Batteries, battery packs including the same, and automobiles
The battery design addresses the challenge of maintaining electrical insulation in high temperature environments by using a gasket and cover member configuration, effectively preventing short circuits and reducing thermal event risks.
Patent Information
- Application Number
- JP2024553211
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- Priority Date
- 2022-07-19
- Filing Date
- 2023-07-19
- Publication Date
- 2025-04-16
- Estimated Expiration
- 2043-07-19
AI Technical Summary
High temperature environments during thermal events in batteries can damage electrical insulation components, leading to short circuits and the diffusion of thermal events, posing a safety risk.
A battery design that includes an electrode assembly, a battery housing, a terminal, a gasket, and a cover member, where the gasket is interposed between the terminal and the battery housing, and the cover member covers the exposed area of the gasket to prevent direct contact with the electrode assembly, thereby maintaining electrical insulation even in high temperature environments.
The battery design effectively maintains electrical insulation between the battery terminals and the housing, even in high temperature conditions, thereby preventing short circuits and reducing the risk of thermal event diffusion.
Smart Images

Figure 2025511494000001_ABST
Abstract
Description
[Technical field]
[0001] The present invention relates to a battery, a battery pack including the same, and a vehicle.
[0002] This application claims priority to Korean Patent Application No. 10-2022-0089126 filed on July 19, 2022, the entire contents of which are incorporated herein by reference in their entirety in the specification and drawings. [Background technology]
[0003] Batteries that can be easily applied to various products and have electrical properties such as high energy density are widely used not only in portable devices but also in electric vehicles (EVs) and hybrid electric vehicles (HEVs) that are driven by electric driving sources.
[0004] Such batteries are attracting attention as a new energy source not only because they have the primary advantage of dramatically reducing the use of fossil fuels, but also because they are environmentally friendly and improve energy efficiency, as they do not produce any by-products associated with energy use.
[0005] Currently, the types of batteries that are widely used include lithium ion batteries, lithium polymer batteries, nickel cadmium batteries, nickel metal hydride batteries, nickel zinc batteries, etc. The operating voltage of such a unit battery cell is about 2.5V to 4.5V. Therefore, when a higher output voltage is required, a battery pack is constructed by connecting a plurality of batteries in series. Also, a battery pack may be constructed by connecting a plurality of batteries in parallel depending on the charge / discharge capacity required for the battery pack. Therefore, the number and electrical connection form of battery cells included in the battery pack can be variously set depending on the required output voltage and / or charge / discharge capacity.
[0006] In recent years, as the demand for high-capacity and / or high-power batteries increases, active research has been conducted into batteries that can ensure safety when a thermal event occurs in the battery.
[0007] If an abnormality occurs during battery use, the internal pressure of the battery may increase, causing a thermal event to spread due to the generation of high-temperature gases and / or flames inside. If such a thermal event occurs in a high-capacity and / or high-power battery, it can cause significant damage.
[0008] When a thermal event occurring inside a battery damages the battery's internal components, a short circuit may occur due to electrical contact between the components. The components that function as the positive and negative terminals of the battery may be kept in an insulated state by electrically insulating components. When such electrically insulating components are damaged in a high-temperature environment, the positive and negative terminals may come into direct electrical contact with each other, which may greatly diffuse the thermal event.
[0009] Therefore, it is necessary to ensure the safety of the battery by configuring the battery so that the electrical insulating components are not damaged even if an abnormality occurs during the use of the battery and the internal components of the battery are exposed to a high-temperature environment. Summary of the Invention [Problem to be solved by the invention]
[0010] The present invention has been made in consideration of the above problems, and has an object to easily maintain electrical insulation between battery terminals having mutually opposite polarities and a battery housing even in a high-temperature environment.
[0011] However, the technical problems that the present invention aims to solve are not limited to the problems described above, and other problems not mentioned will be clearly understood by those skilled in the art from the description of the invention below. [Means for solving the problem]
[0012] In order to achieve the above object, a battery according to one embodiment of the present invention includes an electrode assembly, a battery housing configured to receive the electrode assembly from an opening provided on one side, a terminal configured to electrically connect to the electrode assembly through a closing portion provided on an opposite side of the opening of the battery housing, a gasket interposed between the terminal and the battery housing, and a cover member configured to cover the gasket in an area where the gasket and the electrode assembly face each other.
