Method for controlling weeds in field of herbicide-resistant crops

Abstract

To provide a method for controlling weeds that occur in a field where herbicide-resistant crops are cultivated.SOLUTION: A method for controlling weeds in a field of at least one herbicide-resistant crop selected from the group consisting of corn and soybean comprises: sowing seeds of the herbicide-resistant crop; and treating the field of the herbicide-resistant crop with at least one herbicide selected from the group consisting of flumioxazin, epyrifenacil, and the compounds represented by the Compounds X1 to X3 in the figure, where the herbicide-resistant crop has a bacterial PPO gene.SELECTED DRAWING: None

Description

[Technical Field]

[0001] The present invention relates to a method for controlling weeds in areas where herbicide-resistant crops are cultivated. [Background technology]

[0002] Currently, many herbicides are used for the purpose of weed control, and for example, flumioxazin and epirifenacil are known (see Patent Documents 1-2 and Non-Patent Document 1), and compounds represented by the present compounds X1-X3 shown below are known (see Patent Documents 4-6). Also known is a method of controlling weeds by combining crops that have been made resistant to specific herbicides by genetic engineering technology (herbicide-resistant crops) with specific herbicides (see Patent Documents 7-11 and Non-Patent Documents 2-4). [Prior art documents] [Patent documents]

[0003] [Patent Document 1] U.S. Patent No. 4,640,707 [Patent Document 2] U.S. Patent No. 6,537,948 [Patent Document 3] U.S. Patent No. 6,403,534 [Patent Document 4] International Publication No. 2023 / 228935 [Patent Document 5] International Publication No. 2023 / 249039 [Patent Document 6] U.S. Patent Application Publication No. 2020 / 0315173 [Patent Document 7] US Patent Application Publication No. 2019 / 0241903 [Patent Document 8] International Publication No. 2023 / 150754 [Patent Document 9] International Publication No. 2024 / 137408 [Patent Document 10] International Publication No. 2025 / 128414 [Non-patent literature]

[0004] [Non-Patent Document 1] Pest Manag. Sci. 81 (2025), 2463-2468 [Non-patent document 2] Pest Manag. Sci. 75 (2019), 2086-2094 [Non-patent document 3] Pest Manag. Sci. 76 (2020), 1031-1038 [Non-patent document 4] Pest Manag. Sci. 78 (2022), 2816-2827 Summary of the Invention [Problem to be solved by the invention]

[0005] An object of the present invention is to provide a method that is highly effective in controlling weeds in areas where herbicide-resistant crops are cultivated. [Means for solving the problem]

[0006] The present invention relates to a method for controlling weeds that appear in a field where herbicide-resistant crops are cultivated, by using at least one herbicide selected from the group consisting of flumioxazin, epirifenacil, and the present compounds X1 to X3 shown below in combination with the herbicide-resistant crops. The present invention includes the following aspects.

[0007] [1] A method for controlling weeds in a field where at least one herbicide-resistant crop selected from the group consisting of corn and soybean is cultivated, the method comprising the steps of sowing seeds of the herbicide-resistant crop and treating the field where the herbicide-resistant crop is cultivated with at least one herbicide selected from the group consisting of flumioxazin, epirifenacil, and the present compounds X1 to X3 shown below, wherein the herbicide-resistant crop has a bacterial PPO gene. [ka] (Hereinafter, this compound will be referred to as "the present compound X1" in the specification.) [ka] (Hereinafter referred to as "the present compound X2" in the specification) [ka] (Hereinafter referred to as "the present compound X3" in the specification) [2] The method according to [1], wherein the herbicide-resistant crop is a maize strain Zm_CSM63715 or MON80616 having a bacterial PPO gene. [3] The method according to [2], wherein the herbicide-resistant crop is a maize line that is a cross between the Zm_CSM63715 line or the MON80616 line and the MON87429 line having the ft_t gene, the cp4 epsps gene, the pat gene, and the dmo gene. [4] The method according to [1], wherein the herbicide-resistant crop is a soybean strain Gm_CSM63717 or MON91445 having a bacterial PPO gene. [5] The method according to [4], wherein the herbicide-tolerant crop is a soybean line that is a cross between the Gm_CSM63717 line or the MON91445 line and the Gm_CSM63714 line that has the ft_tv7 gene, the tdo gene, the pat gene, and the dmo gene. [6] The method according to [4], wherein the herbicide-resistant crop is a soybean line that is a cross between the Gm_CSM63717 line or the MON91445 line and the MON89788 line having the cp4 epsps gene. [7] The method according to [4], wherein the herbicide-resistant crop is a soybean line that is a cross between the Gm_CSM63717 line or the MON91445 line and the MON89788 line and the MON89788 line. [Effects of the Invention]

[0008] The weed control method of the present invention makes it possible to control weeds in areas where herbicide-resistant crops are cultivated. DETAILED DESCRIPTION OF THE INVENTION

[0009] The weed control method of the present invention includes the steps of sowing seeds of herbicide-resistant crops and applying a herbicide to a cultivated field of the herbicide-resistant crops.

[0010] The weed control method of the present invention (hereinafter referred to as the method of the present invention) comprises: (1) a step of sowing seeds of herbicide-resistant crops (hereinafter sometimes referred to as step (1)); and (2) The method includes a step of treating a cultivated area of ​​herbicide-resistant crops with at least one compound selected from the group consisting of flumioxazin, epirifenacil, and the present compounds X1 to X3 before, simultaneously with, and / or after sowing seeds of the herbicide-resistant crops (hereinafter, sometimes referred to as step (2)).

[0011] Flumioxazin is a known compound and can be prepared by known methods, such as the method described in U.S. Pat. No. 4,640,707. Epirifenacil is a known compound and can be prepared by known methods, such as the method described in U.S. Pat. No. 6,537,948.

[0012] The present compound X1 is a known compound and can be produced by known methods, such as the method described in U.S. Pat. No. 6,403,534. The present compound X2 is a known compound and can be produced by known methods, such as the method described in WO 2023 / 228935. The present compound X3 is a known compound and can be produced by known methods, such as the method described in WO 2023 / 249039. Hereinafter, flumioxazin, epirifenacil, and the present compounds X1 to X3 may be collectively referred to as the compounds of the present invention.

[0013] Herbicide-tolerant crops that can be used in the method of the present invention include corn and soybean (hereinafter, these two herbicide-tolerant crops may be collectively referred to as the crops of the present invention).

[0014] The corn (Zea mays) of the present invention may be of any maturity group, from early to late maturity, and is most commonly dent corn, but may also be flint corn, flower corn, popcorn, waxy corn, sweet corn, etc. Also very commonly, it is field corn, a complex consisting primarily of dent and hard corn varieties and their hybrids. In either case, the corn variety is usually a hybrid variety. The soybean (Glycine max) crop of the present invention may be of any maturity group, such as early to late maturity; the growth type (determinate, determinate, or semi-determinate) is not important, but determinate is preferred; the growth type (creeping or shrub) is not important, but shrub is preferred; the cotyledon color (yellow or green) is not important, but yellow is preferred; and the seed coat color (colorless, black, green, or brown) is not important, but colorless is preferred. Any of the above soybeans may be green-harvested varieties that are harvested young, or edamame varieties, but varieties from which fully ripe seeds are harvested are preferred. Furthermore, the method of the present invention is not limited by the various uses to which the harvested product of the crop of the present invention is provided. For example, the harvested product of the crop of the present invention may be used for any of seed production, ornamental purposes, green manure, silage, grain production, fiber, etc. Furthermore, the crop of the present invention can be used for any of the following purposes, primarily for grain processing: starch production, ethanol refining, brewing, oil extraction, feed, sugar production, and food. Corn, a crop of the present invention, is primarily grown for its grains and is used for feed and ethanol refining. Soybean, a crop of the present invention, is primarily grown for its grains and is used for feed and oil extraction.

[0015] Examples of corn crops of the present invention include, but are not limited to, the Zm_CSM63715 or MON80616 strains, which have a bacterial PPO gene. The bacterial PPO gene possessed by the Zm_CSM63715 or MON80616 strains is known in patent literature (WO 2024 / 137408) or non-patent literature (Pest Manag. Sci. 76 (2020), 1031-1038, Pest Manag. Sci. 78 (2022), 2816-2827), and is the H_N90 gene (GenBank accession number MN102108) derived from Enterobacter cloacae. Because these PPO genes are all derived from bacteria, they are also known as the HemG gene in bacterial genetics.

[0016] The corn crop of the present invention may be a line resulting from crossing the Zm_CSM63715 or MON80616 line with the MON87429 line. The MON87429 line is a line (event) known in the GMO Approval Database provided by the International Agri-Biotechnology Agency (https: / / www.isaa.org / ). It is a genetically modified herbicide-tolerant corn strain containing the pat gene from Streptomyces viridochromogenes, the dmo gene from Stenotrophomonas maltophilia strain DI-6, the cp4 epsps gene from Agrobacterium tumefaciens strain CP4, and the ft_t gene from Sphingobium herbicidovorans. Each gene confers tolerance to glufosinate, dicamba, glyphosate, and quizalofop-ethyl, and its sequence can be found in U.S. Patent Application Publication No. 2019 / 0241903. Of these, ft_t is also publicly known in non-patent literature (Pest Manag. Sci. 75 (2019), 2086-2094) and is also known by other names such as AAD and RpdA.

[0017] Examples of soybean crops of the present invention include, but are not limited to, the Gm_CSM63717 or MON91445 strains that have a bacterial PPO gene. The bacterial PPO gene of the Gm_CSM63717 strain is known in patent literature (WO 2025 / 128414) or non-patent literature (Pest Manag. Sci. 76 (2020), 1031-1038, Pest Manag. Sci. 78 (2022), 2816-2827), and is the H_N90 gene (GenBank accession number MN102108) derived from Enterobacter cloacae. The PPO genes possessed by the MON91445 strain are publicly known on the Canadian Food Inspection Agency (CFIA) website (https: / / inspection.canada.ca / en / plant-health / plant-varieties / novel-traits / notices-submission / mon-94115). Because these PPO genes are all derived from bacteria, they are also known as HemG genes in bacterial genetics.

[0018] The soybean crop of the present invention may be a line obtained by crossing the Gm_CSM63717 line or the MON91445 line with the Gm_CSM63714 line and / or the MON89788 line. The Gm_CSM63714 line is known in patent literature (WO 2025 / 128414 or WO 2023 / 212564) and contains the pat gene, dmo gene, FT-Tv7 gene (sometimes referred to as the ft_t.1 gene), and tdo gene. The FT-Tv7 gene is known in non-patent literature (Pest Manag. Sci. 75 (2019), 2086-2094) and confers tolerance to 2,4-D in soybeans. In this specification, the FT-Tv7 gene in soybeans and the ft_t gene in maize are collectively referred to as the FT_T gene. The tdo gene has been disclosed in a non-patent document (Pest Manag. Sci. 78 (2022), 2816-2827) as a modified version of the HIS1 gene derived from japonica rice (GenBank accession number ON092642), and confers resistance to triketone HPPD inhibitors such as mesotrione.

[0019] The MON89788 line is a known line in the GMO Approval Database and contains the cp4 epsps gene, which confers tolerance to glyphosate.

[0020] Specific lines of the above-mentioned crops of the present invention are those obtained by crossing the Zm_CSM63715 line or the MON80616 line with the MON87429 line according to patent documents (WO 2024 / 137408, WO 2025 / 128414). Lines having bacterial PPO genes, pat genes, dmo genes, cp4 epsps genes, and ft_t genes are called HT5 corn, and lines having bacterial PPO genes, pat genes, dmo genes, cp4 epsps genes, FT_T genes, and tdo genes are called HT5 soybeans. HT5 corn and HT5 soybeans into which an ikaphorin methyl resistance gene has been further introduced can also be used as crops of the present invention.

[0021] When introducing multiple genes into a gene recombination process, the transgenes are arranged in tandem within a vector. A promoter is typically located 5' upstream of the aligned genes and a terminator is typically located 3' downstream. Each gene may contain a signal protein coding sequence upstream followed by an enzyme domain coding sequence downstream, or it may contain only the enzyme domain coding sequence. Examples of signal proteins include plastid targeting peptides and mitochondrial targeting peptides. For example, non-patent literature (Pest Manag. Sci. 75 (2019), 2086-2094, Pest Manag. Sci. 76 (2020), 1031-1038) discloses examples in which plastid targeting peptides are added to both the FT_T gene and the bacterial PPO gene. Such sequences inserted into a vector are sometimes referred to as expression cassettes. The structure and sequence of the expression cassettes can be confirmed in preserved samples of each strain deposited at genetic resource preservation institutions such as the American Type Culture Collection (ATCC).

[0022] In the method of the present invention, the term "line" (event) is a term used in genetic engineering. In a genetic engineering operation, typically, one copy of a specific gene or genes is introduced into a single cell of a specific variety (or multiple genes, respectively). The cell regenerates, resulting in an individual plant, which then self-fertilizes and produces a homozygous seed population at the introduced gene locus. This is one physically recognizable form of the "line." Unlike green plants or cells, such seed populations are easily viable over the years, making them suitable for preserving lineages. Furthermore, since essentially the same genome can be reproduced by self-fertilization, they are also suitable for maintaining lineages. Different seed populations obtained by repeating the same genetic engineering operation using the same material are considered to be different lineages, even if they share the same genes and phenotype. Furthermore, multiple cells may be introduced with genes during a single operation, resulting in multiple individuals (and subsequently, multiple seed populations) derived from each of these, but these are still considered to be different lineages. This is because the introduction site on the genome usually differs depending on the opportunity for gene introduction. Even if precise manipulation using new breeding techniques (NBT) such as CRISPR-CAS9 allows genes to be introduced into the same location on the genome of multiple cells, the cells that receive the gene are different, and the lineages of subsequent cell culture and redifferentiation will not be identical, so they will be considered separate lineages. Because the identity of the "opportunity" for gene introduction identifies a lineage, another name for a lineage is called an "event."

[0023] The above article states that, for example, in the case of soybeans, one specific line name can be selected as one of the optimal ones, while at the same time there can be various varieties (elongation type, seed coat color, etc.). This is due to the following mechanism. The developed line is then used as a breeding mother for crossbreeding. For example, even if an indeterminate soybean is used to create a line, a determinate variety carrying an introduced gene can be produced by crossbreeding that line with a non-recombinant determinate variety. Similarly, varieties of various maturity groups carrying an introduced gene can also be produced, although they belong to the indeterminate type of the same variety group. For these reasons, it is sometimes said that a lineage is "comprise" in each variety. Therefore, commercially cultivated lines are usually commonly possessed in many varieties. Practicing the method of the present invention in a specific lineage encompasses and discloses its implementation in all varieties that possess that lineage. Furthermore, in the variety thus cultivated, it is also possible to refer to a plant, cell, or the like that possesses a specific lineage. In light of the above-mentioned meaning of "a seed population is one form of a lineage," it may seem strange to say that there are seeds within cells, but such a seed population is also understood to possess a lineage. Lines may also be given specific trademarks. For example, the soybean line MON89788 is trademarked "Genuity® Roundup Ready 2 Yield™" (GMO Approval Database). Various soybean varieties are referred to as Genuity® Roundup Ready 2 Yield™ soybeans (the actual variety name is further identified by a different symbol, e.g., AG25X9), and individual plants are referred to as Genuity® Roundup Ready 2 Yield™ soybeans because of this usage of the term "line," and are understood to be soybeans that possess the Genuity® Roundup Ready 2 Yield™ line.

[0024] The crops of the present invention may be conferred with a pest resistance trait using genetic engineering techniques, either by crossing with the commercial lines listed below or by introducing genes contained in those lines.

