Conductive roll, transfer device, process cartridge, and image forming apparatus

Abstract

To provide a conductive roll that easily increases the parallelism of an image transferred to a recording medium.SOLUTION: A conductive roll has a support member, an elastic layer arranged on an outer peripheral surface of the support member, a surface layer arranged on an outer peripheral surface of the elastic layer, and an intermediate layer arranged between the elastic layer and the surface layer and having a Poisson ratio of 0.40 or less.SELECTED DRAWING: Figure 3

Description

[Technical field]

[0001] The present invention relates to a conductive roll, a transfer device, a process cartridge, and an image forming apparatus. [Background technology]

[0002] Patent Document 1 proposes a transfer roll having "a conductive support, a conductive elastic layer provided on the conductive support, and a conductive resin layer provided on the conductive elastic layer and containing a resin material and a conductive agent, the conductive resin layer having a first region forming an outermost surface, and a second region provided between the first region and the conductive elastic layer in contact with the conductive elastic layer and having a surface resistivity lower than that of the first region, wherein a nip is formed so that a bite amount gradient exists in the axial direction, and when a recording medium is inserted into the nip, the difference between the transport amount at a portion where the bite amount is 0.5 mm and the transport amount at a portion where the bite amount is 1.3 mm is 1.5 mm or more / 400 mm." Patent Document 2 describes a toner supply roll for electrophotographic equipment, comprising a shaft and a roll-shaped polyurethane foam formed on the outer periphery of the shaft, the polyurethane foam having a storage modulus of 100 kPa or more, having surface cells and central cells which communicate with each other, the central cells having an average cell diameter of 200 to 1000 μm, and a relationship between a curved surface pressure contact nip width, which is a nip width when the polyurethane foam is in pressure contact with a curved surface, and a flat surface pressure contact nip width, which is a nip width when the polyurethane foam is in pressure contact with a flat surface, satisfies the following formula (1): It has been proposed that the curved surface pressure nip width should be equal to or greater than (flat surface pressure nip width × 0.65) (1). [Prior art documents] [Patent documents]

[0003] [Patent Document 1] JP 2014-126602 A [Patent Document 2] JP 2014-071147 A Summary of the Invention [Problem to be solved by the invention]

[0004] The objective of the present invention is to provide a conductive roll having a support member, an elastic layer arranged on the outer peripheral surface of the support member, a surface layer arranged on the outer peripheral surface of the elastic layer, and an intermediate layer arranged between the elastic layer and the surface layer, which makes it easier to increase the parallelism of an image transferred to a recording medium compared to when the Poisson's ratio of the intermediate layer exceeds 0.40. [Means for solving the problem]

[0005] Specific means for solving the above problems include the following aspects.

[0006] <1> A support member; an elastic layer disposed on an outer circumferential surface of the support member; a surface layer disposed on an outer peripheral surface of the elastic layer; an intermediate layer disposed between the elastic layer and the surface layer, the intermediate layer having a Poisson's ratio of 0.40 or less; A conductive roll having a <2> a thickness Td of the elastic layer, a thickness Tm of the intermediate layer, and a thickness Ts of the surface layer satisfy the relationship Td>Tm>Ts; <1> The conductive roll according to claim 1. <3> a thickness Td of the elastic layer, a thickness Tm of the intermediate layer, and a thickness Ts of the surface layer satisfy the relationship: 0.07≦Tm / (Td+Tm+Ts)≦0.43 <2> The conductive roll according to claim 1. <4> The thickness Tm of the intermediate layer is 0.5 mm or more and 4 mm or less. <2> or <3> The conductive roll according to claim 1. <5> The thickness Ts of the surface layer is 10 μm or more and 50 μm or less. <2> ~ <4> 13. The conductive roll according to claim 12. <6> The Young's modulus Ys of the surface layer is 10 MPa or more and 400 MPa or less. <1> ~ <5> 13. The conductive roll according to claim 12. <7> The elastic layer includes a cylindrical elastic foam and a conductive coating layer that covers an exposed surface of the elastic foam. <1> ~ <6> 13. The conductive roll according to claim 12. <8> The elastic foam has an open cell structure. <7> The conductive roll according to claim 1. <9> The density of the elastic foam is 50 kg / m 3 More than 90kg / m 3 Is less than or equal to <7> or <8> The conductive roll according to claim 1. <10> <1> ~ <9> 2. A transfer device comprising the conductive roll according to claim 1 . <11> Image carrier and <10> and a transfer device according to claim 1, wherein the process cartridge is detachably mounted on an image forming apparatus. <12> An image carrier; a charging device for charging the surface of the image carrier; an electrostatic latent image forming device for forming an electrostatic latent image on a charged surface of the image carrier; a developing device for developing the electrostatic latent image formed on the surface of the image carrier with a developer containing a toner to form a toner image; The toner image is transferred onto a surface of a recording medium. <10> A transfer device according to the present invention; An image forming apparatus comprising: Effect of the Invention

[0007] <1> According to the invention, there is provided a conductive roll having a support member, an elastic layer arranged on the outer peripheral surface of the support member, a surface layer arranged on the outer peripheral surface of the elastic layer, and an intermediate layer arranged between the elastic layer and the surface layer, which makes it easier to increase the parallelism of an image transferred to a recording medium compared to when the intermediate layer has a Poisson's ratio of more than 0.40.

[0008] <2> According to the present invention, there is provided a conductive roll which makes it easier to improve the parallelism of an image transferred to a recording medium, compared to a case where the relationship Td>Tm>Ts is not satisfied. <3> According to the invention relating to the above, there is provided a conductive roll which makes it easier to improve the parallelism of an image transferred to a recording medium, as compared with the case where 0.07>Tm / (Td+Tm+Ts) is satisfied. <4> According to the present invention, there is provided a conductive roll which can easily improve the parallelism of an image transferred to a recording medium, as compared with a case in which the thickness Tm of the intermediate layer is less than 0.5 mm or exceeds 4 mm.

[0009] <5> According to the present invention, a conductive roll having excellent cleaning properties is provided, as compared with a case in which the thickness Ts of the surface layer is less than 10 μm or exceeds 50 μm. <6> According to the present invention, a conductive roll having excellent cleaning properties is provided, as compared with a case in which the Young's modulus Ys of the surface layer is less than 10 MPa or exceeds 400 MPa.

[0010] <7> According to the present invention, a conductive roll is provided that can easily improve the parallelism of an image transferred to a recording medium, compared to a case in which the elastic layer is made of a cylindrical elastic foam into which a conductive agent is kneaded. <8> According to the present invention, there is provided a conductive roll which can easily improve the parallelism of an image transferred onto a recording medium, as compared with a case in which the elastic foam has a closed cell structure. <9> According to the invention, the density of the elastic foam is 50 kg / m 3 Less than or equal to 90kg / m 3 In comparison with the case where the thickness exceeds this range, a conductive roll is provided which can easily improve the parallelism of an image transferred onto a recording medium.

