Method for producing hexafluoropropene and composition

By preheating trifluoromethane and controlling reaction conditions, the method suppresses the formation of octafluorocyclobutane during hexafluoropropene production, improving the selectivity and reducing by-products in the hexafluoropropene synthesis process.

JP2026092583APending Publication Date: 2026-06-05AGC INC
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Patent Information

Application Number
JP2024205765
Authority / Receiving Office
JP · JP
Patent Type
Applications
Current Assignee / Owner
Filing Date
2024-11-26
Publication Date
2026-06-05

AI Technical Summary

Technical Problem

The production of hexafluoropropene (HFP) through the thermal decomposition of trifluoromethane (R23) and tetrafluoroethylene (TFE) often results in the formation of octafluorocyclobutane (C318), a compound with high global warming potential, which needs to be minimized.

Method used

A method involving preheating trifluoromethane to 350-700°C, mixing it with a second preheating heat transfer medium at a higher temperature, and reacting it with tetrafluoroethylene at 800-1000°C for a brief duration, while controlling the reactor pressure and using specific ratios and heat transfer mediums to suppress the formation of C318.

Benefits of technology

The method effectively reduces the production of octafluorocyclobutane, enhancing the selectivity of hexafluoropropene production and minimizing the generation of other by-products like hydrogen fluoride adducts and perfluoroisobutene.

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Abstract

To provide a method for producing hexafluoropropene in which the formation of octafluorocyclobutane, a by-product, is suppressed, and a composition obtained by the said production method. [Solution] A method for producing hexafluoropropene, comprising preheating trifluoromethane at a first preheating temperature of 350 to 700°C, then contacting it with tetrafluoroethylene to obtain a product containing hexafluoropropene.
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