1RS,4SR,9RS) and a mixture of anti-epimeric racemate (1RS,4SR,9SR)), (2.014) Isopyrazam (syn-epimeric enantiomer 1R,4S,9R), (2.015) I sopyrazam (syn-epimeric enantiomer 1S,4R,9S), (2.016) Iso pyrazam (syn-epimeric racemate 1RS,4SR,9RS), (2.017) Penf lufen, (2.018) Penthiopyrad, (2.019) Pydiflumetofen (pyd iflumetofen), (2.020) Pyraflumide, (2.021) Sedaxane , (2.022) 1,3-Dimethyl-N-(1,1,3-trimethyl-2,3-dihydro -1H-inden-4-yl)-1H-pyrazole-4-carboxamide, (2.023 ) 1,3-Dimethyl-N-[(3R)-1,1,3-trimethyl-2,3-dihydro-1 H-inden-4-yl]-1H-pyrazole-4-carboxamide, (2.024) 1 ,3-Dimethyl-N-[(3S)-1,1,3-trimethyl-2,3-dihydro-1H- inden-4-yl]-1H-pyrazole-4-carboxamide, (2.025) 1-Meth yl-3-(trifluoromethyl)-N-[2′-(trifluoromethyl)biphenyl- 2-yl]-1H-pyrazole-4-carboxamide, (2.026) 2-Fluoro-6 -(trifluoromethyl)-N-(1,1,3-trimethyl-2,3-dihydro-1H- (2.027) 3-(difluoromethyl)-1-methylinden-4-ylbenzamide Tyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1H-Pyrazole-4-carboxamide, (2.028) Impirfluxam, (2. 029) 3-(difluoromethyl)-1-methyl-N-[(3S)-1,1,3-trimethyl 2,3-dihydro-1H-inden-4-yl]-1H-pyrazole-4-carbo oxamide, (2.030) fluindapyr, (2.031) 3-(difluoromethyl)- N-[(3R)-7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-iso 1-methyl-1H-pyrazole-4-carboxamide, (2.03 2) 3-(Difluoromethyl)-N-[(3S)-7-fluoro-1,1,3-trimethyl 1-methyl-1H-pyrazole-2,3-dihydro-1H-inden-4-yl 4-Carboxamide, (2.033) 5,8-difluoro-N-[2-(2-fluoro- 4-{[4-(trifluoromethyl)pyridin-2-yl]oxy}phenyl)ethyl] Quinazoline-4-amine, (2.034) N-(2-cyclopentyl-5-fluorobenzene Dimethyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl- 1H-Pyrazole-4-carboxamide, (2.035) N-(2-tert-butyl- 5-Methylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro -1-Methyl-1H-pyrazole-4-carboxamide, (2.036)N-(2-te rt-Butylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro 1-Methyl-1H-pyrazole-4-carboxamide, (2.037) N-(5-chloro -2-ethylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro ro-1-methyl-1H-pyrazole-4-carboxamide, (2.038) N-(5 -chloro-2-isopropylbenzyl)-N-cyclopropyl-3-(difluoromethyl )-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.039 ) N-[(1R,4S)-9-(dichloromethylene)-1,2,3,4-tetrahydro- 1,4-methanonaphthalen-5-yl]-3-(difluoromethyl)-1-methyl-1H -pyrazole-4-carboxamide, (2.040) N-[(1S,4R)-9-(dichloro romethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl )-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.041) N-[1-(2,4-dichlorophenyl)-1-methoxypropan-2- yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide d, (2.042) N-[2-chloro-6-(trifluoromethyl)benzyl]-N-cyclo propyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole -4-carboxamide, (2.043) N-[3-chloro-2-fluoro-6-(trifluoro romethyl)benzyl]-N-cyclopropyl-3-(difluoromethyl)-5-fluoro ro-1-methyl-1H-pyrazole-4-carboxamide, (2.044) N-[5 -chloro-2-(trifluoromethyl)benzyl]-N-cyclopropyl-3-(difluoro romethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, ([[]] 2.045) N-Cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl -N-[5-methyl-2-(trifluoromethyl)benzyl]-1H-pyrazole-4 -carboxamide, (2.046) N-Cyclopropyl-3-(difluoromethyl)-5 -fluoro-N-(2-fluoro-6-isopropylbenzyl)-1-methyl-1H-py razole-4-carboxamide, (2.047) N-Cyclopropyl-3-(difluoro methyl)-5-fluoro-N-(2-isopropyl-5-methylbenzyl)-1-methyl -1H-pyrazole-4-carboxamide, (2.048) N-Cyclopropyl-3-( difluoromethyl)-5-fluoro-N-(2-isopropylbenzyl)-1-methyl- 1H-pyrazole-4-carbothioamide, (2.049) N-Cyclopropyl-3-( difluoromethyl)-5-fluoro-N-(2-isopropylbenzyl)-1-methyl- 1H-pyrazole-4-carboxamide, (2.050) N-Cyclopropyl-3-(di fluoromethyl)-5-fluoro-N-(5-fluoro-2-isopropylbenzyl)- 1-methyl-1H-pyrazole-4-carboxamide, (2.051) N-Cyclopropi l-3-(difluoromethyl)-N-(2-ethyl-4,5-dimethylbenzyl)-5- fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.052) N-Si cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-fluorobenzyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.053) N-Cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-methylbenz (R)-5-Fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.05 4) N-Cyclopropyl-N-(2-cyclopropyl-5-fluorobenzyl)-3-( difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxami de, (2.055) N-Cyclopropyl-N-(2-cyclopropyl-5-methylbenzyl )-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4- carboxamide, (2.056) N-Cyclopropyl-N-(2-cyclopropylbenzyl )-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4- carboxamide, (2.057) Pyrapropoyne.

[0153] 3) Inhibitors of the respiratory chain in Complex III, for example, (3.001) Ametoctradin, ( 3.002) Amisulbrom, (3.003) Azoxystrobin, (3.004) Coume thoxystrobin, (3.005) Cumoxystrobin, (3.006) Cyazofamid, (3.007) Dimoxystrobin, (3. 008) Enoxystrobin, (3.009) Famoxadone, (3.010) Fenamin done, (3.011) Flufenoxystrobin, (3.012) Fluoxastrobin, (3.013) Kresoxim-methyl, (3 .014) Metominostrobin, (3.015) Orysastrobin, (3.016) Pic oxystrobin, (3.017) Pyraclostrobin, (3.018) Pyrametostrobin , (3.019) Pyraoxystrobin, (3.020) Trifloxystrobin, ( 3.021) Trifloxystrobin-cis, (3.022) Trifloxystrobin-trans, (3.023) Trifloxystrobin mixture, (3.024) Trifloxystrobin-single enantiomer, (3.025) Trifloxystrobin 3.021) (2E)-2-{2-[({[(1E)-1-(3-{[(E)-1-Flu oro-2-phenylvinyl]oxy}phenyl)ethylidene]amino}oxy)methyl] phenyl}-2-(methoxyimino)-N-methylacetamide, (3.022) (2E ,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy }-2-(methoxyimino)-N,3-dimethylpent-3-enamide, (3.023 )(2R)-2-{2-[(2,5-dimethylphenoxy)methyl]phenyl}-2-me thoxy-N-methylacetamide, (3.024) (2S)-2-{2-[(2,5-di methylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamide, (3 .025) fenpicoxamid, (3.026) mandestrobin, (3.027) N- (3-ethyl-3,5,5-trimethylcyclohexyl)-3-formamido-2-hyd roxybenzamide, (3.028) (2E,3Z)-5-{[1-(4-chloro-2- fluorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino) -N,3-dimethylpent-3-enamide, (3.029) methyl{5-[3-(2, 4-dimethylphenyl)-1H-pyrazol-1-yl]-2-methylbenzyl}carb amate, (3.030) methyltetraprole, (3.031) flurypicoxamid.

[0154] 4) Inhibitors of mitosis and cell division, for example, (4.001) carbendazim, (4. 002) diethofencarb, (4.003) ethaboxam, (4.004) fluopic rid, (4.005) pencycuron, (4.006) thiabendazole, (4.007) Thiophanate-methyl, (4.008) Zoxamide, (4.009) 3-chloro-4- (2,6-difluorophenyl)-6-methyl-5-phenylpyridazine, (4.010 ) 3-chloro-5-(4-chlorophenyl)-4-(2,6-difluorophenyl)-6 -methylpyridazine, (4.011) 3-chloro-5-(6-chloropyridin-3-yl )-6-methyl-4-(2,4,6-trifluorophenyl)pyridazine, (4.012 ) 4-(2-bromo-4-fluorophenyl)-N-(2,6-difluorophenyl)- 1,3-dimethyl-1H-pyrazole-5-amine, (4.013) 4-(2-bromo- 4-fluorophenyl)-N-(2-bromo-6-fluorophenyl)-1,3-dimethyl -1H-pyrazole-5-amine, (4.014) 4-(2-bromo-4-fluorop henyl)-N-(2-bromophenyl)-1,3-dimethyl-1H-pyrazole-5-a mine, (4.015) 4-(2-bromo-4-fluorophenyl)-N-(2-chloro- 6-fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine, (4.0 16) 4-(2-bromo-4-fluorophenyl)-N-(2-chlorophenyl)-1, 3-dimethyl-1H-pyrazole-5-amine, (4.017) 4-(2-bromo-4- fluorophenyl)-N-(2-fluorophenyl)-1,3-dimethyl-1H-pyraz ole-5-amine, (4.018) 4-(2-chloro-4-fluorophenyl)-N-( 2,6-difluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine, ([[]] 4.019) 4-(2-chloro-4-fluorophenyl)-N-(2-chloro-6-flu orophenyl)-1,3-dimethyl-1H-pyrazole-5-amine, (4.020) 4 -(2-Chloro-4-fluorophenyl)-N-(2-chlorophenyl)-1,3-dime thyl-1H-pyrazole-5-amine, (4.021) 4-(2-chloro-4-fluoro phenyl)-N-(2-fluorophenyl)-1,3-dimethyl-1H-pyrazole-5 -amine, (4.022) 4-(4-chlorophenyl)-5-(2,6-difluorophe nyl)-3,6-dimethylpyridazine, (4.023) N-(2-bromo-6-fluoro phenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H-py razole-5-amine, (4.024) N-(2-bromophenyl)-4-(2-chloro -4-fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine, (4. 025) N-(4-chloro-2,6-difluorophenyl)-4-(2-chloro-4-f luorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine.

[0155] 5) Compounds capable of having multi-site action, for example, (5.001) Bordeaux mixture, ( 5.002) Captan, (5.003) Captan, (5.004) Chlorothalonil , (5.005) Copper hydroxide, (5.006) Copper naphthenate, (5.007) Copper oxide, (5 .008) Basic copper chloride, (5.009) Copper sulfate (2+), (5.010) Dithianon, (5.011) Dodine, (5.012) Folpet, (5.013) Mancozeb, (5.0 14) Maneb, (5.015) Methiram, (5.016) Methiram zinc, (5.017 ) Copper oxine, (5.018) Propineb, (5.019) Sulfur and sulfur agents, for example, poly Calcium sulfide, (5.020) Thiram, (5.021) Dinneb, (5.022) Dira Mu, (5.023) 6-Ethyl-5,7-dioxo-6,7-dihydro-5H-pyrrolo 3′,4′:5,6][1,4]dithiino[2,3-c][1,2]thiazole-3-car bonitrile.

[0156] 6) Compounds that can induce the host's defense, for example, (6.001) acibenzolar-S-methyl , (6.002) isothianyl, (6.003) probenazole, (6.004) th azinyl.

[0157] 7) Inhibitors of amino acid and / or protein biosynthesis, for example, (7.001) cyclo dinyl, (7.002) kasugamycin, (7.003) kasugamycin hydrochloride hydrate, (7.004) oxytetracycline, (7.005) pyrimethanil, (7.006) 3-(5-Fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin- 1-yl)quinoline.

[0158] 8) ATP production inhibitors, for example, (8.001) silthiopham.

[0159] 9) Inhibitors of cell wall synthesis, for example, (9.001) benzov alicarb, (9.002 ) dimethomorph, (9.003) fluomorph, (9.004) iprovalicarb, (9. 005) mandipropamid, (9.006) pyrimorph, (9. 007) valifenalate, (9.008)(2E)-3-(4-tert-butylphen yl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)prop -2-en-1-one, (9.009)(2Z)-3-(4-tert-butylphenyl )-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)prop-2 -en-1-one.

[0160] 10) Inhibitors of lipid and membrane synthesis, for example, (10.001) propamocarb, (10 .002) propamocarb hydrochloride, (10.003) tolclofos-methyl.

[0161] 11) Inhibitors of melanin biosynthesis, for example, (11.001) tricyclazole, (11 .002) 2,2,2-trifluoroethyl {3-methyl-1-[(4-methylbenzoyl yl)amino]butan-2-yl} carbamate.

[0162] 12) Inhibitors of nucleic acid synthesis, for example, (12.001) benalaxyl, (12.002) benalaxyl-M (kiralaxyl), (12.003) metalaxyl, (12.004) metalaxyl-M (mefenoxam).

[0163] 13) Inhibitors of signal transduction, for example, (13.001) fluazinam, (13. 002) iprodione, (13.003) procymidone, (13.004) proquinazid , (13.005) quinoxyfen, (13.006) vinclozolin.

[0164] 14) Compounds that can act as uncouplers, for example, (14.001) fluazinam, ( 14.002) meptyldinocap.

[0165] 15) (15.001) abscisic acid, (15.002) benziothiazole, (15.0 03) benzoxazin, (15.004) capsimycin, (1 5.005) carvone, (15.006) quinomethionate, (15.007) coufural b, (15.008) difenoconazole, (15.009) simoxanil, (15.01 0) Cyprosulfamide, (15.011) Flutianil, (15.012) Phosphonyl- aluminum, (15.013) Phosphonyl-calcium, (15.014) Phosphonyl-sodi um, (15.015) Methyl isothiocyanate, (15.016) Metrafenone , (15.017) Mildiomycin, (15.018) Natamycin, (15.01 9) Nickel dimethyldithiocarbamate, (15.020) Nitrotal-isopropyl , (15.021) Oxamocarb, (15.022) Oxathi apiprolin, (15.023) Oxyfenthiin, (1 5.024) Pentachlorophenol and salts, (15.025) Phosphorous acid and its salts, (15.026) Propamocarb-fosetylate, (15.027) Pyriofenone (Chlazafen one), (15.028) Tebufenozide, (15.029) Techlofthalam, (15 030) Tolfenpyrad, (15.031) 1-(4-{4-[(5R)-5-(2, .030) Tolfenpyrad, (15.031) 1-(4-{4-[(5R)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1 ,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(tri ,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone, (15.032) 1-(4 -{4-[(5S)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2 -oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl) -2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]etha none, (15.033) 2-(6-Benzylpyridin-2-yl)quinazoline, (15. 33) 2-(6-Benzylpyridin-2-yl)quinazoline, (15. 034) Dipimetitrone, (15.035) 2 - [3,5 - bis(difluoromethyl)- 1H - pyrazol - 1 - yl] - 1 - [4 - (4 - {5 - [2 - (prop - 2 - yn - 1 - yloxy)phenyl] - 4,5 - dihydro - 1,2 - oxazole - 3 - yl} - 1 ,3 - thiazol - 2 - yl)piperidin - 1 - yl]ethanone, (15.036) 2 - [3,5 - bis(difluoromethyl)-1H - pyrazol - 1 - yl] - 1 - [4 - (4 -{5 - [2 - chloro - 6 - (prop - 2 - yn - 1 - yloxy)phenyl] - 4,5 - dihydro - 1,2 - oxazole - 3 - yl} - 1,3 - thiazol - 2 - yl)pipe ridine - 1 - yl]ethanone, (15.037) 2 - [3,5 - bis(difluoromethyl ) - 1H - pyrazol - 1 - yl] - 1 - [4 - (4 - {5 - [2 - fluoro - 6 - (prop - 2 - yn - 1 - yloxy)phenyl] - 4,5 - dihydro - 1,2 - oxazole - 3 - yl} - 1,3 - thiazol - 2 - yl)piperidin - 1 - yl]ethanone, ([[]] 15.038) 2 - [6 - (3 - fluorophenyl - 4 - methoxyphenyl) - 5 - methylpyrid ine - 2 - yl]quinazoline, (15.039) 2 - {(5R) - 3 - [2 - (1 - {[3 ,5 - bis(difluoromethyl)-1H - pyrazol - 1 - yl]acetyl}piperidine - 4 - yl) - 1,3 - thiazol - 4 - yl] - 4,5 - dihydro - 1,2 - oxazole - 5 - yl} - 3 - chlorophenyl methanesulfonate, (15.040) 2 - { (5S) - 3 - [2 - (1 - {[3,5 - bis(difluoromethyl)-1H - pyrazole - 1 - yl]acetyl}piperidine - 4 - yl) - 1,3 - thiazol - 4 - yl] - 4 - [3,5 - bis(difluoromethyl)-1H - pyrazol - 1 - yl] - 1 - [4 - (4 - {5 - [2 - fluoro - 6 - (prop - 2 - yn - 1 - yloxy)phenyl] - 4,5 - dihydro - 1,2 - oxazole - 3 - yl} - 1,3 - thiazol - 2 - yl)piperidin - 1 - yl]ethanone, ([[]] ,5-Dihydro-1,2-oxazol-5-yl}-3-chlorophenyl methanesul phonate, (15.041) ipfencarbazone, (15.042) 2-{2-fluoro -6-[(8-fluoro-2-methylquinolin-3-yl)oxy]phenyl}propane -2-ol, (15.043) flucoxapropin, (15.044) 2-{3- 2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acet yl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro- 1,2-oxazol-5-yl}phenyl methanesulfonate, (15.045) 2 -phenylphenol and salts, (15.046) 3-(4,4,5-trifluoro-3, 3-dimethyl-3,4-dihydroisoquinolin-1-yl)quinoline, (15.047) quinofumelin, (15.048) 4-amino-5-fluoropyrimidin-2-ol (mut ant form: 4-amino-5-fluoropyrimidin-2(1H)-one), (15.049 ) 4-oxo-4-[(2-phenylethyl)amino]butanoic acid, (15.050) 5- amino-1,3,4-thiadiazole-2-thiol, (15.051) 5-chloro-N '-phenyl-N'-(prop-2-yn-1-yl)thiophene 2-sulfonohydra zide, (15.052) 5-fluoro-2-[(4-fluorobenzyl)oxy]pyrimi dine-4-amine, (15.053) 5-fluoro-2-[(4-methylbenzyl)oxy pyrimidine-4-amine, (15.054) 9-fluoro-2,2-dimethyl-5- (quinolin-3-yl)-2,3-dihydro-1,4-benzoxazepine, (15.0 55) but-3-yn-1-yl{6-[({[(Z)-(1-methyl-1H-tetraz -{[(1-Methyl-1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl }carbamate, (15.056)(2Z)-3-Amino-2-cyano-3-phenylac rylic acid ethyl ester, (15.057)Phenazine-1-carboxylic acid, (15.058)3, 4,5-Trihydroxybenzoic acid propyl ester, (15.059)Quinolin-8-ol, ( 15.060)Quinolin-8-ol sulfate (2:1), (15.061){6- [({[(1-Methyl-1H-tetrazol-5-yl)(phenyl)methylene]amino }oxy)methyl]pyridin-2-yl}carbamic acid tert-butyl, (15.06 2)5-Fluoro-4-imino-3-methyl-1-[(4-methylphenyl)sulfonyl -3,4-dihydropyrimidin-2(1H)-one, (15.063)Aminopyrifl ene, (15.064)(N′-[2-Chloro-4-(2-fluorophenoxy)-5-meth ylphenyl]-N-ethyl-N-methylimidohydroxylamine), (15.065)(N ′-(2-Chloro-5-methyl-4-phenoxyphenyl)-N-ethyl-N-methylim idohydroxylamine), (15.066)(2-{2-[(7,8-Difluoro-2-meth ylquinolin-3-yl)oxy]-6-fluorophenyl}propan-2-ol), ( 15.067)(5-Bromo-1-(5,6-dimethylpyridin-3-yl)-3,3- dimethyl-3,4-dihydroisoquinoline), (15.068)(3-(4,4-Diflu oro-5,5-dimethyl-4,5-dihydrothieno[2,3-c]pyridin-7-yl) quinoline), (15.069)(1-(4,5-Dimethyl-1H-benzimidazol- (1-ethyl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline) 、(15.070)8-fluoro-3-(5-fluoro-3,3-dimethyl-3,4-di hydroisoquinolin-1-yl)quinolone、(15.071)8-fluoro-3-(5- fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl) quinolone、(15.072)3-(4,4-difluoro-3,3-dimethyl-3,4-di hydroisoquinolin-1-yl)-8-fluoroquinoline、(15.073)(N-methyl -N-phenyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol -3-yl]benzamide)、(15.074)(methyl{4-[5-(trifluorometh yl)-1,2,4-oxadiazol-3-yl]phenyl}carbamate)、(15 .075)(N-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol -3-yl]benzyl}cyclopropanecarboxamide)、(15.076)N-methyl -4-(5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]ben zamide、(15.077)N-[(E)-methoxyiminomethyl]-4-[5-(tri fluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide、(15. 078)N-[(Z)-methoxyiminomethyl]-4-[5-(trifluoromethyl)- 1,2,4-oxadiazol-3-yl]benzamide、(15.079)N-[4- [5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl] -cyclopropanecarboxamide、(15.080)N-(2-fluorophenyl)-4 -[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzam Mido, (15.081) 2,2-difluoro-N-methyl-2-[4-[5-(trifluoro methyl)-1,2,4-oxadiazol-3-yl]phenyl]-acetamide, (15.082) N-allyl-N-[[4-[5-(trifluoromethyl)-1,2,4 -oxadiazol-3-yl)phenyl]methyl]acetamide, (15.083) N -[(E)-N-methoxy-C-methyl-carbonimidoyl]-4-(5-(trifluoro methyl)-1,2,4-oxadiazol-3-yl]-benzamide, (15.08 4) N-[(Z)-N-methoxy-C-methyl-carbonimidoyl]-4-[5-(tri fluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15. 085) N-allyl-N-[[4-[5-(trifluoromethyl)-1,2,4-oxa diazol-3-yl)phenyl]methyl]propanamide, (15.086) 4,4 -dimethyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol yl-3-yl]phenyl]methyl]pyrrolidin-2-one, (15.087) N-methyl -4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]-be nzencarbothioamide, (15.088) 5-methyl-1-[[4-[5-(triflu oromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]pyrrolidi ne-2-one, (15.089) N-((2,3-difluoro-4-[5-(trifluoro romethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]-3,3, 3-trifluoro-propanamide, (15.090) 1-methoxy-1-methyl-3- [[4-[5-(Trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.091) 1,1-diethyl-3-[[4-[5-(trifluoro romethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea , (15.092) N-[[4-[5-(Trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide, (15.093) N-methoxy -N-[[4-[5-(Trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]cyclopropanecarboxamide, (15.094) 1-methoxy -3-methyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.095) N-methoxy-N- [4-[5-(Trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]cyclopropanecarboxamide, (15.096) N,2-dimethoxy-N -[[4-[5-(Trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide, (15.097) N-ethyl-2-methyl-N- 4-[5-(Trifluoromethyl)-1,2,4-oxadiazol-3-yl)phenyl]methyl]propanamide, (15.098) 1-methoxy-3-methyl-1-[[4 [5-(Trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.099) 1,3-dimethoxy-1-[[4-[5-(trifluoro romethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, ( [4-[5-(Trifluoromethyl)-1,2,4-oxadiazol-3-yl] phenyl]methyl]propanamide, (15.097) N-ethyl-2-methyl-N- 4-[5-(Trifluoromethyl)-1,2,4-oxadiazol-3-yl)phenyl]methyl]propanamide, (15.098) 1-methoxy-3-methyl-1-[[4 [5-(Trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.099) 1,3-dimethoxy-1-[[4-[5-(trifluoro romethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, ( methyl]urea, (15.099) 1,3-dimethoxy-1-[[4-[5-(trifluoro romethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, ( ​​15.100) 3-Ethyl-1-methoxy-1-[[4-[5-(trifluoromethyl) -1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.101 ) 1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl phenyl]methyl]piperidin-2-one, (15.102) 4,4-dimethyl-2 -[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl] phenyl]methyl]isoxazolidin-3-one, (15.103) 5,5-dimethyl -2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl phenyl]methyl]isoxazolidin-3-one, (15.104) 3,3-dimethyl -1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3 -yl]phenyl]methyl]piperidin-2-one, (15.105) 1-[[3-fluoro -4-(5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl] phenyl]methyl]azepan-2-one, (15.106) 4,4-dimethyl-2- 4-(5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl methyl]isoxazolidin-3-one (15.107) 5,5-dimethyl-2- [[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl methyl]isoxazolidin-3-one, (15.108) ethyl (1-{4- [5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzyl} -1H-pyrazol-4-yl)acetate, (15.109) N,N-dimethyl-1- {4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzene Zir}-1H-1,2,4-triazol-3-amine and (15.110) N-{2, 3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol- 3-yl]benzyl}butanamide.

