Composition for industrial pest control
The combination of iminoctadine albesilate with other pest control agents achieves a synergistic effect, enhancing pest control efficacy by inhibiting growth and providing antiseptic, antifungal, and anti-algae properties, as confirmed by specific ratios and FIC indices.
Patent Information
- Application Number
- JP2024028558
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- Filing Date
- 2024-02-28
- Publication Date
- 2025-09-09
AI Technical Summary
Existing pest control compositions, including those containing iminoctadine albesilate, do not effectively demonstrate synergistic effects when combined with other industrial pest control agents, and there is a lack of confirmation of such synergies in previous patent documents.
The combination of iminoctadine albesilate with compounds like antiseptics, fungicides, and algae inhibitors in specific ratios achieves a synergistic effect, demonstrated by a Fractional Inhibitory Concentration index (FIC) less than 1, indicating enhanced pest control efficacy.
The synergistic composition exhibits visible inhibition of pest growth and provides effective pest control as an antiseptic, antifungal, and anti-algae agent, with a synergistic effect confirmed through specific ratios of iminoctadine albesilate and other pest control agents.
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Abstract
Description
[Technical Field]
[0001] The present invention relates to an industrial pest control composition. More specifically, the present invention relates to an industrial pest control composition containing iminoctadine albesilate, which is used to control bacteria, mold, yeast, algae, etc. [Background technology]
[0002] Iminoctadine is a guanidine fungicide available as the acetate and albesilate salts. Iminoctadine is also written as 1,1'-[iminodi(octamethylene)]diguanidine. Iminoctadine albesilate is also known as 1,1'-iminiodi(octamethylene)diguanidinium tris(dodecylbenzenesulfonate) and has the following structural formula: [ka]
[0003] Iminoctadine acetate is also known as 1,1'-iminiodi(octamethylene)diguanidinium triacetate and has the following structural formula: [ka]
[0004] Its biological activity is based on the free base iminoctadine, and it is thought to exert bactericidal effects by acting on the lipid biosynthesis system and cell membrane function of pathogenic bacteria, inhibiting spore germination and germ tube elongation. In inventions relating to compounds and compositions thereof having pesticidal activity, there are many patent documents (e.g., Patent Documents 1, 2, and 3) which state that the above-mentioned iminoctadine albesilate and iminoctadine acetate may be used in combination, but none of them have specifically confirmed that a synergistic effect is achieved by using them in combination. Furthermore, a pest control composition for industrial use, excluding agriculture or medicine, containing iminoctadine acetate or albesilate is described in Patent Document 4. However, this document also merely describes that an antimicrobial component may be further contained, and that examples of the antimicrobial component include antibacterial components, bactericidal components, antiviral components, antifungal components, antiseptic components, and antialgal components, but does not confirm that a synergistic effect is achieved by using them in combination. [Prior art documents] [Patent documents]
[0005] [Patent Document 1] WO2006 / 118283 Pamphlet [Patent Document 2] Japanese Patent Application Publication No. 2019-104711 [Patent Document 3] Special Publication No. 2023-528844 [Patent Document 4] Japanese Patent Publication No. 2022-189422 Summary of the Invention
[0006] As a result of extensive research, the present inventors have found that when iminoctadine albesilate is used in combination with compounds known as industrial pest control agents, such as antiseptics, fungicides, and algae inhibitors, a synergistic effect is achieved as a pest control agent. That is, the present invention includes the following aspects.
[0007] (1) An industrial pest control composition containing iminoctadine albesilate and another industrial pest control agent. (2) Other industrial pest control agents 1,2-benzisothiazol-3(2H)-one, 2-methyl-4-isothiazolin-3-one, 5-chloro-2-methyl-4-isothiazolin-3-one, bis(2-pyridylthio)zinc 1,1'-dioxide, 2-(tert-butylamino)-4-(cyclopropylamino)-6-(methylthio)-1,3,5-triazine, 3-(3,4-dichlorophenyl)-1,1-dimethylurea, 2-methylthio-4,6-bis(isopropylamino)-s-triazine, and 3-(3,4-dichlorophenyl)-1-methoxy-1-methylurea The industrial pest control composition according to (1), which is at least one selected from the following: [Effects of the Invention]
[0008] The industrial pest control composition of the present invention exerts a synergistic effect as a pest control agent when used in combination with compounds known as industrial pest control agents, such as antiseptics, fungicides and algaecides. DETAILED DESCRIPTION OF THE INVENTION
[0009] The industrial pest control composition of the present invention contains iminoctadine albesilate and another industrial pest control agent in a ratio that produces a synergistic effect. Here, "industrial use" means commercial or consumer use, excluding agricultural and pharmaceutical use. Examples of pests include bacteria, oomycetes, slime molds, fungi (molds, yeasts, etc.), algae, etc. Pest control properties mean having the effect of preventing the proliferation of pests and / or the effect of eliminating pests. The industrial pest control composition of the present invention can be used as an antiseptic, antifungal agent, anti-algae agent, etc. in combination with other industrial pest control agents.
[0010] In the present invention, the rate at which a synergistic effect is achieved refers to a rate at which inhibition of pest growth is visible to the naked eye and the FIC index (Fractional Inhibitory Concentration index) calculated according to the following formula is less than 1. Details are provided in the Examples. FIC index = a / a0+ b / b0 a0: MIC of component A alone, b0: MIC of B component alone a: MIC of component A when component A and component B are used together b: MIC of component B when component A and component B are used together MIC: minimum inhibitory concentration
[0011] The content of iminoctadine albesilate in the industrial pest control composition of the present invention can be appropriately set depending on the formulation, use, etc., and can be set in the range of, for example, 1 to 90 parts by mass, 5 to 75 parts by mass, 20 to 50 parts by mass, etc., per 100 parts by mass of the industrial pest control composition. The ratio of iminoctadine albesilate to other industrial pest control agents in the industrial pest control composition of the present invention can be in the range of 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400 mass parts, etc. of the other industrial pest control agent per 100 mass parts of iminoctadine albesilate.
[0012] Specifically, at least the following combinations have been confirmed to have a synergistic effect: In addition, the ratio of iminoctadine albesilate to other industrial pest control agents in the industrial pest control composition of the present invention is also described. (1) Iminoctadine albesilate and preservatives Iminoctadine albesilate and 1,2-benzisothiazol-3(2H)-one (BIT) A preferred ratio is 100 to 1600 parts by mass of BIT per 100 parts by mass of iminoctadine albesilate. Iminoctadine albesilate and 2-methyl-4-isothiazolin-3-one (HMIT) A preferred ratio is 800 to 6,400 parts by mass of HMIT relative to 100 parts by mass of iminoctadine albesilate. Iminoctadine albesilate, 2-methyl-4-isothiazolin-3-one (HMIT) and 5-chloro-2-methyl-4-isothiazolin-3-one (CMIT) A preferred ratio is 40 to 60 parts by mass of HMIT and CMIT per 100 parts by mass of iminoctadine albesilate, and a more preferred ratio is about 50 parts by mass of HMIT and CMIT per 100 parts by mass of iminoctadine albesilate. (2) Iminoctadine albesilate and fungicide Iminoctadine albesilate and bis(2-pyridylthio)zinc 1,1'-dioxide (zinc pyrithione) A preferred ratio is 12.5 to 1600 parts by mass of zinc pyrithione to 100 parts by mass of iminoctadine albesilate. (3) Iminoctadine albesilate and anti-algae agents Iminoctadine albesilate and 2-(tert-butylamino)-4-(cyclopropylamino)-6-(methylthio)-1,3,5-triazine (sibutrin) A preferred ratio is 7 to 20 parts by mass of sibutrin per 100 parts by mass of iminoctadine albesilate, and a more preferred ratio is about 12.5 parts by mass of sibutrin per 100 parts by mass of iminoctadine albesilate. Iminoctadine albesilate and 3-(3,4-dichlorophenyl)-1,1-dimethylurea (diuron, DCMU) A preferred ratio is 100 to 200 parts by mass of DCMU relative to 100 parts by mass of iminoctadine albesilate. Iminoctadine albesilate and 2-methylthio-4,6-bis(isopropylamino)-s-triazine (Prometryne) A preferred ratio is 25 to 100 parts by mass of prometryne to 100 parts by mass of iminoctadine albesilate. Iminoctadine albesilate and 3-(3,4-dichlorophenyl)-1-methoxy-1-methylurea (linuron) A preferred ratio is 50 to 800 parts by mass of linuron to 100 parts by mass of iminoctadine albesilate.