[0013] The gasket may include an exposed area that is exposed outside the terminals within the battery housing.
[0014] The cover member may cover the exposed region of the gasket so that the exposed region is not exposed in a direction toward the electrode assembly.
[0015] The battery may include an insulator interposed between the electrode assembly and the closure of the battery housing.
[0016] The insulator may include an insulator hole having an inner diameter that is the same as or smaller than an outer diameter of the combination of the terminal and the gasket.
[0017] The cover member may be formed integrally with the insulator.
[0018] The cover member may be disposed within a space formed inside the insulator hole along a radial direction of the battery.
[0019] The cover member may be disposed between the insulator and the electrode assembly.
[0020] The cover member may include a cover member hole having a smaller diameter than the insulator hole.
[0021] The battery may include a current collector disposed between the electrode assembly and an inner surface of the closure portion of the battery housing and electrically coupled to the electrode assembly and the terminal.
[0022] The cover member may be formed integrally with the current collector.
[0023] The terminal may include a coupling portion configured to couple with the current collector, and the cover member may be configured to extend outside the coupling portion to cover the gasket.
[0024] A battery pack according to an embodiment of the present invention may include the battery.
[0025] A vehicle according to an embodiment of the present invention may include the battery pack. Effect of the Invention
[0026] According to one aspect of the present invention, electrical insulation between the battery housing and the battery terminals of opposite polarity is easily maintained even in high temperature environments.
[0027] However, the effects derived from the present invention are not limited to the effects described above, and other effects of the present invention not mentioned will be clearly understood by those skilled in the art from the description of the invention described below.
[0028] The following drawings attached to this specification illustrate preferred embodiments of the present invention and, together with the detailed description of the invention, serve to further understand the technical ideas of the present invention. Therefore, the present invention should not be interpreted as being limited to only the matters described in the drawings. [Brief description of the drawings]
[0029] [Figure 1] FIG. 2 is a diagram showing the structure of a lower portion of a battery according to an embodiment of the present invention. [Diagram 2]FIG. 2 is a partially enlarged view showing only some components of the battery shown in FIG. [Diagram 3] FIG. 3 is a diagram showing a lower structure of a battery according to an embodiment of the present invention, illustrating an embodiment different from the battery shown in FIGS. [Figure 4] FIG. 4 is a partially enlarged view showing only some components of the battery shown in FIG. 3. [Diagram 5] FIG. 5 is a diagram showing a lower structure of a battery according to an embodiment of the present invention, illustrating an embodiment different from the battery shown in FIGS. [Figure 6] FIG. 6 is a partially enlarged view showing only some components of the battery shown in FIG. 5. [Figure 7] FIG. 7 is a diagram showing a lower structure of a battery according to an embodiment of the present invention, illustrating an embodiment different from the battery shown in FIGS. [Figure 8] FIG. 8 is a partial enlarged view showing only some components of the battery shown in FIG. 7. [Figure 9] FIG. 9 is a diagram showing a lower structure of a battery according to an embodiment of the present invention, illustrating an embodiment different from the battery shown in FIGS. [Figure 10] 10 is a partially enlarged view showing only some components of the battery shown in FIG. 9. [Figure 11] FIG. 11 is a diagram showing a lower structure of a battery according to an embodiment of the present invention, illustrating an embodiment different from the battery shown in FIGS. [Figure 12] FIG. 12 is a partially enlarged view showing only some components of the battery shown in FIG. [Figure 13] 1A-1C show exemplary structures of current collectors of the present invention. [Figure 14] FIG. 2 is a diagram showing the structure of the upper portion of a battery according to an embodiment of the present invention. [Figure 15] FIG. 1 illustrates a battery pack according to an embodiment of the present invention. [Figure 16] FIG. 1 shows a vehicle according to an embodiment of the present invention. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0030] Hereinafter, a preferred embodiment of the present invention will be described in detail with reference to the attached drawings. Prior to this, the terms and words used in this specification and claims should not be interpreted as being limited to their ordinary or dictionary meanings, but should be interpreted as being in accordance with the meaning and concept of the technical idea of the present invention, in accordance with the principle that the inventor himself can appropriately define the concept of the term in order to best describe the invention. Therefore, it should be understood that the embodiment described in this specification and the configuration shown in the drawings are only one most preferred embodiment of the present invention, and do not represent the entire technical idea of the present invention, and therefore there may be various equivalents and modifications that can be substituted for them at the time of this application.