[0166] Biopesticides as a mixing component The compound of formula (I) can be combined with biopesticides.

[0167] Biopesticides include, in particular, bacteria, fungi, yeasts, plant extracts, and products formed by microorganisms (e.g., proteins or secondary metabolites), etc.

[0168] Biopesticides include bacteria, such as spore-forming bacteria, bacteria that form colonies on roots, and bacteria that act as biological insecticides, fungicides, or nematicides.

[0169] Examples of such bacteria used or usable as biopesticides are as follows : Bacillus amyloliquefaciens strain FZB42 (DSM 231179), or Bacillus cereus, in particular, Bacillus cereus strain C NCM I-1562, or Bacillus firmus strain I-1582 (deposit number CNCM I-1582), or Bacillus pumilus , in particular, strain GB34 (deposit number ATCC 70081 4) and strain QST2808 (deposit number NRRL B-30087), or Bacillus s 4) and strain QST2808 (deposit number NRRL B-30087), or Bacillus s ​Bacillus subtilis, particularly strain GB03 (deposit number ATC C SD-1397), or Bacillus subtilis strain QST713 (deposit number NRRL B-21661), or Bacillus subtil is strain OST 30002 (deposit number NRRL B-50421), Bacillus thuringiensis, particularly Bacillus thuringiensis subspecies israelensis (antigen type H-14) strain AM65-52 (deposit number ATCC 1276), or Bacillus thuring iensis subspecies aizawai, particularly strain ABTS-1857 (SD-1372), or Bacillus thuringiensis subspecies kurstaki strain HD-1, or Bacillus thuringiensis subspecies tenebrioni s strain NB 176 (SD-5428), Pasteuria penetrans, Pasteuria spp. (Ro tylenchulus reniformis nematode)-PR3 (deposit number ATCC SD-5834), Streptomyces microflavus strain AQ6121 (= QRD 31.013, NRRL B-50550), Streptomyces galbus strain HD-1, or Bacillus thuringiensis subspecies tenebrioni s) strain NB 176 (SD-5428), Pasteuria penetrans, Pasteuria spp. (Ro tylenchulus reniformis nematode)-PR3 (deposit number ATCC SD-5834), Streptomyces microflavus strain AQ6121 (= QRD 31.013, NRRL B-50550), Streptomyces galbus strain AQ6121 (= QRD 31.013, NRRL B-50550), Streptomyces galbus strain AQ6121 (= QRD Paecilomyces galbus strain AQ 6047 (Accession No. NRRL 30232) .

[0170] Examples of fungi and yeasts that are used or can be used as biopesticides are as follows.

[0171] Beauveria bassiana, in particular, strain ATC C 74040, Coniothyrium minit ans, in particular, strain CON / M / 91-8 (Accession No. DSM-9660), Lecanicillium spp., in particular, strain HRO LEC 12, Lecanicillium lecanii (formerly known as Verticillium lecanii), in particular, strain KV01, Metarhizium anisopliae, in particular, strain F52 (DSM3884 / ATCC 90448 )), Metschnikowia fructic ola, in particular, strain NRRL Y-30752, Paecilomyces fumosoroseus (Pa ecilomyces fumosoroseus) (currently: Isaria fumosorosea( Isaria fumosorosea)), in particular, strain IFPC 200613 or strain A popka 97 (Accession No. ATCC 20874), Paecilomyces lilacinus (P aecilomyces lilacinus), in particular, Paecilomyces lilacinus (P. lilacinus) strain 251 (AGAL 89 / 030550), Talaro myces · Talaromyces flavus, in particular strain V117b, Trichoderma atroviride, in particular strain SC 1 (deposit number CBS 122089), Trichoderma harzianum rma harzianum, in particular Trichoderma harzianum rifai T39 (deposit number CNCM I-952).

[0172] Examples of viruses that are used or can be used as biopesticides are as follows: Adoxophyes orana granulovirus (GV), Cydia pomonella granulovirus (GV), Helicoverpa armigera nucleopolyhedrovirus (NPV), Spodoptera exigua mNPV, Spodoptera frugiperda mNPV, Spodoptera littoralis NPV. Spodoptera exigua mNPV, Spodoptera frugiperda mNPV, Spodoptera littoralis NPV. ican cotton leafworm)(Spodoptera littora lis)NPV.

[0173] Bacteria and fungi that are added as "inoculum sources" to plants or plant parts or plant organs and that enhance plant growth and plant health by virtue of their specific properties are likewise included. Examples that can be cited are as follows. Agrobacterium spp., Azorhizobium · caulinodans, Azospirillum

[0174] Agrobacterium spp., Azorhizobium · caulinodans, Azospirillum Azospirillum spp., Azotobacter spp., Bradyrhizobium sp p., Burkholderia spp., in particular, Burkholderia cepacia (previously known as Pseudomonas cepacia) , Gigaspora spp. or Gigaspora monosporum, Glomus spp. , Laccaria spp., Lactobacillus buchneri , Paraglomus spp., Pisolithus tinctorus , Pseudomonas spp., Rhizobium spp., in particular, Rhizobium trifolii , Rhizopogon spp., Scleroderma spp. , Suillus spp. , Streptomyces spp. Examples of products formed by plant extracts and microorganisms (which include proteins and secondary metabolites) that are used or can be used as biopesticides are as follows: Garlic (Allium sativum), wormwood (Artemisia ab .

[0175] ​​​​​​sinthium), azadirachtin, Biokeepe r WP, Cassia nigricans, Celastrus angulatus, Chenopodium anthelminticum chitin, Armour-Z en, Dryopteris filix-mas, Equisetum arvense Fortune Aza, Fungastop, He ads Up (Chenopodium quinoa saponin extract), Pyrethrum / pyrethrins Quassia amara, Quercus, Quillaja Regalia, ("Requiem (trademark) Insecticide"), rotenone, Ryania / ryania noidin, Symphytum officinale, Tanacetum vulgare thymol, Triact 70, TriCon Tropaeulum majus, Urtica dioica Veratrin, Viscum album Brassicaceae extract, especially rapeseed powder or mustard powder and biopesticide / acaricidal active substances obtained from olive oil, especially, for example, carbon chain lengths C -C having 16 -C 20 unsaturated fats / carboxylic acids. A phytotoxicity reducing agent as a mixed component

[0176] A phytotoxicity reducing agent as a mixed component The compound of formula (I) is a phytotoxicity reducing agent, for example, benoxacor, cloquintocet (-mexyl), cimetrinil, cyprosulfamide, dichloramide, fenchlorazole ( -ethyl), fenclorim, flurazole, flutriafol, furilazole, isoxa difen (-ethyl), mefenpyr (-diethyl), naphthalic anhydride, oxabet rinyl, 2-methoxy-N-({4-[(methylcarbamoyl)amino]phenyl}sulf honyl)benzamide (CAS 129531-12-0), 4-(dichloroacetyl) -1-oxa-4-azaspiro[4.5]decane (CAS 71526-07-3), 2 ,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine (CAS 52836-31-4).

[0177] Plants and parts of plants According to the present invention, all plants and plant parts can be treated. Here, plants are all plants and plant parts such as desirable and undesirable wild plants or crop plants (including naturally occurring crop plants), for example, cereals (wheat, rice, triticale, barley, rye, oats), maize, soybeans, potatoes, sugar beets, sugarcane, tomatoes, peppers, cucumbers, melons, carrots, watermelons, onions, lettuce, spinach, leeks, kidney beans, plants of the genus Brassica of the family Brassicaceae (Brassica o leracea) (for example, cabbage) and other vegetable species, cotton, tobacco, rapeseed, and further, fruit plants (fruits include apples, pears, citrus fruits and grapes), etc. are to be understood as such. Crop plants can be obtained by conventional breeding methods and optimization methods. may be obtained by biotechnological and genetic engineering methods or a plant obtainable by a combination of these methods. Such crop plants also include transgenic plants. It also includes plant varieties which may or may not be protected by plant variety property rights. Plants may be grown at all stages of development, e.g. seeds, seedlings, young plants (immature plants) to mature plants. Plant parts include shoots, leaves, flowers and roots. " should be understood to mean all parts and organs of the plant, above ground and below ground. Examples which may be mentioned are leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, as well as tubers. Plant parts include harvested plants or harvested plant parts, as well as In addition, vegetative propagation materia l) and reproductive organs (generative propagation materi al), such as seedlings, tubers, rhizomes, cuttings and seeds.

[0178] The treatment according to the invention of plants and plant parts with compounds of formula (I) can be carried out according to conventional treatment methods. For example, by immersion, spraying, vaporization, fogging, scattering, painting, injection or by applying the compounds to the surroundings, habitat or areas of plants and plant parts. This is done by affecting the storage space and the propagation organs. In the case of the material, especially in the case of seeds, one or more additional coatings may be applied. This can also be done by:

[0179] As already described above, according to the present invention, all plants and parts thereof can be processed. In preferred embodiments, wild plant species and plant varieties, or plant species and plant varieties obtained by conventional methods of plant breeding such as crossing or protoplast fusion, and their parts are processed. In yet another preferred embodiment, transgenic plants and plant varieties (genetically modified organisms) obtained by genetic engineering methods, optionally in combination with conventional methods, and their parts are processed when appropriate. The terms "parts" or "parts of plants" or "plant parts" have already been described above. The present invention is particularly preferably used to process individual commercially available conventional varieties or plants of conventional varieties in use. A plant variety should be understood to mean a plant having new characteristics ("traits") obtained by conventional breeding or mutagenesis or recombinant DNA technology. They can be varieties, variants, biotypes or genotypes.

[0180]

[0180] According to the present invention, the compounds of formula (I) can be advantageously used to treat transgenic plants, plant cultivars or plant parts that have received genetic material conferring advantageous and / or useful characteristics (traits) to these plants, plant varieties or plant parts. Thus, the present invention is considered to be combinable with one or more recombinant traits or transgenic events, or combinations thereof. For the purposes of the present application, a transgenic event is the integration of a specific recombinant DNA molecule at a specific location (locus) within the chromosome of the plant genome. It is created by insertion. Upon insertion, a new DNA sequence called an "event" is created, which is characterized by the inserted recombinant DNA molecule and some amount of genomic DNA flanking / adjacent to both ends of the inserted DNA. Such traits or transgenic events include, but are not limited to, disease organism resistance, water use efficiency, yield performance, drought tolerance, seed quality, improved nutritional quality, hybrid seed production, and herbicide tolerance. The trait is measured with respect to a plant lacking such a trait or transgenic event. Specific examples of such advantageous and / or useful characteristics (traits) are better plant growth, vigor, stress tolerance, standability, lodging tolerance, nutrient uptake, plant nutrients, and / or yield, particularly improved growth, increased tolerance to high or low temperatures, improved tolerance to drought or water or soil salt levels, improved flowering performance, ease of harvesting, accelerated ripening, increased yield, improved quality and / or nutritional value of the harvested product, improved storage life and / or processability of the harvested product, and increased resistance or tolerance to animal and microbial disease organisms such as insects, arachnids, nematodes, mites, slugs, and snails. Among the DNA sequences encoding proteins conferring such resistance or tolerance to animal and microbial disease organisms, particularly insects, the genetic material from Bacillus thuringiensis encoding the Bt protein is particularly mentioned. Genetic materials from bacteria such as Photorhabdus (WO97 / 17432 and WO98 / 08932) are also extracted.

[0181] well-documented in the literature and known to those skilled in the art. ringiensis) is particularly mentioned. Genetic materials from bacteria such as Photorhabdus (WO97 / 17432 and WO98 / 08932) are In particular, the proteins CryA, CryIAb, CryIAc, and C ryIIA, CryIIIA, CryIIIB2, Cry9cCry2Ab, Cry3B b and CryIF proteins or toxic fragments thereof, and hybrids or combinations thereof In particular, CryIF proteins or hybrids derived from CryIF proteins (e.g. For example, a hybrid CryIA-CryIF protein or a toxic fragment thereof, CryIA type protein or a toxic fragment thereof, preferably a CryIAc protein or a CryIAc Protein-derived hybrids (e.g., hybrid CryIAb-CryIAc proteins) protein) or CryIAb or Bt2 protein or a toxic fragment thereof, Cry2Ae, C ry2Af or Cry2Ag protein or a toxic fragment thereof, CryIA.105 protein protein or a toxic fragment thereof, VIP3Aa19 protein, VIP3Aa20 protein, VIP3A protein produced in COT202 or COT203 cotton events, Est ruch et al., (1996), Proc Natl Acad Sci USA 28;93(11):5389-94 or a VIP3Aa protein thereof the toxic fragments thereof, the Cry proteins described in WO2001 / 47952, Xenorhabdus (X enorhabdus), Serratia (especially Serratia entomoph from S. entomophila or Photorhabdus Insecticidal proteins from species of the genus W. dus (described in WO 98 / 50427), e.g. Tc- from Photorhabdus described in O98 / 08932 Proteins such as Bt Cry or VIP proteins are also included. Variants or mutants of any of these proteins, or any other protein or peptide, which differ from any of these sequences, in particular their toxic fragments, by several amino acids (1 to 10, preferably or 1 to 5), or which are fused to a transport peptide, such as a plastid transport peptide, are also included herein. Another and particularly emphasized example of such a property is the imparted resistance to one or more herbicides, such as imidazolinones, sulfonylureas, glyphosate or phosphinothricin. Among the DNA sequences encoding proteins that confer resistance to specific herbicides in transformed plant cells and plants, in particular, the bar or PAT genes described in WO2009 / 152359, which confer resistance to glyphosate-based herbicides, or the Streptomyces coelicolor genes described in WO2009 / 152359, which confer resistance to glufosinate-based herbicides,

[0182] targeting herbicides having EPSPS, in particular herbicides such as glyphosate and its salts, suitable genes encoding EPSPS (5-enolpyruvylshikimate-3-phosphate synthase) that confer resistance, genes encoding glyphosate -n-acetyltransferase, or genes encoding glyphosate oxidoreductase can be mentioned. Further suitable herbicide resistance traits include at least one ALS (acetolactate synthase) inhibitor (e.g., WO2007 / 024782), a mutated Arabidopsis ALS / AHAS gene (e.g., U.S. Patent No. 6,855,533), 2,4-D (2,4-dichloro phenoxyacetic acid), coelicolor) gene, AHAS gene (e.g., U.S. Patent No. 6,855,533), 2,4-D (2,4-dichloro ​​​​​​​​​​​A gene encoding a 2,4-D-monooxygenase that confers resistance to (chlorophenoxyacetic acid) and a gene encoding a dicamba monooxygenase that confers resistance to dicamba (3,6-dichloro-2-methoxybenzoic acid). is included. Further particularly emphasized examples of such properties are, for example, systemic acquired resistance (SAR),

[0183] systemins, phytoalexins, elicitors, and an increase in resistance to phytopathogenic fungi, bacteria and / or viruses by resistance genes and correspondingly expressed proteins and toxins. Particularly useful transgenic events in transgenic plants or plant varieties that can preferably be processed according to the invention include event 531 / PV-GHBK0 4 (cotton, insect control, described in WO2002 / 040677), event 1143-14A

