Fragrance Compounds

Abstract

The present invention provides novel fragrance mixtures based on fragrances that inherently have balsamic and / or leathery scent notes. The fragrance mixture comprises or consists of: (a) at least one first fragrance having balsamic and / or leathery scent notes; and (b) p-Tolylmethanol (pTM).

Description

[Technical field]

[0001] The present invention relates to the field of fragrances and to fragrance mixtures containing p-tolylmethanol (pTM) having improved odor notes. [Background technology]

[0002] In the perfume industry, there is a great demand for fragrances, especially notes, that allow the perfumer to expand their palette, especially those that, in small doses, have a big impact on other fragrances, changing them for the better.

[0003] P-Tolylmethanol [ka] (Cas Nr.:589-18-4) is a known compound, but nothing is known about its fragrance potential.

[0004] For example, Patent Document 1 describes a recording medium that has excellent fixability without nozzle clogging by blending p-tolylmethanol, alkylamide, and piperonyl alcohol as essential components with a colorant.

[0005] Patent Document 2 claims a process for obtaining poly(arylene sulfide), which includes the following steps: (1) a polymerization step of subjecting at least one sulfur source and a dihaloaromatic compound to a polymerization reaction in an organic amide solvent; (2) a reaction step of adding a hydroxyl group-containing organic compound to react the formed polymer with the hydroxyl group-containing organic compound; and (3) a recovery step of recovering the formed polymer from the polymerization reaction system, wherein the hydroxyl group-containing organic compound is p-tolylmethanol.

[0006] US Pat. No. 5,399,633 claims a polymer comprising a polyacrylate homopolymer or copolymer backbone and at least one moiety derived from p-tolylmethanol.

[0007] US Patent No. 5,399,633 discloses a one-pot process for the preparation of imines comprising the steps of refluxing a reaction mixture containing a catalyst, an alcohol, an aniline, a base and a solvent; and cooling the reaction mixture and then separating the catalyst under a strong magnetic field, wherein the alcohol is p-tolylmethanol. [Prior art documents] [Patent documents]

[0008] [Patent Document 1] Japanese Patent Application Publication No. 4-222876 [Patent Document 2] US Patent Publication No. 2012 / 065361 [Patent Document 3] International Publication No. 2012 / 007463 A1 [Patent Document 4] Indian Patent No. 361896 Summary of the Invention [Means for solving the problem]

[0009] It is therefore an object of the present invention to provide novel fragrance mixtures based on fragrances which inherently have balsamic and / or leathery odor notes, which mixtures show a particular improvement with respect to the more intense woody, powdery, cinnamic, balsamic and leathery odor notes, while odor notes such as, for example, vanilla, plastic, fatty and smoky are reduced. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0010] A first object of the present invention resides in a fragrance mixture comprising or consisting of: (a) at least one first fragrance having balsamic and / or leathery scent notes; and (b) p-Tolylmethanol.

[0011] Surprisingly, it has been observed that even in very small amounts, P-tolylmethanol can increase, improve and / or adjust the original odor of a first fragrance with balsamic and / or leathery odor notes. In particular, the balsamic and / or leathery odor notes are increased and made more intense, while other desirable odor notes such as woody, powdery or cinnamon are emphasized and less desirable odor notes such as vanilla, plastic, oily or smoky are attenuated. Thus, the perfumer's fragrance palette is considerably expanded by adding only small amounts of the ingredient.

[0012] <P-トリルメタノール> p-Tolylmethanol is a known compound available in the form of white crystals with a melting point of 59-61° C. and a partition coefficient logP of 1.50. This compound is commercially available, for example from Sigma-Aldrich.

[0013] <First Fragrance> The first fragrance group is characterized by a dominant balsamic and / or leathery odor. Typical examples are: ethyl vanillin, vanillin, propenyl guaethol, coumarin delta octalactone, benzyl cinnamate, 3-phenylpropanol, methyl lightone, furaneol, isopropylcyclohexanol, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1-penten-3-one, cade oil, styrax oil, 2,3,3-trimethylindanone, butylquinoline, isobutylquinoline and mixtures thereof.

[0014] The mixture according to the invention may comprise the first fragrance and p-tolylmethanol (pTM) in a ratio of about 98:2 to about 99.9:0.5% by weight, with pTM being preferably present in an amount ranging from about 0.6 to 1.0% by weight, calculated on the mixture.

[0015] <Solvent> In a preferred embodiment, the mixture according to the invention may comprise at least one solvent. Suitable solvents are selected from the group consisting of water, ethanol, propylene glycol, dipropylene glycol, glycerol and triethyl citrate. Typically, the at least one solvent is present in the mixture in an amount ranging from about 10 to about 90% by weight, preferably from about 25 to about 50% by weight.

[0016] <PERFUME COMPOSITIONS> Another object of the invention relates to a fragrance composition comprising a mixture as defined above and at least one second fragrance different from the first fragrance and from pTM. The second fragrance may be chosen from the group consisting of: [Table 1-1] [Table 1-2] [Table 1-3] [Table 1-4] [Table 1-5] [Table 1-6] [Table 1-7] The fragrance composition may contain either the pTM alone or a mixture of the pTM with the first fragrance in an amount ranging from about 0.01 to about 2% by weight of the composition, preferably from about 0.1 to 1% by weight.

[0017] <Cosmetics and personal care products> Another object of the present invention relates to a cosmetic or personal care product comprising said fragrance mixture or said perfume composition. Said product may contain said fragrance mixture or perfume composition in an amount ranging from about 0.01 to about 2% by weight of the product, preferably from about 0.1 to about 1% by weight. The composition may represent, for example, a cosmetic cream, lotion, spray, milk, ointment, gel or mouse.

[0018] The preparations according to the invention may be used as antidandruff agents, anti-irritation agents, irritation inhibitors, antioxidants, astringents, antiperspirants, preservatives, antistatic agents, binders, buffers, carrier substances, chelating agents, cell stimulants, cleaning agents, care agents, deodorants, antiperspirants, softeners, emulsifiers, enzymes, essential oils, fibres, film-forming agents, fixing agents, foam-forming agents, foam stabilisers, anti-foaming substances, foam boosters, gelling agents, gel formers, hair care agents, hair setting agents, hair straightening agents, moisturising agents, moisturising substances, bleaching agents, strengthening agents, stain removers, optical brighteners Impregnating agents, antifouling agents, friction reducers, lubricants, moisturizing creams, ointments, opacifying agents, plasticizers, coating agents, polishing agents, glossing agents, polymers, powders, proteins, re-oiling agents, polishing agents, silicones, hair promoters, cooling agents, skin cooling agents, heat retaining agents, skin heat retaining agents, stabilizers, UV absorbers, UV filters, detergents, thickeners, vitamins, oils and fats, waxes, fats, phospholipids, saturated fatty acids, mono- or polyunsaturated fatty acids, alpha-hydroxy acids, polyhydroxy fatty acids, liquefying agents, dyes, coloring protection agents, pigments, odor substances, polyols, surfactants, electrolytes, organic solvents or silicone derivatives may be contained as additional auxiliaries and additives.

[0019] <Surfactant> Preferred auxiliaries and additives are anionic and / or amphoteric or zwitterionic surfactants. Nonionic and cationic surfactants may also be present in the composition. Suitable examples are described together with the paragraph dealing with emulsifiers.