[0031] 1 and 2, a battery 1 according to an embodiment of the present invention may include an electrode assembly 10, a battery housing 20, a terminal 30, a gasket 40, and a cover member 50. The battery 1 may be a secondary battery. The battery 1 may be a cylindrical battery.
[0032] The electrode assembly 10 may include a positive electrode, a negative electrode, and a separator interposed between the positive electrode and the negative electrode. The electrode assembly 10 may be, for example, a jelly roll type electrode assembly formed by winding up a laminate including the positive electrode, the negative electrode, and the separator.
[0033] The battery housing 20 may be configured to receive the electrode assembly 10 through an opening formed on one side thereof. The battery housing 20 may include a conductive metal. The battery housing 20 may be electrically connected to the electrode assembly 10.
[0034] An electrolyte may be housed in the battery housing 20 together with the electrode assembly 10. The terminal 30 may be configured to be exposed to the outside of the battery housing 20 through a closed portion provided on the opposite side of the open portion of the battery housing 20. The terminal 30 may be electrically connected to, for example, the first non-coated portion 11 of the electrode assembly 10.
[0035] The terminal 30 may include an exposed portion 31, a coupling portion 32, and a flange portion 33. The exposed portion 31 may be exposed to the outside of the battery housing 20. The exposed portion 31 may be configured to have a diameter (or width) larger than a hole formed in the closed portion of the battery housing 20 for the insertion of the terminal 30. The coupling portion 32 may be configured to be electrically coupled to the electrode assembly 10 in the battery housing 20. The coupling portion 32 may be provided at a position corresponding to a winding center hole formed in the core of the electrode assembly 10, for example. The flange portion 33 may be provided on the outside of the coupling portion 32 and configured to extend in a direction toward the closed portion of the battery housing 20. The flange portion 33 may be riveted to have a shape bent from the outer periphery of the coupling portion 32 toward the inner surface of the closed portion of the battery housing 20. Due to such shape deformation of the flange portion 33, the terminal 30 may be fixed on the inner surface of the closed portion of the battery housing 20.
[0036] The gasket 40 may be interposed between the terminal 30 and the battery housing 20. The gasket 40 may include an electrically insulating material. The terminal 30 and the battery housing 20 may have opposite polarities, in which case the gasket 40 may be configured to prevent a short circuit due to contact between the terminal 30 and the battery housing 20. The gasket 40 may include a material that is electrically insulating and chemically resistant to an electrolyte.
[0037] The gasket 40 may be deformed together with the terminal 30 during riveting inside the battery housing 20. The gasket 40 may be interposed between the inner surface of the closed part of the battery housing 20 and the terminal 30 by such deformation.
[0038] The gasket 40 may include a first portion 41 and a second portion 42. The first portion 41 may be interposed between the exposed portion 31 of the terminal 30 and an outer surface of the closed portion of the battery housing 20. The second portion 42 may be interposed between the flange portion 33 and an inner surface of the closed portion of the battery housing 20. The gasket 40 may include an exposed region exposed to the outside of the terminal 30 inside the battery housing 20. For example, the second portion 42 of the gasket 40 may be at least partially exposed to the outside of the flange portion 33 of the terminal 30.
[0039] The cover member 50 may cover an exposed region of the gasket 40 exposed outside the terminal 30 inside the battery housing 20 so that the exposed region is not exposed in a direction toward the electrode assembly 10. The cover member 50 may be configured to cover the gasket 40 in a region where the gasket 40 and the electrode assembly 10 face each other.
[0040] The cover member 50 may include a material having a higher melting point than the gasket 40. The cover member 50 may include, for example, a flame-retardant material. The cover member 50 may include, for example, glass fiber. The cover member 50 may further include at least one material selected from the group including polypropylene (PP), polybutylene terephthalate (PBT), and polyphenylene sulfide (PPS), and a flame-retardant material and / or glass fiber. In this case, the amount of the flame-retardant material and / or glass fiber added may be about 30 wt% or less. However, this does not limit the material of the cover member 50, and the cover member 50 may include a metal if the cover member 50 is disposed so as not to contact the inner surface of the closing part of the housing 20. In this case, the melting point of the cover member 50 can be increased, thereby improving the protective function of the gasket 40 provided by the cover member 50.