[0184] (cotton, insect control, not deposited, described in WO2006 / 128569); event 1143- 51B (cotton, insect control, not deposited, described in WO2006 / 128570); event 14 (cotton, herbicide resistance, not deposited, described in US-A2002-120964 or WO2002 / 034946); event 17053 (rice, herbicide resistance, deposited as PTA-9843, described in WO2010 / 117737); event 17314 (rice, herbicide resistance , deposited as PTA-9844, described in WO2010 / 117735); event 281 (cotton, insect control - herbicide resistance, deposited as PTA-6233, described in WO20 05 / 103266 or US-A2005-216969); event 3006- 210-23 (cotton, insect control - herbicide resistance, deposited as PTA-6233, described in US-A2 and deposited as PTA-6233, described in US-A2005-216969); event 3006- 210-23 (cotton, insect control - herbicide resistance, deposited as PTA-6233, US-A2 05 / 103266 or US-A2005-216969); event 3006- 210-23 (cotton, insect control - herbicide resistance, deposited as PTA-6233, US-A2 007 - 143876 or as described in WO2005 / 103266); Event 3272 (maize, quality trait, deposited as PTA - 9972, as described in WO2006 / 098952 or US - A2006 - 230473); Event 33391 (wheat, herbicide tolerance, deposited as PTA - 2347, as described in WO2002 / 027004), Event 4041 6 (maize, insect control - herbicide tolerance, deposited as ATCC PTA - 11508, W O11 / 075593); Event 43A47 (maize, insect control - herbicide tolerance, deposited as ATCC PTA - 11509, as described in WO2011 / 075595); Event 5307 (maize, insect control, deposited as ATCC PTA - 9561, W O2010 / 077816); Event ASR - 368 (bentgrass, herbicide tolerance, deposited as ATCC PTA - 4816, as described in US - A2006 - 162007 or WO2 004 / 053062); Event B16 (maize, herbicide tolerance, not deposited, as described in US - A2003 - 126634); Event BPS - CV127 - 9 (soybean, herbicide tolerance, deposited as NCIMB No.41603, described in WO2010 / 080829 ); Event BLR1 (rape, restoration of male sterility, deposited as NCIMB41193 , as described in WO2005 / 074671), Event CE43 - 67B (cotton, insect control, deposited as DSM ACC2724, as described in US - A2009 - 217423 or WO2006 / 128573 ); Event CE44 - 69D (cotton, insect control, not deposited, US - A 2010 - 0024077); Event CE44 - 69D (cotton, insect control, not deposited ), as described in US - A2010 - 0024077 Deposited, described in WO2006 / 128571); Event CE46-02A (cotton, insect control , not deposited, described in WO2006 / 128572); Event COT102 (cotton, insect control, not deposited, described in US-A2006-130175 or WO2004 / 039986) ; Event COT202 (cotton, insect control, not deposited, described in US-A2007-067868 or WO2005 / 054479); Event COT203 (cotton, insect control, not deposited, described in WO2005 / 054480); Event DAS21606-3 / 1606 ( soybean, herbicide tolerance, deposited as PTA-11028, described in WO2012 / 033794) , Event DAS40278 (maize, herbicide tolerance, deposited as ATCC PTA-102 44, described in WO2011 / 022469); Event DAS-44406- 6 / pDAB8264.44.06.1 (soybean, herbicide tolerance, deposited as PTA-11336 and described in WO2012 / 075426), Event DAS-14536-7 / pD AB8291.45.36.2 (soybean, herbicide tolerance, deposited as PTA-11335 and described in WO2012 / 075429), Event DAS-59122-7 (maize , insect control-herbicide tolerance, deposited as ATCC PTA11384, described in US-A2006-0 70139); Event DAS-59132 (maize, insect control-herbicide tolerance, not deposited, described in WO2009 / 100188); Event DAS68416 (soybean , herbicide tolerance, deposited as ATCC PTA-10442, described in WO2011 / 066384 or WO2011 / 066360); Event DP-098140-6 (maize , herbicide tolerance, deposited as ATCC PTA-8296, described in US-A2009-13739 5 or as described in WO08 / 112019; Event DP-305423-1 (soybean, variety trait, un-deposited, described in US-A2008-312082 or WO2008 / 054747 ); Event DP-32138-1 (maize, hybridization system, deposited as AT CCPTA-9158, described in US-A2009-0210970 or WO2009 / 103049); Event DP-356043-5 (soybean, herbicide tolerance, deposited as AT CCPTA-8287, described in US-A2010-0184079 or WO2008 / 002872); Event EE-I (eggplant, insect control, un-deposited, described in WO07 / 09 1277); Event Fil 17 (maize, herbicide tolerance, deposited as ATCC209 031, described in US-A2006-059581 or WO98 / 044140 ); Event FG72 (soybean, herbicide tolerance, deposited as PTA-11041 in WO2011 / 063 413, described therein), Event GA21 (maize, herbicide tolerance, deposited as ATCC 209033, described in US-A2005-086719 or WO98 / 044140 ); Event GG25 (maize, herbicide tolerance, deposited as ATCC209032 and described in US-A2005-188434 or WO98 / 044140); Event GHB119 (cotton, insect control - herbicide tolerance, deposited as ATCCPTA-8398, described in W O2008 / 151780); Event GHB614 (cotton, herbicide tolerance, deposited as ATC CPTA-6878, described in US-A2010-050282 or W02007 / 0 17186); Event GJ11 (maize, herbicide tolerance, deposited as ATCC2090 Deposited as 30, described in US-A2005-188434 or WO98 / 044140) ; event GMRZ13 (sugar beet, virus resistance, deposited as NCIMB-41601 and described in WO2010 / 076212); event H7-l (sugar beet, herbicide tolerance, deposited as NCIMB41158 or NCIMB41159, described in US-A20 04-172669 or WO2004 / 074492); event JOPLINl (wheat, disease resistance, not deposited, described in US-A2008-064032); event LL 27 (soybean, herbicide tolerance, deposited as NCIMB41658, described in WO2006 / 1086 74 or US-A2008-320616); event LL55 (soybean, herbicide tolerance, deposited as NCIMB41660, described in WO2006 / 108675 or US-A20 08-196127); event LL cotton 25 (cotton, herbicide tolerance, deposited as ATCCPT A-3343, described in WO2003 / 013224 or US-A2003-0976 87); event LLRICE06 (rice, herbicide tolerance, deposited as ATCC203353 and described in US6,468,747 or WO2000 / 026345); event LL rice 62 (rice, herbicide tolerance, deposited as ATCC203352, described in WO2000 / 0 26345), event LL rice 601 (rice, herbicide tolerance, deposited as ATCCPTA-2 600, described in US-A2008-2289060 or WO2000 / 026356 ); event LY038 (maize, quality trait, deposited as ATCCPTA-5623 and described in US-A2007-028322 or WO2005 / 061720); event MIR162 (maize, insect control, deposited as PTA-8166, US- A2009-300784 or as described in WO2007 / 142840); event MIR6 04 (maize, insect control, not deposited, US-A2008-167456 or WO20 05 / 103301); event MON15985 (cotton, insect control, deposited as ATCCP TA-2516, US-A2004-250317 or as described in WO2002 / 100 163); event MON810 (maize, insect control, not deposited, US-A2 002-102582); event MON863 (maize, insect control, deposited as AT CCPTA-2605, WO2004 / 011601 or US-A2006- 095986); event MON87427 (maize, pollination control, deposited as ATCC PTA-7899, as described in WO2011 / 062904); event MON8 7460 (maize, stress tolerance, deposited as ATCCPTA-8910, WO2 009 / 111263 or US-A2011-0138504); event MON 87701 (soybean, insect control, deposited as ATCCPTA-8194, US-A200 9-130071 or as described in WO2009 / 064652); event MON87705 (soybean, quality trait - herbicide tolerance, deposited as ATCCPTA-9241, US-A20 10-0080887 or as described in WO2010 / 037016); event MON877 08 (soybean, herbicide tolerance, deposited as ATCCPTA-9670, WO2011 / 03 4704); event MON87712 (soybean, yield, deposited as PTA-10296 and as described in WO2012 / 051199), event MON87754 (soybean, quality Quality trait, deposited as ATCC PTA-9385, described in WO2010 / 024976; Event MON87769 (soybean, quality trait, deposited as ATCC PTA-8911, described in US-A2011-0067141 or WO2009 / 102873); event MON88017 (maize, insect control - herbicide tolerance, deposited as ATCC PTA-5582 and described in US-A2008-028482 or WO2005 / 059103); Event MON88913 (cotton, herbicide tolerance, deposited as ATCC PTA-4854, described in WO2004 / 072235 or US-A2006-059590); event M ON88302 (rape, herbicide tolerance, deposited as PTA-10955, described in WO2011 / 153186); event MON88701 (cotton, herbicide tolerance, deposited as PTA-11 754 and described in WO2012 / 134808); event MON89034( maize, insect control, deposited as ATCC PTA-7455, described in WO07 / 14025 6 or US-A2008-260932); event MON89788 (soybean, herbicide tolerance, deposited as ATCC PTA-6708, described in US-A2006-282915 or WO2006 / 130436); event MS11 (rape, pollination control - herb icide tolerance, deposited as ATCC PTA-850 or PTA-2485, described in WO2001 / 03 1042); event MS8 (rape, pollination control - herbicide tolerance, deposited as ATCC PTA -730 and described in WO2001 / 041558 or US-A2003-188347 ); event NK603 (maize, herbicide tolerance, deposited as ATCC PTA-2478 and described in US-A2007-292854); event PE-7 (rice, insect Control, not deposited, described in WO2008 / 114282); Event RF3 (rape, pollination Control - herbicide tolerance, deposited as ATCC PTA - 730, described in WO2001 / 041558 or also described in US - A2003 - 188347); Event RT73 (rape, herbicide tolerance , not deposited, described in WO2002 / 036831 or US - A2008 - 070260); Event SYHT0H2 / SYN - 000H2 - 5 (soybean, herbicide tolerance, deposited as PTA - 11 2 26, described in WO2012 / 082548), Event T227 - 1 (sugar beet, herbicide tolerance, not deposited, described in WO2002 / 44407 or US - A2009 - 26 5817); Event T25 (maize, herbicide tolerance, not deposited, described in US - A20 01 - 029014 or WO2001 / 051654); Event T304 - 40 (cotton, insect control - herbicide tolerance, deposited as ATCC PTA - 8171, described in US - A201 0 - 077501 or WO2008 / 122406); Event T342 - 142 (cotton, insect control, not deposited, described in WO2006 / 128568); Event TC150 7 (maize, insect control - herbicide tolerance, not deposited, described in US - A2005 - 039226 or also described in WO2004 / 099447); Event VIP1034 (maize, insect control - herbicide tolerance, deposited as ATCC PTA - 3925, described in WO2003 / 052073 ); Event 32316 (maize, insect control - herbicide tolerance, deposited as PTA - 115 07, described in WO2011 / 084632), Event 4114 (maize , insect control - herbicide tolerance, deposited as PTA - 11506, described in W02011 / 08462 described in 1), the event EE-GM1 / LL27 or the event EE-GM2 / LL55 (W O2011 / 063413A2) may be stacked with the event EE-GM3 / FG72 (soy beans, herbicide tolerance, ATCC Deposit No. PTA-11041), the event DAS-6841 6-4 (soybeans, herbicide tolerance, ATCC Deposit No. PTA-10442, WO2011 / 0 66360A1), the event DAS-68416-4 (soybeans, herbicide tolerance, ATCC deposit number PTA-10442, WO2011 / 066384A1), the event DP-040 416-8 (corn, insect control, ATCC Deposit No. PTA-11508, WO20 11 / 075593A1), the event DP-043A47-3 (corn, insect control , ATCC Deposit No. PTA-11509, WO2011 / 075595A1), the event DP-004114-3 (corn, insect control, ATCC Deposit No. PTA-1150 6, WO2011 / 084621A1), the event DP-032316-8 (corn , insect control, ATCC Deposit No. PTA-11507, WO2011 / 084632A1 ), the event MON-88302-9 (rape, herbicide tolerance, ATCC deposit number PTA -10955, WO2011 / 153186A1), the event DAS-21606-3( soybeans, herbicide tolerance, ATCC Deposit No. PTA-11028, WO2012 / 03379 4A2), the event MON-87712-4 (soybeans, quality traits, ATCC deposit number PT A-10296, WO2012 / 051199A2), the event DAS-44406-6 (soybeans, cumulative herbicide tolerance, ATCC Deposit No. PTA-11336, WO2012 / 07 5426A1), the event DAS-14536-7 (soybeans, cumulative herbicide tolerance, ATCC Deposit number PTA - 11335, WO2012 / 075429A1), event SYN - 0 00H2 - 5 (soybean, herbicide tolerance, ATCC deposit number PTA - 11226, WO201 2 / 082548A2), event DP - 061061 - 7 (rape, herbicide tolerance, commission number not available, WO2012071039A1), event DP - 073496 - 4 (rape, herbicide tolerance, commission number not available, US2012131692), event 8264.44.06.1 (soybean, cumulative herbicide tolerance, deposit number PTA - 11336 , WO2012075426A2), event 8291.45.36.2 (soybean, cumulative herbicide tolerance, deposit number PTA - 11335, WO2012075429A2), event SYHT0H2 (soybean, ATCC deposit number PTA - 11226, WO2012 / 082 548A2), event MON88701 (cotton, ATCC deposit number PTA - 11754 , WO2012 / 134808A1), event KK179 - 2 (alfalfa, AT CC deposit number PTA - 11833, WO2013 / 003558A1), event pDA B8264.42.32.1 (soybean, cumulative herbicide tolerance, ATCC deposit number PTA - 11 993, WO2013 / 010094A1), event MZDT09Y (maize, ATCC deposit number PTA - 13025, WO2013 / 012775A1), etc. are available.

[0185] Furthermore, a list of such transgenic events is provided by the Animal and Plant Health Inspection Service (APHIS) of the United States Department of Agriculture (USDA). aphis.usda.gov of Website on the World Wide Web can be found at For the present application, in this application What mattered was the status of such a list as of the filing date.

[0186] The gene / event conferring the desired trait of interest may also be present in combination with each other in the transgenic plant. Examples of transgenic plants that can be mentioned are cereals (wheat, rice, triticale, barley, rye, oats), maize soybeans, potatoes, sugarcane, sugarcane, tomatoes, peas and other types of vegetables, cotton, tobacco, rape, and furthermore important crop plants such as fruit plants (including fruit apples, pears, citrus fruits, grapes), with particular emphasis on maize, soybeans wheat, rice, potatoes, cotton, sugarcane, tobacco and rape. Particular emphasis

[0187] is placed on the enhanced resistance of the plant to insects, spiders, nematodes and slugs and snails and the enhanced resistance of the plant to one or more herbicides. Examples of commercially available such plants, plant parts or plant seeds that can be preferably treated according to the invention are GENUITY®, DROUGHTGARD®, SMART TSTAX®, RIB COMPLETE®, ROUNDUP R DTM EADY®, VT DOUBLE PRO®, VT TRIPLE PRO®, BOLLGARD II®, ROUNDUP READ There are commercial products such as plant seeds sold or distributed under the trademark name of (

[0188] Crop protection - Type of treatment The treatment of plants and plant parts with the compounds of formula (I) is carried out using conventional treatment methods, for example by dipping, spraying, atomizing, irrigation, vaporization, dusting, smoking, scattering, foaming, coating, diffusion (sp reading-on), injection, watering (drenching), drip irrigation, etc., and, in the case of propagation material, especially seeds, furthermore, as a powder for dry seed treatment, as a liquid for liquid seed treatment, as an aqueous solvent for slurry treatment, by coating, coating with one or more coatings, etc., directly, or by acting on the surroundings, habitat or storage space of the plants and plant parts. Furthermore, it is also possible to apply the compounds of formula (I) by the ultra-low volume method, or to inject the application form or the compounds of formula (I) themselves into the soil. soil.

[0189] A preferred direct treatment of the plant is foliar application, i.e., applying the compounds of formula (I) to the foliar parts, in which case the treatment frequency and application rate should be adjusted according to the level of occurrence of the pest.

[0190] In the case of systemic active compounds, the compounds of formula (I) can also reach the plant via the root system. Therefore, the plant is treated by acting the compounds of formula (I) on the habitat of the plant. This can be done, for example, by drenching, or by mixing with the soil or nutrient solution [i.e., in the growth place of the plant (e.g., soil, or hydroponic system)] or ​​By impregnating a liquid form of the compound of formula (I), or by introducing the compound of formula (I) according to the invention in solid form (e.g. in granular form) into the plant growth site (i.e. by soil application), or by drip application (often also referred to as "chemigation"), i.e. surface or subsurface drip lines near the plant with various amounts of water over a specific period, by liquid application of the compound of formula (I) according to the invention. In the case of rice crops, this can also be done by metering the compound of formula (I) in solid application form (e.g. as a granule) and supplying it to flooded paddy fields. This can be done by introducing the compound of formula (I) according to the invention in solid form (e.g. in granular form) into the plant growth site. Or by drip application (often also referred to as "chemigation"), i.e. with various amounts of water at a defined location near the plant, by liquid application of the compound of formula (I) according to the invention from surface or subsurface drip lines over a specific period. This can be done by impregnating a liquid form of the compound of formula (I), or by introducing the compound of formula (I) according to the invention in solid form (e.g. in granular form) into the plant growth site (i.e. by soil application), or by drip application (often also referred to as "chemigation"), i.e. with various amounts of water at a defined location near the plant, by liquid application of the compound of formula (I) according to the invention from surface or subsurface drip lines over a specific period. In the case of rice crops, this can also be done by metering the compound of formula (I) in solid application form (e.g. as a granule) and supplying it to flooded paddy fields. This can be done by introducing the compound of formula (I) according to the invention in solid form (e.g. in granular form) into the plant growth site. .

[0191] Digital technology The compounds of the invention can be used in combination with models embedded in computer programs for, for example, site-specific crop management, satellite farming, precision farming or precision agriculture. Such models use data from a variety of sources, such as soil, climate, crops (e.g. type, growth stage, plant health), weeds (e.g. species, growth stage), diseases, pests, nutrients, water, moisture, biomass, satellite data, yield, etc., with the aim of optimizing profitability, sustainability and environmental protection, to assist in site-specific management of agricultural sites. In particular, such models can help to optimize agricultural decisions, control the accuracy of pesticide application and record the work performed. This can be done by introducing the compound of formula (I) according to the invention in solid form (e.g. in granular form) into the plant growth site. Such models use data from a variety of sources, such as soil, climate, crops (e.g. type, growth stage, plant health), weeds (e.g. species, growth stage), diseases, pests, nutrients, water, moisture, biomass, satellite data, yield, etc., with the aim of optimizing profitability, sustainability and environmental protection, to assist in site-specific management of agricultural sites. In particular, such models can help to optimize agricultural decisions, control the accuracy of pesticide application and record the work performed. This can be done by introducing the compound of formula (I) according to the invention in solid form (e.g. in granular form) into the plant growth site. This can be done by introducing the compound of formula (I) according to the invention in solid form (e.g. in granular form) into the plant growth site. This can be done by introducing the compound of formula (I) according to the invention in solid form (e.g. in granular form) into the plant growth site. This can be done by introducing the compound of formula (I) according to the invention in solid form (e.g. in granular form) into the plant growth site. This can be done by introducing the compound of formula (I) according to the invention in solid form (e.g. in granular form) into the plant growth site.

[0192] As an example, the compounds of the invention can be applied to crop plants according to appropriate application methods when the model models the development of pests and calculates that a threshold has been reached at which application of the compound to the crop plants is recommended. This can be done by introducing the compound of formula (I) according to the invention in solid form (e.g. in granular form) into the plant growth site. This can be done by introducing the compound of formula (I) according to the invention in solid form (e.g. in granular form) into the plant growth site.

[0193] Commercially available systems that include agronomic models are, for example, FieldScriptsTM from The Climate Corporation, XarvioTM from BASF, AGLogicTM from John Deere, and the like. Commercially available systems that include agronomic models are, for example, FieldScriptsTM from The Climate Corporation, XarvioTM from BASF, AGLogicTM from John Deere, and the like. Commercially available systems that include agronomic models are, for example, FieldScriptsTM from The Climate Corporation, XarvioTM from BASF, AGLogicTM from John Deere, and the like.

