Manufacturing method for transparent decorative molding

Abstract

To provide a method of fabricating a light-transmitting decorated molding article.SOLUTION: A method of fabricating a decorated molding article includes: forming an all-in-one coating on a substrate and performing a curing step, thereby forming a composite layer structure with a protective effect, a color effect, and a bonding effect. Compared with the printing layer in the conventional In Mold Label (IML) and InSert molding (INS) that is made by a plurality of anti-impact and bonding processes, the composite layer structure of the embodiment can form a molded film with better physical properties (e.g., higher hardness, better protection effect, etc.) after the blister molding process. Therefore, the molded film of the embodiment can be applied to a laser engraving process to form a variety of light-transmitting decorative molded products. Further, the present disclosure further forms a protective layer locally in the grooves formed after the laser engraving process, so as to protect the texture after the laser engraving process from damage.SELECTED DRAWING: Figure 14

Description

[Technical field]

[0001] The present invention relates to a method for producing a light-transmitting decorated molded article. [Background technology]

[0002] Generally, decoration such as patterns and texts formed on the surface of an object shell is mainly formed by spraying or printing processes to give a certain visual effect and increase the variety of the object's appearance. The conventional forming method is to spray a hardening layer on the surface of the shell after the shell of the related product is completed. This method is complicated in process, has a low yield, and may cause pollution of organic solvent gas, resulting in many pollution problems. Meanwhile, the spraying process has the disadvantages of being time-consuming, complicated, and has low thickness uniformity, so there is an urgent need to improve the overall production yield and cost. To solve these problems, various specific decoration processes using decorative films have been proposed. For example, in-mold decoration (IMD) or out-mold decoration (OMD) have become alternative means for forming surface graphics.

[0003] Currently, the polymer substrate materials commonly used in in-mold decoration include polycarbonate (PC), poly(methyl methacrylate), (PMMA), polyethylene terephthalate (PET), and acrylonitrile butadiene styrene (ABS). However, substrates including PC and ABS have low hardness and the substrate surface is easily damaged. Therefore, the substrate is generally coated with a protective layer to improve the hardness and scratch resistance of the substrate surface. On the other hand, substrates including PMMA have high hardness but are prone to cracking during molding, making it difficult to carry out the hot pressing process.

[0004] Specifically, in-mold decoration (IMD) can include in-mold labeling (IML), in-mold film (IMF or INS), and in-mold roller (IMR), as shown in Table 1. In-mold labeling (IML) is characterized by a hardened transparent film on the surface, a printed pattern layer in the middle, and a plastic layer on the back. The ink is sandwiched between the hardened transparent film and the plastic layer, which can prevent the surface of the product from being scratched, is wear-resistant, can prolong the color brightness, and is not easy to fade for a long time. The process flow of IML is as follows: (1) Cutting: Take a roll of film substrate (usually PMMA / PC or PET or PC substrate with hard coating) and cut it into the size designed for printing and blister molding. (2) Planar printing: Usually, screen printing (silkscreen printing), inkjet printing process is carried out to provide graphics, text effects, and finally impact-resistant adhesive. Generally, the number of printings is determined according to the effect of the product design, but especially, impact-resistant adhesive needs to be matched with high temperature and high pressure injection molding plastic material (generally, the injection molding temperature is about 200℃ or higher), so usually multiple stacks need to be printed, which results in increased cost, reduced film usage efficiency, and reduced overall yield. (3) Ink drying: The printed ink is baked at high temperatures and dried to ensure the ink's physical properties. (4) Adhesion of protective film: In order to prevent the post-punching positioning holes from damaging the surface of the printed film, a protective film must be attached to protect the surface. (5) Punching positioning holes: Because the film shrinks during the molding and heating process, it is necessary to punch the positioning hole design to ensure the accuracy of positioning with the product aligned with the printing film. (6) High temperature and high pressure molding: After the printed film has undergone a high temperature and heat process, it is blister molded in a preheated state using a molding machine. (7) Shape cutting: Use blade cutting or laser cutting to cut out the waste of the three-dimensional film after blister molding. (8) Injection molding: Finally, the cut-out three-dimensional film is placed into the injection molding machine to form the final product, and then the relevant physical inspection is carried out before shipment.

[0005] In-mold labeling (IMR) is a process in which a pattern is printed on a film, the film is attached to a mold cavity through a film feeder, and then it is injected. After injection, the patterned ink layer is separated from the film to leave the ink layer on the plastic part, and a plastic part with a decorative pattern on the surface is obtained. Therefore, there is no transparent protective film on the surface of the final product processed by in-mold labeling, and the film is only a carrier in the production process. In other words, the biggest difference between in-mold labeling (IML) and in-mold labeling (IMR) is whether there is a transparent protective film on the surface of the product. In addition, in-mold film (IMF) is similar to in-mold labeling (IML).

[0006] [Table 1]

[0007] Out-mold decoration (OMD) is also called high pressure transfer printing. After printing the pattern on the transparent film, the pattern is directly transferred to the plastic shell by using high / medium / low pressure and vacuum transfer. The main feature is that it is a tactile product, which is used in 3C, home appliances, and automobiles. Summary of the Invention [Problem to be solved by the invention]

[0008] However, printing and lamination are used to process translucent decorative moldings, regardless of IMD or OMD film. The blister, cutting and injection molding processes are performed by the customer, which may cause disadvantages such as difficult alignment, excessive material loss, high cost, and the difficulty of the subsequent laser engraving process also makes it impossible to process products such as translucent patterns.

[0009] Table 2 lists the properties and advantages of various conventional decoration techniques.

[0010] [Table 2] [Means for solving the problem]

[0011] The present invention provides a method for manufacturing a decorated molded product, which includes: providing a coating including at least a uniformly mixed protective material, an ink material, and a bonding material; forming a coating on a substrate using a coating method or a printing method; performing a first curing step to form a composite layer structure, the composite layer structure including at least a photocured layer disposed on the substrate; performing a blister molding process to form a molded film; performing a second curing step to increase the hardness of the molded film; performing a laser engraving process to form a groove, form a protective layer in the groove, and attaching the molded film to a surface of a workpiece to form a decorated molded product.