[0041] The battery 1 according to an embodiment of the present invention may be configured such that the portion of the gasket 40 extending outward from the terminal 30 inside the battery housing 20 is not exposed in a direction toward the electrode assembly 10. Therefore, even if an abnormally high temperature environment occurs inside the battery 1 due to the occurrence of a thermal event, it is possible to prevent melting of the gasket 40, which prevents contact between the terminal 30 and the battery housing 20, which are configured to have opposite polarities.
[0042] 3 and 4, unlike those shown in Fig. 1 and 2, the cover member 50 is configured to partially fill the space between the inner surface of the closed part of the housing 20 and the electrode assembly 10. If the battery 1 includes a current collector 60 (first current collector) described below, the cover member 50 may be interposed between the inner surface of the closed part of the housing 20 and the current collector 60. The current collector 60 will be described in detail later.
[0043] The cover member 50 may be configured not only to cover the end of the second portion 42 of the gasket 40 in this manner, but also to function as a spacer between the inner surface of the closed portion of the housing 20 and the electrode assembly 10. In this case, the cover member 50 may include an insulating material. In this case, electrical insulation between the housing 20 and the terminal 30 and / or electrical insulation between the first electrode of the electrode assembly 10 and the housing 20 may be ensured.
[0044] 5 and 6, the battery 1 may include an insulator 70. The insulator 70 may be interposed between the electrode assembly 10 and the closure of the housing 20. The insulator 70 may include an electrically insulating material. The insulator 70 may have an insulator hole having an inner diameter equal to or smaller than an outer diameter of the combination of the terminal 30 and the gasket 40. The terminal 30 may be exposed toward the electrode assembly 10 from the insulator hole.
[0045] In the case where the battery 1 includes the insulator 70 in this manner, the cover member 50 may be formed integrally with the insulator 70. The cover member 50 may be configured to have a thickness thinner than that of the insulator 70. The cover member 50 may be configured to extend from the inner circumferential surface of the insulator 70 in a direction toward the center along the radial direction of the battery 1, and to cover the exposed area of the gasket 40 (the area exposed to the outside of the terminal 30).
[0046] When the cover member 50 is formed integrally with the insulator 70 in this manner, it is possible to achieve both insulation between the electrode assembly 10 and the inner surface of the housing 20 and protection of the gasket 40 exposed to the outside of the terminal 30 with a single part.
[0047] 7 to 10, the cover member 50 may be provided as a separate part from the insulator 70. As shown in FIG.
[0048] 7 and 8, the cover member 50 may be disposed, for example, in a space formed inside an insulator hole along the radial direction of the battery 1. In this case, the cover member 50 may include an insulating material.
[0049] The cover member 50 may be configured to fill at least a portion of the space remaining after being filled by the insulator 70 in the space between the electrode assembly 10 and the inner surface of the closed part of the housing 20. The cover member 50 may have a thickness corresponding to the distance between the electrode assembly 10 and the inner surface of the closed part of the housing 20. The cover member 50 may have a cover member hole having a smaller diameter than the insulator hole. The terminal 30 may be exposed to the electrode assembly 10 side through the cover member hole.
[0050] 9 and 10, the cover member 50 may be disposed between the insulator 70 and the electrode assembly 10. In this case, the cover member 50 may include an insulating material or may include a metal. When the cover member 50 includes a metal, the melting point of the cover member 50 can be sufficiently increased, and thus the gasket 40 can be more effectively protected from a high-temperature environment.
[0051] 11 and 12, the battery 1 may include a current collector (first current collector) 60. The current collector 60 may also be provided in the battery 1 shown in FIGS. 1 to 10. The current collector 60 may be disposed between the electrode assembly 10 and the inner surface of the closing part of the battery housing 20. The current collector 60 may be configured to electrically connect between the first electrode of the electrode assembly 10 and the terminal 30.
[0052] The current collector 60 may be electrically coupled to the electrode assembly 10 and the terminal 30. The current collector 60 may be coupled to a first non-coated portion 11 of the electrode assembly 10. The first electrode of the electrode assembly 10 may have a first non-coated portion 11 extending in the winding direction at one end thereof. Thus, the first non-coated portion 11 may be provided on one surface of the electrode assembly 10. The first non-coated portion 11 may extend downward of the electrode assembly 10, for example.