[0194] The compounds of the present invention can also be used in combination with smart spray devices such as spot sprayers or precision sprayers attached to or housed within agricultural vehicles such as tractors, robots, helicopters, airplanes, and unmanned aerial vehicles (UAVs) such as drones. Such devices typically include an input sensor (e.g., a camera, etc.), and a processing unit configured to analyze the input data and provide a decision based on the analysis of the input data to apply the compounds of the present invention to crop plants (and each weed) in an individual and accurate manner. To use such a smart spray device, it is usually necessary to localize the recorded data, a positioning system (e.g., a GPS receiver) for guiding or controlling the agricultural vehicle; a geographic information system (GIS) for representing information on an understandable map, and an appropriate agricultural vehicle for performing necessary agricultural operations such as spraying. The compounds of the present invention can also be used in combination with smart spray devices such as spot sprayers or precision sprayers attached to or housed within agricultural vehicles such as tractors, robots, helicopters, airplanes, and unmanned aerial vehicles (UAVs) such as drones. Such devices typically include an input sensor (e.g., a camera, etc.), and a processing unit configured to analyze the input data and provide a decision based on the analysis of the input data to apply the compounds of the present invention to crop plants (and each weed) in an individual and accurate manner. To use such a smart spray device, it is usually necessary to localize the recorded data, a positioning system (e.g., a GPS receiver) for guiding or controlling the agricultural vehicle; a geographic information system (GIS) for representing information on an understandable map, and an appropriate agricultural vehicle for performing necessary agricultural operations such as spraying. The compounds of the present invention can also be used in combination with smart spray devices such as spot sprayers or precision sprayers attached to or housed within agricultural vehicles such as tractors, robots, helicopters, airplanes, and unmanned aerial vehicles (UAVs) such as drones. Such devices typically include an input sensor (e.g., a camera, etc.), and a processing unit configured to analyze the input data and provide a decision based on the analysis of the input data to apply the compounds of the present invention to crop plants (and each weed) in an individual and accurate manner. To use such a smart spray device, it is usually necessary to localize the recorded data, a positioning system (e.g., a GPS receiver) for guiding or controlling the agricultural vehicle; a geographic information system (GIS) for representing information on an understandable map, and an appropriate agricultural vehicle for performing necessary agricultural operations such as spraying. The compounds of the present invention can also be used in combination with smart spray devices such as spot sprayers or precision sprayers attached to or housed within agricultural vehicles such as tractors, robots, helicopters, airplanes, and unmanned aerial vehicles (UAVs) such as drones. Such devices typically include an input sensor (e.g., a camera, etc.), and a processing unit configured to analyze the input data and provide a decision based on the analysis of the input data to apply the compounds of the present invention to crop plants (and each weed) in an individual and accurate manner. To use such a smart spray device, it is usually necessary to localize the recorded data, a positioning system (e.g., a GPS receiver) for guiding or controlling the agricultural vehicle; a geographic information system (GIS) for representing information on an understandable map, and an appropriate agricultural vehicle for performing necessary agricultural operations such as spraying. The compounds of the present invention can also be used in combination with smart spray devices such as spot sprayers or precision sprayers attached to or housed within agricultural vehicles such as tractors, robots, helicopters, airplanes, and unmanned aerial vehicles (UAVs) such as drones. Such devices typically include an input sensor (e.g., a camera, etc.), and a processing unit configured to analyze the input data and provide a decision based on the analysis of the input data to apply the compounds of the present invention to crop plants (and each weed) in an individual and accurate manner. To use such a smart spray device, it is usually necessary to localize the recorded data, a positioning system (e.g., a GPS receiver) for guiding or controlling the agricultural vehicle; a geographic information system (GIS) for representing information on an understandable map, and an appropriate agricultural vehicle for performing necessary agricultural operations such as spraying. The compounds of the present invention can also be used in combination with smart spray devices such as spot sprayers or precision sprayers attached to or housed within agricultural vehicles such as tractors, robots, helicopters, airplanes, and unmanned aerial vehicles (UAVs) such as drones. Such devices typically include an input sensor (e.g., a camera, etc.), and a processing unit configured to analyze the input data and provide a decision based on the analysis of the input data to apply the compounds of the present invention to crop plants (and each weed) in an individual and accurate manner. To use such a smart spray device, it is usually necessary to localize the recorded data, a positioning system (e.g., a GPS receiver) for guiding or controlling the agricultural vehicle; a geographic information system (GIS) for representing information on an understandable map, and an appropriate agricultural vehicle for performing necessary agricultural operations such as spraying. The compounds of the present invention can also be used in combination with smart spray devices such as spot sprayers or precision sprayers attached to or housed within agricultural vehicles such as tractors, robots, helicopters, airplanes, and unmanned aerial vehicles (UAVs) such as drones. Such devices typically include an input sensor (e.g., a camera, etc.), and a processing unit configured to analyze the input data and provide a decision based on the analysis of the input data to apply the compounds of the present invention to crop plants (and each weed) in an individual and accurate manner. To use such a smart spray device, it is usually necessary to localize the recorded data, a positioning system (e.g., a GPS receiver) for guiding or controlling the agricultural vehicle; a geographic information system (GIS) for representing information on an understandable map, and an appropriate agricultural vehicle for performing necessary agricultural operations such as spraying. The compounds of the present invention can also be used in combination with smart spray devices such as spot sprayers or precision sprayers attached to or housed within agricultural vehicles such as tractors, robots, helicopters, airplanes, and unmanned aerial vehicles (UAVs) such as drones. Such devices typically include an input sensor (e.g., a camera, etc.), and a processing unit configured to analyze the input data and provide a decision based on the analysis of the input data to apply the compounds of the present invention to crop plants (and each weed) in an individual and accurate manner. To use such a smart spray device, it is usually necessary to localize the recorded data, a positioning system (e.g., a GPS receiver) for guiding or controlling the agricultural vehicle; a geographic information system (GIS) for representing information on an understandable map, and an appropriate agricultural vehicle for performing necessary agricultural operations such as spraying. The compounds of the present invention can also be used in combination with smart spray devices such as spot sprayers or precision sprayers attached to or housed within agricultural vehicles such as tractors, robots, helicopters, airplanes, and unmanned aerial vehicles (UAVs) such as drones. Such devices typically include an input sensor (e.g., a camera, etc.), and a processing unit configured to analyze the input data and provide a decision based on the analysis of the input data to apply the compounds of the present invention to crop plants (and each weed) in an individual and accurate manner. To use such a smart spray device, it is usually necessary to localize the recorded data, a positioning system (e.g., a GPS receiver) for guiding or controlling the agricultural vehicle; a geographic information system (GIS) for representing information on an understandable map, and an appropriate agricultural vehicle for performing necessary agricultural operations such as spraying. The compounds of the present invention can also be used in combination with smart spray devices such as spot sprayers or precision sprayers attached to or housed within agricultural vehicles such as tractors, robots, helicopters, airplanes, and unmanned aerial vehicles (UAVs) such as drones. Such devices typically include an input sensor (e.g., a camera, etc.), and a processing unit configured to analyze the input data and provide a decision based on the analysis of the input data to apply the compounds of the present invention to crop plants (and each weed) in an individual and accurate manner. To use such a smart spray device, it is usually necessary to localize the recorded data, a positioning system (e.g., a GPS receiver) for guiding or controlling the agricultural vehicle; a geographic information system (GIS) for representing information on an understandable map, and an appropriate agricultural vehicle for performing necessary agricultural operations such as spraying.

[0195] In one example, the disease organisms can be detected from the images obtained by the camera. In one example, the pests can be identified and / or classified based on the images. Such identification and / or classification can utilize image processing algorithms. Such image processing algorithms can utilize machine learning algorithms such as trained neutral networks, decision trees, and the like, and artificial intelligence algorithms can be utilized. In one example, the disease organisms can be detected from the images obtained by the camera. In one example, the pests can be identified and / or classified based on the images. Such identification and / or classification can utilize image processing algorithms. Such image processing algorithms can utilize machine learning algorithms such as trained neutral networks, decision trees, and the like, and artificial intelligence algorithms can be utilized. In one example, the disease organisms can be detected from the images obtained by the camera. In one example, the pests can be identified and / or classified based on the images. Such identification and / or classification can utilize image processing algorithms. Such image processing algorithms can utilize machine learning algorithms such as trained neutral networks, decision trees, and the like, and artificial intelligence algorithms can be utilized. In one example, the disease organisms can be detected from the images obtained by the camera. In one example, the pests can be identified and / or classified based on the images. Such identification and / or classification can utilize image processing algorithms. Such image processing algorithms can utilize machine learning algorithms such as trained neutral networks, decision trees, and the like, and artificial intelligence algorithms can be utilized. In one example, the disease organisms can be detected from the images obtained by the camera. In one example, the pests can be identified and / or classified based on the images. Such identification and / or classification can utilize image processing algorithms. Such image processing algorithms can utilize machine learning algorithms such as trained neutral networks, decision trees, and the like, and artificial intelligence algorithms can be utilized. Thus, the compounds described herein can be applied only when necessary.

[0196] Treatment of seeds The control of pests by treating the seeds of plants has long been known and has been continuously improved. However, the treatment of seeds is accompanied by a series of problems that cannot always be satisfactorily solved. Thus, during the storage of plants, after sowing or it is desirable to develop a method for protecting seeds and germinating plants that eliminates or at least significantly reduces the need for additional application of pesticides after germination. Furthermore, it is desirable to optimize the amount of active compound used such that the seeds and germinating plants are optimally protected from attack by pests without causing damage to the plants themselves by the active compounds used. In particular, in the method of treating seeds, the endogenous insecticidal or nematicidal properties of pest-resistant transgenic plants or pest-tolerant transgenic plants should also be taken into account in order to achieve optimal protection of the seeds and germinating plants using the minimum amount of pesticides. Accordingly, the present invention also relates to a method for protecting seeds and germinating plants from attack by phytopathogenic organisms, wherein the method comprises treating said seeds with one of the compounds of formula (I). The method of the present invention for protecting seeds and germinating plants from attack by phytopathogenic organisms further encompasses methods in which the seeds are treated simultaneously or sequentially in a single operation with a compound of formula (I) and a mixing component. It further encompasses methods in which the seeds are treated with a compound of formula (I) and a mixing component at different times.

[0197] Accordingly, the present invention particularly relates to a method for protecting seeds and germinating plants from attack by phytopathogenic organisms, wherein the method comprises treating the seeds with one of the compounds of formula (I). The method of the present invention for protecting seeds and germinating plants from attack by phytopathogenic organisms further encompasses methods in which the seeds are treated simultaneously or sequentially in a single operation with a compound of formula (I) and a mixing component. It further encompasses methods in which the seeds are treated with a compound of formula (I) and a mixing component at different times.

[0198] ​​​​​​​​ The present invention also relates to the use of a compound of formula (I) for treating seeds in order to protect the seeds and the plants resulting from said seeds against pests.

[0199] Furthermore, the present invention relates to seeds treated with a compound of formula (I) according to the invention so as to provide protection against pests. The present invention further relates to seeds treated simultaneously with a compound of formula (I) and a mixing component. The present invention further relates to seeds treated at different times with a compound of formula (I) and a mixing component. In the case of seeds treated at different times with a compound of formula (I) and a mixing component, the individual substances may be present in different layers on the surface of the seeds. Here, the layer containing the compound of formula (I) and the mixing component can optionally be separated by an intermediate layer. The present invention also further relates to seeds on which a compound of formula (I) and a mixing component are applied as components of a coating or as an additional one or more layers added to a coating.

[0200] The present invention further relates to seeds subjected to a film coating process in order to prevent abrasion of the seeds by dust after being treated with a compound of formula (I).

[0201] One of the advantages obtained with the systemic compound of formula (I) is that by treating the seeds, not only the seeds themselves but also the plants obtained from said seeds are protected against pests after germination. In this way, it is possible to save the effort of directly treating the crop at the time of sowing or shortly after sowing.

[0202] By treating the seeds with a compound of formula (I), the germination and emergence of the treated seeds are increased. ​​​​​​​​​​​​​Further advantages that can be advanced should be considered.

[0203] Similarly, it is considered advantageous that the compounds of formula (I) can be used, in particular, for transgenic seeds. is also considered advantageous.

[0204] Furthermore, the compounds of formula (I) can be used in combination with compositions or compounds of signal transduction technology, as a result of which colonization by symbiotic organisms (e.g., rhizobia, mycorrhizal fungi and / or endophytic bacteria or fungi) is improved and / or nitrogen fixation is optimized. The compounds of formula (I) are suitable for protecting the seeds of all plant varieties used in agriculture, in greenhouses, in forests or in horticulture. In particular, this takes the form of seeds of cereals (e.g., wheat, barley, rye, oats and millet), maize, cotton, soybeans, rice, potatoes, sunflowers, coffee, tobacco, canola, rapeseed, beet (e.g., sugar beet and fodder beet), peanuts, vegetables (e.g., tomatoes, cucumbers, green beans, brassica vegetables, onions and lettuce), fruit plants, lawns and ornamental plants. Treating the seeds of cereals (e.g., wheat, barley, rye and millet), maize, soybeans, cotton, canola, rapeseed, vegetables and rice is particularly important. is optimized.

[0205] As already described above, the treatment of transgenic seeds with the compounds of formula (I) is also particularly important. This is in the form of seeds of plants that basically contain at least one heterologous gene that controls the expression of a polypeptide having pesticidal properties and / or nematicidal properties.

[0206] As already described above, the treatment of transgenic seeds with the compounds of formula (I) is also particularly important. This is particularly important for seeds of plants that basically contain at least one heterologous gene that controls the expression of a polypeptide having pesticidal properties and / or nematicidal properties. Obtained. These foreign genes in transgenic seeds can be derived from microorganisms such as Bacillus species, Rhizobium species, Pseudomonas species, Serratia species, Trichoderma species, Clavibacter species, Glomus species or Gliocladium species. The present invention is particularly suitable for treating transgenic seeds containing at least one foreign gene derived from Bacillus species (Bacillus sp.). It is particularly preferably a foreign gene derived from Bacillus thuringiensis.

[0207] In connection with the present invention, the compound of formula (I) is applied to the seeds. Preferably, the seeds are treated in a sufficiently stable state to avoid damage during treatment. Generally, the seeds can be treated at any time between harvest and sowing. The seeds commonly used are separated from the plant and have the ear axis, husk, petiole, epicarp, hair or pulp removed. For example, harvested seeds that have been cleaned of impurities and dried to a moisture content that allows storage can be used. Alternatively, seeds treated with, for example, water after drying and then dried again (e.g., priming) can also be used. In the case of rice seeds, for example, seeds that are immersed in water up to a certain stage of the rice embryo (the "pigeon breast stage") to thereby stimulate germination and result in more uniform emergence can also be used.

[0208] When treating seeds, care must generally be taken to select the amount of the compound of formula (I) and / or the amount of further additives to be applied to the seeds such that the germination of the seeds is not adversely affected or the plants emerging from the seeds are not damaged. This must be ensured especially in the case of active compounds which may exhibit phytotoxic effects at certain application rates. In general, the compounds of formula (I) are applied to the seeds in a suitable formulation. Suitable formulations and processes for treating seeds are known to the person skilled in the art. The compounds of formula (I) can be converted into customary seed dressing formulations, such as solutions, emulsions, suspensions, powders, foams, slurries or other coating compositions for seeds, and can furthermore be converted into ULV formulations. These formulations are prepared in a known manner by mixing the compounds of formula (I) with customary additives, such as customary extenders, and solvents or diluents, colorants, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins etc., and furthermore by mixing with water.

[0209] Colorants which can be incorporated into the seed dressing formulations which can be used according to the invention are all colorants customary for such purposes. Pigments which are sparingly soluble in water or dyes which are soluble in water can be used. Examples thereof include colorants known under the names "Rhodamine B", "C.I.Pigment Red 112" and "C.I.Solvent Red 1". The suitable formulations and processes for treating seeds are known to those skilled in the art.

[0210] The compounds of formula (I) can be converted into customary seed dressing formulations, such as solutions, emulsions, suspensions, powders, foams, slurries or other coating compositions for seeds, and can furthermore be converted into ULV formulations. These formulations are prepared in a known manner by mixing the compounds of formula (I) with customary additives, such as customary extenders, and solvents or diluents, colorants, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins etc., and furthermore by mixing with water. The colorants which can be incorporated into the seed dressing formulations which can be used according to the invention are all colorants customary for such purposes. Pigments which are sparingly soluble in water or dyes which are soluble in water can be used. Examples thereof include colorants known under the names "Rhodamine B", "C.I.Pigment Red 112" and "C.I.Solvent Red 1".

[0211] These formulations are prepared in a known manner by mixing the compounds of formula (I) with customary additives, such as customary extenders, and solvents or diluents, colorants, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins etc., and furthermore by mixing with water. Colorants which can be incorporated into the seed dressing formulations which can be used according to the invention are all colorants customary for such purposes. Pigments which are sparingly soluble in water or dyes which are soluble in water can be used. Examples thereof include colorants known under the names "Rhodamine B", "C.I.Pigment Red 112" and "C.I.Solvent Red 1". These formulations are prepared in a known manner by mixing the compounds of formula (I) with customary additives, such as customary extenders, and solvents or diluents, colorants, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins etc., and furthermore by mixing with water. These formulations are prepared in a known manner by mixing the compounds of formula (I) with customary additives, such as customary extenders, and solvents or diluents, colorants, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins etc., and furthermore by mixing with water.

[0212] Colorants which can be incorporated into the seed dressing formulations which can be used according to the invention are all colorants customary for such purposes. Pigments which are sparingly soluble in water or dyes which are soluble in water can be used. Examples thereof include colorants known under the names "Rhodamine B", "C.I.Pigment Red 112" and "C.I.Solvent Red 1". Pigments which are sparingly soluble in water or dyes which are soluble in water can be used. Examples thereof include colorants known under the names "Rhodamine B", "C.I.Pigment Red 112" and "C.I.Solvent Red 1". n B", "C.I.Pigment Red 112" and "C.I.Solvent Red 1" and the like.

[0213] Useful wetting agents that can be incorporated into the seed coating formulations that can be used according to the present invention are all substances that promote wetting and are customarily used in formulations of pesticidal active compounds Preferably, alkylnaphthalenesulfonates, such as diisopropyl or diisobutylnaphthalenesulfonate, etc., are used

[0214] Useful dispersants and / or emulsifiers that can be incorporated into the seed coating formulations that can be used according to the present invention are all nonionic, anionic and cationic dispersants conventionally used in formulations of pesticidal active ingredients. Preferably, nonionic or anionic dispersants or mixtures of nonionic or anionic dispersants are used. Suitable nonionic dispersants include, in particular, ethylene oxide / propylene oxide block polymers, alkylphenol polyglycol ethers and tristyrylphenol polyglycol ethers, as well as their phosphorylated derivatives or sulfated derivatives, etc. Suitable anionic dispersants include, in particular, lignosulfonates, polyacrylates and aryl sulfonates / formaldehyde condensates

[0215] Defoamers that can be incorporated into the seed coating formulations that can be used according to the present invention are all foam-suppressing substances conventionally used in formulations of pesticidal active ingredients. Preferably, silicone defoamers and magnesium stearate are used

[0216] Preservatives that can be incorporated into the seed coating formulations that can be used according to the present invention are all substances that can be used for this purpose in pesticidal compositions. As an example​ Examples include dichlorophene and benzyl alcohol hemiformal.

[0217] Secondary agents that may be present in seed dressing formulations that may be used in accordance with the present invention include Thickeners are all substances that can be used for that purpose in pesticide compositions. Preferred are cellulose derivatives, acrylic acid derivatives, xanthan, modified clays and finely divided silica. .

[0218] Adhesives which may be present in seed dressing formulations which may be used according to the invention The binders are all customary binders which can be used in seed dressing products. , polyvinyl acetate, polyvinyl alcohol and tylose are preferred. can be done.

[0219] Gibberellin, which may be present in seed dressing formulations that can be used in accordance with the present invention. The gibberellins are preferably gibberellin A1, gibberellin A3 (=gibberellic acid), gibberellin A4 (=gibberellic acid), gibberellin B5 (=gibberellic acid), gibberellin C6 (=gibberellic acid), gibberellin B7 (=gibberellic acid), gibberellin B8 (=gibberellic acid), gibberellin A Gibberellin A4 and gibberellin A7 are preferred, with gibberellic acid being particularly preferred. The compounds are known (R. Wegler "Chemie der Pflanzens chutz- and Schadlingsbekampfungsmittel″ vol. 2, Springer Verlag, 1970, pp. 401-4 12).

[0220] Seed dressing formulations that can be used in accordance with the present invention are suitable for use on a wide variety of seeds. It can be used directly or after prior dilution with water to treat bacteria. For example, it can be prepared as a concentrate or diluted with water. The preparations obtainable from the concentrate formulation can be used to coat the seeds of cereals such as wheat, barley, rye, oats and triticale, and can also be used to coat the seeds of maize, rice, rapeseed, pea, bean, cotton, sunflower, soybean and beet, or can be used to coat the seeds of a wide range of different vegetables. The seed coating formulations or their diluted forms that can be used according to the invention can also be used to coat the seeds of transgenic plants. When treating seeds with the seed coating formulations that can be used according to the invention or with the forms prepared from such seed coating formulations by adding water, all the mixing devices customarily usable for seed coating are useful. Specifically, the procedure in seed coating is to place the seeds in a mixer operating batchwise or continuously, add the desired specific amount of the seed coating formulation either undiluted or after pre-dilution with water, and mix everything until the formulation is homogeneously distributed on the surface of the seeds. Where appropriate,

[0221] a subsequent drying step is carried out. The application rate of the seed coating formulations that can be used according to the invention can be varied within a relatively wide range. It depends on the specific content of the compound of formula (I) in the formulation and on the seeds. The application rate of the compound of formula (I) is generally from 0.001 to 50 g per kg of seeds, preferably from 0.01 to 15 g per kg of seeds.