[0011] <10> , <11> or <12> According to the invention, there is provided a transfer device, a process cartridge, or an image forming apparatus equipped with a conductive roll having a support member, an elastic layer arranged on the outer peripheral surface of the support member, a surface layer arranged on the outer peripheral surface of the elastic layer, and an intermediate layer arranged between the elastic layer and the surface layer, which is more likely to increase the parallelism of an image transferred to a recording medium than when the Poisson's ratio of the intermediate layer is more than 0.40. [Brief description of the drawings]

[0012] [Figure 1] 5 is a schematic diagram for explaining the parallelism of an image transferred onto a recording medium. FIG. [Diagram 2] FIG. 2 is a schematic perspective view illustrating an example of a conductive roller according to the present embodiment. [Diagram 3] FIG. 3 is a schematic cross-sectional view showing an example of a conductive roller according to the present embodiment, and is a cross-sectional view taken along the line AA in FIG. [Figure 4] 1 is a schematic configuration diagram illustrating an example of an image forming apparatus according to an embodiment of the present invention. [Diagram 5] FIG. 4 is a schematic configuration diagram illustrating another example of an image forming apparatus according to the present embodiment. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0013] Hereinafter, embodiments of the present disclosure will be described. These descriptions and examples are merely illustrative of the embodiments, and are not intended to limit the scope of the embodiments.

[0014] In the present disclosure, a numerical range indicated using "~" indicates a range that includes the numerical values ​​before and after "~" as the minimum and maximum values, respectively.

[0015] In the numerical ranges described in the present disclosure in stages, the upper or lower limit value described in one numerical range may be replaced with the upper or lower limit value of another numerical range described in stages. In addition, in the numerical ranges described in the present disclosure, the upper or lower limit value of the numerical range may be replaced with a value shown in the examples.

[0016] In the present disclosure, the term "step" includes not only an independent step, but also a step that cannot be clearly distinguished from other steps, as long as the intended purpose of the step is achieved.

[0017] When an embodiment of the present disclosure is described with reference to the drawings, the configuration of the embodiment is not limited to the configuration shown in the drawings. In addition, the size of the members in each drawing is conceptual, and the relative relationship between the sizes of the members is not limited to this.

[0018] In the present disclosure, each component may contain multiple types of corresponding substances. When referring to the amount of each component in a composition in the present disclosure, if multiple substances corresponding to each component are present in the composition, the total amount of the multiple substances present in the composition is meant unless otherwise specified.

[0019] <Conductive roll> The conductive roll according to this embodiment includes a support member, an elastic layer disposed on an outer peripheral surface of the support member, a surface layer disposed on an outer peripheral surface of the elastic layer, and an intermediate layer disposed between the elastic layer and the surface layer, the intermediate layer having a Poisson's ratio of 0.40 or less.

[0020] The conductive roll according to the present embodiment is not particularly limited in its application, so long as it is a conductive roll used for pressing its outer peripheral surface against an opposing roll, forming an insertion part through which a recording medium passes, and transferring an image to the recording medium at the insertion part. In other words, the conductive roll according to the present embodiment is used for pressing its outer peripheral surface against an opposing roll, inserting the recording medium through the pressing region as the insertion part, and transferring an image to the recording medium at the insertion part. The conductive roll according to the present embodiment is preferably used as a transfer roll in an electrophotographic image forming apparatus, for example. However, the applications of the conductive roll according to the present embodiment are not limited to those mentioned above, and examples thereof include a peeling roll, a backup roll, and a tension roll.

[0021] The conductive roll according to the present embodiment, with the above-mentioned configuration, is likely to improve the parallelism of the image transferred onto the recording medium. The reason for this is presumed to be as follows.

[0022] When the outer peripheral surface of a conductive roll is pressed against an opposing roll to form an insertion portion through which a recording medium passes, and an image is transferred to the recording medium at the insertion portion, the parallelism of the image transferred to the recording medium may decrease. Here, the parallelism of the transferred image means the degree of parallelism of the image in the direction perpendicular to the conveying direction of the recording medium P in the insertion portion (the direction of the arrow Y in Figs. 1(a) and (b)). Specifically, the parallelism of the transferred image means, for example, the degree of parallelism of the image in the direction perpendicular to the conveying direction of the recording medium P in the insertion portion (the direction of the arrow X in Figs. 1(a) and (b)). In particular, when a rectangular image G1 consisting of sides parallel to each side of the recording medium P is to be formed on the recording medium P as shown in Fig. 1(a), the parallelism of the transferred image means the degree of parallelism of the line image length L at one end side in the direction of the arrow X (indicated as Front in Fig. 1) as shown in Fig. 1(b) that is actually generated in the image G2 transferred onto the recording medium P. Front and the line image length L at the other end (referred to as Rear in Fig. 1). Rear The difference between ΔL (=L Front -L Rear ) as shown.

[0023] As a method for correcting the above ΔL, there is a method in which the amount of pressure of the conductive roll against the opposing roll is adjusted at both ends in the axial direction of the conductive roll, thereby making a difference in the amount of transport of the recording medium in a direction perpendicular to the transport direction of the recording medium.

[0024] Therefore, in the conductive roll, the intermediate layer disposed between the elastic layer and the surface layer has a Poisson's ratio of 0.40 or less to make it easy to deform. By making the intermediate layer easy to deform, the amount of pressing of the conductive roll against the opposing roll can be increased, and it becomes easy to adjust at both ends in the axial direction of the conductive roll.

[0025] Therefore, it is presumed that the conductive roll according to this embodiment can easily improve the parallelism of an image transferred onto a recording medium.

[0026] In the conductive roll according to this embodiment, from the viewpoint of easily increasing the parallelism of an image transferred to a recording medium, the Poisson's ratio of the intermediate layer is preferably 0.4 or less, and more preferably 0.38 or less. However, if the Poisson's ratio of the intermediate layer is too low, the compressive deformation of the intermediate layer becomes large, and the effect of controlling the paper passing speed becomes small. From this viewpoint, it is preferable that the Poisson's ratio is 0.3 or more.

[0027] Here, the Poisson's ratio is measured as follows. The composition of the intermediate layer of the target conductive roll is analyzed. A strip with the same composition as the analyzed intermediate layer, width 10 mm, thickness 1 mm, and gauge length 40 mm is prepared and attached to a tensile tester. The width of the strip is measured with a laser at a position 20 mm from the bottom of the gauge line, and the transverse strain εb is calculated from the strip width when it is pulled 30% at a tensile speed of 10 mm / min, and the longitudinal strain εL is calculated from the tensile direction, and the equation is εb / εL.

[0028] The conductive roller according to the present embodiment will be described with reference to the drawings. Fig. 2 is a schematic perspective view showing an example of a conductive roll according to the present embodiment, Fig. 3 is a cross-sectional view taken along line AA in Fig. 2, and is a cross-sectional view of the conductive roll shown in Fig. 2 cut in the radial direction.

[0029] 2, the conductive roll 100 is a roll member including a cylindrical support member 110 and a layered material 120 including an elastic layer, an intermediate layer, and a surface layer, which is disposed on the outer peripheral surface of the support member 110. Also, as shown in FIG. 3, the layer configuration of the conductive roll 100 includes an elastic layer 122 disposed on the outer peripheral surface of the cylindrical support member 110, an intermediate layer 124 disposed on the outer peripheral surface of the elastic layer 122, and a surface layer 126 disposed on the outer peripheral surface of the intermediate layer 124. The conductive roll according to this embodiment is not limited to the configuration shown in FIGS. 2 and 3, and may have, for example, an adhesive layer between the support member 110 and the elastic layer 122, between the elastic layer 122 and the intermediate layer 124, and between the intermediate layer 124 and the surface layer 126, as appropriate.