[0053] When the battery 1 includes the current collector 60 in this manner, the cover member 50 may be formed integrally with the current collector 60. In this case, the gasket 40 can be protected from a high-temperature environment by applying the current collector 60 without applying a separate part for protecting the gasket 40. When the cover member 50 is formed integrally with the current collector 60, the cover member 50 may include a metal, and thus the melting point of the cover member 50 may be formed to be sufficiently high. Therefore, the gasket 40 can be more effectively protected from a high-temperature environment.
[0054] As described above, the terminal 30 may include the coupling portion 32 configured to couple with the current collector 60. In this case, the cover member 50 may be configured to extend outside the coupling portion 32 to cover the gasket 40 exposed to the outside of the terminal 30.
[0055] Meanwhile, referring to FIG. 13 together with FIG. 11 and FIG. 12, the current collector 60 may include a first coupling portion 61 and a second coupling portion 62. The first coupling portion 61 may be configured to be electrically coupled to the terminal 30. The second coupling portion 62 may be configured to be electrically coupled to the electrode assembly 10. The first coupling portion 61 and the second coupling portion 62 may be spaced apart from each other along a radial direction of the battery 1. The current collector 60 may include a connection portion 63 configured to electrically connect the first coupling portion 61 and the second coupling portion 62. The connection portion 63 may be substantially in the form of a rim. The first coupling portion 61 may extend inward from the connection portion 63. The current collector 60 may include a bridge 64 configured to connect the connection portion 63 and the first coupling portion 61. The bridge 64 may extend inward from the connection portion 63. The first coupling portion 61 may be located approximately at the center inside the connection portion 63. The first coupling portion 61 may be provided at a position corresponding to a winding center hole formed in the core of the electrode assembly 10 .
[0056] As described above, in the battery 1 according to the embodiment of the present invention, the first coupling part 61 and the second coupling part 62 are spaced apart from each other along the radial direction of the battery 1, and the gasket 40 exposed to the outside of the terminal 30 may be exposed to the electrode assembly 10 side due to a space formed between the first coupling part 61 and the second coupling part 62. Therefore, even if the current collector 60 is provided, there is a risk that the gasket 40 may be damaged by high-temperature gas and / or flame generated from the electrode assembly 10. Therefore, when a cover member 50 formed integrally with the current collector 60 and configured to cover the exposed area of the gasket 40 is provided, the risk of such damage to the gasket 40 can be eliminated or significantly reduced.
[0057] When the cover member 50 is formed integrally with the current collector 60 in this manner, the cover member 50 may extend from the first connection portion 61 in a direction toward the outside of the battery 1, or may extend from the second connection portion 62 in a direction toward the inside of the battery 1.
[0058] On the other hand, the battery 1 shown in Figures 1 to 10 can also be provided with a current collector 60, and in this case, a cover member 50 can be provided at a position corresponding to the space between the first connecting portion 61 and the second connecting portion 62 of the current collector 60.
[0059] 14, the battery 1 according to an embodiment of the present invention may include a cap 80. The cap 80 may be configured to cover an opening formed on one side of the battery housing 20. The cap 80 may include a metal.
[0060] The cap 80 may include a vent portion. The vent portion may be an area of the cap 80 that is weaker than other areas around the cap 80. The vent portion may be, for example, an area having a smaller thickness compared to the remaining area. The vent portion may be, for example, an area in which one or both sides of the cap 80 are notched. The vent portion may have a shape that extends to describe a closed loop surrounding the center of the cap 80. The vent portion may be formed continuously or discontinuously.
[0061] In this manner, when the battery 1 according to the embodiment of the present invention has a vent, the internal pressure of the battery 1 can be prevented from increasing above a certain level even if an abnormality occurs in the battery 1. However, even if such a vent is formed, the internal gas and / or flame cannot escape to the closed side of the battery housing 20, and as a result, the gasket 40 may be exposed to a high-temperature environment. Therefore, it is necessary to apply the cover member 50 as described above to the closed side of the battery housing 20.