[0013] Iminoctadine albesilate used in the present invention can be used in combination with not only industrial pesticides but also agricultural and horticultural pesticides such as insecticides, fungicides, and herbicides. Examples of pesticides that can be used in combination with iminoctadine albesilate and their blending ratios are listed below.
[0014] (Composition containing iminoctadine albesilate and an insecticide) An example of a composition containing iminoctadine albesilate and an insecticide is the composition shown below containing iminoctadine albesilate and a pyrethroid compound. Iminoctadine albesilate and cyfluthrin (parts by mass of cyfluthrin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and cypermethrin (parts by mass of cypermethrin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and deltamethrin (parts by mass of deltamethrin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fenpropathrin (parts by mass of fenpropathrin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fenvalerate (parts by mass of fenvalerate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and esfenvalerate (parts by mass of esfenvalerate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and tralomethrin (parts by mass of tralomethrin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and acrinathrin (parts by mass of acrinathrin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and bifenthrin (parts by mass of bifenthrin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and resmethrin (parts by mass of resmethrin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and tetramethrin (parts by mass of tetramethrin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and tefluthrin (parts by mass of tefluthrin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and etofenprox (parts by mass of etofenprox per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and cyphenothrin (parts by mass of cyphenothrin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and permethrin (parts by mass of permethrin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and prallethrin (parts by mass of prallethrin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and pyrethrin (parts by mass of pyrethrin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and silafluofen (parts by mass of silafluofen per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0015] An example of a composition containing iminoctadine albesilate and an insecticide is a composition containing iminoctadine albesilate and a carbamate compound shown below. Iminoctadine albesilate and propoxor (parts by mass of propoxor per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and isoprocarb (parts by mass of isoprocarb per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and xylylcarb (parts by mass of xylylcarb per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and metolcarb (parts by mass of metolcarb per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and XMC (parts by mass of XMC per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and carbaryl (parts by mass of carbaryl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and pirimicarb (parts by mass of pirimicarb per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and carbofuran (parts by mass of carbofuran per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and methomil (parts by mass of methomil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fenoxycarb (parts by mass of fenoxycarb per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and alanycarb (parts by mass of alanycarb per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and methoxadiazone (parts by mass of methoxadiazone per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0016] Examples of compositions containing iminoctadine albesilate and an insecticide include the following compositions containing iminoctadine albesilate and an organophosphorus compound. Iminoctadine albesilate and acephate (parts by mass of acephate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and phenthoate (parts by mass of phenthoate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and vamidothion (parts by mass of vamidothion per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and trichlorfon (parts by mass of trichlorfon per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and monocrotophos (parts by mass of monocrotophos per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and tetrachlorvinphos (parts by mass of tetrachlorvinphos per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and dimethylvinphos (parts by mass of dimethylvinphos per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and phosalone (parts by mass of phosalone per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and chlorpyrifos (parts by mass of chlorpyrifos per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and chlorpyrifos-methyl (parts by mass of chlorpyrifos-methyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and pyridaphenthion (parts by mass of pyridaphenthion per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and quinalphos (parts by mass of quinalphos per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and methidathion (parts by mass of methidathion per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and methamidophos (parts by mass of methamidophos per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and dimethoate (parts by mass of dimethoate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fermothion (parts by mass of fermothion per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and azinphos ethyl (parts by mass of azinphos ethyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and azinphosmethyl (parts by mass of azinphosmethyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and salithion (mass parts of salithion per 100 mass parts of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fenitrothion (parts by mass of fenitrothion per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0017] An example of a composition containing iminoctadine albesilate and an insecticide is a composition containing iminoctadine albesilate and a urea compound shown below. Iminoctadine albesilate and diflubenzuron (parts by mass of diflubenzuron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and chlorfluazuron (parts by mass of chlorfluazuron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and lufenuron (parts by mass of lufenuron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and hexaflumuron (parts by mass of hexaflumuron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and flufenoxuron (parts by mass of flufenoxuron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and flucycloxuron (parts by mass of flucycloxuron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and cyromazine (parts by mass of cyromazine per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and diafenthiuron (parts by mass of diafenthiuron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and hexythiazox (parts by mass of hexythiazox per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and Novaluron (parts by mass of Novaluron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and teflubenzuron (parts by mass of teflubenzuron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and triflumuron (parts by mass of triflumuron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), iminoctadine albesilate and 4-chloro-2-(2-chloro-2-methylpropyl)-5-(6-iodo-3-pyridylmethoxy)pyridazin-3(2H)-one (parts by mass of 4-chloro-2-(2-chloro-2-methylpropyl)-5-(6-iodo-3-pyridylmethoxy)pyridazin-3(2H)-one per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 1-(2,6-difluorobenzoyl)-3-[2-fluoro-4-(trifluoromethyl)phenyl]urea (parts by mass of 1-(2,6-difluorobenzoyl)-3-[2-fluoro-4-(trifluoromethyl)phenyl]urea per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 1-(2,6-difluorobenzoyl)-3-[2-fluoro-4-(1,1,2,3,3,3-hexafluoropropoxy)phenyl]urea (parts by mass of 1-(2,6-difluorobenzoyl)-3-[2-fluoro-4-(1,1,2,3,3,3-hexafluoropropoxy)phenyl]urea per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), iminoctadine albesilate and 2-tert-butylimino-3-isopropyl-5-phenyl-3,4,5,6-tetrahydro-2H-1,3,5-thiadiazon-4-one (parts by mass of 2-tert-butylimino-3-isopropyl-5-phenyl-3,4,5,6-tetrahydro-2H-1,3,5-thiadiazon-4-one per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 1-(2,6-difluorobenzoyl)-3-[2-fluoro-4-(1,1,2,2-tetrafluoroethoxy)phenyl]urea (parts by mass of 1-(2,6-difluorobenzoyl)-3-[2-fluoro-4-(1,1,2,2-tetrafluoroethoxy)phenyl]urea per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0018] Examples of compositions containing iminoctadine albesilate and an insecticide include the following compositions containing iminoctadine albesilate and a neonicotinoid compound. Iminoctadine albesilate and imidacloprid (parts by mass of imidacloprid per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and acetamiprid (parts by mass of acetamiprid per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and nitenpyram (parts by mass of nitenpyram per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and diacrodene (parts by mass of diacrodene per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and thiamethoxam (parts by mass of thiamethoxam per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and clothianidin (parts by mass of clothianidin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and thiacloprid (parts by mass of thiacloprid per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and dinotefuran (parts by mass of dinotefuran per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0019] Examples of compositions containing iminoctadine albesilate and an insecticide include the following compositions containing iminoctadine albesilate and an insecticide other than those listed above. Iminoctadine albesilate and fipronil (parts by mass of fipronil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and cartap (parts by mass of cartap per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and buprofezin (parts by mass of buprofezin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and thiocyclam (parts by mass of thiocyclam per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and bensultap (parts by mass of bensultap per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fenoxycarb (parts by mass of fenoxycarb per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fenazaquin (parts by mass of fenazaquin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fenpyroximate (parts by mass of fenpyroximate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and pyridaben (parts by mass of pyridaben per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and riproxifen (parts by mass of riproxifen per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and hydramethylnon (parts by mass of hydramethylnon per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and thiodicarb (parts by mass of thiodicarb per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fenobucarb (parts by mass of fenobucarb per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and chlorfenapyr (parts by mass of chlorfenapyr per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fenproximate (parts by mass of fenproximate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and pymetrozine (parts by mass of pymetrozine per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and pyrimidifen (parts by mass of pyrimidifen per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and