[0222]

[0223] Animal health​​​​​​​ In the field of animal health, i.e. in the field of veterinary medicine, the compounds of formula (I) are active against animal parasites , in particular against ectoparasites or endoparasites. The term "endoparasite" in particular includes helminths and protozoa (e.g. coccidia). Ecto parasites are typically and preferably arthropods, in particular insects or mites .

[0224] In the field of veterinary medicine, the compounds of formula (I) have a favorable toxicity profile in warm-blooded animals and are suitable for controlling parasites occurring in livestock animals, breeding animals, zoo animals, laboratory animals, experimental animals and domestic animals in animal breeding and livestock farming.

[0225] Examples of agricultural livestock include mammals such as sheep, goats, horses, donkeys, camels, pigs, rabbits, reindeer, roe deer, and in particular cattle and pigs; or poultry , such as turkeys, ducks, geese, and in particular chickens; or fish or crustacean animals, such as fish and crustacean animals in aquaculture; or optionally insects such as bees, etc.

[0226] Examples of domestic animals include mammals such as hamsters, mice, rats, mice, chinchillas, ferrets, or in particular dogs, cats, cage birds, reptiles, amphibians, or aquarium fish, etc.

[0227] According to certain embodiments, the compounds of formula (I) are administered to mammals.

[0228] According to another specific embodiment, the compound of formula (I) is administered to birds, i.e., caged birds, or in particular, to poultry.

[0229] By using the compound of formula (I) to control animal parasites, diseases, mortality events and productivity losses (in the case of meat, milk, wool, leather, eggs, honey, etc.) are intended to be reduced or prevented, resulting in a more economical and simpler livestock industry and a better animal health condition can be achieved.

[0230] As used herein in the field of animal health, the term "control" or "controlling" means that the compound of formula (I) is effective in reducing the occurrence of individual parasites in animals infected with the parasite to a non-harmful level. More specifically, as used herein "control" means that the compound of formula (I) is effective in killing individual parasites, inhibiting their growth or inhibiting their proliferation.

[0231] Examples of arthropods include, but are not limited to, the following.

[0232] Of the order Anoplurida, for example, species of the genus Haematopinus, species of the genus Linognathus, species of the genus Pediculus, species of the genus Phtirus and species of the genus Solenopotes; Of the order Mallophagida and the suborder Ambly such as Bovicola spp., Damalina spp., Felicola spp. of the suborders Amblycerina and Ischnocerina ; Lepikentron spp., Menopon spp., Trichodectes spp., Trimenopon spp., Trinoton spp., Werneckiella spp. ; of the suborders Nematocerina and Brachycerina of the order Diptera, such as Aedes spp., Anopheles spp., Atylotus spp., Braula spp., Calliphora spp., Chrysomyia spp., Chrysops spp., Culex spp., Culicoides spp., Eusimulium spp., Fannia spp., Gasterophilus spp., Glossina spp., Haematobia spp., Haematopota spp., Hippobosca spp., Hybomitra spp., Hydrota ​​​​​​​​​​​​​​​​Species of Hydrotaea, Hypoderma s pp., Lipoptena spp., Lucilia spp., Luci lia spp., Lutzomyia spp., Melophagus spp., Morellia spp ., Musca spp., Odagmia spp ., Oestrus spp., Phil ipomyia spp., Phlebotomus spp , Rhinoestrus spp., Sarcophaga spp ., Simulium spp., Stomoxys spp., Tabanus spp (), Tipula spp., Wilhelmia spp., Wohlfahrtia spp; Of the order Siphonapterida, for example, Cera tophyllus spp., Ctenocephali des spp., Pulex spp., Tunga spp., Xenopsylla spp; Of the order Heteropterida, for example, Cim ex spp., Panstrongylus spp , Rhodnius spp., Triatoma spp.); and harmful and sanitary pests of the order Blattarida.

[0233] Furthermore, among the arthropods, but not limited to, the following mites can be mentioned as examples can be.

[0234] of the subclass Acari (Acarina) and the order Metastig mata), for example, of the family Argasidae, for example, species of the genus Argas Argas spp.), species of the genus Ornithodorus (Ornithodorus spp.) , species of the genus Otobius (Otobius spp.), of the family Ixodidae, for example species of the genus Amblyomma (Amblyomma spp.), species of the genus Dermacentor (D ermacentor spp.), species of the genus Haemaphysalis (Haemaphysali s spp.), species of the genus Hyalomma (Hyalomma spp.), species of the genus Ixodes (I xodes spp.), Rhipicephalus (Boophilus) spp., species of the genus Rhipiceph alus (Rhipicephalus spp. (original genus of multi-host mites)); of the order Mesostigmata (mesostigmat a), for example, species of the genus Dermanyssus (Dermanyssus spp.), Ornithonyssus species (Ornithonyssus spp.), Pneumonyssus species (Pneum onyssus spp.), Raillietia species (Raillietia spp.), Sternostoma species (Sternostoma spp.), Tropilaelaps species (T ropilaelaps spp.), Varroa species (Varroa spp.); Acti ropilaelaps spp.), Varroa species (Varroa spp.); Acti Actinedida (Prostigmata) of mites, such as Acarapis species (Acarapis spp.), Cheyletiella species (Cheyletiella spp.), Demodex species (Demodex spp.), Listrophorus species (Li strophorus spp.), Myobia species (Myobia spp.), Neot rombicula species (Neotrombicula spp.), Ornithocheyletiella species ( Ornithocheyletia spp.), Psorergates species (Psorerg ates spp.), Trombicula species (Trombicula spp.; and, A caridida (Astigmata) of mites, such as Acarus species ( Acarus spp.), Caloglyphus species (Caloglyphus spp.), Chorioptes species (Chorioptes spp.), Cytodites species (Cytodi tes spp.), Hypodectes species (Hypodectes spp.), Knemido coptes species (Knemidocoptes spp.), Laminosioptes species (La minosioptes spp.), Notoedres species (Notoedres spp .), Otodectes species (Otodectes spp.), Psoroptes species (Pso roptes spp.), Pterolichus species (Pterolichus spp.), Sarcoptes species (Sarcoptes spp.), Trixacarus species (Trixa carus spp.), Tyrophagus species (Tyrophagus spp.).

[0235] Examples of parasitic protozoa include, but are not limited to, the following, among others.

[0236] The subclass Mastigophora (Flagellata), for example: For example: Metamonada: Diplomonadida a) For example, Giardia spp., Spironucleus spp.; (Spironucleus spp.); Parabasala: Trichomonadida a) For example, Histomonas spp., Pentatrichomonas spp., Tetratrichomonas spp., Trichomonas spp., Tritrichomonas spp; (Tetratrichomonas spp.), Trichomonas spp., Tritrichomonas spp onas spp.), Tritrichomonas spp ); Euglenozoa: Trypanosomatida a) For example, Leishmania spp., Trypanosoma spp.; (Trypanosoma spp.); The subclass Sarcomastigophora (Rhizopoda), for example, the family Entamoebidae, for example, Entamoeba spp., the family Centramoebidae, for example, Acanthamoeba sp., the family Euamoebidae, for example, Hartmannella sp.; da)), for example, the family Entamoebidae, for example, Entamoeba spp., the family Centramoebidae ebidae), for example, Entamoeba spp., the family Centramoebidae ebidae), for example, Acanthamoeba sp., the family Euamoebidae, for example, Hartmannella sp.); (Hartmannella sp.); Alveolata, for example, the phylum Apicomplexa ​mplexa) (Sporozoa), for example, species of the genus Cryptosporidium (Cryptosporidium spp.); of the order Eimeriida such as, for example, species of the genus Besnoitia, species of the genus Cystoisospora (Cystoisospora spp.), species of the genus Eimeria (Eimeria sp p.), species of the genus Hammondia (Hammondia spp.), species of the genus Isospora (Isos pora spp.), species of the genus Neospora (Neospora spp.), species of the genus Sarcocystis (Sarcocystis spp.), species of the genus Toxoplasma (Toxoplas ma spp.); of the order Adeleida, such as, for example, species of the genus Hepatozoon (Hepatozoon spp.), species of the genus Klossiella (Klossiella spp. ); of the order Haemosporida, such as, for example, species of the genus Leucocytozoon (Leucocytozoon spp.), species of the genus Plasmodium (Plasmodiu m spp.); of the order Piroplasmida, such as, for example, species of the genus Babesia (Babesia spp.), species of the genus Ciliophora (Ciliophora spp. ), species of the genus Echinozoon (Echinozoon spp.), species of the genus Theileria (Thei leria spp.); of the order Vesibuliferida, for exam ple, species of the genus Balantidium (Balantidium spp.), species of the genus Buxtonella (Buxtonella spp.); Microspora, for example, species of the genus Encephalitozoon (Enc ephalitozoon spp.), species of the genus Enterocytozoon (Enterocyt ozoon spp.), Globidium spp., Nosema spp., and further, for example, Myxozoa spp. Worms pathogenic to humans or animals include, for example, Acanthocephala, Nematodes, Pentastomida, and Platyhelminthes [e.g., Monogenea, Cestodes, and Trematodes].

[0237] Examples of worms include, but are not limited to, the following. Monogenea: For example: Dactylogyrus spp., Gyrodactylus spp., Microbothrium spp., Polystoma spp., Troglocephalus spp. Cestodes: Of the order Pseudophyllidea, for example, Bothridium spp., Diphyllobothrium spp., Diplogonoporus spp., Ichthyobothrium spp., Ligula spp., Schistocephalus spp., Spirometra spp.

[0238]

[0239] Monogenea: For example: Dactylogyrus spp. Gyrodactylus spp., Microbothrium spp., Polystoma spp., Troglocephalus spp. spp.); Cestodes: Of the order Pseudophyllidea for example, Bothridium spp., Diphyllobothrium spp., Diplogonoporus spp., Ichthyobothrium spp., Ligula spp., Schistocephalus spp., Spirometra spp. ometra spp.); from the order Cyclophyllida, for example: species of the genus Andyra ( Andyra spp.), species of the genus Anoplocephala (Anoplocephala sp p.), species of the genus Avitellina (Avitellina spp.), species of the genus Bertiella (Ber tiella spp.), species of the genus Cittotaenia (Cittotaenia spp.), species of the genus Davainea (Davainea spp.), species of the genus Diorchis (Diorchis spp.), species of the genus Diplopylidium (Diplopylidium spp.), Dipyli dium spp.), species of the genus Echinococcus (Echinoc occus spp.), species of the genus Echinocotyle (Echinocotyle spp.), species of the genus Echinolepis (Echinolepis spp.), species of the genus Hydat igera (Hydatigera spp.), species of the genus Hymenolepis (Hymenolepis spp.), Di species of the genus Joyeuxiella (Joyeuxiella spp.), species of the genus Mesocestoides ( Mesocestoides spp.), species of the genus Moniezia (Moniezia spp .), species of the genus Paranoplocephala (Paranoplocephala spp.), Raillie tina spp.), species of the genus Stilesia (Stilesi a spp.), species of the genus Taenia (Taenia spp.), species of the genus Thysaniezia (Thy saniezia spp.), species of the genus Thysanosoma (Thysanosoma spp.) ; Trematodes: from the subclass Digenea, for example: Austro bilharzia spp.), species of the genus Brachylaima (Brachylaima spp.), Calicophoron spp., Catatropis spp., Clonorchis spp., Collyriclum spp., Cotylophoron spp., Cyclocoelum spp., Dicrocoelium spp., Diplostomum spp., Echinochasmus spp., Echinoparyphium spp., Echinostoma spp., Eurytrema spp., Fasciola spp., Fascioloides spp., Fasciolopsis spp., Fischoederius spp., Gastrothylacus spp., Gigantobilharzia spp., Gigantocotyle spp., Heterophyes spp., Hypoderaeum spp., Leucochloridium spp., Metagonimus spp., Metorchis spp., Nanophyetus spp., Notocotylus sp ​​​​​​​​​​​​​​​​​ p.), Opisthorchis spp., Ornithobilharzia spp., Paragonimus spp., Paramphistomum spp., Plagiorchis spp., Posthodiplostomum spp., Prosthogonimus spp., Schistosoma spp., Trichobilharzia spp., Troglotrema spp., Typhlocoelum spp.); Nematodes: of the order Trichinellida, for example: Capillaria spp., Eucoleus spp., Paracapillaria spp., Trichinella spp., Trichomosoides spp., Trichuris spp.); Of the order Tylenchida, for example: Micronema spp., Parastrongyloides spp., Strongyloides spp.); Of the order Rhabditina, for example: Aelurostrongylus spp.) Of the order Rhabditina, for example: Micronema spp., Parastrongyloides spp., Strongyloides spp.) ; Of the order Rhabditina, for example: (Aelurostrongylus spp.), Amidostomum spp., Ancylostoma spp., Angiostrongylus spp., Bronchonema spp., Bunostomum spp., Chabertia spp., Cooperia spp., Cooperioides spp., Crenosoma spp., Cyathostomum spp., Cyclococercus spp., Cyclodontostomum spp., Cyclicocyclus spp., Cylicostephanus spp., Cylindropharynx spp., Cystocaulus spp., Dictyocaulus sp., Elaphostrongylus spp., Filaroides spp., Globocephalus spp., Graphidium spp., Gyalocephalus spp., Haemonchus spp., Heligmosomoides spp., Hyostrongylus spp., ​​​​​​​​​​ spp.), Marshallagia spp., Metas trongylus spp., Muellerius spp., Necator spp., Nemat odirus spp., Neostrongylus spp., Nippostrong ylus spp., Obeliscoides spp., Oesophagodontus spp., Oesoph agostomum spp., Ollulanus spp.; Ornithostrongylus spp., Oslerus spp., Ostertagia spp., Paracooperia spp., Paracrenosoma spp., Parafilaroides spp., Parelaphostrongylus spp., Pneumocaulus spp., Pneumostrongylus spp., Poteriostomum spp., Protostrongylus spp., Spicocaulus spp., Stephanurus spp. ylus spp.), Obeliscoides spp. agus spp.), Oesophagodontus spp.), Oesoph agus spp.), Oesophagostomum spp.), Orlanus spp.), O llulanus spp.), Ornithostrongylus spp.), Oslerus spp.), Oslerus spp.), Ostertagia spp.), Paracooperia spp.), Paracrenosoma spp.), Parafilaroides spp.), Parelaphostrongylus spp.), Pneumocaulus spp.), Pneumostrongylus spp.), Poteriostomum spp.), Protostrongylus spp.), Spicocaulus spp.), Stephanurus spp. ngylus spp.), Oslerus spp.), Ostertagia spp.), Paracooperia spp.), Paracrenosoma spp.), Parafilaroides spp.), Parelaphostrongylus spp.), Pneumocaulus spp.), Pneumostrongylus spp.), Poteriostomum spp.), Protostrongylus spp.), Spicocaulus spp.), Stephanurus spp. agus spp.), Ostertagia spp.), Paracooperia spp.), Paracrenosoma spp.), Parafilaroides spp.), Parelaphostrongylus spp.), Pneumocaulus spp.), Pneumostrongylus spp.), Poteriostomum spp.), Protostrongylus spp.), Spicocaulus spp.), Stephanurus spp. eria spp.), Paracrenosoma spp.), Parafilaroides spp.), Parelaphostrongylus spp.), Pneumocaulus spp.), Pneumostrongylus spp.), Poteriostomum spp.), Protostrongylus spp.), Spicocaulus spp.), Stephanurus spp. agus spp.), Paracrenosoma spp.), Parafilaroides spp.), Parelaphostrongylus spp.), Pneumocaulus spp.), Pneumostrongylus spp.), Poteriostomum spp.), Protostrongylus spp.), Spicocaulus spp.), Stephanurus spp. agus spp.), Parafilaroides spp.), Parelaphostrongylus spp.), Pneumocaulus spp.), Pneumostrongylus spp.), Poteriostomum spp.), Protostrongylus spp.), Spicocaulus spp.), Stephanurus spp. agus spp.), Pneumocaulus spp.), Pneumostrongylus spp.), Poteriostomum spp.), Protostrongylus spp.), Spicocaulus spp.), Stephanurus spp. agus spp.), Poteriostomum spp.), Protostrongylus spp.), Spicocaulus spp.), Stephanurus spp. agus spp.), Protostrongylus spp.), Spicocaulus spp.), Stephanurus spp. agus spp.), Spicocaulus spp.), Stephanurus spp. Species of Stephanurus, Strongylus, Syngamus, Teladorsagia, Trichonema, Trichostrongylus, Triodontophorus, Troglostrongylus, Uncinaria; Species of Spirurida, such as: Acantocheilonema spp., Anisakis spp., Ascaridia spp.; Ascaris spp., Ascarops spp., Aspiculuris spp., Baylisascaris spp., Brugia spp., Cercopithifilaria spp., Crassicauda spp., Dipetalonema spp., Dirofilaria spp., Dracunculus spp.; Draschia spp., Enterobius spp., Filaria spp., Gnathostoma spp Species of Spirurida, such as: Acantocheilonema spp., Anisakis spp., Ascaridia spp.; Ascaris spp., Ascarops spp., Aspiculuris spp., Baylisascaris spp., Brugia spp., Cercopithifilaria spp., Crassicauda spp., Dipetalonema spp., Dirofilaria spp., Dracunculus spp.; Draschia spp., Enterobius spp., Filaria spp., Gnathostoma spp Species of Spirurida, such as: Acantocheilonema spp., Anisakis spp., Ascaridia spp.; Ascaris spp., Ascarops spp., Aspiculuris spp., Baylisascaris spp., Brugia spp., Cercopithifilaria spp., Crassicauda spp., Dipetalonema spp., Dirofilaria spp., Dracunculus spp.; Draschia spp., Enterobius spp., Filaria spp., Gnathostoma spp .), Triodontophorus spp., Troglostrongylus spp., Uncinaria spp.; Species of Spirurida, such as: Acantocheilonema spp., Anisakis spp., Ascaridia spp.; Ascaris spp., Ascarops spp., Aspiculuris spp., Baylisascaris spp., Brugia spp., Cercopithifilaria spp., Crassicauda spp., Dipetalonema spp., Dirofilaria spp., Dracunculus spp.; Draschia spp., Enterobius spp., Filaria spp., Gnathostoma spp Species of Spirurida, such as: Acantocheilonema spp., Anisakis spp., Ascaridia spp.; Ascaris spp., Ascarops spp., Aspiculuris spp., Baylisascaris spp., Brugia spp., Cercopithifilaria spp., Crassicauda spp., Dipetalonema spp., Dirofilaria spp., Dracunculus spp.; Draschia spp., Enterobius spp., Filaria spp., Gnathostoma spp Species of Spirurida, such as: Acantocheilonema spp., Anisakis spp., Ascaridia spp.; Ascaris spp., Ascarops spp., Aspiculuris spp., Baylisascaris spp., Brugia spp., Cercopithifilaria spp., Crassicauda spp., Dipetalonema spp., Dirofilaria spp., Dracunculus spp.; Draschia spp., Enterobius spp., Filaria spp., Gnathostoma spp Species of Spirurida, such as: Acantocheilonema spp., Anisakis spp., Ascaridia spp.; Ascaris spp., Ascarops spp., Aspiculuris spp., Baylisascaris spp., Brugia spp., Cercopithifilaria spp., Crassicauda spp., Dipetalonema spp., Dirofilaria spp., Dracunculus spp.; Draschia spp., Enterobius spp., Filaria spp., Gnathostoma spp Species of Spirurida, such as: Acantocheilonema spp., Anisakis spp., Ascaridia spp.; Ascaris spp., Ascarops spp., Aspiculuris spp., Baylisascaris spp., Brugia spp., Cercopithifilaria spp., Crassicauda spp., Dipetalonema spp., Dirofilaria spp., Dracunculus spp.; Draschia spp., Enterobius spp., Filaria spp., Gnathostoma spp Species of Spirurida, such as: Acantocheilonema spp., Anisakis spp., Ascaridia spp.; Ascaris spp., Ascarops spp., Aspiculuris spp., Baylisascaris spp., Brugia spp., Cercopithifilaria spp., Crassicauda spp., Dipetalonema spp., Dirofilaria spp., Dracunculus spp.; Draschia spp., Enterobius spp., Filaria spp., Gnathostoma spp Species of Spirurida, such as: Acantocheilonema spp., Anisakis spp., Ascaridia spp.; Ascaris spp., Ascarops spp., Aspiculuris spp., Baylisascaris spp., Brugia spp., Cercopithifilaria spp., Crassicauda spp., Dipetalonema spp., Dirofilaria spp., Dracunculus spp.; Draschia spp., Enterobius spp., Filaria spp., Gnathostoma spp Species of Spirurida, such as: Acantocheilonema spp., Anisakis spp., Ascaridia spp.; Ascaris spp., Ascarops spp., Aspiculuris spp., Baylisascaris spp., Brugia spp., Cercopithifilaria spp., Crassicauda spp., Dipetalonema spp., Dirofilaria spp., Dracunculus spp.; Draschia spp., Enterobius spp., Filaria spp., Gnathostoma spp Species of Spirurida, such as: Acantocheilonema spp., Anisakis spp., Ascaridia spp.; Ascaris spp., Ascarops spp., Aspiculuris spp., Baylisascaris spp., Brugia spp., Cercopithifilaria spp., Crassicauda spp., Dipetalonema spp., Dirofilaria spp., Dracunculus spp.; Draschia spp., Enterobius spp., Filaria spp., Gnathostoma spp Species of Spirurida, such as: Acantocheilonema spp., Anisakis spp., Ascaridia spp.; Ascaris spp., Ascarops spp., Aspiculuris spp., Baylisascaris spp., Brugia spp., Cercopithifilaria spp., Crassicauda spp., Dipetalonema spp., Dirofilaria spp., Dracunculus spp.; Draschia spp., Enterobius spp., Filaria spp., Gnathostoma spp Species of Spirurida, such as: Acantocheilonema spp., Anisakis spp., Ascaridia spp.; Ascaris spp., Ascarops spp., Aspiculuris spp., Baylisascaris spp., Brugia spp., Cercopithifilaria spp., Crassicauda spp., Dipetalonema spp., Dirofilaria spp., Dracunculus spp.; Draschia spp., Enterobius spp., Filaria spp., Gnathostoma spp Species of Spirurida, such as: Acantocheilonema spp., Anisakis spp., Ascaridia spp.; Ascaris spp., Ascarops spp., Aspiculuris spp., Baylisascaris spp., Brugia spp., Cercopithifilaria spp., Crassicauda spp., Dipetalonema spp., Dirofilaria spp., Dracunculus spp.; Draschia spp., Enterobius spp., Filaria spp., Gnathostoma spp Species of Spirurida, such as: Acantocheilonema spp., Anisakis spp., Ascaridia spp.; Ascaris spp., Ascarops spp., Aspiculuris spp., Baylisascaris spp., Brugia spp., Cercopithifilaria spp., Crassicauda spp., Dipetalonema spp., Dirofilaria spp., Dracunculus spp.; Draschia spp., Enterobius spp., Filaria spp., Gnathostoma spp Species of Spirurida, such as: Acantocheilonema spp., Anisakis spp., Ascaridia spp.; Ascaris spp., Ascarops spp., Aspiculuris spp., Baylisascaris spp., Brugia spp., Cercopithifilaria spp., Crassicauda spp., Dipetalonema spp., Dirofilaria spp., Dracunculus spp.; Draschia spp., Enterobius spp., Filaria spp., Gnathostoma spp .), Gongylonema spp., Habronema spp., Heterakis spp.; Litomosoides spp., Loa spp., Onchocerca spp., Oxyuris spp., Parabronema spp., Parafilaria spp., Parasaris spp., Passalurus spp., Physaloptera spp., Prostmayria spp., Pseudofilaria spp., Setaria spp., Skjrabinema spp., Spirocerca spp., Stephanofilaria spp., Strongyluris spp., Syphacia spp., Thelazia spp., Toxascaris spp., Toxocara spp.), Wuchereria spp.; bronema spp.), Heterakis spp.); Lito mosoides spp.), Loa spp. ), Onchocerca spp.), Oxyuris spp.), Parabronema spp.), Para filaria spp.), Paras caris spp.), Paras caris spp.), Passalurus spp.), Physa loptera spp.), Prost obstmayria spp.), Pseudofilar ia spp.), Setaria spp.), Skjrabinema spp. (Skjrabinema spp.), Spirocerca s pp.), Stephanofilaria spp.), Strongyluris spp.), Syph acia spp.), Thelazia spp.), Toxascaris spp.), Toxocara spp .), Wuchereria spp.); Acanthocephala: Oligacanthorhynchida of, for example: Macracanthorhynchus spp., Prosthenorchis spp., nthorhynchida), for example: Macracantha nthorhynchus spp.), Prosthenor Chiidae spp.); Moniliformida of the For example: Moniliformis spp.); Of Polymorphida, for example: Fil icollis spp.); Of Echinorhynchida , for example, Acanthocephalus spp., E chinorhynchus spp., Leptorhynchoides spp.); Pentastomida: Porocephalida a), for example, Linguatula spp.).