[0020] Representative examples of anionic and zwitterionic surfactants include the following: Almondamidopropylamine oxide, almondamidopropyl betaine, aminopropyl lauryl glutamine, C12-15 ammonium alkyl sulfate, C12-16 ammonium alkyl sulfate, ammonium caprylyl sulfate, coco monoglyceride ammonium sulfate, ammonium cocoyl sulfate, ammonium cocoyl isethionate, ammonium cocoyl sarcosinate, C12-15 ammonium pareth sulfate, C9-10 ammonium perfluoroalkyl sulfonate, ammonium dinonyl sulfosuccinate, ammonium dodecylbenzenesulfonate, ammonium isostearate, ammonium laureth-6 carboxylate, ammonium laureth-8 carboxylate, ammonium laureth sulfate, ammonium laureth-5 sulfate, ammonium laureth-7 sulfate, ammonium laureth-9 sulfate, ammonium laureth-12 sulfate, ammonium lauroyl sarcosinate, ammonium lauryl sulfate, ammonium lauryl sulfosuccinate, ammonium myreth sulfate, ammonium myristyl sulfate, ammonium nonoxynol-4 sulfate, ammonium nonoxynol-30 sulfate, hydrolyzed coco Lagen, AMP-rosostearoyl hydrolyzed collagen, AMP-rosostearoyl hydrolyzed collagen, AMP-rosostearoyl hydrolyzed keratin, AMP-rosostearoyl hydrolyzed soy protein, AMP-rosostearoyl hydrolyzed wheat protein, apricot amidopropyl betaine, arachidic acid, arginine hexyldecyl phosphate, avocado amidopropyl betaine, avocado oil glycereth-8 ester, babassu acid, babassu amidopropylamine oxide, babassu amidopropyl betaine, beeswax acid, behenamidopropyl betaine. behenyl betaine, beheneth-25, beheneth-30, behenic acid, behenyl betaine, bis-butyl dimethicone polyglyceryl-3, butoxynol-5 carboxylic acid, butoxynol-19 carboxylic acid, butyldimonium hydroxypropyl butyl glucoside chloride, butyldimonium hydroxypropyl lauryl glucoside chloride, butyl glucoside, butyl glucoside capric acid, butyl glucoside hydroxypropyl trimonium chloride, butyl octanoic acid, C18-36 acid, C20-40 acid, C30-50 acid, C16-22 acid amide MEA,Calcium Dodecyl Benzene Sulfonate, Calcium Lauroyl Taurate, C9-16 Alkane / Cycloalkane, C10-14 Alkyl Benzene Sulfonate, C12-14 Alkyl Diaminoethyl Glycine HCL, C9-15 Alkyl Phosphate, Candida Bombicola / Glucose / Rapeseed Methyl Ferment, Canolamidpropyl Betaine, Capric Acid, Caproic Acid, Caproyl Ethyl Glucoside, Caprylic / Capramidopropyl Betaine, Capryl-4 Carboxylic Acid, Capryl-6 Carboxylic Acid, Capryl-9 Carboxylic Acid, Capryloyl Collagen Capryloyl Amino Acids, Capryloyl Glycine, Capryloyl Hydrolyzed Collagen, Capryloyl Hydrolyzed Keratin, Capryloyl Keratin Amino Acids, Capryloyl Silk Amino Acids Caprylyl / Capryl Glucoside, Caprylyl / Capryl Wheat Bran / Straw Glycoside, Caprylyl Glucoside, Caprylyl Glyceryl Ether, Caprylyl Pyrrolidone, Carnitine Ceteareth-20, Ceteareth-23, Ceteareth-24, Ceteareth-25, Ceteareth-27, Ceteareth-28, Ceteareth-29, Ceteareth-30, Ceteareth-33, Ceteareth -34 Ceteareth-40, Ceteareth-50, Ceteareth-55, Ceteareth-60, Ceteareth-80, Ceteareth-100, Ceteareth-25 carboxylic acid, Ceteareth-2 phosphate, Ceteareth-4 phosphate, Ceteareth-5 phosphate, Ceteareth-10 phosphate, Ceteth-20, Ceteth-23, Ceteth-24, Ceteth-25, Ceteth-30, Ceteth-40, Ceteth-45, Ceteth-150, Ceteth-8 phosphate, Ceteth-10 phosphate, Ceteth-20 phosphate, Cetoleth-22, Cetoleth-24, Cetoleth-25, Cetoleth-30, Cetyl betai , Chrysanthemum Sinense Flower Extract, C12-14 Hydroxyalkyl Hydroxyethyl Beta-Alanine, C12-14 Hydroxyalkyl Hydroxyethyl Sarcosine, Cocamidoethyl Betaine, Cocamidopropyl Amine Oxide, Cocamidopropyl Betaine Amide MEA Chloride, Cocamidopropyl Betaine, Cocamidopropyl Hydroxysultaine, Cocamine Oxide, Cocaminobutyric Acid, Cocoaminopropionic Acid, Coceth-7 Carboxylic Acid, Coceth-4 Glucoside, Cocoamphodipropionic Acid, Cocobetaine Amido Amphopropionic Acid, Cocobetaine,Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Coco-Glucoside, Coco-Glucoside Hydroxypropyltrimonium Chloride, Coco Hydroxysultaine, Coco-Morpholine Oxide, Coconut Acid, Coconut Oil Glycereth-8 Esters, Coco / Oleamidopropyl Betaine, Coco Slutate, Coco / Sunflower Amidopropyl Betaine, Cocoyl Choline Methosulfate, Cocoyl Glutamate, Cocoyl Hydrolyzed Collagen, Cocoyl Hydrolyzed Keratin, Cocoyl Hydrolyzed Oat Protein, Cocoyl Hydrolyzed Rice Protein, Cocoyl Hydrolyzed Silk, Cocoyl Hydrolyzed Soy Protein, Cocoyl Hydrolyzed Wheat Protein, Cocoyl Sarcosine, Corn Acid, Cottonseed Acid, Cottonseed Oil Glycereth-8 Ester, C10-16 Pareth-1, C10-16 Pareth-2, C11-13 Pareth-6, C11-13 Pareth-9, C11-13 Pareth-10, C11-15 Pareth-30, C11-15 Pareth-40, C12-13 Pareth-1, C12-13 Pareth-23, C12- 14 Par-5, C12-14 Par-9, C13-15 Par-21, C14-15 Par-8, C20-22 Par-30, C20-40 Par-40, C20-40 Par-95, C22-24 Par-33, C30-50 Par-40, C9-11 Par-6 carboxylic acid, C9-11 Par-8 carboxylic acid, C11-15 Par-7 carboxylic acid, C12-13 Par-5 carboxylic acid, C12-13 Par-7 carboxylic acid, C12-13 Par-8 carboxylic acid, C12-13 Par-12 carboxylic acid, C12-15 Par-7 carboxylic acid, C1 2-15 Pareth-8 carboxylic acid, C12-15 Pareth-12 carboxylic acid, C14-15 Pareth-8 carboxylic acid, C6-10 Pareth-4 phosphate, C12-13 Pareth-2 phosphate, C12-13 Pareth-10 phosphate, C12-15 Pareth-6 phosphate, C12-15 Pareth-8 phosphate, C12-15 Pareth-10 phosphate, C12-16 Pareth-6 phosphate, C4-18 Perfluoroalkylethylthiohydroxypropyltrimonium chloride, Cupuasamidopropyl betaine, DEA-C12-13 alkyl sulfate, DEA-C12-15 alkyl sulfate,DEA-Ceteareth-2 Phosphate, DEA-Cetyl Sulfate, DEA-Cocoamphodipropionic Acid, DEA-C12-13 Pareth-3 Sulfate, DEA-Cyclocarboxypropyl Oleate, DEA-Dodecylbenzene Sulfonic Acid, DEA-Isostearic Acid, DEA-Laureth Sulfate, DEA-Lauryl Sulfate, DEA-Linoleic Acid, DEA-Methyl Myristate, DEA-Myristic Acid Sulfate, DEA-Myristic Acid, DEA-Myristyl Sulfate, DEA-Oleth-5 Phosphate, DEA-Oleth-20 Phosphate, DEA-Oleic Acid, Deceth-7 Carboxylic Acid, Deceth-7 Glycol, DEA-G ... Glucoside, Deceth-9 Phosphate, Decylamine Oxide, Decyl Betaine, Decyl Glucoside, Decyl Tetradeceth-30, Decyl Tetradecylamine Oxide, Lauramide-MEA Diammonium Sulfosuccinate, Lauryl Diammonium Sulfosuccinate, Diammonium Oleamide PEG-2 Sulfosuccinate, Dibutoxymethane, Di-CI2-15 Pareth-2 Phosphate, Di-CI2-15 Pareth-4 Phosphate, Di-CI2-15 Pareth-6 Phosphate, Di-C12-15 Pareth-8 Phosphate, Di-CI2-15 Pareth-10 Phosphate, Butanetetracarboxylic Acid Didodecyl, Diethylamine Laureth Sulfate, Diethylhexyl Sodium Sulfosuccinate, Dihydroxyethyl C8-10 Alkoxypropylamine Oxide, Dihydroxyethyl C9-11 Alkoxypropylamine Oxide, Dihydroxyethyl C12-15 Alkoxypropylamine Oxide, Dihydroxyethyl Cocamine Oxide, Dihydroxyethyl Lauramine Oxide, Dihydroxyethyl Stearamine Oxide, Dihydroxyethyl Tallowamine Oxide, Dimethicone PEG-7 Phosphate, Dimethicone PEG-10 Phosphate, Dimethicone P EG / PPG-7 / 4 Phosphate, Dimethicone PEG / PPG-12 / 4 Phosphate, Dimethicone / Polyglycerin-3 Crosspolymer, Dimethicone Propyl PG-Betaine, Dimyristyl Phosphate, Dioleoylamidoethyl Hydroxyethylmonium Methosulfate, DIPA-Hydrogenated Cocoate, DIPA-Lanolate, DIPA-Myristate, Dipotassium Capryloyl Glutamate, Dipotassium Lauryl Sulfosuccinate, Dipotassium Undecylenoyl Glutamate, Disodium Sulfosuccinate, Disodium Caproate, Disodium Caproate, Babasamido MEA-Diacetate, Disodium Caproate,Disodium Caproamphodipropionate, Disodium Capryloamphodiacetate, Disodium Capryloamphodipropionate, Disodium Capryloyl Glutamate, Disodium Cetearyl Sulfosuccinate, Disodium Cetyl Phenyl Ether Disulfonate, Disodium Cetyl Sulfosuccinate, Disodium Cocamide MEA-Sulfosuccinate, Disodium Cocamide MIPA PEG-4 Sulfosuccinate, Disodium Cocamide MIPA-Sulfosuccinate, Disodium Cocamide PEG-3 Sulfosuccinate, Disodium Coceth-3 Sulfosuccinate UM, Cocoampho Carboxyethyl Hydroxypropyl Sulfonate Disodium, Cocoampho Diacetate Disodium, Cocoampho Dipropionate Disodium, Cocoglucoside Sulfosuccinate Disodium, Cocosulfosuccinate Disodium, Cocoyl Butyl Glucoceth-10 Sulfosuccinate Disodium, Cocoyl Glutamate Disodium, C12-14 Pareth-1 Sulfosuccinate Disodium, C12-14 Pareth-2 Sulfosuccinate Disodium, C12-15 Pareth-3 Sulfosuccinate Disodium, C12-14 Sec-Pareth-3 Sulfoco Disodium succinate, Disodium C12-14Sec-Pareth-5 Sulfosuccinate, Disodium C12-14Sec-Pareth-7 Sulfosuccinate, Disodium C12-14Sec-Pareth-9 Sulfosuccinate, Disodium C12-14Sec-Pareth-12 Sulfosuccinate, Disodium Deceth-5 Sulfosuccinate, Disodium Deceth-6 Sulfosuccinate, Disodium Decyl Phenyl Ether Disulfonate, Disodium Dihydroxyethyl Sulfosuccinyl Undecylenate, Disodium Ethylene Dicocamide PEG-15 Disulfinate, Hydrogenated cottonseed glyceride sulfosuccinate disodium, hydrogenated scutellaria glutamate disodium, hydroxydecyl sorbitol citrate disodium, isodecyl sulfosuccinate disodium, isostearamide MEA-sulfosuccinate disodium, isostearamide MIPA-sulfosuccinate disodium, isostearoyl amphodiacetate disodium, isostearoyl amphodipropionate disodium, isostearyl sulfosuccinate disodium, laneth-5 sulfosuccinate disodium, lauramide MEA-sulfosuccinate disodium,Lauramide MIPA Glycol Sulfosuccinate Disodium, Lauramide PEG-2 Sulfosuccinate Disodium, Lauramide PEG-5 Sulfosuccinate Disodium, Laureth-5 Carboxyamphodiacetate Disodium, Laureth-7 Citrate Disodium, Laureth Sulfosuccinate Disodium, Laureth-6 Sulfosuccinate Disodium, Laureth-9 Sulfo, Disodium succinate, disodium laureth-12 sulfosuccinate, disodium lauriminobishydroxypropylsulfonate, disodium lauriminodiacetate, disodium lauriminodipropionate, disodium lauriminodipropionate tocopheryl phosphate, disodium lauroyl diacetate, disodium lauroyl dipropionate, disodium N-lauroyl aspartate, disodium lauroyl glutamate, disodium lauryl phenyl ether disulfonate, disodium lauryl sulfosuccinate, myristamide Disodium MEA-sulfosuccinate, Disodium Nonoxynol-10 Sulfosuccinate, Disodium Oleamide MEA-sulfosuccinate, Disodium Oleamide MIPA-sulfosuccinate, Disodium Oleamide PEG-2 Sulfosuccinate, Disodium Oleamide Dipropionate, Disodium Oleate-3 Sulfosuccinate, Disodium Oleyl Phosphate, Disodium Oleyl Sulfosuccinate, Disodium Palmitamide PEG-2 Sulfosuccinate, Disodium Palmitoleamide PEG-2 Sulfosuccinate, Disodium PEG-4 Cocamide MIP Disodium A-Sulfosuccinate, Disodium PEG-12 Dimethicone Sulfosuccinate, Disodium PEG-8 Palm Glycerides Sulfosuccinate, Disodium PPG-2-Rosodeceth-7 Carboxyamphodiacetate, Disodium Ricinoleamide MEA-Sulfosuccinate, Disodium Sitosterol-14 Sulfosuccinate, Disodium Soybean Amphodiacetate, Disodium Stearamide MEA-Sulfosuccinate, Disodium Steariminodipropionate, Disodium Stearoyl Amphodiacetate, Disodium Stearoyl Glutamate , disodium stearyl sulfosuccinate, disodium stearyl sulfosuccinate, disodium 2-sulfolaurate, disodium 2-sulfopalmitate, disodium talamide MEA-sulfosuccinate, disodium tallowamide MEA-sulfosuccinate, disodium tallow amphodiacetate, disodium tallow iminodipropionate, disodium tallow sulfosuccinate, disodium tridecyl sulfosuccinate, disodium undecylenamide MEA-sulfosuccinate, disodium undecylenamide PEG-2 sulfosuccinate,Disodium Undecylenoyl Glutamate, Disodium Wheat Germ Amide MEA-Sulfosuccinate, Disodium Wheat Germ Amide PEG-2 Sulfosuccinate, Disodium Wheat Germ Amide Diacetate, Di-TEA-Cocamide Diacetate, Di-TEA-Oleamide PEG-2 Sulfosuccinate, Di-TEA-Palmitoyl Aspartate, Sodium Ditridecyl Sulfosuccinate, Dodecyl Benzene Sulfonic Acid, Erucamidopropyl Hydroxysultaine, Ethylhexyl-3 Carboxylate, Ethyl PEG-15 Cocamine Sulfate, Glyceryl Caprylyl Acetone Terephthalic Acid, Hexyldecanoic Acid, Hydrogenated Coconut Acid, Hydrogenated Laneth-25, Hydrogenated Menhaden Acid, Hydrogenated Palm Acid, Hydrogenated Palm Kernel Amine Oxide, Hydrogenated Tallow Acid, Hydrogenated Tallow Amine Oxide, Hydrogenated Tallow Betaine, Hydrogenated Tallow S-25, Hydrogenated Tallowyl Glutamic Acid, Hydrolyzed Candida Bombicola Extract, Hydroxyceteth-60, Hydroxyethyl Acetomonium PG-Dimethicone, Hydroxyethyl Butylamine Laureth Sulfate, Hydroxyethyl Carboxymethyl Cocamidopropylamine, Hydroxyethyl Hydroxypropyl C12-15 Alkyl Propylene Glycol, Pyramine Oxide, Hydroxyl Lauryl / Hydroxymyristyl Betaine, Hydroxystearic Acid, Hydroxysuccinimidyl C10-40 Isoalkyl Acid Salt, Hydroxysuccinimidyl C21-22 Isoalkyl Acid Salt, Hydroxysultaine, IPDI / PEG-15 Soy Oxide Copolymer, IPDI / PEG-15 Soy Ethonium Ethosulfate Copolymer, IPDI / PEG-15 Soy Glycinate Copolymer, Isoceteth-30, Isolaureth-4 Phosphate, Isopolyglyceryl-3 Dimethicone, Isopolyglyceryl-3 Dimethiconol, Isopropyl Alcohol. Lane 20, lane 25, lane 40, lane 41, lane 42, lane 43, lane 44, lane 45, lane 46, lane 47, lane 48, lane 49, lane 50, lane 51, lane 52, lane 53, lane 54, lane 55, lane 56, lane 57, lane 58, lane 59, lane 60, lane 61, lane 62, lane 63, lane 64, lane 65, lane 66, lane 67, lane 68, lane 69, lane 70, lane 71, lane 72, lane 73, lane 74, lane 75, lane 76, lane 77, lane 78, lane 79, lane 80, lane 81, lane 82, lane 83, lane 84, lane 85, lane 86, lane 87, lane 88, lane 89, lane 90, lane 91, lane 92, lane 93, lane 94, lane 95, lane 96, lane 97, lane 98, lane 99, lane 100, lane 101, lane 102, lane 103, lane 104, lane 105, lane 106, lane 107, lane 108, lane 109, lane 101, lane 109, lane 101, lane 102, lane 103, lane 104, lane 105, lane 106, lane 107, lane 108Lane-50, Lane-60, Lane-75, Lanolinic acid, Lauramidopropylamine oxide, Lauramidopropyl betaine, Lauramidopropyl hydroxysultaine, Lauramine oxide, Lauraminopropionic acid, Laurdimonium hydroxypropyl decyl glucoside chloride, Laurdimonium hydroxypropyl lauryl glucoside chloride, 16, Laureth-20, Laureth-21, Laureth-23, Laureth-25, Laureth-30, Laureth-38, Laureth-40, Laureth-3 carboxylic acid, Laureth-4 carboxylic acid, Laureth Laureth-5 carboxylic acid, laureth-6 carboxylic acid, laureth-8 carboxylic acid, laureth-10 carboxylic acid, laureth-11 carboxylic acid, laureth-12 carboxylic acid, laureth-13 carboxylic acid, laureth-14 carboxylic acid, laureth-17 carboxylic acid, laureth-6 citric acid, laureth-7 citric acid, laureth-1 phosphate, laureth-2 phosphate, laureth-3 phosphate, laureth-4 phosphate, laureth-7 phosphate, laureth-8 phosphate, laureth-7 tartaric acid, lauric acid, lauriminobispropanediol, lauriminodipropionic acid, lauroyl beta alanine, laureth Lauroyl collagen amino acid, lauroyl ethyltrimonium methosulfate, lauroyl hydrolyzed collagen, lauroyl hydrolyzed elastin, lauroyl methyl glucamide, lauroyl sarcosine, silk amino acid, lauryl betaine, lauryl dimethicone / polyglycerin-3 crosspolymer, lauryl dimonium hydroxypropyl cocoglucoside chloride, lauryl glucoside, lauryl glucoside hydroxypropyltrimonium chloride, lauryl glycol hydroxypropyl ether, lauryl hydroxysultaine, lauryl malamide, la Uryl Methyl Glucamide, Lauryl / Myristyl Glycol Hydroxypropyl Ether, Lauryl / Myristyl Wheat Bran / Straw Glycosides, Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Lauryl Pyrrolidone, Lauryl Sultaine, Linoleic Acid, Linolenic Acid, Flaxseed Acid, Lysine Cocoate, Macadamia Seed Oil Glycereth-8 Ester, Magnesium Coceth Sulfate, Magnesium Coco Sulfate, Magnesium Isododecyl Benzene Sulfonate, Magnesium Laureth-11 Carboxylate, Magnesium Laureth Sulfate, Magnesium Laureth-5 Sulfate,Magnesium Laureth-8 Sulfate, Magnesium Laureth-16 Sulfate, Magnesium Laureth-3 Sulfosuccinate, Magnesium Lauryl Hydroxypropyl Sulfonate, Magnesium Lauryl Sulfate, Magnesium Methyl Cocoyl Taurate, Magnesium Myreth Sulfate, Magnesium Oleth Sulfate, Magnesium / TEA-Coco Sulfate, Manicouagan Clay, MEA-Cocoate, MEA-Laureth-6 Carboxylate, MEA-Laureth Sulfate, MEA-Lauryl Sulfate, MEA-PPG-6 Laureth-7 Carboxylate, MEA-PPG-8-Steareth-7 Carboxylate , MEA-Undecylenate, Meroxapol 108, Meroxapol 174, Meroxapol 178, Meroxapol 254, Meroxapol 255, Meroxapol 258, Meroxapol 314, Methoxy PEG-450 Amido Glutaroyl Succinimide, Methoxy PEG-450 Amido Hydroxy Succinimidyl Succinate, Methoxy PEG-450 Maleimide, Methylmorpholine Oxide, Myramidopropylamine Oxide, Myramidopropyl Betaine, Mincamidopropylamine Oxide, Mincamidopropyl Betaine, MIPA C12-15 Pareth Sulfate, MIPA-Dodecylbenzene Sulfonate, MIPA-Laureth Sulfate, MIPA-Lauryl Sulfate, Mixed Isopropanolamine Lanolate, Mixed Isopropanolamine Lauryl Sulfate, Mixed Isopropanolamine Myristic Acid, Morpholine Oleate, Morpholine Stearate, Myreth-3 Carboxylic Acid, Myreth-5 Carboxylic Acid, Myristalkonium Chloride, Myristamidopropylamine Oxide, Myristamidopropyl Betaine, Myristamidopropyl Dimethylamine Phosphate, Myristamidopropyl Hydroxysultaine, Myristamidopropyl Stamidopropyl PG-dimonium chloride phosphate, Myristamine oxide, Myristaminopropionic acid, Myristic acid, Myristoyl ethyltrimonium methosulfate, Myristoyl glutamic acid, Myristoyl hydrolyzed collagen, Myristoyl sarcosine, Myristyl betaine, Myristyl / cetylamine oxide, Myristyldimonium hydroxypropyl cocoglucoside chloride, Myristyl glucoside, Myristyl phosphate, Nonoxynol-20, Nonoxynol-23, Nonoxynol-25, Nonoxynol-30, Nonoxynol-35,Nonoxynol-40, Nonoxynol-44, Nonoxynol-50, Nonoxynol-100, Nonoxynol-120, Nonoxynol-5 carboxylic acid, Nonoxynol-8 carboxylic acid, Nonoxynol-10 carboxylic acid, Nonoxynol-3 phosphate, Nonoxynol-4 phosphate, Nonoxynol-6 phosphate, Nonoxynol-9 phosphate, Nonylnoxinol-10 phosphate, Nonylnoxinol-30, Nonylnoxinol-49, Nonylnoxinol-100, Nonylnoxinol-150 , nonylnonoxynol-7 phosphate, nonylnonoxynol-8 phosphate, nonylnonoxynol-9 phosphate, nonylnonoxynol-10 phosphate, nonylnonoxynol-11 phosphate, nonylnonoxynol-15 phosphate, nonylnonoxynol-24 phosphate, oatamidopropyl betaine, octoxynol-16, octoxynol-25, octoxynol-30, octoxynol-33, octoxynol-40, octoxynol-70, octoxynol-20 carboxylic acid, octyldodeceth-20, octyldodeceth-25, octoxynol-20 carboxylate ...oxynol-20 carboxylate, octyldodeceth-20, octyldodec Ctyldodeceth-30, oleamidopropylamine oxide, oleamidopropyl betaine, oleamidopropyl hydroxysultaine, oleic acid, oleyl hydrolyzed collagen, oleyl sarcosine, olease-20, olease-23, olease-24, olease-25, olease-30, olease-35, olease-40, olease-44, olease-50, olease-3 carboxylic acid, olease-6 carboxylic acid, olease-10 carboxylic acid, oleyl betaine, olivanidopropylamine oxide, olivanidopropyl betaine, olivanidopropyl acid, oleic acid, oleyl hydrolyzed collagen, oleyl hydrolyzed collagen, oleyl hydrolyzed collagen, oleyl hydrolyzed collagen, oleyl hydrolyzed collagen, oleyl hydrolyzed collagen, oleyl hydrolyzed collagen, oleamidopropylamine oxide, oleamidopropyl betaine, olivanidopropyl hydrolyzed collagen, oleic acid ...amidopropylamine oxide, oleamidopropyl betaine, olivanidopropyl hydrolyzed collagen, oleic acid, oleyl hydrolyzed collagen, oleamidopropyl hydrolyzed collagen, oleamidopropyl hydrolyzed collagen, oleamidopropyl hydrolyzed collagen, oleamidopropyl hydrolyzed collagen, oleamidopropyl hydrolyzed collagen, oleamidopropyl hydrolyzed collagen, oleamidopropyl hydrolyzed collagen, oleamidopropyl hydrolyzed collagen, oleamidopropyl hydrolyzed collagen, oleamidopropyl hydro Boiled Hydrolyzed Wheat Protein, Ophiopogon Extract Stearate, Ozonized Olease-10, Ozonized PEG-10 Oleate, Ozonized PEG-14 Oleate, Ozonized Polysorbate 80, Palm Acid, Palmidopropyl Betaine, Palmeth-2 Phosphate, Palmitamidopropylamine Oxide, Palmitamidopropyl Betaine, Palmitamine Oxide, Palmitic Acid, Palmitoyl Collagen Amino Acid, Palmitoyl Glycine, Palmitoyl Hydrolyzed Collagen, Palmitoyl Hydrolyzed Milk Protein, Palmitoyl Hydrolyzed Wheat Protein,Palmitoyl keratin amino acid, palmitoyl oligopeptide, palmitoyl silk amino acid, palm nucleic acid, palm amidopropyl betaine, peach kernel oil glyceryl-8 ester, peanut acid, PEG-10 castor oil, PEG-40 castor oil, PEG-44 castor oil, PEG-5, 0 Castor Oil, PEG-54 Castor Oil, PEG-55 Castor Oil, PEG-60 Castor Oil, PEG-80 Castor Oil, PEG-100 Castor Oil, PEG-200 Castor Oil, PEG-11 Cocamide, PEG-6 Cocamide Phosphate, PEG-4 Cocamine, PEG-8 Cocamine, PEG-12 Cocamine, PEG-150 Dibehenate, PEG-90 Diisostearate, PEG-75 Dilaurate, PEG-150 Dilaurate, PEG-75 Dioleate, PEG-150 Dioleate, PEG-75 Distearate, PEG-120 Distearate, PEG-150 Distearate, PEG-175 Distearate, PEG-190 Distearate, PEG-250 Distearate, PEG-30 Glyceryl Cocoate, PEG-40 Glyceryl Cocoate, PEG-78 Glyceryl Cocoate, PEG-80 Glyceryl Cocoate, PEG-30 Glyceryl Isostearate, PEG-40 Glyceryl Isostearate, PEG-50 Glyceryl Isostearate, PEG-60 Glyceryl Isostearate, PEG-90 Glyceryl Isostearate, PEG-23 Glyceryl Laurate, PEG-30 Laurate Glyceryl, PEG-25 Glyceryl Oleate, PEG-30 Glyceryl Oleate, PEG-30 Glyceryl Soybean Acid, PEG-25 Glyceryl Stearate, PEG-30 Glyceryl Stearate, PEG-40 Glyceryl Stearate, PEG-120 Glyceryl Stearate, PEG-200 Glyceryl Stearate, PEG-28 Glyceryl Tawa Oat, PEG-80 Glyceryl Tawa Oat, PEG-82 Glyceryl Tawa Oat, PEG-130 Glyceryl Tawa Oat, PEG-200 Glyceryl Tawa Oat, PEG-45 Hydrogenated Castor Oil , PEG-50 hydrogenated castor oil, PEG-54 hydrogenated castor oil, PEG-50 hydrogenated castor oil, PEG-60 hydrogenated castor oil, PEG-80 hydrogenated castor oil, PEG-100 hydrogenated castor oil, PEG-200 hydrogenated castor oil, PEG-30 hydrogenated lanolin, PEG-70 hydrogenated lanolin, PEG-50 hydrogenated palmamide, PEG-2 isostearate, PEG-3 isostearate, PEG-4 isostearate, PEG-6 isostearate, PEG-8 isostearate, PEG-10 isostearate, PEG-12 isostearate, PEG-20 isostearate,PEG-30 Isostearate, PEG-40 Isostearate, PEG-26 Jojoba Acid, PEG-40 Jojoba Acid, PEG-15 Jojoba Alcohol, PEG-26 Jojoba Alcohol, PEG-40 Jojoba Alcohol, PEG-35 Lanolin, PEG-40 Lanolin, PEG-50 Lanolin, PEG-55 Lanolin, PEG-60 Lanolin, PEG-70 Lanolin, PEG-75 Lanolin, PEG-85 Lanolin, PEG-100 Lanolin, PEG-150 Lanolin, PEG-75 Lanolin Oil, PEG-2 Lauramide, PEG-3 Lauramine Oxide, PE G-20 Laurate, PEG-32 Laurate, PEG-75 Laurate, PEG-150 Laurate, PEG-70 Mango Glycerides, PEG-20 Mannitan Laurate, PEG-8 Methyl Ether Dimethicone, PEG-120 Methyl Glucose Dioleate, PEG-80 Methyl Glucose Laurate, PEG-120 Methyl Glucose Trioleate, PEG-4 Montanic Acid, PEG-30 Oleamine, PEG-20 Oleic Acid, PEG-23 Oleic Acid, PEG-32 Oleic Acid, PEG-36 Oleic Acid, PEG-75 Oleate , PEG-150 Oleate, PEG-20 Palmitate, PEG-150 Polyglyceryl-2 Tristearate, PEG / PPG-28 / 21 Acetate Dimethicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-3 / 17 Copolymer, PEG / PPG-5 / 35 Copolymer, PEG / PPG-8 / 55 Copolymer, PEG / PPG-10 / 30 Copolymer, PEG / PPG-10 / 65 Copolymer, PEG / PPG-12 / 35 Copolymer, PEG / PPG-16 / 17 Copolymer, PEG / PPG-20 / 9 Copolymer, PEG / PPG-20 / 20 copolymer, PEG / PPG-20 / 60 copolymer, PEG / PPG-20 / 65 copolymer, PEG / PPG-22 / 25 copolymer, PEG / PPG-28 / 30 copolymer, PEG / PPG-30-35 copolymer, PEG / PPG-30 / 55 copolymer, PEG / PPG-35 / 40 copolymer, PEG / PPG-50 / 40 copolymer, PEG / PPG-150 / 35 copolymer, PEG / PPG-160 / 30 copolymer, PEG / PPG-190 / 60 copolymer, PEG / PPG-200 / 40 copolymer,PEG / PPG-300 / 55 Copolymer, PEG / PPG-20 / 22 Methyl Ether Dimethicone, PEG-26-PPG-30 Phosphate, PEG / PPG-4 / 2 Propylheptyl Ether, PEG / PPG-6 / 2 Propylheptyl Ether, PEG-7 / PPG-2 Propylheptyl Ether, PEG / PPG-8 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Propylheptyl Ether, PEG / PPG-14 / 2 Propylheptyl Ether, PEG / PPG-40 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Ricinoleate, PEG / PPG-32 / 3 Ricinoleate, PEG-55 Propylene Glycol Oleate, PEG-25 Propylene Glycol Stearate, PEG-75 Propylene Glycol Stearate, PEG-120 Propylene Glycol Stearate, PEG-5 Rapeseed Sterol, PEG-10 Rapeseed Sterol, PEG-40 Ricinoleamide, PEG-75 Shea Butter Glycerides, PEG-75 Shorea Butter Glycerides, PEG-20 Sorbitan Cocoate, PEG-20 Sorbitan Isostearate, PEG- 40 Sorbitan Lanolate, PEG-75 Sorbitan Lanolate, PEG-10 Sorbitan Laurate, PEG-40 Sorbitan Laurate, PEG-44 Sorbitan Laurate, PEG-75 Sorbitan Laurate, PEG-80 Sorbitan Laurate, PEG-20 Sorbitan Oleate, PEG-80 Sorbitan Palmitate, PEG-40 Sorbitan Stearate, PEG-60 Sorbitan Stearate, PEG-160 Sorbitan Triisostearate, PEG-40 Soy Sterol, PEG-2 Stearamide Carboxylate, PEG-9 Sodium Stearate, PEG-10 Sodium Stearate, PEG-11 Sodium Stearate, PEG-12 Sodium Stearate, PEG-13 Sodium Stearate, PEG-14 Sodium Stearate, PEG-15 Sodium Stearate, PEG-16 Sodium Stearate, PEG-17 Sodium Stearate, PEG-18 Sodium Stearate, PEG-19 Sodium Stearate, PEG-20 Sodium Stearate, PEG-21 Sodium Stearate, PEG-19 Sodium Stearate, PEG-19 Sodium Stearate, PEG-17 Sodium Stearate, PEG-19 ... Thearamide carboxylic acid, PEG-20 stearate, PEG-23 stearate, PEG-25 stearate, PEG-30 stearate, PEG-32 stearate, PEG-35 stearate, PEG-36 stearate, PEG-40 stearate, PEG-45 stearate, PEG-50 stearate, PEG-55 stearate, PEG-75 stearate, PEG-90 stearate, PEG-100 stearate, PEG-120 stearate, PEG-150 stearate, PEG-45 stearate phosphate, PEG-20 stearate,PEG-50 Tallowamide, PEG-2 Tallowamide DEA, PEG-20 Tallow, PEG-66 Trihydroxystearin, PEG-200 Trihydroxystearin, PEG-60 Camellia Glyceride, Pelargonic Acid, Pentadoxynol-200, Phenes-6 Phosphate, Poloxamer 105, Poloxamer 108, Poloxamer 182, Poloxamer 183, Poloxamer 184, Poloxamer 188, Poloxamer 217, Poloxamer 234, Poloxamer 235, Poloxamer 237, Poloxamer 238, Poloxam, er334, Poloxamer 335, Poloxamer 338, Poloxamine 908, Poloxamine 1508, Polydimethylsiloxy PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-6 Caprate, Polyglyceryl-10 Dilaurate, Polyglyceryl-20 Heptacaprylate, Polyglyceryl-20 Hexacaprylate, Polyglyceryl-2 Lauryl Ether, Polyglyceryl-10 Lauryl Ether, Polyglyceryl-20 Octaisononanoate, Polyglyceryl Pentacaprylate Ceryl-6, Polyglyceryl-10 Pentacaprylate, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Polyglyceryl-6 Tetracaprylate, Polyglyceryl-10 Tetralaurate, Polyglyceryl-6 Tricaprylate, Polyglyceryl-10 Trilaurate, Polyquaternium-77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81, Polyquaternium-82, Pomadris Coumera Flower / Leaf Extract, Polyacocos Extract, Potassium Abietoyl Hydrolyzed Collagen, Baba Potassium stearate, potassium behenate, potassium C9-15 alkyl phosphate, potassium C11-15 alkyl phosphate, potassium C12-13 alkyl phosphate, potassium C12-14 alkyl phosphate, potassium caprate, potassium capryloyl glutamate, capryloyl hydrolyzed rice protein, potassium castorate, potassium cocoate, potassium cocoyl glutamate, potassium cocoyl glycine, potassium cocoyl hydrolyzed casein, potassium cocoyl hydrolyzed collagen, potassium cocoyl hydrolyzed corn protein, potassium cocoyl hydrolyzed keratin,Cocoyl hydrolyzed oat protein potassium, cocoyl hydrolyzed potato protein potassium, cocoyl hydrolyzed rice bran protein potassium, cocoyl hydrolyzed rice protein potassium, cocoyl hydrolyzed silk potassium, cocoyl hydrolyzed soy protein potassium, cocoyl hydrolyzed wheat protein potassium, cocoyl hydrolyzed yeast protein potassium, cocoyl PCA potassium, cocoyl sarcosinate potassium, cocoyl taurate potassium, cornate potassium, cyclocarboxypropyl oleate potassium, dihydroxyethyl cocamine oxide potassium phosphate, dimethicone PEG-7 phosphate potassium, dodecylbenzenesulfonate potassium, hemp seed acid potassium, hydrogenated cocoate potassium, hydrogenated palmate potassium, hydrogenated tallowate potassium, hydroxystearate potassium, isostearate potassium, lanolate potassium, laurate potassium, laureth-3 carboxylate potassium, laureth-4 carboxylate potassium, laureth-5 carboxylate potassium, laureth-6 carboxylate potassium, laureth-10 carboxylate potassium, laureth phosphate potassium, lauroyl collagen Potassium lauroyl glutamate, potassium lauroyl hydrolyzed collagen, potassium lauroyl hydrolyzed pea protein, potassium lauroyl hydrolyzed soy protein, potassium lauroyl PCA, potassium lauroyl pea amino acid, potassium lauroyl sarcosinate, potassium lauroyl silk amino acid, potassium lauroyl wheat amino acid, potassium lauroyl phosphate, potassium lauroyl sulfate, potassium linoleate, potassium metaphosphate, potassium methyl cocoyl taurate, potassium myristate, potassium myristoyl glutamate, potassium myristoyl hydrolyzed collagen, potassium octoxynol-12 phosphate, potassium oleate, potassium oleoyl hydrolyzed collagen, potassium olivine, potassium olivoyl hydrolyzed oat protein, potassium olivoyl hydrolyzed wheat protein, potassium olivoyl / lauroyl wheat amino acid, potassium olivoyl PCA, potassium palmate, potassium palmitate, palmitoyl hydrolyzed corn protein, palmitoyl hydrolyzed oat protein, palmitoyl hydrolyzed rice protein,Palmitoyl hydrolyzed sweet almond protein, palmitoyl hydrolyzed wheat protein, potassium palm kernelate, potassium peanutate, potassium rapeseed, potassium ricinoleate, potassium safflowerate, potassium soyate, potassium stearate, potassium stearoyl hydrolyzed collagen, potassium tartarate, potassium tallowate, potassium taurate, , potassium laurate taurate, potassium trideceth-3 carboxylate, potassium trideceth-4 carboxylate, potassium trideceth-7 carboxylate, potassium trideceth-15 carboxylate, potassium trideceth-19 carboxylate, potassium trideceth-6 phosphate, potassium trideceth-7 phosphate, potassium camellia acid, potassium undecylenate, undecylenoyl hydrolyzed collagen, potassium undecylenoyl hydrolyzed rice protein, PPG-30-buteth-30, PPG-36-buteth-36, PPG-38-buteth-37, PPG-30-capryles-4 lysine PPG-10 Cetyl Ether Phosphate, PPG-2C9-11 Pareth-8, PPG-1-Deceth-5, PPG-3-Deceth-2 Carboxylic Acid, PPG-30 Ethylhexyl-4 Phosphate, PPG-20 Glycereth-30, PPG-2 Hydroxyethyl Coco / Rostearamide, PPG-2-Rosodeceth-8, PPG-2-Rosodeceth-10, PPG-2-Rosodeceth-18, PPG-2-Rosodeceth-25, PPG-4-Rosodeceth-10, Propyltrimonium Hydrolyzed Collagen, Quaternium-24, Quaternium-52, Quaternium-87, Naphthalene Neic acid, rice bran acid, rice oil glycereth-8 ester, ricinoleamidopropyl betaine, ricinoleic acid, ricinoleic acid-40, safflower acid, soapberry fruit extract, saponaria root powder, saponin, soap-potassium, soap-sodium / potassium, soap-sodium, soap-sodium, sesame oil glycereth-8 ester, sesame propylamine oxide, sesame propyl betaine, shea butter glycereth-8 ester, sodium arachidate, sodium alginate, sodium arginate, sodium astrocalm murumurate, sodium avocado acid thorium, sodium babassu amphoacetate, sodium babassu acid, sodium babassu sulfate, sodium behenate, sodium bisglycolate lysinosulfosuccinate, sodium bishydroxyethylglycine coco glucoside crosspolymer, sodium bishydroxyethylglycine lauryl glucoside crosspolymer, sodium boragemidopropyl PG-dimonium chloride phosphate, sodium butoxynol-12 sulfate, sodium butyl glucoside, sodium C13-17 alkanesulfonate, sodium C14-18 alkanesulfonate,C12-15 Alkoxypropyliminodipropionate, Sodium C10-16 Alkyl Sulfate, Sodium C11-15 Alkyl Sulfate, Sodium C12-13 Alkyl Sulfate, Sodium C12-15 Alkyl Sulfate, Sodium C12-18 Alkyl Sulfate, Sodium C16-20 Alkyl Sulfate, Sodium C9-22 Alkyl Sec Sulfonate, Sodium C14-17 Alkyl Sec Sulfonate, Sodium Caprate, Sodium Caproamphoacetate, Sodium Caproamphohydroxypropylsulfonate, Sodium Caproamphopropionate , Sodium Caproyl Methyl Taurate, Sodium Caprylate, Sodium Capryleth-2 Carboxylate, Sodium Caprylos-9 Carboxylate, Sodium Capryloamphoacetate, Sodium Capryloamphohydroxypropylsulfonate, Sodium Capryloamphopropionate, Sodium Capryloyl Glutamate, Sodium Capryloyl Hydrolyzed Wheat Protein, Sodium Caprylyl PG-Sulfonate, Sodium Caprylyl Sulfonate, Sodium Castorate, Sodium Ceteareth-13 Carboxylate, Sodium Cetearyl Sulfate, Ceteth- Sodium 13 Carboxylate, Sodium Cetyl Sulfate, Sodium Cocamidopropyl PG-Dimonium Chloride Phosphate, Sodium Cocaminopropionate, Sodium Coceth Sulfate, Sodium Coceth-30 Sulfate, Sodium Cocoa Butter Amphoacetate, Sodium Cocobutyrate, Sodium Cocoamphoacetate, Sodium Cocoamphohydroxypropylsulfonate, Sodium Cocoamphopropionate, Sodium Cocoate, Coco / Babassu / Andiloba Sulfate, Sodium Cocoglucoside Hydroxypropyl Phosph ... Sodium Glucoside Hydroxypropyl Sulfonate, Sodium Coco Glucoside Tartrate, Sodium Coco Glyceryl Ether Sulfonate, Sodium Coco / Hydrogenated Scutellaria Baicalensis Sulfate, Sodium Cocoiminodiacetate, Sodium Coco Monoglyceride Sulfate, Sodium Coco Monoglyceride Sulfonate, Sodium Coco PG-Dimonium Chloride Phosphate, Sodium Coco Sulfate, Sodium Coco Acetate, Sodium Cocoyl Alanine Acid, Sodium Cocoyl Amino Acid, Sodium Cocoyl Collagen Amino Acid, Sodium Cocoyl Glutamate, Sodium Cocoyl Glutamate,Sodium cocoyl glycinate, Sodium cocoyl / hydrogenated tallow glutamate, Sodium cocoyl hydrolyzed collagen, Sodium cocoyl hydrolyzed keratin, Sodium cocoyl hydrolyzed rice protein, Sodium cocoyl hydrolyzed silk, Sodium cocoyl hydrolyzed soy protein, Sodium cocoyl hydrolyzed sweet almond protein, Sodium cocoyl hydrolyzed wheat protein, Sodium cocoyl hydrolyzed wheat protein glutamate, Sodium cocoyl isethionate, Sodium cocoyl methylaminopropionate, Sodium cocoyl autoamino acids, Sodium cocoyl / palmoyl / sunflower glutamate, Sodium cocoyl proline, Sodium cocoyl sarcosinate, Sodium cocoyl taurate, Sodium cocoyl threonate, Sodium cocoyl wheat amino acids, Sodium C12-14 olefin sulfonate, Sodium C14-16 olefin sulfonate, Sodium C14-18 olefin sulfonate, Sodium C16-18 olefin sulfonate, Sodium cocoyl propionate, Sodium cottonseed amphoacetate, Sodium C13-15 pa Sodium C9-11 Pareth-6 Carboxylate, Sodium C11-15 Pareth-7 Carboxylate, Sodium C12-13 Pareth-5 Carboxylate, Sodium C12-13 Pareth-8 Carboxylate, Sodium C12-13 Pareth-12 Carboxylate, Sodium C12-15 Pareth-6 Carboxylate, Sodium C12-15 Pareth-7 Carboxylate, Sodium C12-15 Pareth-8 Carboxylate, Sodium C14-15 Pareth-8 Carboxylate, Sodium C12-14 Pareth-8 Carboxylate, Sodium C14-15 Pareth- -PG Sodium Sulfonate, C12-13 Pareth-2 Sodium Phosphate, C13-15 Pareth-8 Sodium Phosphate, C9-15 Pareth-3 Sodium Sulfate, C10-15 Pareth Sodium Sulfate, C10-16 Pareth-2 Sodium Sulfate, C12-13 Pareth Sodium Sulfate, C12-15 Pareth Sodium Sulfate, C12-15 Pareth-3 Sodium Sulfate, C13-15 Pareth-3 Sodium Sulfate, C12-14 Sec Pareth-3 Sodium Sulfate, C12-15 Pareth-3 Sodium Sulfonate, C12-15 Pareth-7 Sodium Sulfonate,Sodium C12-15 Pareth-15 Sulfonate, Sodium Deceth-2 Carboxylate, Sodium Deceth Sulfate, Sodium Decyl Benzene Sulfonate, Sodium Decyl Glucoside Hydroxypropyl Phosphate, Sodium Decyl Glucoside Hydroxypropyl Sulfonate, Sodium Dilaureth-7 Citrate, Sodium Dilaureth-10 Phosphate, Sodium Dilinoleate Amidopropyl PG-Dimonium Chloride Phosphate, Sodium Dilinoleate, Sodium Dioleth-8 Phosphate, Sodium Dodecyl Benzene Sulfonate, Sodium Ethyl 2-Sulfolaurate, Sodium Oleate Glyceryl Phosphate, Sodium Grape Seed Amphopropyl PG-Dimonium Chloride Phosphate, Sodium Grape Seed Amphoacetate, Sodium Grape Seed Acid, Sodium Hemp Seed Amphoacetate, Sodium Hexeth-4 Carboxylate, Sodium Hydrogenated Cocoyl Acid, Sodium Hydrogenated Cocoyl Methyl Isethionate, Sodium Hydrogenated Palmitate, Sodium Hydrogenated Tallow Acid, Sodium Hydrogenated Tallowyl Glutamate, Sodium Hydroxylauryldimonium Ethyl Phosphate, Hydroxypropyl Palmitic Acid Sulfate Sodium hydroxypropyl phosphate decyl glucoside crosspolymer hydroxypropyl phosphate lauryl glucoside crosspolymer, sodium hydroxypropyl sulfonate cocoglucoside crosspolymer, sodium hydroxypropyl sulfonate decyl glucoside crosspolymer, sodium hydroxypropyl sulfonate lauryl glucoside crosspolymer, sodium hydroxypropyl sulfonate, sodium hydroxystearate, sodium isostearate, sodium isosteareth-6 carboxylate, sodium isosteareth-11 carboxylate, sodium isostearoyl amphoacetate, sodium isostearoyl amphopropionate, sodium N-isostearoyl methyl taurate, sodium laneth sulfate, sodium lanolate, sodium laurate, sodium lauramide diacetate, sodium lauraminopropionate, sodium laurate, sodium laureth-3 carboxylate, sodium laureth-4 carboxylate, sodium laureth-5 carboxylate, sodium laureth-6 carboxylate, sodium laureth-8 carboxylate, sodium laureth-11 carboxylate,Sodium laureth-12 carboxylate, sodium laureth-13 carboxylate, sodium laureth-14 carboxylate, sodium laureth-16 carboxylate, sodium laureth-17 carboxylate, sodium laureth sulfate, sodium laureth-5 sulfate, sodium laureth-7 sulfate, sodium laureth-8 sulfate, sodium laureth-12 sulfate, sodium laureth-40 sulfate, sodium laureth-7 tartrate, sodium laurimidin dipropionate, sodium lauroamphoacetate, sodium lauroamphohydroxypropylsulfonate, sodium lauroamphoPG acetate phosphate, sodium lauroamphopropionate, sodium lauroyl aspartate, sodium lauroyl collagen amino acid, sodium lauroyl glycine propionate, sodium lauroyl hydrolyzed collagen, sodium lauroyl hydrolyzed silk, sodium lauroyl hydroxypropylsulfonate, sodium lauroyl isethionate, sodium lauroyl methylaminopropionate, sodium lauroyl methylisethionate, sodium lauroyl millet amino acid, lauroyl Sodium uroyl / myristoyl aspartate, sodium lauroyl oat amino acid, sodium lauroyl sarcosinate, sodium lauroyl silk amino acid, sodium so-lauroyl taurate, sodium lauroyl wheat amino acid, sodium lauryl diethylenediaminoglycinate, sodium lauryl glucose carboxylate, sodium lauryl glucoside hydroxypropyl phosphate, sodium lauryl glucoside hydroxypropyl sulfonate, sodium lauryl glycol carboxylate, sodium lauryl hydroxyacetamide sulfate, sodium lauryl phosphate, sodium lauryl sulfate, sodium lauryl sulfoacetate, sodium linoleate, sodium macadamiase, sodium mango amphoacetate, sodium mango seed acid, sodium laureth-2 sulfosuccinate / MEA, sodium methoxy PPG-2 acetate, sodium methyl cocoyl taurate, sodium methyl lauroyl taurate, sodium methyl myristoyl taurate, sodium methyl oleyl taurate, sodium methyl palmitoyl taurate,Sodium methyl stearoyl taurate, Sodium methyl 2-sulfolaurate, Sodium methyl 2-sulfopalmitate, Sodium methyl taurine isopalmitate, Sodium methyl taurine cocoyl methyl taurate, Sodium myristate, Sodium myristamphoacetate, Sodium myristoyl glutamate, Sodium myristoyl hydrolyzed collagen, Myri, Sodium stoyl isethionate, sodium myristoyl sarcosinate, sodium myristyl sulfate, sodium nonoxynol-6 phosphate, sodium nonoxynol-9 phosphate, sodium nonoxynol-1 sulfate, sodium nonoxynol-3 sulfate, sodium nonoxynol-4 sulfate, sodium nonoxynol-6 sulfate, sodium nonoxynol-8 sulfate, sodium nonoxynol-10 sulfate, sodium nonoxynol-25 sulfate, sodium octoxynol-2 ethanesulfonate, sodium octoxynol-2 ... Sodium octoxynol-6 sulfate, sodium octoxynol-9 sulfate, sodium oleate, sodium oleoamphoacetate, sodium oleoamphohydroxypropylsulfonate sodium oleoamphopropionate, sodium oleoyl hydrolyzed collagen, sodium oleoyl isethionate, sodium oleate sulfate, sodium oleyl methyl isethionate, sodium oleyl sulfate, sodium olivanfoacetate, sodium olivoyl glutamate, sodium palm amphoacetate, sodium palmate, sodium palm glyceride sulfonate, sodium palmitate, sodium palmitoyl hydrolyzed collagen, sodium palmitoyl hydrolyzed wheat protein, sodium palmitoyl sarcosinate, sodium palm kernelate, sodium palm kernel isethionate, sodium palmoyl glutamate, sodium passiflora edulis seed acid, sodium peanut amphoacetate, sodium peanut acid, sodium PEG-6 cocamide carboxylate, sodium PEG-8 cocamide carboxylate, sodium PEG-4 cocamide sulfate, PEG-3 lauryl stearate Sodium myocarboxylate, PEG-4 sodium lauramidocarboxylate, PEG-8 sodium palm glyceride carboxylate, sodium pentaerythrityl hydroxypropyliminodiacetate dendrimer, sodium propoxy PPG-2acetate, sodium rapeseed acid, sodium rice bran amphoacetate, sodium ricinoleate, sodium ricinoleic amphoacetate, sodium rose hypsamphoacetate, sodium rosinate, sodium safflowerate, sodium safflower oil hydrolyzed soy protein, sodium sesame seed acid, sodium sesame seed acid, sodium sesame seed acid,Shea Butter Sodium Amphoacetate, Sodium Hydroxide, Soy Sodium Reduced Collagen, Sodium Stearate, Sodium Stearoamphoacetate, Sodium Stearoamphohydroxypropylsulfonate, Sodium Stearoamphopropionate, Sodium Stearoyl Caseinate, Sodium Stearoyl Glutamate, Sodium Stearoyl Hyaluronate, Sodium Stearoyl Hydrolyzed Collagen, Sodium Stearoyl Hydrolyzed Corn Protein, Sodium Stearoyl Hydrolyzed Silk, Sodium Stearoyl Hydrolyzed Soy Protein, Sodium Stearoyl Hydrolyzed Wheat Protein, Sodium Stearoyl Lactalbumin, Sodium Stearoyl Methylisethionate, Sodium Stearoyl Oat Protein, Sodium Stearoyl Pea Protein, Sodium Stearoyl Soy Protein, Sodium Stearyl Dimethylglycine, Sodium Stearyl Sulfate, Sunflower Seed Sodium Amphoacetate, Sodium Surfactin, Sweet Almond Sodium Amphoacetate, Sodium Sweet Almonate, Sodium Taraxacum Propionate, Sodium Taraxacum Acid thorium, sodium tallow amphoacetate, sodium tallowate, sodium tallow sulfate, sodium tamanuseate, sodium taurate, sodium methyl cocoyl taurate, sodium taurine laurate, sodium / TEA-lauroyl collagen amino acid, sodium / TEA-lauroyl hydrolyzed collagen, sodium / TEA-lauroyl hydrolyzed keratin, sodium / TEA-lauroyl keratin amino acid, sodium / TEA-undecylenoyl collagen amino acid, sodium / TEA-undecylenoyl hydrolyzed collagen, sodium / TEA-undecylenoyl hydrolyzed corn protein, sodium / TEA-undecylenoyl hydrolyzed soy protein, sodium / TEA-undecylenoyl hydrolyzed wheat protein, sodium theobroma grandiflorum seed acid, sodium trideceth-3 carboxylate, sodium trideceth-4 carboxylate, sodium trideceth-6 carboxylate, sodium trideceth-7 carboxylate, sodium trideceth-8 carboxylate, sodium trideceth-12 carboxylate, sodium trideceth-15 carboxylate,Sodium Trideceth-19 Carboxylate, Sodium Trideceth Sulfate, Sodium Tridecyl Benzene Sulfonate, Sodium Tridecyl Sulfate, Sodium Trimethylolpropane Hydroxypropylminodiacetate Dendrimer, Sodium Undeceth-5 Carboxylate, Sodium Undecylenate, Sodium Undecylenoamphoacetate, Sodium Undecylenoamphopropionate Sodium Undecylenoyl Glutamate, Sodium Wheat Germ Amphoacetate, Sorbeth-160 Tristearate, Soy Acid, Soyamidopropylamine Oxide, Soyamido Propyl betaine, soybean oil glyceryl-8 ester, stearamidopropylamine oxide, stearamidopropyl betaine, stearamine oxide, steareth-15, steareth-16, steareth-20, steareth-21, steareth-25, steareth-27, steareth-30, steareth-40, steareth-50, steareth-80, steareth-100, steareth-2 phosphate, steareth-3 phosphate, stearic acid, stearoxypropyltrimonium chloride, stearoyl glutamic acid, stearoyl sarcosine, stearilin betaine, stearyldimonium hydroxypropyl butyl glucoside chloride, stearyldimonium hydroxypropyl decyl glucoside chloride, stearyldimonium hydroxypropyl lauryl glucoside chloride, sulfated castor oil, sulfated coconut oil, sulfated glyceryl oleate, sulfated olive oil, sulfated peanut oil, sunflower amide MEA, sunflower seed acid, sunflower seed amidopropyl hydroxyethyl dimonium chloride, sunflower seed oil glycereth-8 ester, tall oil acid, tallow acid, tallow amidopropyl amine oxide, Tallowamidopropyl betaine, tallowamidopropyl hydroxysultaine, tallowamine oxide, tallow betaine, tallow dihydroxyethyl betaine, tallowyl ethyl glucoside, TEA-abietyl hydrolyzed collagen, TEA-C12-14 alkyl phosphate, TEA-C10-15 alkyl sulfate, TEA-C11-15 alkyl sulfate, TEA-C12-13 alkyl sulfate, TEA-C12-14 alkyl sulfate, TEA-C12-15 alkyl sulfate, TEA-C14-17 alkyl sec sulfonate, TEA-canolate,TEA-cocamide diacetate, TEA-cocoate, TEA-cocosulfate, TEA-cocoyl alaninate, TEA-cocoyl glutamic acid, TEA-cocoyl glutamate, TEA-cocoyl glycinate, TEA-cocoyl hydrolyzed collagen, TEA-cocoyl hydrolyzed soy protein, TEA-cocoyl sarcosinate, dimethicone PEG-7 phosphate TEA, dodecylbenzenesulfonate TEA, hydrogenated cocoate TEA, hydrogenated tallow glutamate TEA, rostearate TEA, rostearoyl hydrolyzed collagen TEA, laurami TEA-nopropionate, TEA-laurate, TEA-laurate / myristate, TEA-laureth sulfate, TEA-lauroyl collagen amino acid salt, TEA-lauroyl glutamate, TEA-lauroyl hydrolyzed collagen, TEA-lauroyl keratin amino acid salt, TEA-lauroyl methylaminopropionate, TEA-lauroyl / myristoyl aspartate, TEA-lauroyl sarcosinate, TEA-lauryl phosphate, TEA-lauryl sulfate, TEA-myristyl aminopropionate, TEA-myristate, TEA- Myristoyl hydrolyzed collagen, TEA-oleate, TEA-oleyl hydrolyzed collagen, TEA-oleyl sarcosinate, TEA-oleyl sulfate, TEA-palmitate, TEA-palm kernel sarcosinate, TEA-PEG-3 cocamide sulfate, TEA-rosinate, TEA-stearate, TEA-tartarate, TEA-tridecylbenzenesulfonate, TEA-undecylenate, undecylenoyl hydrolyzed collagen, tetrasodium tetramethyldecylendiol dicarboxyethylstearyl sulfosuccinate, TIPA-laureth sulfate, TI PA-Lauryl Sulfate, TIPA-Myristate, TIPA-Stearate, Tocopheryl Phosphate, Trehalose Undecylenoate, TM-C12-15 Pareth-2 Phosphate, TM-C12-15 Pareth-6 Phosphate, TM-C12-15 Pareth-8 Phosphate, TM-C12-15 Pareth-10 Phosphate, Trideceth-20, Trideceth-50, Trideceth-3 Carboxylic Acid, Trideceth-4 Carboxylic Acid, Trideceth-7 Carboxylic Acid, Trideceth-8 Carboxylic Acid, Trideceth-15 Carboxylic Acid, Trideceth-19 Carboxylic Acid, Trideceth-10 Phosphate,Tridecylbenzenesulfonic acid, Trilaureth-9 citrate, Trimethylolpropane hydroxypropyl bis-hydroxyethylamine dendrimer, Lauroampho PG-Acetic acid chloride trisodium phosphate, Undecanoic acid, Undeceth-5 carboxylic acid, Undecylenamidopropylamine oxide, Undecylenamidopropyl betaine, Undecylenic acid, Undecylenoyl collagen amino acid, Undecylenoyl glycine, Undecylenoyl hydrolyzed collagen, Undecylenoyl wheat amino acid, Undecyl glucoside, Wheat germ acid, Wheat germamidopropylamine oxide, Wheat germamidopropyl betaine, Yucca schidigera leaf / root / stem extract, Yucca schidigera stem extract, Zinc coceth sulfate, Zinc coco sulfate.,

[0021] Preferred are one or more compounds selected from the group consisting of sodium laureth sulfate, cocamidopropyl betaine, sodium cocoamphoacetate, cocoglucoside and ammonium lauryl sulfosuccinate.

[0022] The content of the surfactant in the formulation may be from 0.1 to 10% by weight, preferably from 0.5 to 5% by weight, based on the weight of the formulation.

[0023] <Oil body> Suitable oil bodies which form constituents of the O / W emulsions are, for example, gelbet alcohols based on fatty alcohols having 6 to 18, preferably 8 to 10, carbon atoms, esters of linear C6 to C22 fatty acids with linear or branched C6 to C22 fatty alcohols or esters of branched C6 to C13 carboxylic acids with linear or branched C6 to C22 fatty alcohols, such as, for example, myristyl myristate, myristyl palmitate, myristyl stearate, myristyl isostearate, myristyl oleate, myristyl behenate, myristyl erucate, cetyl myristate, cetyl palmitate, cetyl stearate, cetyl isostearate, cetyl oleate, cetyl behenate, cetyl erucate, stearyl myristate, stearyl palmitate, stearyl stearate, oleyl, stearyl isostearate, stearyl oleate, stearyl behenate, stearyl erucate, isostearyl myristate, isostearyl palmitate, isostearyl stearate, isostearyl isostearate, isostearyl oleate, isostearyl behenate, isostearyl oleate, oleyl myristate, oleyl palmitate, oleyl stearate, oleyl myristate, oleyl palmitate, oleyl behenate, oleyl erucate, behenyl myristate, behenyl palmitate, behenyl stearate, behenyl isostearate, behenyl oleate, behenyl behenate, behenyl erucate, erucyl myristate, erucyl palmitate, erucyl stearate, erucyl isostearate, erucyl oleate, erucyl behenate and erucyl erucate.Also preferred are esters of linear C6-C22-fatty acids with branched alcohols, in particular 2-ethylhexanol, esters of C18-C38-alkylhydroxycarboxylic acids with linear or branched C6-C22-fatty alcohols, in particular dioctyl malate, linear and / or branched fatty acids with polyhydric alcohols (for example propylene glycol, dimerdiol or trimertriol) and / or gelbet alcohols, triglycerides based on C6-C10-fatty acids, liquid mono- / di- / triglyceride mixtures based on C6-C18-fatty acids, esters of C6-C22-fatty alcohols and / or gelbet alcohols with aromatic carboxylic acids, in particular benzoic acid, esters of C2-C12-dicarboxylic acids with linear or branched alcohols having 1 to 22 carbon atoms or polyols having 2 to 10 carbon atoms and 2 to 6 hydroxyl groups, Vegetable oils, branched primary alcohols, substituted cyclohexanes, linear and branched C6-C22-fatty alcohol carbonates, such as dicaprylyl carbonate (Cetiol® CC), Guerbet carbonates based on fatty alcohols having 6 to 18, preferably 8 to 10, carbon atoms, esters of benzoic acid with linear and / or branched C6 to C22-alcohols (e.g. C6 to C22) (Finsolv® TN), linear or branched, symmetrical or asymmetrical dialkyl ethers having 6 to 22 carbon atoms per alkyl group, such as dicaprylyl ether (Cetiol® OE), ring-opening products of epoxidized fatty acid esters with polyols, silicone oils (cyclomethicone, silicone methicone grades, etc.) and / or aliphatic or naphthenic hydrocarbons, such as squalane, squalene or dialkylcyclohexanes.