tebufenozide (parts by mass of tebufenozide per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and tebufenpyrad (parts by mass of tebufenpyrad per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and methoxyfenozide (parts by mass of methoxyfenozide per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and triazamate (parts by mass of triazamate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and indoxacarb (parts by mass of indoxacarb per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and sulfluramide (parts by mass of sulfluramide per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and milbemectin (parts by mass of milbemectin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and avermectin (parts by mass of avermectin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and chlorantraniliprole (parts by mass of chlorantraniliprole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and pyriprole (parts by mass of pyriprole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and brofuranilide (parts by mass of brofuranilide per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and flupyradifurone (parts by mass of flupyradifurone per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and dichloromezothiaz (parts by mass of dichloromezothiaz per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and boric acid (parts by mass of boric acid per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and disodium octaborate tetrahydrate (parts by mass of disodium octaborate tetrahydrate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and borax (parts by mass of borax per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and borax pentahydrate (parts by mass of borax pentahydrate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and paradichlorobenzene (parts by mass of paradichlorobenzene per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and capric acid (parts by mass of capric acid per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0020] (Composition containing iminoctadine albesilate and a fungicide) Examples of compositions containing iminoctadine albesilate and a fungicide include the following compositions containing iminoctadine albesilate and a benzimidazole compound. Iminoctadine albesilate and benomyl (parts by mass of benomyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and carbendazim (parts by mass of carbendazim per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and thiabendazole (parts by mass of thiabendazole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and thiophanate methyl (parts by mass of thiophanate methyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0021] An example of a composition containing iminoctadine albesilate and a fungicide is a composition containing iminoctadine albesilate and a phenylcarbamate compound shown below. Iminoctadine albesilate and diethofencarb (parts by mass of diethofencarb per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0022] An example of a composition containing iminoctadine albesilate and a fungicide is the composition shown below containing iminoctadine albesilate and a dicarboximide compound. Iminoctadine albesilate and procymidone (parts by mass of procymidone per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and iprodione (parts by mass of iprodione per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and vinclozolin (parts by mass of vinclozolin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0023] Examples of compositions containing iminoctadine albesilate and a fungicide include the following compositions containing iminoctadine albesilate and an azole compound. Iminoctadine albesilate and triflumizole (parts by mass of triflumizole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and hexaconazole (parts by mass of hexaconazole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and diniconazole (parts by mass of diniconazole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and epoxiconazole (parts by mass of epoxiconazole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and tebuconazole (parts by mass of tebuconazole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and difenoconazole (parts by mass of difenoconazole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and cyproconazole (parts by mass of cyproconazole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and propiconazole (parts by mass of propiconazole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and flusilazole (parts by mass of flusilazole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and triadimefon (parts by mass of triadimefon per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and metconazole (parts by mass of metconazole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and myclobutanil (parts by mass of myclobutanil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and imazalil (parts by mass of imazalil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and triforine (parts by mass of triforine per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0024] Examples of compositions containing iminoctadine albesilate and a fungicide include the following compositions containing iminoctadine albesilate and an acylalanine compound. Iminoctadine albesilate and metalaxyl (parts by mass of metalaxyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0025] Examples of compositions containing iminoctadine albesilate and a fungicide include the following compositions containing iminoctadine albesilate and a carboxyamide compound. Iminoctadine albesilate and furametpyr (parts by mass of furametpyr per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and mepronil (parts by mass of mepronil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and flutolanil (parts by mass of flutolanil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and trifluzamide (parts by mass of trifluzamide per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0026] Examples of compositions containing iminoctadine albesilate and a fungicide include the following compositions containing iminoctadine albesilate and an organophosphorus compound. Iminoctadine albesilate and tolclofos-methyl (parts by mass of tolclofos-methyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fosetyl aluminum (parts by mass of fosetyl aluminum per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and pyrazophos (parts by mass of pyrazophos per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0027] Examples of compositions containing iminoctadine albesilate and a fungicide include the following compositions containing iminoctadine albesilate and an anilinopyrimidine compound. Iminoctadine albesilate and pyrimesanil (parts by mass of pyrimesanil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and mepanipyrim (parts by mass of mepanipyrim per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and cyprodinil (parts by mass of cyprodinil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0028] An example of a composition containing iminoctadine albesilate and a fungicide is the composition shown below containing iminoctadine albesilate and a cyanopyrrole compound. Iminoctadine albesilate and fludioxonil (parts by mass of fludioxonil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fenpiclonil (parts by mass of fenpiclonil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0029] Examples of the composition containing iminoctadine albesilate and a bactericide include the following compositions containing iminoctadine albesilate and an antibiotic. Iminoctadine albesilate and blasticidin S (mass parts of blasticidin S per 100 mass parts of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and polyoxin (parts by mass of polyoxin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and kasugamycin (parts by mass of kasugamycin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and validamycin (parts by mass of validamycin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0030] An example of a composition containing iminoctadine albesilate and a fungicide is the following composition containing iminoctadine albesilate and methoxyacrylate. Iminoctadine albesilate and azoxystrobin (parts by mass of azoxystrobin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and pyraclostrobin (parts by mass of pyraclostrobin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and trifloxystrobin (parts by mass of trifloxystrobin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and kresoxim methyl (parts by mass of kresoxim methyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and SSF-126 (parts by mass of SSF-126 per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0031] Examples of compositions containing iminoctadine albesilate and a fungicide include the following compositions containing iminoctadine albesilate and a fungicide other than those listed above. Iminoctadine albesilate and iminoctadine acetate (parts by mass of iminoctadine acetate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and penflufen (parts by mass of penflufen per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and chlorothalonil (parts by mass of chlorothalonil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and mancozeb (parts by mass of mancozeb per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and captan (parts by mass of captan per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and folpet (parts by mass of folpet per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and oxine copper (parts by mass of oxine copper per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and basic copper chloride (parts by mass of basic copper chloride per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and tricyclazole (parts by mass of tricyclazole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and pyroquilon (parts by mass of pyroquilon per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and probenazole (parts by mass of probenazole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fthalide (parts by mass of fthalide per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and cymoxanil (parts by mass of cymoxanil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and dimethomorph (parts by mass of dimethomorph per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and CGA245704 (parts by mass of CGA245704 per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and famoxadone (parts by mass of famoxadone per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and oxolinic acid (parts by mass of oxolinic acid per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fluazinam (parts by mass of fluazinam per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and ferimzone (parts by mass of ferimzone per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and clobentiazone (parts by mass of clobentiazone per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and isovaledione (parts by mass of isovaledione per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and thiophthalimidoxybisphenoxyarsine (parts by mass of thiophthalimidoxybisphenoxyarsine per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 3-iodo-2-propynyl butylcarbamate (parts by mass of 3-iodo-2-propynyl butylcarbamate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0032] (Composition containing iminoctadine albesilate and a herbicide) Examples of compositions containing iminoctadine albesilate and a herbicide include the following compositions containing iminoctadine albesilate and