[0012] In one embodiment of the invention, the protective material comprises polymethyl methacrylate (PMMA), an aliphatic urethane diacrylate, an epoxy acrylate (EA), a polyester polyol, or a combination thereof, the ink material comprises polyurethane (PU), and the bonding material comprises thermoplastic polyurethane (TPU), an aromatic urethane diacrylate, or a combination thereof.

[0013] In one embodiment of the invention, the protective layer is formed using a 3D printing or jet printing process.

[0014] In one embodiment of the present invention, attaching the formed film to the surface of the workpiece includes performing a blister molding process and then performing an in-mold decoration or out-mold decoration technique on the formed film to attach the formed film to the outer surface of the workpiece to form a decorated molded product.

[0015] In one embodiment of the present invention, the step of attaching the formed film to the surface of the workpiece includes performing an in-mold decoration or out-mold decoration technique on the formed film after performing a blister molding process, and attaching the formed film to the inner surface of the workpiece to form a decorated molded product.

[0016] The present invention provides a method for manufacturing a decorated molded product, which includes: providing a substrate having a first surface and a second surface facing each other; forming a second coating on the second surface of the substrate using a coating method or a printing method; forming a first coating on the second coating using a coating method or a printing method; performing a first curing process to form a composite layer structure, the composite layer structure including at least the substrate, a first decorative layer disposed on the second surface of the substrate, and a second decorative layer disposed between the second surface of the substrate and the first decorative layer; performing a blister molding process to form a molded film; performing a laser engraving process to form a groove, forming a protective layer in the groove, and attaching the molded film to a surface of a workpiece to form a decorated molded product.

[0017] In one embodiment of the invention, the first coating and the second coating each include a uniformly mixed protective material, an ink material, and a bonding material.

[0018] In one embodiment of the invention, the protective layer is formed using a 3D printing or jet printing process.

[0019] The present invention provides a method for manufacturing a decorated molded product, which includes: providing a coating including at least a uniformly mixed protective material, an ink material, and a bonding material; using a coating method or a printing method to form a coating on a substrate; performing a first curing step to form a composite layer structure; performing a blister molding process to form a molded film; performing a second curing step to increase the hardness of the molded film; forming a mask layer on the composite layer structure; performing a laser engraving process to form a groove in the mask layer and the composite layer structure; using a deposition method or a sputtering method to form a plating layer on the mask layer, so that a part of the plating layer fills the groove; removing the mask layer and the plating layer thereon; forming a protective layer in the groove, so that the protective layer covers the plating layer; and attaching the molded film to a surface of a workpiece to form a decorated molded product.

[0020] In one embodiment of the invention, the protective layer is formed using a 3D printing or jet printing process. Effect of the Invention

[0021] As described above, the present invention forms an all-in-one coating on a substrate, and then performs a curing process to form a composite layer structure having protective, coloring, and bonding effects. This composite layer structure can form a molded film with excellent physical properties (e.g., high hardness and good protective effect) after the blister molding process. Therefore, the molded film of this embodiment can be applied to a laser engraving process to form various translucent decorative molded products. In addition, the present invention further partially forms a protective layer in the groove to protect the texture after laser engraving from damage, thereby improving the protective effect of the composite layer structure and extending its life. Furthermore, the present invention performs the laser engraving process after the blister molding process. Therefore, the present invention can solve the alignment problem of the prior art, thereby improving the yield and reducing the manufacturing cost.

[0022] On the other hand, while the conventional INS requires that the ink layer or the printing layer be matched to the bonding process of the substrate, the multiple laminated decorative layers in the present embodiment not only provide a variety of coloring effects, but also have a protective effect and a bonding effect, and no additional bonding process is required. Furthermore, while the conventional IML technology requires that an additional 3 to 10 adhesive layers be formed to attach to the workpiece, the present embodiment does not require the formation of an additional adhesive layer. That is, the present invention can effectively simplify the manufacturing process of the composite layer structure and provide a composite layer structure with better protective and bonding effects. Furthermore, compared with the conventional spray technology, INS technology, or IML technology, the decorated molded product of the present invention can further simplify the manufacturing process, thereby effectively reducing the manufacturing cost. [Brief description of the drawings]

[0023] [Figure 1] 3 is a flowchart showing a method for manufacturing a decorated molded product according to the first embodiment of the present invention. [Figure 2A] 1 is a schematic cross-sectional view of a decorated molded product according to a first embodiment of the present invention. [Figure 2B] FIG. 3 is a schematic cross-sectional view of another decorated molded product according to the first embodiment of the present invention. [Diagram 3] 10 is a flowchart showing a method for manufacturing a decorated molded product according to a second embodiment of the present invention. [Figure 4] FIG. 4 is a schematic cross-sectional view of a decorated molded product according to a second embodiment of the present invention. [Diagram 5] 10 is a flowchart showing a method for manufacturing a decorated molded product according to a third embodiment of the present invention. [Figure 6] FIG. 11 is a schematic cross-sectional view of a decorated molded product according to a third embodiment of the present invention. [Figure 7] FIG. 11 is a schematic cross-sectional view of a decorated molded product according to a fourth embodiment of the present invention. [Figure 8] FIG. 11 is a schematic cross-sectional view of a decorated molded product according to a fifth embodiment of the present invention. [Figure 9]1 is a flow chart illustrating an in-mold decoration technique according to one embodiment of the present invention. [Figure 10] 1 is a flow chart illustrating an out-mold decoration technique according to one embodiment of the present invention. [Figure 11] FIG. 13 is a schematic cross-sectional view of a decorated molded product according to a sixth embodiment of the present invention. [Figure 12A] FIG. 13 is a schematic cross-sectional view of a decorated molded product according to a seventh embodiment of the present invention. [Figure 12B] FIG. 12B is a schematic top view of the structure of FIG. 12A when the light source is in an off state. [Figure 12C] FIG. 12B is a schematic top view of the structure of FIG. 12A with the light source in an on state. [Figure 13A] FIG. 13 is a schematic cross-sectional view of a decorated molded product according to an eighth embodiment of the present invention. [Figure 13B] FIG. 13B is a schematic top view of the structure of FIG. 13A when the light source is in an off state. [Figure 13C] FIG. 13B is a schematic top view of the structure of FIG. 13A when the light source is in an on state; [Figure 14] 13 is a flowchart showing a method for manufacturing a decorated molded product according to a ninth embodiment of the present invention. [Figure 15A] 13A to 13C are schematic cross-sectional views illustrating a process for producing a decorated molded product according to a ninth embodiment of the present invention. [Figure 15B] 13A to 13C are schematic cross-sectional views illustrating a process for producing a decorated molded product according to a ninth embodiment of the present invention. [Figure 15C] 13A to 13C are schematic cross-sectional views illustrating a process for producing a decorated molded product according to a ninth embodiment of the present invention. [Figure 15D] 13A to 13C are schematic cross-sectional views illustrating a process for producing a decorated molded product according to a ninth embodiment of the present invention. [Figure 15E] 13A to 13C are schematic cross-sectional views illustrating a process for producing a decorated molded product according to a ninth embodiment of the present invention. [Figure 16] FIG. 2 is a schematic cross-sectional view of a decorated molded article according to an alternative embodiment of the present invention. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0024] In the following paragraphs, the present invention will be generally described with reference to the accompanying drawings. However, the present invention may be implemented in many different forms and is not limited to the embodiments shown in the text. The directional terms described in the following embodiments, such as "upper", "lower", etc., are used based on the orientation of the drawings described. Therefore, the directional terms used are for the purpose of explaining the present invention and are not intended to limit it. In addition, the thickness of each film layer and region may be expanded for clarity. The same or similar elements are given the same or similar reference numbers, and their description will be omitted in the following paragraphs.