[0030] The materials of the layers constituting the conductive roll according to this embodiment will be described below.

[0031] [Support member] In the conductive roll according to this embodiment, the support member may be any member that functions as a support member for the conductive roll. The support member may be a hollow member (ie, a cylindrical member) or a solid member (ie, a columnar member). When an electric field is formed between the conductive roll and the opposing roll, the support member is preferably a conductive support member.

[0032] Examples of conductive support members include metal members such as iron (free-cutting steel, etc.), copper, brass, stainless steel, aluminum, nickel, etc.; resin members or ceramic members having plated outer surfaces; and resin members or ceramic members containing a conductive agent.

[0033] The outer diameter of the support member may be determined depending on the application of the conductive roll. For example, if the conductive roll according to this embodiment is a secondary transfer roll, the outer diameter of the support member is, for example, 3 mm or more and 30 mm or less.

[0034] [Elastic layer] The elastic layer contains, for example, an elastic material, a conductive agent, and, if necessary, other additives.

[0035] Examples of elastic materials include isoprene rubber, chloroprene rubber, epichlorohydrin rubber, butyl rubber, polyurethane, silicone rubber, fluororubber, styrene-butadiene rubber, butadiene rubber, nitrile rubber, ethylene propylene rubber, epichlorohydrin-ethylene oxide copolymer rubber, epichlorohydrin-ethylene oxide-allyl glycidyl ether terpolymer rubber, ethylene-propylene-diene terpolymer rubber (EPDM), acrylonitrile-butadiene copolymer rubber (NBR), natural rubber, and rubber mixtures of these.

[0036] Examples of the conductive agent include electronic conductive agents and ionic conductive agents. Examples of the electronic conductive agent include powders of carbon black such as ketjen black and acetylene black; pyrolytic carbon, graphite; various conductive metals or alloys such as aluminum, copper, nickel, and stainless steel; various conductive metal oxides such as tin oxide, indium oxide, titanium oxide, tin oxide-antimony oxide solid solution, and tin oxide-indium oxide solid solution; and insulating materials whose surfaces have been treated to be conductive. Examples of the ionic conductive agent include perchlorates and chlorates such as tetraethylammonium and lauryltrimethylammonium; and perchlorates and chlorates of alkali metals and alkaline earth metals such as lithium and magnesium. These conductive agents may be used alone or in combination of two or more kinds.

[0037] Other additives include known materials that can be added to elastomers, such as softeners, plasticizers, hardeners, vulcanizing agents, vulcanization accelerators, antioxidants, surfactants, coupling agents, and fillers (silica, calcium carbonate, etc.).

[0038] The elastic layer preferably includes a cylindrical elastic foam and a conductive coating layer that covers an exposed surface of the elastic foam. The elastic layer of such a configuration is given the desired electrical conductivity by the conductive coating layer, and a softer elastic layer is obtained compared to the case where a conductive agent is contained in an elastic foam. In this way, when the conductive roll is pressed into the opposing roll, the elastic layer also becomes more easily deformed, and therefore the conductive roll tends to be one that can more easily improve the parallelism of the image transferred to the recording medium.

[0039] (Elastic foam) The elastic foam constituting the elastic layer is a foam containing an elastic material (also called a rubber material).

[0040] As the elastic material, the above-mentioned materials are applied.

[0041] Examples of blowing agents for obtaining elastic foams include water; azo compounds such as azodicarbonamide, azobisisobutyronitrile, and diazoaminobenzene; benzenesulfonyl hydrazides such as benzenesulfonyl hydrazide, 4,4'-oxybisbenzenesulfonyl hydrazide, and toluenesulfonyl hydrazide; bicarbonates such as sodium hydrogen carbonate that generate carbon dioxide gas upon thermal decomposition; a mixture of NaNO2 and NH4Cl that generates nitrogen gas; and peroxides that generate oxygen. In order to obtain a foamed elastic layer, a foaming assistant, a foam stabilizer, a catalyst, etc. may be used as necessary.

[0042] The elastic foam may contain a conductive agent from the viewpoint of controlling the electrical conductivity of the elastic layer. The conductive agent contained in the elastic foam includes an electronic conductive agent and an ionic conductive agent. From the viewpoint of obtaining a conductive roll that can easily improve the parallelism of an image transferred to a recording medium, the content of the conductive agent (particularly when it is an electronic conductive agent) in the elastic foam is 1 mass % or less, preferably 0.5 mass % or less, and more preferably 0 mass % or less, relative to the total mass of the elastic foam. In other words, the less electronic conductive agent there is in the elastic foam, the better. Even if the elastic foam contains conductive particles, the content of the electronic conductive agent must be 1 mass % or less relative to the total mass of the elastic foam.

[0043] In addition, if the elastic foam contains particulate matter such as the electronic conductive agent, filler, etc., the hardness of the elastic layer increases and the releasability of the medium tends to decrease. Therefore, the less particulate matter there is in the elastic foam, the better, and even if the elastic foam contains particulate matter, the total content of the particulate matter is preferably 1% by mass or less relative to the total mass of the elastic foam.

[0044] It is more preferable that the cell structure in the elastic foam be an open cell structure from the viewpoint of formability of a conductive coating layer and from the viewpoint of providing a conductive roll that can easily improve the parallelism of an image transferred to a recording medium. Here, the open cell structure means a structure in which adjacent cells (that is, cells) are connected to each other, and a part of the connected cells is exposed (open) to the surface. Furthermore, the elastic foam preferably has a smaller closed cell ratio, and the closed cell ratio is preferably, for example, 50% or less (more preferably 30% or less).

[0045] The cell diameter (also referred to as air bubble diameter) of the elastic foam is preferably 50 μm or more and 1000 μm or less, more preferably 100 μm or more and 800 μm or less, and even more preferably 150 μm or more and 600 μm or less, from the viewpoint of the formability of the conductive coating layer and from the viewpoint of obtaining a conductive roll that can easily improve the parallelism of the image transferred to the recording medium.

[0046] The density of the elastic foam (also called the air bubble ratio) is set to 50 kg / m from the viewpoint of forming a conductive coating layer and from the viewpoint of obtaining a conductive roll which can easily improve the parallelism of an image transferred to a recording medium. 3 More than 90kg / m 3 It is preferable that the thickness is less than 55 kg / m 3 More than 85kg / m 3 More preferably, it is 60 kg / m or less. 3 More than 80kg / m 3 It is even more preferable that:

[0047] Here, the cell diameter (cell diameter), expansion rate (cell rate), and closed cell rate in the elastic foam are measured as follows. First, a cross section of the elastic layer (elastic foam in the elastic layer) in the thickness direction is prepared using a razor. A total of four cross sections are prepared in parallel to the axial direction of the conductive roll and at 90° intervals in the circumferential direction. The central part of the cross section in the axial direction is photographed with a laser microscope (Keyence, VK-X200) to obtain an image. The image is analyzed with image analysis software (Media Cybernetics, Image-Pro Plus) to measure the maximum diameter and area of ​​the cells (air bubbles). In addition, when the elastic foam has an open-cell structure, the continuous state of the cells (air bubbles) is inferred from the shape of the open cells, and each continuous (connected) cell is artificially separated and the maximum diameter of the separated cell is measured. In other words, if it is inferred that the open cells are in the shape of, for example, five connected cells, the five cells are artificially separated into five and the maximum diameter of the five separated cells is measured. The cell diameter is determined by calculating the arithmetic mean of the maximum diameters of 100 randomly selected cells in the analyzed cross-sectional image, and then calculating the arithmetic mean of the four cross-sections based on the obtained value. The foaming ratio is calculated by (total area of ​​cells in the analyzed cross-sectional images) / (total area of ​​the analyzed cross-sectional images)×100. The closed cell ratio is calculated by (total area of ​​closed cells in the analyzed cross-sectional images) / (total area of ​​cells in the analyzed cross-sectional images × 100). Here, an isolated bubble is defined as a bubble that is entirely surrounded by a wall in a cross-sectional image.