a triazine compound. Iminoctadine albesilate and atrazine (parts by mass of atrazine per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and metribuzin (parts by mass of metribuzin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0033] Examples of compositions containing iminoctadine albesilate and a herbicide include the following compositions containing iminoctadine albesilate and a urea compound. Iminoctadine albesilate and fluometuron (parts by mass of fluometuron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and isoproturon (parts by mass of isoproturon per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0034] An example of a composition containing iminoctadine albesilate and a herbicide is a composition containing iminoctadine albesilate and a hydroxybenzonitrile compound shown below. Iminoctadine albesilate and bromoxynil (parts by mass of bromoxynil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and ioxynil (parts by mass of ioxynil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0035] An example of a composition containing iminoctadine albesilate and a herbicide is a composition containing iminoctadine albesilate and a 2,6-dinitroaniline compound shown below. Iminoctadine albesilate and pendimesalin (parts by mass of pendimesalin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and trifluralin (parts by mass of trifluralin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0036] An example of a composition containing iminoctadine albesilate and a herbicide is a composition containing iminoctadine albesilate and an aryloxyalkanoic acid compound shown below. Iminoctadine albesilate and 2,4-D (parts by mass of 2,4-D per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and dicamba (parts by mass of dicamba per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fluroxypyr (parts by mass of fluroxypyr per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and mecoprop (parts by mass of mecoprop per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0037] Examples of compositions containing iminoctadine albesilate and a herbicide include the following compositions containing iminoctadine albesilate and a sulfonylurea compound. Iminoctadine albesilate and bensulfuron methyl (parts by mass of bensulfuron methyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and metsulfuron methyl (parts by mass of metsulfuron methyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and nicosulfuron (parts by mass of nicosulfuron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and primisulfuron methyl (parts by mass of primisulfuron methyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and cyclosulfamuron (parts by mass of cyclosulfamuron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0038] Examples of compositions containing iminoctadine albesilate and a herbicide include the following compositions containing iminoctadine albesilate and an imidazolinone compound. Iminoctadine albesilate and imazapyr (parts by mass of imazapyr per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and imazaquin (parts by mass of imazaquin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and imazethapyr (parts by mass of imazethapyr per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0039] Examples of the composition containing iminoctadine albesilate and a herbicide include the following compositions containing iminoctadine albesilate and a herbicide other than those listed above. Iminoctadine albesilate and bispyribac-sodium salt (parts by mass of bispyribac-sodium salt per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and Bisthiobac Na salt (parts by mass of Bisthiobac Na salt per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and acifluorfen sodium salt (parts by mass of acifluorfen sodium salt per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400). Iminoctadine albesilate and sulfentrazone (parts by mass of sulfentrazone per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and paraquat (parts by mass of paraquat per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and flumetsulam (parts by mass of flumetsulam per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and triflusulfuron methyl (parts by mass of triflusulfuron methyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fenoxaprop-p-ethyl (parts by mass of fenoxaprop-p-ethyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and cyhalofop butyl (parts by mass of cyhalofop butyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and diflufenican (parts by mass of diflufenican per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and norflurazon (parts by mass of norflurazon per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and isoxaflutole (parts by mass of isoxaflutole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and glufosinate ammonium salt (parts by mass of glufosinate ammonium salt per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and glyphosate (parts by mass of glyphosate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and bentazone (parts by mass of bentazone per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and benthiocarb (parts by mass of benthiocarb per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and mefenacet (parts by mass of mefenacet per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and propanil (parts by mass of propanil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fluthiamide (parts by mass of fluthiamide per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0040] (Composition containing iminoctadine albesilate and a plant growth regulator) Examples of the composition containing iminoctadine albesilate and a plant growth regulator include the following compositions containing iminoctadine albesilate and a plant growth regulator. Iminoctadine albesilate and maleic hydrazide (parts by mass of maleic hydrazide per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and chlormecut (parts by mass of chlormecut per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and ethephon (parts by mass of ethephon per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and gibberellin (parts by mass of gibberellin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and mepicat chloride (parts by mass of mepicat chloride per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and thidiazuron (parts by mass of thidiazuron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and inabenfide (parts by mass of inabenfide per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and paclobutrazol (parts by mass of paclobutrazol per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and uniconazole (parts by mass of uniconazole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0041] (Composition containing iminoctadine albesilate and insect repellent) Examples of the composition containing iminoctadine albesilate and an insect repellent include the following compositions containing iminoctadine albesilate and an insect repellent. Iminoctadine albesilate and 1S,3R,4R,6R-carane-3,4-diol (parts by mass of 1S,3R,4R,6R-carane-3,4-diol per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and dipropyl 2,5-pyridinedicarboxylate (parts by mass of dipropyl 2,5-pyridinedicarboxylate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0042] (Composition containing iminoctadine albesilate and an industrial pesticide) Examples of the industrial pesticide include the above-mentioned agricultural and horticultural agents, fungicides, antiseptics, anti-algae agents, and wood preservatives. Examples of compositions containing iminoctadine albesilate and an industrial pesticide include the following compositions containing iminoctadine albesilate and a quaternary ammonium salt compound. Iminoctadine albesilate and didecyldimethylammonium chloride (DDAC) (parts by mass of didecyldimethylammonium chloride (DDAC) per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and didecyldimethylammonium adipate (DDAA) (parts by mass of didecyldimethylammonium adipate (DDAA) per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and benzalkonium chloride (parts by mass of benzalkonium chloride per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and N,N-didecyl-N-methyl-polyoxyethyl-ammonium propionate (DMPAP) (parts by mass of N,N-didecyl-N-methyl-polyoxyethyl-ammonium propionate (DMPAP) per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and N,N-didecyl-N,N-dimethylammonium bicarbonate (parts by mass of N,N-didecyl-N,N-dimethylammonium bicarbonate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and N,N-didecyl-N,N-dimethylammonium carbonate (parts by mass of N,N-didecyl-N,N-dimethylammonium carbonate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0043] Examples of compositions containing iminoctadine albesilate and an industrial pesticide include the following compositions containing iminoctadine albesilate and a biguanide compound. Iminoctadine albesilate and polyhexamethylene biguanide (PHMB) (parts by mass of polyhexamethylene biguanide (PHMB) per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and polyhexamethyleneguanidine (PHMG) (parts by mass of polyhexamethyleneguanidine (PHMG) per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and chlorhexidine gluconate (parts by mass of chlorhexidine gluconate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0044] Examples of compositions containing iminoctadine albesilate and an industrial pesticide include the following compositions containing iminoctadine albesilate and a pyridinium-based compound. Iminoctadine albesilate and cetylpyridinium chloride (parts by mass of cetylpyridinium chloride per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and dodecylpyridinium chloride (parts by mass of dodecylpyridinium chloride per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0045] Examples of compositions containing iminoctadine albesilate and an industrial pesticide include the following compositions containing iminoctadine albesilate and an organic iodine compound. Iminoctadine albesilate and 3-iodo-2-propynyl-butylcarbamate (IPBC) (parts by mass of 3-iodo-2-propynyl-butylcarbamate (IPBC) per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0046] Examples of compositions containing iminoctadine albesilate and an industrial pesticide include the following compositions containing iminoctadine albesilate and a pyridine compound. Iminoctadine albesilate and 2,3,5,6-tetrachloro-4-(methylsulfonyl)pyridine (TCMSP) (parts by mass of 2,3,5,6-tetrachloro-4-(methylsulfonyl)pyridine (TCMSP) per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0047] Examples of compositions containing iminoctadine albesilate and an industrial pesticide include the following compositions containing iminoctadine albesilate and a pyrithione compound. Iminoctadine albesilate and zinc pyrithione (parts by mass of zinc pyrithione per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and sodium pyrithione (parts by mass of sodium pyrithione per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0048] Examples of compositions containing iminoctadine albesilate and an industrial pesticide include the following compositions containing iminoctadine albesilate and a benzothiazole compound. Iminoctadine albesilate and 2-(4-thiocyanomethylthio)benzothiazole (parts by mass of 2-(4-thiocyanomethylthio)benzothiazole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0049] Examples of compositions containing iminoctadine albesilate and an industrial pesticide include the following