[0025] An example of a plant that has been conferred resistance to lepidopteran pests through genetic engineering technology is the crop of the present invention, into which a gene encoding delta-endotoxin, an insecticidal protein derived from the soil bacterium Bacillus thuringiensis (hereinafter referred to as Bt bacteria), has been introduced. Delta-endotoxins that confer resistance to lepidopteran pests include, for example, Cry1A, Cry1Ab, modified Cry1Ab (Cry1Ab with a deleted portion), Cry1Ac, Cry1Ab-Ac (a hybrid protein in which Cry1Ab and Cry1Ac are fused), Cry1C, Cry1F, Cry1Fa2 (modified Cry1F), moCry1F (modified Cry1F), Cry1A.105 (a hybrid protein in which Cry1Ab, Cry1Ac, and Cry1F are fused), Cry2Ab2, Cry2Ae, Cry9C, Vip3A, and Vip3Aa20. An example of a plant that has been conferred resistance to coleopteran pests through genetic engineering is corn into which a gene encoding a delta-endotoxin, an insecticidal protein derived from the soil bacterium Bt, has been introduced. Examples of delta-endotoxins that confer resistance to coleopteran pests include Cry3A, mCry3A (modified Cry3A), Cry3Bb1, Cry34Ab1, Cry35Ab1, Cry6A, Cry6Aa, and mCry6Aa (modified Cry6Aa). Examples of plants that have been conferred resistance to dipteran pests through genetic engineering include maize (Zea mays L.) into which a synthetic gene encoding the hybrid protein eCry3.1Ab, which combines Cry3A and Cry1Ab derived from the soil bacterium Bt, has been introduced, and cotton (Gossypium hirsutum L.) into which a gene encoding the trypsin inhibitor CpTI derived from cowpea (Vigna unguiculata) has been introduced. An example of a plant that has been conferred resistance to nematodes through genetic engineering is soybean (Glycine max L.) into which a gene encoding Cry14Ab-1.b derived from the soil bacterium Bt has been introduced. Insecticidal proteins that confer pest resistance to plants also include hybrid proteins, partially deleted proteins, and modified proteins of the above insecticidal proteins. Hybrid proteins are produced using genetic engineering by combining different domains of multiple insecticidal proteins, and known examples include Cry1Ab-Ac and Cry1A.105. Known examples of partially deleted proteins include Cry1Ab, which lacks a portion of its amino acid sequence. Known modified proteins include proteins in which one or more amino acids of natural delta-endotoxin have been replaced, such as Cry1Fa2, moCry1F, and mCry3A. Modified proteins also include toxins in which a non-naturally occurring protease recognition sequence has been inserted, such as Cry3A055 (see WO2003 / 018810), in which a cathepsin G recognition sequence has been inserted into Cry3A toxin. Using genetic engineering technology, a soybean called "Intacta (trademark) Roundup Ready (trademark) 2 Pro" has been developed that expresses the insecticidal protein Cry1Ac derived from the modified Bt protein, Bt bacteria. Monsanto has developed cotton (event MON88702) that incorporates a modified BT protein, Cry51Aa2 (Cry51Aa2.834_16), using genetic engineering technology. This cotton exhibits resistance to lygus species such as Lygus lineolaris, Hemiptera such as aphids, and thrips such as Frankliniella species. Other insecticidal proteins that confer pest resistance to plants by genetic engineering include, for example, insecticidal proteins derived from Bacillus cereus or Bacillus popilliae; plant insecticidal proteins Vip1, Vip2, Vip3 (subclasses Vip3Aa to Vip3Aj, Vip3Ba, Vip3B, and Vip3Ca are known, and specific examples include Vip3Aa20 and Vip3Aa61) and Vip4; insecticidal proteins derived from Photorhabdus spp. such as Photorhabdus luminescens or Xenorhabdus nematophilus; insecticidal proteins from bacteria that are symbiotic (colonize) with nematodes, such as Pseudomonas spp.; toxins produced by animals, including insect-specific neurotoxins such as scorpion toxins, spider toxins, and wasp toxins; toxins produced by filamentous fungi, such as Streptomycetes toxins; plant lectins, such as pea lectin, barley lectin, and snowdrop lectin; agglutinins; protease inhibitors, such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin, and papain inhibitors; ricin, corn-RIP, abrin, These include ribosome-inactivating proteins (RIPs) such as ruffin, saporin, and bryodin; steroid metabolic enzymes such as 3-hydroxysteroid oxidase, ecdysteroid-UDP-glucosyltransferase, and cholesterol oxidase; ecdysone inhibitors; HMG-CoA-reductase; ion channel inhibitors such as sodium channel inhibitors and calcium channel inhibitors; juvenile hormone esterase; diuretic hormone receptor; stilbene synthase; bibenzyl synthase; chitinase; and glucanase.

[0026] Furthermore, plants that have been conferred pest resistance by introducing one or more insecticidal protein genes are already known, and some of these plants are commercially available. Examples of cotton that has been given pest resistance include "Bollgard™ cotton," "BXN™ Plus Bollgard™ Cotton," "BXN™ Plus Bollgard™ Cotton," "JK 1," "Roundup Ready™ Bollgard™ Cotton," and "Ingard™," which express the insecticidal protein Cry1Ac derived from Bt bacteria; "Herculex™ I" and "Herculex™ CB," which express the insecticidal protein modified Cry1F (Cry1Fa2) derived from Bt bacteria; "VIPCOT™ Cotton," which expresses the insecticidal protein Vip3A derived from Bt bacteria; "Bollgard II™ cotton," "Roundup Ready™ Bollgard II™ Cotton," and "Roundup Ready™ Flex™ Bollgard II™," which express the insecticidal proteins Cry1Ac and Cry2Ab derived from Bt bacteria. Cotton" and "Fivermax™ Liberty Link™ Bollgard II™"; "Bollgard III™" and "Bollgard™ III x Roundup Ready™ Flex™" expressing the insecticidal proteins Cry1Ac, Cry2Ab, and Vip3A derived from Bt bacteria; "VIPCOT™ Roundup Ready Flex™ Cotton" expressing the insecticidal proteins Vip3A and Cry1Ab derived from Bt bacteria; "VIPCOT™ Cotton" expressing the insecticidal proteins Vip3A and Cry1Ac derived from Bt bacteria; "WideStrike™ Cotton", "WideStrike™ Roundup Ready™ Cotton" and "Widestrike™ Roundup Ready Flex™ Cotton" expressing the insecticidal proteins Cry1Ac and Cry1F derived from Bt bacteria;These include "TwinLink™ Cotton" and "Glytol™ x Twinlink™", which express the insecticidal proteins Cry1Ab and Cry2Ae derived from Bt bacteria; "Widestrike™ 3" and "Widestrike™ x Roundup Ready Flex™ x VIPCOT™ Cotton", which express the insecticidal proteins Cry1Ac, Cry1F, and Vip3A derived from Bt bacteria; and "Glytol™ x Twinlink™ x VIPCOT™ Cotton", which expresses the insecticidal proteins Cry1Ab, Cry2Ae, and Vip3A derived from Bt bacteria, all of which are commercially available. Examples of maize to which pest resistance has been imparted include "YieldGard (registered trademark) Rootworm RW," "YieldGard (trademark) RW + RR," "YieldGard (trademark) VT (trademark) Rootworm (trademark) RR2," and "MaxGard (trademark)," which express the insecticidal protein Cry3Bb1 derived from Bt bacteria; "YieldGard (trademark) VT Triple" and "YieldGard (trademark) Plus with RR," which express the insecticidal protein Cry3Bb1 and Cry1Ab derived from Bt bacteria; "Bt Xtra (trademark) Maize," which expresses the insecticidal protein Cry1Ac derived from Bt bacteria; "YieldGard Plus (registered trademark)," which expresses the insecticidal protein Cry1Ab and Cry3Bb1 derived from Bt bacteria; "Bt10" and "Liberty Link (trademark) Yieldgard (trademark)," which express the insecticidal protein Cry1Ab derived from Bt bacteria. Maize, Agrisure™ GT / CB / LL, and YieldGard™ CB + RR; containing the insecticidal protein Cry1A derived from Bt bacteria.YieldGard™ VT Pro™ and Genuity™ VT Double Pro™ expressing 105 and Cry2Ab2; Agrisure™ RW and Agrisure™ GT / RW expressing the insecticidal protein mCry3A derived from Bt bacteria; Starlink™ Maize expressing the insecticidal protein Cry9C derived from Bt bacteria; YieldGard™, MaizeGard™, NaturGard KnockOut™, Maximizer™, Roundup Ready™ YieldGard™ maize, Agrisure™ CB / LL, and Mavera™ YieldGard™ expressing the insecticidal protein Cry1Ab derived from Bt bacteria. Maize; Agrisure (registered trademark) 3122 expressing the insecticidal proteins Cry1Ab, Cry1F, modified Cry3A, Cyr34Ab1, and Cyr35Ab1 derived from Bt bacteria; Agrisure (registered trademark) Viptera expressing the insecticidal protein Vip3Aa20 derived from Bt bacteria; Agrisure (registered trademark) Viptera 2100 and Agrisure (registered trademark) Viptera 3110 expressing the insecticidal proteins Vip3Aa20 and Cry1Ab derived from Bt bacteria; Agrisure (registered trademark) Viptera 3100, Agrisure (registered trademark) Viptera 3111, and Agrisure (registered trademark) Viptera 3112 expressing the insecticidal proteins Vip3Aa20, Cry1Ab, and modified Cry3A derived from Bt bacteria. "Agrisure (registered trademark) Viptera (trademark) 3220" expressing the insecticidal proteins Vip3Aa20, Cry1Ab, and modified Cry1F derived from Bt bacteria; "Agrisure (registered trademark) Duracade (trademark)" expressing the insecticidal protein eCry3.1Ab (a chimeric protein of Cry3A-Cry1Ab) derived from Bt bacteria; and "Agrisure (registered trademark) Duracade (trademark)" expressing the insecticidal protein eCry3.1Ab derived from Bt bacteria.Agrisure (registered trademark) Duracade (trademark) 5122 expresses the insecticidal protein eCry3.1Ab (a chimeric protein of Cry3A-Cry1Ab), modified Cry3A, Cry1Ab, and modified Cry1F; Agrisure (registered trademark) Duracade (trademark) 5222 expresses the insecticidal protein eCry3.1Ab (a chimeric protein of Cry3A-Cry1Ab), modified Cry3A, modified Cry1Ab, and a Vip3A variant derived from Bt bacteria; Herculex (trademark) RW expresses the insecticidal proteins Cyr34Ab1 and Cyr35Ab1 derived from Bt bacteria; and Herculex XTRA expresses the insecticidal proteins Cyr34Ab1, Cyr35Ab1, and Cry1F derived from Bt bacteria. (trademark)"; "Genuity (registered trademark) VT Triple Pro (trademark)" expressing insecticidal proteins Cry1A.105, Cry2Ab2, and Cry3Bb1 derived from Bt bacteria; "Genuity (registered trademark) SmartStax (trademark)" expressing insecticidal proteins Cry1F, Cry2Ab, Cyr34Ab1, Cyr35Ab1, Cry3Bb1, and Cry1A.105 derived from Bt bacteria; "Power Core (trademark)" expressing insecticidal proteins modified Cry1F, Cry2Ab, and Cry1A.105 derived from Bt bacteria; and "Herculex XTRA (trademark)" expressing insecticidal proteins modified Cry1F, Cyr34Ab1, and Cyr35Ab1 derived from Bt bacteria. These are commercially available, including "Optimum (registered trademark) Intrasect Xtreme" which expresses the insecticidal proteins modified Cry1F, Cyr34Ab1, Cyr35Ab1, Cry1Ab, and modified Cry3A derived from Bt bacteria; "Optimum (registered trademark) Intrasect XTRA" which expresses the insecticidal proteins modified Cry1F, Cyr34Ab1, Cyr35Ab1, and Cry1Ab derived from Bt bacteria; and "Optimum (registered trademark) TRIsect" which expresses the insecticidal proteins modified Cry1F and modified Cyr3A derived from Bt bacteria. Another example of a plant that has been conferred pest resistance is the soybean "Intacta™ Roundup Ready™ 2 Pro," which expresses the insecticidal protein Cry1Ac derived from Bt bacteria, and is commercially available. Also available are corn rootworm-resistant corn varieties "YieldGard corn rootworm," "YieldGard VT," "Herculex RW," "Herculex Rootworm," and "Agrisure CRW"; corn borer-resistant corn varieties "YieldGard corn borer," "YieldGard plus," "YieldGard VT Pro," "Agrisure CB / LL," "Agrisure 3000GT," "Hercules I," "Hercules II," "KnockOut," "NatureGard," and "StarLink"; western bean cutworm-resistant corn varieties "Herculex I," "Herculex Xtra," "NewLeaf," "NewLeaf Y," and "NewLeaf Plus"; corn borer-resistant corn varieties "YieldGard Plus"; and cotton varieties "Bollgard I" and "Bollgard" resistant to tobacco budworm. Known varieties include "Bollgard II", "WideStrike (trademark)", and "VipCot" cotton varieties that are resistant to tobacco budworm, cotton bollworm, fall armyworm, beet armyworm, cabbage looper, soybean looper, and pink bollworm; "NewLeaf", "NewLeaf Y", and "NewLeaf Plus" potatoes that are resistant to tobacco hornworm; and "Bt brinjal", "Dumaguete Long Purple", and "Mara" eggplant varieties that are resistant to eggplant borer, fruit borer, and cotton bollworm (see, e.g., U.S. Pat. No. 5,128,130).

[0027] Plants that have been made pest-resistant using RNA interference technology include corn that is resistant to Lepidoptera pests (e.g., corn borers, corn earworms, cutworms such as black cutworms, and fall armyworms) and Coleoptera pests (corn rootworms), and are commercially available or under development under the trade names "SmartStax®," "SmartStax® Pro," or "Genuity® SmartStax Pro."

[0028] Examples of plants that have been conferred pest resistance through conventional breeding techniques or genomic breeding techniques include soybeans that are resistant to the soybean aphid (Aphis glycines) and contain the aphid resistance genes "Rag1 (Resistance to Aphis glycines 1)" or "Rag2 (Resistance to Aphis glycines 2)" (see J. Econ. Entomol., 2015, 108, 326); soybeans that are resistant to the soybean cyst nematode (Heterodera glycines) (see Phytopathology, 2016, 106, 1444); and cotton that is resistant to the root-knot nematode (Meloidogyne incognita) (J. Nematol., 2009, 41, 140).

[0029] In the step (1) of sowing seeds of the crop of the present invention in the method of the present invention, the seeds are usually sown in an outdoor field. At this time, the seeds of the crop of the present invention may be seed-treated with at least one pesticide or agricultural material selected from the group consisting of neonicotinoid compounds, diamide compounds, carbamate compounds, organophosphate compounds, biological nematicide compounds, other insecticides and nematicide compounds, as well as azole compounds, strobilurin compounds, metalaxyl compounds, SDHI compounds, other fungicide compounds, plant growth regulators, nitrogen-fixing bacteria, and mycorrhizal fungi. The field in step (1) may be one that has been tilled in advance (a field where tillage cultivation is performed), one that has not been tilled in advance (a field where no-till cultivation is performed), or a field where strip-till cultivation, which combines these, or minimum-till cultivation, which involves minimal tillage, is performed. The field in step (1) is preferably a field where no-till cultivation is performed. In no-till cultivation, a cover crop may be sown after the harvest of the previous crop.

[0030] In step (2) of applying the compound of the present invention to the cultivated land of the present crop, the compound of the present invention is usually mixed with a carrier such as a solid carrier or a liquid carrier, and further, if necessary, formulation adjuvants such as surfactants are added, and the compound is used in the form of a formulation or a dilution thereof. When the compound of the present invention is formulated, preferred dosage forms are aqueous liquid suspension concentrates (SC), water dispersible dusts (WP), water dispersible granules (WG), granules (GR), aqueous emulsion concentrates (EW), oil emulsion concentrates (EO), suspoemulsions (SE), and emulsifiable concentrates (EC). In one embodiment, when the compound of the present invention is formulated, aqueous liquid suspension concentrates (SC) and water dispersible granules (WG) are preferred. In another embodiment, when the compound of the present invention is flumioxazin, aqueous liquid suspension concentrates (SC) and water dispersible granules (WG) are preferred. In another embodiment, when the compound of the present invention is epirifenacil or the present compounds X1 to X3, aqueous emulsion concentrates (EW) and emulsifiable concentrates (EC) are preferred. In yet another embodiment, when the compound of the present invention is formulated, a suspoemulsion (SE) is preferred, in which epirifenacil or one to three of the compounds represented by X1 to X3 are dispersed in water in a solvent-dissolved state, and the remaining compounds of the present invention or other agricultural chemicals are suspended as solids. In another embodiment, when a formulation containing both flumioxazin and epirifenacil is prepared, a suspoemulsion (SE) is preferred, in which epirifenacil is dispersed in water in a solvent-dissolved state, and flumioxazin technical substance is suspended as a solid. In step (2), a formulation containing the compound of the present invention as the sole ingredient may be used alone, or it may be mixed (tank-mixed) with a formulation containing another herbicide as an active ingredient. Furthermore, a formulation containing the compound of the present invention and another herbicide as an active ingredient may be used, or a formulation containing the compound of the present invention and another herbicide as an active ingredient may be mixed (tank-mixed) with a formulation containing another herbicide as an active ingredient.

[0031] Although epirifenacil is known to exist in multiple crystalline polymorphs with different crystal structures, the crystals described in WO 2018 / 012573 are suitable for use in the method of the present invention. Although flumioxazin is known to exist in multiple crystalline polymorphs with different crystal structures, the crystals described in WO 2013 / 122241 are suitable for use in the method of the present invention. When the crystals of the compound of the present invention are formulated into aqueous liquid suspensions (SC), oily liquid suspensions (OD), wettable powders (WP), suspoemulsions (SE), or water dispersible granules (WG), the volume median diameter of the crystal particles is typically 0.1 to 10 μm, preferably 0.2 to 5 μm, more preferably 1 to 4 μm, and even more preferably 2 to 3 μm. Aqueous liquid suspensions (SC) with a volume median diameter of 2 to 3 μm are particularly preferred. The particle size distribution of the crystals can be expressed based on any percentage other than the median (50%), and the "more preferred range" can be expressed as "40% volume diameter of 2.5 μm to 60% volume diameter of 2.5 μm", etc. Furthermore, since the density of the crystals of the compound of the present invention having a specified crystal structure is specific, it is essentially the same even if the volume median diameter is expressed as the weight median diameter, and this can also be expressed as any percentage.

[0032] Any one or more of the compounds represented by compounds X1 to X3 may have multiple crystalline polymorphs with different crystalline structures. When the crystals of the compound of the present invention are formulated into aqueous liquid suspensions (SC), oily liquid suspensions (OD), wettable powders (WP), suspoemulsions (SE), or water dispersible granules (WG), the volume median diameter of the crystal particles is usually 0.1 to 10 μm, preferably 0.2 to 5 μm, more preferably 1 to 4 μm, and even more preferably 2 to 3 μm. In particular, aqueous liquid suspensions (SC) with a volume median diameter of 2 to 3 μm are preferred. The particle size distribution of the crystals can be expressed based on any percentage other than the median (50%), and the "more preferred range" can be expressed as "40% volume diameter of 2.5 μm to 60% volume diameter of 2.5 μm," etc. Furthermore, since the density of the crystals of the compound of the present invention having a specific crystal structure is specific, the volume median diameter can be expressed as substantially the same as the weight median diameter, and can also be expressed as an arbitrary percentage.