[0024] <Emulsifier> Other nonionic or cationic surfactants can also be added to the formulation as emulsifiers, such as: - addition products of 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide onto linear C8-22 fatty alcohols, C12-22 fatty acids and alkylphenols containing from 8 to 15 carbon atoms in the alkyl group; - C12 / 18 fatty acid mono- and diesters of addition products of 1 to 30 moles of ethylene oxide onto glycerol; - glycerol mono- and diesters, sorbitan mono- and diesters of saturated and unsaturated fatty acids having 6 to 22 carbon atoms and their ethylene oxide addition products; - addition products of 15 to 60 moles of ethylene oxide onto castor oil and / or hydrogenated castor oil; - polyol esters, in particular polyglycerol esters, such as, for example, polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate or polyglycerol dimerate isostearate; mixtures of compounds from these classes are also suitable; - addition products of 2 to 15 moles of ethylene oxide onto castor oil and / or hydrogenated castor oil; - partial esters based on linear, branched, unsaturated or saturated C6 / 22 fatty acids, ricinoleic acid and 12-hydroxystearic acid, as well as glycerol, polyglycerol, pentaerythritol, -dipentaerythritol, sugar alcohols (e.g. sorbitol), alkyl glucosides (e.g. methyl glucoside, butyl glucoside, lauryl glucoside) and polyglucosides (e.g. cellulose); - mono-, di- and trialkyl phosphates, mono-, di- and / or tri-PEG-alkyl phosphates and their salts; - Wool wax alcohol; - polysiloxane / polyalkylpolyether copolymers and corresponding derivatives; - mixed esters of pentaerythritol, fatty acids, citric acid and fatty alcohols and / or mixed esters of C6-22 fatty acids, methylglucose and a polyol, preferably glycerol or polyglycerol; - polyalkylene glycols; and - Glycerin carbonate.

[0025] Addition products of ethylene oxide and / or propylene oxide onto fatty alcohols, fatty acids, alkylphenols, glycerol mono- and diesters, sorbitan mono- and diester fatty acids or onto castor oil are known commercially. These are homolog mixtures whose average degree of alkoxylation corresponds to the ratio of the amounts of ethylene oxide and / or propylene oxide to the substrates undergoing the addition reaction. C12 / 18 fatty acid mono- and diesters of addition products of ethylene oxide onto glycerol are known as lipid layer enhancers in cosmetic formulations. Preferred emulsifiers are described in more detail below:

[0026] Partial glycerides. Representative examples of suitable partial glycerides are hydroxystearic acid monoglyceride, hydroxystearic acid diglyceride, isostearic acid monoglyceride, isostearic acid diglyceride, oleic acid monoglyceride, oleic acid diglyceride, ricinoleic acid monoglyceride, ricinoleic acid diglyceride, linoleic acid monoglyceride, linoleic acid diglyceride, linolenic acid monoglyceride, linolenic acid diglyceride, erucic acid monoglyceride, tartaric acid diglyceride, citric acid monoglyceride, citric acid diglyceride, malic acid monoglyceride, malic acid diglyceride, and technical mixtures thereof which may contain small amounts of triglycerides from the manufacturing process. Also suitable are addition products of partial glycerides with 1 to 30 moles, preferably 5 to 10 moles, of ethylene oxide.

[0027] Sorbitan esters. Suitable sorbitan esters are sorbitan monoisostearate, sorbitan sesquiisostearate, sorbitan diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan dioleate, sorbitan trioleate, sorbitan monoerucate, sorbitan sesquierucate, sorbitan dierucate, sorbitan trioleate, sorbitan monoricinoleate, sorbitan sesquierucate, sorbitan diricinoleate, sorbitan triricin ... sorbitan esters, sorbitan monohydroxystearate, sorbitan sesquihydroxystearate, sorbitan dihydroxystearate, sorbitan trihydroxystearate, sorbitan monotartrate, sorbitan sesquitartrate, sorbitan ditartrate, sorbitan tritartrate, sorbitan monocitrate, sorbitan sesquienoate, sorbitan dicitrate, sorbitan tricitrate, sorbitan monomaleate, sorbitan sesquimaleate, sorbitan dimaleate, sorbitan trimaleate and technical mixtures thereof. Also suitable are addition products of sorbitan esters with 1 to 30, preferably 5 to 10, moles of ethylene oxide.

[0028] Polyglycerol ester. Representative examples of suitable polyglycerol esters are polyglyceryl-2 dipolyhydroxystearate (Dehymuls® PGPH), polyglycerin-3-diisostearate (Lameform® TGI), polyglyceryl-4 isostearate (Isolan® GI34), polyglyceryl-3 oleate, polyglyceryl-3 diisostearoyl diisostearate (Isolan® PDI), polyglyceryl-3 methylglucose distearate (TegoCare® PGPH), ...3 diisostearate (TegoCare® PGPH), polyglyceryl-3 methylglucose distearate (TegoCare® PGPH), polyglyceryl-3 diisostearate (TegoCare® PGPH), polyglyceryl-3 diisostearate (TegoCare® PGPH), polyglyceryl-3 diisostearate (TegoCare® PGPH), polyglyceryl-3 methylglucose distearate (TegoCare® PGPH), polyglyceryl-3 diisostearate (TegoCare® PGPH), polyglyceryl-3 diisostearate (TegoCare® PGPH), polyglyceryl-3 diisostearate (TegoCare® PGPH), polyglyceryl-3 methylglucose distearate (TegoCare® PGPH), polyglyceryl-3 diisostearate (TegoCare® PGPH), polyglyceryl Polyglyceryl-3 beeswax (CeraBellina® 450), polyglyceryl-4 caprate (Polyglycerin Caprate T2010 / 90), polyglyceryl-3 cetyl ether (Chimexane® NL), polyglyceryl-3 distearate (Cremophor® GS32) and polyglyceryl polyricinoleate (Admul® WOL1403), polyglyceryl dimerate isostearate and mixtures thereof. Examples of other suitable polyol esters include mono-, di- and triesters of trimethylolpropane or pentaerythritol with lauric acid, coco fatty acid, tallow fatty acid, palmitic acid, stearic acid, oleic acid, behenic acid, and the like, optionally reacted with 1 to 30 moles of ethylene oxide.

[0029] Tetraalkylammonium salts. Cationic active surfactants consist of hydrophobic polymeric groups necessary for cationic surface activity by dissociation in aqueous solution. An important representative group of cationic surfactants are tetraalkylammonium salts of the general formula: (R1R2R3R4N+)X-, where R1 represents C1-C8 alkyl(enyl) and R2, R3 and R4, independently of each other, represent alkyl(enyl) radicals having 1 to 22 carbon atoms. X is a counterion, preferably selected from the group of halides, alkyl sulfates and alkyl carbonates. Particularly preferred are cationic surfactants in which the nitrogen group is substituted with two long acyl groups and two short alkyl(enyl) groups.

[0030] Esterquat. A further class of cationic surfactants particularly useful as co-surfactants for the present invention is represented by the so-called ester quats. Ester quats are generally understood to be quaternized fatty acid triethanolamine ester salts. These are known compounds that can be obtained by relevant methods of preparative organic chemistry. In this connection, reference is made to WO91 / 01295A1, according to which triethanolamine is partially esterified with fatty acid in the presence of hypophosphorous acid, air is passed through the reaction mixture, and then the whole is quaternized with dimethyl sulfate or ethylene oxide. Furthermore, German patent DE4308794C1 describes a method for the preparation of solid ester quats, in which the quaternization of triethanolamine esters is carried out in the presence of a suitable dispersant, preferably a fatty alcohol.

[0031] Typical examples of ester quats suitable for use according to the invention are products whose acyl component is derived from a monocarboxylic acid corresponding to the formula RCOOH, where RCO is an acyl group containing 6 to 10 carbon atoms, and whose amine component is triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid and technical mixtures thereof, such as, for example, the so-called head-fraction fatty acids. Ester quats whose acyl component is derived from a monocarboxylic acid containing 8 to 10 carbon atoms are preferably used. Other ester quats are those whose acyl component is derived from a dicarboxylic acid such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and / or dodecanedioic acid, but preferably adipic acid. Overall, ester quats whose acyl component is derived from a mixture of a monocarboxylic acid containing 6 to 22 carbon atoms and adipic acid are preferably used. The molar ratio of mono- and dicarboxylic acids in the final ester quat may range from 1:99 to 99:1, preferably from 50:50 to 90:10, more particularly from 70:30 to 80:20. Besides the quaternized fatty acid triethanolamine ester salts, other suitable ester quats are quaternized ester salts of mono- / dicarboxylic acid mixtures with diethanolalkylamines or 1,2-dihydroxypropyldialkylamines. Ester quats can be obtained either from fatty acids or from the corresponding triglycerides mixed with the corresponding dicarboxylic acids. As representative of the relevant prior art, such a preparation is proposed in EP 0750606 B1. To prepare the quaternized esters, mixtures of mono- and dicarboxylic acids with triethanolamine (based on available carboxyl functional groups) can be used in a molar ratio of 1.1:1 to 3:1. Taking into account the performance properties of the ester quats, ratios of 1.2:1 to 2.2:1, preferably 1.5:1 to 1.9:1, have proven to be particularly advantageous. Preferred ester quats are technical mixtures of mono-, di- and triesters with an average degree of esterification of 1.5 to 1.9.

[0032] <Superfatting Agents and Consistency Factors> Superfatting agents may be selected from materials such as lanolin and lecithin, and polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides, the latter also functioning as foam stabilizers.

[0033] The consistency factors mainly used are fatty alcohols or hydroxyfatty alcohols containing from 12 to 22, preferably from 16 to 18, carbon atoms, as well as partial glycerides, fatty acids or hydroxyfatty acids. Combinations of these substances with alkyl oligoglucosides of the same chain length and / or fatty acid N-methylglucamides and / or polyglycerol poly-12-hydroxystearates are preferably used.

[0034] <Thickeners and Rheology Additives> Suitable thickening agents are polymeric thickening agents, such as Aerosil® types (hydrophilic silicas), polysaccharides, more particularly xanthan gum, guar-guar, agar agar, alginates and tyloses, carboxymethylcellulose and hydroxyethylcellulose, also relatively high molecular weight polyethylene glycol mono- and diesters of fatty acids, polyacrylates (for example Carbopols® [Goodrich] or Synthalens® [Sigma]), polyacrylamides, polyvinyl alcohols, polyvinylpyrrolidones, surfactants, such as ethoxylated fatty acid glycerides, esters of fatty acids with polyols, such as pentaerythritol and trimethylolpropane, narrow range fatty alcohol ethoxylates, electrolytes, such as sodium chloride and ammonium chloride.

[0035] <Polymer> Suitable cationic polymers are cationic cellulose derivatives, such as, for example, quaternized hydroxyethylcellulose available from Amerchol under the name Polymer JR400®, cationic starch, copolymers of diallyl ammonium salts and acrylamide, quaternized vinylpyrrolidone / vinylimidazole polymers, such as, for example, Luviquat® (BASF), condensation products of polyglycols with amines, such as, for example, quaternized collagen polypeptides, such as, for example, lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat® L, Grunau), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers, such as, for example, amodimethicone, copolymers of adipic acid and dimethylaminohydroxypropyldiethylenetriamine (Cartaretine® Sandoz), copolymers of acrylic acid and dimethyldiallylammonium chloride (Merquat®), 550, Chemviron), polyaminopolyamides and their crosslinked water-soluble polymers, cationic chitin derivatives such as quaternized chitosan, optionally microcrystalline, condensation products of dihaloalkyls, such as dibromobutane, with bis-dialkylamines, such as bis-dimethylamino-1,3-propane, cationic guar gums, such as Jaguar® CBS, Jaguar® C-17, Jaguar® C-16 from Celanese, quaternized ammonium salt polymers, such as Mirapol® A-15, Mirapol® AD-1, Mirapol® AZ-1 from Miranol, and the various polyquaternium types (for example 6, 7, 32 or 37) available commercially under the trade names Rheocare® CC or Ultragel® 300.

[0036] Suitable anionic, zwitterionic, amphoteric and nonionic polymers are, for example, vinyl acetate / crotonic acid copolymers, vinylpyrrolidone / vinyl acrylate copolymers, vinyl acetate / butyl maleate / isobornyl acrylate copolymers, methyl vinyl ether / maleic anhydride copolymers and their esters, uncrosslinked and polyol-crosslinked polyacrylic acids, acrylamido-propyltrimethylammonium chloride / acrylate copolymers, octylacrylamide / methyl methacrylate / tert.butylaminoethyl methacrylate / 2-hydroxypropyl methacrylate copolymers, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymers, vinylpyrrolidone / dimethylaminoethyl methacrylate / vinyl caprolactam terpolymers, and optionally derivatized cellulose ethers and silicones.

[0037] <Pearlized wax> Suitable pearlizing waxes are, for example, alkylene glycol esters, in particular ethylene glycol distearate; fatty acid alkanolamides, in particular coco fatty acid diethanolamide; partial glycerides, in particular stearic acid monoglyceride; esters of polybasic, optionally hydroxy-substituted carboxylic acids with fatty alcohols containing from 6 to 22 carbon atoms, in particular the long-chain esters of tartaric acid; fatty compounds, for example fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates containing a total of at least 24 carbon atoms, in particular laurone and distearyl ether; fatty acids, for example stearic acid, hydroxystearic acid or behenic acid, ring-opening products of olefin epoxides containing from 12 to 22 carbon atoms with fatty alcohols containing from 12 to 22 carbon atoms and / or polyols containing from 2 to 15 carbon atoms and 2 to 10 hydroxyl groups, and mixtures thereof.

[0038] <Silicone> Suitable silicones may be selected from the group consisting of: Acrylates / Behenyl, Acrylates / Dimethicone Methacrylate Copolymer, Acrylates / Behenyl Methacrylate / Dimethicone Methacrylate Copolymer, Acrylates / Bis-Hydroxypropyl Dimethicone Crosspolymer, Acrylates / Dimethicone Copolymer, Acrylates / Dimethicone Methacrylate / Ethylhexyl Acrylate Copolymer, Acrylates / Dimethiconol Acrylate Copolymer, Acrylates / Ethylhexyl Acrylate / Dimethicone Methacrylate Copolymer, Acrylates / Octylacrylamide / Diphenylamodimethicone copolymer, acrylates / polytrimethylsiloxymethacrylate copolymer, acrylates / propyl trimethicone methacrylate copolymer, acrylates / stearyl acrylate / dimethicone methacrylate copolymer, acrylates / tridecyl acrylate / triethoxysilylpropyl methacrylate / dimethicone methacrylate copolymer, acrylates / trifluoropropyl methacrylate / polytrimethylsiloxymethacrylate copolymer, aminobispropyl dimethicone, aminoethylaminopropyl Ingredients include: propyl dimethicone, aminopropyl dimethicone, aminopropyl phenyl trimethicone, aminopropyl triethoxysilane, dimethicone PEG-7 ammonium sulfate, amodimethicone, amodimethicone hydroxystearate, amodimethicone / silsesquioxane copolymer, ascorbyl carboxydecyl trisiloxane, ascorbyl methylsilanol pectinate, behenoxy dimethicone, behentrimonium phthalate, dimethicone PEG-8, behenyl dimethicone, bisamino PEG / PPG-4 1 / 3 aminoethyl PG-propyl dimethicone. , bisaminopropyl / ethoxyaminopropyl dimethicone, bis(butyl benzoate)diaminotriazine aminopropyl trisiloxane, bisbutyl dimethicone polyglyceryl-3, bisbutyloxy amodimethicone / PEG-60 copolymer, bis(C13-15 alkoxy)hydroxybutamide amodimethicone, bis(C13-15 alkoxy)PG-amodimethicone, bis-(C1-8 alkyl lauroyl lysine decyl carboxamide)dimethicone, bis-cetyl cetyl dimethicone, bis-cetyl / PEG-8 cetyl PEG-8 dimethicone,Bisdiphenylethyldisiloxane, bisethylethylmethicone, bisgluconamidoethylaminopropyl dimethicone, bishydrogen dimethicone, bishydroxyethoxypropyl dimethicone bishydroxylauryl, dimethicone / IPDI copolymer, bishydroxy / methoxyamodimethicone, bishydroxypropyl dimethicone behenate, bishydroxypropyl dimethicone / SMDI copolymer, bisisobutyl PEG-14 / amodimethicone copolymer, bisisobutyl PEG-15 / amodimethicone copolymer, bisisobutyl PEG / PPG-20 / 35 / Amodimethicone Copolymer, Bis-Isobutyl PEG / PPG-10 / 7 / Dimethicone Copolymer, Bis-Isobutyl PEG-24 / PPG-7 / Dimethicone Copolymer, Bis-PEG-1 Dimethicone, Bis-PEG-4 Dimethicone, Bis-PEG-8 Dimethicone, Bis-PEG-12 Dimethicone, Bis-PEG-20 Dimethicone, Bis-PEG-12 Dimethicone Beeswax, Bis-PEG-12 Dimethicone Candilylate, Bis-PEG-15 Dimethicone / IPDI Copolymer, Bis-PEG-15 Methyl Ether Dimethicone, Bis- PEG-18 methyl ether dimethyl silane, bis-PEG / PPG-14 / 14 dimethicone, bis-PEG / PPG-15 / 5 dimethicone, bis-PEG / PPG-18 / 6 dimethicone, bis-PEG / PPG-20 / 20 dimethicone, bis-PEG / PPG-16 / 16 PEG / PPG-16 / 16 dimethicone, bis-PEG / PPG-20 / 5 PEG / PPG-20 / 5 dimethicone, bisphenylhexamethicone, bis-phenylpropyl dimethicone, bispolyethylene dimethicone, bis-(polyglyceryl-3 oxyphenylpropyl) dimethicone Chicone, Bis-(Polyglyceryl-7 Oxyphenylpropyl) Dimethicone, Bis-PPG-15 Dimethicone / IPDI Copolymer, Bis(PPG-7 Undeceneth-21) Dimethicone, Bis-Stearyl Dimethicone, Bis-Trimethoxysilylethyl Tetramethyldisiloxyethyl Dimethicone, Bis-Vinyl Dimethicone, Bis-Vinyl Dimethicone / Dimethicone Copolymer, Borage Seed Oil PEG-7 Dimethicone Esters, Butyl Acrylate / C6-14 Perfluoroalkylethyl Acrylate / Mercaptopropyl Dimethicone Copolymer,Butyl Acrylate / Hydroxypropyl Dimethicone Acrylate Copolymer, Butyl Dimethicone Acrylate / Cyclohexyl Methacrylate / Ethylhexyl Acrylate Copolymer, Butyl Dimethicone Methacrylate / Methyl Methacrylate Crosspolymer, t-Butyldimethylsiloxyl Grape Seed Extract, Butyl Polydimethylsiloxyl Ethylene / Propylene / Vinyl Norbornene Copolymer, C6-8 Alkyl C3-6 Alkyl Glucoside Dimethicone, C20-24 Alkyl Dimethicone, C24-28 Alkyl Dimethicone, C26-28 Alkyl Dimethicone, C30-45 Alkyl Dimethicone, C30-60 Alkyl Dimethicone, C32 Alkyl Dimethicone, C30-45 Alkyl Dimethicone / Polycyclohexene Oxide Crosspolymer, C26-28 Alkyl Dimethylsilyl Polypropyl Silsesquioxane, C30-45 Alkyl Dimethylsilyl Polypropyl Silsesquioxane, C20-24 Alkyl Methicone, C24-28 Alkyl Methicone, C26-28 Alkyl Methicone, C30-45 Alkyl Methicone, C20-28 Alkyl Perfluorodecyl Ethoxy Dimethicone, C26-54 Alkyltetradecyldimethicone, Capryldimethicone, Capryldimethiconeethoxyglucoside, Caprylylmethicone, Caprylyltrimethicone, Carboxydecyltrisiloxane, Castor Oil Bis-Hydroxypropyl Dimethicone Esters Cerotyle Dimethicone, Cetearyl Dimethicone Crosspolymer, Cetearyl Dimethicone / Vinyl Dimethicone Crosspolymer, Cetearyl Methicone, Cetrimonium Carboxydecyl PEG-8 Dimethicone, Cetrimonium Dimethicone PEG-7 Phthalate, Cetylbehenyl Dimethicone, Cetyl Dimethicone, Cetyl Dimethicone Ingredients include: Cetyl / Bis-Vinyl Dimethicone Crosspolymer, Cetyl Hexacosyl Dimethicone, Cetyl Oxydimethicone, Cetyl PEG-8 Dimethicone, Cetyl PEG / PPG-15 / 15 Butyl Ether Dimethicone, Cetyl PEG / PPG-7 / 3 Dimethicone, Cetyl PEG / PPG-10 / 1 Dimethicone, Cetyl Triethylmonium Dimethicone PEG-8 Phthalate, Cetyl Triethylmonium Dimethicone PEG-8 Succinate, Copper Acetyl Tyrosine Methylsilanol, Copper PCA Methylsilanol, C4-14 Perfluoroalkyl Ethoxy Dimethicone,Cycloethoxymethicone, Cycloheptasiloxane, Cyclohexasiloxane, Cyclomethicone, Cyclopentasiloxane, Cyclophenylmethicone, Cyclotetrasiloxane, m-Cyclovinylmethicone, Cystine Bis-PG-Propyl Silanetriol, DEAPG-Propyl PEG / PPG-18 / 21 Dimethicone, Diisostearoyl Trimethylolpropane Siloxysilicate, Dilauroyl Trimethylolpropane Siloxysilicate, Dilinoleamidopropyl Dimethylamine, Dimethicone PEG-7 Phosphate, Dimethicone, Dimethicone Crosspolymer -, Dimethicone Crosspolymer-3, Dimethicone / Divinyl Dimethicone / Silsesquioxane Crosspolymer, Dimethicone Ethoxyglucoside, Dimethicone Hydroxypropyltrimonium Chloride, Dimethicone / Mercaptopropyl Methicone Copolymer, Dimethicone PEG-15 Acetate, Dimethicone PEG-8 Adipate, Dimethicone PEG-7 Avocadoate, Dimethicone PEG-8 Avocadoate, Dimethicone PEG-8 Beeswax, Dimethicone PEG-8 Benzoate, Dimethicone PEG-8 Borageate, Dimethicone PEG-7 Cocoate, Dimethicone / PEG-10 Crosspolymer, Dimethicone / PEG-10 / 15 Crosspolymer, Dimethicone / PEG-15 Crosspolymer, Dimethicone PEG-7 Isostearate, Dimethicone PEG-8 Isostearate, Dimethicone PEG-7 Lactate, Dimethicone PEG-8 Lanolate, Dimethicone PEG-8 Laurate, Dimethicone PEG-8 Meadowfoamate, Dimethicone PEG-7 Octyldodecyl Citrate, Dimethicone PEG-7 Olivate, Dimethicone PEG-8 Olivate, Dimethicone PEG-7 Phosphate, Dimethicone PE G-8 Phosphate, Dimethicone PEG-10 Phosphate, Dimethicone PEG-7 Phthalate, Dimethicone PEG-8 Phthalate, Dimethicone PEG-8 Polyacrylate, Dimethicone PEG / PPG-20 / 23 Benzoate, Dimethicone PEG / PPG-7 / 4 Phosphate, Dimethicone PEG / PPG-12 / 4 Phosphate, Dimethicone PEG-7 Succinate, Dimethicone PEG-8 Succinate, Dimethicone PEG-7 Sulfate, Dimethicone PEG-7 Non-Decylenate, Dimethicone PG-Diethylmonium Chloride, Dimethicone / Phenyl Vinyl Dimethicone Crosspolymer,Dimethicone / Polyglycerin-3 Crosspolymer, Dimethicone / PPG-20 Crosspolymer, Dimethicone Propyl Ethylenediamine Behenate, Dimethicone Propyl PG Betaine, Dimethicone / Silsesquioxane Copolymer, Dimethicone Silylate, Dimethicone / Vinyl Dimethicone Crosspolymer, Dimethicone / Vinyl Trimethylsiloxysilicate Crosspolymer, Dimethiconol, Dimethiconol Arginine, Dimethiconol Beeswax, Dimethiconol Behenate, Dimethiconol Borageate, Dimethiconol Candelillate, Dimethiconol Calcium Carbonate Nabatate, Dimethiconol Cysteine, Dimethiconol Dupa Butterate, Dimethiconol Fluoroalcohol Dilinoleate, Dimethiconol Hydroxystearate, Dimethiconol Lipetate, Dimethiconol / IPDI Copolymer, Dimethiconol Isostearate, Dimethiconol Kokum Butterate, Dimethiconol Lactate, Dimethiconol Meadowfoamate, Dimethiconol Methionine, Dimethiconol / Methylsilanol / Silicate Crosspolymer, Dimethiconol Mowa Butterate, Dimethiconol Panthenol, Dimethiconol Salvatrate, Dimethiconol / Silica Crosspolymer, Dimethiconol / Silsesquioxane Copolymer, Dimethiconol Stearate, Dimethiconol / Stearyl, Methicone / Phenyl Trimethicone Copolymer, Dimethoxysilyl Ethylenediaminopropyl Dimethicone, Dimethylaminopropylamide PCA Dimethicone, Dimethyloxobenzodioxasilane, Dimethylsilanol Hyaluronate, Dioleyl Tocopheryl Methylsilanol, Diphenylamodimethicone, Diphenyl Dimethicone, Diphenyl Dimethicone Crosspolymer, Diphenyl Dimethicone, Diphenyl Dimethicone Crosspolymer, Phenyl Dimethicone / Ylenyl Diphenyl Dimethicone / Silsesquioxane Crosspolymer, Diphenylethyl Benzyloxydisiloxane, Diphenylisopropyl Dimethicone, Diphenylsiloxyphenyl / Propyl Trimethicone, Diphenylsiloxyphenyl Trimethicone Disiloxane, Amodimethicone Disuccinamate Disodium, PEG-12 Dimethicone Disodium Sulfosuccinate, PEG-8 Lauryl Dimethicone Disodium Sulfosuccinate, Divinyl Dimethicone / Dimethicone Copolymer, Divinyl Dimethicone / Dimethicone Crosspolymer,Drometrizole Trisiloxane, Ethylhexyl Acrylate / VP / Dimethicone Methacrylate Copolymer, Ethyl Methicone, Ethyl Trisiloxane, Fluoro C2-8 Alkyl Dimethicone, Gluconamidopropyl Aminopropyl Dimethicone, 4-(2-β-Glucopyranosyloxy)propoxy-2-Hydroxybenzophenone, G, Lyceryl undecyl dimethicone, glycidoxy dimethicone, hexadecyl methicone, hexyl dimethicone, hexylmethicone, hexyltrimethoxysilane hydrogen dimethicone, hydrogen dimethicone / octylsilsesquioxane copolymer, hydrolyzed collagen PG-propyl dimethiconol, hydrolyzed collagen PG-propyl methylsilanediol, hydrolyzed collagen PG-propyl silanetriol, hydrolyzed keratin PG-propyl methylsilanediol, hydrolyzed sesame protein PG-propyl methylsilanediol, hydrolyzed silk PG-propyl Hydrolyzed Silk PG-Propyl Methyl Silanediol Crosspolymer, Hydrolyzed Soy Protein / Dimethicone PEG-7 Acetate, Hydrolyzed Soy Protein PG-Propyl Methyl Silanediol, Hydrolyzed Vegetable Protein PG-Propyl Silanetriol, Hydrolyzed Wheat Protein / Cystine Bis-PG-Propyl Silanetriol Copolymer, Hydrolyzed Wheat Protein / Dimethicone PEG-7 Acetate, Hydrolyzed Wheat Protein / Dimethicone PEG-7 Phosphate Copolymer, Hydrolyzed Wheat Protein PG-Propyl Methyl Silanediol, Hydrolyzed Wheat Protein PG-Propyl Silanetriol, Hydroxyethyl Acetomonoacetone PG-Dimethicone, Hydroxypropyl Dimethicone, Hydroxypropyl Behenate, Hydroxypropyl Dimethicone Isostearate, Hydroxypropyl Dimethicone Stearate, Isobutyl Methacrylate / Bis-Hydroxypropyl Dimethicone Acrylate Copolymer, Isobutyl Methacrylate / Trifluoroethyl Methacrylate / Bis-Hydroxypropyl Dimethicone Acrylate Copolymer, Trimethoxy Isopentyl Trisiloxane Cinnamate, Isopolyglyceryl-3 Dimethicone, Isopolyglyceryl-3 Dimethiconol, Isopropyl Titanium (Triisostearate / Triethoxysilylethyl), Polydimethylsiloxyethyl Dimethicone Crosspolymer, Isostearyl Carboxydecyl PEG-8 Dimethicone, Lactoyl Methylsilanol Elastic Acid, Lauryl Dimethicone, Lauryl Dimethicone PEG-15 Crosspolymer, Lauryl Dimethicone PEG-10 Phosphate, Lauryl Dimethicone / Polyglycerin-3 Crosspolymer, Lauryl Methicone,Lauryl PEG-8 Dimethicone, Lauryl PEG-10 Methyl Ether Dimethicone, Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone, Lauryl PEG / PPG-18 / 18 Methicone, Lauryl Phenyl Isopropyl Methicone, Lauryl Phenyl Propyl Methicone, Lauryl Polydimethylsiloxyethyl Dimethicone / Bisvinyl Dimethicone Crosspolymer, Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Lauryl Trimethicone, Linoleamidopropyl PG-Dimonium Chloride Phosphate Dimethicone, Methacrylo ... Pyrtrimethoxysilane, Methicone, Methoxyamodimethicone / Silsesquioxane Copolymer, Methoxycinnamidopropyl polysilsesquioxane, Methoxycinnamoylpropyl silsesquioxane, MethoxyPEG-13 Ethylpolysilsesquioxane, MethoxyPEG / PPG-7 / 3 Aminopropyl Dimethicone, MethoxyPEG / PPG-25 / 4 Dimethicone, MethoxyPEG-10 Propyltrimethoxysilane, Methylurenyl PEG-8 Dimethicone, Methylpolysiloxane Emulsion, Methylsilanol Acetyl Methionate, Methylsil Lanol ​​acetyl tyrosine, methylsilanol ascorbate, methylsilanol carboxymethyl theophylline, methylsilanol carboxymethyl theophylline alginate, methylsilanol elastinate, methylsilanol glycyrrhizinate, methylsilanol hydroxyproline, methylsilanol hydroxyproline aspartate, methylsilanol mannuronate, methylsilanol PCA, methylsilanol PEG-7 glyceryl cocoate, methylsilanol / silicate crosspolymer, methylsilanol spirulina acid, Tri-PEG-8 Glyceryl Cocoate, Methyl Trimethicone, Methyltrimethoxysilane, PEG-7 Myristylamidopropyl Dimethicone Phosphate, Myristyl Methicone, Myristyl Trisiloxane, Nylon-611 / Dimethicone Copolymer, PCA Dimethicone, PEG-7 Amodimethicone, PEG-8 Amodimethicone, PEG-8 Cetyl Dimethicone, PEG-3 Dimethicone, PEG-6 Dimethicone, PEG-7 Dimethicone, PEG-8 Dimethicone, PEG-9 Dimethicone, PEG-10 Dimethicone, PEG-12 Dimethicone, PEG-14 Dimethicone,PEG-17 Dimethicone, PEG-10 Dimethicone Crosspolymer, PEG-12 Dimethicone Crosspolymer, PEG-8 Dimethicone Dimer Dilinoleate, PEG-8 Dimethicone / Dimer Dilinoleate Copolymer, PEG-10 Dimethicone / Vinyl Dimethicone Crosspolymer, PEG-8 Distearate Ammonium Chloride PG-Dimethicone, PEG-10 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Polydimethylsiloxyethyl Dimethicone Crosspolymer, PEG-8 Methicone, PEG-6 Methicone Acetate, PEG-6 Methyl Ether Dimethicone, PEG-7 Methyl Ether Dimethicone, PEG-8 Methyl Ether Dimethicone, PEG-9 Methyl Ether Dimethicone, PEG-10 Methyl Ether Dimethicone, PEG-11 Methyl Ether Dimethicone, PEG-32 Methyl Ether Dimethicone, PEG-8 Methyl Ether Triethoxysilane, PEG-10 Nonafluorohexyl Dimethicone Copolymer, PEG-4 PEG-12 Dimethicone, PEG-8 PG-Coco-Glucoside Dimethicone, PEG-9 Polydimethylsiloxyethyl Dimethicone Dimethicone, PEG / PPG-20 / 22 Butyl Ether Dimethicone, PEG / PPG-22 / 22 Butyl Ether Dimethicone, PEG / PPG-23 / 23 Butyl Ether Dimethicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-27 / 9 Butyl Ether Dimethicone, PEG / PPG-3 / 10 Dimethicone, PEG / PPG-4 / 12 Dimethicone, PEG / PPG-6 / 4 Dimethicone, PEG / PPG-6 / 11 Dimethicone, PEG / PPG-8 / 14 Dimethicone, PEG / PPG-8 / 26 Dimethicone, PEG / PPG-1 0 / 2 Dimethicone, PEG / PPG-12 / 16 Dimethicone, PEG / PPG-12 / 18 Dimethicone, PEG / PPG-14 / 4 Dimethicone, PEG / PPG-15 / 5 Dimethicone, PEG / PPG-15 / 15 Dimethicone, PEG / PPG-16 / 2 Dimethicone, PEG / PPG-16 / 8 Dimethicone, PEG / PPG-17 / 18 Dimethicone, PEG / PPG-18 / 6 Dimethicone, PEG / PPG-18 / 12 Dimethicone, PEG / PPG-18 / 18 Dimethicone, PEG / PPG-19 / 19 Dimethicone, PEG / PPG-20 / 6 Dimethicone,PEG / PPG-20 / 15 Dimethicone, PEG / PPG-20 / 20 Dimethicone, PEG / PPG-20 / 23 Dimethicone, PEG / PPG-20 / 29 Dimethicone, PEG / PPG-22 / 23 Dimethicone, PEG / PPG-22 / 24 Dimethicone, PEG / PPG-23 / 6 Dimethicone, PEG / PPG-25 / 25 Dimethicone, PEG / PPG-27 / 27 Dimethicone, PEG / PPG-30 / 10 Dimethicone, PEG / PPG-25 / 25 Dimethicone / Acrylates Copolymer, PEG / PPG-20 / 22 Methyl Ether Dimethicone, PEG / PPG-24 / 24 Methyl Ether Glycidoxy Dimethicone, PEG / PPG-10 / 3 Oleyl Ether Dimethicone, PEG / PPG-5 / 3 Trisiloxane, PEG-4 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trifluoropropyl Dimethicone Copolymer, PEG-10 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trisiloxane, Perfluorocaprylyl Liethoxysilyl Methicone, Perfluorononyl Dimethicone, Perfluorononyl Dimethicone / Methicone / Amodimethicone Crosspolymer, Perfluorononyl Ethyl Carboxydecyl Behenyl Dimethicone, Perfluorononylethyl Carboxydecyl Hexacosyl Dimethicone, Perfluorononylethyl Carboxydecyl Lauryl / Behenyl Dimethicone, Perfluorononylethyl Carboxydecyl Lauryl Dimethicone, Perfluorononylethyl Carboxydecyl PEG-8 Dimethicone, Perfluorononylethyl Carboxydecyl PEG-10 Dimethicone, Perfluorononylethyl Dimethicone / Methicone Copolymer, Perfluorononylethyl PEG-8 Dimethicone, Perfluorononylethyl Stearyl Dimethicone, Perfluorooctylethyl / Diphenyl Dimethicone Copolymer, Perfluorooctylethyl Triethoxysilane, Perfluorooctylethyl Trimethoxysilane, Perfluorooctyl Trisiloxane, Perfluorooctyl Triethoxysilane, PG-Amodimethicone, Phenethyl Dimethicone, Phenethyl Disiloxane, Phenyl Dimethicone, Phenylisopropyl Dimethicone, Phenylmethicone, Phenylmethiconol Phenylpropyl Dimethylsiloxysilicate, Phenylpropyl Ethyl Methicone, Phenylpropyl Trimethicone,Phenylpropyl Trimethicone / Diphenylmethicone, Phenyl Trimethicone, Platinum Divinyldisiloxane, Polyacrylate-6, Polydiethylsiloxane, Polydimethylsiloxyethyl Dimethicone / Bis-Vinyl Dimethicone Crosspolymer, Polydimethylsiloxyethyl Dimethicone / Methicone Copolymer, Polydimethylsiloxy PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-3 Disiloxane Dimethicone, Polyglyceryl-3 / Lauryl Polydimethylsiloxyethyl Dimethicone Crosspolymer, Poly-Glyceryl-3 Polydimethylsiloxyethyl Dimethicone, Poly(glycol adipate) / Bis-Hydroxyethoxypropyl Dimethicone Copolymer, Polymethylsilsesquioxane, Polymethylsilsesquioxane / Trimethylsiloxysilicate, Polyphenylsilsesquioxane, Polypropylsilsesquioxane, Polysilicone-1, Polysilicone-2, Polysilicone-3, Polysilicone-4, Polysilicone-5, Polysilicone-6, Polysilicone-7, Polysilicone Polysilicone-8, Polysilicone-9, Polysilicone-10, Polysilicone-11, Polysilicone-12, Polysilicone-13, Polysilicone-14, Polysilicone-15, Polysilicone-16, Polysilicone-17, Polysilicone-18, Polysilicone-19, Polysilicone-20, Polysilicone-21, Polysilicone-18 Cetyl Phosphate, Polysilicone-1 Crosspolymer, Polysilicone-18 Stearate, Polyurethane-10, Dimethicone PEG-7 Potassium Panthenyl Phosphate, Dimethicone PEG-7 Potassium Phosphate, PPG-12 Butyl Ether Dimethicone, PPG-2 Dimethicone, PPG-12 Dimethicone, PPG-27 Dimethicone, PPG-4 Olease-10 Dimethicone, Propoxytetramethylpiperidinyl Dimethicone, Propyl Trimethicone, Quaternium-80, Retinoxytrimethylsilane, Silanediol Salicylate, Silanetriol, Silanetriol Alginate, Silanetriol Glutamate, Silanetriol Lysinate, Silanetriol Melaninate, Silanetriol Trehalose Ether, Silica, Silica Dimethicone Silylate,Silica dimethyl silylate, silica silylate, silicon carbide, silicone quaternium-1, silicone quaternium-2, silicone quaternium-2 succinate panthenol, silicone quaternium-3, silicone quaternium-4, silicone quaternium-5, silicone quaternium-6, silicone quaternium-, 7, Silicone Quaternium-8, Silicone Quaternium-9, Silicone Quaternium-10, Silicone Quaternium-11, Silicone Quaternium-12, Silicone Quaternium-15, Silicone Quaternium-16, Silicone Quaternium-16 / Glycidoxy Dimethicone Crosspolymer, Silicone Quaternium-17, Silicone Quaternium-18, Silicone Quaternium-19, Silicone Quaternium-20, Silicone Quaternium-21, Silicone Quaternium-22, Silicone Quaternium-24 , Silicone Quaternium-25, Siloxanetriol Alginate, Siloxanetriol Phytate, Simethicone, Sodium Carboxydecyl PEG-8 Dimethicone, Dimethicone PEG-7 Sodium Acetyl Methyl Taurate, Sodium Hyaluronate Dimethylsilanol, Sodium Methylsilanol Lactate, Sodium Methylsilanol Mannuronate, Sodium Methylsilanol PCA, PG-Propyl Dimethicone Sodium Thiosulfate Copolymer, Sodium PG-Propyl Thiosulfate Dimethicone, Sodium Propoxymethyl PEG-Propyl Thiosulfate Dimethicone, Hydroxypropyl Thiosulfate Silica, Sorbityl Silanediol, Soy Triethoxysilylpropyldimonium Chloride, Stearalkonium Dimethicone PEG-8 Phthalate, S-Tetrabutoxypropyl Trisiloxane, Tetramethylhexaphenyltetrasiloxane, Tetramethyltetraphenyltrisiloxane, Tocopheryloxypropyl Trisiloxane, Trideceth-9 PG-Amodimethicone, Triethoxycaprylylsilane, Triethoxysilylethyl Dimethicone / Methicone Copolymer, Triethoxysilylethyl Poly Dimethylsiloxyethyl Dimethicone, Triethoxysilylethyl Polydimethylsiloxyethylhexyl Dimethicone, Triethoxysilylpropyl Carbamoylethoxypropyl Butyl Dimethicone, Trifluoromethyl C1-4 Alkyl Dimethicone, Trifluoropropyl Cyclopentasiloxane, Trifluoropropyl Cyclotetrasiloxane, Trifluoropropyl Dimethicone, Trifluoropropyl Dimethicone / PEG-10 Crosspolymer, Trifluoropropyl Dimethicone / Trifluoropropyl Divinyl Dimethicone Crosspolymer,Trifluoropropyl dimethicone / vinyl trifluoropropyl, dimethicone / silsesquioxane crosspolymer, trifluoropropyl dimethiconol, trifluoropropyl dimethyl / trimethylsiloxysilicate, trifluoropropyl methicone, trimethoxycaprylylsilane, trimethoxysilyl dimethicone, trimethylpentaphenyl trisiloxane, trimethylsiloxyamodimethicone, trimethylsiloxyphenyl dimethicone, trimethylsiloxysilicate, trimethylsiloxysilicate / dimethicone crosspolymer, trimethylsiloxysilicate / dimethiconol crosspolymer, trimethylsiloxysilylcarbamoyl pullulan, trimethylsilyl hydrolyzed conchiolin protein PG-propyl methylsilanediol crosspolymer, trimethylsilyl hydrolyzed silk PG-propyl methylsilanediol crosspolymer Polymer, Trimethylsilyl Hydrolyzed Wheat Protein PG-Propyl Methylsilanediol Crosspolymer, Trimethylsilyl Pullulan, Trimethylsilyl Trimethylsiloxy Glycolate, Trimethylsilyl Trimethylsiloxy Lactate, Trimethylsilyl Trimethylsiloxy Salicylate, Triphenyl Trimethicone, Trisiloxane, Tris-tributoxysiloxymethylsilane, Undecyl Clylene Dimethicone, Vinyl Dimethicone, Vinyl Dimethicone / Lauryl Dimethicone Crosspolymer, Vinyl Dimethicone / Methicone Silsesquioxane Crosspolymer, Vinyl Dimethicone / Stearyl Trimethylsiloxysilicate Crosspolymer, VP / Dimethiconyl Acrylate / Polycarbamyl / Polyglycol Esters, Carboxydecyl Trisiloxane Zinc, Dimethicone PEG-8 Zinc Succinate, and mixtures thereof.