compositions containing iminoctadine albesilate and an imidazole compound. Iminoctadine albesilate and methyl-2-benzimidazole carbamate (parts by mass of methyl-2-benzimidazole carbamate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 2-(4-thiazolyl)-benzimidazole (parts by mass of 2-(4-thiazolyl)-benzimidazole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0050] Examples of compositions containing iminoctadine albesilate and an industrial pesticide include the following compositions containing iminoctadine albesilate and a thiocarbamate compound. Iminoctadine albesilate and tetramethylthiuram disulfide (parts by mass of tetramethylthiuram disulfide per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0051] Examples of compositions containing iminoctadine albesilate and an industrial pesticide include the following compositions containing iminoctadine albesilate and a nitrile compound. Iminoctadine albesilate and 2,4,5,6-tetrachloroisophthalonitrile (parts by mass of 2,4,5,6-tetrachloroisophthalonitrile per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0052] Examples of compositions containing iminoctadine albesilate and an industrial pesticide include the following compositions containing iminoctadine albesilate and a haloalkylthio compound. Iminoctadine albesilate and N-(fluorodichloromethylthio)-phthalimide (parts by mass of N-(fluorodichloromethylthio)-phthalimide per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and N-(fluorodichloromethylthio)-N,N'-dimethyl-N-phenyl-sulfamide (parts by mass of N-(fluorodichloromethylthio)-N,N'-dimethyl-N-phenyl-sulfamide per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0053] Examples of compositions containing iminoctadine albesilate and an industrial pesticide include the following compositions containing iminoctadine albesilate and a triazole compound. Iminoctadine albesilate and tebuconazole (parts by mass of tebuconazole per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0054] Examples of compositions containing iminoctadine albesilate and an industrial pesticide include the following compositions containing iminoctadine albesilate and an isothiazolinone compound. Iminoctadine albesilate and 1,2-benzisothiazolin-3-one (parts by mass of 1,2-benzisothiazolin-3-one per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and N-methyl-1,2-benzisothiazol-3(2H)-one (parts by mass of N-methyl-1,2-benzisothiazol-3(2H)-one per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 2-methyl-4,5-trimethylene-4-isothiazolin-3-one (parts by mass of 2-methyl-4,5-trimethylene-4-isothiazolin-3-one per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 5-chloro-2-methyl-4-isothiazolin-3-one (parts by mass of 5-chloro-2-methyl-4-isothiazolin-3-one per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 2-methyl-4-isothiazolin-3-one (parts by mass of 2-methyl-4-isothiazolin-3-one per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 2-n-octyl-4-isothiazolin-3-one (parts by mass of 2-n-octyl-4-isothiazolin-3-one per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 4,5-dichloro-2-n-octyl-4-isothiazolin-3-one (parts by mass of 4,5-dichloro-2-n-octyl-4-isothiazolin-3-one per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 2-ethyl-4-isothiazolin-3-one (parts by mass of 2-ethyl-4-isothiazolin-3-one per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 4,5-dichloro-2-cyclohexyl-4-isothiazolin-3-one (parts by mass of 4,5-dichloro-2-cyclohexyl-4-isothiazolin-3-one per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 5-chloro-2-ethyl-4-isothiazolin-3-one (parts by mass of 5-chloro-2-ethyl-4-isothiazolin-3-one per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 5-chloro-2-methyl-4-isothiazolin-3-one (parts by mass of 5-chloro-2-methyl-4-isothiazolin-3-one per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 5-chloro-2-t-octyl-4-isothiazolin-3-one (parts by mass of 5-chloro-2-t-octyl-4-isothiazolin-3-one per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 2-n-butyl-1,2 benzisothiazolin-3-one (parts by mass of 2-n-butyl-1,2 benzisothiazolin-3-one per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 4,5-dichloro-2-n-octyl-4-isothiazolin-3-one (parts by mass of 4,5-dichloro-2-n-octyl-4-isothiazolin-3-one per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0055] Examples of compositions containing iminoctadine albesilate and an industrial pesticide include the following compositions containing iminoctadine albesilate and a bromine-based compound. Iminoctadine albesilate and 2-bromo-2-nitro-1,3-propanediol (parts by mass of 2-bromo-2-nitro-1,3-propanediol per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 2,2-dibromo-2-nitroethanol (parts by mass of 2,2-dibromo-2-nitroethanol per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 2,2-dibromo-3-nitrilopropionamide (parts by mass of 2,2-dibromo-3-nitrilopropionamide per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0056] Examples of compositions containing iminoctadine albesilate and an industrial pesticide include the following compositions containing iminoctadine albesilate and an industrial pesticide other than those listed above. Iminoctadine albesilate and parachlorometacresol (parts by mass of parachlorometacresol per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and 4-chloro-3,5-xylenol (parts by mass of 4-chloro-3,5-xylenol per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and triazine-1,3,5(2H,4H,6H)-triethanol (parts by mass of triazine-1,3,5(2H,4H,6H)-triethanol per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and streptomycin (parts by mass of streptomycin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and diuron (DCMU) (parts by mass of diuron (DCMU) per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and Dimron (parts by mass of Dimron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and metobenzuron (parts by mass of metobenzuron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and cumyluron (parts by mass of cumyluron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and nicosulfuron (parts by mass of nicosulfuron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and linuron (parts by mass of linuron per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and sibutrin (parts by mass of sibutrin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and terbutryn (parts by mass of terbutryn per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and simazine (parts by mass of simazine per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and atrazine (parts by mass of atrazine per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and propazine (parts by mass of propazine per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and cyanazine (parts by mass of cyanazine per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and dimethametryn (parts by mass of dimethametryn per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and Prometryne (parts by mass of Prometryne per 100 parts by mass of Iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and butralin (parts by mass of butralin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and benfluralin (parts by mass of benfluralin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and prodiamine (parts by mass of prodiamine per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and benzofenap (parts by mass of benzofenap per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and pyraflufen-ethyl (parts by mass of pyraflufen-ethyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and Bifenox (parts by mass of Bifenox per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and bromobutide (parts by mass of bromobutide per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and bromoxynil (parts by mass of bromoxynil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and propanil (parts by mass of propanil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and diflufenican (parts by mass of diflufenican per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and mefenacet (parts by mass of mefenacet per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and clomeprop (parts by mass of clomeprop per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and diclosulam (parts by mass of diclosulam per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and dithiopyr (parts by mass of dithiopyr per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and isoxaben (parts by mass of isoxaben per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and lenacil (parts by mass of lenacil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and pyributicarb (parts by mass of pyributicarb per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and pyriminobac-methyl (parts by mass of pyriminobac-methyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and oxadiazone (parts by mass of oxadiazone per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and oryzalin (parts by mass of oryzalin per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and oxadiargyl (parts by mass of oxadiargyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and fluthiacet-methyl (parts by mass of fluthiacet-methyl per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and pyribenzoxime (parts by mass of pyribenzoxime per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and pentoxazone (parts by mass of pentoxazone per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and silver zeolite (parts by mass of silver zeolite per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and silver silica gel (parts by mass of silver silica gel per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and silver zirconium phosphate (parts by mass of silver zirconium phosphate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and histidine silver complex (parts by mass of histidine silver complex per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and parahydroxybenzoate ester (parts by mass of parahydroxybenzoate ester per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and sodium benzoate (parts by mass of sodium benzoate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and sodium dehydroacetate (parts by mass of sodium dehydroacetate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and potassium sorbate (parts by mass of potassium sorbate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and methylparaben (parts by mass of methylparaben per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and methylene bisthiocyanate (parts by mass of methylene bisthiocyanate per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and cupric oxide (parts by mass of cupric oxide per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and cupric hydroxide (parts by mass of cupric hydroxide per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and creosote oil (parts by mass of creosote oil per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and lithium salt (parts by mass of lithium salt per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and sodium salt (parts by mass of sodium salt per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and potassium salt (parts by mass of potassium salt per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and magnesium salt (parts by mass of magnesium salt per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400), Iminoctadine albesilate and calcium salt (parts by mass of calcium salt per 100 parts by mass of iminoctadine albesilate: 0.1, 1, 12.5, 25, 50, 100, 200, 400, 800, 1600, 3200, 6400).