[0033] Methods for applying the compound of the present invention include, for example, spraying the compound of the present invention on soil (soil treatment) and spraying it on emerged weeds (foliage treatment). Soil treatment and foliage treatment are usually carried out by mixing the composition of the present invention with water to obtain a spray solution, which is then sprayed onto the soil or weeds using a sprayer. The amount of spray solution is usually in the range of 50 to 1000 L / ha, and may be, for example, in the range of 100 to 500 L / ha or 140 to 300 L / ha.

[0034] The amount of the compound of the present invention applied was 10,000 m 2 When the compound of the present invention is flumioxazin, the treatment amount is usually 1 to 1,000 g, preferably 2 to 500 g, and more preferably 5 to 200 g per 10,000 m of the cultivated area of ​​the crop of the present invention. 2 When the compound of the present invention is epirifenacil or any of the compounds represented by the present compounds X1 to X3, the specific treatment amount is 50 g, 70 g, 87 g, 105 g, 140 g, 210 g, 280 g, or 420 g per 10,000 m of the cultivated area of ​​the present crop. 2 Examples of the amount of treatment can be 10 g, 15 g, 20 g, 22 g, 30 g, 33 g, 40 g, 44 g, 60 g, or 80 g per unit area. The above treatment amounts can also be expressed as "approximately." "Approximately" means plus or minus 10%, for example, approximately 20 g means 18 to 22 g. "Approximately" can be used in the same sense not only for treatment amounts, but also for numerical values ​​described herein, such as spray volume, percentage, parts per million (ppm), and volume median diameter.

[0035] The spray solution sprayed in step (2) of the method of the present invention may contain an adjuvant. The type of adjuvant contained in the spray solution is not particularly limited. When the spray solution contains an oil-based adjuvant such as Agri-Dex or MSO (a mineral oil such as paraffinic hydrocarbons, naphthenic hydrocarbons, or aromatic hydrocarbons, or a methylated seed oil obtained by esterifying vegetable oils (soybean oil or rapeseed oil)), which functions as a spreading agent, the concentration of the adjuvant in the spray solution may be, for example, 0.25%, 0.5%, 1%, 2%, 3%, 4%, 5%, or 6% (volume / volume). When the spray solution contains a nonionic adjuvant such as Induce (a polyoxyalkylene alkyl ether, polyoxyalkylene fatty acid ester, alkylaryl alkoxylate, or alkylaryl polyoxyalkylene glycol) which functions as a spreading agent, the concentration of the adjuvant in the spray solution may be, for example, 0.05%, 0.1%, 0.25%, or 0.5% (volume / volume). Other adjuvants include, for example, anionic adjuvants (substituted sulfonates) such as Gramin S, cationic adjuvants (polyoxyethyleneamines) such as Genamin T 200BM, and organosilicon adjuvants such as Silwet L77. The spray solution applied in step (2) of the method of the present invention may also contain drift-reducing adjuvants such as Intact (polyethylene glycol) and Intact Maxx (a mixture of potassium acetate, guar, etc.), or adjuvants that function as liquid fertilizers, such as AMS (ammonium sulfate) and UAN (urea ammonium nitrate). When a drift-reducing adjuvant is contained in the spray solution, the adjuvant concentration in the spray solution may be, for example, 0.875%, 1.75%, 1.875%, or 3.5% (volume / volume). When the spray solution contains an adjuvant that has the effect of a liquid fertilizer, the concentration of the adjuvant in the spray solution may be 0.5%, 1.0%, 1.5%, 2.0% or 3.0% (weight / volume).

[0036] The pH and hardness of the spray solution to be sprayed in step (2) of the method of the present invention are not particularly limited, but the pH is usually in the range of 5 to 9, and the hardness is usually in the range of 0 to 500 ppm on the American hardness scale. In step (2) of the method of the present invention, the time period for treating the compound of the present invention is not particularly limited, but is usually between 5:00 a.m. and 9:00 p.m., the photon flux density at the treatment location is usually in the range of 10 to 2,500 micromoles / m² / sec, the temperature at the treatment location is usually in the range of 0 to 35 degrees Celsius, and the wind speed is usually 3 MPH or less.

[0037] In step (2) of the method of the present invention, the nozzle used to treat the compound of the present invention may be a flat fan nozzle or a drift-reducing nozzle. Examples of flat fan nozzles include Teejet's Teejet 110 series and XR Teejet 110 series. When these nozzles are used at a normal spray pressure, typically in the range of 30 to 120 PSI, the volume median diameter of droplets discharged from the nozzle is typically less than 430 microns. A drift-reducing nozzle is a nozzle that reduces the drift of the spray liquid compared to a flat fan nozzle, and is also known as an air induction nozzle or pre-orifice nozzle. The volume median diameter of droplets discharged from a drift-reducing nozzle is typically 430 microns or more.

[0038] An air induction nozzle has an air introduction section between the nozzle inlet (chemical solution introduction section) and outlet (chemical solution discharge section), and forms droplets filled with air by mixing air into the chemical solution. Examples of air induction nozzles include Green Leaf Technology's TDXL11003-D, TDXL11004-D1, TDXL11005-D1, and TDXL11006-D; Teejet's TTI110025, TTI11003, TTI11004, TTI11005, TTI11006, and TTI11008; and Pentair's ULD120-041, ULD120-051, and ULD120-061. A particularly preferred nozzle is the TTI11004.

[0039] A pre-orifice nozzle has a metering orifice at the nozzle inlet (chemical introduction point), which restricts the flow rate into the nozzle and reduces the pressure inside the nozzle, forming larger droplets. When using this nozzle, the pressure is roughly halved during discharge compared to before introduction. Examples of pre-orifice nozzles include Wilger's DR110-10, UR110-05, UR110-06, UR110-08, and UR110-10, and Teejet's 1 / 4TTJ08 Turf Jet and 1 / 4TTJ04 Turf Jet.

[0040] The sprayer used to apply the compound of the present invention in step (2) of the method of the present invention may be a hooded sprayer certified by the U.S. Environmental Protection Agency (EPA) for drift reduction technology (DRT). Examples of DRT-certified hooded sprayers include REDBALL 642, REDBALL 642E, REDBALL SPK645, REDBALL 645, REDBALL 645T, REDBALL SP645, and REDBALL ATV642, all manufactured by Willmar Fabrication LLC.

[0041] In the method of the present invention, step (1) is usually performed once, and step (2) is usually performed one to three times. The order of steps (1) and (2) does not matter. The compound of the present invention may be applied to the cultivation area of ​​the crop of the present invention before sowing the seeds of the crop of the present invention, or may be applied simultaneously with or after sowing the seeds of the crop of the present invention. That is, examples of the number of times the compound of the present invention is applied include once before, simultaneously with, or after sowing the seeds of the crop of the present invention; twice excluding before sowing; twice excluding simultaneously with sowing; or twice excluding after sowing; or three times, i.e., before, simultaneously with, or after sowing the seeds of the crop of the present invention. When the compound of the present invention is applied before sowing seeds of the crop of the present invention, the compound of the present invention is applied 50 days to immediately before sowing, preferably 30 days to immediately before sowing, more preferably 20 days to immediately before sowing, and even more preferably 10 days to immediately before sowing. When the compound of the present invention is applied after sowing seeds of the crop of the present invention, the compound of the present invention is usually applied immediately after sowing to before flowering, more preferably between immediately after sowing and before emergence, and when the crop of the present invention has one to six true leaves. The case where the compound of the present invention is applied simultaneously with the sowing of the seeds of the crop of the present invention is when the sowing machine and the sprayer are integrated.

[0042] All of the compounds of the present invention are PPO inhibitors. Therefore, when the crop of the present invention has a bacterial PPO gene and becomes a PPO inhibitor-resistant crop, specific methods of use become possible. The pre-sowing and post-sowing pre-emergence treatment doses of the crop of the present invention can be increased by 2 to 8 times or more compared to when the crop of the present invention does not have a bacterial PPO gene, and the post-emergence treatment dose can also be increased to the same level (g / ha). This fact is disclosed in a non-patent document (Pest Manag. Sci. 76 (2020), 1031-1038), but this document does not disclose that the crop of the present invention may also have the FT_T gene or the tdo gene. When the crops of the present invention having a bacterial PPO gene (for example, HT5 corn and HT5 soybean) become volunteer crops and are targeted for control with herbicides, it is difficult to control them with the compound of the present invention or other herbicides to which other genes confer resistance. However, such volunteer crops can be controlled with yet another herbicide. For example, when HT5 corn becomes a volunteer crop in an area where soybeans (not limited to the crops of the present invention) or cotton are cultivated and become a target for control, it can be controlled with clethodim. Specifically, WO 2020 / 017667 discloses that corn (not HT5) having a bacterial PPO gene can be controlled with clethodim. HT5 corn can also be controlled by the methods disclosed in WO 2020 / 017667.

[0043] As described above, methods for applying the compound of the present invention include soil treatment, in which the compound of the present invention is applied to soil where weeds emerge, and foliar treatment, in which the compound of the present invention is applied to weeds that have emerged and are currently growing. When the compound of the present invention is applied to growing weeds, the treatment can be both foliar and soil treatment. The timing of treatment can be determined independently of the growth stage of the crop of the present invention described above. For example, foliar treatment can be performed on growing weeds before sowing the crop of the present invention, or soil treatment can be performed while the crop of the present invention is growing. These treatments can be uniform, area-wide treatments on the cultivation area, or spot treatments. The timing of application of the compound of the present invention before weed emergence includes the seed stage and cotyledon stage, and after weed emergence, includes, but is not limited to, the cotyledon stage, 2-leaf stage, 4-leaf stage, 6-leaf stage, and 8-leaf stage.

[0044] In the method of the present invention, spot treatment is a concept that is the opposite of uniform, area-wide application of a herbicide, and refers to selective application of a herbicide to areas where weeds are growing or where weeds will infest. "Applying to an area" means application to weeds or soil if weeds are growing, or application to soil in areas where weeds are predicted to infest in the future if weeds have not yet emerged. Even when a small amount of the compound of the present invention is sprayed in an area where weeds have not yet emerged or will not infest in the future due to drift, transpiration, etc., it is included in spot treatment, as long as it is not a uniform area-wide application. Furthermore, selective treatment of all areas where weeds are growing or where weeds infest in a continuous area of ​​cultivation of the crop of the present invention is not necessarily considered spot treatment. In other words, even if only part of the cultivation area is area-wide treatment, or even if only some areas where weeds are growing or where weeds infest are not treated, it is still included in spot treatment as long as there is a spot-treated area in the continuous area of ​​cultivation of the crop of the present invention. The spot treatment may be carried out while avoiding the crop of the present invention, or may be carried out based only on the location of the weeds, regardless of the location of the crop of the present invention.

[0045] Specific examples of spot treatment methods are given below. Spot treatment may be performed in a cultivated area of ​​the present crop by an applicator visually applying the compound of the present invention using a handheld nozzle or robotic arm nozzle while walking or aboard a ground-based or flying device. Alternatively, spot treatment may be performed by mapping the area where weeds grow or occur in advance and applying the compound of the present invention based on the map information. In application based on map information, in addition to the above-mentioned methods, spot treatment may be performed by automatically or manually opening and closing the boom nozzle or robotic arm nozzle while the sprayer is traveling or flying, based on the sprayer's position information (obtained by GPS, etc.) and the map information. The map information may be created based on image information captured by a manned or unmanned flying object, or may be created visually by an observer walking on the ground, riding on a ground-based or flying device, or by an observer aboard a flying device. Furthermore, a mobile or flying sprayer may be equipped with a function for detecting where weeds are growing or occurring, and spot treatment may be performed using the boom or robotic arm while performing real-time mapping. Such technology is described in patent literature (e.g., WO2018001893, WO2018036909) and non-patent literature (e.g., Crop Protection 26, 270-277, Weed Technology 17, 711-717, Applied Engineering in Agriculture 30, 143-152). These technologies are a form of emerging agriculture known as precision agriculture, smart agriculture, or digital agriculture, and the uneven spray pattern resulting from spot treatment is also referred to as VRA (Variable Rate Application) in this emerging agriculture term. Furthermore, technology in which a mobile sprayer performs spot treatment in real time while detecting growing weeds is known as "See & Spray" or "OSST (Optical Spot Spray Technology)." In addition, the John Deere 400 series and other sprayers equipped with See & Spray are in practical use.

[0046] Examples of weeds that can be controlled by the method of the present invention include the following: Urticaceae weeds: Urtica urens Polygonaceae weeds: Bindweed (Polygonum convolvulus), Polygonum lapathifolium, Polygonum pensylvanicum, Polygonum persicaria, Polygonum longisetum, Polygonum aviculare, Polygonum arenastrum, Polygonum cuspidatum, Rumex japonicus, Rumex crispus, Rumex obtusifolius, and Rumex acetosa. Portulacaceae weeds: Common purslane (Portulaca oleracea) Caryophyllaceae weeds: chickweed (Stellaria media), cow chickweed (Stellaria aquatica), earweed (Cerastium holosteoides), Dutch earweed (Cerastium glomeratum), giant clover (Spergula arvensis), and Silene gallica Molluginaceae: Wood mulberry (Mollugo verticillata) Chenopodiaceae weeds: Chenopodium album, Chenopodium ambrosioides, Kochia scoparia, Salsola kali, Atriplex spp.

[0047] Amaranthaceae weeds: Amaranthus retroflexus, Amaranthus viridis, Amaranthus lividus, Amaranthus spinosus, Amaranthus hybridus, Amaranthus palmeri, Amaranthus patulus, Waterhemp (Amaranthus tuberculatus = Amaranthus rudis = Amaranthus tamariscinus), American blackweed (Amaranthus blitoides), Amaranthus deflexus, Amaranthus quitensis, Alternanthera philoxeroides), Alternative vine (Alternanthera sessilis), Sanguinaria (Alternanthera tenella) Papaveraceae (weeds): Corn poppy (Papaver rhoeas), long-legged poppy (Papaver dubium), and thistle poppy (Argemone mexicana) Brassicaceae weeds: Wild radish (Raphanus raphanistrum), radish (Raphanus sativus), wild mustard (Sinapis arvensis), shepherd's purse (Capsella bursa-pastoris), mustard (Brassica juncea), rapeseed (Brassica napus), ragweed (Descurainia pinnata), burdock (Rorippa islandica), mustard (Rorippa sylvestris), shepherd's purse (Thlaspi arvense), mustard (Myagrum rugosum), shepherd's purse (Lepidium virginicum), shepherd's purse (Coronopus didymus) Capparaceae weed: Cleome affinis

[0048] Legume weeds (Fabaceae): Water hyacinth (Aeschynomene indica), zigzag-jointed vetch (Aeschynomene rudis), American hornbeam (Sesbania exaltata), Slipper grass (Cassia obtusifolia), Boxweed (Cassia occidentalis), Day bush clover (Desmodium tortuosum), Field bush clover (Desmodium adscendens), Illinois bush clover (Desmodium illinoense), White clover (Trifolium repens), Kudzu (Pueraria lobata), Vetch (Vicia angustifolia), Japanese ragwort (Indigofera hirsuta), Indigofera truxillensis, and Wild cowpea (Vigna sinensis) Oxalidaceae: Wood sorrel (Oxalis corniculata), wood sorrel (Oxalis stricta), and Oxalis oxyptera Geraniaceae weeds: American buttercup (Geranium carolinense), Dutch buttercup (Erodium cicutarium) Euphorbiaceae weeds: Spurge (Euphorbia helioscopia), Western weed (Euphorbia maculata), Western weed (Euphorbia humistrata), Common grass (Euphorbia esula), Cardinal flower (Euphorbia heterophylla), Hyssop-leaf sand mat (Euphorbia brasiliensis), Chinese hackberry (Acalypha australis), Tropic croton (Croton glandulosus), Lobed croton (Croton lobatus), Brazilian phyllanthus (Phyllanthus corcovadensis), and Castor bean (Ricinus communis)

[0049] Malvaceae: Abutilon theophrasti, Sida rhombifolia, Sida cordifolia, Sida spinosa, Sida glaziovii, Sida santaremnensis, Hibiscus trionum, Caladium laurel, Malvastrum coromandelianum Onagraceae weeds: Ludwigia epilobioides, Ludwigia octovalvis, Ludwigia decurrens, Oenothera biennis, Oenothera laciniata Sterculiaceae: Waltheria indica Violaceae: Viola arvensis, Viola tricolor Cucurbitaceae: Sicyos angulatus, wild cucumber (Echinocystis lobata), wild bitter melon (Momordica charantia) Lythraceae weeds: Ammannia multiflora, Ammannia auriculata, Ammannia coccinea, Lythrum salicaria, Rotala indica Elatinaceae: Elatine triandra, California waterwort

[0050] Apiaceae weeds: Oenanthe javanica, Daucus carota, Conium maculatum Araliaceae: Hydrocotyle sibthorpioides, Brazilian Hydrocotyle ranunculoides Ceratophyllaceae weeds: Ceratophyllum demersum Cabombaceae: Cabomba caroliniana Haloragaceae weeds: Myriophyllum aquaticum, Myriophyllum verticillatum, watermilfoil (Myriophyllum spicatum, Myriophyllum heterophyllum, etc.) Sapindaceae weeds: Cardiospermum halicacabum Primulaceae weeds: Anagallis arvensis Asclepiadaceae: Giant milkweed (Asclepias syriaca), honeyvine milkweed (Ampelamus albidus) Rubiaceae weeds: Catchweed bedstraw (Galium aparine), cleaver (Galium spurium var. echinospermon), broadleaf weed (Spermacoce latifolia), Brazilian false hawkweed (Richardia brasiliensis), winged phallus buttonweed (Borreria alata)