[0048] The density of the elastic foam is measured as follows. Using the elastic layer (elastic foam in the elastic layer), create a cube with a razor. The larger the cube is made, the more accurate the density measurement. Next, measure the length, width, and height of the cube, calculate the volume, measure the weight, and calculate the density by dividing the weight by the volume.

[0049] (Young's modulus of elastic layer) In the conductive roll according to this embodiment, from the viewpoint of providing a conductive roll that can easily improve the parallelism of an image transferred to a recording medium, the Young's modulus of the elastic layer is preferably 50 kPa or more and 500 kPa or less, more preferably 60 kPa or more and 300 kPa or less, and even more preferably 80 kPa or more and 150 kPa or less. The above Young's modulus can be easily achieved by reducing the content of particulate matter (eg, electronic conductive agent, filler, etc.) in the elastic foam.

[0050] The Young's modulus is measured as follows. The method for measuring Young's modulus basically complies with ISO527. The composition of the elastic layer from the subject conductive roll is analyzed. A dumbbell-shaped tensile test piece with a gauge length of 50 mm and a thickness of 5 mm was prepared in the form of a single-layer sheet with the same composition as the elastic layer being analyzed. A stress (σ) strain (ε) curve was obtained at a tensile speed of 5 mm / min using a benchtop precision universal testing machine (AGS-X; manufactured by Shimadzu Corporation). The stress at strains of 0.05% to 0.25% was measured, and the Young's modulus was calculated from Δσ / Δε.

[0051] - Formation of elastic foam - The method for forming the cylindrical elastic foam is not particularly limited, and any known method can be used. For example, a method includes preparing a composition containing an elastic material, a foaming agent, and other components (such as a vulcanizing agent) that are used as needed, extruding the composition into a cylindrical shape, and then heating the molded product to vulcanize and foam it, or cutting a cylindrical shape from a large foam. Alternatively, after forming a cylindrical elastic foam, a central hole for inserting a support member may be formed to obtain a cylindrical elastic foam. After the cylindrical elastic foam is obtained, the shape may be further adjusted, or post-treatment such as surface polishing may be carried out, if necessary.

[0052] (Conductive coating layer) The conductive coating layer that constitutes the elastic layer is a conductive layer that covers the exposed surface of the elastic foam (i.e., the surface of the elastic foam that comes into contact with the atmosphere, including the inner and outer surfaces and cell wall surfaces of the cylindrical elastic foam). The exposed surface of the elastic foam may be entirely or partially covered with a conductive coating layer.

[0053] The conductive coating layer is formed using a treatment liquid containing a conductive agent and a resin. Examples of the conductive agent used in the treatment liquid include electronic conductive agents and ionic conductive agents, and among these, electronic conductive agents are preferred. The conductive agent contained in the treatment liquid may be of one type or of two or more types. Here, examples of the electronic conductive agent are the same as those of the electronic conductive agent contained in the elastic foam, and preferred embodiments are also the same.

[0054] The resin used in the treatment liquid is not particularly limited as long as it is a resin capable of forming a coating layer on the exposed surface of the elastic foam, and examples thereof include acrylic resin, urethane resin, fluororesin, silicone resin, etc. These resins are preferably used as latex. Examples of the latex include the above-mentioned resin latexes, as well as natural rubber latex, butadiene rubber latex, acrylonitrile-butadiene rubber latex, acrylic rubber latex, polyurethane rubber latex, fluororubber latex, and silicone rubber latex.

[0055] The treatment liquid preferably contains a conductive agent, a resin, and water, that is, is an aqueous dispersion containing a conductive agent and a resin. The concentrations of the conductive agent and resin in the treatment liquid may be determined depending on the formability of the conductive coating layer, the resistance value required for the elastic layer, and the like.

[0056] - Formation of conductive coating layer - The conductive coating layer is formed by applying a treatment liquid to the elastic foam and drying it by heating. Methods for applying the treatment liquid to the elastic foam include a method of applying the treatment liquid to the elastic foam by spray coating or the like, and a method of immersing the elastic foam in the treatment liquid. By these methods, the treatment liquid is impregnated into the surface and the inside of the cells of the elastic foam. The applied treatment liquid is then dried by heating or the like to form a conductive coating layer.

[0057] As the conductive coating layer, for example, the coating layer and the method for forming the same described in JP-A-2009-244824 may be used.

[0058] As described above, the conductive coating layer is formed on the exposed surface of the elastic foam, thereby forming the elastic layer in the conductive roll according to the present embodiment.

[0059] (Volume resistance of elastic layer) In the conductive roll according to this embodiment, the volume resistance value of the elastic layer when a voltage of 10 V is applied is preferably 105Ω or less, more preferably 101Ω to 105Ω, and even more preferably 102Ω to 104Ω.

[0060] Here, the volume resistivity of the elastic layer is measured as follows. First, a roll member having an elastic layer to be measured on the outer periphery of a conductive support member is prepared, and the volume resistance value of the elastic layer is measured using the obtained roll member. In addition, when the conductive roll according to the present embodiment has a conductive support member, the roll member obtained by peeling off the surface layer from the conductive roll may be measured. The roll member is placed on a metal plate such as a copper plate with a load of 500 g applied to each end of the roll member, and a voltage (V) of 10 V (in the case of an elastic layer) is applied between the conductive support member of the roll member and the metal plate using a microcurrent meter (R8320 manufactured by Advantest). The current value I (A) after 5 seconds is read and calculated using the following formula. Formula: Volume resistance Rv(Ω)=V / I The measurements are carried out in an environment with a temperature of 22°C and a humidity of 55% RH.

[0061] (Elastic layer thickness) In the conductive roll according to this embodiment, the thickness of the elastic layer may be determined depending on the application of the conductive roll. For example, when the conductive roll according to the present embodiment is a secondary transfer roll, the thickness of the elastic layer is, for example, 1 mm or more and 10 mm or less.

[0062] [Middle layer] The intermediate layer is a layer disposed between the elastic layer and the surface layer. The intermediate layer is composed of a soft binder material having a Poisson's ratio in the above range. The binder material is not particularly limited as long as it has a Poisson's ratio in the above range, and examples of the binder material include resins and elastic materials capable of forming the intermediate layer. Examples of the resins used in the intermediate layer include urethane resins, acrylic resins, epoxy resins, silicone resins, etc. In addition, the elastic material contained in the intermediate layer is the same as the elastic material used in the elastic layer. From the viewpoint of setting the Poisson's ratio in the above range, the binder material is preferably a urethane resin.

[0063] The intermediate layer also contributes to adjusting the resistance of the conductive roll. When a voltage of 100 V is applied to the intermediate layer, the volume resistance is 10 4 Ω or more 10 9 Ω or less (preferably 10 6 Ω or more 10 9 Ω or less). The volume resistivity of the intermediate layer is measured in the same manner as the volume resistivity of the elastic layer.