[0057] The industrial pest control composition of the present invention may contain a solvent. The solvent is preferably one capable of dispersing or dissolving iminoctadine albesilate and other pest control compounds used in combination. Specific examples of the solvent include water; glycol ether solvents such as diethylene glycol monobutyl ether, triethylene glycol monomethyl ether, triethylene glycol monobutyl ether, 2-ethylhexyl glycol, tripropylene glycol monomethyl ether, diethylene glycol monohexyl ether, dipropylene glycol monomethyl ether, and dipropylene glycol monobutyl ether; organic acids such as formic acid, acetic acid, lactic acid, oxalic acid, citric acid, and benzoic acid; alcohols such as methanol, ethanol, isopropyl alcohol, isobutyl alcohol, and n-butanol; Examples of suitable solvents include amines such as ethanolamine, dimethylamine, and pyridine; amides such as dimethylformamide, dimethylacetamide, and N-methylpyrrolidone; ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, and acetylacetone; ethers such as diethyl ether, dimethyl ether, and tetrahydrofuran; hydroxyethers such as ethyl cellosolve, butyl cellosolve, and propylene glycol monomethyl ether; esters such as ethyl acetate, butyl acetate, ethyl lactate, and butyl lactate; hydrocarbons such as hexane, benzene, xylene, and toluene; halogenated hydrocarbons such as dichloromethane, carbon tetrachloride, chloroform, and trichloroethylene; acetonitrile; dimethyl sulfoxide (DMSO); mineral oil, synthetic hydrocarbon oil, synthetic ester oil, natural fats and oils, natural fats and oil derivatives, ether oil, silicone oil, and fluorinated oil. These solvents can be used alone or in combination of two or more.
[0058] The amount of solvent contained in the industrial pest control composition of the present invention can be appropriately set depending on the application, for example, 5 to 99 parts by mass, 10 to 80 parts by mass, 30 to 60 parts by mass, etc., per 100 parts by mass of the industrial pest control composition.
[0059] The industrial pest control composition of the present invention can further contain other components depending on its purpose and application. Examples of other components include flame retardants, heat stabilizers, antioxidants, lubricants, antistatic agents, UV absorbers, colorants, dyes / pigments, release agents, heat shielding agents, dispersants, surfactants, pH adjusters, antifoaming agents, rust inhibitors, viscosity modifiers, sequestering agents, friction modifiers, fillers, and lac shells. These can be used alone or in combination of two or more.
[0060] The industrial pest control composition of the present invention can be formulated according to its purpose and use. Examples of the formulation form include aqueous suspensions, liquids containing oils, pastes, powders, granules, microcapsules, etc.
[0061] The liquid industrial pest control composition of the present invention can be added to, mixed with, applied to, sprayed on, impregnated with, etc. other materials. The solid industrial pest control composition of the present invention can be added to, mixed with, sprayed on, attached to, etc. other materials. In this way, pest control properties can be imparted to other materials.
[0062] The industrial pest control composition of the present invention may contain a resin. The resin can be appropriately selected depending on the application, the required performance, etc. The resin in the present invention is a resin in a broad sense, and includes not only resin in the narrow sense but also elastomer, rubber, etc. The resin in the present invention may be a thermoplastic resin, a thermosetting resin, or a photocurable resin.
[0063] Examples of thermoplastic resins include styrene resins, acrylic resins, vinyl acetate resins, acrylonitrile copolymers, polyphenylene oxide resins, polysulfone resins, polyethersulfone, polyarylate, polyetherimide, polyamideimide, polyimide, polymethyl methacrylate, acrylonitrile-styrene copolymer resins, acrylonitrile-styrene-N-substituted maleimide terpolymers, acrylonitrile-butadiene-styrene copolymer resins, styrene-maleic anhydride copolymer resins, styrene-maleic anhydride-N-substituted maleimide copolymer resins, polycarbonate resins, polybutylene terephthalate resins, polyethylene (linear low-density polyethylene, low-density polyethylene, high-density polyethylene, etc.), polyethylene terephthalate, polybutylene terephthalate, polyvinyl chloride, polypropylene, styrene-butadiene Examples of the polymerizable compound include ethylene block copolymers and hydrogenated products thereof, styrene-butadiene rubber, acrylonitrile-butadiene rubber, polybutadiene, polyisoprene, styrene-isoprene-styrene block copolymers and hydrogenated products thereof, polyolefin elastomers, polyester elastomers, polystyrene, acrylic resins, methyl methacrylate-styrene copolymers, acrylonitrile-styrene-methyl methacrylate copolymers, polyacetal resins, modified polyphenylene ether resins, ethylene-vinyl acetate copolymers, polyphenylene sulfide resins, polyphenylsulfone, polyether ketone, polyether ether ketone, polyethers, cycloolefin polymers, liquid crystal polyester resins, liquid crystal polymers, polyamides, fluororesins, polyvinylpyrrolidone, natural rubber, butyl rubber, polyisobutylene, and polysulfides.
[0064] Thermosetting resins are cured by heating through a polymerization reaction or a crosslinking reaction. Examples of thermosetting resins include phenolic resins, epoxy resins, melamine resins, urea resins, unsaturated polyester resins, alkyd resins, polyurethanes, thermosetting polyimides, and diallyl phthalate resins. Thermoplastic resins may also be blended with vulcanizing agents, curing agents, or crosslinking agents.
[0065] Photocurable resins are cured by irradiating them with light such as ultraviolet light, which causes a polymerization reaction or a crosslinking reaction to proceed. For example, they are prepared by blending a photoinitiator such as a photoradical generator, a photocation generator, a photoacid generator, or a photobase generator with a desired monomer or oligomer. Monomers or oligomers that can be used in the photocurable resin are not particularly limited, and examples thereof include (meth)acrylate monomers, (meth)acrylate oligomers, bisphenol A diglycidyl ether, hydrogenated bisphenol A diglycidyl ether, bisphenol F diglycidyl ether, cyclohexanedimethanol diglycidyl ether 3,4-epoxycyclohexylmethyl-3',4'-epoxycyclohexanecarboxylate, 1,2-epoxy-4-(2-oxiranyl)cyclohexane adduct of 2,2-bis(hydroxymethyl)-1-butanol; oxetane compounds such as xylylene bisoxetane and 3-ethyl-3-hydroxymethyloxetane; and vinyl ether monomers such as cyclohexanedimethanol divinyl ether, 2-ethylhexyl vinyl ether, cyclohexanedimethanol monovinyl ether, and 4-hydroxybutyl vinyl ether.
[0066] Other resins include silicone, acrylic silicone, modified silicone, lacquer, glue, petroleum resin, and hydrogenated petroleum resin; starch from rice, wheat, corn, potato, sweet potato, tapioca, and other natural products, or biodegradable plastics made from these.
[0067] When resin is used in the industrial pest control composition of the present invention, known resin additives can be added as necessary and mixed by known methods. Examples of resin additives include antioxidants, heat deterioration inhibitors, light stabilizers, lubricants, release agents, polymer processing aids, antistatic agents, flame retardants, dyes and pigments, light diffusing agents, organic dyes, matting agents, impact resistance modifiers, fluorescent substances, fillers, preservatives, anti-algae agents, pigment dispersants, plasticizers, drying accelerators, surfactants, defoamers, anti-skinning agents, low-temperature film-forming agents, film-forming aids, thickeners, leveling agents, dispersants, anti-settling agents, curing agents, curing aids, antifreeze agents, etc.
[0068] The industrial pest control composition of the present invention, the resin, and any known resin additives used as needed can be mixed using a known mixing or kneading device, such as a kneader-ruder, a single-screw or multi-screw extruder, a mixing roll, a Banbury mixer, etc. For liquid thermosetting resins or photocurable resins before curing, the industrial pest control composition of the present invention and any known resin additives used as needed can be mixed by tank blending.
[0069] The resin composition containing the industrial pest control composition of the present invention can be formed into a desired shape by a known molding method. The resin composition can also be added to, coated on, sprayed on, or impregnated into other materials. The solid resin composition can be mixed with or attached to other materials.