[0039] More preferably, the silicones to be included in the mixture according to the invention are dimethicone, cyclomethicone, phenyltrimethicone, cyclohexasiloxane and cyclopentasiloxane.A detailed overview of suitable volatile silicones can be found in Todd et al., Cosm. Toil. 91, 27 (1976).

[0040] <Waxes and stabilizers> In addition to the natural oils used, waxes may also be present in the preparation, more particularly natural waxes such as candelilla wax, carnauba wax, Japan wax, espartograss wax, cork wax, guaruma wax, rice oil wax, sugarcane wax, ouricury wax, montan wax, beeswax, shellac wax, spermaceti, lanolin (wool wax), uropygien fat, ceresin, ozocerite (earth wax), petrolatum, paraffin wax, microwaxes; chemically modified waxes (hard waxes) such as montan ester wax, sazol wax, hydrogenated jojoba wax, synthetic waxes such as polyalkylene waxes, polyethylene glycol waxes, etc.

[0041] As stabilizers there can be used, for example, metal salts of fatty acids, such as magnesium, aluminium and / or zinc stearates or ricinoleates.

[0042] <Primary sun protection filter> Primary sun protection filters in the sense of the invention are, for example, organic substances (light filters) which are liquid or crystalline at room temperature and are capable of absorbing ultraviolet radiation and releasing the absorbed energy in the form of long-wave radiation, for example heat.

[0043] The products according to the invention advantageously contain at least one UV-A filter and / or at least one UV-B filter and / or a broadband filter and / or at least one inorganic pigment. The products according to the invention preferably contain at least one UV-B filter or a broadband filter, more particularly preferably at least one UV-A filter and at least one UV-B filter.

[0044] The UV filters cited below which can be used within the context of the present invention are preferred but of course are not limiting. The UV filters preferably used are selected from the group consisting of one, two, three, four, five or more of the following: [Table 2]

[0045] In a preferred embodiment, the sun protection filter forming component (II) represents a blend of UV-A- and UV-B-filters selected from the group consisting of homosalate, octocrylene, bis-ethylhexyloxyphenol methoxyphenyl triazine, butyl methoxydibenzoylmethane, ethylhexyl salicylate and mixtures thereof. Particularly preferred is the blend of all these filters as marketed under the name NeoHeliopan® Flat (SYMRISE) of WO2020 / 088778A1.

[0046] Suitable pigments include oxides of titanium (TiO2), zinc (ZnO), iron (Fe2O3), zirconium (ZrO2), silicon (SiO2), manganese (e.g. MnO), aluminum (Al2O3), cerium (e.g. Ce2O3) and / or mixtures thereof.

[0047] In a further preferred embodiment, the product according to the invention contains a total amount of sunscreen agents, i.e. in particular UV filters and / or inorganic pigments (UV filter pigments), such that the product according to the invention has a photoprotection factor of ≧5 and ≦50. Such products according to the invention are particularly suitable for protecting the skin and hair.

[0048] <Secondary sun protection filter> In addition to the group of primary sun protection factors mentioned above, secondary sun protection factors of the antioxidant type can also be used. The antioxidant type secondary sun protection factors interrupt the photochemical reaction chain that is initiated when UV radiation penetrates the skin. Representative examples are amino acids (e.g. glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g. urocanic acid) and their derivatives, peptides such as D,L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g. anserine), carotenoids, carotenes (e.g. α-carotene, β-carotene, lycopene, β-carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, liponic acid and its derivatives (e.g. dihydroliponic acid), aurothioglucose, propylthiouracil, other thiols (thioredoxin, glutathione, cysteine, cystine, cystamine, glycosyl, N-acetylglucosamine, ... methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, α-linoleyl, cholesteryl and glyceryl esters) and their salts, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides and their salts), sulfoximine compounds (e.g. buthionine sulfoximine, homocysteine ​​sulfoximine, buthionine sulfone, penta-, hexa-, hepta-thionine sulfoximine), (metal) chelating agents (e.g. α-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), α-hydroxy acids (e.g. citric acid, lactic acid, malic acid), humic acid, bile acids, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (linoleic acid, oleic acid, etc.), folic acid and its derivatives, ubiquinone, ubiquinol and its derivatives, Vitamin C and its derivatives (ascorbyl palmitate, magnesium ascorbyl phosphate, ascorbyl acetate, etc.), tocopherol and its derivatives (vitamin E acetate, etc.), vitamin A and its derivatives (vitamin A palmitate), coniferyl benzoate from benzoin resin, rutinic acid and its derivatives, glycosyl rutin, ferulic acid, furfurylidene glucitolCarnosine, butylated hydroxytoluene, butylated hydroxyanisole, nordihydroguaiac resin acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, titanium dioxide (e.g. dispersion in ethanol), zinc and its derivatives (e.g. ZnO, ZnSO4), selenium and its derivatives (e.g. selenium methionine), stilbene and its derivatives (e.g. stilbene oxide, trans-stilbene oxide), as well as derivatives of these active substances (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids) suitable for the purposes of the present invention.

[0049] Advantageous inorganic secondary light protection pigments are the finely dispersed metal oxides and metal salts also described in WO 2005 / 123101 A1. The total amount of inorganic pigments, in particular hydrophobic inorganic micropigments, in the finished cosmetic preparation according to the invention is advantageously in each case from 0.1 to 30% by weight, preferably from 0.5 to 10.0% by weight, based on the total weight of the preparation.

[0050] Also preferably, particulate UV filters or inorganic pigments, which may optionally be hydrophobized, can be used, such as oxides of titanium (TiO2), zinc (ZnO), iron (Fe2O3), zirconium (ZrO2), silicon (SiO2), manganese (e.g. MnO), aluminum (Al2O3), cerium (e.g. Ce2O3) and / or mixtures thereof.

[0051] <Biogenic substances and antioxidants> Examples of bioactive substances include tocopherol, tocopherol acetate, tocopherol palmitate, ascorbic acid, (deoxy)ribonucleic acid and fragment products thereof, β-glucan, retinol, bisabolol, allantoin, phytantriol, panthenol, AHA acids, amino acids, ceramides, pseudoceramides, essential oils, plant extracts such as Prunus, bisabolol, allantoin, phytantriol, panthenol, AHA acids, amino acids, ceramides, pseudoceramides, essential oils, plant extracts such as Prunus extract and Bambaranus extract, vitamin complexes.

[0052] Antioxidants interrupt the photochemical reaction chain that is triggered when UV radiation penetrates the skin. Typical examples are amino acids (e.g. glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g. urocanic acid) and their derivatives, peptides such as D,L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g. anserine), carotenoids, carotenes (e.g. -carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g. dihydrophosphate), aurothioglucose, propylthiouracil and other thiols (e.g. thioredoxin, glutathione, cysteine, cystine, cystamine and their glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, linoleyl, cholesteryl and glyceryl esters and their salts, dilauryl thiodipropionate, ditearyl thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts), and sulfoximine compounds (e.g. onine sulfoximine, homocysteine ​​sulfoximine, buthionine sulfone, penta-, hexa-, heptathionine sulfoximine) at very low tolerated doses (e.g. pmol to mol / kg), as well as (metal) chelating agents (e.g. hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), tocopherol and its derivatives (e.g. Vitamin E acetate), Vitamin A and derivatives (vitamin A palmitate), as well as coniferous aryl benzoates of benzoin resin, rutinic acid and its derivatives, glycosyl rutin, ferulic acid, furfurydene glucitol, carnosine, butylated hydroxytoluene, butylated hydroxyanisole, nordihydroguaiac resin acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, zinc and its derivatives (E.Examples: ZnO, ZnSO4), selenium and its derivatives (e.g., selenium-methionine), stilbene and its derivatives (e.g., styrene oxide, trans-stilbene oxide), as well as derivatives of these named active substances suitable for the present invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids).

[0053] <Active ingredient that regulates hair pigmentation> Preferred active ingredients for lightening hair are selected from the group consisting of: kojic acid (5-hydroxy-2-hydroxymethyl-4-pyranone), kojic acid derivatives, preferably kojic acid dipalmitate, arbutin, ascorbic acid, ascorbic acid derivatives, preferably magnesium ascorbyl phosphate, hydroquinone, hydroquinone derivatives, resorcinol, resorcinol derivatives, preferably 4-alkylresorcinols and 4-(1-phenylethyl)1,3-dihydroxybenzene (phenylethylresorcinol), cyclohexyl carbamates (preferably one or more of the cyclohexyl carbamates disclosed in WO2010 / 122178 and WO2010 / 097480), sulfur-containing molecules, preferably glutathione or cysteine, alpha-hydroxy acids (preferably citric acid, lactic acid, malic acid), salts and esters thereof, N-acetyl tyrosine and derivatives, undecenoyl phenylalanine, glucosides, glyceryl phosphate ... acids, chromone derivatives, preferably aloesin, flavonoids, 1-aminoethylphosphinic acid, thiourea derivatives, ellagic acid, nicotinamide (niacinamide), zinc salts, preferably zinc chloride or zinc gluconate, thujaplicin and derivatives, triterpenes, preferably maslinic acid, sterols, preferably ergosterol, benzofuranones, preferably cnidium chloride, vinyl guacol, ethyl guacol, dionic acids, preferably octodecenedioic acid and / or azelaic acid, inhibitors of nitric oxide synthesis, preferably L-nitroarginine and its derivatives, 2,7-dinitroindazole or thiocitrulline, metal chelators (preferably alpha-hydroxy fatty acids, phytic acid, humic acid, bile acids, bile extracts, EDTA, EGTA and its derivatives), retinoids, soy milk and extracts, serine protease inhibitors or lipoic acid or other synthetic or natural active ingredients for lightening the skin and hair.The latter are preferably used in the form of extracts from plants, preferably Sasa kumamotoense extract, rice extract, papaya extract, turmeric extract, mulberry extract, Crassulaceae extract, feverfew extract, licorice root extract or components concentrated or isolated therefrom, preferably glabridin or licochalcone A, Artocarpus extract, Rumex and Ramulus extract, Pinus extract, Grape extract or stilbene derivatives isolated or concentrated therefrom, Saxifragaceae extract, Scutellaria extract, Grape extract and / or microalgae extract, in particular Tetraselmis suecica extract.

[0054] In this respect, active ingredients for skin and hair tanning are preferably selected from the group consisting of substrates or substrate analogues of tyrosinase, such as L-tyrosine, N-acetyltyrosine, L-DOPA, or L-dihydroxyphenylalanine, xanthine alkaloids, such as caffeine, theobromine, and theophylline and their derivatives, proopiomelanocortin peptides, such as ACTH, α-MSH and its peptide analogues and other substances that bind to the melanocortin receptor, such as peptides VAL-GLY-VAL-ALA-PRO-GLY, LYS-LLE-GLY-ARG-LYS, or LEU-LLE-GLY-LYS, purines, pyrimidines, folic acid, copper salts, such as copper gluconate, copper chloride, or copper pyrrolidonate, 1,3,4-oxadiazole-2-thiols, such as 5-pyrazin-2-yl-1,3,4-oxadiazole-2-thiol, curcumin, zinc diglycinate (Zn (Gly)2), manganese(II) bicarbonate complexes ("pseudocatalase"), as described, for example, in EP 0584178, tetrasubstituted cyclohexene derivatives, as described, for example, in WO 2005 / 032501, isoprenoids, as described, for example, in WO 2005 / 102252 and WO 2006 / 010661, melanin derivatives, such as MELASYN-100 and MELANZE, compounds which activate the transfer of melanosomes into keratinocytes, such as diacylglycerols, aliphatic or cyclic diols, psoralens, prostaglandins and analogues thereof, activators of adenylate cyclase, and serine proteases or agonists of the PAR-2 ​​receptor, extracts of plants and plant parts of the genera Chrysanthemum and Sanguisorba, walnut extracts, urucum extracts, rhubarb extracts, microalgae extracts, in particular Isochrysis galbana, trehalose, erythrulose and dihydroxyacetone. Flavonoids which cause skin and hair pigmentation or browning (eg, quercetin, rhamnetin, kaempferol, fisetin, genistein, daidzein, chrysin and apigenin, epicatechin, diosmin and diosmetin, morin, quercitrin, naringenin, hesperidin, phloridzin and phloretin) may also be used.

[0055] The amount of the aforementioned examples of additional active ingredients (one or more compounds) for regulating skin and hair pigmentation in the products according to the invention is then preferably from 0.00001 to 30% by weight, preferably from 0.0001 to 20% by weight, particularly preferably from 0.001 to 5% by weight, based on the total weight of the preparation.

[0056] <Hair growth activators or inhibitors> The products and products according to the invention may also contain one or more hair growth activators, i.e. agents that stimulate hair growth. The hair growth activators are preferably selected from the group consisting of pyrimidine derivatives such as 2,4-diaminopyrimidine-3-oxide (Aminexil), 2,4-diamino-6-piperidinopyrimidine-3-oxide (Minoxidil) and their derivatives, 6-amino-1,2-dihydro-1-hydroxy-2-imino-4-piperidinopyrimidine and its derivatives, xanthine alkaloids and their derivatives, such as caffeine, theobromine, theophylline, quercetin and its derivatives, Dihydroquercetin (taxifolin) and its derivatives, potassium channel openers, antiandrogens, synthetic or natural 5-reductase inhibitors, nicotinic acid esters such as tocopherol nicotinate, benzyl nicotinate, C1-C6 alkyl nicotinates, proteins such as the tripeptide Lys-Pro-Val, diphencyprene, hormones, finasteride, dutasteride, flutamide, bicalutamide, pregnane derivatives, progesterone and its derivatives, cyproterone acetate, diuretics such as spironolactone, calcineurin inhibitors such as FK506 (tacrolimus, fujimycin) and its derivatives, cyclosporin A and its derivatives, zinc and zinc salts, polyphenols, procyanidins, proanthocyanidins These are phytosterols such as β-sitosterol, biotin, eugenol, (±)-β-citronellol, panthenol, glycogen, e.g. from mussels, extracts from microorganisms, algae, plants and plants and plant parts, such as, e.g., Dandelion (Leontodon or Taraxacum), Orthosiphon, Vitex, Coffea, Paulinia, Theobroma, Asiasarum, Cucurbita or Styphnolobium, Saw Palmetto, Sophora flavescens, Pygium africanum, Millet, Cimicifuga racemosa, Soybean, Eugenia caryophyllata, Cotinus kogyglia, Hibiscus, Tea, Yew, Isochrysis galbana, Licorice, Grape, Apple, Barley or Hops, or / and hydrolysates from rice or wheat.

[0057] Alternatively, the products and supplies may contain one or more hair growth inhibitors (as described above), ie, agents that reduce or prevent hair growth. The hair growth inhibitor is preferably an activin, an activin derivative or an activin agonist, an ornithine decarboxylase inhibitor, such as alpha difluoromethylornithine or a pentacyclic triterpene, such as ursolic acid, betulin, betulinic acid, oleanolic acid and its derivatives, a 5α-reductase inhibitor, an androgen receptor antagonist, an S-adenosylmethionine decarboxylase inhibitor, a gamma glutamyl transpeptidase inhibitor, a transglutaminase inhibitor, a soybean-derived serine protease inhibitor, such as an inhibitor of the genus Chondrus, Gloiopeltis, Ceramium, Durvillea, Glycine max, Sanguisorba officinalis, Calendula officinalis, Hamamelis virginiana, Arnica montana, Salix alba, Hypericum perforatum or Gymnema They are extracts from microorganisms of the genus sylvestre, algae, various microalgae or plants and plant parts.

[0058] <Physiological cooling and heating agents> The physiological cooling agent is preferably selected from the group formed by the species depicted in the table below, including their optical isomers and racemates: [Table 3]

[0059] The physiological warming agent may be selected from the group consisting of capsaicin, dihydrocapsaicin, nordihydrocapsaicin, homocapsaicin, homodihydrocapsaicin nonivamide, and chili pepper extract.

[0060] <Anti-inflammatory agents> Suitable anti-inflammatory agents may be selected from the group formed by: (i) steroidal anti-inflammatory substances of the corticosteroid type, in particular hydrocortisone, hydrocortisone derivatives such as hydrocortisone 17-butyrate, dexamethasone, dexamethasone phosphate, methylprednisolone or cortisone, (ii) nonsteroidal anti-inflammatory substances, in particular oxicams such as piroxicam and tenoxicam, salicylates such as aspirin, disalcid, solprin and fendosal, acetate derivatives such as diclofenac, fenclofenac, indomethacin, sulindac, tolmetin and clindanac, fenamates such as mefenam, meclofenam, flufenam and niflumin, propionate derivatives such as ibufenam, flufenam and niflumin, acetate derivatives such as tolmetin and clindanac, fenamic acid derivatives such as mefenam, meclofenam, flufenam and niflumin, propionate derivatives such as ibuprofen, naproxen and benoxaprofen, pyrazoles such as phenylbutazone, oxyphenylbutazone, febrazone and azapropazone, (iii) natural or naturally occurring anti-inflammatory substances or substances which relieve redness and / or itching, in particular extracts or fractions from chamomile, Aloe vera, Commiphora spp., Rubia spp., willow, willow herb, oats, calendula, arnica, St. John's wort, honeysuckle, rosemary, Passiflora incarnata, witch hazel, ginger or echinacea, or single active compounds thereof; (iv) histamine receptor antagonists, serine protease inhibitors (e.g., of soybean extracts), TRPV1 antagonists (e.g., 4-t-butylcyclohexanol), NK1 antagonists (e.g., aprepitant, hydroxyphenylpropamidobenzoic acid), cannabinoid receptor agonists (e.g., palmitoylethanolamine) and TRPV3 antagonists.

[0061] <Antimicrobial agents> Suitable antimicrobial agents are in principle all substances which are effective against gram-positive bacteria, such as, for example, 4-hydroxybenzoic acid and its salts and esters, N-(4-chlorophenyl)-N'-(3,4-dichloro-phenyl)urea, 2,4,4'-trichloro-2'-hydroxy-diphenyl ether (triclosan), 4-chloro-3,5-dimethyl-phenol, 2,2'-methylenebis(6-bromo-4-chlorophenol), 3-methyl-4-(1-methylethyl)phenol, 2-benzyl-4-chloro-phenol, 3-(4-chlorophenoxy)-1,2-propanediol, 3-iodo-2-propynyl butylcarbamate, chlorhexidine, 3,4,4'-trichlorocarbanilide (TTC), antibacterial fragrances, thymol, thyme oil, eugenol, clove oil, menthol, mint oil, farnesol, Phenoxyethanol, glycerol monocaprate, glycerol monocaprylate, glycerol monolaurate (GML), diglycerol monocaprate (DMC), salicylic acid N-alkylamides such as n-octyl salicylamide or n-decyl salicylamide.

[0062] <Enzyme inhibitors> Suitable enzyme inhibitors are, for example, esterase inhibitors. These are preferably trialkyl citrates, such as trimethyl citrate, tripropyl citrate, triisopropyl citrate, tributyl citrate, and especially triethyl citrate (Hydagen CAT). These substances inhibit enzyme activity and suppress odor generation. Other substances that are suitable esterase inhibitors are sterol sulfates or phosphates, such as lanosterol, cholesterol, campesterol, stigmasterol and sitosterol sulfates or phosphates, dicarboxylic acids and their esters, such as glutaric acid, monoethyl glutarate, diethyl glutarate, adipic acid, monoethyl adipate, diethyl adipate, malonic acid, diethyl malonate, and other dicarboxylic acids and their esters, hydroxycarboxylic acids and their esters, such as citric acid, malic acid, tartaric acid, diethyl tartrate, and other zinc glycinate.

[0063] <Odor Absorbent and Antiperspirant Activator> Suitable odor absorbers are substances that are able to absorb odor-forming compounds and retain a large part of them. They reduce the partial pressure of the individual components and also the diffusion rate. It is important that the fragrance is not damaged in the process. Odor absorbers are ineffective against bacteria. They consist, for example, of complex zinc salts of ricinoleic acid as the main ingredient, or of specific, mainly odorless fragrances, known to those skilled in the art as "fixatives", such as extracts of labdanum or styrax, or of specific abietic acid derivatives. Odor masking agents are fragrances or perfume oils, which, in addition to their function as odor masking agents, also impart the respective fragrance notes to the deodorant. Perfume oils are, for example, mixtures of natural and synthetic fragrances. Natural fragrances are those extracted from flowers, stems, leaves, fruits, peels, roots, trees, herbs, grasses, needles, branches, resins and balsams. Also suitable are animal products, such as, for example, civet or castoreum. Typical synthetic fragrance compounds are ester, ether, aldehyde, ketone, alcohol, and hydrocarbone type products. Ester type fragrance compounds include, for example, benzyl acetate, p-tert-butylcyclohexyl acetate, linalyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, allyl cyclohexylpropionate, styryl propionate, and benzyl salicylate. Ethers include, for example, benzyl ethyl ether, and aldehydes include, for example, linear alkanals having 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilial, and burgeonal. The ketones include, for example, ionones, methyl cedryl ketone, etc., the alcohols include anethole, citronellol, eugenol, isoeugenol, geraniol, linalool, phenylethyl alcohol, terpineol, etc., and the hydrocarbons include mainly terpenes, balsams, etc. However, it is preferable to use mixtures of different fragrances that produce a pleasant fragrance note.Essential oils with relatively low volatility are primarily used as aroma ingredients, but are also suitable as perfume oils, such as sage oil, chamomile oil, clove oil, melissa oil, mint oil, cinnamon leaf oil, linden flower oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil, labdanum oil, and lavandin oil. It is preferable to use bergamot oil, dihydromyrcenol, lilial, lyral, citronellol, phenylethyl alcohol, α-hexylcinnamaldehyde, geraniol, benzyl acetone, cyclamen aldehyde, linalool, boisambrene forte, ambroxan, indole, hedione, sandelice, lemon oil, mandarin oil, orange oil, allyl amyl glycolate, cyclovertal, lavandin oil, clary sage oil, β-damascone, bourbon geranium oil, cyclohexyl salicylic acid, vertfix cour, iso-E-super, fixolide NP, evernyl, iraldein gamma, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romirat, irotyl and floramat, either alone or in admixture.

[0064] Suitable astringent antiperspirant active ingredients are mainly salts of aluminum, zirconium or zinc.Such suitable antiperspirant active ingredients are, for example, aluminum chloride, aluminum chlorohydrate, aluminum dichlorohydrate, aluminum sesquichlorohydrate and their complexes, for example with 1,2-propylene glycol, aluminum hydroxyalantoinate, aluminum chloride tartrate, aluminum zirconium trichlorohydrate, aluminum zirconium tetrachlorohydrate, aluminum zirconium pentachlorohydrate and their complexes, for example with amino acids, such as glycine.

[0065] <Film-forming agents and anti-dandruff agents> Standard film-forming agents are, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymers, polymers of the acrylic acid series, quaternized cellulose derivatives, collagen, hyaluronic acid and its salts, and similar compounds.

[0066] Suitable antidandruff agents include Piroctone Olamine (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2-(1H)-pyridinone monoethanolamine salt), Baypival™ (climbazole), Ketoconazol™ (4-acetyl-1-{4-[2-(2,4-dichlorophenyl)R-2-(1H-imidazol-1-ylmethyl)-1,3-dioxiran-C-4-ylmethoxyphenyl}-piperazine, ketoconazole, elubiol, selenium disulfide, colloidal sulfur, Sulfur polyethylene glycol sorbitan monooleate, sulfur ricinol polyethoxylate, sulfur tar distillate, salicylic acid (or in combination with hexachlorophene), undecylenic acid, monoethanolamide sulfosuccinic acid sodium salt, Lamepon™ UD (protein / undecylenic acid condensate), zinc pyrithione, aluminum pyrithione, magnesium pyrithione / dipyrithione sulfate.

[0067] <Carriers and hydrotropes> Preferred cosmetic carrier materials are solid or liquid (including highly viscous substances) at 25°C and 1013 mbar, such as, for example, glycerol, 1,2-propylene glycol, 1,2-butylene glycol, 1,3-propylene glycol, 1,3-butylene glycol, ethanol, water and mixtures of two or more of the above liquid carrier materials with water. Optionally, these preparations according to the invention can be prepared using preservatives or solubilizers. Other preferred liquid carrier substances that may be components of the preparations according to the invention are selected from the group consisting of oils, such as vegetable oils, neutral oils and mineral oils.

[0068] Preferred solid carrier materials which may be components of the formulation according to the invention are hydrocolloids such as starch, degraded starches, chemically or physically modified starches, dextrins, (powdered) maltodextrins (preferably with a dextrose equivalent value of 5 to 25, preferably 10 to 20), lactose, silicon dioxide, glucose, modified cellulose, gum arabic, gum ghatti, tragacanth, karaya, carrageenan, pullulan, curdlan, xanthan gum, gellan gum, guar flour, carob flour, alginates, agar-agar, pectin and inulin, and mixtures of two or more of these solids, in particular maltodextrins (preferably with a dextrose equivalent value of 15 to 20), lactose, silicon dioxide and / or glucose.

[0069] In addition, hydrotropes such as ethanol, isopropyl alcohol or polyols can be used to improve the flow behavior. Suitable polyols preferably contain 2 to 15 carbon atoms and at least two hydroxyl groups. The polyols may contain other functional groups, in particular amino groups, or may be modified with nitrogen. Typical examples are: - glycerol; - alkylene glycols having an average molecular weight of 100 to 1000 daltons, such as ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol, polyethylene glycol; - methylol compounds, in particular trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol, dipentaerythritol; - lower alkyl glucosides, especially those containing 1 to 8 carbon atoms in the alkyl group, such as methyl glucoside and butyl glucoside; - sugar alcohols containing 5 to 12 carbon atoms, such as sorbitol and mannitol; - sugars containing 5 to 12 carbon atoms, such as glucose and sucrose; - amino sugars, for example glucamine; - dialcoholamines, such as diethanolamine or 2-aminopropane-1,3-diol.