[0025] Fig. 1 is a flow chart showing a method for producing a decorated molded product according to a first embodiment of the present invention.Fig. 2A is a schematic cross-sectional view of the decorated molded product according to the first embodiment of the present invention.

[0026] 1 and 2A, the first embodiment of the present invention provides a manufacturing method S10 for a decorated molded product 10 as follows. Step S100 is carried out to form a composite layer structure 110 (shown in FIG. 2A). Specifically, the step of forming the composite layer structure 110 includes the following steps: Step S102 is carried out. A first coating is formed on the substrate 102 (shown in FIG. 2A) using a coating method or a printing method. In one embodiment, the material of the substrate 102 includes acrylonitrile-butadiene-styrene copolymer (ABS), polycarbonate (PC), polymethyl methacrylate (PMMA), or a combination thereof, and the method of forming them includes an extrusion molding method, etc. For example, the ABS solid plastic can be heated, melted, extruded, and cooled to form the ABS substrate 102 by an extrusion molding method. Also, the ABS solid plastic is mixed with a color master batch, a pigment, a pearl powder, and related additives to form a mixture. The mixture can then be extruded by extrusion to form another ABS substrate, which can provide the ABS substrate with visual effects such as color, pearlescent, bright surface, mirror, non-glossy matte surface, etc. In an alternative embodiment, the material of the substrate 102 can be wood grain sheet, aluminum sheet, steel plate, and the like, or a combination thereof.

[0027] Specifically, the coating method distributes the coating material in a coating device and uniformly applies the coating material on the substrate 102 through the coating head of the coating device. In one embodiment, the opening of the coating head may be flat, which can provide a bright surface effect on the coating material applied on the substrate 102. In another embodiment, the opening of the coating head may have a plurality of microstructures (e.g., micro recesses), which can provide a matte effect on the coating material applied on the substrate 102. Also, in an alternative embodiment, the opening of the coating head may have a plurality of concave-convex structures, which can provide a hairline effect on the coating material applied on the substrate 102. Meanwhile, the printing method may include any suitable printing method, such as gravure printing, screen printing, offset printing, reverse printing, transfer printing, inkjet printing, etc. Compared with the coating method, the printing method can form a thinner film layer.

[0028] In one embodiment, the first coating includes at least a protective material, an ink material, and a bonding material that are uniformly mixed. The protective material can include polymethyl methacrylate (PMMA), aliphatic urethane diacrylate, epoxy acrylate (EA), polyester polyol, or a combination thereof. The ink material can include polyurethane (PU) and similar materials. The bonding material can include thermoplastic polyurethane (TPU), aromatic urethane diacrylate, or a combination thereof. The first coating further includes a heat-resistant material, a solvent, and a hardener. In one embodiment, the heat-resistant material can include polycarbonate (PC) and similar materials. The solvent can include ethyl acetate, methyl ethyl ketone, toluene, xylene, or a combination thereof. The hardener can include polyisocyanate and similar materials. However, the present invention is not limited thereto. In another embodiment, the first coating may also include other additives such as matte powder, pearl powder, etc., which can provide different visual effects such as a matte surface or pearl luster to the first decorative layer 104 (shown in FIG. 2A) formed in a subsequent process.

[0029] Then, proceed to step S104. A coating method or a printing method is used to form a second coating on the first coating. In one embodiment, the second coating includes at least a uniformly mixed protective material, an ink material, and a bonding material. In addition, the coating method, the printing method, the protective material, the ink material, and the bonding material are described in detail in the above paragraphs, so they will not be described again here. It should be noted that, as shown in FIG. 2A, the first coating is used to form the first decorative layer 104, and the second coating is used to form the second decorative layer 106. In this embodiment, the first coating and the second coating have different compositions to achieve different visual effects. In another embodiment, the decorative layer 104 or 106 may use deposition or sputtering to achieve a metallized decorative effect. For example, the first decorative layer 104 formed by the first coating may be a wood grain layer, and the second decorative layer 106 formed by the second coating has a matte silver color, so that the composite layer structure 110 can display a matte silver color with a wood grain pattern.

[0030] Then, proceed to step S106. Using a coating method or a printing method, a third coating is formed on the second coating. In one embodiment, the third coating includes at least a uniformly mixed protective material, an ink material, and a bonding material. In addition, the coating method, the printing method, the protective material, the ink material, and the bonding material are described in detail in the above paragraphs, so they will not be described again here. It should be noted that the third coating is used to form the photocurable layer 108. In this embodiment, the content of the protective material in the third coating may be higher than the content of the protective material in the first coating or the second coating.