[0240] In the field of veterinary medicine and in the livestock industry, the administration of the compounds of formula (I) is by methods generally known in the art, for example, in the form of suitable preparations, enterally, parenterally, trans dermally or nasally. Administration can be carried out prophylactically, metaphylactically ) or therapeutically.

[0241] Accordingly, one embodiment of the present invention refers to the compounds of formula (I) for use as a drug .

[0242] Another aspect refers to the compounds of formula (I) for use as an anti-endoparasitic agent.

[0243] Another specific aspect refers to the compounds of formula (I) for use as an anthelmintic, in particular as a nematicide, a flatwormicide , a hookwormicide, or a pentastomidicide.

[0244] Another specific embodiment refers to a compound of formula (I) for use as an antiprotozoal agent.

[0245] Another embodiment refers to a compound of formula (I) for use as an anti-external parasite agent, particularly an acaricide, more specifically an insecticide or a miticide. Another embodiment refers to a compound of formula (I) for use as an anti-external parasite agent, particularly an acaricide, more specifically an insecticide or a miticide.

[0246] A further embodiment of the present invention is an animal pharmaceutical preparation comprising an effective amount of at least one compound of formula (I) and the following: a pharmaceutically acceptable excipient (e.g., a solid diluent or a liquid diluent), a pharmaceutically acceptable adjuvant (e.g., a surfactant), in particular a pharmaceutically acceptable excipient, and / or at least one of the pharmaceutically acceptable adjuvants commonly used in animal pharmaceutical preparations. An animal pharmaceutical preparation comprising an effective amount of at least one compound of formula (I) and the following:

[0247] A related embodiment of the present invention is a method for producing an animal pharmaceutical preparation described herein, comprising mixing at least one compound of formula (I) with a pharmaceutically acceptable excipient and / or adjuvant, in particular a pharmaceutically acceptable excipient, and / or an adjuvant commonly used in animal pharmaceutical preparations. A related embodiment of the present invention is a method for producing an animal pharmaceutical preparation described herein, comprising mixing at least one compound of formula (I) with a pharmaceutically acceptable excipient and / or adjuvant, in particular a pharmaceutically acceptable excipient, and / or an adjuvant commonly used in animal pharmaceutical preparations.

[0248] Another specific embodiment of the present invention is an animal pharmaceutical preparation selected from the group of anti-external parasite pharmaceutical preparations and anti-internal parasite pharmaceutical preparations according to the above embodiments, specifically, an anthelmintic pharmaceutical preparation, an antiprotozoal pharmaceutical preparation, and an acaricidal pharmaceutical preparation, more specifically, an animal pharmaceutical preparation selected from the group of nematocidal pharmaceutical preparations, cestocidal pharmaceutical preparations, acanthocephalicidal pharmaceutical preparations, linguatulicidal pharmaceutical preparations, insecticidal pharmaceutical preparations, and acaricidal pharmaceutical preparations, and methods for producing the same. Another specific embodiment of the present invention is an animal pharmaceutical preparation selected from the group of anti-external parasite pharmaceutical preparations and anti-internal parasite pharmaceutical preparations according to the above embodiments, specifically, an anthelmintic pharmaceutical preparation, an antiprotozoal pharmaceutical preparation, and an

[0249] Another embodiment is a parasitic infection, particularly an external parasite and an internal parasite A method for treating an infection caused by a parasite selected from the group of organisms, comprising applying an effective amount of a compound of formula (I) in an animal, particularly a non-human animal, in need of such treatment. This refers to a method by which. Another aspect refers to a method for treating an infection caused by a parasite selected from the group of ectoparasites and endoparasites described above, particularly an infection caused by a parasite, comprising applying an animal pharmaceutical preparation as defined herein in an animal, particularly a non-human animal, in need of such treatment.

[0250] Another aspect refers to the use of a compound of formula (I) in the treatment of a parasitic infection in an animal (particularly a non-human animal), particularly an infection caused by a parasite selected from the group of ectoparasites and endoparasites described above. In the animal health or veterinary medicine field, the term "treatment" encompasses prophylactic treatment, post-infection defensive treatment, or therapeutic treatment. In certain embodiments, a mixture of at least one compound of formula (I) and another active compound, particularly an endoparasiticide and an ectoparasiticide, is provided in the field of veterinary medicine. In the field of animal health, "mixture" not only means that two (or more) different active ingredients are formulated into a joint preparation and thereby applied together, but also refers to a product containing separate preparations for each active compound. Thus, when using more than two active compounds, all active compounds can be formulated jointly.

[0251] In relation to the field of animal health or veterinary medicine, the term "treatment" includes prophylactic treatment, post-infection defensive treatment, or therapeutic treatment. In the treatment of a parasitic infection in an animal (particularly a non-human animal), particularly an infection caused by a parasite selected from the group of ectoparasites and endoparasites described above. This refers to the use of a compound of formula (I).

[0252] In the field of animal health or veterinary medicine, the term "treatment" encompasses prophylactic treatment, post-infection defensive treatment, or therapeutic treatment. This includes preventive treatment, post-infection defensive treatment, or therapeutic treatment.

[0253] In certain embodiments, a mixture of at least one compound of formula (I) and another active compound, particularly an endoparasiticide and an ectoparasiticide, is provided in the field of veterinary medicine. This provides a mixture of at least one compound of formula (I) and another active compound, particularly an endoparasiticide and an ectoparasiticide. In the field of animal health, "mixture" not only means that two (or more) different active ingredients are formulated into a joint preparation and thereby applied together, but also refers to a product containing separate preparations for each active compound. Thus, when using more than two active compounds, all active compounds can be formulated jointly.

[0254] In the field of animal health, "mixture" not only means that two (or more) different active ingredients are formulated into a joint preparation and thereby applied together, but also refers to a product containing separate preparations for each active compound. This means that they are formulated into a joint preparation and applied together, but also refers to a product that includes separate preparations for each active compound. Therefore, when using more than two active compounds, all active compounds can be formulated jointly. Can it be formulated into a dosage form, or is it possible to formulate all the active compounds into separate dosage forms? Furthermore, a mixed form is also possible, where some of the active compounds are formulated together and some are formulated separately. In separate dosage forms, the plurality of active compounds can be administered separately or continuously.

[0255] The active compounds identified by the "generic name" in this specification are known and can be found, for example, in the "Pesticide Manual" (see above) or can be searched for on the Internet (e.g., " "). http: / / www.alan wood.net / pesticides

[0256] Exemplary active ingredients selected from the group of ectoparasiticides as mixing partners include insecticides and acaricides, etc., which are described in detail above, but are not limited thereto. For additional active ingredients that can be used, based on the current "IRAC Mode of Action Classification Scheme" and according to the above classification, they are listed below: (1) acetylcholinesterase (AChE) inhibitors; (2) GABA-dependent chloride channel blockers; (3) sodium channel regulators; (4) nicotinic acetylcholine receptor (nAChR) competitive regulators; (5) nicotinic acetylcholine receptor (nAChR) allosteric regulators; (6) glutamate-dependent chloride channel (GluCl) allosteric regulators; (7) juvenile hormone mimics; (8) various non-specific (multi-site) inhibitors; (9) chordotonal organ regulators; (1 ); (2) GABA-dependent chloride channel blockers; (3) sodium channel regulators; (4) nicotinic acetylcholine receptor (nAChR) competitive regulators; (5) nicotinic acetylcholine receptor (nAChR) allosteric regulators; (6) glutamate dependent chloride channel (GluCl) allosteric regulators; (7) juvenile hormone mimics; (8) various non-specific (multi-site) inhibitors; (9) chordotonal organ regulators; (1 0) Mite growth inhibitor; (12) Inhibitor of mitochondrial ATP synthase, e.g., ATP disruptor; (13) Uncoupler of oxidative phosphorylation by disrupting the proton gradient Agent; (14) Nicotinic acetylcholine receptor channel blocker; (15) Inhibitor of chitin biosynthesis (type 0); Inhibitor of chitin biosynthesis (type 1); (17) Molting Disruptor (especially in Diptera, i.e., flies); (18) Ecdysone receptor agonist ; (19) Octopamine receptor agonist; (21) Inhibitor of mitochondrial complex I electron transport ; (25) Inhibitor of mitochondrial complex II electron transport; (20) Mitochondrial complex I II electron transport inhibitor; (22) Voltage-dependent sodium channel blocker; (23) Acetyl CoA carboxylase inhibitor; (28) Ryanodine receptor modulator; (30) GAB A-dependent chloride channel allosteric regulator.

[0257] Active compounds with unknown or non-specific mechanism of action, e.g., fentrifanil, f enoxacrim, cycloprene, chlorobenzilate, chlorodimeform, flubenzimine, diclany, amidoflumet, quinomethionate, triarathene, chlorothiazobenz , tetrasul, potassium oleate, petroleum, methoxadiazone, gossypol, flutenzin , bromopropylate, cryolite; Another type of compound, e.g., butacarb, dimethilan, chlorethocarb, phosphocarb , pirimiphos (-ethyl), parathion (-ethyl), methacrifos, o-isopropyl salicylate, trichlorfon, tigolaner, sulprofos, pro paphos, sebufos, pyridathion, protoate, dichlofenthion, dimethon-S- propyl, trichlorfon, tigolaner, sulprofos, propaphos, sebufos, pyridathion, protoate, dichlofenthion, dimethon-S- propyl, trichlorfon, tigolaner, sulprofos, propaphos, sebufos, pyridathion, protoate, dichlofenthion, dimethon-S- Methyl sulfone, isazophos, cyanofenphos, dialifos, carbophenothion, a uthionphos, alomphosvinphos (-methyl), azinphos (-ethyl), chlorpy rifos (-ethyl), phosphamidon, iodofenphos, dioxabenzophos, formothi on, honohos, flupyrazophos, fensulfothion, ethirimfos; Organochlorine compounds, such as, camphechlor, lindane, heptachlor; or, phenyl pyrazole-based, such as, acetoprole, pyrafluprole, pyriprole, vaniliprole l, cisapronil; or, isoxazoline-based, such as, sarolaner, afoxolaner l, lotilaner, fluralaner; Pyrethroid-based, such as, (cis-, trans-) metofluthrin, profluthrin, fulfenprox, flubrocythrinate, fubfenprox, fenfluthrin, protrifenbute, pyresmethrin, RU15525, terallethrin, cis-res methrin, heptafluthrin, bioethanomethrin, biopermethrin, fenpyrethrin l, cis-cyphenothrin, cis-permethrin, cyfluthrin, cyhalothrin (lambda -), chlorvapeorthrin, or, halogenated hydrocarbon compounds (HCHs); Neonicotinoid-based, such as, nithiazine; Dicloromezotiaz, triflumizopyrim; Macrocyclic lactone-based, such as, nemadectin, ivermectin, latidectin, moxide ctin, selamectin, eprinomectin, doramectin, emamectin benzoate; m ilbemyscin oxime; Triprene, epofenonan, diphenolan; Biological agents, hormones, or, pheromones, such as, natural products, such as, turi Thuringiensin, codlemone, or neem components; Dinitrophenol-based, such as dinocap, dinobuton, binapacryl; Benzoylurea-based, such as fluazuron, penfluron; Amidine derivatives, such as chlormebuform, simiazole, demiditraz; Zole, demiditraz; Beehive varroa acaricides, such as organic acids, such as formic acid, oxalic acid. cides), such as organic acids, such as formic acid, oxalic acid.

[0258] Exemplary active ingredients selected from the group of said endoparasiticidal agents as a mixing partner include, but are not limited to, anthelmintic active compounds and antiprotozoal active compounds. Exemplary active ingredients selected from the group of said endoparasiticidal agents as a mixing partner include, but are not limited to, anthelmintic active compounds and antiprotozoal active compounds.

[0259] Said anthelmintic active compounds include, but are not limited to, the following nematicidal active compounds, trematocidal active compounds and / or cestodicidal active compounds; Said anthelmintic active compounds include, but are not limited to, the following nematicidal active compounds, trematocidal active compounds and / or cestodicidal active compounds;

[0260] Macrolide lactones of the kind, for example: eprinomectin, abamectin, nemadectin, moxidectin, doramectin, selamectin, lepimectin, latidectin, milbemycin, ivermectin, emamectin, milbemycin; Macrolide lactones of the kind, for example: eprinomectin, abamectin, nemadectin, moxidectin, doramectin, selamectin, lepimectin, latidectin, milbemycin, ivermectin, emamectin, milbemycin; Macrolide lactones of the kind, for example: eprinomectin, abamectin, nemadectin, moxidectin, doramectin, selamectin, lepimectin, latidectin, milbemycin, ivermectin, emamectin, milbemycin; Benzimidazoles and probenzimidazoles of the kind, for example: oxibendazole, mebendazole, triclabendazole, thiophanate, parbendazole, oxfendazole, netobimin, fenbendazole, febantel, thiabendazole; Benzimidazoles and probenzimidazoles of the kind, for example: oxibendazole, mebendazole, triclabendazole, thiophanate, parbendazole, oxfendazole, netobimin, fenbendazole, febantel, thiabendazole; Benzimidazoles and probenzimidazoles of the kind, for example: oxibendazole, mebendazole, triclabendazole, thiophanate, parbendazole, oxfendazole, netobimin, fenbendazole, febantel, thiabendazole; Benzimidazoles and probenzimidazoles of the kind, for example: oxibendazole, mebendazole, triclabendazole, thiophanate, parbendazole, oxfendazole, netobimin, fenbendazole, febantel, thiabendazole; Benzimidazoles and probenzimidazoles of the kind, for example: oxibendazole, mebendazole, triclabendazole, thiophanate, parbendazole, oxfendazole, netobimin, fenbendazole, febantel, thiabendazole; Thiabendazole, cyclobenzadiazole, cambendazole, albendazole sulfoxide, albendazole, flubendazole; Of the type of depsipeptides, preferably of the type of cyclic depsipeptides (depsipeti des), in particular of the type of 24-membered cyclic depsipeptides, such as, for example: emodepsi de (emodepside), PF1022A; Of the type of tetrahydropyrimidines, such as, for example: morantel, pyrantel, oxantel ; Of the type of imidazothiazoles, such as, for example: butamisole, levamisole, tetramiso le; Of the type of aminophenylamidines, such as, for example: amidantel, deacylated amidantel (dAMD), tribendimidine; Of the type of aminoacetonitriles, such as, for example: monepantel; Of the type of paraherquamides, such as, for example: paraherquamide, derquantel; Of the type of salicylanilides, such as, for example: tribromsalan, bromoxanide, brotian ide, clioxanide, closantel, niclosamide, oxyclozanide, rafoxanide ; Of the type of substituted phenols, such as, for example: nitroxynil, bithionol, disophenol , hexachlorophene, niclorofuran, meniclopholan ; Of the type of organophosphates, such as, for example: trichlorfon, naphthalophos (napht halofos), dichlorvos / DDVP, crufomate, coumaphos, haloxon; Of the type of piperazinones / quinolines, such as, for example: praziqua ntel, epsiprantel; Types of piperazines, such as: piperazine, hydroxydine; Types of tetracyclines, such as: tetracycline, chlortetracycline, doxycycline, oxytetracycline, rolitetracycline; Various other types, such as: bunamidine, niridazole, resorantel, omphalotin , oriptal, nitros canate, nitroxynil, oxamniquine, mirazan (mi rasan), miracil, lucanthone, hicanthone, hetolin (he tolin), emetine, diethylcarbamazine, dichlorophene, diamphenethide, clonazepam, bephenium, amoscanate, chlorthrion .