[0051] Convolvulaceae weeds: Morning glory (Ipomoea nil), American morning glory (Ipomoea hederacea), round morning glory (Ipomoea purpurea), round morning glory (Ipomoea hederacea var. integriuscula), common morning glory (Ipomoea lacunosa), starry morning glory (Ipomoea triloba), common morning glory (Ipomoea acuminata), ivy weed (Ipomoea hederifolia), common morning glory (Ipomoea coccinea), morning glory (Ipomoea quamoclit), Ipomoea grandifolia, Ipomoea aristolochiaefolia, sweet bindweed (Ipomoea cairica), European bindweed (Convolvulus arvensis), Little bindweed (Calystegia hederacea), Bindweed (Calystegia japonica), Ivy bindweed (Merremia hederacea), Hairy woodrose (Merremia aegyptia), Roadside woodrose (Merremia cissoides), Morning glory (Jacquemontia tamnifolia) Boraginaceae weeds: Forget-me-not (Myosotis arvensis) Lamiaceae weeds: Lamium purpureum, Lamium amplexicaule, Leonotis nepetaefolia, Hyptis suaveolens, Hyptis lophanta, Leonurus sibiricus, Stachys arvensis

[0052] Solanaceae weeds: Datura stramonium, Solanum nigrum, Solanum americanum, Solanum ptycanthum, Solanum sarrachoides, Solanum rostratum, Solanum aculeatissimum, Solanum sisymbriifolium, Solanum carolinense, Solanum angulata, Solanum smooth ground cherry, Solanum subglabrata, Solanum physalodes Scrophulariaceae weeds: Veronica hederaefolia, Veronica persica, Veronica arvensis, Lindernia procumbens, Lindernia dubia, Lindernia angustifolia, Bacopa rotundifolia, Dopatrium junceum, Gratiola japonica Plantaginaceae: Plantain (Plantago asiatica), Plantain (Plantago lanceolata), Common plantain (Plantago major), Water chickweed (Callitriche palustris)

[0053] Asteraceae weeds: Cocklebur (Xanthium pensylvanicum), Giant cocklebur (Xanthium occidentale), Brimbur (Xanthium italicum), Wild sunflower (Helianthus annuus), Chamomile (Matricaria chamomilla), Chamomile (Matricaria perforata), Corn marigold (Chrysanthemum segetum), Oriental daisy (Matricaria matricarioides), Wormwood (Artemisia princeps), Artemisia vulgaris, Chinese mugwort (Artemisia verlotorum), Goldenrod (Solidago altissima), Dandelion (Taraxacum officinale), Starburst weed (Galinsoga ciliata), and Oriental daisy (Galinsoga parviflora, Senecio vulgaris, Senecio brasiliensis, Senecio grisebachii, Conyza bonariensis, Conyza smatrensis, Conyza canadensis, Ambrosia artemisiifolia, Ambrosia trifida, Bidens tripartita, Bidens pilosa, Bidens frondosa, Bidens subalternans, Cirsium arvense, Cirsium serrata vulgare), milk thistle (Silybum marianum), musk thistle (Carduus nutans), thorny lettuce (Lactuca serriola), sowweed (Sonchus oleraceus), common sowweed (Sonchus asper), beach creeping oxeye (Wedeliaglauca, Perfoliate Blackfoot (Melampodium perfoliatum), Marshmallow Weed (Emilia sonchifolia), Shiozaki (Tagetes minuta), Paracles (Blainvillea latifolia), Japanese Stinging Star (Tridax procumbens), Yerba Polosa (Porophyllum ruderale), Paraguay Starburst (Acanthospermum australe), Bristle Starburst (Acanthospermum hispidum), Balloon Vine (Cardiospermum halicacabum), Ageratum (Ageratum conyzoides), Common Boneset (Eupatorium perfoliatum), Dandloose Flower (Erechtites hieracifolia), American Everlasting (Gamochaeta spicata), White-legged Weed (Gnaphalium spicatum, Jaegeria hirta, Parthenium hysterophorus, Siegesbeckia orientalis, Soliva sessilis, Eclipta prostrata, Eclipta alba, Centipeda minima

[0054] Alismataceae weeds: Sagittaria pygmaea, Sagittaria trifolia, Sagittaria sagittifolia, Sagittaria montevidensis, Sagittaria aginashi, Alisma canaliculatum, Alisma plantago-aquatica Limnocharitaceae weeds: Limnocharis flava Hydrocharitaceae: Frogbit (Limnobium spongia), Hydrilla verticillata, Common water nymph (Najas guadalupensis) Araceae weeds: Water duckweed (Pistia stratiotes) Duckweeds (Lemnaceae): Duckweed (Lemna aoukikusa, Lemna paucicostata, Lemna aequinoctialis), duckweed (Spirodela polyrhiza), Wolffia spp. Potamogetonaceae: Pondweed (Potamogeton distinctus), Pondweeds (Potamogeton crispus, Potamogeton illinoensis, Stuckenia pectinata, etc.) Liliaceae: Wild onion (Allium canadense), wild garlic (Allium vineale), and wild nobile (Allium macrostemon) Pontederiaceae weeds: Water hyacinth (Eichhornia crassipes), American whiteweed (Heteranthera limosa), water hyacinth (Monochoria korsakowii), and whiteweed (Monochoria vaginalis) Commelinaceae weeds: Commelina communis, Commelina benghalensis, Commelina erecta, Murdannia keisak

[0055] Grass weeds (Poaceae): Barnyard grass (Echinochloa crus-galli), Oriental watergrass (Echinochloa oryzicola), Oriental watergrass (Echinochloa crus-galli var. formosensis), Latewatergrass (Echinochloa oryzoides), Oriental barnyard grass (Echinochloa colona), Gulf cockspur (Echinochloa crus-pavonis), Green foxtail (Setaria viridis), Setaria faberi, Golden foxtail (Setaria glauca), American green foxtail (Setaria geniculata), Large crabgrass (Digitaria ciliaris), Large crabgrass (Digitaria sanguinalis), Jamaican crabgrass (Digitaria horizontalis), Large crabgrass (Digitaria insularis), Goosegrass (Eleusine indica), annual bluegrass (Poa annua), annual bluegrass (Poa trivialis), longgrass (Poa pratensis), annual foxtail (Alopecurus aequalis), blackgrass (Alopecurus myosuroides), wild oat (Avena fatua), common sorghum (Sorghum halepense), shattercane (Sorghum vulgare), quackgrass (Agropyron repens), loosegrass (Lolium multiflorum), ryegrass (Lolium perenne), barley (Lolium rigidum), corngrass (Bromus catharticus), bromegrass (Bromus sterilis), annual bluegrass (Bromus japonicus), common bromegrass (Bromus secalinus), and horsegrass (Bromus tectorum), Hordeum jubatum, Goat wheat (Aegilops cylindrica), Phalaris arundinacea, Phalaris arundinaceaminor), Silky bentgrass (Apera spica-venti), Common sorghum (Panicum dichotomiflorum), Texas panicum (Panicum texanum), Guinea millet (Panicum maximum), American millet (Brachiaria platyphylla), Ruzigrass (Brachiaria ruziziensis), Alexandergrass (Brachiaria plantaginea), Surinamegrass (Brachiaria decumbens), Palisade grass (Brachiaria brizantha), Columbiagrass (Brachiaria humidicola), Sinqueweed moth (Cenchrus echinatus), Small chestnut moth (Cenchrus pauciflorus), Narco barnyard grass (Eriochloa villosa), Pennisetum (Pennisetum setosum), African sorghum (Chloris gayana), Large sorghum (Chloris virgata, Eragrostis pilosa, Ruby grass (Rhynchelytrum repens), Seagrass (Dactyloctenium aegyptium), Taiwan grass (Ischaemum rugosum), Isachne globosa, Wild rice (Oryza sativa), American paspalum (Paspalum notatum), Coastal sand paspalum (Paspalum maritimum), Japanese knotgrass (Paspalum distichum), Kikuyu grass (Pennisetum clandestinum), Narrow-leaved grass (Pennisetum setosum), Horngrass (Rottboellia cochinchinensis), Japanese ragwort (Leptochloa chinensis), Japanese oak grass (Leptochloa fascicularis), Leptochloa filiformis, Amazon sprangle top (Leptochloa panicoides), Leersia japonica, Leersiasayanuka, Leersia oryzoides, Duckgrass (Glyceria leptorrhiza), Mudgrass (Glyceria acutiflora), Loach (Glyceria maxima), Marsh marsh (Agrostis gigantea), Scarlet marsh (Agrostis stolonifera), Horsegrass (Cynodon dactylon), Orchardgrass (Dactylis glomerata), Centipede grass (Eremochloa ophiuroides), Tall fescue (Festuca arundinacea), Big fescue (Festuca rubra), Imperata cylindrica, Miscanthus sinensis, Switchgrass (Panicum virgatum), Zoysia japonica)

[0056] Cyperaceae weeds: Cyperus microiria, Cyperus iria, Cyperus compressus, Cyperus difformis, Cyperus flaccidus, Cyperus globosus, Cyperus nipponicus, Cyperus odoratus, Cyperus serotinus, Cyperus rotundus, Cyperus esculentus, Kylerius gracillima, Kylerius brevifolia, Fimbristylis miliacea, Japanese trevally (Fimbristylis dichotoma), Japanese shrike (Eleocharis acicularis), Japanese water guayaba (Eleocharis kuroguwai), Japanese bulrush (Schoenoplectiella hotarui), Japanese bulrush (Schoenoplectiella juncoides), Taiwan mountain scallop (Schoenoplectiella wallichii), Japanese scallop (Schoenoplectiella mucronatus), Japanese scallop (Schoenoplectiella triangulatus), Japanese sea bass (Schoenoplectiella nipponicus), Japanese triangular scallop (Schoenoplectiella triqueter), Japanese club-headed ... Horsetail weeds (Equisetaceae): Horsetail (Equisetum arvense), Horsetail (Equisetum palustre) Salviniaceae weeds: Salvinia natans Azollaceae: Azolla japonica, Azolla pinnata Marsileaceae weeds: Marsilea quadrifolia Other: suckers of filamentous algae (Pithophora, Cladophora), mosses, liverworts, hornworts, cyanobacteria, ferns, and perennial crops (pome fruits, stone fruits, berries, nuts, citrus fruits, hops, grapes, etc.).

[0057] The intraspecific mutations of the above-mentioned weeds are not particularly limited. They also include those with reduced sensitivity (also known as resistance) to certain herbicides. Reduced sensitivity can be due to mutations in the target site (site mutations) or factors other than site mutations (non-site mutations). Site mutations include those in the nucleic acid sequence (open reading frame) corresponding to the amino acid sequence of a protein, resulting in amino acid substitutions in the target protein, and those resulting in overexpression of the target protein due to mutations such as deletion of a suppressor sequence in the promoter region, amplification of an enhancer sequence, or increased gene copy number. Non-site mutations include enhanced metabolism, inadequate absorption, inadequate translocation, and extracellular excretion. Factors that contribute to enhanced metabolism include increased activity of metabolic enzymes such as cytochrome P450 monooxygenase, aryl acylamidase, esterase, and glutathione S-transferase. Extracellular excretion can be achieved by transport to the vacuole via ABC transporters.

[0058] Examples of amino acid substitutions at the target site include the following: ALS: A122T, A122V, A122Y, P197S, P197H, P197T, P197R, P197L, P197Q, P197A, P197I, A205V, A205F, D376E, D376N, D376Q, R377H, W574L, W574G, W574M, S653T, S653N, S653I, G654E, or G654D; ACCase: I1781A, I1781L, I1781V, I1781T, L1818F, W1999C, W1999L, W1999S, A2004V, W2027C, W2027L, I2041D, I2041N, I2041T, I2041V, D2078E, D2078G, C2088F, C2088R, G2096A or G2096S; PPX2: G114E, R128A, R128C, R128E, R128G, R128H, R128I, R128K, R128L, R128M, R128N, R128Q, R128S, R128T, R128V, R128Y, S149I, A210 deletion, G210 deletion, A210T, G210T, G211 deletion, V361A, or G399A (all amino acid numbers are standardized to the sequence of Amaranthus palmeri PPO2); PPX1: A212T (standardized with the sequence of PPO1 from Goosegrass), F454I, F454L, F454V (standardized with the sequence of PPO1 from Kochia japonica) EPSP: T102I, A103V, P106S, P106A or P106L. Double substitution of T102I and P106S. Triple substitution of T102I, A103V and P106S.

[0059] The compound of the present invention can also control weeds that have multiple amino acid substitutions as described above. In this case, the multiple amino acid substitutions may be in the same protein or different proteins. Furthermore, the compound may have multiple non-acting and acting point mutations.

[0060] Examples of weeds with site-of-action mutations include the following: Amaranthella retroflexus having a G210 deletion, R128M, R128G, V361A, or G399A amino acid substitution in PPX2; Waterhemp with G210 deletion, R128M, R128G, V361A, or G399A amino acid substitutions in PPX2; ragweed, which has an amino acid substitution of R98L in PPX2; giant ragweed with an R98L amino acid substitution in PPX2; Bomugi, which has an amino acid substitution of R98H in PPX2; goosegrass with an amino acid substitution of A212T in PPX1; Kochia having an amino acid substitution of F454I, F454L or F454V in PPX1 goosegrass with the amino acid substitutions T102I, A103V, P106S, P106A, or P106L in EPSP; Bomugi with the amino acid substitutions T102I, A103V, P106S, P106A, or P106L in EPSP; Large crabgrass with the amino acid substitutions T102I, A103V, P106S, P106A, or P106L in EPSP; waterhemp with the amino acid substitutions T102I, A103V, P106S, P106A, or P106L in EPSP; Amaranthus retroflexus having an amino acid substitution of T102I, A103V, P106S, P106A or P106L in EPSP; and Echinochloa koenigii having an amino acid substitution of T102I, A103V, P106S, P106A or P106L in EPSP.

[0061] Amaranth, waterhemp, and common ragweed, which have the above-mentioned site mutations in PPX2, are resistant to PPO inhibitors such as lactofen and fomesafen.

[0062] Examples of weeds with multiple amino acid substitutions include glyphosate-resistant goosegrass, woolly barley, burdock, large crabgrass, waterhemp, and barnyard grass, which have the amino acid substitutions T102I and P106S, and glyphosate-resistant arugula, which has the triple amino acid substitutions T102I, A103V, and P106S.

[0063] Other weeds include the following: Overexpression of EPSP genes reduced the sensitivity of amaryllis, waterhemp, and broomcornium to glyphosate; Echinochloa gracilis showed reduced sensitivity to glyphosate due to increased expression of aldo-keto reductase; Resistant mugwort, giant ragweed, and ragweed that have reduced sensitivity to glyphosate via ABC transporters.