[0070] <Preservatives and / or product protectants> Suitable preservatives are listed in parts A and B of Annex 6 of the Kosmetikver-ordnung ("Cosmetics Directive").

[0071] Suitable species may be selected from the group consisting of preservatives selected from the group consisting of: Benzoic acid and parahydroxybenzoic acid, their esters and salts, benzyl benzoate, propionic acid and its salts, salicylic acid and its salts, 2,4-hexadienoic acid (sorbic acid) and its salts, levulinic acid and its salts, anisic acid and its salts, perillic acid and its salts, cinnamic acid and its salts, formaldehyde and paraformaldehyde, 4-hydroxybenzaldehyde, ortho-, meta- and para-anisaldehyde, cinnamic aldehyde, cinnamic alcohol, 2-hydroxybiphenyl ether and its salts, 2-zinc-sulfidopyridine-N-oxide, inorganic sulfites and bisulfites, sodium iodate, Chlorobutanol, 4-ethylmercury-(II) 5-amino-1,3-bis(2-hydroxybenzoic acid), its salts and esters, dehydrated acetic acid, formic acid, 1,6-bis(4-amidino-2-bromophenoxy)-N-hexane and its salts, sodium salt of ethylmercury-(II)-thiosalicylic acid, phenylmercury and its salts, 10-undecylenic acid and its salts, 5-amino-1,3-bis(2-ethylhexyl)-5-methyl-hexahydropyrimidine, 5-bromo-5-nitro-1,3-dioxane, 2-bromo-2-nitro-1,3-propanediol, 2,4-Dichlorobenzyl alcohol, N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)-urea, 4-chloro-M-cresol, 2,4,4'-trichloro-2'-hydroxy-diphenyl ether, 4-chloro-3,5-dimethylphenol, 1,1'-methylene-bis(3-(1-hydroxymethyl-2,4-dioxyimidazolidin-5-yl)urea), poly-(hexamethylenediguanide) hydrochloride, (benzyloxymethoxy)-methanol hexamethylenetetramine, 1-(3-chloroallyl)-3,5,7-triaza-1-azonia-adamantane chloride, 1-(4-chlorophenoxy)-1-(1H-imidazol-1-yl)-3,3-dimethyl-2-butanone, 1,3-bis-(hydroxymethyl)-5,5-dimethyl-2, 4-Imidazolidinedione, 1,2-Dibromo-2,4-dicyanobutane, 2,2'-Methylene-bis(6-bromo-4-chlorophenol), bromochlorophene, mixture of 5-chloro-2-methyl-3(2H)-isothiazolinone, mixture of 2-methyl-3(2H)-isothiazolinone with magnesium chloride and magnesium nitrate, 2-octyl-2H-isothiazol-3-one, 1,2-benzisothiazol-3(2H)-one, 2-benzyl-4-chlorophenol, 3-(4-chlorophenoxy)-1,2-propanediol (chlorphenesin), 2-chloroacetamide, chlorhexidine, chlorhexidine acetate, chlorhexidine gluconate, chlorhexidine hydrochloride, N-alkyl (C12-C22) trimethylammonium bromides and chlorides, 4,4-dimethyl-1,3-oxazolidine, N-hydroxymethyl-N-(1,3-di(hydroxymethyl)-2,5-dioxoimidazolidin-4-yl)-N'-hydroxymethylurea, 1,6-bis(4-amidino-phenoxy)-N-hexane and its salts, glutaraldehyde, 5-ethyl-1-aza-3,7-dioxabicyclo(3.3.0)octane, 3-(4-chlorophenoxy)-1,2-propanediol, hyamine, alkyl-(C8-C18)-dimethyl-benzylammonium chloride, alkyl- (C8-C18)-Dimethyl-benzylammonium bromide, alkyl-(C8-C18)-dimethyl-benzylammonium saccharinate, benzyl hemiformal, 3-iodo-2-propynyl butylcarbamate, sodium hydroxymethylaminoacetate or sodium hydroxymethylaminoacetate, imidazolidinyl urea, diazolidinyl urea, sodium hydroxymethylglycinate, DMDM ​​hydantoin, tropolone, (ethylenedioxy)dimethanol, 2-Bromo-2-(bromomethyl)pentanedinitrile, N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine, α,α',α"-trimethyl-1,3,5-triazine-1,3,5(2H,4H,6H)-triethanol, pyridine-2-thiol-1-oxide, sodium salt, tetrahydro-1,3,4,6-tetrakis(hydroxymethyl)imidazo[4,5-D]imidazole-2,5(1H,3H)-dione, 1,3-bis(hydroxymethyl)-1-(1,3,4-Tris(hydroxymethyl)-2,5-dioxoimidazolidin-4-yl)urea (diazolidinyl urea), 1.3-bis(hydroxymethyl)-5,5-dimethylimidazolidine-2,4-dione, 3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one, cetylpyridinium chloride, caprylhydroxamic acid, sorbohydroxamic acid and mixtures thereof; 1,3-propanediol, methylpropanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol, 1,5-pentanediol, 1,6-hexanediol, 1,8-octanediol, 1,2-decanediol, ethylhexylglycerin, hexoxy-propane-1,2-diol, heptoxy-propane-1,2-diol, octoxy-propane-1,2-diol, 3-phenoxy-propane-1,2-diol, 3-benzyloxy-propane-1,2-diol, 3-phenylethyloxy-propane-1,2-diol, 3-phenylpropyloxy-propane-1,2-diol, 3-methylbenzyloxy-propane-1,2-diol, sorbitan caprylate, triclosan, climbazole, Octopirox (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2(1H)-pyridone, 2-aminoethanol), chitosan, farnesol, 2-butyloctanoic acid, 2-benzylheptan-1-ol, glycerol monolaurate, bis(2-pyridylthio)zinc 1,1'-dioxide, N,N'-(decane-1,10-diyldipyridin-1-yl-4-ylidene)-dioctan-1-amine dihydrochloride (octenidine dihydrochloride), thymol, eugenol, benzyl alcohol, 2-phenylethyl alcohol, 3-phenylpropanol, 2-phenoxyethanol, 1-phenoxy-propan-2-ol, 3-phenoxypropanol, benzyloxymethanol, 4-hydroxyacetophenone, and mixtures thereof.

[0072] <Perfume oil> Suitable perfume oils are mixtures of natural and synthetic fragrances. Natural fragrances include flowers (lily, lavender, rose, jasmine, neroli, ylang-ylang), stems and leaves (geranium, patchouli, petitgrain), fruits (anise, coriander, caraway, juniper), peels (bergamot, lemon, orange), roots (nutmeg, angelica, celery, cardamom, costus, iris, calmus), woods (pinewood, sandalwood, guaiacwood, cedarwood, rosewood), herbs and grasses (tarragon, lemongrass, sage, thyme), needles and branches (spruce, fir, pine, dwarf pine), resins and balsams (galbanum, elemi, benzoin, myrrh, olibanum, opoponax). Animal sources such as civet and beaver may also be used.

[0073] <Wood-scented fragrance> Suitable fragrances having a woody scent are selected from the group consisting of: [Table 4]

[0074] <Amber scented fragrance> Suitable fragrances having an amber scent are selected from the group consisting of: [Table 5]

[0075] <Fruity fragrance> Suitable fragrances having a fruity smell are selected from the group consisting of: [Table 6]

[0076] <Musky fragrance> Suitable fragrances having a musk odor are selected from the group consisting of: [Table 7] The fragrances summarized above also represent preferred embodiments for said secondary fragrances which form the main components of the claimed perfume compositions.

[0077] <dye> Suitable dyes are any of the substances suitable and approved for cosmetic purposes, for example as described in the publication "Kosmetische Farbemittel" of the Farbstoff-kommission der Deutschen Forschungsgemeinschaft, Verlag Chemie, Weinheim, 1984, pp. 81 to 106. Examples include cochineal red A (CI 16255), patent blue V (CI 42051), indigotine (CI 73015), chlorophyllin (CI 75810), quinoline yellow (CI 47005), titanium dioxide (CI 77891), indanthrene blue RS (CI 69800) and madder lake (CI 58000). Luminol may also be present as a luminescent dye. Advantageous color pigments are, for example, titanium dioxide, mica, iron oxides (e.g. Fe2O3 Fe3O4, FeO(OH)) and / or tin oxide. Advantageous dyes are, for example, carmine, Berlin blue, chromium oxide green, ultramarine blue and / or manganese violet.

[0078] <Prescription> Preferred compositions according to the invention are selected from the group of products for the treatment, protection, care and cleansing of the skin and / or hair or as make-up products, preferably as leave-on products (meaning that one or more compounds remain on the skin and / or hair for a longer period of time compared to rinse-off products).

[0079] The products according to the invention are preferably emulsions, such as W / O (water in oil), O / W (oil in water), W / O / W (oil in water), O / W / O (water in oil) emulsions, PIT emulsions, Pickering emulsions, emulsions with a low oil content, microemulsions or nanoemulsions, solutions, such as in oils (fatty oils or fatty acid esters, in particular C6-C32 fatty acid C2-C30 esters) or silicone oils, dispersions, suspensions, creams, lotions or milks ( depending on the method of manufacture and the ingredients), gels (including hydrogels, hydrodispersion gels, oleogels), sprays (e.g. pump sprays or sprays with propellers) or foams or impregnating solutions for cosmetic wipes, cleaning agents, e.g. soaps, detergents, liquid cleaning agents, shower and bath products, bath products (capsules, oils, tablets, salts, bath additives, soaps, etc.), foaming agents, skin care products, e.g. milks (mentioned above), ointments, pastes, gels (mentioned above), oils, balsams, serums, powders (e.g. Face powders, body powders), eau de parfums, eau de toilettes, aftershaves, masks, pencils, sticks, roll-ons, pumps, aerosols (foaming, non-foaming or post-foaming), deodorants and / or antiperspirants, mouthwashes and mouth rinses, foot care products (including keratolytics, deodorants), insect repellents, sunscreens, aftersun products, shaving products, aftershave balms, pre- and aftershave lotions, depilatories, shampoos (2-in-1 shampoos, anti-dandruff These include hair care products such as hair straightening shampoos, hair tonics, hair waters, hair rinses, styling creams, pomades, perm / setting lotions, hair sprays, styling aids (gels, waxes, etc.), hair smootheners (detangling agents, relaxers), hair dyes (temporary direct dyes, semi-permanent hair dyes, permanent hair dyes, etc.), hair conditioners, hair mousses, eye care products, make-up, make-up removers, baby products, etc.

[0080] The auxiliary substances and additives can be contained in an amount of 5 to 99% by weight, preferably 10 to 80% by weight, based on the total weight of the product. The amount of cosmetic or dermatological auxiliary substances and additives and fragrances to be used in each case can be easily determined by the skilled artisan by simple trial and error, depending on the nature of the particular product.

[0081] The formulation may also contain water in an amount of up to 99 percent by weight, preferably from about 5 to about 80 percent by weight, more preferably from about 10 to about 50 percent by weight or from about 60 to about 80 percent by weight, based on the total weight of the formulation.

[0082] <Detergent products> Another object of the present invention relates to a detergent product comprising said fragrance mixture or said perfume composition. Said product may contain said fragrance mixture or perfume composition in an amount ranging from about 0.01 to about 2% by weight, preferably from about 0.1 to 1% by weight, calculated on the detergent product. Suitable examples of detergents include heavy duty powder detergents, heavy duty liquid detergents, light duty powder detergents, light duty liquid detergents, detergent tablets, fabric softeners, manual dishwashing agents, all-purpose cleaners, etc.

[0083] The detergent compositions according to the invention may comprise any of the ingredients conventionally found in such compositions, such as, for example, anionic, nonionic, cationic, amphoteric or zwitterionic (co)surfactants, organic solvents, builders, enzymes, and additional adjuvants such as soil repellents, thickeners, colourants and fragrances.