[0261] Antiprotozoal active compounds include, but are not limited to, the following active compounds , but are not limited thereto;

[0262] Types of triazines, such as: diclazuril, ponazuril, retrazuril, toltrazuril; Types of polyether ionophores, such as: monensin, salinomycin, maduramycin, narasin; Types of macrolides, such as: milbemycin, erythromycin; Types of quinolones, such as: enrofloxacin, pradofloxacin; Types of quinine, such as: chloroquine; Types of pyrimidines, such as: pyrimethamine; Types of sulfonamides, such as: sulfachinoxaline, trimethoprim, sulf acrodine; Types of thiamines, such as: amprolium; Types of lincosamides, such as: clindamycin; ​​Types of carbanylides, for example: imidocarb; Types of nitrofurans, for example: nifurtimox; Types of quinazoline alkaloids, for example: halofuginone; Various other types, for example: oxamniquine, paromomycin; Types of vaccines or antigens from microorganisms, for example: Babesia canis rossi, Eimeria tenella, Eimeria praecox, Eimeria necatrix, Eimeria mitis, Eimeria maxima, Eimeria brunetti, Eimeria acervulina, Babesia canis vogeli, Leishmania infantum, Babesia canis canis, Dictyocaulus viviparus. esia canis rossi), Eimeria tenella, Eimeria praecox, Eimeria lla), Eimeria praecox, Eimeria · necatrix, Eimeria mitis, Eime ria mitis, Eimeria maxima, Eimeria brunetti, Eimeria acervulina (Eimeria acervulina), Babesia canis vogeli, Babesi a canis vogeli, Leishmania infantum ia infantum, Babesia canis canis canis, Dictyocaulus vivip arus).

[0263] All the mixing partners described can form salts with suitable bases or acids, if possible, by their functional groups. or acids to form salts.

[0264] Control of vectors The compounds of formula (I) can also be used in the control of vectors. For the purposes of the present invention, a vector is an organism that transports pathogens (e.g., viruses, worms, unicellular organisms, and bacteria) from a pathogen-carrying host (plants, animals, humans, etc.) to a host. For the purposes of the present invention, a vector is an organism that transports pathogens (e.g., viruses, worms ), unicellular organisms, and bacteria) from a pathogen-carrying host (plants, animals, humans, etc.) to a host. is an arthropod (especially an insect or arachnid) capable of doing so. The pathogen can be mechanically carried (e.g., trachoma by non-biting flies), or can be carried after injection into the host (e.g., malaria parasites by mosquitoes).

[0265] Examples of vectors and the diseases or pathogens carried by vectors are as follows: 1) Mosquitoes - Anopheles: malaria, filariasis; - Culex: Japanese encephalitis, another viral disease, filariasis, transportation of helminths; - Aedes: yellow fever, dengue fever, other viral diseases, filariasis; - Simulidae: transportation of helminths (especially Onchocerca volvulus); - Psychodidae: transmission of leishmaniasis; 2) Lice: skin infections, epidemic typhus; 3) Fleas: infectious diseases, spotted fever, tapeworms; 4) Flies: sleeping sickness (trypanosomiasis); cholera, another bacterial disease; 5) Ticks: acariosis, epidemic typhus, rickettsialpox, wild rabbit disease, St. Louis encephalitis, tick-borne encephalitis (TBE), Crimean-Congo hemorrhagic fever, borreliosis; 6) Mites: borrelioses, e.g., Borrelia burgdorferi sensu lato., Borrelia duttoni, tick-borne encephalitis, Q fever (Coxiella burnetii), Babesia canis canis, ​Ehrlichiosis.

[0266] In the context of the present invention, examples of vectors are insects capable of carrying plant viruses to plants such as aphids, flies, leafhoppers or thrips. Another vector capable of carrying plant viruses is mites, lice, beetles and nematodes. .

[0267] In the context of the present invention, further examples of vectors are insects and arachnids capable of carrying pathogens to animals and / or humans such as mosquitoes [in particular, mosquitoes of the genus Aedes, mosquitoes of the genus Anopheles, such as Aedes gambiae, Anopheles arabiensis, Anopheles funestus, Anopheles dirus (malaria), and mosquitoes of the genus Culex], sand flies (Psychodidid) such as Phlebotomus, Lutzomyia, lice, fleas, flies, mites and ticks. When the compound of formula (I) is resistance-breaking, control of the vector is similarly possible.

[0268] The compound of formula (I) is suitable for use in the prevention of diseases and / or the prevention of pathogens carried by vectors. Thus, a further aspect of the present invention is, for example, in agriculture

[0269] , in horticulture, in gardens and leisure facilities, and furthermore, in material substances and storage production ​​​​​The use of a compound of formula (I) for controlling vectors in the protection of objects.

[0270] Protection of industrial materials The compounds of formula (I) are suitable for protecting industrial materials against attack or destruction by insects [e.g., insects of the order Coleoptera, Hymenoptera, Isoptera, Lepidoptera, Psocoptera and Zygentoma]. Order (Hymenoptera), Termite order (Isoptera), Butterfly order (Lepi doptera), Psocoptera and Zygent oma) insects].

[0271] In the context of the present invention, industrial materials are understood to mean abiotic materials, such as, preferably, plastics, adhesives, sizes, paper and cardboard, leather, wood, processed wood products and paints, etc. The present invention is particularly preferably used for protecting wood. Adhesives, sizes, paper and cardboard, leather, wood, processed wood products and paints, etc. are understood to mean. The present invention is particularly preferably used for protecting wood. It is understood that. The present invention is particularly preferably used for protecting wood.

[0272] In a further embodiment, the compounds of formula (I) are used together with at least one further insecticide and / or at least one fungicide. / or together with at least one fungicide.

[0273] In a further embodiment, the compounds of formula (I) are present as ready-to-use pesticides, i.e., they can be applied to the material substance without further modification. Suitable further insecticides or fungicides are, in particular, those mentioned above. That is, they can be applied to the material substance without further modification. It means that there is. Suitable further insecticides or fungicides are, in particular, those mentioned above. It is.

[0274] Surprisingly, the compounds of formula (I) can also be used to protect those in contact with seawater or brackish water, in particular hulls, Screens, nets, buildings, mooring facilities and signal systems, etc., from fouling. It has also been found that. Similarly, the compounds of formula (I) can be used alone or can be used as a biocide in combination with another active compound.

[0275] Control of pests in the hygiene field The compounds of formula (I) are suitable for controlling pests in the hygiene field. In particular, the present invention is in the household field, in the hygiene field, and in the protection of stored products, in particular, in enclosed spaces such as residences, factory passageways, offices, vehicle passenger compartments, and animal breeding facilities it can be applied to control insects, arachnids, ticks and mites encountered. To control pests, the compounds of formula (I) can be used alone or in combination with other active compounds and / or adjuvants. They are preferably used in household insecticide products. The compounds of formula (I) are effective against sensitive and resistant species and furthermore are effective against all stages of development.

[0276] These pests include, for example, pests of the orders Scorpiones, Araneae and Opiliones of the class Arachnida, pests of the classes Chilopoda and Diplopoda, and pests of the class Insecta of the orders Blattodea, Coleoptera, Dermaptera, Diptera, Heteroptera, Hymenoptera, Isoptera, Lepidoptera, Phthiraptera, Psocoptera, Saltatoria or Orthoptera, Siphonaptera and ​​​​​​​​ Pests of Zygentoma, as well as pests of Isopoda of Malacostraca etc. can be mentioned.

[0277] They are used, for example, in aerosol, non-pressurized spray products such as pump sprays and atomizer sprays, automatic fogging systems , foggers, foams, gels, evaporator products having cellulose or plastic evaporator -tablets, liquid evaporators, gel and film evaporators, propeller-driven evaporators, energy-free or passive evaporation systems , moth papers, moth bags and moth gels (moth gels), or used as granules or powders, incorporated into baits for spreading and used, or used in feeding places.

[0278] Abbreviations and Symbols AcOH: acetic acid aq.: aqueous br.: broad Boc: tert-butyloxycarbonyl d: doublet DCC: N,N′-dicyclohexylcarbodiimide DIPEA: N,N-diisopropylethylamine DMF: N,N-dimethylformamide DMSO: dimethyl sulfoxide ee: enantiomeric excess eq.: equivalent ES: electrospray ionization Et3N: triethylamine EtOAc: ethyl acetate hr(s): hour(s) HATU: 1-[Bis(dimethylamino)methylene]-1H-1,2,3-triazolo 4,5-b]pyridinium-3-oxide hexafluorophosphate HOBt: 1-Hydroxybenzotriazole hydrate HPLC: High Performance Liquid Chromatography iPrOH: Isopropanol J: Coupling constant LCMS: Liquid Chromatography-Mass Spectrometry m / z: Mass / charge ratio M: Molar concentration m: Multiplet MeCN: Acetonitrile MeOH: Methanol NaH2PO4: Sodium dihydrogen phosphate NaOH: Sodium hydroxide Na2SO4: Sodium sulfate NH4Cl: Ammonium chloride NMR: Nuclear Magnetic Resonance q: Quartet rt: Room temperature R t : Retention time s: Singlet sat.: Saturated T: Temperature t: Triplet T3P (registered trademark): Propylphosphonic anhydride THF: Tetrahydrofuran TMSOK: Potassium trimethylsilanolate wt.: Weight δ: Chemical shift λ: Wavelength.

[0279] Description of Processes and Intermediates The compounds shown in Formula I and Table 3 can be produced as shown in Scheme 1 below , where R 1 , R 2 , R 3 , R 4 and R 5 are as previously defined or in Table 3 Represents the corresponding fragment of the compound shown. X represents OH or Cl.

[0280] Scheme 1

Chemical formula

[0281] X = OH: React the triazole compound of formula (a) with the carboxylic acid of formula (b) (X = OH) to form the compound of formula I. For example, in a suitable solvent such as ethyl acetate or DMF mix the triazole of formula (a), the carboxylic acid of formula (b) (X = OH), a suitable coupling reagent such as T3P (registered trademark) , HATU or DCC / HOBt, and a mixture of a suitable base such as triethylamine or DIPEA at a temperature in the range of about 0 to 100 °C to provide the compound of formula I , which can then be isolated and, if necessary and desired, purified using techniques known in the art such as chromatography .

[0282] X = Cl: React the triazole compound of formula (a) with the carboxylic acid chloride of formula (b) (X = Cl ) to form the compound of formula I. For example, in a suitable solvent such as dichloromethane or THF mix the triazole of formula (a), the carboxylic acid chloride of formula (b) (X = Cl), and a mixture of a suitable base such as tri ethylamine or DIPEA at a temperature in the range of about 0 to 100 °C to obtain the compound of formula I, which can then be isolated and, if necessary and desired, purified using techniques known in the art such as chromatography .

[0283] The carboxylic acid of formula (b) (X = OH) and the carboxylic acid chloride of formula (b) (X = Cl) are It can be synthesized by a method that is commercially available or known to those skilled in the art. Formula (b) The synthesis of the specific carboxylic acid (X = OH) is described in WO2019197468 .

[0284] The required triazole compound of formula (a) can be produced according to the method shown in Scheme 2 below, where R and R 3 are as described above, R 4 is as described above, R 1 is C1-C6 alkyl and R 5 is ethyl or n-propyl; or, R 1 , R 3 , R 4 and R 5 represent the corresponding fragments of the compounds shown in Table 3. LG is a suitable leaving group (see also WO201 7192385).

[0285] Scheme 2

Chemical formula

[0286] React the amine of formula (c) with the substituted triazole of formula (d) to form the compound of formula (a). For example, in a suitable solvent such as acetonitrile or DMF, a mixture of the triazole of formula (d), the amine of formula (c), and a suitable base such as K2CO NaH or DIPEA is mixed at a temperature in the range of about 20-120 °C to provide the compound of formula (a), which is then isolated and, if necessary and desired, purified using techniques known in the art such as chromatography l, the amine of formula (c), and a suitable base such as K2CO 3、 NaH or DIPEA is mixed at a temperature in the range of about 20-120 °C to provide the compound of formula (a), which is then isolated and, if necessary and desired, purified using techniques known in the art such as chromatography l, the amine of formula (c), and a suitable base such as K2CO NaH or DIPEA is mixed at a temperature in the range of about 20-120 °C to provide the compound of formula (a), which is then isolated and, if necessary and desired, purified using techniques known in the art such as chromatography .

[0287] Alternatively, react the substituted triazole of formula (d) with ammonia to form the compound of formula (e) is formed. For example, in a suitable solvent such as methanol, a solution of ammonia and a substituted azole of formula (d) are mixed in a sealed tube at a temperature in the range of about 0 to 25 ° C to obtain a compound of formula (e), and then it is isolated and, if necessary and desired, can be purified using techniques known in the art such as grinding. In a suitable solvent such as acetonitrile or DMF, a substituted triazole of formula (e ), a compound of formula (f), and a suitable base such as K2CO3 or DIPEA are mixed at a temperature in the range of about 20 to 120 ° to obtain a compound of formula (a), and then it is isolated and, if necessary, can be purified using techniques known in the art such as chromatography. The amine of formula (c) and the compound of formula (f) are commercially available or can be synthesized by methods known to those skilled in the art. The required triazole compound of formula (d) can be produced according to the method shown in Scheme 3 below, where R and R are as described above, R is ethyl or n-propyl; or, R

[0288] 3 and R 4 are as described above, R is as described above, R 5 is ethyl or n-propyl; or, R 3 4 and R 5 represent the corresponding fragments of the compounds shown in Table 3, and LG is a suitable leaving group (see also WO201719 2385). The amide of formula (h) is reacted with N,N-dimethylamidedimethylacetal (g) to

[0289] Scheme 3

Chemical Formula

[0290] Form a compound of formula (i), which is then reacted with hydrazine (j) under acidic conditions to form a compound of formula (d). For example, a compound of formula (h) and N,N-dimethyl amidodimethylacetal of formula (g) are reacted in a suitable solvent such as CH2Cl2 under reflux to provide a compound of formula (i). After removing the solvent, the compound of formula (i) is reacted with a substituted hydrazine (j) at a temperature in the range of about 20-100 °C in a suitable solvent such as 1,4-diox ane, acetic acid or a mixture of such solvents to obtain a compound of formula (d), which is then isolated and, if necessary and desired, can be purified using techniques known in the art such as chromatography . The N,N-dimethylamide acetal of formula (g), the amide of formula (h) and the hyd

[0291] razine of formula (j) are commercially available or can be synthesized by methods known to those skilled in the art . .

[0292] For example: For 5-bromo-2-hydrazinopyridine, see WO2013 / 038362 .

[0293] For 2-hydrazino-1,3-thiazole, see US2008 / 0234327, W O2018 / 064119, WO2008 / 144767, WO2008 / 121861 .

[0294] The compounds of formula I and the compounds shown in Table 3 can be prepared according to the method shown in Scheme 4 below, where R , R 1 , R 2 , R 3 and R 4 are as previously defined and R 5 is ethyl or n-propyl; or R 1 , R 2 , R 3 , R 4 and R 5 The compounds shown in Table 3 Represents the corresponding fragment of the thing.

[0295] Scheme 4 [ka]

[0296] An amide of formula (n) is reacted with an N,N-dimethylamide dimethyl acetal of formula (g). to form a compound of formula (o), which is subsequently reacted under acidic conditions with a substituted hydrazine of formula (j). reacting to form a compound of formula I. For example, a compound of formula (n) and an N,N- Dimethylamide dimethyl acetal is reacted in a suitable solvent such as CH2Cl2 under reflux. The solvent is removed and the compound of formula (o) is reacted with 1,4-dioxane to obtain the compound of formula (o). in a suitable solvent such as acetic acid, ethyl ether, or a mixture of such solvents at a temperature in the range of about 20 to 100° C. and reacting the resulting compound of formula I with a substituted hydrazine of formula (j) at room temperature. If necessary and desired, purification may be performed using techniques known in the art, such as chromatography. It can be manufactured.

[0297] The requisite amide of formula (n) may be prepared according to the methodology depicted in Scheme 5 below: Here, R 2 and R 3 is as mentioned above, and R 1 is C1-C6 alkyl or H ( see also WO2017192385); or R 1 , R 2 and R 3 is a compound shown in Table 3 represents the corresponding fragment.

[0298] Scheme 5

Chem.

[0299] React the aminoamide of formula (p) with the carboxylic acid of formula (b) to form the compound of formula (n). For example, in a suitable solvent such as ethyl acetate or DMF, a mixture of the aminoamide of formula (p), the carboxylic acid (b), a suitable coupling reagent such as T3P® (registered trademark), HATU or DCC / HOBt, and a suitable base such as triethylamine or DIPEA is mixed at a temperature in the range of about 0 to 100 °C to obtain the compound of formula (n), which is then isolated and, if necessary and desired, purified using techniques known in the art such as chromatography. It is possible. Alternatively, the amino acid of formula (q) is reacted with thionyl chloride in a suitable solvent such as MeOH at room temperature to provide the aminoester of formula (r). The resulting aminoester (r) is reacted in a suitable solvent such as acetic acid at room temperature with an aldehyde or ketone, a suitable reducing agent such as sodium triacetoxyborohydride, and a dehydrating agent such as Na2SO4 to obtain the compound of formula (s).

[0300] Next, the resulting aminoester of formula (s) is reacted with the carboxylic acid of formula (b), a suitable coupling reagent such as T3P® (registered trademark), a suitable base such as DIPEA, and in a suitable solvent such as ethyl acetate at about 90 °C to obtain the amidoester of formula (t), which is then isolated and, if necessary and desired, purified using techniques known in the art. The resulting amidoester of formula (t) is placed in a sealed tube with M (registered trademark), etc., and reacted in a suitable solvent such as ethyl acetate at about 90 °C to obtain the amidoester of formula (t), which is then isolated and, if necessary and desired, purified using techniques known in the art. The resulting amidoester of formula (t) is isolated and, if necessary and desired, purified using techniques known in the art. ​ In a suitable solvent such as eOH, react with magnesium nitride at about 80 °C to obtain a compound of formula (n), which is then isolated and, if necessary and desired, can be purified using techniques well known in the art such as chromatography or extraction. The compounds of formulas (b) and (q) are commercially available or can be synthesized by methods known to those skilled in the art. The synthesis of a specific carboxylic acid (X = OH) of formula (b) is described in WO2019197468. The required aminoamide compound of formula (p) is commercially available or can be prepared according to the method shown in Scheme 6 below, where R and R

[0301] are as described above or represent the corresponding fragments of the compounds shown in Table 3, and LG is a suitable leaving group (see also WO2017192385). The compounds of formulas (c) and (h) are commercially available. The required amine of formula (p) can be prepared according to the method shown in Scheme 6 below, where R and R 1 are as previously described (see also WO2017192385) 3 or represent the corresponding fragments of the compounds shown in Table 3. React the amine of formula (c) with the amide of formula (h) to form a compound of formula (p).

[0302] The compounds of formulas (c) and (h) are commercially available.

[0303] The required amine of formula (p) can be prepared according to the method shown in Scheme 6 below, where R and R 1 are as previously described (see also WO2017192385) 3 or represent the corresponding fragments of the compounds shown in Table 3. React the amine of formula (c) with the amide of formula (h) to form a compound of formula (p).

[0304] Scheme 6

Chemical Formula

[0305] React the amine of formula (c) with the amide of formula (h) to form a compound of formula (p). For example, in a suitable solvent such as acetonitrile or DMF, a mixture of the amine of formula (c), the amide of formula (h), and a suitable base such as K2CO3 or DIPEA is mixed at 25-80 °C to obtain the compound of formula (p), which is then isolated and, if necessary and desired, purified using techniques known in the art such as chromatography. It can be purified using techniques known in the art such as chromatography.

[0306] In another approach, the compound of formula I can be prepared according to the method shown in Scheme 7 below, wherein R 1 , R 2 , R 3 , R 4 are as previously defined, and R 5 is ethyl , n-propyl, isopropyl, difluoromethyl or cyclopropyl; or, R 1 , R 2 , R 3 , R 4 and R 5 represent the corresponding fragments of the compounds shown in Table 3.

[0307] Scheme 7

Chemical formula

[0308] The amidine hydrochloride of formula (u) is reacted with the acid of formula (v). For example, in a suitable solvent such as acetonitrile or DMF, the amidine hydrochloride of formula (u), the carboxylic acid (v), a suitable coupling reagent such as HATU , DCC or HOBt, and a suitable base such as triethylamine or DIPEA are mixed at a temperature in the range of about 0-100 °C to form the compound of formula (w), which is then reacted with the substituted hydrazine of formula (j) under acidic conditions to form the compound of formula I. Then, isolate it and, if necessary and desired, purify it using techniques known in the art, such as chromatography. It can be purified using techniques known in the art.