[0031] Then, proceed to step S108. A first curing step is performed to form a composite layer structure 110. As shown in FIG. 2A, the composite layer structure 110 includes a first decorative layer 104, a second decorative layer 106, and a photocured layer 108. The first decorative layer 104 can be disposed on the first surface 102a of the substrate 102. The second decorative layer 106 can be disposed on the first decorative layer 104. The photocured layer 108 can be disposed on the second decorative layer 106, so that the second decorative layer 106 is disposed between the first surface 102a of the substrate 102 and the photocured layer 108. Although FIG. 2A shows only two decorative layers 104 and 106, the present invention is not limited thereto. In another embodiment, the composite layer structure 110 can also have multiple (e.g., three, four, or more) decorative layers stacked together. In addition to the coating method, the photocurable layer 108 can be formed on the second decorative layer 106 using a lamination method, an embossing method, a 3D printing method, or a jet printing method. In an alternative embodiment, the material of the photocurable layer 108 can be a UV material or a heat curable material.

[0032] In one embodiment, the first curing step can include a thermal curing step, an ultraviolet (UV) curing step, a combination thereof, or other suitable curing steps. This first curing step allows the bonding material to undergo a crosslinking reaction and bond to the substrate 102. In this embodiment, the coating material can be regarded as an all-in-one coating material, and can provide the composite layer structure 110 with all of the protective effect, coloring effect, and bonding effect after curing. In this case, the composite layer structure 110 is also called an all-in-one composite layer structure. Compared with the prior art process that requires the purchase of a protective layer and forms an adhesive film structure through a printing and bonding process, the present invention can effectively facilitate the manufacturing process, reduce the manufacturing cost, and prevent the pollution problem caused by the adhesive film.

[0033] While the conventional INS requires the ink layer or printing layer to be matched with the bonding process of the substrate, the multiple laminated decorative layers in the present embodiment not only provide a variety of coloring effects, but also have a protective effect and bonding effect, and no additional bonding process is required. That is, the present invention can effectively simplify the manufacturing process of the composite layer structure and provide a composite layer structure with better protective and bonding effects. Furthermore, compared with the conventional spray technology and INS technology, the composite layer structure of the present invention can further simplify the manufacturing process, thereby effectively reducing the manufacturing cost.

[0034] After forming the composite layer structure 110, proceed to step S120. A blister molding process is performed to form the formed film 100A. In one embodiment, the blister molding process includes heating the composite layer structure 110 and the substrate 102 to soften the composite layer structure 110 and the substrate 102, placing the softened composite layer structure 110 and the substrate 102 in a mold and applying pressure to form the softened composite layer structure 110 and the substrate 102 into a desired shape, performing a cooling process, and cutting off the excess to form the formed film 100A.

[0035] Next, proceed to step S130. An in-mold decoration technique or an out-mold decoration technique is carried out to attach the formed film 100A to the outer surface 200a of the workpiece 200 to form the decorated formed product 10 shown in FIG. 2A. In one embodiment, the substrate 102 has a first surface 102a and a second surface 102b facing each other. As shown in FIG. 2A, the second surface 102b of the substrate 102 contacts the outer surface 200a of the workpiece 200, the first surface 102a of the substrate 102 contacts the first decorative layer 104, and the upper surface 110a of the composite layer structure 110 is exposed upward. In this embodiment, the upper surface 110a of the composite layer structure 110 may be a visual surface, so that consumers can see the visual effect of the formed film 100A from the upper surface 110a of the composite layer structure 110.

[0036] Figure 9 is a flow chart illustrating an in-mold decoration technique according to one embodiment of the present invention.Figure 10 is a flow chart illustrating an out-mold decoration technique according to one embodiment of the present invention.

[0037] 9, step S200 of the in-mold decoration technique is as follows: First, step S202 is carried out to provide a formed film. The formed film may be, for example, formed film 100A. The composition of formed film 100A has been described in the above paragraph, and will not be repeated here.

[0038] Next, proceed to step S204. The formed film 100A is placed in an in-mold decoration mold. Specifically, the in-mold decoration mold includes a hollow mold cavity. The mold cavity has a surface. The formed film 100A is then attached to the surface of the mold cavity such that the formed film 100A covers at least a portion of the surface of the mold cavity. In an alternative embodiment, before step S206, a heating pre-forming process may be selectively performed to remove excess film by die cutting, laser cutting, or water jet cutting.

[0039] Next, proceed to step S206. The molding material is injected into the mold cavity of the in-mold decoration mold to bond the molding material and the molded film 100A together. In one embodiment, the molding material may be a material suitable for molding, such as a plastic material, a resin material, a metal material, a carbon fiber material, or a glass.

[0040] Then, proceed to step S208. The molding material is cooled to form the workpiece 200. The workpiece 200 may be an electronic device housing or part, a vehicle housing or part, or a combination thereof, depending on the application of the decorative molded product of the present invention. For example, the workpiece 200 may be a mobile phone, a digital camera, a personal digital assistant (PDA), a laptop, a desktop computer, a touch panel, a television, a global positioning system (GPS) device, a car monitor, a navigation device, a display, a digital photo frame, a DVD player, an automobile interior trim panel (e.g., a handle, a trim strip, a touch front bumper, etc.), an automobile exterior decorative panel (e.g., an exterior handle, a back door decorative strip, a welcome pedal, etc.), an automobile dashboard, an automobile logo, an intelligent key (I-key), an engine start button, a clock, a radio, a toy, a watch, or other housing or part used in an electronic product that requires power. However, the present invention does not limit the shape and structure of the workpiece 200, and as long as the shape and structure of the workpiece 200 can be implemented by the in-mold decoration technique, it is within the scope of the present invention.

[0041] Next, proceed to step S210. The molded decorative article 10 is removed from the in-mold decoration mold. The obtained molded decorative article 10 is shown in detail in FIG. 2A, so a description thereof will not be repeated here.