[0064] In order to achieve the above volume resistivity, the intermediate layer preferably contains a conductive agent. As the conductive agent, either an electronic conductive agent or an ionic conductive agent can be used. Among them, it is preferable to use an ionic conductive agent from the viewpoint of improving the charge retention. That is, the intermediate layer preferably contains an ionic conductive agent. The ionic conductive agent contained in the intermediate layer may be the same as the ionic conductive agent contained in the elastic foam, and the preferred embodiments are also the same. The ion conductive agent may be used alone or in combination of two or more kinds.

[0065] The ionic conductive agent used in the intermediate layer may be a polymeric material having ionic conductivity, such as epichlorohydrin rubber, epichlorohydrin-ethylene oxide copolymer rubber, epichlorohydrin-ethylene oxide-allyl glycidyl ether terpolymer rubber, or the like. The ionic conductive agent used in the intermediate layer may be a compound in which an ionic conductive agent is bonded to the end of a polymer material such as a resin.

[0066] The content of the ion conductive agent may be within a range that allows the above-mentioned volume resistivity to be achieved. The content of the ion conductive agent is preferably 0.1 parts by mass or more and 5.0 parts by mass or less, and more preferably 0.5 parts by mass or more and 3.0 parts by mass or less, relative to 100 parts by mass of the binding material.

[0067] The intermediate layer may contain other additives depending on the physical properties required for the intermediate layer.

[0068] (Thickness of middle layer) In the conductive roll according to this embodiment, the thickness of the intermediate layer may be determined depending on the application of the conductive roll. However, from the viewpoint of obtaining a conductive roll that can easily improve the parallelism of an image transferred to a recording medium, it is preferable to adjust the thickness of the intermediate layer so that the thickness Td of the elastic layer, the thickness Tm of the intermediate layer, and the thickness Ts of the surface layer satisfy the relationship Td>Tm>Ts. Specifically, it is preferable to adjust the thickness of the intermediate layer so that the thickness Td of the elastic layer, the thickness Tm of the intermediate layer, and the thickness Ts of the surface layer satisfy the relationship 0.07≦Tm / (Td+Tm+Ts)≦0.43 (in particular, the relationship 0.08≦Tm / (Td+Tm+Ts)≦0.3). More specifically, the thickness of the intermediate layer is preferably 0.5 mm or more and 5 mm or less, and more preferably 0.5 mm or more and 3 mm or less.

[0069] The method for forming the intermediate layer is not particularly limited, and for example, a method of applying a coating liquid for forming the intermediate layer onto the elastic layer and drying the resulting coating film can be mentioned.

[0070] [Surface layer] The surface layer is a layer disposed on the outer peripheral surface of the intermediate layer, and is a layer that constitutes the outermost surface of the conductive roll. Since the surface layer comes into contact with the medium, it is preferable that the surface layer has releasability.

[0071] The surface layer is preferably a layer containing a resin. The resin contained in the surface layer is not particularly limited, but examples thereof include urethane resin, polyester resin, phenol resin, acrylic resin, epoxy resin, and cellulose resin.

[0072] The surface layer preferably contains a conductive agent. The conductive agent contained in the surface layer includes an electronic conductive agent and an ionic conductive agent. The electronic conductive agent contained in the surface layer is the same as the electronic conductive agent used in the conductive coating layer, and the ionic conductive agent contained in the surface layer is the same as the ionic conductive agent used in the intermediate layer.

[0073] The surface layer may contain other additives depending on the physical properties required for the surface layer.

[0074] (Young's modulus of surface layer) From the viewpoint of improving the cleaning property, the Young's modulus of the surface layer is preferably from 10 MPa to 400 MPa, more preferably from 50 MPa to 400 MPa, and particularly preferably from 100 MPa to 350 MPa. The Young's modulus of the surface layer is measured in the same manner as that of the elastic layer. However, a dumbbell-shaped tensile test piece with a thickness of 0.2 mm is used. This dumbbell test piece is obtained by analyzing the surface layer of the target conductive roll, placing the analyzed surface layer material with the same composition in a resin mold with high releasability such as PTFE, and then heat-curing and demolding it.

[0075] (Surface layer thickness) In the conductive roll according to this embodiment, the thickness of the surface layer may be determined depending on the application of the conductive roll. However, from the viewpoint of improving the cleaning property, the thickness of the surface layer is preferably 10 μm or more and 50 μm or less, and more preferably 12 μm or more and 45 μm or less.

[0076] (Volume resistivity of surface layer) The volume resistance of the surface layer when a voltage of 10 V is applied is 10 4 Ω or more 10 14It is preferable that the resistance is 10 Ω or less. 6 Ω or more 10 12 It is more preferable that it is Ω or less. The volume resistivity of the surface layer is measured in accordance with JIS K 6911 as follows. First, the surface layer of the target conductive roll is analyzed, a single-layer sheet member is prepared using the analyzed surface layer material with the same composition, and the volume resistivity is measured using the obtained sheet member. The sheet member is 0.2 mm thick. The sheet member is placed between circular electrodes, and a voltage (V) of 10 V is applied between the front and back electrodes using a microcurrent meter (Advantest R8320). The current value I (A) is read after 5 seconds, and the volume resistivity is calculated using the following formula. Formula: Volume resistance Rv(Ω)=V / I

[0077] The method for forming the surface layer is not particularly limited, and for example, a method of applying a coating liquid for forming the surface layer onto the intermediate layer and drying the resulting coating film can be mentioned.

[0078] [Volume resistance of conductive roll] The conductive roll according to the present embodiment has a volume resistance of 10 4 Ω or more 10 12 It is preferable that the resistance is 10 Ω or less. 5 Ω or more 10 11 More preferably, it is 10 6 Ω or more 10 10 It is more preferable that the resistance is Ω or less. The volume resistivity of the conductive roll is measured in the same manner as the volume resistivity of the elastic layer.

[0079] (Volume resistance of conductive roll) The conductive roll according to the present embodiment has a volume resistance of 10 4 Ω or more 10 12 It is preferable that the resistance is 10 Ω or less. 5 Ω or more 10 11 More preferably, it is 10 6 Ω or more 10 10It is more preferable that the resistance is Ω or less. The volume resistivity of the conductive roll is measured in the same manner as the volume resistivity of the elastic layer.

[0080] <Image forming devices, transfer devices, process cartridges> FIG. 4 is a schematic diagram showing the configuration of a direct transfer type image forming apparatus, which is an example of the image forming apparatus according to the present embodiment.

[0081] The image forming apparatus 200 shown in FIG. 4 includes a photoconductor 207 (an example of an image carrier), a charging roll 208 (an example of a charging means) that charges the surface of the photoconductor 207, an exposure device 206 (an example of an electrostatic image forming means) that forms an electrostatic image on the charged surface of the photoconductor 207, a developing device 211 (an example of a developing means) that develops the electrostatic image formed on the surface of the photoconductor 207 into a toner image using a developer containing toner, and a transfer roll 212 (an example of a transfer means, an example of a transfer device according to this embodiment) that transfers the toner image formed on the surface of the photoconductor 207 to the surface of a recording medium. Here, the conductive roll according to this embodiment is applied to a transfer roll 212 which presses its outer peripheral surface against a photoconductor 207 which corresponds to an opposing roll and forms an insertion portion through which a recording paper 500 passes.