[0064] In the method of the present invention, the compound of the present invention may be applied in combination with one or more other herbicides and safeners. Here, "combined application" includes tank-mix, pre-mix, and sequential application, and in the case of sequential application, the order of application is not particularly limited. Examples of the above herbicides and safeners include the following: Herbicides: 2,3,6-TBA (2,3,6-trichlorobenzoic acid), 2,3,6-TBA dimethylammonium, 2,3,6-TBA lithium, 2,3,6-TBA potassium, 2,3,6-TBA sodium, 2,4-D, 2,4-D choline, 2,4-D biproamine, 2,4-D doboxyl, 2,4-D 2-ethylhexyl, 2,4-D 3-Butoxypropyl (2,4-D-3-butoxypropyl), 2,4-D-ammonium (2,4-D-ammonium), 2,4-D-butotyl, 2,4-D-butyl, 2,4-D-diethylammonium, 2,4-D-dimethylammonium, 2,4-D-diolamine, 2,4-D-dodecylammonium, 2,4-D-ethyl, 2,4-D-heptylammonium, 2,4-D-isobutyl (2 ,4-D-isobutyl), 2,4-D-isooctyl, 2,4-D-isopropyl, 2,4-D-isopropylammonium, 2,4-D-lithium, 2,4-D-meptyl, 2,4-D-methyl, 2,4-D-octyl, 2,4-D-pentyl, 2,4-D-propyl, 2,4-D-sodium, 2,4-D-tefuryl, 2,4-D-tetradecylammonium4-D-tetradecylammonium, 2,4-D triethylammonium, 2,4-D tris(2-hydroxypropyl)ammonium, 2,4-D trolamine, 2,4-DB, 2,4-DB choline salt), 2,4-DB biproamine, 2,4-DB butyl, 2,4-DB dimethylammonium, 2,4-DB isooctyl, 2,4-DB potassium salt, 2,4-DB sodium salt, acetochlor, acifluorfen, acifluorfen sodium salt, aclonifen, ACN (2-amino-3-chloronaphthalene-1,4-dione), alachlor, allidochlor, alloxydim, ametryn, Amicarbazone, amidosulfuron, aminocyclopyrachlor, aminocyclopyrachlor-methyl, aminocyclopyrachlor potassium salt, aminopyralid, aminopyralid choline salt, aminopyralid potassium salt, aminopyralid Trypromine (aminopyralid-tripromine), amiprophos-methyl, amitrole, anilofos, asulam, atrazine, azafenidin, azimsulfuron, beflubutamid, benazolin-ethyl, bencarbazone, benfluralin, benfuresate, benquitrione, bensulfuron, bensulfuron-methyl, ben bensulide, bentazon, benthiocarb, benzfendizone, benzobicyclon, benzofenap, benzthiazuron, bialafos, bicyclopyrone, bifenox, bipyrazone, bispyribac, bispyribac-sodium, bixlozone, broclozone, bromacil, bromobutide,Bromofenoxim, bromoxynil, bromoxynil-octanoate, butachlor, butafenacil, butamifos, butralin, butroxydim, butyrate, cafenstrole, carbetamide, carfentrazone, carfentrazone-ethyl, chlomethoxyfen, chloramben, chloridazon, chlorimuron, chlorimuron-ethyl, chlorbromuron chlorobromuron, chlorotoluron, chloroxuron, chlorpropham, chlorsulfuron, chlorthal-dimethyl, chlorthiamid, cinflubrolin, cinidon, cinidon-ethyl, cinmethylin, cinosulfuron, clethodim, clodinafop, clodinafop-propargyl, clomazone, clomeprop, clopyralid, clopyralid choline salt choline salt, clopyralid methyl, clopyralid olamine salt, clopyralid potassium salt,Clopyralid tris(2-hydroxypropyl)ammonium, cloransulam, cloransulam-methyl, cumyluron, cyanazine, cyclopyranil, cycloate, cyclopyrimorate, cyclosulfamuron, cycloxydim, cyhalofop, cyhalofop-butyl, cypyrafluone, daimuron, dalapon, dazomet, desmedipham, desmetryn, di-allate, dicamba, dicamba choline salt, dicamba-biproamine, dicamba-trolamine salt, dicamba-diglycolamine salt, dicamba-dimethylammonium, dicamba-diolamine salt, dicamba-isopropylammonium, dicamba-methyl, dicamba-olamine salt, dicamba-potassium salt, dicamba-sodium salt, dichlobenil, dichlorprop, dichlorprop choline salt, dichlorprop-biproamine, dichlorprop-etexyl, dichlorprop-butotyl,Dichlorprop-dimethylammonium, dichlorprop-ethylammonium, dichlorprop-isoctyl, dichlorprop-methyl, dichlorprop-P, dichlorprop-P choline salt salt), dichlorprop-P biproamine, dichlorprop-P etexyl, dichlorprop-P dimethylammonium, dichlorprop potassium salt, dichlorprop sodium salt, diclofop, diclofop-methyl, diclosulam, difenoxuron, difenzoquat, difenzoquat methylsulfate, diflufenican, diflufenzopyr, diflufenzopyr sodium salt, Dimefuron, dimepiperate, dimepyrolimet, dimesulfazet, dimethachlor, dimethametryn, dimethenamid, dimethenamid-P, dimepiperate, dinitramine, dinoseb, dinoterb, dioxopyritrione, diphenamid, diquat, diquat-dibromide, disodium DSMA methylarsonate, dithiopyr, diuron, DNOC (2-methyl-4,6-dinitrophenol), esprocarb, ethalfluralin, ethametsulfuron, ethametsulfuron-methyl, ethidimuron, ethofumesate, ethoxyfen-ethyl, ethoxysulfuron, etobenzanid, fendioxypyracil oxypyracil, fenoxaprop, fenoxaprop-ethyl, fenoxaprop P, fenoxaprop-P-ethyl, fenoxasulfone, fenpyrazone, fenquinotrione, fentrazamide, fenuron, feproxydim, flamprop-M, flazasulfuron, florasulam,florpyrauxifen, florpyrauxifen-benzyl, fluazifop, fluazifop-butyl, fluazifop-P, fluazifop-P-butyl, fluazolate, flucarbazone, flucarbazone-sodium, flu Cetosulfuron, fluchloraminopyr, fluchloraminopyr-tefuryl, flufenauxirim, flufenacet, flufenazopyr, flufenoximacil, flufenpyr, flufenpyr-ethyl, flumetsulam etsulam, flumetsulam, flumiclorac, flumiclorac-pentyl, fluometuron, fluoroglycofen-ethyl, flupoxam, flupropanate, flupyrsulfuron, flupyrsulfuron-methyl sodium l-sodium), flurenol, fluridone, flurochloridone, fluroxypyr, fluroxypyr-butometyl, fluroxypyr-meptyl, flurtamone, flusulfinam, fluthiacet, fluthiacet-methyl,Fomesafen, fomesafen sodium, foramsulfuron, fosamine, glufosinate, glufosinate ammonium, glufosinate-P, glufosinate-P ammonium, glufosinate-P sodium, glyphosate, glyphosate choline salt, glyphosate isopropylammonium salt (glyphosate-isopropylammonium), glyphosate biproamine salt (glyphosate-biproamine), glyphosate ammonium salt (glyphosate-ammonium), glyphosate diammonium salt (glyphosate-diammonium), glyphosate potassium salt (glyphosate-potassium), glyphosate sodium salt (glyphosate-sodium), glyphosate trimesium salt (glyphosate-trimesium), halauxifen, halauxifen-benzyl, halauxifen-methyl uxifen-methyl), halosafen, halosulfuron, halosulfuron-methyl, haloxyfop, haloxyfop-ethotyl, haloxyfop-methyl, haloxyfop-P, haloxyfop-P-ethotyl, haloxyfop-P-methyl, hexazinone, icafolin, icafolin-methyl, imazamethabenz,Imazamethabenz-methyl, imazamox, imazamox ammonium salt, imazamox sodium salt, imazapic, imazapic-ammonium salt, imazapyr, imazapyr ammonium salt, imazapyr-isopropylammonium salt, imazaquin, Imazaquin ammonium salt (imazaquin-ammonium), imazethapyr, imazethapyr ammonium salt (imazethapyr-ammonium), imazosulfuron, indanofan, indaziflam, indolauxipyr, indolauxipyr-cyanomethyl, iodosulfuron, iodosulfuron-methyl-sodium, iofensulfuron, iofensulfuron Iofensulfuron sodium, ioxynil, ioxynil-octanoate, ipfencarbazone, iptriazopyrid, isoproturon, isouron, isoxaben, isoxachlortole, isoxafenacil, isoxaflutole, lactofen, lenacil, linuron, maleic hydrazide, MCPA (2-(4-chloro-2-methylphenoxy)acetic acid), MCPA choline saltsalt, MCPA-biproamine, MCPA-etexyl, MCPA-butotyl, MCPA-butyl, MCPA-dimethylammonium, MCPA-diolamine, MCPA-ethyl, MCPA-isobutyl, MCPA-isoctyl, MCPA-isopropyl, MCPA-methyl, MCPA-olamine, MCPA-sodium, MCPA-trolamine, MCPB (4-(4-chloro-2-methylphenoxy)butanoic acid), MCPB choline salt), MCPB-biproamine, MCPB-ethyl, MCPB-methyl, MCPB-sodium, mecoprop, mecoprop choline salt, mecoprop-biproamine, mecoprop 2-Ethylhexyl (mecoprop-2-ethylhexyl), mecoprop-dimethylammonium, mecoprop-diolamine salt, mecoprop-ethadyl, mecoprop-isoctyl, mecoprop-methyl, mecoprop-potassium salt, mecoprop-sodium salt, mecoprop-trolamine salt, mecoprop-P, mecoprop-P choline salt, mecoprop P2-ethylhexyl (mecoprop-P-2-ethylhexyl), mecoprop-P dimethylammonium (mecoprop-P-dimethylammonium), mecoprop-P isobutyl (mecoprop-P-isobutyl), mecoprop-P potassium salt (mecoprop-P-potassium), mefenacet, mesosulfuron, mesosulfuron-methyl, mesotrione, metam, metamifop, metamitron, metazachlor, metazosulfuron, methabenzthiazuron, methiozolin, Methyldymron, metobromuron, metolachlor, metosulam, metoxuron, metproxybicyclone, metribuzin, metsulfuron, metsulfuron-methyl, molinate, monolinuron, naproanilide, napropamide, napropamide-M, naptalam, neburon, nicosulfuron, norflurazon, oleic acidacid, orbencarb, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxasulfuron, oxaziclomefone, oxyfluorfen, paraquat, paraquat-dichloride, pebulate, pelargonic acidacid, pendimethalin, penoxsulam, pentanochlor, pentoxazone, pethoxamid, phenisopham, phenmedipham, picloram, picolinafen, pinoxaden, piperophos, pretilachlor lachlor, primisulfuron, primisulfuron-methyl, prochlorosulfone, prodiamine, profluazol, propoxydim, prometon, prometryn, propachlor, propanil, propaquizafop p), propazine, propham, propisochlor, propoxycarbazone, propoxycarbazone sodium salt, propyrisulfuron, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyraquinate (p yraquinate, pyraflufen-ethyl, pyrasulfotole, pyrazolinate, pyrazosulfuron, pyrazosulfuron-ethyl, pyrazoxyfen, pyribenzoxim, pyributicarb, pyridafol, pyridate, Pyriflubenzoxim, pyriftalid, pyriminobac, pyriminobac-methyl, pyrimisulfan, pyrithiobac, pyrithiobac-sodium, pyroxasulfone, pyroxsulam, quinclorac, quinmerac, Quizalofop, quizalofop-ethyl, quizalofop-tefuryl, quizalofop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl, rimisoxafen, rimsulfuron, saflufenacil, sethoxydim, EPTC(S-ethyl) N,N-dipropylcarbamothioate, siduron, simazine, simetryn, S-metolachlor, MSMA (sodium hydrogen methylarsonate), sulcotrione, sulfentrazone, sulfometuron, sulfometuron-methyl, sulfosulfuron, swep, TCA (2,2,2-trichloroacetic acid)acid, TCA ammonium (TCA-ammonium), TCA calcium (TCA-calcium), TCA ethadyl (TCA-ethadyl), TCA magnesium (TCA-magnesium), TCA sodium (TCA-sodium), tebutam, tebuthiuron, tefuryltrione, tembotrione, tepraloxydim, terbacil, terbumeton, terbuthylazine, terbutryn, tetflupyrolimet, thaxtomin AA), thenylchlor, thiazopyr, thidiazimine, thiencarbazone, thiencarbazone-methyl, thifensulfuron, thifensulfuron-methyl, thiafenacil, thiocarbazil, tolpyralate ), topramezone, tralkoxydim, triafamone, tri-allate, triasulfuron, triaziflam, tribenuron, tribenuron-methyl, triclopyr, triclopyr-butotyl, triclopyr-ethyl hyl), triclopyr-triethylammonium, tridiphane, trietazine, trifloxysulfuron, trifloxysulfuron-sodium, trifludimoxazin, trifluralin, triflusulfuron, triflusulfuron triflusulfuron-methyl, tripyrasulfone, tritosulfuron, vernolate, 4-(4-fluorophenyl)-6-[(2-hydroxy-6-oxo-1-cyclohexen-1-yl)carbonyl]-2-methyl-1,2,4-triazine-3,5(2H,4H)-dione, 1-{2-chloro-6-[(5-chloropyrimidin-2-yl)oxy]phenyl}-4,4,4-trifluorobutan-1-one.

[0065] Safeners: Benoxacor, cloquintocet, cloquintocet-mexyl, cyometrinil, cyprosulfamide, dichlormid, daimuron, fenchlorazole, fenchlorazole-ethyl, fenclorim, flurazole, furilazole, fluxofenim, isoxadifen, isoxadifen-ethyl, mefenpyr, mefenpyr-ethyl, mefenpyr-diethyl, and metcamifen.

[0066] In the present invention, preferred herbicides that can be used in combination with the compound of the present invention include glyphosate potassium salt, glyphosate dimethylamine salt, glyphosate monoethanolamine salt, glufosinate ammonium salt, glufosinate P ammonium salt, glyphosate isopropylammonium salt, 2,4-D choline salt, 2,4-D trolamine salt, 2,4-D 2-ethylhexyl, pyroxasulfone, dicamba diglycolamine salt, dicambabiproamine, flumiclorac pentyl, clethodim, methoproxybicyclon, lactofen, mesotrione, tembotrione, diflufenican, icafolin methyl, and quizalofop P ethyl.

[0067] In the present invention, preferred safeners that can be used in combination with the compounds of the present invention are cyprosulfamide, benoxacor, dichlormid and furilazole.

[0068] In the method of the present invention, examples of combinations of other herbicides that can be used in combination with the compound of the present invention are listed below, but are not limited to these. The ratio of the other herbicide to the compound of the present invention is usually in the range of 0.01 to 1000 times, and preferably 0.1 to 300 times, by weight. Specific examples of the ratio of other herbicides to the compound of the present invention, by weight, include 0.1 times, 0.2 times, 0.3 times, 0.4 times, 0.5 times, 0.6 times, 0.7 times, 0.8 times, 0.9 times, 1 times, 1.2 times, 1.5 times, 1.7 times, 2 times, 2.5 times, 3 times, 4 times, 5 times, 7 times, 10 times, 15 times, 20 times, 30 times, 40 times, 50 times, 60 times, 70 times, 80 times, 100 times, 150 times, and 200 times. The combination examples also include combinations of flumioxazin with a compound of the present invention other than flumioxazin. The ratio of flumioxazin to the compound of the present invention other than flumioxazin is usually in the range of 0.01 to 1000 times, and preferably 0.1 to 300 times, by weight. Specific examples of the ratio of flumioxazin to the compound of the present invention other than flumioxazin include, by weight, 0.1-fold, 0.2-fold, 0.3-fold, 0.4-fold, 0.5-fold, 0.6-fold, 0.7-fold, 0.8-fold, 0.9-fold, 1-fold, 1-fold, 1.2-fold, 1.5-fold, 1.7-fold, 2-fold, 2.5-fold, 3-fold, 4-fold, 5-fold, 7-fold, 10-fold, 15-fold, 20-fold, 30-fold, 40-fold, 50-fold, 60-fold, 70-fold, 80-fold, 100-fold, 150-fold, and 200-fold.

[0069] As used herein, when the herbicide is a salt or ester (e.g., glyphosate potassium salt, 2,4-D 2-ethylhexyl), the weight refers to the acid equivalent weight unless otherwise specified.