[0042] Meanwhile, the decorated molded product 10 can also be manufactured by an out-mold decoration technique. Referring to FIG. 10, step S200 of the out-mold decoration technique is as follows. First, step S302 is performed to provide a workpiece 200. In one embodiment, the workpiece 200 may be a housing or part of an electronic device, a housing or part of a vehicle, or a combination thereof, depending on the application of the decorated molded product of the present invention. In another embodiment, the material of the outer surface 200a of the workpiece 200 may be plastic, resin, metal, carbon fiber, glass, or other various shell materials that have already been molded, for example, after undergoing a suitable pretreatment process, a workpiece with required properties can be manufactured. For example, when the material of the workpiece is plastic, a plastic workpiece (e.g., a plastic housing, etc.) can be obtained through an injection mold by an injection molding process, or when the material of the workpiece is metal, a metal workpiece (e.g., a metal housing, etc.) can be obtained after surface treatment of the metal.

[0043] Next, proceed to step S304. Provide a formed film. For example, the formed film is formed film 100A shown in Figure 2A. The composition of formed film 100A is described in the paragraph above, and will not be repeated here.

[0044] Then, proceed to step S306. The workpiece 200 and the formed film 100A are placed in a jig. It should be noted that before step S306, the jig may be selectively designed and prepared according to the requirements of the final product.

[0045] Next, proceed to step S308. A high-pressure decorative molding process is performed to attach the molded film 100A to the outer surface 200a of the workpiece 200. To be more specific, in the high-pressure decorative molding process, the molded film 100A is first subjected to, for example, a heat softening process. In one embodiment, the temperature of the heat softening process may be in the range of 80°C to 150°C, and the time of the heat softening process may be in the range of 30 seconds to 180 seconds. Next, the molded film 100A is brought into contact with the workpiece 200, and a pressing process is performed. After that, the molded film 100A is subjected to a high-pressure vacuum molding process, and the molded film 100A is attached to the workpiece 200. Finally, the remaining composite layer structure is selectively removed by die cutting, laser cutting, or water jet cutting. In short, in this embodiment, the molded film 100A can be attached in close contact with a part of the outer surface 200a of the workpiece 200 by the out-mold decoration technology.

[0046] Referring again to FIG. 1, after forming the decorated molded product 10, proceed to step S140. A second curing step is performed to increase the hardness of the composite layer structure 110. In one embodiment, the second curing step can include a thermal curing step, an ultraviolet (UV) curing step, a combination thereof, or other suitable curing steps. In this embodiment, the first curing step is different from the second curing step. For example, the first curing step can be a thermal curing step, and the second curing step can be a UV curing step, or vice versa. In an alternative embodiment, when the first curing step and the second curing step are both thermal curing steps, the curing temperature of the second curing step can be higher than the curing temperature of the first curing step. It should be noted that the second curing step causes the protective material to undergo a cross-linking reaction, which increases the hardness of the upper surface 108a of the photocurable layer 108, thereby improving the protective effect. That is, when performing the in-mold decoration or out-mold decoration technique (i.e., step S130), the photocured layer 108 is not yet fully cured and is ductile, so it is completely attached to the outer surface 200a of the workpiece 200. After the second curing step (i.e., step S140), the photocured layer 108 is fully cured and has an overall protective effect. In this embodiment, the hardness of the photocured layer 108 may have a stepwise change. Specifically, the hardness of the photocured layer 108 may increase from the bottom surface 108b to the top surface 108a. That is, the hardness of the top surface 108a of the photocured layer 108 may be higher than the hardness of the bottom surface 108b of the photocured layer 108. In addition, the second curing step can increase the hardness of the first decorative layer 104 and the second decorative layer 106, thereby facilitating the subsequent laser engraving process (i.e., step S150).

[0047] Next, proceed to step S150. A laser engraving process is carried out to form a groove 105 in the composite layer structure 110. As shown in FIG. 2A, the groove 105 can extend downward from the upper surface 110a of the composite layer structure 110 to expose the upper surface 104t of the first decorative layer 104. However, the present invention is not limited thereto. In another embodiment, the groove 105 can have different depths. That is, the bottom surface 105bt of the groove 105 can be higher or lower than the upper surface 104t of the first decorative layer 104, or the bottom surface 105bt of the groove 105 can be higher, lower, or equal to the upper surface 106t of the second decorative layer 106. Furthermore, although FIG. 2A shows only one groove 105, the present invention is not limited thereto. In an alternative embodiment, the decorated molded product 10 can have multiple grooves to form various laser engraving patterns, thereby improving the consumer's visual perception.

[0048] Then, the process proceeds to step S160. A protective layer 112A is formed in the groove 105. Specifically, the protective layer 112A is formed by a three-dimensional (3D) printing technique. In one embodiment, the 3D printing technique includes an aerosol jet printing (AJP) process. The aerosol jet printing process uses an aerosol jet deposition head to form an annular propagating jet composed of an outer sheath flow and an inner aerosol-laden carrier flow. During the annular aerosol jet printing process, an aerosol stream of the material to be deposited is focused and deposited on the surface to be formed. The above process is also called maskless mesoscale material deposition (M3D). That is, the deposition process can be performed without the use of a mask. In an alternative embodiment, the protective layer 112A may be formed by a jet printing technique.

[0049] In this embodiment, as shown in FIG. 2A, the filling ink is filled into the groove 105 through the nozzle of the 3D printing device. In one embodiment, the filling ink may be similar to the third coating described above, including at least a uniformly mixed protective material, an ink material, and a bonding material, and the content of the protective material in the filling ink may be higher than that in the first coating or the second coating. In addition, after filling the groove 105 with the filling ink, an additional curing process may be performed, so that the protective material in the filling ink can undergo a cross-linking reaction to increase the hardness of the protective layer 112A. In this case, the protective layer 112A can partially protect the laser-engraved texture. That is, the first decorative layer 104 and the second decorative layer 106 exposed by the groove 105 can be prevented from being damaged, so that the protective effect of the composite layer structure 110 can be further improved and the life can be extended.