[0082] The image forming apparatus 200 shown in FIG. 4 further includes a cleaning device 213 that removes toner remaining on the surface of the photoconductor 207, a discharge device 214 that discharges electricity from the surface of the photoconductor 207, and a fixing device 215 (an example of a fixing means) that fixes the toner image to a recording medium.

[0083] The charging roll 208 may be of a contact charging type or a non-contact charging type. A voltage is applied to the charging roll 208 from a power source 209.

[0084] The exposure device 206 may be an optical device equipped with a light source such as a semiconductor laser or an LED (light emitting diode).

[0085] The developing device 211 is a device that supplies toner to the photoconductor 207. The developing device 211, for example, brings a roll-shaped developer holder into contact with or close to the photoconductor 207 and causes the toner to adhere to the electrostatic charge image on the photoconductor 207, thereby forming a toner image.

[0086] The transfer roll 212 is a transfer roll that directly contacts the surface of the recording medium, and is disposed at a position facing the photoreceptor 207. Recording paper 500 (an example of a recording medium) is supplied to the gap where the transfer roll 212 and the photoreceptor 207 are in contact with each other via a supply mechanism. When a transfer bias is applied to the transfer roll 212, an electrostatic force from the photoreceptor 207 to the recording paper 500 acts on the toner image, and the toner image on the photoreceptor 207 is transferred onto the recording paper 500.

[0087] The fixing device 215 may be, for example, a heat fixing device including a heating roll and a pressure roll that presses against the heating roll.

[0088] The cleaning device 213 may be a device equipped with a blade, a brush, a roll, or the like as a cleaning member.

[0089] The static eliminator 214 is a device that irradiates the surface of the photoconductor 207 with light after transfer, thereby eliminating the residual potential of the photoconductor 207.

[0090] The photoconductor 207 and the transfer roll 212 may be integrated into a single housing, for example, to form a cartridge structure (the process cartridge according to the present embodiment) that is detachably attached to the image forming apparatus. The cartridge structure (the process cartridge according to the present embodiment) may further include at least one selected from the group consisting of a charging roll 208, an exposure device 206, a developing device 211, and a cleaning device 213.

[0091] The image forming apparatus may be a tandem type image forming apparatus in which a photoconductor 207, a charging roll 208, an exposure device 206, a developing device 211, a transfer roll 212 and a cleaning device 213 are configured as one image forming unit, and multiple such image forming units are mounted side by side.

[0092] Fig. 5 is a schematic diagram showing an intermediate transfer type image forming apparatus, which is an example of an image forming apparatus according to the present embodiment. The image forming apparatus shown in Fig. 5 is a tandem type image forming apparatus in which four image forming units are arranged in parallel.

[0093] 5, the transfer unit that transfers the toner image formed on the surface of the image carrier to the surface of the recording medium is configured as a transfer unit (one example of the transfer device according to the present embodiment) that includes an intermediate transfer body, a primary transfer unit, and a secondary transfer unit. The transfer unit may have a cartridge structure that is detachably attached to the image forming apparatus.

[0094] The image forming apparatus shown in FIG. 5 includes a photoconductor 1 (an example of an image carrier), a charging roll 2 (an example of a charging means) that charges the surface of the photoconductor 1, an exposure device 3 (an example of an electrostatic image forming means) that forms an electrostatic image on the charged surface of the photoconductor 1, a developing device 4 (an example of a developing means) that develops the electrostatic image formed on the surface of the photoconductor 1 into a toner image using a developer containing toner, an intermediate transfer belt 20 (an example of an intermediate transfer body), a primary transfer roll 5 (an example of a primary transfer means) that transfers the toner image formed on the surface of the photoconductor 1 to the surface of the intermediate transfer belt 20, and a secondary transfer roll 26 (an example of a secondary transfer means) that transfers the toner image transferred to the surface of the intermediate transfer belt 20 to the surface of a recording medium. Here, the conductive roll according to this embodiment is applied to the secondary transfer roll 26, which presses its outer peripheral surface against the support roll 24, which corresponds to the opposing roll, and forms an insertion portion through which the recording paper P passes.

[0095] The image forming apparatus shown in FIG. 5 further includes a fixing device 28 (an example of a fixing means) that fixes the toner image onto a recording medium, a photoreceptor cleaning device 6 that removes toner remaining on the surface of the photoreceptor 1, and an intermediate transfer belt cleaning device 30 that removes toner remaining on the surface of the intermediate transfer belt 20.

[0096] The image forming apparatus shown in Fig. 5 includes first to fourth electrophotographic image forming units 10Y, 10M, 10C, and 10K that output images in the colors of yellow (Y), magenta (M), cyan (C), and black (K) based on color-separated image data. These image forming units 10Y, 10M, 10C, and 10K are arranged side by side and spaced apart from each other in the horizontal direction. Each of the image forming units 10Y, 10M, 10C, and 10K may be a process cartridge that is detachably attached to the image forming apparatus.

[0097] Above each of the image forming units 10Y, 10M, 10C, and 10K, an intermediate transfer belt 20 is provided to extend through each of the image forming units. The intermediate transfer belt 20 is provided wound around a drive roll 22 and a support roll 24 that are in contact with the inner surface of the intermediate transfer belt 20, and runs in a direction from the first image forming unit 10Y to the fourth image forming unit 10K. A force is applied to the support roll 24 by a spring or the like (not shown) in a direction away from the drive roll 22, and tension is applied to the intermediate transfer belt 20 wound around them. An intermediate transfer belt cleaning device 30 is provided on the image bearing surface side of the intermediate transfer belt 20, facing the drive roll 22.

[0098] The developing devices 4Y, 4M, 4C, and 4K of the image forming units 10Y, 10M, 10C, and 10K are supplied with yellow, magenta, cyan, and black toners contained in toner cartridges 8Y, 8M, 8C, and 8K, respectively.

[0099] Since the first to fourth image forming units 10Y, 10M, 10C, and 10K have the same configuration and operation, in the following description of the image forming units, the first image forming unit 10Y will be representatively described.

[0100] The first image forming unit 10Y includes a photoconductor 1Y, a charging roll 2Y that charges the surface of the photoconductor 1Y, a developing device 4Y that develops the electrostatic charge image formed on the surface of the photoconductor 1Y into a toner image using a developer containing toner, a primary transfer roll 5Y that transfers the toner image formed on the surface of the photoconductor 1Y to the surface of the intermediate transfer belt 20, and a photoconductor cleaning device 6Y that removes toner remaining on the surface of the photoconductor 1Y after the primary transfer.

[0101] The charging roll 2Y charges the surface of the photoreceptor 1Y. The charging roll 2Y may be of a contact charging type or a non-contact charging type.

[0102] The charged surface of the photoconductor 1Y is irradiated with a laser beam 3Y from the exposure device 3. As a result, an electrostatic charge image of a yellow image pattern is formed on the surface of the photoconductor 1Y.

[0103] The developing device 4Y contains an electrostatic image developer that contains at least yellow toner and a carrier. The yellow toner is triboelectrically charged by being stirred inside the developing device 4Y. As the surface of the photoconductor 1Y passes through the developing device 4Y, the electrostatic image formed on the photoconductor 1Y is developed into a toner image.