[0070] More preferred specific combinations of the compound of the present invention with one or more herbicides are listed below: In this paragraph, the numbers in parentheses represent the preferred application rates (g / ha). Epirifenacil (20) + Glyphosate potassium salt (1261) Epirifenacil (20) + Dicamba Diglycolamine Salt (560) Epirifenacil (20) + Dicambabiproamine (560) Epirifenacil (20) + Glyphosate Potassium Salt (1261) + Dicamba Diglycolamine Salt (560) Epirifenacil (20) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Epirifenacil (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) Epirifenacil (20) + Flumioxazin (89) + Dicamba Diglycolamine Salt (1261) Epirifenacil (20) + Flumioxazin (89) + Dicambabiproamine (560) Epirifenacil (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Epirifenacil (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Epirifenacil (20) + 2,4-D Choline Salt (1065) Epirifenacil (20) + 2,4-Dimethylamine Salt (1065) Epirifenacil (20) + 2,4-D-trolamine salt (1065) Epirifenacil (20) + 2,4-D 2-Ethylhexyl (1065) Epirifenacil (20) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Epirifenacil (20) + Glyphosate Potassium Salt (1261) + 2,4-D Triolamine Salt (1065) Epirifenacil (20) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Epirifenacil (20) + Flumioxazin (89) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Flumioxazin (89) + 2,4-Dimethylamine Salt (1065) Epirifenacil (20) + Flumioxazin (89) + 2,4-D 2-Ethylhexyl (1065) Epirifenacil (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Epirifenacil (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Epirifenacil (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Flumioxazin (89) + Glyphosate potassium salt (1261) Flumioxazin (89) + Dicamba Diglycolamine Salt (1261) Flumioxazin (89) + Dicambabiproamine (560) Flumioxazin (89) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Flumioxazin (89) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Flumioxazin (89) + 2,4-D Choline Salt (1065) Flumioxazin (89) + 2,4-D dimethylamine salt (1065) Flumioxazin (89) + 2,4-D 2-Ethylhexyl (1065) Flumioxazin (89) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Flumioxazin (89) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Flumioxazin (89) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Epirifenacil (20) + Mesotrione (210) + Glyphosate potassium salt (1261) Epirifenacil (20) + Mesotrione (210) + Dicamba Diglycolamine Salt (560) Epirifenacil (20) + Mesotrione (210) + Dicambabiproamine (560) Epirifenacil (20) + Mesotrione (210) + Glyphosate Potassium Salt (1261) + Dicamba Diglycolamine Salt (560) Epirifenacil (20) + Mesotrione (210) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Epirifenacil (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) Epirifenacil (20) + Flumioxazin (89) + Mesotrione (210) + Dicamba Diglycolamine Salt (1261) Epirifenacil (20) + Flumioxazin (89) + Mesotrione (210) + Dicambabiproamine (560) Epirifenacil (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Epirifenacil (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Epirifenacil (20) + Mesotrione (210) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Mesotrione (210) + 2,4-D Dimethylamine Salt (1065) Epirifenacil (20) + Mesotrione (210) + 2,4-D-Trolamine Salt (1065) Epirifenacil (20) + Mesotrione (210) + 2,4-D 2-Ethylhexyl (1065) Epirifenacil (20) + Mesotrione (210) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Mesotrione (210) + Glyphosate Potassium Salt (1261) + 2,4-Dimethylamine Salt (1065) Epirifenacil (20) + Mesotrione (210) + Glyphosate Potassium Salt (1261) + 2,4-D Triolamine Salt (1065) Epirifenacil (20) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Epirifenacil (20) + Flumioxazin (89) + Mesotrione (210) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Flumioxazin (89) + Mesotrione (210) + 2,4-D Dimethylamine Salt (1065) Epirifenacil (20) + Flumioxazin (89) + Mesotrione (210) + 2,4-D 2-Ethylhexyl (1065) Epirifenacil (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Epirifenacil (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Epirifenacil (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) Flumioxazin (89) + Mesotrione (210) + Dicamba Diglycolamine Salt (1261) Flumioxazin (89) + Mesotrione (210) + Dicambabiproamine (560) Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Flumioxazin (89) + Mesotrione (210) + 2,4-D Choline Salt (1065) Flumioxazin (89) + Mesotrione (210) + 2,4-D dimethylamine salt (1065) Flumioxazin (89) + Mesotrione (210) + 2,4-D 2-Ethylhexyl (1065) Flumioxazin (89) + Mesotrione (210) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Epirifenacil (20) + Tembotrione (92) + Glyphosate potassium salt (1261) Epirifenacil (20) + Tembotrione (92) + Dicamba Diglycolamine Salt (560) Epirifenacil (20) + Tembotrione (92) + Dicambabiproamine (560) Epirifenacil (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Epirifenacil (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Epirifenacil (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) Epirifenacil (20) + Flumioxazin (89) + Tembotrione (92) + Dicamba Diglycolamine Salt (1261) Epirifenacil (20) + Flumioxazin (89) + Tembotrione (92) + Dicambabiproamine (560) Epirifenacil (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Epirifenacil (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Epirifenacil (20) + Tembotrione (92) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Tembotrione (92) + 2,4-Dimethylamine Salt (1065) Epirifenacil (20) + Tembotrione (92) + 2,4-D-Trolamine Salt (1065) Epirifenacil (20) + Tembotrione (92) + 2,4-D 2-Ethylhexyl (1065) Epirifenacil (20) + Tembotrione (92) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Epirifenacil (20) + Tembotrione (92) + Glyphosate Potassium Salt (1261) + 2,4-D Triolamine Salt (1065) Epirifenacil (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Epirifenacil (20) + Flumioxazin (89) + Tembotrione (92) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Flumioxazin (89) + Tembotrione (92) + 2,4-Dimethylamine Salt (1065) Epirifenacil (20) + Flumioxazin (89) + Tembotrione (92) + 2,4-D 2-Ethylhexyl (1065) Epirifenacil (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Epirifenacil (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Epirifenacil (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) Flumioxazin (89) + Tembotrione (92) + Dicamba Diglycolamine Salt (1261) Flumioxazin (89) + Tembotrione (92) + Dicambabiproamine (560) Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Flumioxazin (89) + Tembotrione (92) + 2,4-D Choline Salt (1065) Flumioxazin (89) + Tembotrione (92) + 2,4-Dimethylamine Salt (1065) Flumioxazin (89) + Tembotrione (92) + 2,4-D 2-Ethylhexyl (1065) Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Epirifenacil (20) + Clethodim (200) + Glyphosate potassium salt (1261) Epirifenacil (20) + Clethodim (200) + Dicamba Diglycolamine Salt (560) Epirifenacil (20) + Clethodim (200) + Dicambabiproamine (560) Epirifenacil (20) + Clethodim (200) + Glyphosate Potassium Salt (1261) + Dicamba Diglycolamine Salt (560) Epirifenacil (20) + Clethodim (200) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Epirifenacil (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) Epirifenacil (20) + Flumioxazin (89) + Clethodim (200) + Dicamba Diglycolamine Salt (1261) Epirifenacil (20) + Flumioxazin (89) + Clethodim (200) + Dicambabiproamine (560) Epirifenacil (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Epirifenacil (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Epirifenacil (20) + Clethodim (200) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Clethodim (200) + 2,4-D Dimethylamine Salt (1065) Epirifenacil (20) + Clethodim (200) + 2,4-D-Trolamine Salt (1065) Epirifenacil (20) + Clethodim (200) + 2,4-D 2-Ethylhexyl (1065) Epirifenacil (20) + Clethodim (200) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Clethodim (200) + Glyphosate Potassium Salt (1261) + 2,4-Dimethylamine Salt (1065) Epirifenacil (20) + Clethodim (200) + Glyphosate Potassium Salt (1261) + 2,4-D Triolamine Salt (1065) Epirifenacil (20) + Clethodim (200) + Glyphosate Potassium Salt (1261) + 2,4-D 2-Ethylhexyl (1065) Epirifenacil (20) + Flumioxazin (89) + Clethodim (200) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Flumioxazin (89) + Clethodim (200) + 2,4-D Dimethylamine Salt (1065) Epirifenacil (20) + Flumioxazin (89) + Clethodim (200) + 2,4-D 2-Ethylhexyl (1065) Epirifenacil (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Epirifenacil (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Epirifenacil (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) Flumioxazin (89) + Clethodim (200) + Dicamba Diglycolamine Salt (1261) Flumioxazin (89) + Clethodim (200) + Dicambabiproamine (560) Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) and flumioxazin (89) + clethodim (200) + glyphosate potassium salt (1261) + dicambabiproamine (560). Flumioxazin (89) + Clethodim (200) + 2,4-D Choline Salt (1065) Flumioxazin (89) + Clethodim (200) + 2,4-D dimethylamine salt (1065) Flumioxazin (89) + Clethodim (200) + 2,4-D 2-Ethylhexyl (1065) Flumioxazin (89) + Clethodim (200) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Epirifenacil (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) Epirifenacil (20) + Methoxybicyclon (100) + Dicamba Diglycolamine Salt (560) Epirifenacil (20) + Methoxybicyclon (100) + Dicambabiproamine (560) Epirifenacil (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Epirifenacil (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Epirifenacil (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) Epirifenacil (20) + Flumioxazin (89) + Methoxybicyclon (100) + Dicamba Diglycolamine Salt (1261) Epirifenacil (20) + Flumioxazin (89) + Methoxybicyclon (100) + Dicambabiproamine (560) Epirifenacil (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Epirifenacil (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Epirifenacil (20) + Methoxybicyclon (100) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Methoxybicyclon (100) + 2,4-D Dimethylamine Salt (1065) Epirifenacil (20) + Methoxybicyclon (100) + 2,4-D-Trolamine Salt (1065) Epirifenacil (20) + Methoxybicyclon (100) + 2,4-D 2-Ethylhexyl (1065) Epirifenacil (20) + Methoxybicyclon (100) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Epirifenacil (20) + Methoxybicyclon (100) + Glyphosate Potassium Salt (1261) + 2,4-D Triolamine Salt (1065) Epirifenacil (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Epirifenacil (20) + Flumioxazin (89) + Methoxybicyclon (100) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Flumioxazin (89) + Methoxybicyclon (100) + 2,4-D Dimethylamine Salt (1065) Epirifenacil (20) + Flumioxazin (89) + Methoxybicyclon (100) + 2,4-D 2-Ethylhexyl (1065) Epirifenacil (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Epirifenacil (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Epirifenacil (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) Flumioxazin (89) + Methoxybicyclon (100) + Dicamba Diglycolamine Salt (1261) Flumioxazin (89) + Methoxybicyclon (100) + Dicambabiproamine (560) Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) and flumioxazin (89) + methoxybicyclon (100) + glyphosate potassium salt (1261) + dicambabiproamine (560). Flumioxazin (89) + Methoxybicyclon (100) + 2,4-D Choline Salt (1065) Flumioxazin (89) + Methoxybicyclon (100) + 2,4-D Dimethylamine Salt (1065) Flumioxazin (89) + Methoxybicyclon (100) + 2,4-D 2-Ethylhexyl (1065) Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Epirifenacil (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) Epirifenacil (20) + Pyroxasulfone (112) + Dicamba Diglycolamine Salt (560) Epirifenacil (20) + Pyroxasulfone (112) + Dicambabiproamine (560) Epirifenacil (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Epirifenacil (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Epirifenacil (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) Epirifenacil (20) + Flumioxazin (89) + Pyroxasulfone (112) + Dicamba Diglycolamine Salt (1261) Epirifenacil (20) + Flumioxazin (89) + Pyroxasulfone (112) + Dicambabiproamine (560) Epirifenacil (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Epirifenacil (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Epirifenacil (20) + Pyroxasulfone (112) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Pyroxasulfone (112) + 2,4-Dimethylamine Salt (1065) Epirifenacil (20) + Pyroxasulfone (112) + 2,4-D-Trolamine Salt (1065) Epirifenacil (20) + Pyroxasulfone (112) + 2,4-D 2-Ethylhexyl (1065) Epirifenacil (20) + Pyroxasulfone (112) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Epirifenacil (20) + Pyroxasulfone (112) + Glyphosate Potassium Salt (1261) + 2,4-D Triolamine Salt (1065) Epirifenacil (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Epirifenacil (20) + Flumioxazin (89) + Pyroxasulfone (112) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Flumioxazin (89) + Pyroxasulfone (112) + 2,4-Dimethylamine Salt (1065) Epirifenacil (20) + Flumioxazin (89) + Pyroxasulfone (112) + 2,4-D 2-Ethylhexyl (1065) Epirifenacil (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Epirifenacil (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Epirifenacil (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) Flumioxazin (89) + Pyroxasulfone (112) + Dicamba Diglycolamine Salt (1261) Flumioxazin (89) + Pyroxasulfone (112) + Dicambabiproamine (560) Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Flumioxazin (89) + Pyroxasulfone (112) + 2,4-D Choline Salt (1065) Flumioxazin (89) + Pyroxasulfone (112) + 2,4-Dimethylamine Salt (1065) Flumioxazin (89) + Pyroxasulfone (112) + 2,4-D 2-Ethylhexyl (1065) Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Epirifenacil (20) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) Epirifenacil (20) + Icaforin Methyl (150) + Dicamba Diglycolamine Salt (560) Epirifenacil (20) + Icaforin Methyl (150) + Dicambabiproamine (560) Epirifenacil (20) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) + Dicamba Diglycolamine Salt (560) Epirifenacil (20) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) + Dicambabiproamine (560) Epirifenacil (20) + Flumioxazin (89) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) Epirifenacil (20) + Flumioxazin (89) + Icaforin Methyl (150) + Dicamba Diglycolamine Salt (1261) Epirifenacil (20) + Flumioxazin (89) + Icaforin methyl (150) + Dicambabiproamine (560) Epirifenacil (20) + Flumioxazin (89) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) + Dicamba Diglycolamine Salt (560) Epirifenacil (20) + Flumioxazin (89) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) + Dicambabiproamine (560) Epirifenacil (20) + Icaforin Methyl (150) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Icaforin Methyl (150) + 2,4-Dimethylamine Salt (1065) Epirifenacil (20) + Icaforin Methyl (150) + 2,4-D-Trolamine Salt (1065) Epirifenacil (20) + Icaforin Methyl (150) + 2,4-D 2-Ethylhexyl (1065) Epirifenacil (20) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-Dimethylamine Salt (1065) Epirifenacil (20) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-D Triolamine Salt (1065) Epirifenacil (20) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-D 2-Ethylhexyl (1065) Epirifenacil (20) + Flumioxazin (89) + Icaforin Methyl (150) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Flumioxazin (89) + Icaforin Methyl (150) + 2,4-Dimethylamine Salt (1065) Epirifenacil (20) + Flumioxazin (89) + Icaforin Methyl (150) + 2,4-D 2-Ethylhexyl (1065) Epirifenacil (20) + Flumioxazin (89) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Epirifenacil (20) + Flumioxazin (89) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-Dimethylamine Salt (1065) Epirifenacil (20) + Flumioxazin (89) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-D 2-Ethylhexyl (1065) Flumioxazin (89) + Icaforin methyl (150) + Glyphosate potassium salt (1261) Flumioxazin (89) + Icaforin Methyl (150) + Dicamba Diglycolamine Salt (1261) Flumioxazin (89) + Icaforin methyl (150) + Dicambabiproamine (560) Flumioxazin (89) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) + Dicamba Diglycolamine Salt (560) Flumioxazin (89) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) + Dicambabiproamine (560) Flumioxazin (89) + Icaforin Methyl (150) + 2,4-D Choline Salt (1065) Flumioxazin (89) + Icaforin Methyl (150) + 2,4-Dimethylamine Salt (1065) Flumioxazin (89) + Icaforin Methyl (150) + 2,4-D 2-Ethylhexyl (1065) Flumioxazin (89) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Flumioxazin (89) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-Dimethylamine Salt (1065) Flumioxazin (89) + Icaforin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-D 2-Ethylhexyl (1065)