[0050] It should be noted that in this embodiment, the nozzle used in the 3D printing technology is small enough, so that the filling ink can be accurately filled into the groove to form a protective layer locally and protect the laser-engraved texture. Compared with the general spray technology that volatilizes a large amount of coating into the air, the use of the 3D printing technology in this embodiment can effectively reduce material consumption and reduce production costs. In addition, the nozzle of the general spray technology is relatively large, so that the spray layer is distributed in a dotted manner and has no continuity, which makes the spray effect rough and uneven. On the other hand, the 3D printing technology nozzle of this embodiment is small enough to completely fill the narrow groove with the filling ink, so that the filling ink can be continuously distributed on the surface of the object, so that the protective layer is smoother and more beautiful. In addition, the 3D printing technology of this embodiment can also be locally toned. That is, in this embodiment, protective layers of different colors can be filled into different groove positions according to customer requirements, which can improve the visual experience of the viewer.

[0051] Furthermore, the protective layer 112A shown in FIG. 2A is located only in the groove 105. That is, the upper surface of the protective layer 112A is flush with the upper surface 108a of the photocurable layer 108, but the present invention is not limited thereto. In another embodiment, as shown in FIG. 2B, the protective layer 112B may extend from the groove 105 to cover the upper surface 108a of the photocurable layer 108. The range or area of ​​the extending portion of the protective layer 112B can be adjusted according to design requirements.

[0052] Next, referring again to FIG. 2A, the decorated molding 10 can be placed on the light source 300 and emit various colors of light through the protective layer 112A in the groove 105. For example, the light source 300 can be blue light, the protective layer 112A can be a white light-transmitting material, and the second decorative layer 106 can be a wood grain layer. When the light source 300 is turned off, the consumer can see the white light-transmitting laser-engraved pattern on the wood grain layer from the visual surface 110a. Meanwhile, when the light source 300 is turned on, the consumer can see the blue light effect laser-engraved pattern from the visual surface 110a through the protective layer 112A in the groove 105. In one embodiment, the light source 300 can include an LED point light source, an LED light bar, a mini LED, etc. Also, the protective layer 112A can have various colors to produce different color mixing effects in combination with the light source 300. For example, if the light source 300 is blue light and the protective layer 112A is a red light-transmitting material, when the light source 300 is turned on, the consumer can see the laser engraved pattern of purple light effect from the visual surface 110a through the protective layer 112A in the groove 105. In alternative embodiments, the protective layer 112A may be made of a translucent material or an opaque material.

[0053] In the traditional spraying technology, multiple spraying steps and multiple laser engraving steps are required to form a multi-colored film. This technology has the disadvantages of complicated manufacturing process, difficult processing, high cost, and large environmental pollution. In addition, in the traditional decoration process (such as IMD or OMD), hollow printing method is usually used to form a multi-colored film. However, this technology has the disadvantages of difficult alignment, low yield, high material consumption, and high cost after the customer performs processes such as blister molding, cutting, and injection molding. In addition, IMD film and OMD film are relatively thin and therefore not suitable for the laser engraving process. That is, even if the laser engraving process is performed, the laser engraving film may peel off or be damaged due to the poor physical properties of the surface, which results in the need for additional protective coating to protect the film, which increases the cost.

[0054] To solve this problem, in an embodiment of the present invention, an all-in-one coating is formed on a substrate, and a curing process is performed to form a composite layer structure having protective, coloring, and bonding effects. The composite layer structure can form a formed film with excellent physical properties (e.g., high hardness and good protective effect) after the blister molding process. In addition, compared with the conventional spray technology and INS technology, the composite layer structure of the present invention can further simplify the manufacturing process, thereby effectively reducing the manufacturing cost. Therefore, the formed film of the present embodiment can be applied to the laser engraving process to form various translucent decorative molded products. In addition, the present invention partially forms a protective layer 112A or 112B in the groove 105 to protect the laser-engraved texture from damage, thereby improving the protective effect of the composite layer structure 110 and extending its life.

[0055] In addition, in the conventional in-mold labeling (IML) technology, a 3-5 layer decorative layer is formed by screen printing on the back surface of a substrate (e.g., PC, PMMA, ABS, etc.), and then 3-10 layers of adhesive layers are formed and attached to a workpiece. Compared with the conventional IML technology, the substrate 102 of the present embodiment can be melted by high temperature and high pressure during the injection molding process and then directly bonded to a part of the outer surface 200a of the workpiece 200. In other words, compared with the conventional IML technology, the present invention does not require the formation of an additional adhesive layer, so that the manufacturing process of the decorated molded product can be simplified and the manufacturing cost can be reduced.

[0056] Fig. 3 is a flow chart showing a method for producing a decorated molded product according to a second embodiment of the present invention Fig. 4 is a schematic cross-sectional view of a decorated molded product according to a second embodiment of the present invention.

[0057] 3 and 4, the second embodiment of the present invention provides a manufacturing method S20 for the decorated molded product 20 as follows. Step S100 is performed to form a composite layer structure 120 (shown in FIG. 4). Specifically, the step of forming the composite layer structure 120 includes performing step S102 to form a first coating on the substrate 102 (shown in FIG. 4) using a coating method or a printing method. Then, step S104 is performed to form a second coating on the first coating using a coating method, a printing method, or a 3D printing method. Furthermore, step S107 is performed to form a fourth coating on the second coating using a coating method, a printing method, or a 3D printing method. In one embodiment, the fourth coating at least includes a uniformly mixed protective material, an ink material, and a bonding material. Moreover, the coating method, the printing method, the protective material, the ink material, and the bonding material have been described in detail in the above paragraphs, and will not be described again here. It should be noted that the fourth coating is used to form an impact-resistant adhesive layer 118 (shown in FIG. 4). In this embodiment, the content of the bonding material in the fourth coating may be higher than the content of the bonding material in the first coating or the second coating, thereby improving the adhesion between the composite layer structure 120 and the subsequently formed workpiece 200 to form the composite layer structure 120. As shown in FIG. 4, the composite layer structure 120 includes a first decorative layer 104, a second decorative layer 106, and an impact-resistant adhesive layer 118. The first decorative layer 104 can be disposed on the first surface 102a of the substrate 102. The second decorative layer 106 can be disposed on the first decorative layer 104. The impact-resistant adhesive layer 118 can be disposed on the second decorative layer 106, so that the second decorative layer 106 is disposed between the first surface 102a of the substrate 102 and the impact-resistant adhesive layer 118. In addition to the coating method, the impact-resistant adhesive layer 118 may also be formed on the second decorative layer 106 using a lamination method, an embossing method, a 3D printing method, or a jet printing method.Whereas the conventional INS needs to match the ink layer or printing layer with the bonding process of the substrate, and the conventional IML technology needs to form an additional 3 to 10 layers of adhesive layers to attach to the workpiece, the impact-resistant adhesive layer 118 of the present embodiment not only provides a coloring effect, but also has high temperature resistance, protection effect, and bonding effect, and at the same time does not require an additional bonding process or additional adhesive layer. That is, the present invention can effectively simplify the manufacturing process of the composite layer structure 120 and provide the composite layer structure 120 with better high temperature resistance, protection effect, and bonding effect. Furthermore, compared with the conventional spray technology, INS, or IML technology, the composite layer structure of the present invention can further simplify the manufacturing process, thereby effectively reducing the manufacturing cost.