[0309] The amidine hydrochloride of formula (u), the carboxylic acid derivative of formula (v), and the hydrazine of formula (j) are commercially available or can be synthesized by methods known to those skilled in the art.

[0310] The compound of formula (j′) can be prepared according to the method shown in Scheme 8 below, where E is trifluoromethoxy, difluoromethoxy, or trifluoromethylsulfanyl, LG is chlorine, fluorine, methylthio, methylsulfinyl, or methylsulfonyl, and A is N or CH.

[0311] Scheme 8 [Chemical Formula]

[0312] React a compound of formula (x) containing a leaving group (LG = methylsulfonyl in the case of WO201 6 / 00126) with hydrazine hydrate to form the hydrazine of formula (j′). For example, in a suitable solvent such as methanol or ethanol, react a mixture of the leaving group-containing compound (x) and hydrazine hydrate at 0 to 80 °C to obtain the compound of formula (j′) or its hydrochloride, hydrobromide, or methanesulfonate salt, and then isolate it and, if necessary and desired, purify it using techniques known in the art.

[0313] The compound of formula (x) is commercially available or can be synthesized by methods known to those skilled in the art. It can be synthesized.

[0314] The sulfoxides (sulfines) of general formula (z) and the sulfones of formula (za) can be produced as shown in the following scheme 9, where Ar is phenyl or heteroaryl, R x is C1-C3 alkyl, C 1-2 C haloalkyl or cyclopropyl.

[0315] Scheme 9

Chemical formula

[0316] React a sulfanyl group-containing compound of formula (y) with an oxidizing reagent such as 3-chloroperbenzoic acid, ruthenium(III) chloride combined with sodium periodate, or a combination of formic acid and hydrogen peroxide (abbreviated as [O] in Scheme 9), and according to the molar equivalent of the oxidizing agent used, form a compound of formula ( z) or (za). When 1 equivalent of the oxidizing agent is used, a sulfinyl compound of formula (z) is obtained, and when 2 equivalents are used, a sulfone compound of formula (za) is obtained. The sulfinyl compound of formula ( z) is a chiral compound that forms a mixture of optical isomers. z) or (za). When 1 equivalent of the oxidizing agent is used, a sulfinyl compound of formula (z) is obtained, and when 2 equivalents are used, a sulfone compound of formula (za) is obtained. The sulfinyl compound of formula ( z) is a chiral compound that forms a mixture of optical isomers. z) is a chiral compound that forms a mixture of optical isomers.

[0317] The compound of formula (zd) can be produced according to the method shown in the following Scheme 10, where E is 、H or C1-C6 alkyl, Hal is bromine or iodine, G is cyclopropyl and the cyclopropyl may be substituted by 1 to 2 substituents selected from the group consisting of halogen, -CN, methyl or trifluoromethyl yl. A * is fluorine 、chlorine, bromine, iodine, -CN, difluoromethyl, trifluoromethyl, difluoromethoxy oxy, trifluoromethoxy, methylsulfonyl, ethylsulfonyl, isopropylsulfonyl Rufonyl, cyclopropylsulfonyl, difluoromethylsulfonyl, trifluoroethyl sulfonyl, trifluoromethylsulfonyl, -SF5 and cyclopropyl, and the cyclopropyl may be substituted by 1 to 2 substituents selected from the group consisting of halogen, -CN, methyl, difluoromethyl and trifluoromethyl.

[0318] Scheme 10

Chemical formula

[0319] React the halogen-containing compound of formula (zb) with the boronic acid of formula (zc) to form the compound of formula (zd). For example, in a suitable solvent or solvent mixture such as toluene and water, the halogen-containing compound of formula (zb), the boric acid (zc), a suitable catalyst such as palladium(II) acetate combined with tricyclohexylphosphine, and a suitable base such as tripotassium phosphate are reacted at a temperature in the range of about 0 to 100 °C to obtain the compound of formula (zd), which is then isolated and, if necessary and desired, purified using techniques known in the art such as chromatography. The compound of formula (zd) where E is C1-C6 alkyl can be converted to the compound of formula (zd) where E is H by treatment with an alkali hydroxide in a suitable solvent or solvent mixture containing, for example, tetrahydrofuran, ethanol or water at a temperature in the range of about 0 to 100 °C.

[0320] The compound of formula (zb) can be commercially available or synthesized by methods known to those skilled in the art. A * is methylsulfonyl, ethylsulfonyl, isopropylsulfonyl​​​​​​​​​​​ , the synthesis of the compound of formula (zb) equal to cyclopropylsulfonyl is described in Scheme 11 and FIGS. 12 and 9.

[0321] The compound of formula (zf) can be produced according to the method shown in Scheme 11 below, where E is H or C1-C6 alkyl, Hal is iodine or bromine, and R a is C1 -C3 alkyl or cyclopropyl; A * is fluorine, chlorine, difluoromethyl, trifluoromethyl, difluoromethoxy, trifluoromethoxy and cyclopropyl, and the cyclopropyl may be substituted by 1 to 2 substituents selected from the group of halogen, -CN, methyl, difluoromethyl and trifluoro romethyl.

[0322] Scheme 11

Chemical formula

[0323] React the aryl halide of formula (zb) with the sulfinate of formula (ze) under copper catalysis to form the sulfone of formula (zf).

[0324] For example, a mixture of a compound of formula (zb), sodium sulfinate of formula (ze), copper(I) iodide , proline and sodium hydroxide is reacted in a suitable solvent such as dimethyl sulfoxide at a temperature in the range of 40 to 140 °C (compare with WO2019197468). In another approach, a compound of formula (zb), sodium sulfinate of formula (ze), iodo copper(I), trans-N,N-dimethylcyclohexane-1,2-diamine and carbonic acid React the cesium mixture in a suitable solvent such as DMF at a temperature in the range of 40 to 140 °C. (For example, refer to 3-methylsulfonyl-5-(trifluoromethoxy)benzoic acid reported in this application).

[0325] Next, the obtained compound of formula (zf) is isolated and can be purified, if necessary and desired, using techniques known in the art such as chromatography. The compound of formula (zf) where E is C1-C6 alkyl can be converted to the compound of formula (zf) where E is H by treatment with an alkali hydroxide in a suitable solvent or solvent mixture containing tetrahydrofuran, ethanol, or water, etc. at a temperature in the range of about 0 to 100 °C. When E is a tert-butyl group, this ester can be cleaved under acidic conditions in a suitable solvent such as dichloromethane in the presence of a suitable acid such as trifluoroacetic acid at a temperature in the range of 0 to 40 °C. (Refer also to the synthesis of 3-bromo-5-(1-fluorocyclopropyl)benzoic acid as an example of the acidic cleavage of tert-butyl esters in this application).

[0326] The aryl halide (zb) and the sulfinate salt of formula (zf) can be commercially available or synthesized by methods known to those skilled in the art. * A is cyclopropyl which may be substituted by one or two substituents selected from the group consisting of halogen, -CN, methyl, difluoromethyl, and trifluoromethyl. The synthesis of the compound of formula (zb) is described in Scheme 10 and Scheme 21.

[0327] The compound of formula (zj) can be produced according to the method shown in Scheme 12 below. Hal is fluorine or chlorine, and Rd is C1- which may be substituted by fluorine -C3 alkyl or cyclopropyl; A * is chlorine, bromine, iodine, difluoromethyl l, trifluoromethyl, difluoromethoxy, trifluoromethoxy and cyclopropyl l, and the cyclopropyl may be substituted by 1 to 2 substituents selected from the group consisting of halogen, -CN, methyl, difluoromethyl and trif luoromethyl.

[0328] Scheme 12

Chemical formula

[0329] React the halogenated aryl of formula (zg) with the thiolate salt of formula (zh) to form the thioether of formula (zi ), and then hydrolyze this to form the carboxylic acid of formula (zj) .

[0330] For example, a mixture of the halide of formula (zg) and the sodium thiolate of formula (zh) is reacted in a suitable solvent such as N ,N-dimethylformamide at a temperature in the range of -20 to 50 °C . Next, the obtained nitrile of formula (zi) is in a suitable solvent or solvent mixture such as ethanol or methanol / THF at a temperature in the range of 40 to 100 °C, for example, in an aqueous solution of sodium hydroxide , under basic conditions or at a temperature in the range of 40 to 100 °C, in a suitable strong acid such as sulfuric acid or hydrochloric acid diluted with no diluent or any suitable diluent such as water and hydrolyzed under acidic conditions. Next, the obtained carboxylic acid (zj) is purified using techniques known in the art such as chromatography if necessary and desired. Next, the carboxylic acid (zj) contains in it The sulfanyl group can be oxidized to a sulfinyl group or a sulfonyl group according to the method described in Scheme 9. It can be made into a group.

[0331] The required aryl halide (zg) and the thiolate salt of formula (zh) are commercially available or can be synthesized by methods known to those skilled in the art (for example, for the synthesis of cyclopropane thiol, see WO2013049250). The thiolate salt can be synthesized from the corresponding thiol by deprotonation using sodium hydride in a suitable solvent such as N,N-dimethyl formamide. It can be synthesized by deprotonation with sodium hydride in a suitable solvent such as N,N-dimethylformamide. A * However, it is a cyclopropyl optionally substituted with 1 to 2 substituents s...

Claims

1. A compound of the following formula (I). 【Chemical 1】 [Wherein, R １ is hydrogen; R ２ is phenyl, where the phenyl is substituted with a total of 1 to 2 substituents , provided that the substituent is not on any carbon adjacent to the carbon bonded to C=O, and one substituent is methylsulfonyl, ethylsulfonyl, isopropylsulfonyl, cyclopropylsulfonyl, difluoromethylsulfonyl, trifluoroethylsulfonyl, trifluoro propyl may be substituted by 1 to 2 substituents selected from the group consisting of halogen, -CN, methyl, difluoromethyl and trifluoromethyl; Methylsulfonyl and -SF ５ selected from group A consisting of cyclopropyl, said cycl The other substituents are independently selected from Group B consisting of fluorine, chlorine, bromine, iodine, -CN, difluoromethyl, trifluoromethyl, difluoro fluoromethoxy, trifluoromethoxy and cyclopropyl, and the cyclopropyl may be substituted by 1 to 2 substituents selected from the group consisting of halogen, -CN, methyl, difluoromethyl and trifluoro loromethyl; or thiophene which may be substituted by 1 substituent selected from the group consisting of fluorine, chlorine, bromine and trifluoromethyl; or pyrazole which may be substituted by 1 to 2 substituents selected from the group consisting of fluorine, chlorine, bromine, methyl and trifluoromethyl; R ２ is pyrazine may be substituted by 1 substituent selected from the group consisting of chlorine and -CN; , methoxy, ethoxy, iso-propoxy or halogen.] R ２ is

2. 3-chlorophenyl, 5-chloro-3-thienyl, 3-chloro-5-(2,2,2-trifluoro R ３ is C １ -C ３ alkyl; R ４ is pyridine, pyrimidine or pyrazine, where pyridine, pyrimidine or ethylsulfonyl)phenyl, 3-chloro-5-isopropylsulfonylphenyl, 3- cyclopropylsulfonyl-5-(trifluoromethyl)phenyl, 3-chloro-5-eth R ５ is ethyl, n-propyl, isopropyl, difluoromethyl, cyclopropyl ylsulfonylphenyl, 3-chloro-5-cyclopropylsulfonylphenyl, 3-eth ylsulfonyl-5-(trifluoromethyl)phenyl, 3-cyclopropyl-5-(tri R １ is hydrogen; R ２ is 3-chloro-5-cyclopropylphenyl, 3-chloro-5-methylsulfonyl fluoromethoxy)phenyl, 3-chloro-5-(difluoromethylsulfonyl)phenyl, 3-methylsulfonyl-5-(trifluoromethyl)phenyl, 1-methyl-5- (trifluoromethyl)-1H-pyrazol-3-yl, 3-chloro-5-(pentaflu oro-λ6-sulfanyl)phenyl, 3-chloro-5-(1-cyanocyclopropyl) phenyl, 3-chloro-5-(trifluoromethylsulfonyl)phenyl, 3-bromo- ​ ​ ​ ​ ​ ​ 5-[1-(Trifluoromethyl)cyclopropyl]phenyl, 3-cyclopropyl-5 -methylsulfonylphenyl, 3-(difluoromethyl)-5-methylsulfonylphenyl l, 3-cyclopropyl-5-cyclopropylsulfonylphenyl, 3-fluoro-5- methylsulfonylphenyl, 3-(difluoromethoxy)-5-methylsulfonylphenyl l, 3-methylsulfonyl-5-(trifluoromethoxy)phenyl, 3-cyclopropyl l-5-(difluoromethyl)phenyl, 3-bromo-5-(1-fluorocyclopropyl l)phenyl, 3-bromo-5-(2,2-difluorocyclopropyl)phenyl, 3- cyclopropyl-5-(difluoromethoxy)phenyl, 3-cyclopropylsulfonyl -5-(difluoromethoxy)phenyl, 3-cyclopropylsulfonyl-5-(trif luoromethoxy)phenyl, or 3-cyclopropylsulfonyl-5-(difluoromethyl l)phenyl; R ３ is methyl; R ４ is 5-cyanopyridin-2-yl, pyrimidin-2-yl, 5-chloropyrimidine n-2-yl or 5-chloropyridin-2-yl; R ５ is ethyl, n-propyl, isopropyl, difluoromethyl, cyclopropyl , methoxy, ethoxy, iso-propoxy, iodine, bromine or chlorine, as claimed in claim 1 compound.

3. Compound of formula (e). 【Chemical 2】 [wherein, structural element R ３ , R ４ and R ５ has the meaning provided in claim 1 or claim 2 。］

4. Compound 6-[5-[(1S)-1-aminoethyl]-3-ethyl-1,2,4-triazol -1-yl]pyridine-3-carbonitrile hydrochloride, 6-[5-[(1S)-1-amino ethyl]-3-isopropyl-1,2,4-triazol-1-yl]pyridine-3-car bonitrile, 6-[5-[(1S)-1-aminoethyl]-3-cyclopropyl-1, 2,4-triazol-1-yl]pyridine-3-carbonitrile hydrochloride, 6-[5-( 1-aminoethyl)-3-(difluoromethyl)-1,2,4-triazol-1-yl pyridine-3-carbonitrile, 6-[5-[(1S)-1-aminoethyl]-3-meth oxy-1,2,4-triazol-1-yl]pyridine-3-carbonitrile, 6- 5-[(1S)-1-aminoethyl]-3-ethoxy-1,2,4-triazol-1- yl]pyridine-3-carbonitrile, 6-[5-[(1S)-1-aminoethyl]-3 -isopropoxy-1,2,4-triazol-1-yl]pyridine-3-carbonitrile l, (1S)-1-[1-(5-chloropyrimidin-2-yl)-3-cyclopropyl- [[1H-1,2,4-triazol-5-yl]ethanamine hydrochloride, (1S)-1-[1 -(5-chloropyridin-2-yl)-3-methoxy-1H-1,2,4-triazol -5-yl]ethanamine, (1S)-1-[1-(5-chloropyridin-2-yl)- 3-cyclopropyl-1H-1,2,4-triazol-5-yl]ethanamine hydrochloride , (1S)-1-[1-(5-chloropyrimidin-2-yl)-3-methoxy-1H-1 ,2,4-triazol-5-yl]ethanamine, 6-[5-(1-aminoethyl)- 3-iodo-1H-1,2,4-triazol-1-yl]nicotinonitrile, 6-[5 -(1-aminoethyl)-3-bromo-1,2,4-triazol-1-yl]pyridine -3-carbonitrile, 6-[5-(1-aminoethyl)-3-chloro-1,2,4-tri azole-1-yl]pyridine-3-carbonitrile, and salts thereof, and, in the case of the amine hydrochlorides, the free amine.

5. A compound of the following formula (yf′): [Chemical Formula 3] [wherein E′ is hydrogen, chlorine or -CN, and A is N or CH.], and salts of said compound, preferably hydrochloride, and 5-[(1S)-1-aminoethyl]-1-(pyrimi din-2-yl)-1H-1,2,4-triazole-3-amine hydrochloride.

6. The compounds 3-chloro-5-[(difluoromethyl)sulfanyl]benzoic acid, 3-cyclo propyl-5-(difluoromethyl)benzoic acid, 3-cyclopropyl-5-iodobenzoic acid, 3-chloro-5-[(difluoromethyl)sulfonyl]benzoic acid, 3-cyano-5- cyclopropylbenzoic acid, 3-cyclopropyl-5-methylsulfonyl-benzoic acid, 3- cyclopropyl-5-cyclopropylsulfonyl-benzoic acid and 3-fluoro-5-methyl sulfonyl-benzoic acid and salts thereof.

7. A formulation comprising the compound of formula (I) according to any one of claims 1 to 2, in particular an agrochemical formulation.

8. The formulation according to claim 7, further comprising at least one bulking agent and / or at least one surfactant.

9. The formulation according to claim 7 or 8, characterized in that the compound of formula (I) is mixed with at least one further active compound.

10. A method for treating the body of a human or animal by surgery or therapy and performed on the body of a human or animal ​ ​ A method for controlling pests, especially pest animals, which comprises applying a compound of formula (I) according to any one of claims 1 to 2 or a preparation according to any one of claims 7 to 9 to the pests and / or their habitats, excluding the diagnostic methods to be carried out. A method for controlling pests, especially pest animals, which comprises applying a compound of formula (I) according to any one of claims 1 to 2 or a preparation according to any one of claims 7 to 9 to the pests and / or their habitats, excluding the diagnostic methods to be carried out. A method for controlling pests, especially pest animals, which comprises applying a compound of formula (I) according to any one of claims 1 to 2 or a preparation according to any one of claims 7 to 9 to the pests and / or their habitats, excluding the diagnostic methods to be carried out.

11. A method for treating the body of a human or animal by surgery or therapy and excluding diagnostic methods carried out on the body of a human or animal, wherein the pest is a pest animal, including insects, arachnids or nematodes, or the pest is an insect, arachnid or nematode, according to claim 10. wherein the pest is a pest animal, including insects, arachnids or nematodes, or the pest is an insect, arachnid or nematode, according to claim 10.

12. A method for treating the body of a human or animal by surgery or therapy and excluding diagnostic methods carried out on the body of a human or animal, Use of a compound of formula (I) according to any one of claims 1 to 2 or a preparation according to any one of claims 7 to 9 for controlling pest animals, excluding the use of diagnostic methods carried out on the body of a human or animal by surgery or therapy. Use of a compound of formula (I) according to any one of claims 1 to 2 or a preparation according to any one of claims 7 to 9 for controlling pest animals, excluding the use of diagnostic methods carried out on the body of a human or animal by surgery or therapy.

13. A method for treating the body of a human or animal by surgery or therapy and excluding diagnostic methods carried out on the body of a human or animal, wherein the pest animal includes insects, arachnids or nematodes, or the pest animal is an insect, arachnid or nematode, according to claim 12. wherein the pest animal includes insects, arachnids or nematodes, or the pest animal is an insect, arachnid or nematode, according to claim 12.

14. A method for treating the body of a human or animal by surgery or therapy and excluding diagnostic methods carried out on the body of a human or animal, Use according to claim 12 or 13 in crop protection, excluding the use of diagnostic methods carried out on the body of a human or animal by surgery or therapy.

15. A method for treating the body of a human or animal by surgery or therapy and excluding diagnostic methods carried out on the body of a human or animal, Use according to claim 12 or 13 in the field of animal health, excluding the use of diagnostic methods carried out on the body of a human or animal by surgery or therapy.

16. A method for treating the body of a human or animal by surgery or therapy and excluding diagnostic methods carried out on the body of a human or animal, A method for protecting seeds or germinating plants from pests, especially pest animals, which comprises a method step of contacting the seeds with a compound of formula (I) according to any one of claims 1 to 2 or a preparation according to any one of claims 7 to 9. A method for protecting seeds or germinating plants from pests, especially pest animals, which comprises a method step of contacting the seeds with a compound of formula (I) according to any one of claims 1 to 2 or a preparation according to any one of claims 7 to 9. A method for protecting seeds or germinating plants from pests, especially pest animals, which comprises a method step of contacting the seeds with a compound of formula (I) according to any one of claims 1 to 2 or a preparation according to any one of claims 7 to 9.

17. Seeds obtained by the method according to claim 16.

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