[0084] <Anionic and zwitterionic surfactants> Representative examples of anionic and zwitterionic surfactants include the following: Almondamidopropylamine oxide, almondamidopropyl betaine, aminopropyl lauryl glutamine, C12-15 alkyl ammonium sulfate, C12-16 alkyl ammonium sulfate, ammonium caprylyl sulfate, coco monoglyceride ammonium sulfate, Ammonium coco sulfate, ammonium cocoyl isethionate, ammonium cocoyl sarcosinate, C12-15 ammonium palmitate sulfate, C9-10 ammonium perfluoroalkyl sulfonate, ammonium di-nonyl sulfosuccinate, ammonium dodecylbenzenesulfonate, ammonium isostearate, ammonium laureth-6 carboxylate, ammonium laureth-8 carboxylate, ammonium laureth sulfate, ammonium laureth-5 sulfate, ammonium laureth-7 sulfate, ammonium laureth-9 sulfate, ammonium laureth-12 sulfate, ammonium lauroyl sarcosinate, ammonium lauryl sulfate, ammonium lauryl sulfosuccinate, ammonium myreth sulfate, ammonium myristyl sulfate, ammonium nonoxynol-4 sulfate, ammonium nonoxynol-30 sulfate, ammonium oleate, ammonium palm kernel sulfate, ammonium stearate, ammonium tartarate, AMPD-isostearic acid AMP-isostearoyl hydrolyzed collagen, AMPD-rosin hydrolyzed collagen, AMP-isostearoyl hydrolyzed collagen, AMP-isostearoyl hydrolyzed keratin, AMP-isostearoyl hydrolyzed soy protein, AMP-isostearoyl hydrolyzed wheat protein, apricotamidopropyl betaine, arachidic acid, arginine hexyldecyl phosphate, avocadoamidopropyl betaine, avocado oil glycereth-8 ester, babassu acid, babassuamidopropylamine o Oxide, Babassuamidopropyl Betaine, Beeswax Acid, Behenamidopropyl Betaine, Behenamine Oxide, Beheneth-25, Beheneth-30, Behenic Acid, Behenyl Betaine, Bis-Butyldimethicone Polyglyceryl-3, Butoxynol-5 Carboxylic Acid, Butoxynol-19 Carboxylic Acid, Butyldimonium Hydroxypropyl Butylglucoside Chloride, Butyldimonium Hydroxypropyl Laurylglucoside Chloride, Butyl Glucoside, Butyl Glucoside Caprate,Butyl Glucoside Hydroxypropyltrimonium Chloride, Butyl Octanoic Acid, C18-36 Acid, C20-40 Acid, C30-50 Acid, C16-22 Acid Amide MEA, Calcium Dodecyl Benzene Sulfonate, Calcium Lauroyl Taurate, C9-16 Alkane / Cycloalkane, C10-14 Alkyl Benzene Sulfonate, C12-14 Alkyl Diaminoethyl Glycine HCL, C9-15 Alkyl Phosphate, Candida Bombicola / Glucose / Methyl Rapeseed Oil Ferment, Canolamidopropyl Betaine, Capric Acid, Caproic Acid, Caproyl Ethyl Glycine Capryl / Capramidopropyl Betaine, Capryleth-4 Carboxylic Acid, Capryleth-6 Carboxylic Acid, Capryleth-9 Carboxylic Acid, Capryloyl Collagen Amino Acid, Capryloyl Glycine, Capryloyl Hydrolyzed Collagen, Capryloyl Hydrolyzed Keratin, Capryloyl Keratin Amino Acid, Capryloyl Silk Amino Acid, Caprylyl / Capryl Glucoside, Caprylyl / Capryl Wheat Bran / Straw Glycoside, Caprylyl Glucoside, Caprylyl Glyceryl Ether, Caprylyl Pyrrolidone, Carnitine, Ceteareth-20, Ceteareth-23, Ceteareth-24, Ceteareth-25, Ceteareth-27, Ceteareth-28, Ceteareth-29, Ceteareth-30, Ceteareth-33, Ceteareth-34, Ceteareth-40, Ceteareth-50, Ceteareth-55, Ceteareth-60, Ceteareth-80, Ceteareth-100, Ceteareth-25 carboxylic acid, Ceteareth-2 phosphate, Ceteareth-4 phosphate, Ceteareth-5 phosphate, Ceteareth-10 phosphate, Ceteth-20, Ceteth-23, Ceteth-24, Ceteth-25, Ceteth-30, Ceteth-40, Ceteth-45, Ceteth-1 50, Ceteth-8 Phosphate, Ceteth-10 Phosphate, Ceteth-20 Phosphate, Cetyl-22, Cetyl-24, Cetyl-25, Cetyl-30, Chrysanthemum Flower Extract, C12-14 Hydroxyalkyl Hydroxyethyl Beta-Alanine, C12-14 Hydroxyalkyl Hydroxyethyl Sarcosine, Cocamidoethyl Betaine, Cocamidopropyl Amine Oxide, Cocamidopropyl Betaine Amide MEA Chloride, Cocamidopropyl Betaine, Cocamidopropyl Hydroxysultaine, Cocamine Oxide, Cocaminobutyric Acid, Cocaminopropionic Acid,Coceth-7 Carboxylic Acid, Coceth-4 Glucoside, Cocoamphodipropionic Acid, Cocobetaine Amido Amphopropionate, Cocobetaine, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Coco-Glucoside, Coco-Glucoside Hydroxypropyltrimonium Chloride, Coco Hydroxysultaine, Cocomorpholine Oxide, Coconut Acid, Coconut Oil Glycereth-8 Esters, Coco / Oleamide Propyl Betaine, Coco Sultaine, Coco / Sunflower Amidopropyl Betaine, Cocoyl Choline Methosulfate, Cocoyl Glutamic Acid, Cocoyl Hydrolyzed Collagen, Cocoyl Hydrolyzed Keratin, Cocoyl Hydrolyzed Oat Protein, Cocoyl Hydrolyzed Rice Protein, Cocoyl Hydrolyzed Silk, Cocoyl Hydrolyzed Soy Protein, Cocoyl Hydrolyzed Wheat Protein, Cocoyl Sarcosine, Corn Acid, Cottonseed Acid, Cottonseed Oil Glycereth-8 Esters, C10-16 Pareth-1, C10-16 Pareth-2, C11-13 Pareth-6, C1 1-13 Pares-9, C11-13 Pares-10, C11-15 Pares-30, C11-15 Pares-40, C12-13 Pares-1, C12-13 Pares-23, C12-14 Pares-5, C12-14 Pares-9, C13-15 Pares-21, C14-15 Pares-8, C20-22 Pares-30, C20-40 Pares-40, C20-40 Pares-95, C22-24 Pares-33, C30-50 Pares-40, C9-11 Pares-6 carboxylic acid, C9-11 Pares-8 carboxylic acid, C11-15 Pares-7 carboxylic acid, C12 -13 paraffin-5 carboxylic acid, C12-13 paraffin-7 carboxylic acid, C12-13 paraffin-8 carboxylic acid, C12-13 paraffin-12 carboxylic acid, C12-15 paraffin-7 carboxylic acid, C12-15 paraffin-8 carboxylic acid, C12-15 paraffin-12 carboxylic acid, C14-15 paraffin-8 carboxylic acid, C6-10 paraffin-4 phosphate, C12-13 paraffin-2 phosphate, C12-13 paraffin-10 phosphate, C12-15 paraffin-6 phosphate, C12-15 paraffin-8 phosphate, C12-15 paraffin-10 phosphate, C12-16 paraffin-6 phosphate,C4-18 Perfluoroalkylethylthiohydroxypropyltrimonium chloride, Cupasamidopropyl betaine, DEA-C12-13 alkyl sulfate, DEA-C12-15 alkyl sulfate, DEA-Ceteareth-2 phosphate, DEA-Cetyl sulfate, DEA-Cocoamphodipropionate, DEA-C12-13 pareth-3 sulfate, DEA-Cyclocarboxypropyl oleate, DEA-Dodecylbenzenesulfonic acid, DEA-Isostearate, DEA-Laureth sulfate, DEA-Lauryl sulfate, DEA-Linoleic acid, DEA-Methylmyristic acid sulfonic acid, DEA-Myristic acid, DEA-Myristyl sulfate, DEA-Oleth-5 phosphate, DEA-Oleth-20 phosphate, DEA PG-oleic acid, deceth-7 carboxylic acid, deceth-7 glucoside, deceth-9 phosphate, decylamine oxide, decyl betaine, decyl glucoside, decyl tetradeceth-30, decyl tetradecylamine oxide, lauramide-MEA diammonium sulfosuccinate, lauryl diammonium sulfosuccinate, oleamide PEG-2 diammonium sulfosuccinate, dibutoxymethane, di-C12-15 pareth-2 phosphate, di-C12-15 pareth-4 phosphate, di-C12-15 pareth-6 phosphate, di-C12-15 pareth-8 phosphate, di-C12-15 pareth-10 phosphate, butanetetracarboxylate didodecyl, diethylamine laureth sulfate, sodium diethylhexyl sulfosuccinate, dihydroxyethyl C8-10 alkoxypropyl Amine Oxide, Dihydroxyethyl C9-11 Alkoxypropylamine Oxide, Dihydroxyethyl C12-15 Alkoxypropylamine Oxide, Dihydroxyethyl Cocamine Oxide, Dihydroxyethyl Rholamine Oxide, Dihydroxyethyl Stearamine Oxide, Dihydroxyethyl Tallowamine Oxide, Dimethicone PEG-7 Phosphate, Dimethicone PEG-10 Phosphate, Dimethicone PEG / PPG-7 / 4 Phosphate, Dimethicone PEG / PPG-12 / 4 Phosphate, Dimethicone / Polyglycerin-3 Crosspolymer, Dimethicone Propyl PG-Betaine, Dimyristyl Phosphate, Dioleoylamidoethyl Hydroxyethylmonium Methosulfate, DIPA-Hydrogenated Cocoate, DIPA-Lanolate, DIPA-Myristate,Dipotassium Capryloyl Glutamate, Dipotassium Lauryl Sulfosuccinate, Dipotassium Undecylenoyl Glutamate, Disodium Vabasamide MEA-Sulfosuccinate, Disodium Caproamphodiacetate, Disodium Caproamphodipropionate, Disodium Capryloamphodiacetate, Disodium Capryloamphodipropionate, Disodium Capryloyl Glutamate, Disodium Cetearyl Sulfosuccinate, Disodium Cetyl Phenyl Ether Disulfonate, Disodium Cetyl Sulfosuccinate, Disodium Cocamide MEA-Sulfosuccinate, Disodium Cocamide MIPA PEG-4 Sulfosuccinate Disodium, Cocamide MIPA-Sulfosuccinate Disodium, Cocamide PEG-3 Sulfosuccinate Disodium, Coceth-3 Sulfosuccinate Disodium, Cocoampho-Carboxyethyl Hydroxypropyl Sulfonate Disodium, Cocoampho Diacetate Disodium, Cocoampho Dipropionate Disodium, Sulfosuccinic Acid Coco-Glucoside, Coco-Sulfosuccinate Disodium, Cocoyl Butyl Gluceth-10 Sulfosuccinate Disodium, Cocoyl Glutamate Disodium, C12-14 Pareth-1 Sulfosuccinate Disodium, C12-14 Pareth-2 Sulfosuccinate Disodium, C12-15 Pareth-3 Sulfosuccinate Disodium, C12-14 Sec-Pareth-5 Sulfosuccinate Disodium Disodium C12-14 Sec-Palace-7 Sulfosuccinate, Disodium C12-14 Sec-Palace-9 Sulfosuccinate, Disodium C12-14 Sec-Palace-12 Sulfosuccinate, Disodium Deceth-5 Sulfosuccinate, Disodium Deceth-6 Sulfosuccinate, Disodium Decyl Phenyl Ether Disulfonate, Disodium Dihydroxyethyl Sulfosuccinyl Undecylenate, Disodium Ethylene Dicocamide PEG-15 Disulfinate, Disodium Hydrogenated Cottonseed Glyceride Sulfosuccinate, Disodium Hydrogenated Scutellaria Glutamate, Disodium Hydroxydecyl Sorbitol Citrate, Disodium Isodecyl Sulfosuccinate, Disodium Isostearamide MEA-Sulfosuccinate, Disodium Isostearamide MIPA-Sulfosuccinate,Disodium Isostearoyl Amphodiacetate, Disodium Isostearoyl Amphodipropionate, Disodium Isostearyl Sulfosuccinate, Disodium Laneth-5 Sulfosuccinate, Disodium Lauramide MEA Sulfosuccinate, Disodium Lauramide MIPA Glycol Sulfosuccinate, Disodium Lauramide PEG-2 Sulfosuccinate, Disodium Lauramide PEG-5 Sulfosuccinate, Disodium Laureth-5 Carboxyamphodiacetate, , disodium laureth-7 citrate, disodium laureth sulfosuccinate, disodium laureth-6 sulfosuccinate, disodium laureth-9 sulfosuccinate, disodium laureth-12 sulfosuccinate, disodium lauriminobishydroxypropylsulfonate, disodium lauriminodiacetate, disodium lauriminodipropionate, disodium lauriminodipropionate tocopheryl phosphate, disodium lauroamphodiacetate, disodium lauroamphodipropionate, disodium N-lauroyl aspartate, lauroyl glycerin Disodium glutamate, disodium lauryl phenyl ether disulfonate, disodium lauryl sulfosuccinate, myristamide MEA-sulfosuccinate, disodium nonoxynol-10 sulfosuccinate, disodium oleamide MEA-sulfosuccinate, disodium oleamide MIPA-sulfosuccinate, disodium oleamide PEG-2 sulfosuccinate, disodium oleoamphodipropionate, disodium olease-3 sulfosuccinate, disodium oleyl phosphate, disodium oleyl sulfosuccinate, palmitate Disodium PEG-2 Sulfosuccinate, Palmitoleamide PEG-2 Sulfosuccinate, Disodium PEG-4 Cocamide MIPA-Sulfosuccinate, Disodium PEG-12 Dimethicone Sulfosuccinate, Disodium PEG-8 Palm Glyceride Sulfosuccinate, Disodium PPG-2-Rosodeceth-7 Carboxyamphodiacetate, Disodium Ricinoleamide MEA-Sulfosuccinate, Disodium Sitosterol-14 Sulfosuccinate, Disodium Soybean Amphodiacetate, Disodium Stearamide MEA-Sulfosuccinate um, disodium stearimidinyl dipropionate, disodium stearoyl amphodiacetate, disodium stearoyl glutamate, disodium stearyl sulfosuccinate, disodium stearyl sulfosuccinate, disodium 2-sulfolaurate, disodium 2-sulfopalmitate, disodium tallowamide MEA-sulfosuccinate, disodium tallowamide MEA-sulfosuccinate, disodium tallowamide MEA-sulfosuccinate, disodium tallowamide amphodiacetate, disodium tallowamide dipropionate, disodium tallowamide sulfosuccinate, disodium tridecyl sulfosuccinate,Disodium Undecylenamide MEA-Sulfosuccinate, Disodium Undecylenamide PEG-2 Sulfosuccinate, Disodium Undecylenoyl Glutamate, Disodium Wheat Germamide MEA-Sulfosuccinate, Disodium Wheat Germamide PEG-2 Sulfosuccinate, Disodium Wheat Germamide F-Diacetate, Di-TEA-Cocamide Diacetate, Disodium Di-TEA-Oleamide PEG-2 Sulfosuccinate, Disodium Di-TEA-Palmitoyl Aspartate, Sodium Ditridecyl Sulfosuccinate, Dodecyl Benzene Sulfonic Acid , Erucamidopropyl Hydroxysultaine, Ethylhexyl-3 Carboxylate, Ethyl PEG-15 Cocamine Sulfate, Glyceryl Capryl Ether, Hexyldecanoic Acid, Hydrogenated Coconut Acid, Hydrogenated Laneth-25, Hydrogenated Menhaden Acid, Hydrogenated Palm Acid, Hydrogenated Palm Kernel Amine Oxide, Hydrogenated Tallow Acid, Hydrogenated Tallow Amine Oxide, Hydrogenated Tallow Betaine, Hydrogenated Tallow-25, Hydrogenated Tallow Oil Glutamic Acid, Hydrolyzed Candida Bombicola Extract, Hydroxyceteth-60, Hydroxyethylacetemonium PG-Dimethicone, Hydroxyethylbutylamine Laureth Sulfate Acid salts, Hydroxyethyl Carboxymethyl Cocamidopropylamine, Hydroxyethyl Hydroxypropyl C12-15 Alkoxypropylamine Oxide, Hydroxylauryl / Hydroxymyristyl Betaine, Hydroxystearic Acid, Hydroxysuccinimidyl C10-40 Isoalkyl Acidate, Hydroxysuccinimidyl C21-22 Isoalkyl Acidate, Hydroxysultaine, IPDI / PEG-15 Soyamine Oxide Copolymer, IPDI / PEG-15 Soyethonium Ethosulfate Copolymer, IPDI / PEG-15 Soybean Oil Iglycinate Copolymer, Isoceteth-30, Isolaureth-4 Phosphate, Isopolyglyceryl-3 Dimethicone, Isopolyglyceryl-3 Dimethiconol, Isopropanolamine Lanolate, Isopropylamine Dodecylbenzene Sulfonate, Isostearamidopropylamine Oxide, Isostearamidopropyl Betaine, Isostearamidopropyl Morpholine Oxide, Isosteareth-8, Isosteareth-16, Isosteareth-22, Isosteareth-25, Isosteareth-50, Isostearic Acid, Isostearoyl Hydrolyzed Collagen,Jojoba Oil PEG-150 Ester, Jojoba Wax PEG-80 Ester, Jojoba Wax PEG-120 Ester, Laneth-20, Laneth-25, Laneth-40, Laneth-50, Laneth-60, Laneth-75, Lanolinic Acid, Lauramidopropylamine Oxide, Lauramidopropyl Betaine, Lauramidopropyl Hydroxysultaine, Lauramine Oxide, Lauraminopropionic Acid, Laurdimonium Hydroxypropyl Decyl Glucoside Chloride Lauryl glucoside chloride, laureth-16, laureth-20, laureth-21, laureth-23, laureth-25, laureth-30, laureth-38, laureth-40, laureth-3 carboxylic acid, laureth-4 carboxylic acid, laureth-5 carboxylic acid, laureth-6 carboxylic acid, laureth-8 carboxylic acid, laureth-10 carboxylic acid, laureth-11 carboxylic acid, laureth-12 carboxylic acid, laureth-13 carboxylic acid, laureth-14 carboxylic acid, laureth-17 carboxylic acid, laureth-6 citrate, laureth-7 citrate, laureth-1 phosphate, laureth-2 phosphate, laureth-3 phosphate, laureth-4 phosphate, laureth-7 phosphate, laureth-8 phosphate, laureth-7 tartrate, lauric acid, lauriminobispropanediol, lauriminodipropionic acid, lauroamphodipropionic acid, lauroyl beta-alanine, lauroyl collagen a Amino Acid, Lauroyl Ethyltrimonium Methosulfate, Lauroyl Hydrolyzed Collagen, Lauroyl Hydrolyzed Elastin, Lauroyl Methyl Glucamide, Lauroyl Sarcosine, Lauroyl Silk Amino Acids, Lauryl Betaine, Lauryl Dimethicone / Polyglycerin-3 Crosspolymer, Lauryl Dimonium Hydroxypropyl Cocoglucoside Chloride, Lauryl Glucoside, Lauryl Glucoside Hydroxypropyltrimonium Chloride, Lauryl Glycol Hydroxypropyl Ether, Lauryl Hydroxysultaine, Lauryl Malamide, Lauryl Methyl Glucamide, Lauryl / Myristyl Glycol Hydroxypropyl Ether, Lauryl / Myristyl Wheat Bran / Straw Glycosides, Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Lauryl Pyrrolidone, Lauryl Sultaine, Linoleic Acid, Linolenic Acid, Flaxseed Acid, Cocoyl Lysine,Macadamia Seed Oil Glycereth-8 Esters, Magnesium Coceth Sulfate, Magnesium Coco Sulfate, Magnesium Isododecyl Benzene Sulfonate, Magnesium Laureth-11 Carboxylate, Magnesium Laureth Sulfate, Magnesium Laureth-5 Sulfate, Magnesium Laureth-8 Sulfate, Magnesium Laureth-16 Sulfate, Magnesium Laureth-3 Sulfosuccinate, Magnesium Lauryl Hydroxypropyl Sulfonate, Magnesium Lauryl Sulfate, Magnesium Methyl Cocoyl Taurate, Magnesium Myreth Sulfate, Magnesium Oleic Acid Sulfate, Magnesium / TEA-Coco Sulfate, Maniqueaghan Clay, MEA-Cocoate, MEA-Laureth-6 Carboxylate, MEA-Laureth Sulfate, MEA-Lauryl ... PPG-6 Laureth-7 Carboxylate, MEA-PPG-8 Steareth-7 Carboxylate, MEA-Undecylenate, Meroxapol 108, Meroxapol 174, Meroxapol 178, Meroxapol 254, Meroxapol 255, Meroxapol 258, Meroxapol 314, Methoxy PEG-450 Amido Glutaroyl Succinimide, Methoxy PEG-450 Amido Hydroxysuccinimidyl Succinamate, Methoxy PEG-450 Maleimide, Methylmorpholine Oxide, Milcamidopropyl Amine Oxide, Milcamidopropyl Betaine, Mincamidopropyl Amine Oxide, Mincamidopropyl Betaine, MIPA C12-15 Pareth Sulfate, MIPA-Dodecylbenzene Sulfonate, MIPA-Laureth Sulfate, MIPA-Lauryl Sulfate, Mixed Isopropanolamine Lanolate, Mixed Isopropanolamine Lauryl Sulfate, Mixed Isopropanolamine Myristate, Morpholine Oleate, Morpholine Stearate, Myreth-3 Carboxylic Acid, Myreth-5 Carboxylic Acid, Myristalkonium Chloride, Myristamidopropylamine Oxide, Myristamidopropyl Betaine, Myristamidopropyl Dimethylamine Phosphate, Myristamidopropyl Hydroxysultaine, Myristamidopropyl PG-Dimonium Chloride Phosphate, Myristamidopropyl Oxide, Myristamidopropyl Aminopropionic Acid, Myristic Acid, Myristoyl Ethyltrimonium Metasulfate, Myristoyl Glutamic Acid, Myristoyl Hydrolyzed Collagen, Myristoyl Sarcosine, Myristyl Betaine,Myristyl / Cetylamine Oxide, Myristyldimonium Hydroxypropyl Coco-Glucoside Chloride, Myristyl Glucoside, Myristyl Phosphate, Nonoxynol-20, Nonoxynol-23, Nonoxynol-25, Nonoxynol-30, Nonoxynol-35, Nonoxynol-40, Nonoxynol-44, Nonoxynol-50, Nonoxynol-100, Nonoxynol-120, Nonoxynol-5 Carboxylic Acid, Nonoxynol-8 Carboxylic Acid, Nonoxynol-10 Carboxylic Acid, Nonoxynol-3 Phosphate, Nonoxynol-4 Phosphate Acid, Nonoxynol-6 phosphate, Nonoxynol-9 phosphate, Nonoxynol-10 phosphate, Nonylnonoxynol-30, Nonylnonoxynol-49, Nonylnonoxynol-100, Nonylnonoxynol-150, Nonylnonoxynol-7 phosphate, Nonylnonoxynol-8 phosphate, Nonylnonoxynol-9 phosphate, Nonylnonoxynol-10 phosphate, Nonylnonoxynol-11 phosphate, Nonylnonoxynol-15 phosphate, Nonylnonoxynol-24 phosphate, Oatamidopropyl betaine, Octoxynol-16, Octoxynol Octyl-25, Octyl-30, Octyl-33, Octyl-40, Octyl-70, Octyl-20 Carboxylic Acid, Octyldodeceth-20, Octyldodeceth-25, Octyldodeceth-30, Oleamidopropylamine Oxide, Oleamidopropyl Betaine, Oleamidopropyl Hydroxysultaine, Oleamine Oxide, Oleic Acid, Oleoyl Hydrolyzed Collagen, Oleoyl Sarcosine, Oleth-20, Oleth-23, Oleth-24, Oleth-25, Oleth-30, Oleth-35, Oleth-40, Oleoyl S-44, Oleth-50, Oleth-3 Carboxylic Acid, Oleth-6 Carboxylic Acid, Oleth-10 Carboxylic Acid, Oleyl Betaine, Olivamidpropylamine Oxide, Olivamidpropyl Betaine, Olive Acid, Olive Oil Hydrolyzed Wheat Protein, Ophiopogon Extract Stearate, Ozonated Oleth-10, Ozonated PEG-10 Oleate, Ozonated PEG-14 Oleate, Ozonated Polysorbate 80, Palm Acid, Palmimidopropyl Betaine, Palmeth-2 Phosphate, Palmitamidopropylamine Oxide, Palmitamidopropyl Betaine,Palmitamine Oxide, Palmitic Acid, Palmitoyl Collagen Amino Acids, Palmitoyl Glycine, Palmitoyl Hydrolyzed Collagen, Palmitoyl Hydrolyzed Milk Protein, Palmitoyl Hydrolyzed Wheat Protein, Palmitoyl Keratin Amino Acids, Palmitoyl Oligopeptide, Palmitoyl Silkure, Amino Acid, Palm Nucleic Acid, Palm Kernel Amidopropyl Betaine, Peach Kernel Oil Glycereth-8 Ester, Peanut Acid, PEG-10 Castor Oil, PEG-40 Castor Oil, PEG-44 Castor Oil, PEG-50 Castor Oil, PEG-54 Castor Oil, PEG-55 Castor Oil, PEG-60 Castor Oil, PEG-80 Castor Oil, PEG-100 Castor Oil, PEG-200 Castor Oil, PEG-11 Cocamide, PEG-6 Cocamide Phosphate, PEG-4 Cocamine, PEG-8 Cocamine, PEG-12 Cocamine, PEG-150 Dibehenate, PEG-90 Diisostearate, P EG-75 Dilaurate, PEG-150 Dilaurate, PEG-75 Dioleate, PEG-150 Dioleate, PEG-75 Distearate, PEG-120 Distearate, PEG-150 Distearate, PEG-175 Distearate, PEG-190 Distearate, PEG-250 Distearate, PEG-30 Glyceryl Cocoate, PEG-40 Glyceryl Cocoate, PEG-78 Glyceryl Cocoate, PEG-80 Glyceryl Cocoate, PEG-30 Glyceryl Isostearate, PEG-40 Glyceryl Isostearate PEG-50 Glyceryl Isostearate, PEG-60 Glyceryl Isostearate, PEG-90 Glyceryl Isostearate, PEG-23 Glyceryl Laurate, PEG-30 Glyceryl Laurate, PEG-25 Glyceryl Oleate, PEG-30 Glyceryl Oleate, PEG-30 Glyceryl Soybean Oil Fatty Acid, PEG-25 Glyceryl Stearate, PEG-30 Glyceryl Stearate, PEG-40 Glyceryl Stearate, PEG-120 Glyceryl Stearate, PEG-200 Glyceryl Stearate, PEG-100 Glyceryl Stearate, PEG-2 ... 28 Glyceryl, PEG-80 Glyceryl Tallowate, PEG-82 Glyceryl Tallowate, PEG-130 Glyceryl Tallowate, PEG-200 Glyceryl Tallowate, PEG-45 Hydrogenated Castor Oil, PEG-50 Hydrogenated Castor Oil, PEG-54 Hydrogenated Castor Oil, PEG-55 Hydrogenated Castor Oil, PEG-60 Hydrogenated Castor Oil, PEG-80 Hydrogenated Castor Oil, PEG-100 Hydrogenated Castor Oil, PEG-200 Hydrogenated Castor Oil, PEG-30 Hydrogenated Lanolin, PEG-70 Hydrogenated Lanolin, PEG-50 Hydrogenated Palmamide, PEG-2 Isostearate, PEG-3 Isostearate,PEG-4 Isostearate, PEG-6 Isostearate, PEG-8 Isostearate, PEG-10 Isostearate, PEG-12 Isostearate, PEG-20 Isostearate, PEG-30 Isostearate, PEG-40 Isostearate, PEG-26 Jojoba Acid, PEG-40 Jojoba Acid, PEG-15 Jojoba Alcohol, PEG-26 Jojoba Alcohol, PEG-40 Jojoba Alcohol, PEG-35 Lanolin, PEG-40 Lanolin, PEG-50 Lanolin, PEG-55 Lanolin, PEG-60 Lanolin, PEG-70 Lanolin Nolin, PEG-75 Lanolin, PEG-85 Lanolin, PEG-100 Lanolin, PEG-150 Lanolin, PEG-75 Lanolin Oil, PEG-2 Lauramide, PEG-3 Lauramine Oxide, PEG-20 Laurate, PEG-32 Laurate, PEG-75 Laurate, PEG-150 Laurate, PEG-70 Mango Glycerides, PEG-20 Mannitan Laurate, PEG-8 Methyl Ether Dimethicone, PEG-120 Methyl Glucose Dioleate, PEG-80 Methyl Glucose Laurate, PEG-120 Trioleate Methyl Glucose, PEG-4 Montanate, PEG-30 Oleate, PEG-20 Oleate, PEG-23 Oleate, PEG-32 Oleate, PEG-36 Oleate, PEG-75 Oleate, PEG-150 Oleate, PEG-20 Palmitic Acid, PEG-150 Polyglyceryl-2 Tristearate, PEG / PPG-28 / 21 Acetate Dimethicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-3 / 17 Copolymer, PEG / PPG-5 / 35 Copolymer, PEG / PPG-8 / 55 Copolymer -, PEG / PPG-10 / 30 copolymer, PEG / PPG-10 / 65 copolymer, PEG / PPG-12 / 35 copolymer, PEG / PPG-16 / 17 copolymer, PEG / PPG-20 / 9 copolymer, PEG / PPG-20 / 20 copolymer, PEG / PPG-20 / 60 copolymer, PEG / PPG-20 / 65 copolymer, PEG / PPG-22 / 25 copolymer, EG / PPG-28 / 30 copolymer, PEG / PPG-30 / 35 copolymer, PEG / PPG-30 / 55 copolymer, PEG / PPG-35 / 40 copolymer,PEG / PPG-50 / 40 Copolymer, PEG / PPG-150 / 35 Copolymer, PEG / PPG-160 / 30 Copolymer, PEG / PPG-190 / 60 Copolymer, PEG / PPG-200 / 40 Copolymer, PEG / PPG-300 / 55 Copolymer, PEG / PPG-20 / 22 Methyl Ether Dimethicone, PEG-26-PPG-30 Phosphate Ester, PEG / PPG-4 / 2 Propylheptyl Ether, PEG / PPG-6 / 2 Propylheptyl Ether, PEG-7 / PPG-2 Propylheptyl Ether, PEG / PPG-8 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Propylheptyl Ether, PEG / PPG-14 / 2 Propylheptyl Ether, PEG / PPG-40 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Ricinoleate, PEG / PPG-32 / 3 Ricinoleate, PEG-55 Propylene Glycol Oleate, PEG-25 Propylene Glycol Stearate, PEG-75 Propylene Glycol Stearate, PEG-120 Propylene Glycol Stearate, PEG-5 Rapeseed Sterol, PEG-10 Rapeseed Sterol Seed Sterols, PEG-40 Ricinoleamide, PEG-75 Shea Butter Glycerides, PEG-75 Shorea Butter Glycerides, PEG-20 Sorbitan Cocoate, PEG-20 Sorbitan Isostearate, PEG-40 Sorbitan Lanolinate, PEG-75 Sorbitan Lanolinate, PEG-10 Sorbitan Laurate, PEG-40 Sorbitan Laurate, PEG-44 Sorbitan Laurate, PEG-75 Sorbitan Laurate, PEG-80 Sorbitan Laurate, PEG-20 Sorbitan Oleate, PEG-80 Sorbitan Palmitate, Sodium Chloride ...0 Sorbitan Palmitate, Sodium Chloride, PEG-10 Sorbitan Laurate, PEG-40 Sorbitan Laurate, PEG-40 Sorbitan Oleate, PEG-80 Sorbitan Palmitate, Sodium Chloride, PEG-10 Sorbitan Laurate, PEG-10 Sorbitan Laurate, PEG-10 Sorbitan Laurate, PEG-10 Sorbitan Laurate, PEG-10 Sorbitan Laurate, PEG-10 Sorbitan Laurate, PEG-10 Sorbitan Laurate, PEG-10 Sorbitan Laurate, PEG-10 Sorbitan Laurate, PEG-40 Sorbitan Stearate, PEG-60 Sorbitan Stearate, PEG-160 Sorbitan Triisostearate, PEG-40 Soy Sterol, PEG-2 Stearamido Carboxylic Acid, PEG-9 Stearamido Carboxylic Acid, PEG-20 Stearate, PEG-23 Stearate, PEG-25 Stearate, PEG-30 Stearate, PEG-32 Stearate, PEG-35 Stearate, PEG-36 Stearate, PEG-40 Stearate, PEG-45 Stearate, PEG-50 Stearate, PEG-55 Stearate,PEG-75 Stearate, PEG-90 Stearate, PEG-100 Stearate, PEG-120 Stearate, PEG-150 Stearate, PEG-45 Stearate Phosphate, PEG-20 Tallowate, PEG-50 Tallowamide, PEG-2 Tallowamide DEA, PEG-20 Tallowate, PEG-66 Trihydroxystearin, PEG-200 Trihydroxystearin, PEG-60 Camellia Glycerides, Pelargonic Acid, Pentadoxyl-200, Phenes-6 Phosphate, Poloxamer 105, Poloxamer 108, Poloxamer Poloxamer 182, Poloxamer 183, Poloxamer 184, Poloxamer 188, Poloxamer 217, Poloxamer 234, Poloxamer 235, Poloxamer 237, Poloxamer 238, Poloxamer 288, Poloxamer 334, Poloxamer 335, Poloxamer 338, Poloxamine 908, Poloxamine 1508, Polydimethylsiloxy PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-6 Caprate, Polyglyceryl Dilaurate -10, Polyglyceryl-20 Heptacaprylate, Polyglyceryl-20 Hexacaprylate, Polyglyceryl-2 Lauryl Ether, Polyglyceryl-10 Lauryl Ether, Polyglyceryl-20 Octaisononanoate, Polyglyceryl-6 Pentacaprylate, Polyglyceryl-10 Pentacaprylate, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Polyglyceryl-6 Tetracaprylate, Polyglyceryl-10 Tetralaurate, Polyglyceryl-6 Tricaprylate, Polyglyceryl-10 Trilaurate, Polyquaternium-1 Polyquaternium-77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81, Polyquaternium-82, Pomadelis Coumera Flower / Leaf Extract, Polyacocos Extract, Potassium Abietoyl Hydrolyzed Collagen, Potassium Babastinate, Potassium Behenate, Potassium C9-15 Alkyl Phosphate, Potassium C11-15 Alkyl Phosphate, Potassium C12-13 Alkyl Phosphate, Potassium C12-14 Alkyl Phosphate, Potassium Caprate, Potassium Capryloyl Glutamate, Capryloyl Hydrolyzed Rice Protein,Potassium Castorate, Potassium Cocoate, Potassium Cocoyl Glutamate, Potassium Cocoyl Glycinate, Potassium Cocoyl Hydrolyzed Caseinate, Potassium Cocoyl Hydrolyzed Collagen, Potassium Cocoyl Hydrolyzed Corn Protein, Potassium Cocoyl Hydrolyzed Keratin Protein, Potassium Cocoyl Hydrolyzed Oat Protein, Potassium Cocoyl Hydrolyzed Potato Protein, Potassium Cocoyl Hydrolyzed Rice Bran Protein, Potassium Cocoyl Hydrolyzed Rice Protein, Potassium Cocoyl Hydrolyzed Silk Protein, Potassium Cocoyl Hydrolyzed Soy Protein, Potassium Cocoyl Hydrolyzed Wheat Protein, Potassium Cocoyl Hydrolyzed Yeast Protein, Potassium Cocoyl PCA, Potassium Cocoyl Sarcosinate, Potassium Cocoyl Taurate, Potassium Cornate, Potassium Cyclocarboxypropylate, Potassium Dihydroxyethyl Cocamine Oxide Phosphate, Potassium Dimethicone PEG-7 Phosphate, Potassium Dodecyl Benzene Sulfonate, Potassium Hemp Seed Acid, Potassium Hydrogenated Cocoate, Potassium Hydrogenated Palmitate, Potassium Hydrogenated Tallowate, Potassium Hydroxystearate, Potassium Isostearate, Potassium Lanolate, Potassium Laurate, La Potassium ureth-3 carboxylate, potassium laureth-4 carboxylate, potassium laureth-5 carboxylate, potassium laureth-6 carboxylate, potassium laureth-10 carboxylate, potassium laureth-phosphate, potassium lauroyl collagen amino acid, potassium lauroyl glutamate, lauroyl hydrolyzed collagen, potassium lauroyl hydrolyzed pea protein, potassium lauroyl hydrolyzed soy protein, potassium lauroyl PCA, potassium lauroyl pea amino acid, potassium lauroyl sarcosinate, potassium lauroyl silk amino acid, potassium lauroyl wheat amino acid, potassium lauryl phosphate, potassium lauryl sulfate, potassium linoleate, potassium metaphosphate, potassium methyl cocoyl taurate, potassium myristate, potassium myristoyl glutamate, potassium myristoyl hydrolyzed collagen, potassium octoxynol-12 phosphate, potassium oleate, potassium oleoyl hydrolyzed collagen, potassium olivine, potassium olivoyl hydrolyzed oat protein, potassium olivoyl hydrolyzed wheat protein, potassium olivoyl / lauroyl wheat amino acid,Olivoyl PCA potassium, potassium palmitate, potassium palmitate, palmitoyl hydrolyzed corn protein, palmitoyl hydrolyzed oat protein, palmitoyl hydrolyzed rice protein, palmitoyl hydrolyzed sweet almond protein potassium, palmitoyl hydrolyzed wheat protein potassium, palm kernel acid potassium, peanut acid, Potassium, Rapeseed Potassium, Potassium Ricinoleate, Potassium Safflowerate, Potassium Soyate, Potassium Stearate, Potassium Stearoyl Hydrolyzed Collagen, Potassium Taurate, Potassium Taurate, Potassium Taurine Laurate, Potassium Trideceth-3 Carboxylate, Potassium Trideceth-4 Carboxylate, Potassium Trideceth-7 Carboxylate, Potassium Trideceth-15 Carboxylate, Potassium Trideceth-19 Carboxylate, Potassium Trideceth-6 Phosphate, Potassium Trideceth-7 Phosphate, Potassium Camellia Acid, Potassium Undecylenate, Potassium Undecylenoyl Hydrolyzed Collagen, Potassium Undecylenoyl Hydrolyzed Rice Protein, PPG-30-Buteth-30, PPG-36-Buteth-36, PPG-38-Buteth-37, PPG-30-Capryles-4 Phosphate, PPG-10 Cetyl Ether Phosphate, PPG-2 C9-11 Pareth-8, PPG-1-Deceth-5, PPG-3-Deceth-2 Carboxylic Acid, PPG-30 Ethylhexyl-4 Phosphate, PPG-20 Glycereth-30, PPG-2 Hydroxyethyl Coco / Isostearamide, PPG-2-Isodeceth-8, PPG-2-Isodeceth-10, PPG-2-Isodeceth-18, PPG-2-Isodeceth-25, PPG-4-Isodeceth-10, Propyltrimonium Hydrolyzed Collagen, Quaternium-24, Quaternium-52, Quaternium-87, Rapeseed Acid, Rice Bran Acid, Rice Oil Glycereth-8 Ester, Ricinoleamidopropyl Betaine, Ricinoleic Acid, Ricinoleic Acid, Ricinoleic Ace-40, Safflower Acid, Sapindus Oauensi Ingredients: Citrus Fruit Extract, Saponaria Officinalis Root Powder, Saponin Soap-K, Soap-Sodium / K, Soap Soap, Soap Soap-K, Sesame Oil Glycereth-8 Ester, Sesamidopropylamine Oxide, Sesamidopropyl Betaine, Shea Butter Amidopropyl Betaine, Shea Butter Glycereth-8 Ester, Sodium Arachidate, Sodium Arganumfoacetate, Sodium Astropotamycin Murmurate, Sodium Avocadoate, Sodium Babassu Amphoacetate, Sodium Babassu Acid, Sodium Babassu Sulfate, Sodium Behenate, Sodium Bis-Glycolricinosulfosuccinate, Sodium Bis-Hydroxyethylglycinate Coco-Glucoside Crosspolymer,Bis-Hydroxyethylglycinate Lauryl-glucoside Crosspolymer Sodium, Boramide Propyl PG-Dimonium Chloride Phosphate Sodium, Butoxynol-12 Sulfate Sodium, Butyl Glucoside Hydroxypropyl Phosphate Sodium, C13-17 Alkanesulfonate Sodium, C14-18 Alkanesulfonate Sodium, C12-15 Alkoxypropyliminodipropionate Sodium, C10-16 Alkyl Sulfate Sodium, C11-15 Alkyl Sulfate Sodium, C12-13 Alkyl Sulfate Sodium, C12-15 Sodium Alkyl Sulfate, Sodium C12-18 Alkyl Sulfate, Sodium C16-20 Alkyl Sulfate, Sodium C9-22 Alkyl Sec Sulfonate, Sodium C14-17 Alkyl Sec Sulfonate, Sodium Caprate, Sodium Caproamphoacetate, Sodium Caproamphohydroxypropylsulfonate, Sodium Caproamphopropionate, Sodium Caproyl Methyl Taurate, Sodium Caprylate, Sodium Capryleth-2 Carboxylate, Sodium Capryleth-9 Carboxylate, Sodium Capryloamphoacetate, Caprylic Acid Sodium loamphohydroxypropylsulfonate, Sodium capryloamphopropionate, Sodium capryloyl glutamate, Sodium capryloyl hydrolyzed wheat protein, Sodium caprylyl PG-sulfonate, Sodium caprylyl sulfonate, Sodium castorate, Sodium ceteareth-13 carboxylate, Sodium cetearyl sulfate, Sodium ceteth-13 carboxylate, Sodium cetyl sulfate, Sodium cocamidopropyl PG-dimonium chloride phosphate, Sodium cocaminopropionate, Sodium coceth sulfate, Sodium coceth sulfate, Sodium Seth-30 Sulfate, Sodium Cocoa Butter Amphoacetate, Sodium Cocoa Butterate, Sodium Cocoamphoacetate, Sodium Cocoamphohydroxypropylsulfonate, Sodium Cocoamphopropionate, Sodium Cocoate, Sodium Coco / Babassu / Andiloba Sulfate, Sodium Coco / Babassu Sulfate, Sodium Coco-Glucoside Hydroxypropyl Phosphate, Sodium Coco-Glucoside Hydroxypropyl Sulfonate, Sodium Coco-Glucoside Tartrate, Sodium Coco-Glyceryl Ether Sulfonate, Sodium Coco / Hydrogenated Scutellaria Baicalensis Sulfate,Sodium Cocoiminodiacetate, Sodium Coco Monoglyceride Sulfate, Sodium Coco Monoglyceride Sulfonate, Sodium Coco PG Dimonium Phosphate Chloride, Sodium Coco Sulfate, Sodium Coco Sulfoacetate, Sodium Cocoyl Alanine, Sodium Cocoyl Amino Acids, Sodium Cocoyl Collagen Amino Acids, Sodium Cocoyl Glutamate, Sodium Cocoyl Glutamate, Sodium Cocoyl Glycinate, Sodium Cocoyl / Hydrogenated Beef Tallow Glutamate, Sodium Cocoyl Hydrolyzed Collagen, Sodium Cocoyl Hydrolyzed Keratin, Sodium Cocoyl Hydrolyzed Rice Protein, Sodium Cocoyl Hydrolyzed Silk, Sodium Cocoyl Hydrolyzed Soy Protein, Sodium Cocoyl Hydrolyzed Sweet Almond Protein, Sodium Cocoyl Hydrolyzed Wheat Protein, Sodium Cocoyl Hydrolyzed Wheat Protein Glutamate, Sodium Cocoyl Isethionate, Sodium Cocoyl Methylaminopropionate, Sodium Cocoyl Oat Amino Acids, Sodium Cocoyl / Palmoyl / Sunflower Oil Glutamate, Sodium Cocoyl Proline, Sodium Cocoyl Sarcosinate , Sodium Cocoyl Taurate, Sodium Cocoyl Threonine Acid, Sodium Cocoyl Wheat Amino Acid, Sodium C12-14 Olefin Sulfonate, Sodium C14-16 Olefin Sulfonate, Sodium C14-18 Olefin Sulfonate, Sodium C16-18 Olefin Sulfonate, Sodium Conanphopropionate, Sodium Cottonseed Amphoacetate, Sodium C13-15 Pareth-8 Butyl Phosphate, Sodium C9-11 Pareth-6 Carboxylate, Sodium C11-15 Pareth-7 Carboxylate, Sodium C12-13 Pareth-5 Carbo Sodium phosphate, C12-13 Pareth-8 carboxylate, C12-13 Pareth-12 carboxylate, C12-15 Pareth-6 carboxylate, C12-15 Pareth-7 carboxylate, C12-15 Pareth-8 carboxylate, C14-15 Pareth-8 carboxylate, C12-14Sec-Pareth-8 carboxylate, C14-15 Pareth-PG sulfonate, C12-13 Pareth-2 sodium phosphate, C13-15 Pareth-8 sodium phosphate, C9-15 Pareth-3 sodium sulfate,C10-15 Pareth-2 Sodium Sulfate, C10-16 Pareth-2 Sodium Sulfate, C12-13 Pareth-2 Sodium Sulfate, C12-15 Pareth-3 Sodium Sulfate, C12-15 Pareth-3 Sodium Sulfate, C13-15 Pareth-3 Sodium Sulfate, C12-14Sec-Pareth-3 Sodium Sulfate, C12-15 Pareth-3 Sodium Sulfonate, C12-15 Pareth-7 Sodium Sulfonate, C12-15 Pareth-15 Sodium Sulfonate, Deceth-2 Sodium Carboxylate, Deceth Sulfate, Decyl Benzene Sulfonate, Decyl Glu Sodium cocoside hydroxypropyl phosphate, sodium decyl glucoside hydroxypropyl sulfonate, sodium dilaureth-7 citrate, sodium dilaureth-10 phosphate, sodium dilinoleate, sodium dilinoleate, sodium dioleate-8 phosphate, sodium dodecylbenzenesulfonate, sodium ethyl 2-sulfolaurate, sodium oleate glyceryl phosphate, grapeseed amidopropyl PG-dimonium chloride phosphate, grapeseed sodium amphoacetate thorium, sodium grapeseed acid, sodium hempseed amphoacetate, sodium hexeth-4 carboxylate, sodium hydrogenated cocoate, sodium hydrogenated cocoyl methyl isethionate, sodium hydrogenated palmitate, sodium hydrogenated tallowate, sodium hydrogenated tallowate, sodium hydrogenated tallowate, sodium hydrogenated tallowate, sodium hydroxylauryldimonium ethyl phosphate, sodium hydroxypropyl palm kernel acid sulfonate, hydroxypropyl phosphate decyl glucoside crosspolymer, sodium hydroxypropyl phosphate lauryl glucoside crosspolymer, sodium hydroxypropyl sulfonate coco glucoside crosspolymer, sodium hydroxypropyl sulfonate decyl glucoside crosspolymer, sodium hydroxypropyl sulfonate lauryl glucoside crosspolymer, sodium hydroxystearate, sodium isostearate, sodium isosteareth-6 carboxylate, sodium isosteareth-11 carboxylate, sodium isostearoamphoacetate, sodium isostearoamphopropionate, sodium N-isostearoyl methyl taurate, sodium ranesulfate,Sodium lanolate, sodium laurate, sodium lauramide diacetate, sodium lauraminopropionate, sodium laurate, sodium laureth-3 carboxylate, sodium laureth-4 carboxylate, sodium laureth-5 carboxylate, sodium laureth-6 carboxylate, sodium laureth-8 carboxylate, sodium laureth-11 carboxylate, sodium laureth-12 carboxylate, sodium laureth-13 carboxylate, sodium laureth-14 carboxylate, sodium laureth-16 carboxylate, sodium laureth-17 carboxylate, sodium laureth sulfate, sodium laureth-5 sulfate, sodium laureth-7 sulfate, sodium laureth-8 sulfate, sodium laureth-12 sulfate, sodium laureth-40 sulfate, sodium laureth-7 tartrate, sodium laurominodipropionate, sodium lauroamphoacetate, sodium lauroamphohydroxypropylsulfonate, sodium lauroamphoPG-acetate phosphate, sodium lauroamphopropionate, sodium lauroyl aspartate, sodium lauroyl collagen amino acid, sodium lauroyl glycine Sodium ampropionate, sodium lauroyl hydrolyzed collagen, sodium lauroyl hydrolyzed silk, sodium lauroyl hydroxypropyl sulfonate, sodium lauroyl isethionate, sodium lauroyl methylaminopropionate, sodium lauroyl methyl isethionate, sodium lauroyl millet amino acid, sodium lauroyl / myristoyl aspartate, sodium lauroyl oat amino acid, sodium lauroyl sarcosinate, sodium lauroyl silk amino acid, sodium lauroyl taurate, sodium lauroyl wheat amino acid, sodium lauryl diethylenediaminoglycinate, sodium lauryl glucose carboxylate, sodium lauryl glucoside hydroxypropyl phosphate, sodium lauryl glucoside hydroxypropyl sulfonate, sodium lauryl glycol carboxylate, sodium lauryl hydroxyacetamide sulfate, sodium lauryl phosphate, sodium lauryl sulfate, sodium lauryl sulfoacetate, sodium linoleate, sodium macadamiase acetate, sodium mango amphoacetate, sodium mangosteenate,MEA Sodium Laureth-2 Sulfosuccinate, Sodium Methoxy PPG-2 Acetate, Sodium Methyl Cocoyl Taurate, Sodium Methyl Lauroyl Taurate, Sodium Methyl Myristoyl Taurate, Sodium Methyl Oleyl Taurate, Sodium Methyl Palmitoyl Taurate, Sodium Methyl Stearoyl Taurate, Sodium Methyl 2-Sulfolaurate, Sodium methyl 2-sulfopalmitate, sodium methyl taurate isopalmitate, sodium methyl taurate cocoyl methyl taurate, sodium myristate, sodium myristamphoacetate, sodium myristoyl glutamate, sodium myristoyl hydrolyzed collagen, sodium myristoyl isethionate, sodium myristoyl sarcosinate, sodium myristyl sulfate, sodium nonoxynol-6 phosphate, sodium nonoxynol-9 phosphate, sodium nonoxynol-1 sulfate, sodium nonoxynol-3 sulfate , Sodium nonoxynol-4 sulfate, Sodium nonoxynol-6 sulfate, Sodium nonoxynol-8 sulfate, Sodium nonoxynol-10 sulfate, Sodium nonoxynol-25 sulfate, Sodium octoxynol-2 ethanesulfonate, Sodium octoxynol-2 sulfate, Sodium octoxynol-6 sulfate, Sodium octoxynol-9 sulfate, Sodium oleate, Sodium oleoamphoacetate, Sodium oleoamphohydroxypropylsulfonate, Sodium oleoamphopropionate, Sodium oleoyl hydrolyzed collagen Sodium, Sodium Oleoyl Isethionate, Sodium Oleate Sulfate, Sodium Oleyl Methyl Isethionate, Sodium Oleyl Sulfate, Sodium Olivanfoacetate, Sodium Olivine, Sodium Olivoyl Glutamate, Sodium Palmofoacetate, Sodium Palmitate, Sodium Palmglyceride Sulfonate, Sodium Palmitate, Sodium Palmitoyl Hydrolyzed Collagen, Sodium Palmitoyl Hydrolyzed Wheat Protein, Sodium Palmitoyl Sarcosinate, Sodium Palm Nucleic Acid, Sodium Palm Nucleic Acid Isethionate , Sodium Palmoyl Glutamate, Sodium Passiflora Edulis Seed Acid, Sodium Peanut Amphoate, Sodium Peanut Acid, Sodium PEG-6 Cocamide Carboxylate, Sodium PEG-8 Cocamide Carboxylate, Sodium PEG-4 Cocamide Sulfate, Sodium PEG-3 Lauramide Carboxylate, Sodium PEG-4 Lauramide Carboxylate, Sodium PEG-8 Palm Glyceride Carboxylate, Sodium Pentaerythrityl Hydroxypropylminodiacetate Dendrimer, Sodium Propoxy PPG-2 Acetate,Sodium rapeseed, sodium ricinoleate, sodium ricinoleate, sodium ricinoleate, sodium rosehip amphoacetate, sodium rosinate, sodium safflowerate, sodium saffloweryl hydrolyzed soy protein, sodium sesaminate, sodium sesamate, sodium shea butter amphoacetate, sodium soy acid, sodium soy hydrolyzed collagen, sodium stearate, sodium stearoyl amphoacetate, sodium stearoyl hydroxypropyl sulfonate, sodium stearoyl hydroxypropyl ... Sodium propionate, sodium stearoyl caseinate, sodium stearoyl glutamate, sodium stearoyl hyaluronate, sodium stearoyl hydrolyzed collagen, sodium stearoyl hydrolyzed corn protein, sodium stearoyl hydrolyzed silk, sodium stearoyl hydrolyzed soy protein, sodium stearoyl hydrolyzed wheat protein, sodium stearoyl lactate, sodium stearoyl methyl isethionate, sodium stearoyl oat protein, sodium stearoyl pea protein , Sodium Stearoyl Soy Protein, Sodium Stearyl Dimethylglycine Sodium Stearyl Sulfate, Sunflower Seed Sodium Amphoacetate, Sodium Surfactin, Sodium Sweet Almond Amphoacetate, Sodium Sweet Almondate, Sodium Talanphopropionate, Sodium Taurate, Sodium Tallow Amphoacetate, Sodium Tallowate, Sodium Tallow Sulfate, Sodium Tamanusade, Sodium Taurate, Sodium Methyl Cocoyl Taurate, Sodium Laurate Taurate, Sodium Lauroyl Collagen Amino Acids / TEA, Sodium Lauroyl Hydrolyzed Collagen / TEA, Sodium Lauroyl Hydrolyzed Keratin / TEA, Sodium Lauroyl Keratin Amino Acids / TEA, Sodium Undecylenoyl Collagen Amino Acids / TEA, Sodium Undecylenoyl Hydrolyzed Collagen / TEA, Sodium Undecylenoyl Hydrolyzed Corn Protein / TEA, Sodium Undecylenoyl Hydrolyzed Soy Protein / TEA, Sodium Undecylenoyl Hydrolyzed Wheat Protein / TEA, Sodium Theobroma Grandiflorum Seed Oil,Sodium trideceth-3 carboxylate, sodium trideceth-4 carboxylate, sodium trideceth-6 carboxylate, sodium trideceth-7 carboxylate, sodium trideceth-8 carboxylate, sodium trideceth-12 carboxylate, sodium trideceth-15 carboxylate, sodium trideceth-19 carboxylate, sodium trideceth sulfate, sodium tridecylbenzenesulfonate, sodium tridecyl sulfate, sodium trimethylolpropane hydroxypropylminodiacetate dendrimer, sodium undeceth-5 carboxylate Sodium, Sodium Undecylenate, Sodium Undecylenoamphoacetate, Sodium Undecylenoamphopropionate, Sodium Undecylenoyl Glutamate, Sodium Wheat Germ Amphoacetate, Sorbeth-160 Tristearate, Soy Acid, Soyamidopropylamine Oxide, Soyamidopropyl Betaine, Soybean Oil Glycereth-8 Ester, Stearamidopropylamine Oxide, Stearamidopropyl Betaine, Stearamine Oxide, Steareth-15, Steareth-16, Steareth-20, Steareth-21, Steareth-25, Steareth Steareth-27, Steareth-30, Steareth-40, Steareth-50, Steareth-80, Steareth-100, Steareth-2 Phosphate, Steareth-3 Phosphate, Stearic Acid, Stearoxypropyltrimonium Chloride, Stearoyl Glutamic Acid, Stearoyl Sarcosine, Stearyl Betaine, Stearyldimonium Hydroxypropyl Butyl Glucoside Chloride, Stearyldimonium Hydroxypropyl Decyl Glucoside Chloride, Stearyldimonium Hydroxypropyl Lauryl Glucoside Chloride, Castor Oil Sulfate, Coconut Sulfate Ingredients: tallow oil, glyceryl oleate sulfate, olive oil sulfate, peanut oil sulfate, sunflower amide MEA, sunflower seed acid, sunflower seed amidopropyl hydroxyethyl dimonium chloride, sunflower seed oil glycereth-8 ester, tall oil acid, tallow acid, tallow amidopropyl amine oxide, tallow amidopropyl betaine, tallow amidopropyl hydroxysultaine, tallow amine oxide, tallow betaine, tallow dihydroxyethyl betaine, tallow ethyl glucoside, TEA-abietyl hydrolyzed collagen, TEA-C12-14 alkyl phosphate,TEA-C10-15 alkyl sulfate, TEA-C11-15 alkyl sulfate, TEA-C12-13 alkyl sulfate, TEA-C12-14 alkyl sulfate, TEA-C12-15 alkyl sulfate, TEA C14-17 alkyl secondary sulfonate, TEA-canolate, TEA-cocamide diacetate, TEA-cocoate, TEA-cocosulfate, TEA-cocoyl alaninate, TEA-cocoyl glutamate, TEA-cocoyl glutamate, TEA-cocoyl glycinate, TEA-cocoyl hydrolyzed collagen, TEA-cocoyl hydrolyzed soy protein, TEA-cocoyl sarcosinate, dimethicone PEG-7 phosphate TEA-dodecylbenzenesulfonate, hydrogenated TEA-cocoate, water TEA-added taloyl glutamate, TEA-rostearate, TEA-rostearoyl hydrolyzed collagen, TEA-lauraminopropionate, TEA-laurate, TEA-lauric acid / myristic acid, TEA-laureth sulfate, TEA-lauroyl collagen amino acid salt, TEA-lauroyl glutamate, TEA-lauroyl hydrolyzed collagen, TEA-lauroyl keratin amino acid salt, TEA-lauroyl methylaminopropionate, TEA-lauroyl / myristoyl aspartate, TEA-lauroyl TEA-yl sarcosinate, TEA-lauryl phosphate, TEA-lauryl sulfate, TEA-myristyl aminopropionate, TEA-myristate, TEA-myristoyl hydrolyzed collagen, TEA-oleate, TEA-oleyl hydrolyzed collagen, TEA-oleyl sarcosinate, TEA-oleyl sulfate, TEA-palmitate, TEA-palm kernel sarcosinate, TEA-PEG-3 cocamide sulfate, EA-rosinate, TEA-stearate, TEA-talate, TEA-tridecyl sulfate Silbenzenesulfonate, TEA-undecylenate, TEA-undecylenoyl hydrolyzed collagen, tetramethyldecynediol, tetrasodium dicarboxyethylstearyl sulfosuccinate, TIPA-laureth sulfate, TIPA-lauryl sulfate, TIPA-myristate, TIPA-stearate, tocopheryl phosphate, trehalose undecylenoate, TM-C12-15 pareth-2 phosphate, TM-C12-15 pareth-6 phosphate, TM-C12-15 pareth-8 phosphate,TM-C12-15 Pareth-10 Phosphate, Trideceth-20, Trideceth-50, Trideceth-3 Carboxylic Acid, Trideceth-4 Carboxylic Acid, Trideceth-7 Carboxylic Acid, Trideceth-8 Carboxylic Acid, Trideceth-15 Carboxylic Acid, Trideceth-19 Carboxylic Acid, Trideceth-10 Phosphate, Tridecylbenzene Sulfonic Acid, Trilaureth-9 Citrate, Trimethylolpropane Hydroxypropyl Bishydroxyethylamine Dendrimer, Lauroampho PG-Acetate Chloride Trisodium Phosphate Ingredients include: Undecanoic Acid, Undeceth-5 Carboxylic Acid, Undecylamidopropylamine Oxide, Undecylamidopropyl Betaine, Undecylenic Acid, Undecylenoyl Collagen Amino Acid, Undecylenoyl Glycine, Undecylenoyl Hydrolyzed Collagen, Undecylenoyl Wheat Amino Acid, Undecyl Glucoside, Wheat Germ Acid, Wheat Germ Amidopropylamine Oxide, Wheat Germ Amidopropyl Betaine, Yucca Schidigera Leaf / Root / Stem Extract, Yucca Schidigera Stem Extract, Zinc Coceth Sulfate and Zinc Coco Sulfate.