[0071] Compound X1 (20) + glyphosate potassium salt (1261) This compound X1 (20) + dicamba diglycolamine salt (560) This compound X1 (20) + dicambabiproamine (560) Compound X1 (20) + glyphosate potassium salt (1261) + dicamba diglycolamine salt (560) Compound X1 (20) + glyphosate potassium salt (1261) + dicambabiproamine (560) Compound X1 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) Compound X1 (20) + Flumioxazin (89) + Dicamba Diglycolamine Salt (1261) This compound X1 (20) + flumioxazin (89) + dicambabiproamine (560) Compound X1 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X1 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) This compound X1 (20) + 2,4-D choline salt (1065) This compound X1 (20) + 2,4-D dimethylamine salt (1065) This compound X1 (20) + 2,4-D trollamine salt (1065) This compound X1 (20) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X1 (20) + glyphosate potassium salt (1261) + 2,4-D dimethylamine salt (1065) Compound X1 (20) + glyphosate potassium salt (1261) + 2,4-D trolamine salt (1065) Compound X1 (20) + glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Flumioxazin (89) + 2,4-D choline salt (1065) Compound X1 (20) + Flumioxazin (89) + 2,4-D dimethylamine salt (1065) This compound X1 (20) + Flumioxazin (89) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X1 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X1 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Mesotrione (210) + Glyphosate potassium salt (1261) Compound X1 (20) + mesotrione (210) + dicamba diglycolamine salt (560) This compound X1 (20) + mesotrione (210) + dicambabiproamine (560) Compound X1 (20) + Mesotrione (210) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X1 (20) + Mesotrione (210) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X1 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) Compound X1 (20) + Flumioxazin (89) + Mesotrione (210) + Dicamba Diglycolamine Salt (1261) Compound X1 (20) + flumioxazin (89) + mesotrione (210) + dicambabiproamine (560) Compound X1 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X1 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X1 (20) + Mesotrione (210) + 2,4-D Choline Salt (1065) Compound X1 (20) + mesotrione (210) + 2,4-D dimethylamine salt (1065) This compound X1 (20) + mesotrione (210) + 2,4-D trolamine salt (1065) This compound X1 (20) + mesotrione (210) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Mesotrione (210) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Compound X1 (20) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X1 (20) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-D Triolamine salt (1065) Compound X1 (20) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Flumioxazin (89) + Mesotrione (210) + 2,4-D Choline Salt (1065) Compound X1 (20) + Flumioxazin (89) + Mesotrione (210) + 2,4-D dimethylamine salt (1065) Compound X1 (20) + Flumioxazin (89) + Mesotrione (210) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X1 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X1 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) Compound X1 (20) + Tembotrione (92) + Dicambadiglycolamine salt (560) This compound X1 (20) + tembotrione (92) + dicambabiproamine (560) Compound X1 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X1 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X1 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) Compound X1 (20) + Flumioxazin (89) + Tembotrione (92) + Dicambadiglycolamine salt (1261) Compound X1 (20) + flumioxazin (89) + tembotrione (92) + dicambabiproamine (560) Compound X1 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X1 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X1 (20) + tembotrione (92) + 2,4-D choline salt (1065) Compound X1 (20) + tembotrione (92) + 2,4-D dimethylamine salt (1065) This compound X1 (20) + tembotrione (92) + 2,4-D-trolamine salt (1065) This compound X1 (20) + tembotrione (92) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X1 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X1 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D-trolamine salt (1065) Compound X1 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Flumioxazin (89) + Tembotrione (92) + 2,4-D choline salt (1065) Compound X1 (20) + Flumioxazin (89) + Tembotrione (92) + 2,4-D dimethylamine salt (1065) Compound X1 (20) + Flumioxazin (89) + Tembotrione (92) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X1 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X1 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Clethodim (200) + Glyphosate potassium salt (1261) Compound X1 (20) + clethodim (200) + dicamba diglycolamine salt (560) This compound X1 (20) + clethodim (200) + dicambabiproamine (560) Compound X1 (20) + Clethodim (200) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X1 (20) + Clethodim (200) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X1 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) This compound X1 (20) + flumioxazin (89) + clethodim (200) + dicamba diglycolamine salt (1261) Compound X1 (20) + flumioxazin (89) + clethodim (200) + dicambabiproamine (560) Compound X1 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X1 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X1 (20) + Clethodim (200) + 2,4-D choline salt (1065) Compound X1 (20) + clethodim (200) + 2,4-D dimethylamine salt (1065) This compound X1 (20) + clethodim (200) + 2,4-D trolamine salt (1065) Compound X1 (20) + clethodim (200) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X1 (20) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X1 (20) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-D trolamine salt (1065) Compound X1 (20) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + flumioxazin (89) + clethodim (200) + 2,4-D choline salt (1065) Compound X1 (20) + flumioxazin (89) + clethodim (200) + 2,4-D dimethylamine salt (1065) Compound X1 (20) + Flumioxazin (89) + Clethodim (200) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X1 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X1 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + methoxybicyclon (100) + glyphosate potassium salt (1261) Compound X1 (20) + methoxybicyclone (100) + dicamba diglycolamine salt (560) This compound X1 (20) + methoxybicyclon (100) + dicambabiproamine (560) Compound X1 (20) + methoxybicyclon (100) + glyphosate potassium salt (1261) + dicamba diglycolamine salt (560) Compound X1 (20) + methoxybicyclon (100) + glyphosate potassium salt (1261) + dicambabiproamine (560) Compound X1 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) Compound X1 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Dicamba Diglycolamine Salt (1261) Compound X1 (20) + flumioxazin (89) + methoxybicyclon (100) + dicambabiproamine (560) Compound X1 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X1 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X1 (20) + methoxybicyclon (100) + 2,4-D choline salt (1065) Compound X1 (20) + methoxybicyclon (100) + 2,4-D dimethylamine salt (1065) This compound X1 (20) + methoxybicyclone (100) + 2,4-D trolamine salt (1065) This compound X1 (20) + methoxybicyclon (100) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + methoxybicyclon (100) + glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X1 (20) + methoxybicyclon (100) + glyphosate potassium salt (1261) + 2,4-D dimethylamine salt (1065) Compound X1 (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D Triolamine salt (1065) Compound X1 (20) + methoxybicyclon (100) + glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Flumioxazin (89) + Methoxybicyclon (100) + 2,4-D choline salt (1065) Compound X1 (20) + Flumioxazin (89) + Methoxybicyclon (100) + 2,4-D dimethylamine salt (1065) Compound X1 (20) + Flumioxazin (89) + Methoxybicyclon (100) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X1 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X1 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + pyroxasulfone (112) + glyphosate potassium salt (1261) Compound X1 (20) + pyroxasulfone (112) + dicamba diglycolamine salt (560) This compound X1 (20) + pyroxasulfone (112) + dicambabiproamine (560) Compound X1 (20) + pyroxasulfone (112) + glyphosate potassium salt (1261) + dicamba diglycolamine salt (560) Compound X1 (20) + pyroxasulfone (112) + glyphosate potassium salt (1261) + dicambabiproamine (560) Compound X1 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) Compound X1 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Dicamba Diglycolamine Salt (1261) This compound X1 (20) + flumioxazin (89) + pyroxasulfone (112) + dicambabiproamine (560) Compound X1 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X1 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X1 (20) + pyroxasulfone (112) + 2,4-D choline salt (1065) Compound X1 (20) + pyroxasulfone (112) + 2,4-dimethylamine salt (1065) This compound X1 (20) + pyroxasulfone (112) + 2,4-D-trolamine salt (1065) This compound X1 (20) + pyroxasulfone (112) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + pyroxasulfone (112) + glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X1 (20) + pyroxasulfone (112) + glyphosate potassium salt (1261) + 2,4-dimethylamine salt (1065) Compound X1 (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D-trolamine salt (1065) Compound X1 (20) + pyroxasulfone (112) + glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Flumioxazin (89) + Pyroxasulfone (112) + 2,4-D choline salt (1065) Compound X1 (20) + Flumioxazin (89) + Pyroxasulfone (112) + 2,4-Dimethylamine Salt (1065) Compound X1 (20) + Flumioxazin (89) + Pyroxasulfone (112) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X1 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X1 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) Compound X1 (20) + Ikafolin methyl (150) + Dicamba diglycolamine salt (560) This compound X1 (20) + icaforin methyl (150) + dicambabiproamine (560) Compound X1 (20) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X1 (20) + Icaphorin Methyl (150) + Glyphosate Potassium Salt (1261) + Dicambabiproamine (560) Compound X1 (20) + Flumioxazin (89) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) This compound X1 (20) + flumioxazin (89) + icaforin methyl (150) + dicamba diglycolamine salt (1261) Compound X1 (20) + flumioxazin (89) + icaforin methyl (150) + dicambabiproamine (560) Compound X1 (20) + Flumioxazin (89) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X1 (20) + Flumioxazin (89) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X1 (20) + Icaphorin methyl (150) + 2,4-D choline salt (1065) Compound X1 (20) + Icaphorin methyl (150) + 2,4-D dimethylamine salt (1065) Compound X1 (20) + Ikafolin methyl (150) + 2,4-D-trolamine salt (1065) This compound X1 (20) + icaphorin methyl (150) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Icaphorin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Compound X1 (20) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X1 (20) + Ikafolin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-D Triolamine Salt (1065) Compound X1 (20) + Icaphorin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-D 2-Ethylhexyl (1065) Compound X1 (20) + Flumioxazin (89) + Ikafolin methyl (150) + 2,4-D choline salt (1065) Compound X1 (20) + Flumioxazin (89) + Ikafolin methyl (150) + 2,4-D dimethylamine salt (1065) Compound X1 (20) + Flumioxazin (89) + Icaforin methyl (150) + 2,4-D 2-ethylhexyl (1065) Compound X1 (20) + Flumioxazin (89) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X1 (20) + Flumioxazin (89) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X1 (20) + Flumioxazin (89) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Glyphosate potassium salt (1261) Compound X2 (20) + dicamba diglycolamine salt (560) This compound X2 (20) + dicambabiproamine (560) Compound X2 (20) + Glyphosate Potassium Salt (1261) + Dicamba Diglycolamine Salt (560) Compound X2 (20) + glyphosate potassium salt (1261) + dicambabiproamine (560) Compound X2 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) This compound X2 (20) + flumioxazin (89) + dicamba diglycolamine salt (1261) This compound X2 (20) + flumioxazin (89) + dicambabiproamine (560) Compound X2 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X2 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) This compound X2 (20) + 2,4-D choline salt (1065) This compound X2 (20) + 2,4-D dimethylamine salt (1065) This compound X2 (20) + 2,4-D trollamine salt (1065) This compound X2 (20) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Compound X2 (20) + glyphosate potassium salt (1261) + 2,4-D dimethylamine salt (1065) Compound X2 (20) + Glyphosate Potassium Salt (1261) + 2,4-D Triolamine Salt (1065) Compound X2 (20) + glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Flumioxazin (89) + 2,4-D choline salt (1065) Compound X2 (20) + Flumioxazin (89) + 2,4-D dimethylamine salt (1065) This compound X2 (20) + Flumioxazin (89) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X2 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X2 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Mesotrione (210) + Glyphosate potassium salt (1261) Compound X2 (20) + Mesotrione (210) + Dicamba Diglycolamine Salt (560) This compound X2 (20) + mesotrione (210) + dicambabiproamine (560) Compound X2 (20) + Mesotrione (210) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X2 (20) + Mesotrione (210) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X2 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) Compound X2 (20) + Flumioxazin (89) + Mesotrione (210) + Dicamba Diglycolamine Salt (1261) This compound X2 (20) + flumioxazin (89) + mesotrione (210) + dicambabiproamine (560) Compound X2 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X2 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X2 (20) + Mesotrione (210) + 2,4-D Choline Salt (1065) Compound X2 (20) + Mesotrione (210) + 2,4-D dimethylamine salt (1065) This compound X2 (20) + mesotrione (210) + 2,4-D trolamine salt (1065) This compound X2 (20) + mesotrione (210) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Mesotrione (210) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Compound X2 (20) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X2 (20) + Mesotrione (210) + Glyphosate Potassium Salt (1261) + 2,4-D Triolamine Salt (1065) Compound X2 (20) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Flumioxazin (89) + Mesotrione (210) + 2,4-D Choline Salt (1065) Compound X2 (20) + Flumioxazin (89) + Mesotrione (210) + 2,4-D dimethylamine salt (1065) Compound X2 (20) + Flumioxazin (89) + Mesotrione (210) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X2 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X2 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) Compound X2 (20) + Tembotrione (92) + Dicambadiglycolamine salt (560) This compound X2 (20) + tembotrione (92) + dicambabiproamine (560) Compound X2 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X2 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X2 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) Compound X2 (20) + Flumioxazin (89) + Tembotrione (92) + Dicambadiglycolamine salt (1261) Compound X2 (20) + flumioxazin (89) + tembotrione (92) + dicambabiproamine (560) Compound X2 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X2 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X2 (20) + Tembotrione (92) + 2,4-D Choline Salt (1065) Compound X2 (20) + Tembotrione (92) + 2,4-D dimethylamine salt (1065) Compound X2 (20) + Tembotrione (92) + 2,4-D-trolamine salt (1065) This compound X2 (20) + tembotrione (92) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X2 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X2 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D-trolamine salt (1065) Compound X2 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Flumioxazin (89) + Tembotrione (92) + 2,4-D Choline Salt (1065) Compound X2 (20) + Flumioxazin (89) + Tembotrione (92) + 2,4-D dimethylamine salt (1065) Compound X2 (20) + Flumioxazin (89) + Tembotrione (92) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X2 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X2 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Clethodim (200) + Glyphosate potassium salt (1261) This compound X2 (20) + clethodim (200) + dicamba diglycolamine salt (560) This compound X2 (20) + clethodim (200) + dicambabiproamine (560) Compound X2 (20) + Clethodim (200) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X2 (20) + Clethodim (200) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X2 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) Compound X2 (20) + Flumioxazin (89) + Clethodim (200) + Dicamba Diglycolamine Salt (1261) Compound X2 (20) + flumioxazin (89) + clethodim (200) + dicambabiproamine (560) Compound X2 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X2 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) This compound X2 (20) + clethodim (200) + 2,4-D choline salt (1065) Compound X2 (20) + Clethodim (200) + 2,4-D dimethylamine salt (1065) This compound X2 (20) + clethodim (200) + 2,4-D trolamine salt (1065) This compound X2 (20) + clethodim (200) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Clethodim (200) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Compound X2 (20) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X2 (20) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-D trolamine salt (1065) Compound X2 (20) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Flumioxazin (89) + Clethodim (200) + 2,4-D Choline Salt (1065) Compound X2 (20) + Flumioxazin (89) + Clethodim (200) + 2,4-D dimethylamine salt (1065) Compound X2 (20) + Flumioxazin (89) + Clethodim (200) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X2 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X2 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + methoxybicyclon (100) + glyphosate potassium salt (1261) Compound X2 (20) + methoxybicyclone (100) + dicamba diglycolamine salt (560) This compound X2 (20) + methoxybicyclon (100) + dicambabiproamine (560) Compound X2 (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X2 (20) + methoxybicyclon (100) + glyphosate potassium salt (1261) + dicambabiproamine (560) Compound X2 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) Compound X2 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Dicamba Diglycolamine Salt (1261) Compound X2 (20) + flumioxazin (89) + methoxybicyclon (100) + dicambabiproamine (560) Compound X2 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X2 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X2 (20) + methoxybicyclon (100) + 2,4-D choline salt (1065) Compound X2 (20) + methoxybicyclon (100) + 2,4-D dimethylamine salt (1065) This compound X2 (20) + methoxybicyclone (100) + 2,4-D trolamine salt (1065) This compound X2 (20) + methoxybicyclon (100) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X2 (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X2 (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D Triolamine salt (1065) Compound X2 (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Flumioxazin (89) + Methoxybicyclon (100) + 2,4-D Choline Salt (1065) Compound X2 (20) + Flumioxazin (89) + Methoxybicyclon (100) + 2,4-D dimethylamine salt (1065) Compound X2 (20) + Flumioxazin (89) + Methoxybicyclon (100) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X2 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X2 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + pyroxasulfone (112) + glyphosate potassium salt (1261) This compound X2 (20) + pyroxasulfone (112) + dicamba diglycolamine salt (560) This compound X2 (20) + pyroxasulfone (112) + dicambabiproamine (560) Compound X2 (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X2 (20) + pyroxasulfone (112) + glyphosate potassium salt (1261) + dicambabiproamine (560) Compound X2 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) Compound X2 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Dicamba Diglycolamine Salt (1261) This compound X2 (20) + flumioxazin (89) + pyroxasulfone (112) + dicambabiproamine (560) Compound X2 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X2 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X2 (20) + pyroxasulfone (112) + 2,4-D choline salt (1065) Compound X2 (20) + pyroxasulfone (112) + 2,4-dimethylamine salt (1065) Compound X2 (20) + Pyroxasulfone (112) + 2,4-D-Trolamine Salt (1065) This compound X2 (20) + pyroxasulfone (112) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X2 (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X2 (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D-trolamine salt (1065) Compound X2 (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Flumioxazin (89) + Pyroxasulfone (112) + 2,4-D choline salt (1065) Compound X2 (20) + Flumioxazin (89) + Pyroxasulfone (112) + 2,4-Dimethylamine Salt (1065) Compound X2 (20) + Flumioxazin (89) + Pyroxasulfone (112) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X2 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X2 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) Compound X2 (20) + Ikafolin methyl (150) + Dicamba diglycolamine salt (560) This compound X2 (20) + icaforin methyl (150) + dicambabiproamine (560) Compound X2 (20) + Ikafolin Methyl (150) + Glyphosate Potassium Salt (1261) + Dicamba Diglycolamine Salt (560) Compound X2 (20) + Icaphorin Methyl (150) + Glyphosate Potassium Salt (1261) + Dicambabiproamine (560) Compound X2 (20) + Flumioxazin (89) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) Compound X2 (20) + Flumioxazin (89) + Ikafolin methyl (150) + Dicamba diglycolamine salt (1261) Compound X2 (20) + Flumioxazin (89) + Icaforin methyl (150) + Dicambabiproamine (560) Compound X2 (20) + Flumioxazin (89) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X2 (20) + Flumioxazin (89) + Icaforin methyl (150) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X2 (20) + Icaphorin methyl (150) + 2,4-D choline salt (1065) Compound X2 (20) + Ikafolin methyl (150) + 2,4-D dimethylamine salt (1065) Compound X2 (20) + Ikafolin methyl (150) + 2,4-D trollamine salt (1065) This compound X2 (20) + Icaphorin methyl (150) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Ikafolin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Compound X2 (20) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X2 (20) + Ikafolin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-D Triolamine Salt (1065) Compound X2 (20) + Icaphorin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-D 2-Ethylhexyl (1065) Compound X2 (20) + Flumioxazin (89) + Ikafolin methyl (150) + 2,4-D choline salt (1065) Compound X2 (20) + Flumioxazin (89) + Ikafolin methyl (150) + 2,4-D dimethylamine salt (1065) Compound X2 (20) + Flumioxazin (89) + Icaforin methyl (150) + 2,4-D 2-ethylhexyl (1065) Compound X2 (20) + Flumioxazin (89) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X2 (20) + Flumioxazin (89) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X2 (20) + Flumioxazin (89) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Glyphosate potassium salt (1261) This compound X3 (20) + dicamba diglycolamine salt (560) This compound X3 (20) + dicambabiproamine (560) Compound X3 (20) + Glyphosate Potassium Salt (1261) + Dicamba Diglycolamine Salt (560) Compound X3 (20) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X3 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) Compound X3 (20) + Flumioxazin (89) + Dicamba Diglycolamine Salt (1261) This compound X3 (20) + flumioxazin (89) + dicambabiproamine (560) Compound X3 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X3 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) This compound X3 (20) + 2,4-D choline salt (1065) This compound X3 (20) + 2,4-D dimethylamine salt (1065) This compound X3 (20) + 2,4-D trollamine salt (1065) This compound X3 (20) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Compound X3 (20) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X3 (20) + Glyphosate Potassium Salt (1261) + 2,4-D Triolamine Salt (1065) Compound X3 (20) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Flumioxazin (89) + 2,4-D choline salt (1065) Compound X3 (20) + Flumioxazin (89) + 2,4-D dimethylamine salt (1065) This compound X3 (20) + Flumioxazin (89) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X3 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X3 (20) + Flumioxazin (89) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Mesotrione (210) + Glyphosate potassium salt (1261) This compound X3 (20) + mesotrione (210) + dicamba diglycolamine salt (560) This compound X3 (20) + mesotrione (210) + dicambabiproamine (560) Compound X3 (20) + Mesotrione (210) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X3 (20) + Mesotrione (210) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X3 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) This compound X3 (20) + flumioxazin (89) + mesotrione (210) + dicamba diglycolamine salt (1261) This compound X3 (20) + flumioxazin (89) + mesotrione (210) + dicambabiproamine (560) Compound X3 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X3 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) This compound X3 (20) + mesotrione (210) + 2,4-D choline salt (1065) Compound X3 (20) + Mesotrione (210) + 2,4-D dimethylamine salt (1065) This compound X3 (20) + mesotrione (210) + 2,4-D trolamine salt (1065) Compound X3 (20) + Mesotrione (210) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Mesotrione (210) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Compound X3 (20) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X3 (20) + Mesotrione (210) + Glyphosate Potassium Salt (1261) + 2,4-D Triolamine Salt (1065) Compound X3 (20) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Flumioxazin (89) + Mesotrione (210) + 2,4-D Choline Salt (1065) Compound X3 (20) + Flumioxazin (89) + Mesotrione (210) + 2,4-D dimethylamine salt (1065) Compound X3 (20) + Flumioxazin (89) + Mesotrione (210) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X3 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X3 (20) + Flumioxazin (89) + Mesotrione (210) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) This compound X3 (20) + tembotrione (92) + dicamba diglycolamine salt (560) This compound X3 (20) + tembotrione (92) + dicambabiproamine (560) Compound X3 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X3 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X3 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) Compound X3 (20) + Flumioxazin (89) + Tembotrione (92) + Dicambadiglycolamine salt (1261) This compound X3 (20) + flumioxazin (89) + tembotrione (92) + dicambabiproamine (560) Compound X3 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X3 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X3 (20) + Tembotrione (92) + 2,4-D Choline Salt (1065) Compound X3 (20) + Tembotrione (92) + 2,4-D dimethylamine salt (1065) This compound X3 (20) + tembotrione (92) + 2,4-D-trolamine salt (1065) This compound X3 (20) + tembotrione (92) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Tembotrione (92) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Compound X3 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X3 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D-trolamine salt (1065) Compound X3 (20) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Flumioxazin (89) + Tembotrione (92) + 2,4-D Choline Salt (1065) Compound X3 (20) + Flumioxazin (89) + Tembotrione (92) + 2,4-D dimethylamine salt (1065) This compound X3 (20) + flumioxazin (89) + tembotrione (92) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X3 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X3 (20) + Flumioxazin (89) + Tembotrione (92) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Clethodim (200) + Glyphosate potassium salt (1261) This compound X3 (20) + clethodim (200) + dicamba diglycolamine salt (560) This compound X3 (20) + clethodim (200) + dicambabiproamine (560) Compound X3 (20) + Clethodim (200) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X3 (20) + Clethodim (200) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X3 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) This compound X3 (20) + flumioxazin (89) + clethodim (200) + dicamba diglycolamine salt (1261) This compound X3 (20) + flumioxazin (89) + clethodim (200) + dicambabiproamine (560) Compound X3 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X3 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) This compound X3 (20) + clethodim (200) + 2,4-D choline salt (1065) Compound X3 (20) + Clethodim (200) + 2,4-D dimethylamine salt (1065) This compound X3 (20) + clethodim (200) + 2,4-D trolamine salt (1065) This compound X3 (20) + clethodim (200) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Clethodim (200) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Compound X3 (20) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X3 (20) + Clethodim (200) + Glyphosate Potassium Salt (1261) + 2,4-D Triolamine Salt (1065) Compound X3 (20) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Flumioxazin (89) + Clethodim (200) + 2,4-D Choline Salt (1065) Compound X3 (20) + Flumioxazin (89) + Clethodim (200) + 2,4-D dimethylamine salt (1065) Compound X3 (20) + Flumioxazin (89) + Clethodim (200) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X3 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X3 (20) + Flumioxazin (89) + Clethodim (200) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) This compound X3 (20) + methoxybicyclone (100) + dicamba diglycolamine salt (560) This compound X3 (20) + methoxybicyclon (100) + dicambabiproamine (560) Compound X3 (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X3 (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X3 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) Compound X3 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Dicamba Diglycolamine Salt (1261) Compound X3 (20) + flumioxazin (89) + methoxybicyclon (100) + dicambabiproamine (560) Compound X3 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X3 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X3 (20) + methoxybicyclon (100) + 2,4-D choline salt (1065) Compound X3 (20) + methoxybicyclon (100) + 2,4-D dimethylamine salt (1065) This compound X3 (20) + methoxybicyclone (100) + 2,4-D trolamine salt (1065) This compound X3 (20) + methoxybicyclon (100) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X3 (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X3 (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D trolamine salt (1065) Compound X3 (20) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Flumioxazin (89) + Methoxybicyclon (100) + 2,4-D choline salt (1065) Compound X3 (20) + Flumioxazin (89) + Methoxybicyclon (100) + 2,4-D dimethylamine salt (1065) Compound X3 (20) + Flumioxazin (89) + Methoxybicyclon (100) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X3 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X3 (20) + Flumioxazin (89) + Methoxybicyclon (100) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) This compound X3 (20) + pyroxasulfone (112) + dicamba diglycolamine salt (560) This compound X3 (20) + pyroxasulfone (112) + dicambabiproamine (560) Compound X3 (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X3 (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X3 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) Compound X3 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Dicamba Diglycolamine Salt (1261) This compound X3 (20) + flumioxazin (89) + pyroxasulfone (112) + dicambabiproamine (560) Compound X3 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + Dicamba diglycolamine salt (560) Compound X3 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X3 (20) + pyroxasulfone (112) + 2,4-D choline salt (1065) Compound X3 (20) + pyroxasulfone (112) + 2,4-dimethylamine salt (1065) This compound X3 (20) + pyroxasulfone (112) + 2,4-D-trolamine salt (1065) This compound X3 (20) + pyroxasulfone (112) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X3 (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X3 (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D-trolamine salt (1065) Compound X3 (20) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Flumioxazin (89) + Pyroxasulfone (112) + 2,4-D choline salt (1065) Compound X3 (20) + Flumioxazin (89) + Pyroxasulfone (112) + 2,4-Dimethylamine Salt (1065) Compound X3 (20) + Flumioxazin (89) + Pyroxasulfone (112) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D choline salt (1065) Compound X3 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X3 (20) + Flumioxazin (89) + Pyroxasulfone (112) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) This compound X3 (20) + icaphorin methyl (150) + dicamba diglycolamine salt (560) This compound X3 (20) + icaforin methyl (150) + dicambabiproamine (560) Compound X3 (20) + Ikafolin Methyl (150) + Glyphosate Potassium Salt (1261) + Dicamba Diglycolamine Salt (560) Compound X3 (20) + Icaphorin Methyl (150) + Glyphosate Potassium Salt (1261) + Dicambabiproamine (560) Compound X3 (20) + Flumioxazin (89) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) This compound X3 (20) + flumioxazin (89) + icaforin methyl (150) + dicamba diglycolamine salt (1261) Compound X3 (20) + Flumioxazin (89) + Icaforin methyl (150) + Dicambabiproamine (560) Compound X3 (20) + Flumioxazin (89) + Ikafolin Methyl (150) + Glyphosate Potassium Salt (1261) + Dicamba Diglycolamine Salt (560) Compound X3 (20) + Flumioxazin (89) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) + Dicambabiproamine (560) Compound X3 (20) + Icaphorin Methyl (150) + 2,4-D Choline Salt (1065) Compound X3 (20) + Icaphorin methyl (150) + 2,4-D dimethylamine salt (1065) This compound X3 (20) + Ikafolin methyl (150) + 2,4-D trolamine salt (1065) This compound X3 (20) + Icaphorin methyl (150) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Icaphorin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Compound X3 (20) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X3 (20) + Ikafolin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-D Triolamine Salt (1065) Compound X3 (20) + Icaphorin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-D 2-Ethylhexyl (1065) Compound X3 (20) + Flumioxazin (89) + Icaforin methyl (150) + 2,4-D choline salt (1065) Compound X3 (20) + Flumioxazin (89) + Ikafolin methyl (150) + 2,4-D dimethylamine salt (1065) Compound X3 (20) + Flumioxazin (89) + Ikafolin methyl (150) + 2,4-D 2-ethylhexyl (1065) Compound X3 (20) + Flumioxazin (89) + Ikafolin Methyl (150) + Glyphosate Potassium Salt (1261) + 2,4-D Choline Salt (1065) Compound X3 (20) + Flumioxazin (89) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) + 2,4-Dimethylamine salt (1065) Compound X3 (20) + Flumioxazin (89) + Ikafolin methyl (150) + Glyphosate potassium salt (1261) + 2,4-D 2-ethylhexyl (1065) In the above "more preferred specific combinations," glyphosate potassium salt (1261) may be replaced with glufosinate P ammonium salt (328) or glufosinate ammonium salt (656). In one aspect of the method of the present invention, any of the above herbicide combinations can be applied to a field of HT5 corn. In one embodiment of the method of the present invention, any of the above-mentioned combinations of herbicides can be applied to a field cultivated with HT5 maize into which an ikaforin methyl resistance gene has been further introduced. In one aspect of the method of the present invention, a field of HT5 soybeans can be treated with any of the above herbicide combinations. In one embodiment of the method of the present invention, any of the above-mentioned combinations of herbicides can be applied to a field cultivated with HT5 soybean into which an ikaforin methyl resistance gene has been further introduced.