[0062] The battery 1 may include a current collector (second current collector) 90. The current collector 90 may be configured to electrically connect the second electrode of the electrode assembly 10 to the battery housing 20. The current collector 90 may be disposed on one surface of the electrode assembly 10. The current collector 90 may be electrically connected to a second non-coated portion 12 of the electrode assembly 10. The second electrode of the electrode assembly 10 may include a second non-coated portion 12 extending along the winding direction at one end thereof. Thus, the second non-coated portion 12 may be provided on one surface of the electrode assembly 10. The second non-coated portion 12 may extend, for example, upwardly of the electrode assembly 10.
[0063] The battery 1 may include a sealing member G interposed between the cap 80 and the inner surface of the battery housing 20. If the sealing member G is included, a current collector 90 may be interposed between the sealing member G and the inner surface of the battery housing 20.
[0064] 15 , a battery pack 3 according to an embodiment of the present invention may include at least one battery 1 according to the embodiment of the present invention as described above. The battery 1 may be accommodated in a pack housing 2. The battery pack 3 may include components for electrical connection of the battery 1 and / or a Battery management system (BMS) configured to control charging and discharging of the battery 1.
[0065] 16, a vehicle 5 according to an embodiment of the present invention includes at least one battery pack 3. The vehicle 5 may be configured to operate by receiving power from the battery pack 3. The vehicle 5 may be, for example, a hybrid electric vehicle (HEV) or an electric vehicle (EV).
[0066] Although the present invention has been described above with reference to limited embodiments and drawings, the present invention is not limited thereto, and it is of course possible for a person having ordinary skill in the art to which the present invention pertains to make various modifications and variations within the technical spirit of the present invention and the equivalent scope of the following claims. [Explanation of symbols]
[0067] 1 Battery 2 Pack Housing 3 Battery pack 5. Automobiles 10 Electrode assembly 11 First non-coating section 12 Second non-coating section 20 Battery Housing 30 Terminals 31 Exposed part 32 Joint 33 Flange section 40 Gasket 41 Part 1 42 Part 2 50 Cover member 60 Current collector (first current collector) 61 1st joint 62 2nd joint 63 Connection 64 Bridge 70 Insulator 80 Cap 90 Current collector (second current collector) G Sealing member
Claims
1. An electrode assembly; a battery housing that receives the electrode assembly through an opening provided on one side thereof; a terminal electrically connected to the electrode assembly through a closed portion provided on the opposite side of the open portion of the battery housing; a gasket interposed between the terminal and the battery housing; a cover member that covers the gasket in an area where the gasket and the electrode assembly face each other.
2. 2. The battery of claim 1, wherein the gasket includes an exposed area that is exposed inside the battery housing and outside the terminals.
3. The battery according to claim 2 , wherein the cover member covers the exposed area of the gasket so that the exposed area is not exposed in a direction toward the electrode assembly.
4. 4. The battery according to claim 1, further comprising an insulator interposed between the electrode assembly and the closure of the battery housing.
5. The insulator is 5. The battery according to claim 4, further comprising an insulator hole having an inner diameter equal to or smaller than an outer diameter of the combination of the terminal and the gasket.
6. 5. The battery according to claim 4, wherein the cover member is integrally formed with the insulator.
7. 6. The battery according to claim 5, wherein the cover member is disposed within a space formed inside the insulator hole along a radial direction of the battery.
8. 5. The battery according to claim 4, wherein the cover member is disposed between the insulator and the electrode assembly.
9. 6. The battery of claim 5, wherein the cover member includes a cover member hole having a diameter smaller than the insulator hole.
10. The battery comprises:
4. The battery of claim 1, further comprising a current collector disposed between the electrode assembly and an inner surface of the closure of the battery housing, the current collector being electrically coupled to the electrode assembly and the terminal.
11. 11. The battery of claim 10, wherein the cover member is integrally formed with the current collector.
12. the terminal has a coupling portion coupled to the current collector, The battery of claim 11 , wherein the cover member extends outside the joint to cover the gasket.
13. A battery pack comprising the battery according to any one of claims 1 to 3.
14. A motor vehicle comprising the battery pack of claim 13.
Citation Information
Patent Citations
Single-head double-pole multi-lug cylindrical lithium ion battery
CN112909445A
Cylindrical battery, battery module and battery pack
CN113346201A
Cylindrical lithium ion battery and battery module thereof
CN216389535U
Rechargeable battery having cathode assembly packaging
CN2681364Y
Battery from which a plurality of output voltages can be taken out
JP1999135151A