[0104] The primary transfer roll 5Y is disposed inside the intermediate transfer belt 20, facing the photoconductor 1Y. A bias power supply (not shown) that applies a primary transfer bias is connected to the primary transfer roll 5Y. The primary transfer roll 5Y transfers the toner image on the photoconductor 1Y onto the intermediate transfer belt 20 by electrostatic force.

[0105] The toner images of each color are transferred in multiple layers onto the intermediate transfer belt 20 from the first to fourth image forming units 10Y, 10M, 10C, and 10K in this order. The intermediate transfer belt 20 onto which the toner images of the four colors have been multiple-transferred through the first to fourth image forming units reaches a secondary transfer means composed of a support roll 24 and a secondary transfer roll 26.

[0106] The secondary transfer roll 26 is a transfer roll that is in direct contact with the surface of the recording medium, and is disposed at a position facing the support roll 24 on the outer side of the intermediate transfer belt 20. Recording paper P (an example of a recording medium) is supplied to the gap where the secondary transfer roll 26 and the intermediate transfer belt 20 are in contact with each other via a supply mechanism. When a secondary transfer bias is applied to the secondary transfer roll 26, an electrostatic force directed from the intermediate transfer belt 20 to the recording paper P acts on the toner image, and the toner image on the intermediate transfer belt 20 is transferred onto the recording paper P.

[0107] The recording paper P onto which the toner image has been transferred is sent into a pressure contact portion (nip portion) of a fixing device 28 consisting of a pair of rolls, where the toner image is fixed onto the recording paper P.

[0108] The toner and developer used in the image forming apparatus according to the present embodiment are not particularly limited, and any known toner and developer for electrophotography can be used. The recording medium used in the image forming apparatus according to this embodiment is not particularly limited, and examples thereof include paper used in electrophotographic copying machines and printers; OHP sheets; and the like. EXAMPLES

[0109] Examples will be described below, but the present invention is not limited to these examples. In the following description, unless otherwise specified, all "parts" and "%" are based on mass.

[0110] <Example 1> [Formation of elastic layer] (Formation of Elastic Foam) EP70 (urethane foam manufactured by Inoac Corporation) was used as the elastic foam, and this was cut into a cylindrical shape with an outer diameter of 26 mm and an inner diameter of 14 mm to obtain a cylindrical elastic foam. The obtained elastic foam has an open cell structure, a cell diameter of 400 μm, and a density of 70 kg / m 3 It was.

[0111] (Formation of conductive coating layer) The elastic foam obtained by the above method was immersed for 10 minutes at 20°C in a treatment liquid prepared by mixing an aqueous dispersion containing 36 mass% carbon black and an acrylic emulsion (manufactured by Zeon Corporation, product name "Nipol LX852") in a mass ratio of 1:1. The elastic foam with the treatment liquid attached was then heated and dried for 60 minutes in a curing oven set at 100°C to remove moisture and crosslink the acrylic resin. A conductive coating layer containing carbon black was formed on the exposed surface of the elastic foam by the acrylic resin hardened by crosslinking. In this manner, an elastic layer composed of an elastic foam and a conductive coating layer covering the exposed surface of the elastic foam was obtained. Next, a conductive supporting member (made of SUS, diameter 14 mm) having an adhesive applied to its surface was inserted into the obtained elastic layer to form a roll member.

[0112] [Formation of intermediate layer] A coating solution for forming an intermediate layer was obtained by mixing 70 parts of a urethane oligomer (Urethane Acrylate UV3700B, manufactured by Nippon Synthetic Chemical Industry Co., Ltd.), 30 parts of a urethane monomer (Isomyristyl Acrylate, manufactured by Kyoeisha Chemical Co., Ltd.), 0.5 parts of a polymerization initiator (1-Hydroxycyclohexyl Phenyl Ketone Irgacure 184, manufactured by Ciba Specialty Chemicals Co., Ltd.), and 3 parts of an alkyl trimethyl ammonium perchlorate (product name "LXN-30", manufactured by Daiso Co., Ltd.). The obtained coating solution for forming an intermediate layer was applied onto the elastic layer using a die coater, and the coating solution was rotated at a UV irradiation intensity of 700 mW / cm. 2 The coating was then irradiated with UV light for 5 seconds. This process formed a 1 mm thick intermediate layer.

[0113] [Formation of surface layer] Next, 5% by mass of a curing agent (WH-1, manufactured by Henkel Japan Co., Ltd.) was added to a urethane resin coating (EMRALON T-862A, manufactured by Henkel Japan Co., Ltd.) and mixed to obtain a coating liquid for forming a surface layer. The obtained coating liquid for forming a surface layer was applied onto the intermediate layer by spray coating, and the coating film was heat-cured at 120°C for 20 minutes to form a surface layer with a thickness of 20 μm.

[0114] In this way, the volume resistivity was 10 6.8 Ω (measured when 1000 V was applied) of conductive roll was obtained.

[0115] <Example 2> When forming the intermediate layer, the UV irradiation intensity was 650 mW / cm 2 A conductive roll was obtained in the same manner as in Example 1, except that the coating film was irradiated with UV light for 5 seconds at 100° C.

[0116] <Example 3> When forming the intermediate layer, the UV irradiation intensity was 600mW / cm 2 A conductive roll was obtained in the same manner as in Example 1, except that the coating film was irradiated with UV light for 5 seconds at 100° C.

[0117] <Example 4> A conductive roll was obtained in the same manner as in Example 2, except that the urethane resin coating material for the surface layer was ST-008E (manufactured by Ube Industries), and a surface layer having a thickness of 40 μm was formed.

[0118] <Example 5> A conductive roll was obtained in the same manner as in Example 2, except that EP69 (urethane foam manufactured by Inoac Corporation) was used as the elastic foam when the elastic layer was formed, and a surface layer having a thickness of 8 μm was formed.

[0119] <Example 6> A conductive roll was obtained in the same manner as in Example 2, except that a surface layer having a thickness of 10 μm was formed.

[0120] <Example 7> A conductive roll was obtained in the same manner as in Example 2, except that a surface layer having a thickness of 60 μm was formed.

[0121] <Example 8> When forming the elastic layer, EP70 (urethane foam manufactured by Inoac Corporation) was used as the elastic foam, carbon black was kneaded into the urethane resin in advance, and then the urethane resin was foamed. A conductive roll was obtained in the same manner as in Example 2, except that a conductive coating layer was not formed.

[0122] <Example 9> A conductive roll was obtained in the same manner as in Example 2, except that RMM (urethane foam manufactured by Inoac Corporation) was used as the elastic foam when the elastic layer was formed.

[0123] <Example 10> A conductive roll was obtained in the same manner as in Example 2, except that an elastic layer was formed as follows. [Formation of elastic layer] (Formation of Elastic Foam) 60 parts of EPDM (ethylene-propylene-diene rubber, Sumitomo Chemical Co., Ltd. Esprene 505) as a rubber component were kneaded with a pressure kneader, 7 parts of 4,4'-oxybisbenzenesulfonylhydrazide (OBSH) as a chemical foaming agent, 12 parts of acetylene black (Denki Kagaku Kogyo Co., Ltd., DBP oil absorption = 212 ml / 100 g) as a conductive agent, 23 parts of thermal black (Asahi Carbon Co., Ltd., DBP oil absorption = 103 ml / 100 g) as a conductive agent, 5 parts of zinc oxide (Nippon Chemical Industry Co., Ltd.) as a filler, 1.5 parts of vulcanization accelerator (Noccela TS, Ouchi Shinko Chemical Industry Co., Ltd.), and 1.5 parts of vulcanization accelerator (Noccela DT, Ouchi Shinko Chemical Industry Co., Ltd.) were added, and further kneaded with two heated rolls. This mixture was inserted into a SUS core metal (14 mm φ) and foam-molded into a roll to form a roll member.