[0072] In the cultivation of the present invention crop, plant nutritional management can be carried out as in general cultivation of the present invention crop. The fertilization system may be variable fertilization based on precision agriculture or conventional uniform fertilization. [Example]

[0073] The present invention will be described below with reference to examples, but the present invention is not limited to these examples.

[0074] First, the evaluation criteria for herbicidal efficacy and phytotoxicity to crops shown in the following examples are shown below.

[0075] [Weed-killing effect] Herbicidal efficacy is evaluated on a scale of 0 to 100, with a score of "0" indicating that there is no or little difference in the emergence or growth of the test weeds at the time of the survey compared to untreated plants, and a score of "100" indicating that the test plants are completely dead or that emergence or growth is completely suppressed. [Crop damage] The assessment of damage to crops is indicated as "harmless" if little damage is observed, "small" if slight damage is observed, "medium" if moderate damage is observed, and "large" if severe damage is observed.

[0076] The herbicides used in the examples are as follows: In this paragraph, the numbers and units in parentheses represent the herbicide treatment rate (fluid ounces (fl oz) or ounces-force (oz) per acre). Formulations containing the present compound X1, the present compound X2, and the present compound X3 were prepared as follows. X1 preparation The emulsion was prepared by thoroughly mixing 5.39 g of the present compound X1, 7.50 g of Phenylsulfonat CAL, 7.50 g of Emulsogen TS290, and 79.61 g of Aromatic 200ND Fluid. X2 Preparation The emulsion was prepared by thoroughly mixing 5.39 g of the present compound X2, 7.50 g of Phenylsulfonat CAL, 7.50 g of Emulsogen TS290, and 79.61 g of Aromatic 200ND Fluid. X3 formulation The emulsion was prepared by thoroughly mixing 5.39 g of the present compound X3, 7.50 g of Phenylsulfonat CAL, 7.50 g of Emulsogen TS290, and 79.61 g of Aromatic 200ND Fluid. Rapidicil: Epirifenacil 55g / L Emulsifiable Concentrate (EC) (5 fl oz) Valor EZ: Flumioxazin 480g / L Aqueous Liquid Suspension (SC) (2.5 fl oz) Valor XLT: Flumioxazin 300g / kg + Chlorimuron Ethyl 103g / kg Water Dispersible Granule (WG) (4 oz) Fierce EZ: Flumioxazin 160g / L + Pyroxasulfone 204g / L Aqueous Liquid Suspension (SC) (7.5 fl oz) Fierce MTZ: Flumioxazin 60g / L + Pyroxasulfone 77g / L + Metribuzin 180g / L Aqueous Liquid Suspension (SC) (20 fl oz) Roundup PowerMAX 3: Glyphosate Potassium Salt 705g / L Liquid (SL) (30 fl oz) Liberty: Glufosinate Ammonium Salt 280g / L Liquid (SL) (32 fl oz) Callisto: Mesotrione 480g / L Aqueous Liquid Suspension (SC) (6 fl oz) Laudis: Tembotrione 419g / L Aqueous Liquid Suspension (SC) (3 fl oz) 2,4-D: 2,4-D trolamine salt 456g (acid equivalent) / L liquid (SL) (32 fl oz) Zidua: Pyroxasulfone 500g / L Aqueous Liquid Suspension (SC) (3 fl oz) XtendiMax: Dicamba Diglycolamine Salt 264g (acid equivalent) / L Liquid (SL) (22 fl oz) Select Max: Clethodim 116g / L Emulsifiable Concentrate (EC) (16 fl oz) Assure II: Quizalofop-P-ethyl 105g / L Emulsifiable Concentrate (EC) (8 fl oz) AAtrex: Atrazine 480g / L Aqueous Liquid Suspension (SC) (64 fl oz) DiFlexx Duo: Dicamba Diglycolamine Salt 151g (acid equivalent) / L + Tembotrione 32g / L Aqueous Liquid Suspension (SC) (40 fl oz) Maverick: Mesotrione 99g / L + Clopyralid Monoethanolamine Salt 63g (acid equivalent) / L + Pyroxasulfone 83g / L Aqueous Liquid Suspension (SC) (18 fl oz) Balance Flexx: Isoxaflutole 83g / L Aqueous Liquid Suspension (SC) (6 fl oz) Acuron: Atrazine 120g / L + Bicyclopyrone 7g / L + Mesotrione 29g / L + S-Metolachlor 256g / L Mixed Microparticle-Capsule Suspension (ZC) (96 fl oz) Resicore XL: Acetochlor 336g / L + Mesotrione 32g / L + Clopyralid Monoethanolamine Salt 22.8g (acid equivalent) / L Mixed Microparticle-Capsule Suspension (ZC) (88 fl oz) Sharpen: Saflufenacil 342g / L aqueous liquid suspension (SC) (2 fl oz) The adjuvants (spreading agent, ammonium sulfate (AMS) or drift-reducing adjuvant) used in the examples are as follows: The numbers indicate the adjuvant concentration in the spray solution. Induce: 0.25% v / v Agri-Dex: 1% v / v AMS: 2% w / v Intact Maxx: 1.75% v / v

[0077] Examples 1 to 32 (tillage cultivation) Seeds of the crop of the present invention are sown in a field that has been plowed to a substantially bare soil (weeds include: giant redroot pigweed resistant to atrazine, an ALS inhibitor, an HPPD inhibitor, and glyphosate and carrying the R98G mutation in PPX2; waterhemp resistant to atrazine, an ALS inhibitor, an HPPD inhibitor, and glyphosate and carrying the G210Δ mutation in PPX2; and glyphosate-resistant large crabgrass and broadleaf sedge). N days after the day of sowing, a spray solution prepared by diluting herbicide X and an adjuvant (or herbicide X alone if no adjuvant is used) with water is applied to the soil surface at a rate of 140 L / ha using a boom sprayer (treatment A). After emergence and growth of the inventive crop, when the true leaves reach the m-leaf stage, a spray solution prepared by diluting herbicide Y and an adjuvant with water is applied to the field at a spray volume of 190 L / ha using a boom sprayer (treatment B). Herbicide Y is applied to the foliage of the growing inventive crop and the weeds, and to the soil of the unemerged weeds. One month after the application of herbicide Y, phytotoxicity to the inventive crop and herbicidal efficacy against the weeds are evaluated. The inventive crop, herbicide X and adjuvant used in treatment A, herbicide Y and adjuvant used in treatment B, n, and m in each example are as shown in Table 1. In Table 1, "x2" means that the herbicide was used at twice the treatment rate. Table 1 [Table 1] Table 1 (continued) [Table 2] Table 1 (continued) [Table 3]

[0078] Examples 33 to 64 (no-till cultivation) In a field that has not been tilled since the previous harvest (where the following weeds have occurred or are occurring: giant redroot pigweed resistant to atrazine, ALS inhibitors, HPPD inhibitors, and glyphosate and carrying the R98G mutation in PPX2; waterhemp resistant to atrazine, ALS inhibitors, HPPD inhibitors, and glyphosate and carrying the G210Δ mutation in PPX2; and glyphosate-resistant large crabgrass and broadleaf moth), a spray solution prepared by diluting herbicide X and an adjuvant with water is applied to the field in a plane fashion using a boom sprayer at a rate of 190 L / ha (Treatment A). Herbicide X is applied to the foliage of growing weeds, and to the soil of unemerged weeds. N days after the treatment, seeds of the present invention crop are sown in the same field. After emergence and growth, when the true leaves reach the m-leaf stage, a spray solution prepared by diluting herbicide Y and an adjuvant with water is applied to the field at a spray volume of 190 L / ha using a boom sprayer (treatment B). Herbicide Y is applied to the foliage of the growing present invention crop and weeds, and to the soil of unemerged weeds. One month after the application of herbicide Y, phytotoxicity to the present invention crop and herbicidal efficacy against the weeds are evaluated. The present invention crop, herbicide X and adjuvant used in treatment A, herbicide Y and adjuvant used in treatment B, n, and m for each example are as shown in Table 2. In Table 2, "x2" means that the herbicide was used at twice the treatment rate. Table 2 [Table 4] Table 2 (continued) [Table 5] Table 2 (continued) [Table 6] Table 2 (continued) [Table 7] Table 2 (continued) [Table 8]

[0079] In the above Examples 1 to 64, it was confirmed that the herbicidal effect on weeds was excellent, and that the phytotoxicity to crops was not significant. [Industrial Applicability]

[0080] The weed control method of the present invention makes it possible to efficiently control weeds in areas where the crop of the present invention is cultivated.

Claims

1. A method for controlling weeds in a cultivated area of ​​at least one herbicide-resistant crop selected from the group consisting of corn and soybean, the method comprising the steps of sowing seeds of the herbicide-resistant crop and treating the cultivated area of ​​the herbicide-resistant crop with at least one herbicide selected from the group consisting of flumioxazin, epirifenacil, and the present compounds X1 to X3 shown below, wherein the herbicide-resistant crop has a bacterial PPO gene. 【Chemical 1】 This compound X1 【Chemistry 2】 This compound X2 【Chemistry 3】 This compound X3

2. The method according to claim 1, wherein the herbicide-tolerant crop is a maize line Zm_CSM63715 or MON80616 having a bacterial PPO gene.

3. 3. The method according to claim 2, wherein the herbicide-tolerant crop is a corn line that is a cross between the Zm_CSM63715 line or the MON80616 line and the MON87429 line that has the ft_t gene, the cp4 epsps gene, the pat gene, and the dmo gene.

4. 2. The method according to claim 1, wherein the herbicide-tolerant crop is a soybean strain Gm_CSM63717 or MON91445 having a bacterial PPO gene.

5. The method according to claim 4, wherein the herbicide-tolerant crop is a soybean line that is a cross between Gm_CSM63717 line or MON91445 line and Gm_CSM63714 line having the ft_tv7 gene, the tdo gene, the pat gene, and the dmo gene.

6. The method according to claim 4, wherein the herbicide-tolerant crop is a soybean line that is a cross between the Gm_CSM63717 line or the MON91445 line and the MON89788 line having the cp4 epsps gene.

7. The method according to claim 4, wherein the herbicide-tolerant crop is a soybean line that is a cross between the Gm_CSM63717 line or the MON91445 line and the MON89788 line and the MON89788 line.

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