[0070] The molded article can be obtained by forming the resin composition into a desired shape by a known molding method, such as extrusion molding, injection molding, compression molding, blow molding, cast molding, layered molding, layered manufacturing, or powder molding.
[0071] A coating composition can be prepared using the industrial pest control composition or its resin composition of the present invention. The liquid coating composition can be applied to a substrate by a coating method such as brush coating, roll coating, bar coating, or spray coating, and then dried and cured as necessary to coat the substrate. The solid coating composition can be applied to a substrate by dusting, sheeting, or filming, and then pressing, fusing, or adhering the composition to coat the substrate.
[0072] The industrial pest control composition or its resin composition of the present invention can be used to prepare an adhesive composition or a paint composition. The adhesive composition or paint composition has properties suitable for adhesives or paints. Examples of properties include fluidity, adhesion, coatability, film-forming properties, blister resistance, adhesion, adhesiveness, sealing properties, and decorative properties. These properties can be achieved by appropriately selecting the type and amount of resin, type and amount of solvent, and type and amount of additives used.
[0073] The industrial pest control composition of the present invention, and its resin composition, coating composition, adhesive composition, or paint composition can be used in a variety of applications. Examples of the materials include bathroom interior materials, floor mats, wall sheets, wallpaper, shoji paper, flooring materials, handrail materials, ceiling materials, non-flammable wood, sealants, caulking agents, sealing agents, adhesives (acrylic, olefin, urethane, epoxy, natural), paints (oil-based paints, alcohol paints, NAD paints, electrodeposition paints, powder paints, cellulose paints, synthetic resin paints, water-based paints, lacquer-based paints, rubber-based paints, urethane-based paints, silicone-based paints, etc.), laminated lumber, decorative plywood and other wood materials, synthetic wood, artificial wood, recycled wood, heat insulation materials, heat-shielding materials, gypsum boards, and other building materials; films, sheets; exterior materials for buildings such as resin-based siding, ceramic-based siding, tiles, eaves materials, roofing materials, and exterior wall materials; starch paste, paper coating liquids, paints, adhesives, repair agents, ceramic materials, cement admixtures, and metal processing oils.
[0074] Examples of synthetic resin paints include phenolic resin paints, phthalic acid resin paints (e.g., alkyd resin paints, etc.), maleic acid resin paints, urea resin paints, melamine resin paints, vinyl resin paints (e.g., vinyl acetate resin paints, vinyl chloride resin paints, styrene resin paints, acrylic acid resin paints, polyvinyl butyral resin paints, etc.), epoxy resin paints, silicone resin paints, furan resin paints, polyester resin paints, urethane resin paints, nitrocellulose resin paints, amino resin paints, and fluororesin paints.
[0075] Examples of water-based paints include water-based paints, emulsion oil paints, and emulsion polymerization paints (e.g., vinyl acetate resin emulsion polymerization paints, vinylidene chloride vinyl chloride copolymer emulsion polymerization paints, acrylic acid resin emulsion polymerization paints, styrene resin emulsion polymerization paints, and synthetic rubber latex paints).
[0076] A molded article according to another embodiment of the present invention has a substrate and a layer made of the resin composition, adhesive composition or coating composition of the present invention laminated thereon. The substrate that can be used in the present invention is not particularly limited. Examples of substrates include general buildings, building materials, metals, rubber, wood, plastic products, fibers, cloth, paper, ceramics, concrete, blocks, bricks, etc. The layer made of the resin composition, adhesive composition, or coating composition of the present invention is resistant to color changes over time, so it does not impair the appearance and exhibits excellent pest control properties. Lamination to the substrate can be performed by known methods. Examples include multicolor extrusion molding, coated extrusion molding, adhesion, fusion, coating, spraying, powder molding, in-mold molding, and film insert molding.
[0077] The embodiments of the present invention will be described below based on the following examples, but the present invention is not limited to these examples. [Example]
[0078] The present invention will be described in more detail below with reference to examples, but the technical scope of the present invention is not limited to the examples below. [Example]
[0079] The bacterial growth inhibitory effect of iminoctadine albesilate plus antiseptic (BIT, HMIT, CMIT) was evaluated using the following method. Test drug: Bercut (registered trademark) Flowable Iminoctadine albesilate 30wt% BIT (1,2-benzisothiazol-3(2H)-one) Purity >98.0%, Tokyo Chemical Industry Co., Ltd. HMIT (2-methyl-4-isothiazolin-3-one) 50% aqueous solution, purity 98%, Bestside-750 (registered trademark) (CMIT (5-chloro-2-methyl-4-isothiazolin-3-one) + HMIT = 3.8%, CMIT:HMIT ≒ 3:1) Solvent: Dimethyl sulfoxide (DMSO), reagent grade, Wako Pure Chemical Industries Test strain: Staphylococcus aureus subsp. aureus (Staphylococcus aureus, NBRC12732) Size: 1 ward, 2 consecutive districts Drug solution preparation: Drugs other than BIT were dispersed or dissolved in a sterilized 0.05% Tween 20 aqueous solution (hereinafter referred to as the active agent solution), and 975 μL of this primary dilution solution was mixed with 25 μL of DMSO to prepare solutions of iminoctadine albesilate 31.25 mg / L, HMIT 4000 mg / L, or CMIT + HMIT 62.5 mg / L (each containing 2.5% DMSO). BIT was first dissolved in DMSO to a concentration of 20,000 mg / L, and 25 μL of this primary dilution solution was mixed with 975 μL of the activator solution to prepare a 500 mg / L BIT solution (DMSO 2.5%). These adjusted solutions were repeatedly diluted two-fold with the surfactant solution in a 96-well plate to prepare a dilution series. A new 96-well plate was prepared, and equal volumes of iminoctadine albesilate solution were mixed with BIT, HMIT, or CMIT + HMIT solutions. The total volume was 40 μL per well. To confirm the effect of DMSO on the test bacteria, a pattern was also set up in which the DMSO solutions were mixed together. Inoculation: Each strain was cultured in 9 mL of NB medium (test tube) at 31°C in the dark for 18 hours with shaking, and 0.5 mL of this culture medium + 50 mL of NB medium was used as the inoculum, and inoculated at 60 μL / well. Culture: The 96-well plate was cultured at 31°C in the dark for 7 days.