[0058] After forming the composite layer structure 120, proceed to step S120. A blister molding process is performed to form a formed film 100B.

[0059] Next, proceed to step S150. A laser engraving process is carried out to form a groove 105 in the composite layer structure 120. As shown in FIG. 4, the groove 105 can extend downward from the upper surface 120a of the composite layer structure 120 to expose the upper surface 104t of the first decorative layer 104. However, the present invention is not limited thereto. In other embodiments, the groove 105 can have different depths.

[0060] Then, proceed to step S160. Form a protective layer 212 in the groove 105. In one embodiment, the protective layer 212 can be formed by 3D printing technology. Specifically, fill the groove 105 with filling ink through the nozzle of the 3D printing device. In one embodiment, the filling ink may be similar to the fourth coating described above, including at least a uniformly mixed protective material, an ink material, and a bonding material, and the content of the bonding material in the filling ink may be higher than the content of the bonding material in the first coating or the second coating. In addition, after filling the groove 105 with the filling ink, an additional curing process may be performed, which can improve the adhesion between the composite layer structure 120 and the workpiece 200 to be formed later. In this case, the protective layer 212 can partially protect the laser-engraved texture. That is, the first decorative layer 104 and the second decorative layer 106 exposed by the groove 105 can be prevented from being damaged, so that the protective effect of the composite layer structure 120 can be further improved and the life can be extended. In an alternative embodiment, the protective layer 212 may be formed by jet printing techniques.

[0061] In an alternative embodiment, 3D printing technology can be used to backfill the laser engraved translucent areas (e.g., grooves 105) with a protective layer, and at the same time, the 3D printing technology can also create different effects in the non-laser engraved translucent areas, such as forming logos, gradients, or other similar opaque film effects. Additional photocurable layers can then be selectively formed by lamination, embossing, 3D printing, or jet printing.

[0062] Then, proceed to step S170. An in-mold decoration technique or an out-mold decoration technique is carried out to attach the formed film 100B to the inner surface 200b of the workpiece 200 to form the decorated formed product 20 shown in FIG. 4. Specifically, the inner surface 200b of the workpiece 200 may contact the upper surface 120a of the composite layer structure 120 and the upper surface of the protective layer 212. In this embodiment, the outer surface 200a of the workpiece 200 may be a visual surface, so that consumers can see the visual effect of the formed film 100B from the outer surface 200a of the workpiece 200 with a deep crystal-like thickness texture. In addition, the in-mold decoration and out-mold decoration techniques have been described in detail in the above paragraphs, so they will not be described again here.

[0063] Fig. 5 is a flow chart showing a method for producing a decorated molded product according to a third embodiment of the present invention Fig. 6 is a schematic cross-sectional view of a decorated molded product according to the third embodiment of the present invention.

[0064] As shown in FIG. 5 and FIG. 6, the third embodiment of the present invention provides a manufacturing method S30 of a decorated molded product 30 as follows. First, step S100 is performed to form a composite layer structure 130 (shown in FIG. 6). Specifically, the step of forming the composite layer structure 130 includes performing step S101 to apply a second coating to a substrate (shown in FIG. 6) using a coating method or a printing method. Then, step S103 is performed to apply a first coating on the second coating using a coating method or a printing method. In one embodiment, as shown in FIG. 6, the first coating is used to form a first decorative layer 104, and the second coating is used to form a second decorative layer 106. In this embodiment, the first coating and the second coating do not require an additional curing step (i.e., at room temperature) to form the first decorative layer 104 and the second decorative layer 106, so that the composite layer structure 130 is formed. As shown in FIG. 6, the composite layer structure 130 includes the first decorative layer 104 and the second decorative layer 106. The second decorated layer 106 can be disposed on the second surface 102b of the substrate 102. The first decorated layer 104 can be disposed below the second decorated layer 106, such that the second decorated layer 106 is sandwiched between the second surface 102b of the substrate 102 and the first decorated layer 104.

[0065] After forming the composite layer structure 130, proceed to step S120. A blister molding process is performed to form a formed film 100C.

[0066] Then, proceed to step S150. A laser engraving process is carried out to form a groove 105 in the composite layer structure 130. As shown in FIG. 6, the groove 105 can extend upward from the bottom surface 130b of the composite layer structure 130 to expose the bottom surface 106b of the second decorative layer 106. However, the present invention is not limited thereto. In other embodiments, the groove 105 can have different depths.

[0067] Next, proceed to step S160. Form a protective layer 312 in the groove 105. In one embodiment, the protective layer 312 can be formed by 3D printing technology. Specifically, fill the groove 105 with filling ink through the nozzle of the 3D printing device. In one embodiment, the filling ink may be similar to the fourth coating described above, including at least a uniformly mixed protective material, an ink material, and a bonding material, and the content of the bonding material in the filling ink may be higher than the content of the bonding material in the first coating or the second coating. In addition, after filling the groove 105 with the filling ink, an additional curing process may be performed, thereby improving the adhesion between the composite layer structure 130 and the light source 300. In this case, the protective layer 312 can partially protect the laser-engraved texture. That is, the first decorative layer 104 and the second decorative layer 106 exposed by the groove 105 can be prevented from being damaged, so that the protective effect of the composite layer structure 130 can be further improved and the life can be extended. In an alternative embodiment, the protective layer 312 may be formed by a jet printing technique.