[0085] <Nonionic surfactant> Alcohol alkoxylates. The nonionic surfactants added are preferably alkoxylated and / or propoxylated, particularly preferably primary alcohols having 8 to 18 carbon atoms and with an average of 1 to 12 moles of ethylene oxide (EO) and / or 1 to 10 moles of propylene oxide (PO) per mole of alcohol. Particularly preferred are C8-C16-alcohol alkoxylates, advantageously ethoxylated and / or propoxylated C10-C15-alcohol alkoxylates, in particular C12-C14 alcohol alkoxylates, with a degree of ethoxylation of 2 to 10, preferably 3 to 8, and / or a degree of propoxylation of 1 to 6, preferably 1.5 to 5. The quoted degrees of ethoxylation and propoxylation constitute statistical average values ​​and may be integers or fractions for a particular product. Preferred alcohol ethoxylates and propoxylates have a narrow homolog distribution (narrow range ethoxylates / propoxylates, NRE / NRP). In addition to these nonionic surfactants, fatty alcohols with an EO greater than 12 can also be used. Examples of these include (tallow) fatty alcohols with 14EO, 16EO, 20EO, 25EO, 30EO, or 40EO.

[0086] Alkyl glycosides (APG™). Furthermore, as additional nonionic surfactants, alkyl glycosides satisfying the general formula RO(G)x can be added, for example, in particular as compounds with anionic surfactants, where R represents a primary linear or methyl-branched, in particular 2-methyl-branched, aliphatic group containing 8 to 22, preferably 12 to 18, carbon atoms, and G represents a glycose unit containing 5 or 6 carbon atoms, preferably glucose. The degree of oligomerization x, which defines the distribution of monoglycosides and oligoglycosides, can be any number between 1 and 10, preferably between 1.1 and 1.4.

[0087] Fatty acid ester alkoxylates. Another class of preferred nonionic surfactants, used as the sole nonionic surfactant or in combination with other nonionic surfactants, especially with alkoxylated fatty alcohols and / or alkyl glycosides, are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably containing 1 to 4 carbon atoms in the alkyl chain, more particularly fatty acid methyl esters, for example, as described in JP-A-58-217598 or preferably prepared by the process described in International Patent Application WO 90 / 13533A. Particularly preferred are methyl esters of C12 to C18 fatty acids containing an average of 3 to 15 EOs, especially an average of 5 to 12 EOs.

[0088] Amine oxides. Nonionic surfactants of the amine oxide type, such as N-cocoalkyl-N,N-dimethylamine oxide, N-tallowalkyl-N,N-dihydroxyethylamine oxide, fatty acid alkanolamides, can also be suitably used. The amount of these nonionic surfactants used is preferably equal to or less than the amount of the ethoxylated fatty alcohols used, in particular equal to or less than half of that amount.

[0089] Gemini surfactants. The so-called gemini surfactants can be considered as further surfactants. In general, such compounds are understood to mean compounds with two hydrophilic and two hydrophobic groups per molecule. As a rule, these groups are separated from each other by a "spacer". The spacer is usually a hydrocarbon chain and is intended to be of sufficient length such that the hydrophilic groups are separated by a sufficient distance to act independently of each other. Surfactants of this type are generally characterized by an unusually low critical micelle concentration and the ability to strongly reduce the surface tension of water. Exceptionally, however, not only dimeric but also trimeric surfactants are meant by the term gemini surfactants. Suitable gemini surfactants are, for example, sulfated hydroxy mixed ethers according to DE 4321022 A1 or dimeric alcohol bis- and trimer alcohol tris sulfates and ether sulfates according to WO 96 / 23768 A1. Block end group dimeric and trimeric mixed ethers according to DE 19513391 A1 are particularly characterized by bi- and polyfunctionality. Gemini polyhydroxy fatty acid amides or polyhydroxy fatty acid amides, such as those described in WO 95 / 19953 A1, WO 95 / 19954 A1 and WO 95 / 19955 A1, may also be used.

[0090] <Cationic surfactant> Tetraalkylammonium salts. Cationic active surfactants consist of hydrophobic polymeric groups necessary for cationic surface activity by dissociation in aqueous solution. An important representative group of cationic surfactants are tetraalkylammonium salts of the general formula: (R1R2R3R4N+)X-, where R1 represents a C1 to C8 alkyl(enyl) group, and R2, R3 and R4, independently of each other, represent alkyl(enyl) radicals having 1 to 22 carbon atoms. X is a counterion, preferably selected from the group of halides, alkyl sulfates and alkyl carbonates. Particularly preferred are cationic surfactants in which the nitrogen group is substituted with two long acyl groups and two short alkyl(enyl) groups.

[0091] Esterquat. A further class of cationic surfactants particularly useful as co-surfactant for the present invention is represented by so-called ester quats. Ester quats are generally understood to be quaternized fatty acid triethanolamine ester salts. These are known compounds that can be obtained by the relevant methods of preparative organic chemistry. In this connection, reference is made to WO91 / 01295A1, according to which triethanolamine is partially esterified with fatty acid in the presence of hypophosphorous acid, air is passed through the reaction mixture, and then the whole is quaternized with dimethyl sulfate or ethylene oxide. Furthermore, DE4308794C1 describes a method for preparing solid ester quats, in which the quaternization of triethanolamine esters is carried out in the presence of a suitable dispersant, preferably a fatty alcohol.

[0092] Typical examples of ester quats suitable for use according to the invention are products whose acyl component is derived from a monocarboxylic acid corresponding to the formula RCOOH, where RCO is an acyl group containing 6 to 10 carbon atoms, and whose amine component is triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid and technical mixtures thereof, such as, for example, the so-called head fraction fatty acids. Ester quats whose acyl component is derived from a monocarboxylic acid containing 8 to 10 carbon atoms are preferably used. Other ester quats are those whose acyl component is derived from a dicarboxylic acid such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and / or dodecanedioic acid, but preferably adipic acid. Overall, ester quats whose acyl component is derived from a mixture of a monocarboxylic acid containing 6 to 22 carbon atoms and adipic acid are preferably used. The molar ratio of mono- and dicarboxylic acids in the final ester quat may range from 1:99 to 99:1, preferably from 50:50 to 90:10, more particularly from 70:30 to 80:20. Besides the quaternized fatty acid triethanolamine ester salts, other suitable ester quats are the quaternized ester salts of mono- / dicarboxylic acid mixtures with diethanolalkylamines or 1,2-dihydroxypropyldialkylamines. Ester quats can be obtained both from fatty acids and from the corresponding triglycerides mixed with the corresponding dicarboxylic acids. As representative of the relevant prior art, European patent EP 0750606B1 proposes such a preparation. To prepare the quaternized esters, mixtures of mono- and dicarboxylic acids with triethanolamine (based on available carboxyl functional groups) can be used in a molar ratio of 1.1:1 to 3:1. Taking into account the performance properties of the ester quats, ratios of 1.2:1 to 2.2:1, preferably 1.5:1 to 1.9:1, have proven to be particularly advantageous. Preferred ester quats are technical mixtures of mono-, di- and triesters with an average degree of esterification of 1.5 to 1.9.

[0093] <Amphoteric surfactant> Betaines. Amphoteric or ampholytic surfactants have multiple functional groups that can be ionized in aqueous solution, thereby endowing the compound with anionic or cationic properties, depending on the conditions of the medium (see DIN 53900, July 1972). Near the isoelectric point (around pH 4), amphoteric surfactants form inner salts and become poorly soluble or insoluble in water. Amphoteric surfactants are divided into amphoteric ions and betaines, the latter being present as zwitterions in solution. Ampholytes are compounds that have both acidic and basic hydrophilic groups and behave as acids or bases depending on the conditions. Betaines in particular are known surfactants, mainly prepared by carboxyalkylation, preferably carboxymethylation, of amine compounds. The starting material is preferably condensed with a halocarboxylic acid or its salt, in particular sodium chloroacetate, to form one mole of salt per mole of betaine. The addition of unsaturated carboxylic acids, such as acrylic acid, is also possible. Examples of suitable betaines are the carboxyalkylation products of secondary amines, especially tertiary amines, corresponding to the formula R1R2R3N-(CH2)qCOOX, where R1 is an alkyl radical having 6 to 22 carbon atoms, R2 is hydrogen or an alkyl group containing 1 to 4 carbon atoms, R3 is an alkyl group containing 1 to 4 carbon atoms, q is a number from 1 to 6 and X is an alkali metal and / or alkaline earth metal or ammonium. Representative examples include the carboxymethylation products of hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, C12 / 14-cocoalkyldimethylamine, myristyldimethylamine, cetyldimethylamine, stearyldimethylamine, stearylethylmethylamine, oleyldimethylamine, C16 / 18-taloalkyldimethylamine and technical mixtures thereof, especially dodecylmethylamine, dodecyldimethylamine, dodecylethylmethylamine and technical mixtures thereof.

[0094] Alkylamidobetaine. Other suitable betaines are the carboxyalkylation products of amidoamines corresponding to the formula R1CO(R3)(R4)-NH-(CH2)PN-(CH2)QCOOX, where R1CO is an aliphatic acyl radical having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds, R2 is hydrogen or an alkyl radical having 1 to 4 carbon atoms, R3 is an alkyl radical having 1 to 4 carbon atoms, P is a number from 1 to 6, Q is a number from 1 to 3 and X is an alkali metal and / or alkaline earth metal or ammonium. Typical examples are the reaction products of fatty acids having 6 to 22 carbon atoms, such as caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, elaeostearic acid, arachidonic acid, gadoleic acid, behenic acid, erucic acid and technical mixtures thereof with N,N-dimethylaminoethylamine, N,N-dimethylaminopropylamine, N,N-diethylaminoethylamine and N,N-diethylaminopropylamine, which are condensed with sodium chloroacetate. Commercially available products include Dehyton® K and Dehyton® PK (Cognis Deutschland GmbH & Co.KG), Tego® Betaine (Goldschmidt), etc.

[0095] Imidazolines. Other suitable starting materials for the betaines used for the purposes of the present invention are imidazolines. These materials are also known and can be obtained, for example, by cyclocondensation of one or two moles of C6-C22 fatty acids with polyfunctional amines, such as aminoethylethanolamine (AEEA) or diethylenetriamine. The corresponding carboxyalkylation products are mixtures of different open-chain betaines. Typical examples are the condensation products of the above fatty acids with AEEA, preferably imidazolines based on lauric acid, which are then betained with sodium chloroacetate. Commercially available products include DEHYTON® G (Cognis Deutschland GmbH & Co.).

[0096] The amount of (co)surfactant(s) comprised in the composition according to the invention is advantageously from 0.1% to 90% by weight, in particular from 10% to 80% by weight and particularly preferably from 20% to 70% by weight.

[0097] <Organic solvent> The liquid light or heavy duty detergents may contain organic solvents, preferably those miscible with water. Polydiols, ethers, alcohols, ketones, amides and / or esters are preferably used as organic solvents for this purpose in amounts of 0.1 to 90% by weight, preferably 0.1 to 70% by weight, in particular 0.1 to 60% by weight. Low molecular weight polar substances such as, for example, methanol, ethanol, propylene carbonate, acetone, acetonylacetone, diacetone alcohol, ethyl acetate, 2-propanol, ethylene glycol, propylene glycol, glycerin, diethylene glycol, dipropylene glycol monomethyl ether and dimethylformamide or mixtures thereof are preferred.

[0098] <Enzyme> Cellulase enzyme. The cellulase enzymes optionally used in the detergent compositions of the present invention, when present, are incorporated at a level sufficient to provide up to about 5 mg by weight, more preferably from about 0.01 mg to about 3 mg of active enzyme per gram of composition. Unless otherwise specified, the compositions herein preferably contain from about 0.001% to about 5%, more preferably from 0.01% to 1% by weight of a commercial enzyme preparation.

[0099] Suitable cellulases for the present invention include bacterial or fungal cellulases. Preferably, their optimum pH is between 5 and 9.5. Suitable cellulases are fungal cellulases produced from Humicola Insolens and Humicola strain DSM1800, or cellulase 212 producing fungi belonging to the genus Aeromonas, and cellulases extracted from the hepatopancreas of marine mollusc Dolabella Auricula Solander, suitable cellulases are also disclosed in GB 2,075,028 A. Furthermore, cellulases particularly suitable for use in the present invention are disclosed in WO 1992 / 013057 A1. Most preferably, the cellulases used in the detergent compositions of the present invention are commercially available from NOVO Industries A / S under the product names CAREZYMEO and CELLUZYMEO.

[0100] Other enzymes Additional enzymes can be included in the detergent compositions herein for a wide variety of fabric washing purposes, including, for example, removal of protein-based, carbohydrate-based, or triglyceride-based stains, and prevention of refugee dye transfer, and fabric repair. Additional enzymes incorporated include proteases, amylases, lipases, peroxidases, and mixtures thereof. Other types of enzymes can also be included. These enzymes can be of any type, such as vegetable, animal, bacterial, fungal, yeast, etc. However, their selection is governed by several factors, such as optimum values ​​of pH activity and / or stability, heat resistance, stability to active detergents, builders, and the potential to cause malodor during use. In this regard, bacterial or fungal enzymes, such as bacterial amylases and proteases, are preferred.

[0101] Enzymes are typically incorporated at levels sufficient to provide up to about 5 mg by weight, more typically about 0.01 mg to about 3 mg of active enzyme per gram of composition. In other words, the compositions herein typically contain about 0.001% to about 5% by weight, preferably 0.01% to 1% by weight, of a commercial enzyme preparation. Protease enzymes are typically present in such commercial preparations at levels sufficient to provide 0.005 to 0.1 Anson Units (AU) of activity per gram of composition.

[0102] Suitable examples of proteases include subtilisins obtained from certain strains of B. Subtilis and B. Licheniforms. Another suitable protease is obtained from a Bacillus strain with maximum activity in the pH range of 8 to 12, developed and sold by Novo Industries A / S under the registered trademark ESPERASE. Preparations of this enzyme and similar enzymes are described in Novo's GB 1,243,784. Commercially available proteolytic enzymes suitable for removing protein-based soils include those sold by Novo Industries A / S under the names ALCALASE and SAVINASE, and by International Bio-Synthetics, INC. under the trade name MAXATASE. Other proteases include protease A; protease B, and the proteases manufactured by Genencor International, Inc. according to US 5,204,015 and US 5,244,791.

[0103] Examples of amylases include α-amylases such as RAPIDASE (trademark) (manufactured by International Bio-Synthetics, Inc.) and TERMAMYL (trademark) (manufactured by Novo Industries).

[0104] Suitable lipase enzymes for detergent applications include those produced by Pseudomonas microorganisms, such as Pseudomonas Stutzeri ATCC 19154. This lipase is available under the trade name Lipase P"AMANO" from Amano Pharmaceutical Co., Ltd. Other commercially available lipases include Amano-CES, lipases from Chromobacter Viscosum, such as Chromobacter Viscosum Var. Lipolyticum NRRLB 3673 available from Toyo Jozo Co., CHROMOBACTER VISCOSUM lipases from US Biochemical Corp. and Disoynth Co., and lipases from Pseudomonas gladioli. The LIPOLASE™ enzyme from HUMICOLA LANUGINOSA (available from Novo Industries A / S) is a preferred lipase for use in the present invention.

[0105] Peroxidase enzymes are used in combination with an oxygen source, such as percarbonate, perborate, persulfate, hydrogen peroxide, etc. Peroxidase enzymes are used for "solution bleaching", i.e., to prevent dyes or pigments removed from a substrate during a washing operation from transferring to other substrates in the wash solution. Peroxidase enzymes are known in the art and include, for example, horseradish peroxidase, ligninase, and haloperoxidases, such as chloroperoxidase and bromoperoxidase. Peroxidase-containing detergent compositions are disclosed, for example, in WO 1989 / 099813 A1.

[0106] Enzyme stabilizer. The enzymes used herein are stabilized by the presence of a water-soluble source of calcium and / or magnesium ions in the finished detergent composition to provide such ions to the enzyme. (Calcium ions are generally somewhat more effective than magnesium ions and are preferred herein when only one type of cation is used). Further stability can be provided by the presence of various other art-disclosed stabilizers, particularly borates (see US 4,537,706, which is incorporated herein in its entirety). Typical detergent compositions, especially liquids, contain about 1 to about 30 millimoles of calcium ions per liter of finished composition, preferably about 2 to about 20 millimoles, more preferably about 5 to about 15 millimoles, and most preferably about 8 to about 12 millimoles. In solid detergent compositions, the product can contain a water-soluble calcium ion source in an amount sufficient to provide such amounts in the wash liquor. Alternatively, natural water hardness is sufficient.

[0107] It is understood that the above calcium ion and / or magnesium ion level is sufficient to provide enzyme stability.Addition of calcium ion and / or magnesium ion to the composition can further enhance grease removal performance.Therefore, as a general proposition, the composition herein typically comprises about 0.05% to about 2% by weight of a water-soluble source of calcium ion or magnesium ion, or both.Of course, the amount may vary depending on the amount and type of enzyme used in the composition.

[0108] The compositions herein may optionally, but preferably, contain various additional stabilizers, particularly borate-type stabilizers. Typically, such stabilizers are used in the composition in an amount of about 0.25% to about 10%, preferably about 0.5% to about 5%, more preferably about 0.75% to about 3% by weight of boric acid or other borate compounds capable of forming boric acid in the composition (calculated on a boric acid basis). Boric acid is preferred, but other compounds such as boric oxide, borax, and other alkali metal borates (e.g., orthoboric acid, metaboric acid, sodium pyroborate, and sodium pentaborate) are also suitable. Substituted boric acids (e.g., phenylboronic acid, butaneboronic acid, and P-bromophenylboronic acid) may also be used in place of boric acid.

[0109] <Builder> Zeolite. Finely crystalline synthetic zeolites containing bound water can be used as builders, for example zeolites A and / or P being preferred. Zeolite P is particularly preferably zeolite MAP.RTM. (commercially available from Crosfield). However, zeolites X and mixtures of A, X, Y and / or P are also suitable. Sodium / potassium aluminium silicate co-crystallised from zeolite A and zeolite X (available as Vegobond® RX. (commercially available from Condea Augusta SpA)) is also of particular interest. The zeolites can preferably be used as spray-dried powders. If the zeolites are added as suspensions, they can contain small amounts of non-ionic surfactants as stabilisers, for example 1 to 3% by weight. Based on the zeolite, 10 to 20% by weight of ethoxylated C12-C18 fatty alcohols with 2 to 5 ethylene oxide groups, C12-C14 fatty alcohols with 4 to 5 ethylene oxide groups or ethoxylated isotridecanol are included. Suitable zeolites have an average particle size of less than 10 μm (test method: volume distribution Coulter Counter) and preferably contain 18 to 22% by weight, in particular 20 to 22% by weight, of bound water. Alternatively, phosphates can also be used as builders.

[0110] Layered silicate. A suitable substitute or partial substitute for phosphates and zeolites is crystalline sodium layered silicate. These types of crystalline layered silicates are described, for example, in EP 0 164 514 A1. Preferred crystalline layered silicates are those obtained, for example, from the process described in WO 91 / 08171 A1.

[0111] Amorphous silicates. Preferred builders also include amorphous sodium silicates with a modulus (Na2O:SiO2 ratio) of 1:2 to 1:3.3, preferably 1:2 to 1:2.8, and even more preferably 1:2 to 1:2.6, which show slow dissolution and multiple wash cycle properties. The slow dissolution compared to conventional amorphous sodium silicates can be achieved in various ways, such as surface treatment, compounding, compaction / compression, or overdrying. In the context of the present invention, the term "amorphous" also means "X-ray amorphous". In other words, silicates do not produce sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but at best produce one or more maxima of scattered X-rays with a width of several degrees of the diffraction angle. However, particularly good builder properties may be achieved even if the silicate particles produce unclear or sharp diffraction maxima in electron diffraction experiments. This is interpreted to mean that the product has microcrystalline regions with a size of 10 nm to several hundreds of nm, with values ​​of up to 50 nm and especially up to 20 nm being preferred. X-ray amorphous silicates of this type also dissolve more slowly than normal water glass and are described, for example, in DE 4400024 A1. Compacted / densified amorphous silicates, complex amorphous silicates and overdried X-ray amorphous silicates are particularly preferred.

[0112] Phosphates. Commonly known phosphates can also be added as builders, unless their use should be avoided for ecological reasons. Orthophosphates, pyrophosphates, and especially the sodium salts of tripolyphosphates are particularly suitable. Their content is generally not more than 25% by weight, preferably not more than 20% by weight, based on the finished composition. In some cases, it has been shown that tripolyphosphates, in particular, in combination with other builders, already in low amounts up to a maximum of 10% by weight, based on the finished composition, provide a synergistic improvement in secondary detergency. The preferred amount of phosphate is not more than 10% by weight, especially 0% by weight.

[0113] <Cobuilder> Polycarboxylic acids. Useful organic cobuilders are polycarboxylic acids, which can be used, for example, in the form of sodium salts of polycarboxylic acids, where polycarboxylic acids are understood to be carboxylic acids carrying two or more acid functions.These include, for example, citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acid, aminocarboxylic acid, nitrilotriacetic acid (NTA) and its derivatives and mixtures thereof.Preferred salts are the salts of polycarboxylic acids, such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acid and mixtures thereof.

[0114] organic acid. Acid itself can also be used.Apart from its construction effect, acid typically also has the properties of an acidifying component, and therefore also plays a role in establishing a relatively low and moderate pH in detergent or cleansing compositions.Citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and their mixtures are particularly mentioned in this respect.Furthermore suitable acidifying agents are known pH adjusting agents, such as sodium hydrogen carbonate and sodium hydrogen sulfate.

[0115] polymer. Particularly suitable polymeric cobuilders are polyacrylates, which preferably have a molecular weight of 2,000 to 20,000 g / mol. Due to their excellent solubility, preferred representatives of this group are also short-chain polyacrylates, which have a molecular weight of 2,000 to 10,000 g / mol, more particularly 3,000 to 5,000 g / mol. Suitable polymers also include substances that are partially or entirely composed of vinyl alcohol units or their derivatives.

[0116] Further suitable copolymeric polycarboxylates are in particular copolymers of acrylic acid and methacrylic acid, and copolymers of acrylic acid or methacrylic acid and maleic acid. Copolymers of acrylic acid and maleic acid, consisting of 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid, have proven particularly suitable. The relative molecular weight based on the free acid is generally in the range of 2,000 to 70,000 g / mol, preferably 20,000 to 50,000 g / mol, in particular 30,000 to 40,000 g / mol. The (co)polymeric polycarboxylates can be added as aqueous solutions or, preferably, as powders. To improve water solubility, the polymers can also contain allylsulfonic acids as monomers, for example allyloxybenzenesulfonic acid and methallylsulfonic acid, as in EP 0727448 B1.

[0117] Particularly preferred are biodegradable polymers consisting of two or more different monomer units, for example those consisting of acrylic acid and a salt of maleic acid and vinyl alcohol or a vinyl alcohol derivative as monomers, as in DE 4300772 A1, or those consisting of acrylic acid and a salt of 2-alkylarylsulfonic acid and a sugar derivative as monomers.Further preferred copolymers are those described in DE 4303320 A1 and DE 4417734 A1, which preferably contain acrolein and acrylic acid / acrylates or acrolein and vinyl acetate as monomers.

[0118] Likewise, other preferred builders are polymeric aminodicarboxylic acids, their salts or precursors. Particular preference is given to those polyaspartic acids or their salts and derivatives which are disclosed in DE 19540086 A1 as having bleach stabilizing action in addition to cobuilder properties.

[0119] Further suitable builders are the polyacetals which can be obtained by treating dialdehydes with polyol carboxylic acids having 5 to 7 carbon atoms and at least 3 hydroxyl groups, as described in EP 0 280 223 A1. Preferred polyacetals are obtained from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof, and polycarboxylic acids such as gluconic acid and / or glucoheptonic acid.

[0120] carbohydrates. Further suitable organic cobuilders are dextrins, oligomers or polymers of carbohydrates obtainable by partial hydrolysis of starch. Hydrolysis can be carried out using typical processes, for example acid or enzyme catalyzed processes. The hydrolysis products preferably have an average molecular weight in the range of 400 to 500,000 g / mol. Polysaccharides with a dextrose equivalent (DE) of 0.5 to 40, especially 2 to 30, are preferred, DE being an accepted measure of the reducing effect of polysaccharides compared to dextrose with a DE of 100. Maltodextrins with a DE of 3 to 20 and dry glucose syrups with a DE of 20 to 37, as well as so-called yellow dextrins and white dextrins of relatively high molecular weight of 2,000 to 30,000 g / mol can also be used. Preferred dextrins are described in British Patent Application 94 19 091.

[0121] The oxidized derivatives of such dextrins refer to their reaction products with oxidizing compositions capable of oxidizing at least one alcohol function of the saccharide ring to a carboxylic acid function. Such oxidized dextrins and their preparation are known, for example, from EP 0 232 202 A1. Products oxidized at C6 of the saccharide ring are particularly advantageous.

[0122] Oxydisuccinate and other derivatives of disuccinate, preferably ethylenediamine disuccinate, are further suitable cobuilders. Here, ethylenediamine-N,N'-disuccinate (EDDS), the synthesis of which is described, for example, in US 3,158,615, is preferably used in the form of its sodium or magnesium salt. In this context, glycerol disuccinate and glycerol trisuccinate are also particularly preferred, for example those described in US 4,524,009. The suitable loading amount in zeolite-containing products and / or silicate-containing formulations is in the range of 3 to 15% by weight.

[0123] Lactone. Other useful organic cobuilders are, for example, acetylated hydroxycarboxylic acids and their salts, optionally also in lactone form, containing at least 4 carbon atoms, at least one hydroxyl group and at most two acid groups. Such cobuilders are, for example, described in WO1995 / 020029A1.

[0124] <Bleaching compounds, bleaching agents and bleaching activators> The detergent composition herein can optionally contain a bleaching agent or a bleaching composition comprising a bleaching agent and one or more bleach activators.When present, the bleaching agent is typically present at a level of about 1% to about 30%, more typically about 5% to about 20% of the detergent composition, especially for fabric washing.When present, the amount of bleach activator is typically present at a level of about 0.1% to about 60%, more typically about 0.5% to about 40% of the bleaching composition consisting of bleaching agent-plus bleach activator.

[0125] The bleaching agent used herein may be any bleaching agent currently known or that becomes known that is useful in detergent compositions for fabric cleaning, hard surface cleaning, or other cleaning purposes. These include oxygen bleaching agents and other bleaching agents. Perborate bleaching agents, such as sodium perborate (e.g., monohydrate or tetrahydrate), may be used herein.

[0126] Another class of bleaching agents that may be used without limitation includes percarboxylic acid bleaching agents and their salts. Suitable examples of this class of agents include magnesium monoperoxyphthalate hexahydrate, the magnesium salt of meta-chloroperbenzoic acid, 4-nonylamino-4-oxoperoxybutyric acid, and diperoxydodecanedioic acid.

[0127] Peroxygen bleaches can also be used. Suitable peroxygen bleaching compounds include sodium carbonate peroxyhydrate and equivalent "percarbonate" bleaches, sodium pyrophosphate peroxyhydrate, urea peroxyhydrate, and sodium peroxide. Persulfate bleaches (e.g., OXONEO™ available from DuPont) can also be used.

[0128] The preferred percarbonate bleaching agent is comprised of dry particles having an average particle size ranging from about 500 μm to about 1,000 μm, with not more than about 10% by weight of the particles being smaller than about 200 μm and not more than about 10% by weight of the particles being greater than about 1,250 μm. Optionally, the percarbonate can be coated with a silicate, borate, or water-soluble surfactant. Percarbonate is available from a variety of commercial sources.

[0129] Mixtures of bleaching agents may also be used.

[0130] Peroxygen bleaches, perborates, percarbonates, etc. are preferably combined with bleach activators, whereby the corresponding peroxyacids are generated in situ in aqueous solution (i.e., during the wash process). Nonanoyloxybenzenesulfonate (NOBS) and tetraacetylethylenediamine (TAED) activators are typical, and mixtures thereof may also be used.

[0131] Preferred amide derived bleach activators include (6-octanamidocaproyl)oxybenzenesulfonate, (6-nonanamidocaproyl)oxybenzenesulfonate, (6-decanamidocaproyl)oxybenzenesulfonate, and mixtures thereof.

[0132] Another class of bleach activators consists of benzoxazine type activators as disclosed in US Pat. No. 4,966,723, which is incorporated herein by reference.

[0133] Highly preferred lactam activators include benzoylcaprolactam, octanoylcaprolactam, 3,5,5-trimethylhexanoylcaprolactam, nonanoylcaprolactam, decanoylcaprolactam, undecenoylcaprolactam, benzoylvalerolactam, octanoylvalerolactam, decanoylvalerolactam, undecenoylvalerolactam, nonanoylvalerolactam, 3,5,5-trimethylhexanoylvalerolactam and mixtures thereof, optionally adsorbed onto a solid support, such as an acylcaprolactam, preferably benzoylcaprolactam, and adsorbed onto sodium perborate.

[0134] Bleaching agents other than oxygen bleaches are also known in the art and can be utilized herein.One type of non-oxygen bleaching agent of particular interest includes photoactivated bleaches such as sulfonated zinc and / or aluminum phthalocyanines.When used, the detergent composition typically contains about 0.025% to about 1.25% by weight of such bleaching agents, particularly sulfonated zinc phthalocyanines.

[0135] Optionally, the bleaching compound can be catalyzed by a manganese compound. Such manganese catalysts are well known in the art and include MnIV2(uO)3(1,4,7-trimethyl-1,4,7-triazacyclononane)2(PF6)2, MnIII2(uO)1(u-OAc)2(1,4,7-trimethyl-1,4,7-triazacyclononane)2(ClO4)2, MnIV4(uO)6(1,4,7-triazacyclononane)4(ClO4)4MnIIIMnIV4(uO)1(u-OAc)2(1,4,7-trimethyl-1,4,7-triazacyclononane)2(ClO4)3, MnIV(1,4,7-trimethyl-1,4,7-triazacyclononane)-(OCH3)3(PF6), and mixtures thereof.

[0136] Practically, but without limitation, the compositions and processes herein can be tailored to provide at least 1 part per million of active bleach catalyst species in the aqueous wash liquor, preferably providing from about 0.1 ppm to about 700 ppm, more preferably from about 1 ppm to about 500 ppm of catalyst species in the wash liquor.

[0137] <Polymer-based stain remover> Any polymeric soil removing agent known to those skilled in the art can be optionally used in the detergent composition and method of the present invention.The polymeric soil removing agent is characterized by having both a hydrophilic segment that hydrophilizes the surface of hydrophobic fibers such as polyester and nylon, and a hydrophobic segment that deposits on the hydrophobic fibers and remains attached there until the completion of the washing and rinsing cycle, serving as an anchor for the hydrophilic segment.This allows the soil generated after treatment with the soil removing agent to be more easily cleaned in the subsequent washing procedure.