[0080] Investigation: The bacterial growth inhibitory effect was judged visually using the following criteria one day after the start (DMSO + DMSO), two days after (iminoctadine albesilate + [CMIT + HMIT]), or seven days after the start (iminoctadine albesilate + BIT, HMIT). The lowest concentration at which bacterial growth inhibition was observed in both n=1 and n=2 cases was defined as the MIC (minimum inhibitory concentration) (mg / L). +: No growth inhibition observed ±: Slight growth inhibition observed -: Growth inhibition observed
[0081] FIC index: Fractional Inhibitory Concentration index (partial inhibitory concentration) was calculated according to the following formula to confirm the presence or absence of synergistic action. FIC index = a / a0+ b / b0 a0: MIC of component A alone, b0: MIC of B component alone a: MIC of component A when component A and component B are used together b: MIC of component B when component A and component B are used together MIC: minimum inhibitory concentration FIC index>1 Antagonism FIC index=1 Additive effect FIC index<1 Synergistic effect Calculation example When the MIC value of component A is 100 mg / L and the MIC value of component B is 50 mg / L A 50mg / L + B 25mg / L has an inhibitory effect on bacterial growth → FIC index = 50 / 100 + 25 / 50 = 1 (additive effect) A 25 mg / L + B 25 mg / L has an inhibitory effect on bacterial growth → FIC index = 25 / 100 + 25 / 50 = 0.75 (synergistic effect)
[0082] The results are shown in Tables 1-1 to 1-4, 2-1 to 2-4, 3-1 to 3-4, and 4. Combinations of DMSO with other drugs showed no inhibition of bacterial growth at the highest concentration, confirming that the combination did not affect the drug test results. Combinations of iminoctadine albesilate with BIT, CMIT, or HMIT all showed synergistic effects. The "+", "±", and "-" symbols in the table have the following meanings: "+": No inhibition of bacterial growth observed "±": Slight inhibition of bacterial growth observed "-": Bacterial growth inhibition observed
[0083] (Iminoctadine albesilate + BIT (7 days after initiation)) [Table 1]
[0084] [Table 2]
[0085] [Table 3]
[0086] [Table 4]
[0087] (Iminoctadine albesilate + HMIT (7 days after initiation)
[0088] [Table 5]
[0089] [Table 6]
[0090] [Table 7]
[0091] [Table 8]
[0092] (Iminoctadine albesilate + [CMIT + HMIT] (2 days after starting)
[0093] [Table 9]
[0094] [Table 10]
[0095] [Table 11]
[0096] [Table 12]
[0097] (DMSO+DMSO (1 day after starting)) [Table 13] [Example]
[0098] The fungal growth inhibitory effect of iminoctadine albesilate plus the fungicide zinc pyrithione was evaluated by the following method. Test drug: Bercut (registered trademark) flowable iminoctadine albesilate 30.0 wt%, Biocut (registered trademark)-ZP Zinc pyrithione (bis(2-pyridylthio)zinc 1,1'-dioxide) ≥ 96.0 wt% Test strain: Alternaria alternata (NBRC 31188) Size: 1 ward, 2 consecutive districts Preparation of drug solution: The drug was dispersed in a sterilized 0.05% Tween 20 aqueous solution (hereinafter referred to as the surfactant solution) to prepare a solution containing 62.5 mg / L of iminoctadine albesilate and 250 mg / L of zinc pyrithione. These solutions were repeatedly diluted two-fold with the surfactant solution in a 96-well plate to prepare a dilution series. A new 96-well plate was prepared, and equal amounts of iminoctadine albesilate solution and zinc pyrithione solution were mixed together in a total volume of 40 μL / well. Inoculation: Add one drop of 30% solution of the nonionic surfactant Penelol N-100 (sterile) to 50 mL of sterile distilled water, add a few mL of this solution to a PDA (potato dextrose agar) slant medium on which the mold had been cultured, scrape the surface of the medium with a spatula to release the mold spores and mycelia, and return the solution to the original container. Sonicate this for 1 minute to disperse the spores and mycelia, then take 2 mL and mix with 50 mL of PDB (potato dextrose broth) to make the inoculum, and drop 60 μL into each well of a 96-well plate. Culture: The 96-well plate was cultured statically at 26°C in the dark for 7 days.
[0099] Investigation: Seven days after the start of the investigation, the mold growth inhibitory effect was judged under a microscope using the following criteria, and the lowest concentration at which growth inhibition was observed in both n=1 and n=2 was defined as the MIC (minimum inhibitory concentration) (mg / L). +: No growth inhibition observed ±: Slight growth inhibition observed -: Growth inhibition observed FIC index: Fractional Inhibitory Concentration index was calculated in the same manner as in Example 1 to confirm the presence or absence of synergistic action.
[0100] The results are shown in Tables 5-1 to 5-4. A synergistic effect was observed when iminoctadine albesilate was combined with the fungicide zinc pyrithione.
[0101] [Table 14]
[0102] [Table 15]
[0103] [Table 16]
[0104] [Table 17] [Example]
[0105] The algae growth inhibitory effects of iminoctadine albesilate and anti-algae agents (sibutrin, DCMU, prometryn, linuron) were evaluated by the following method. Drug: Bercut (registered trademark) flowable iminoctadine albesilate 30.0 wt%, Sibutrin bulk powder (2-(tert-butylamino)-4-(cyclopropylamino)-6-(methylthio)-1,3,5-triazine) Carmex D Wettable Powder DCMU (3-(3,4-dichlorophenyl)-1,1-dimethylurea) 80wt%, Maruwa Biochemical Gezaguard® 50 Prometryn (2-methylthio-4,6-bis(isopropylamino)-s-triazine) 50 wt% wettable powder, Nippon Kayaku Rorox® Wettable Powder Linuron (3-(3,4-dichlorophenyl)-1-methoxy-1-methylurea) 50wt%, Nippon Nohyaku Dimethyl sulfoxide (DMSO) Reagent Grade, Wako Pure Chemical Industries Test algae: Chlorella vulgaris Beijerinck var. vulgaris (NIES-686) Size: 1 ward, 2 consecutive districts Preparation of drug solution: Sibutrin bulk powder was removed and the drug was dispersed in a sterilized 62.5 mg / L Tween 20 aqueous solution (hereinafter referred to as the activator solution) to prepare a solution containing 15.625 mg / L iminoctadine albesilate, DCMU, prometryn and linuron at 31.25 mg / L. Sibutrin bulk powder was first dissolved in DMSO to a concentration of 5000 mg / L, and this was added to the activator solution to make a solution of 1.953125 mg / L. These solutions were repeatedly diluted two-fold with the surfactant solution in a 96-well plate to prepare a dilution series. A new 96-well plate was prepared, and an equal volume of iminoctadine albesilate solution and each anti-algicide solution were mixed together in a total volume of 80 μL per well. In addition, DMSO plates were also prepared to confirm whether or not DMSO, which was used to dissolve sibutrin, had any effect on the growth of Chlorella. Inoculation: 1 mL of algal culture medium + 50 mL of inorganic salt liquid medium was used as the inoculum, and 120 μL was inoculated into each well of a 96-well plate. Culture: Each plate was wrapped in parafilm to prevent evaporation, placed in a zippered polyethylene bag (Unipack F-4) with a wet Kimtowel, and placed under a fluorescent light source (2500-3500 Lux). Static culture was performed at 26°C for 18 days.
[0106] Survey: 18 days after the start of the survey, the algae growth inhibition effect was judged visually using the following criteria, and the lowest concentration at which growth inhibition was observed in both n=1 and n=2 was defined as the MIC (minimum inhibitory concentration) (mg / L). +: No growth inhibition observed ±: Slight growth inhibition observed -: Growth inhibition observed FIC index: Calculated in the same manner as in Example 1.
[0107] The results are shown in Tables 6-1 to 6-4, 7-1 to 7-4, 8-1 to 8-4, 9-1 to 9-4 and 10. DMSO was not found to inhibit algae growth and was confirmed not to affect the test results of the chemicals (Table 10). A synergistic effect was observed when iminoctadine albesilate was combined with the anti-algicides sibutrin, DCMU, prometryn, or linuron.
[0108] (Iminoctadine albesilate + Sibutrine) [Table 18]
[0109] [Table 19]
[0110] [Table 20]
[0111] [Table 21]
[0112] (Iminoctadine albesilate + DCMU) [Table 22]
[0113] [Table 23]
[0114] [Table 24]
[0115] [Table 25]
[0116] (Iminoctadine albesilate + Prometryne) [Table 26]
[0117] [Table 27]
[0118] [Table 28]
[0119] [Table 29]
[0120] (Iminoctadine albesilate + linuron) [Table 30]
[0121] [Table 31]
[0122] [Table 32]
[0123] [Table 33]
[0124] (DMSO only) [Table 34]
Claims
1. An industrial pest control composition containing iminoctadine albesilate and another industrial pest control agent.
2. Other industrial pest control agents include 1,2-benzisothiazol-3(2H)-one, 2-methyl-4-isothiazolin-3-one, 5-chloro-2-methyl-4-isothiazolin-3-one, bis(2-pyridylthio)zinc 1,1'-dioxide, 2-(tert-butylamino)-4-(cyclopropylamino)-6-(methylthio)-1,3,5-triazine, 3-(3,4-dichlorophenyl)-1,1-dimethylurea, 2-methylthio-4,6-bis(isopropylamino)-s-triazine, and 3-(3,4-dichlorophenyl)-1-methoxy-1-methylurea The industrial pest control composition according to claim 1, which is at least one selected from the following:
Citation Information
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