[0124] (Formation of conductive coating layer) The elastic foam obtained by the above method was immersed for 10 minutes at 20°C in a treatment liquid prepared by mixing an aqueous dispersion containing 36 mass% carbon black and an acrylic emulsion (manufactured by Zeon Corporation, product name "Nipol LX852") in a mass ratio of 1:1. The elastic foam with the treatment liquid attached was then heated and dried for 60 minutes in a curing oven set at 100°C to remove moisture and crosslink the acrylic resin. A conductive coating layer containing carbon black was formed on the exposed surface of the elastic foam by the acrylic resin hardened by crosslinking. In this manner, an elastic layer composed of an elastic foam and a conductive coating layer covering the exposed surface of the elastic foam was obtained.

[0125] <Examples 11 to 15> A conductive roll was obtained in the same manner as in Example 1, except that the thicknesses of the elastic layer and the intermediate layer were changed to the values ​​shown in Table 1.

[0126] <Example 16> A conductive roll was obtained in the same manner as in Example 1, except that the urethane resin coating material for the surface layer was "UW-2001A" (manufactured by Ube Industries).

[0127] <Examples 17 to 19> A conductive roll was obtained in the same manner as in Example 1, except that PE Light A-8 (polyethylene foam manufactured by Inoac Corporation), RR26 (urethane foam manufactured by Inoac Corporation), and RR90 (urethane foam manufactured by Inoac Corporation) were used as the elastic foams when forming the elastic layer.

[0128] <Comparative Example 1> When forming the intermediate layer, the UV irradiation intensity was 850 mW / cm 2 A conductive roll was obtained in the same manner as in Example 1, except that the coating film was irradiated with UV light for 5 seconds at 100° C.

[0129] <Comparative Example 2> When forming the intermediate layer, the UV irradiation intensity was 850 mW / cm 2 A conductive roll was obtained in the same manner as in Example 9, except that the coating film was irradiated with UV light for 5 seconds at 100° C.

[0130] <Evaluation> (Parallelism of the image transferred to the recording medium) Using a Fuji Xerox ApeosPort VII C6688, the secondary transfer roll is set with a push amount of 0.2 mm on the rear and 0.8 mm on the front of the opposing intermediate transfer belt, and the push amount (Rear) - (Front) is set with a difference of 0.6 mm. A rectangular line of A3 size 280 mm x 400 mm is imaged on the intermediate transfer belt, transferred in the secondary transfer section, and fixed by the fixing device. After that, the image line length (L) on the rear side and the front side of the output image was Rear , L Front ) and measure the image length difference (L Front )-(L Rear ) and calculated the parallelism ΔL (see Figure 1(b)). -Evaluation criteria- A(〇):ΔL>1.5mm B(△):0.5mm<ΔL<1.5mm C(×):0.5mm>ΔL

[0131] (cleaning ability) Place the created secondary transfer roll on a Fuji Xerox ApeosPort VII C6688 and output a K100% solid image onto one side of an A3 sheet of paper. After outputting 100 sheets of images, observe the back side of the output paper and check for toner stains on the back side. -Evaluation criteria- A(〇): The back side is not dirty at all. B (△): Part of the back surface is colored black. C(×): The back side is colored black in a stripe.

[0132] [Table 1]

[0133] From the above results, it is understood that the conductive roll of this example can more easily improve the parallelism of the image transferred to the recording medium than the conductive roll of the comparative example. [Explanation of symbols]

[0134] 100 conductive roll, 110 support member, 122 elastic layer, 124 intermediate layer, 126 surface layer, 200 image forming apparatus, 206 exposure device, 207 photoconductor, 208 charging roll, 209 power source, 211 developing device, 212 transfer roll, 213 cleaning device, 214 charge removal device, 215 fixing device, 500 recording paper 1Y, 1M, 1C, 1K photoconductor, 2Y, 2M, 2C, 2K charging roll, 3 exposure device, 3Y, 3M, 3C, 3K laser beam, 4Y, 4M, 4C, 4K developing device, 5Y, 5M, 5C, 5K primary transfer roll, 6Y, 6M, 6C, 6K photoconductor cleaning device, 8Y, 8M, 8C, 8K toner cartridge, 10Y, 10M, 10C, 10K Image forming unit, 20 intermediate transfer belt, 22 drive roll, 24 support roll, 26 secondary transfer roll, 28 fixing device, 30 intermediate transfer belt cleaning device, P recording paper

Claims

1. A support member; an elastic layer disposed on an outer circumferential surface of the support member; a surface layer disposed on an outer peripheral surface of the elastic layer; an intermediate layer disposed between the elastic layer and the surface layer, the intermediate layer having a Poisson's ratio of less than 0.40; A conductive roll having a

2. 2. The conductive roll according to claim 1, wherein a thickness Td of the elastic layer, a thickness Tm of the intermediate layer, and a thickness Ts of the surface layer satisfy the relationship Td>Tm>Ts.

3. 3. The conductive roll according to claim 2, wherein a thickness Td of the elastic layer, a thickness Tm of the intermediate layer, and a thickness Ts of the surface layer satisfy the relationship: 0.07≦Tm / (Td+Tm+Ts)≦0.

43.

4. 4. The conductive roll according to claim 2, wherein the intermediate layer has a thickness Tm of 0.5 mm or more and 4 mm or less.

5. The conductive roll according to any one of claims 2 to 4, wherein the surface layer has a thickness Ts of 10 µm or more and 50 µm or less.

6. The conductive roll according to any one of claims 1 to 5, wherein the surface layer has a Young's modulus Ys of 10 MPa or more and 400 MPa or less.

7. The conductive roll according to any one of claims 1 to 6, wherein the elastic layer comprises a cylindrical elastic foam and a conductive coating layer that covers an exposed surface of the elastic foam.

8. The conductive roll according to claim 7 , wherein the elastic foam has an open-cell structure.

9. A conductive roll described in any one of claims 1 to 8, wherein the Poisson's ratio of the intermediate layer is 0.38 or less.

10. A transfer device comprising the conductive roll according to any one of claims 1 to 9.

11. A process cartridge comprising an image carrier and the transfer device according to claim 10, the process cartridge being detachably mountable to an image forming apparatus.

12. A transfer device including a conductive roll having a support member, an elastic layer arranged on the outer peripheral surface of the support member, a surface layer arranged on the outer peripheral surface of the elastic layer, and an intermediate layer arranged between the elastic layer and the surface layer and having a Poisson's ratio of 0.40 or less; An image carrier; Equipped with A process cartridge that is detachably attached to an image processing device.

13. An image carrier; a charging device for charging the surface of the image carrier; an electrostatic latent image forming device for forming an electrostatic latent image on a charged surface of the image carrier; a developing device for developing the electrostatic latent image formed on the surface of the image carrier with a developer containing a toner to form a toner image; a transfer device according to claim 10 for transferring the toner image onto a surface of a recording medium; An image forming apparatus comprising:

Images