[0138] Polymeric stain removing agents useful in the present invention include, among others: (a) one or more non-ionic hydrophilic components consisting essentially of: (i) a polyoxyethylene segment having a degree of polymerization of at least 2, or (ii) the hydrophilic segment is an oxypropylene or polyoxypropylene segment having a degree of polymerization of from 2 to 10 that does not include any oxypropylene units unless they are joined at each end to adjacent moieties by ether bonds; or (iii) one or more non-ionic hydrophilic components comprising a mixture of oxyethylene and oxyalkylene units containing from 1 to about 30 oxypropylene units, said mixture containing a sufficient amount of oxyethylene units to enhance the hydrophilicity of conventional polyester synthetic fiber surfaces when the soil release agent is deposited on the surface, preferably containing at least about 25% oxyethylene units, and more preferably, at least about 50% oxyethylene units, particularly in the case of such components containing from about 20 to 30 oxypropylene units; or (b) one or more hydrophobic moieties, (i) when the hydrophobic component includes a C3 oxyalkylene terephthalate segment and also includes oxyethylene terephthalate, the ratio of oxyethylene terephthalate to C3 oxyalkylene terephthalate units is about 2:2:C3 oxyalkylene terephthalate units is about 2:1 or less; (ii) a C4-C6 alkylene or oxyC4-C6 alkylene segment, or a mixture thereof; (iii) a poly(vinyl ester) segment having a degree of polymerization of at least 2, preferably polyvinyl acetate), or (iv) contain C1-C4 alkyl ether or C4 hydroxyalkyl ether substituents, or mixtures thereof, which are present in the form of C1-C4 alkyl ether or C4 hydroxyalkyl ether cellulose derivatives, or mixtures thereof, which cellulose derivatives are amphiphilic, whereby they have a sufficient level of C1-C4 alkyl ether and / or C4 hydroxyalkyl ether units to deposit on conventional polyester synthetic fibers and, once attached to such conventional synthetic fiber surfaces, retain a sufficient level of hydroxyl groups to enhance the hydrophilicity of the fiber surface; or A combination of (a) and (b).

[0139] Typically, the polyoxyethylene segments in (a)(i) will have a degree of polymerization of from about 200, preferably from 3 to about 150, more preferably from 6 to about 100, although higher levels can be used. Suitable oxy C4-C6 alkylene hydrophobic segments include, but are not limited to, the end caps of polymeric stain removing agents.

[0140] Polymeric soil release agents useful in the present invention also include cellulose derivatives such as hydroxyether cellulose polymers, copolymer blocks of ethylene terephthalate or propylene terephthalate with polyethylene oxide or polypropylene oxide terephthalate. Such agents are commercially available and include hydroxyethers of cellulose such as METHOCEL™ (DOW). Cellulosic soil release agents for use in the present invention also include those selected from the group consisting of C1-C4 alkyl celluloses and C4 hydroxyalkyl celluloses.

[0141] Polymeric stain removal agents featuring poly(vinyl ester) hydrophobic segments include graft copolymers of poly(vinyl ester), such as C1-C6 vinyl esters, preferably poly(vinyl acetate), grafted onto a polyalkylene oxide backbone, such as a polyethylene oxide backbone. See EP0 219048, incorporated herein by reference.

[0142] One preferred polymeric stain release agent is a copolymer having random blocks of ethylene terephthalate and polyethylene oxide (PEO) terephthalate. The molecular weight of this polymeric soil release agent preferably ranges from about 25,000 to about 55,000.

[0143] Another preferred polymeric stain removing agent is a polyester having repeating units of ethylene terephthalate units, containing 10 to 15% by weight of ethylene terephthalate units with 90 to 80% by weight of polyoxyethylene terephthalate units derived from a polyoxyethylene glycol having an average molecular weight of 300 to 5000. Examples of this polymer include the commercially available ZELCON™ 5126 (manufactured by DuPont) and MILEASE™ T (manufactured by ICI).

[0144] Another preferred polymeric stain remover is the sulfonated product of a substantially linear ester oligomer consisting of an oligomeric ester backbone of terephthaloyl and oxyalkyleneoxy repeating units with terminal moieties covalently bonded to the backbone. These stain removers are fully described in US 4,968,451. Other suitable polymeric stain removers include the terephthalic acid polyesters of US 4,711,730, the anionic end-capped oligomeric esters of US 4,721,580, the block polyester oligomeric compounds of US 4,702,857, and the anionic, particularly sulfoaroyl, end-capped terephthalic acid esters of US 4,877,896. All of these cited patents are incorporated herein in their entirety.

[0145] Yet another preferred stain release agent is an oligomer having repeat units of terephthaloyl, sulfoisoterephthaloyl, oxyethyleneoxy and oxy-1,2-propylene units. The repeat units form the backbone of the oligomer and are preferably terminated with modified isethionate end caps. A particularly preferred stain release agent of this type contains about one sulfoisophthaloyl unit, five terephthaloyl units in a ratio of about 1.7 to about 1.8, oxyethyleneoxy and oxy-1,2-propyleneoxy units, and two end cap units of sodium 2-(2-hydroxyethoxy)-ethanesulfonate. The stain release agent also contains about 0.5% to about 20% of a crystal reduction stabilizer by weight of the oligomer, preferably selected from the group consisting of xylenesulfonic acid, cumenesulfonic acid, toluenesulfonic acid, and mixtures thereof.

[0146] If utilized, the stain removing agents generally comprise from about 0.01% to about 10.0% by weight of the detergent compositions herein, typically from about 0.1% to about 5%, preferably from about 0.2% to about 3.0%.

[0147] <Polymer dispersant> Polymeric dispersants can be advantageously utilized in the detergent compositions herein at a level of about 0.1% to about 7% by weight, especially in the presence of zeolite and / or layered silicate builders.Suitable polymeric dispersants include polymeric polycarboxylates and polyethylene glycols, although others known in the art can also be used.Without intending to be limited by theory, it is believed that polymeric dispersants, when used in combination with other builders (including low molecular weight polycarboxylates), enhance the overall detergent builder performance by inhibiting crystal growth, inhibiting the release of particulate soil, and preventing redeposition.

[0148] Polymeric polycarboxylate materials can be prepared by polymerizing or copolymerizing suitable unsaturated monomers, preferably in acid form. Unsaturated monomeric acids that can be polymerized to form suitable polymeric polycarboxylates include acrylic acid, maleic acid (or maleic anhydride), fumaric acid, itaconic acid, aconitic acid, mesaconic acid, citraconic acid, and methylenemalonic acid. The polymeric polycarboxylates or monomer segments herein do not include carboxylate radicals such as vinyl methyl ether, styrene, ethylene, etc., although suitably present as long as such segments do not exceed about 40% by weight.

[0149] Particularly suitable polymeric polycarboxylates can be derived from acrylic acid. Such acrylic acid-based polymers useful in the present invention are water-soluble salts of polymerized acrylic acid. The average molecular weight of such polymers in the acid form preferably ranges from about 2,000 to 10,000, more preferably from about 4,000 to 7,000, and most preferably from about 4,000 to 5,000. Water-soluble salts of such acrylic acid polymers include, for example, alkali metal, ammonium, and substituted ammonium salts. Soluble polymers of this type are known materials. The use of this type of polyacrylate in detergent compositions is disclosed, for example, in US 3,308,067.

[0150] Acrylic acid / maleic acid copolymers can also be used as a preferred component of the dispersant / anti-redeposition agent. Such materials include water-soluble salts of copolymers of acrylic acid and maleic acid. The average molecular weight of such copolymers in the acid form preferably ranges from about 2,000 to 100,000, more preferably from about 5,000 to 75,000, and most preferably from about 7,000 to 65,000. The ratio of acrylate segments to maleic acid segments in such copolymers will generally range from about 30:1 to about 1:1, more preferably from about 10:1 to 2:1. Water-soluble salts of such acrylic acid / maleic acid copolymers can include, for example, alkali metal salts, ammonium salts, and substituted ammonium salts. Soluble acrylic acid / maleic acid copolymers of this type are known materials, as described in EP 0 193 360 A1, in which such polymers consisting of hydroxypropyl acrylate are also described. Still other useful dispersants include maleic acid / acrylic acid / vinyl alcohol terpolymers, such as a 45 / 45 / 10 terpolymer of acrylic acid / maleic acid / vinyl alcohol.

[0151] Another polymeric material that can be included is polyethylene glycol (PEG). PEG can act as a dispersant as well as a clay soil remover and anti-redeposition agent. Typical molecular weight ranges for these purposes are from about 500 to about 100,000, preferably from about 1,000 to about 50,000, and more preferably from about 1,500 to about 10,000.

[0152] Polyaspartic and polyglutamic acid dispersants may also be used, especially in combination with zeolite builders. Dispersants such as polyaspartic acid preferably have a molecular weight (average) of about 10,000.

[0153] <Foam inhibitors / foam suppressors> It is advantageous to add conventional foam inhibitors to the composition, especially when used in automatic cleaning processes. Suitable foam inhibitors include, for example, soaps of natural or synthetic origin that are rich in C18-C24 fatty acids. Suitable non-surface-active type foam inhibitors include, for example, organopolysiloxanes and their mixtures with fine, optionally silanized silica, as well as mixtures with paraffins, waxes, microcrystalline waxes and silanized silica or bis-stearylethylenediamide. Mixtures of various foam inhibitors, such as mixtures of silicones, paraffins or waxes, are also advantageously used. Preferably, the foam inhibitors, especially silicone-containing and / or paraffin-containing foam inhibitors, are supported on a granular, water-soluble or dispersible carrier material. In particular in this case, mixtures of paraffins and bis-stearylethylenediamide are preferred.

[0154] Compounds for reducing or inhibiting the formation of soap suds can be incorporated into the detergent compositions of the present invention. The inhibition of soap suds can be particularly important in the so-called "heavy wash process" and in front-loading European washing machines.

[0155] A wide variety of materials can be used as suds suppressors, and suds suppressors are well known to those skilled in the art. For example, see KIRK OTHMER ENCYCLOPEDIA OF CHEMICAL TECHNOLOGY, THIRD EDITION, VOLUME 7, PAGES 430-447 (JOHN WILEY & SONS, INC., 1979). One category of suds suppressors of particular interest includes monocarboxylic fatty acids and their soluble salts. The monocarboxylic fatty acids and their salts used as suds suppressors typically have hydrocarbyl chains of 10 to about 24 carbon atoms, preferably 12 to 18 carbon atoms. Suitable salts include alkali metal salts such as sodium salts, potassium salts, lithium salts, ammonium salts, alkanolammonium salts, and the like.

[0156] The detergent compositions herein may also contain non-surfactant suds suppressors. These include, for example: high molecular weight hydrocarbons such as paraffins, fatty acid esters (e.g., fatty acid triglycerides), fatty acid esters of monohydric alcohols, aliphatic C18-C40 ketones (e.g., stearone), and the like. Other streak suppressors include N-alkylated aminotriazines such as tri- to hexa-alkylmelamines or di- to tetra-alkyldiamine chlortriazines, propylene oxide formed as the product of cyanuric chloride with 2 to 3 moles of a primary or secondary amine containing 1 to 24 carbon atoms, and monostearyl phosphate esters such as monostearyl alcohol phosphate ester and monostearyl di-alkali metal (e.g., K, Na, and Li) phosphate ester and phosphate ester. Hydrocarbons such as paraffins and haloparaffins may be utilized in liquid form. Liquid hydrocarbons are liquid at room temperature and atmospheric pressure and have a pour point ranging from about -40°C to about 50°C, and a minimum boiling point of about 110°C (atmospheric pressure) or higher. It is also known to utilize waxy hydrocarbons, preferably having a melting point below about 100° C. Hydrocarbon suds suppressors are known in the art and include aliphatic, alicyclic, aromatic and heterocyclic saturated or unsaturated hydrocarbons having from about 12 to about 70 carbon atoms. The term "paraffin" as used in this discussion of suds suppressors is intended to include mixtures of true paraffins and cyclic hydrocarbons.

[0157] Another preferred category of non-surfactant suds suppressors is silicone suds suppressors. This category includes the use of polyorganosiloxane oils such as polydimethylsiloxane, dispersions or emulsions of polyorganosiloxane oils or resins, and combinations of polyorganosiloxane and silica particles where the polyorganosiloxane is chemisorbed or fused to the silica. Silicone suds suppressors are well known in the art.

[0158] Other silicone suds suppressors are disclosed in US Pat. No. 3,455,839, which is incorporated herein in its entirety, and which relates to compositions and processes for defoaming aqueous solutions by incorporating small amounts of polydimethylsiloxane fluids therein.

[0159] Mixtures of silicones and silanated silicas are described, for example, in DE-OS 2124526, which is incorporated herein in its entirety. Silicone antifoam and suds control agents in granular detergent compositions are disclosed in US 4,652,392, which is incorporated herein in its entirety.

[0160] In the preferred silicone suds suppressors used herein, the continuous phase solvent consists of certain polyethylene glycols or polyethylene-polypropylene glycol copolymers or mixtures thereof (preferred), or polypropylene glycol. The primary silicone suds suppressors are branched / crosslinked and preferably not linear.

[0161] The silicone suds suppressors herein preferably consist of polyethylene glycol and polyethylene glycol / polypropylene glycol copolymers, all of which have an average molecular weight of less than about 1000, preferably between about 100 and 800. The polyethylene glycol and polyethylene / polypropylene glycol copolymers herein have a solubility in water at room temperature of about 2% by weight or more, preferably about 5% by weight or more.

[0162] Preferred solvents herein are polyethylene glycols having an average molecular weight of less than about 1000, more preferably between about 100 and 800, and most preferably between 200 and 400, and polyethylene glycol / polypropylene glycol copolymers, preferably PPG200 / PEG300. Preferred are weight ratios of polyethylene glycol:polyethylene-polypropylene glycol copolymer between about 1:1 and 1:10, and most preferably between 1:3 and 1:6.

[0163] Preferred silicone suds suppressors for use herein are specifically free of polypropylene glycols having a molecular weight of 4,000, and preferably free of block copolymers of ethylene oxide and propylene oxide such as PLURONIC® L101.

[0164] Other suds suppressors useful herein consist of secondary alcohols (e.g., 2-alkyl alkanols) and mixtures of such alcohols with silicone oils. Secondary alcohols include C6-C16 alkyl alcohols having C1-C16 chains. A preferred alcohol is 2-butyl octanol, available under the trademark ISOFOL™ 12 from CONDEA. A mixture of secondary alcohols is available under the trademark ISALCHEM™ 123 from ENICHEM. Mixed suds suppressors usually consist of a mixture of alcohols + silicones in a weight ratio of 1:5 to 5:1.

[0165] The compositions herein generally comprise 0% to about 5% of a suds suppressor. When utilized as a suds suppressor, monocarboxylic fatty acids and their salts are generally present in an amount up to about 5% by weight of the detergent composition. Preferably, about 0.5% to about 3% of a fatty monocarboxylic suds suppressor is utilized. Silicone suds suppressors are typically utilized in an amount up to about 2.0% by weight of the detergent composition, although higher amounts can be used. This upper limit is essentially practical, primarily due to concerns about minimizing cost and the effectiveness of low amounts to effectively control suds. Preferably, about 0.01% to about 1% of a silicone suds suppressor is utilized, more preferably about 0.25% to about 0.5%. As used herein, these weight percentage values ​​include any silica that may be utilized in combination with the polyorganosiloxane, and any auxiliary materials that may be utilized. Monostearyl phosphate suds suppressors are generally utilized in an amount of about 0.1% to about 2% by weight of the composition. Hydrocarbon suds suppressors are generally utilized in amounts ranging from about 0.01% to about 5.0%, although higher levels can be used. Alcohol suds suppressors are typically used at 0.2% to 3% by weight of the finished composition.

[0166] <Sequestering and chelating agents> The salts of polyphosphonic acids can be considered as sequestering agents or stabilizers, particularly for peroxidic compounds and enzymes which are sensitive to heavy metal ions, for example the sodium salts of 1-hydroxyethane-1,1-diphosphonate, diethylenetriaminepentamethylenephosphonate or ethylenediaminetetramethylenephosphonate are used here in amounts of 0.1 to 5% by weight.

[0167] The detergent compositions herein may also optionally include one or more iron and / or manganese chelating agents. Such chelating agents may be selected from the group consisting of aminocarboxylates, aminophosphonates, polyfunctionally substituted aromatic chelating agents and mixtures thereof, all of which are defined below. Without wishing to be bound by theory, it is believed that the benefits of these materials are due in part to their exceptional ability to remove iron and manganese ions from the wash liquor by forming soluble chelates. It is understood that some of the aforementioned detergent builders can function as chelating agents, and that such detergent builders can provide both functions when present in sufficient amounts.

[0168] Aminocarboxylates useful as optional chelating agents include ethylenediaminetetraacetate, N-hydroxyethylethylenediaminetriacetate, nitrilotriacetate, ethylenediaminetetrapropionate, triethylenetetraaminehexaacetate, diethylenetriaminepentaacetate, and ethanoldiglycine, their alkali metal, ammonium, and substituted ammonium salts, and mixtures thereof.

[0169] Aminophosphonates are also suitable as chelating agents in the compositions of the present invention, where the total phosphorus content in the detergent composition is at least tolerable at low levels, and include ethylenediaminetetrakis(methylenephosphonate) as DEQUEST. Preferably, these aminophosphonates do not contain alkyl or alkenyl groups having more than about 6 carbon atoms.

[0170] Polyfunctionally substituted aromatic chelating agents are also useful in the compositions herein. Preferred compounds of this type in the acid form are the dihydroxydisulfobenzenes, such as 1,2-dihydroxy-3,5-disulfobenzene.

[0171] A preferred biodegradable chelating agent for use herein is ethylenediamine disuccinate ("EDDS"), particularly the [S,S] isomer.

[0172] When these chelating agents are used, they generally comprise from about 0.1% to about 10% by weight of the detergent compositions herein. More preferably, when chelating agents are used, they comprise from about 0.1% to about 3.0% by weight of such compositions.

[0173] <Clay stain remover / anti-reattachment agent> The detergent compositions of the present invention may also optionally contain water-soluble ethoxylated amines having clay soil removal and anti-redeposition properties. Granular detergent compositions containing these compounds typically contain from about 0.01% to about 10.0% by weight of the water-soluble ethoxylated amine, and liquid detergent compositions typically contain from about 0.01% to about 5%.

[0174] The most preferred soil removal and redeposition inhibitor is ethoxylated tetraethylenepentamine. Exemplary ethoxylated amines are further described in US 4,597,898. Other groups of preferred clay soil removal-redeposition inhibitors are cationic compounds as disclosed in EP 0111965 A1, ethoxylated amine polymers as disclosed in EP 0111984 A1, zwitterionic polymers as disclosed in EP 0112592 A1, and amine oxides as disclosed in US 4,548,744. Another type of preferred redeposition inhibitor includes carboxymethyl cellulose (CMC) materials. These materials are well known in the art.

[0175] <Anti-graying agent> The antigraying agent has the function of keeping the dirt removed from the fibers in suspension in the washing liquid, thereby preventing the dirt from being re-fixed. Mainly organic water-soluble colloids are suitable for this, such as water-soluble salts of (co)polymeric carboxylic acids, adhesives, gelatin, salts of ether carboxylic acids or ether sulfonic acids of starch or cellulose, or salts of acidic sulfates of cellulose or starch. Water-soluble acid group-containing polyamides are also suitable for this purpose. In addition, as the starches, soluble starch preparations can also be used, such as decomposed starch, aldehyde starch, etc. Also polyvinylpyrrolidone can be used. However, preference is given to the use of cellulose ethers such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose and mixed ethers such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof, as well as polyvinylpyrrolidone, which can be added, for example, in amounts of 0.1 to 5% by weight, based on the composition.

[0176] <Fluorescent brightening agents and UV absorbents> Any optical brightener or other brightening or whitening agent known in the art can be incorporated into the detergent compositions herein, typically at a level of about 0.05% to about 1.2% by weight. Commercially available optical brighteners useful in the present invention can be divided into subgroups including, but not limited to, derivatives of stilbenes, pyrazolines, coumarins, carboxylic acids, methine cyanines, dibenzothiophene-5,5-dioxides, azoles, 5- and 6-membered heterocycles, and other miscellaneous agents.

[0177] Preferred brighteners include the PHORWHITE series of brighteners from VERONA. Other brighteners disclosed in this document include: TINOPAL™ UNPA, TINOPAL CBS, and TINOPAL 5BM; available from CIBA-GEIGY; ARTIC WHITE™ CC and ARTIC WHITE CWD; available from HILTON-DAVIS; 2-(4-stryl-phenyl)-2H-naphthol[1,2-D]triazole; 4,4'-bis-(1,2,3-triazol-2-yl)-stilbene; 4,4'-bis(stryl)bisphenyl; and aminocoumarin. Specific examples of these brighteners include 4-methyl-7-diethyl-aminocoumarin; 1,2-bis(-benzimidazol-2-yl)ethylene; 1,3-diphenyl-furazoline; 2,5-bis(benzoxazol-2-yl)thiophene; 2-stryl-naphtho-[1,2-D]oxazole; and 2-(stilben-4-yl)-2H-naphtho-[1,2-D]triazole. Anionic brighteners are preferred herein.

[0178] The composition may contain, as an optical brightener, for example, a derivative of diaminostilbene disulfonic acid or an alkali metal salt thereof. Suitable optical brighteners are, for example, salts of 4,4'-bis-(2-anilino-4-morpholino-1,3,5-triazinyl-6-amino)stilbene-2,2'-di-sulfonic acid, or compounds of similar structure containing diethanolamino, methylamino, anilino or 2-methoxyethylamino groups instead of morpholino groups. Substituted diphenylstyryl type optical brighteners may also be present, such as the alkali metal salts of 4,4'-bis(2-sulfostyryl)diphenyl, 4,4'-bis(4-chloro-3-sulfostyryl)diphenyl or 4-(4-chlorostyryl)-4'-(2-sulfostyryl)diphenyl. Mixtures of the mentioned optical brighteners may also be used.

[0179] In addition, UV absorbents can also be added. These are compounds with a clear absorption ability against ultraviolet light, which not only improve the photostability of colorants and pigments, but also contribute as UV stabilizers, by protecting the textile fibers from UV radiation penetrating the textile, but also the skin of the wearer of the textile product. In general, efficient non-radiative inactivating compounds are derivatives of benzophenones substituted mainly with hydroxyl and / or alkoxy groups in the 2- and / or 4-positions. Also suitable are substituted benzotriazoles, as well as acrylates (cinnamic acid derivatives) with phenyl substitution in the 3-position, acrylates optionally with a cyano group in the 2-position, salicylates, organic NI complexes, and natural substances such as umbelliferone and endogenous urocanic acid. In a preferred embodiment, the UV absorbents absorb UV-A and UV-B radiation as well as possible UV-C radiation and re-emit light of blue wavelengths, so that they additionally have a fluorescent whitening effect. Preferred UV absorbers include triazine derivatives such as hydroxyaryl-1,3,5-triazines, sulfonated 1,3,5-triazines, O-hydroxyphenyl-benzo-triazoles and 2-aryl-2H-benzotriazoles, as well as bis(anilinotriazinyl-amino)stilbenedisulfonic acid and their derivatives. Ultraviolet absorbing pigments such as titanium dioxide can also be used as UV absorbers.

[0180] <Dye transfer inhibitor> The detergent compositions of the present invention may also contain one or more materials that are effective in inhibiting the transfer of dyes from one fabric to another during the washing process. Typically, such dye transfer inhibitors include polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, manganese phthalocyanine, peroxidase, and mixtures thereof. When used, these dye transfer inhibitors typically comprise from about 0.01% to about 10% by weight of the composition, preferably from about 0.01% to about 5% by weight, and more preferably from about 0.05% to about 2% by weight.

[0181] More specifically, preferred polyamine N-oxide polymers for use herein are described in US Pat. No. 6,491,728, which is incorporated herein by reference.

[0182] Any polymer backbone can be used so long as the amine oxide polymer formed is water soluble and has dye transfer inhibiting properties. Examples of suitable polymer backbones are polyvinyl, polyalkylene, polyester, polyether, polyamide, polyimide, polyacrylate, and mixtures thereof. These polymers include random or block copolymers in which one monomer is an amine N-oxide and the other monomer is an N-oxide. Amine N-oxide polymers typically have a ratio of amine to amine N-oxide of 10:1 to 1:1,000,000. However, the number of amine oxide groups present in a polyamine oxide polymer can be varied by appropriate copolymerization or appropriate degree of N-oxidation. Polyamine oxides can be obtained with almost any degree of polymerization. Typically, the average molecular weight is in the range of 500 to 1,000,000; more preferably 1,000 to 500,000; most preferably 5,000 to 100,000. This preferred class of materials can be referred to as "PVNO".

[0183] The most preferred polyamine N-oxide useful in the detergent compositions herein is poly(4-vinylpyridine-N-oxide) having an average molecular weight of about 50,000 and an amine to amine N-oxide ratio of about 1:4.

[0184] Copolymers of N-vinylpyrrolidone and N-vinylimidazole polymers (collectively referred to as "PVPVI") are also preferred for use herein. Preferably, the PVPVI has an average molecular weight ranging from 5,000 to 1,000,000, more preferably from 5,000 to 200,000, and most preferably from 10,000 to 20,000. PVPVI copolymers typically have a molar ratio of N-vinylimidazole to N-vinylpyrrolidone of 1:1 to 0.2:1, more preferably from 0.8:1 to 0.3:1, and most preferably from 0.6:1 to 0.4:1. These copolymers may be linear or branched.

[0185] The compositions of the present invention may also employ polyvinylpyrrolidone ("PVP") having an average molecular weight of about 5,000 to about 400,000, preferably about 5,000 to about 200,000, and more preferably about 5,000 to about 50,000. PVP is known to those skilled in the detergent arts. Compositions containing PVP may also include polyethylene glycol ("PEG") having an average molecular weight of about 500 to about 100,000, preferably about 1,000 to about 10,000. The ratio of PEG to PVP provided to the wash liquor on a ppm basis is preferably about 2:1 to about 50:1, more preferably about 3:1 to about 10:1.

[0186] The detergent compositions herein can also optionally contain about 0.005% to 5% by weight of certain hydrophilic optical brighteners that also provide dye transfer inhibiting activity. When used, the compositions herein preferably contain about 0.01% to 1% by weight of such optical brighteners.

[0187] One preferred brightener is 4,4',-bis[(4-anilino-6-(N-2-bis-hydroxyethyl)-S-triazin-2-yl)amino]-2,2'-stilbenedisulfonic acid and disodium salt. This particular brightener species is commercially available from CIBA-GEIGY CORPORATION under the trade name TINOPAL-UNPA-GX™. TINOPAL-UNPA-GX is a preferred hydrophilic optical brightener useful in the detergent compositions herein.

[0188] Another preferred brightener is 4,4'-bis[(4-anilino-6-(N-2-hydroxyethyl-N-methylamino)-S-triazin-2-yl)amino]2,2'-stilbenedisulfonic acid disodium salt. This particular brightener species is commercially available under the trade name TINOPAL 5BM-GX™ from CIBA-GEIGY.

[0189] Another preferred brightener is 4,4'-bis[(4-anilino-6-morpholino-S-triazin-2-yl)amino]2,2'-stilbenedisulfonic acid, sodium salt. This particular species of brightener is commercially sold under the trade name TINOPAL AMS-GX™ by CIBA-GEIGY.

[0190] The particular fluorescent brightener species selected for use in the present invention provide the advantage of particularly effective dye transfer inhibition performance when used in combination with the selected polymeric dye transfer inhibitors previously described herein. The combination of such selected polymeric materials (e.g., PVNO and / or PVPVI) with such selected fluorescent brighteners (e.g., TINOPAL UNPA-GX, TINOPAL 5BM-GX and / or TINOPAL AMS-GX) provides significantly better dye transfer inhibition in aqueous wash liquors than either of these two detergent composition components when used alone. Without being bound by theory, it is believed that such brighteners function in this way because they have a high affinity for fabrics in the wash liquor and therefore deposit relatively quickly on these fabrics. The extent to which a brightener is attached to fabrics in the wash liquor can be defined by a variable called the "wear factor". The wear factor is generally the ratio of a) the brightener material attached to the fabric to b) the initial brightener concentration in the wash liquor. In the present invention, brighteners with a relatively high wear factor are best suited to inhibit dye transfer.

[0191] Of course, it will be understood that other, conventional optical brightener type compounds can optionally be used in the present compositions to provide a conventional fabric "whitening" effect rather than a true dye transfer inhibition effect, as such uses are conventionally known in detergent products.

[0192] <Thickener> The composition may also include common thickening and anti-settling compositions, as well as viscosity modifiers such as polyacrylates, polycarboxylic acids, polysaccharides and their derivatives, polyurethanes, polyvinylpyrrolidones, castor oil derivatives, polyamine derivatives such as quaternized and / or ethoxylated hexamethylenediamines, and any mixtures thereof. Preferred compositions have a viscosity of 10,000 mPa*s or less, measured with a Brookfield viscometer at a temperature of 20° C. and a shear rate of 50 min-1.

[0193] <Inorganic salts> Further preferred components of the composition are water-soluble inorganic salts such as bicarbonates, carbonates, amorphous silicates or mixtures thereof; alkali carbonates and amorphous silicates are particularly used, mainly sodium silicates in a molar ratio Na2O:SiO2 of 1:1 to 1:4.5, preferably 1:2 to 1:3.5. Preferred compositions contain alkali salts, builders and / or cobuilders, preferably sodium carbonate, zeolites, crystalline, sheet sodium silicates and / or trisodium citrate, in an amount of 0.5 to 70% by weight, preferably 0.5 to 50% by weight, in particular 0.5 to 30% by weight of anhydrous material.

[0194] <Fragrances and colorants> The composition can further include typical detergent and cleansing composition components such as fragrance and / or coloring agent, preferably such coloring agent does not leave any or negligible coloring on the washed fabric.The total preferred amount of coloring agent added is 1% or less by weight, preferably 0.1% or less by weight, based on the composition.The composition can also include a white pigment, such as TiO2. [Industrial Applicability]

[0195] Another object of the invention relates to a method for increasing, improving and / or adjusting the odor of a fragrance that inherently has balsamic and / or leathery odor notes, comprising or consisting of the following steps: (a) providing at least one first fragrance with inherently balsamic and / or leathery scent notes; (b) providing p-tolylmethanol; (c) adding to said at least a first fragrance said p-tolylmethanol in an amount sufficient to enhance, improve and / or adjust the original odor notes of said first fragrance.

[0196] Also claimed is the use of p-tolylmethanol to increase, improve and / or modify the odor of fragrances that inherently have balsamic and / or leathery odor notes.

[0197] For the avoidance of doubt, it should be noted that all of the preferred embodiments already mentioned above, in particular mixtures, combinations, amounts used, etc., are common to the claimed process as well as to the claimed use, and therefore there is no need to repeat them. Furthermore, the indication of an effective amount preferably means the addition of about 0.1% to about 2% by weight, preferably about 0.5% to about 1% by weight, of P-tolylmethanol relative to said first fragrance.

[0198] The final object of the present invention relates to the use of P-tolylmethanol as a fragrance. EXAMPLES

[0199] <Examples 1 to 16> Improvement of aroma by adding p-tolylmethanol

[0200] P-tolylmethanol (pTM) was added in small amounts of 0.1% to 1% by weight to various first fragrances with balsamic or leather notes. The resulting odor modifications were determined by five experienced perfumers. The results are shown in Table 1. Improvement of aroma by adding p-tolylmethanol [Table 8-1] [Table 8-2] <Examples 17 to 19>

[0201] Tables 2 to 4 below show typical fragrance compositions containing P-tolylmethanol. Fragrance Composition I [Table 9]

[0202] The evaluation was carried out in 10% ethanol. Compared to the fragrance composition without pTM, the new fragrance blend is more harmonious. The caramel facets are stronger and more cappuccino-like due to the presence of pTM. The pyrazine portion is balanced and less dominant. Fragrance Composition II [Table 10]

[0203] Evaluation was performed in 10% ethanol. With the addition of pTM, the leather note changed from smooth leather to suede. The blend became softer and the birch tar note was reduced. pTM harmonised the notes and improved performance. Fragrance Composition III [Table 11]

[0204] The evaluation was carried out at 11% in a deodorant (aerosol). pTM reduces technical solvent notes and brings more gourmand and leathery facets to the fragrance without taking the fragrance in a different direction or interfering with the deodorant profile. Overall performance was also improved.

Claims

1. (a) at least one first fragrance having balsamic and / or leathery scent notes; (b) p-tolylmethanol (pTM); A fragrance mixture comprising or consisting of:

2. 2. The fragrance mixture of claim 1, wherein the first fragrance is selected from the group consisting of ethyl vanillin, vanillin, propenyl guaethol, coumarin delta octalactone, benzyl cinnamate, 3-phenylpropanol, methyl lightone, furaneol, isopropylcyclohexanol, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1-penten-3-one, cade oil, styrax oil, 2,3,3-trimethylindanone, butylquinoline and isobutylquinoline, and mixtures thereof.

3. 2. The fragrance mixture of claim 1, wherein said first fragrance and said p-tolylmethanol (pTM) are present in an amount ranging from about 98:2% to about 99.9:0.5% by weight, calculated on the mixture.

4. 10. The fragrance mixture of claim 1 further comprising at least one solvent.

5. 5. The fragrance mixture of claim 4, wherein the solvent is selected from the group consisting of water, ethanol, propylene glycol, dipropylene glycol, glycerol and triethyl citrate.

6. 5. The fragrance mixture of claim 4, wherein the solvent is present in the mixture in an amount ranging from about 10 to about 90% by weight.

7. A fragrance composition comprising the mixture of claim 1 and at least one second fragrance different from the first fragrance and the pTM.

8. 8. The fragrance composition of claim 7, wherein the second fragrance is selected from the group consisting of: 【Table 1-1】 【Table 1-2】 【Table 1-3】 【Table 1-4】 【Table 1-5】 【Table 1-6】 【Table 1-7】

9. 8. The fragrance composition of claim 7, wherein said pTM or any of said fragrance mixtures of claim 1 is present in an amount ranging from about 0.01 to about 2% by weight calculated on said perfume composition.

10. A cosmetic or personal care product comprising the fragrance mixture of claim 1 or the fragrance composition of claim 7.

11. A detergent product comprising the fragrance mixture of claim 1 or the perfume composition of claim 7.

12. 10. A formulation comprising the fragrance mixture of claim 1 or the fragrance composition of claim 7 in an amount of from about 0.01 to about 2% by weight.

12. A personal care product according to claim 10 or a detergent product according to claim 11.

13. 1. A method for increasing, improving and / or adjusting the odor of a fragrance that naturally has balsamic and / or leathery odor notes, comprising: (a) providing at least one first fragrance with inherently balsamic and / or leathery scent notes; (b) providing p-tolylmethanol; (c) adding to said at least a first fragrance an amount of said p-tolylmethanol sufficient to increase, improve and / or adjust the original odor notes of said first fragrance; 20. A method comprising or consisting of:

14. Use of P-tolylmethanol to increase, improve and / or adjust the odor of a fragrance that inherently has balsamic and / or leathery odor notes.

15. Use of p-tolylmethanol as a fragrance.

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