[0068] Then, proceed to step S160. An in-mold decoration technique or an out-mold decoration technique is carried out to attach the formed film 100C to the inner surface 200b of the workpiece 200 to form the decorated formed product 30 shown in FIG. 6. Specifically, the inner surface 200b of the workpiece 200 contacts the first surface 102a of the substrate 102. The light source 300 may contact the bottom surface 130b of the composite layer structure 130 and the bottom surface of the protective layer 312. In this embodiment, the outer surface 200a of the workpiece 200 may be a visual surface, so that consumers can see the visual effect of the formed film 100C from the outer surface 200a of the workpiece 200. In addition, the in-mold decoration and out-mold decoration techniques have been described in detail in the above paragraphs, and will not be described again here.

[0069] In this embodiment, as shown in FIG. 6, the decorated molding 30 can emit light of various colors through the protective layer 312 in the groove 105. For example, the light source 300 can be blue light, the protective layer 312 can be a white translucent material, and the second decorative layer 106 can be a geometric pattern layer. When the light source 300 is turned off, the consumer can see the entire geometric pattern from the visual surface 200a. Meanwhile, when the light source 300 is turned on, the consumer can see the laser carved pattern with a blue geometric pattern effect from the visual surface 200a through the protective layer 312 in the groove 105. In addition, the protective layer 312 can have various colors to produce different color mixing effects in combination with the light source 300.

[0070] FIG. 7 is a schematic cross-sectional view of a decorated molded product according to a fourth embodiment of the present invention.

[0071] Referring to FIG. 7, the decorated molded product 40 of the fourth embodiment may include a workpiece 200 and a forming film 100D. The forming film 100D may be disposed on the outer surface 200a of the workpiece 200, and the light source 300 may be disposed on the inner surface 200b of the workpiece 200. Specifically, the forming film 100D may include a substrate 102, a photocurable layer 108, and a composite layer structure 140. The substrate 102 has a first surface 102a and a second surface 102b facing each other. The photocurable layer 108 may be disposed on the first surface 102a of the substrate 102. In this embodiment, the photocurable layer 108 may be formed with a third coating, and the content of the protective material may be higher than that of the first coating or the second coating. In this embodiment, the photocurable layer 108 is also called an all-in-one hard coating. In this embodiment, the top surface 108a of the photocurable layer 108 may be a visual surface, so that consumers can see the visual effect of the formed film 100D from the top surface 108a of the photocurable layer 108. Furthermore, in addition to the coating method, the photocurable layer 108 may be formed on the first surface 102a of the substrate 102 using a lamination method, an embossing method, a 3D printing method, or a jet printing method.

[0072] Also, the composite layer structure 140 can be disposed on the second surface 102b of the substrate 102. Specifically, the composite layer structure 140 can include, from bottom to top, an impact-resistant adhesive layer 118, a buffer layer 142 (or a decorative layer), a third decorative layer 144, and a fourth decorative layer 146. In this embodiment, the impact-resistant adhesive layer 118 can be formed by a fourth coating, and the content of the bonding material can be higher than that of the first coating or the second coating. In addition, in addition to the coating method, the impact-resistant adhesive layer 118 can be formed by a lamination method, an embossing method, a 3D printing method, or a jet printing method. In one embodiment, the material of the buffer layer 142 includes polyurethane (PU) and polymethyl methacrylate (PMMA), which has the effect of preventing ink from fading and improving the resolution of laser engraving. In one embodiment, the third decorative layer 144 may be formed by a first coating, and may be printed once or multiple times to display different decorative patterns, such as wood grain and geometric patterns. In one embodiment, the fourth decorative layer 146 may be formed by a second coating, and may be formed on the second surface 102b of the substrate 102 by physical vapor deposition (e.g., evaporation, sputtering, etc.), electroplating, etc. For example, the third decorative layer 144 may be a wood grain layer, and the fourth decorative layer 146 may have an evaporated metal layer with a transparency of 50%, so that the composite layer structure 140 can display a metal color wood grain pattern with a transparency of 50%. Also, although FIG. 7 shows only two decorative layers 144 and 146, the present invention is not limited thereto. In another embodiment, multiple decorative layers may be formed alternately according to the requirements of different effects.

[0073] It should be noted that the decorated molded product 40 further includes a groove 105 formed in the impact-resistant adhesive layer 118 and the buffer layer 142, and the groove 105 can be filled with the protective layer 412 using 3D printing technology or jet printing technology. The material and forming method of the protective layer 412 are the same as the protective layers 212 and 312 described above, so they are not repeated here. In another embodiment, the protective layer 412 may have different depths. That is, the protective layer 412 may extend upward into the third decorative layer 144 and / or the fourth decorative layer 146. The outer surface 200a of the workpiece 200 may contact the bottom surface 140b of the composite layer structure 140 and the bottom surface of the protective layer 412.

[0074] In this embodiment, as shown in FIG. 7, the decorative molding 40 can emit light of various colors through the protective layer 412 in the groove 105. For example, the light source 300 can be blue light, the protective layer 412 can be a white translucent material, and the fourth decorative layer 146 can be a vapor-deposited metal layer with a transparency of 50%. When the light source 300 is turned off, the consumer can see the entire vapor-deposited metal layer from the visual surface 108a. Meanwhile, when the light source 300 is turned on, the consumer can see the laser-engraved pattern of blue metal effect from the visual surface 108a through the protective layer 412 in the groove 105. In addition, the protective layer 412 can have various colors to produce different color mixing effects in combination with the light source 300.

[0075] FIG. 8 is a schematic cross-sectional view of a decorated molded product according to a fifth embodiment of the present invention.

[0076] Referring to FIG. 8, the decorated molded product 50 of the fifth embodiment can include a workpiece 200 and a formed film 100E. The formed film 100E can be disposed on the outer surface 200a of the workpiece 200, and the light source 300 can be disposed on the inner surface 200b of the workpiece 200. Specifically, the formed film 100E can include a substrate 102, a first composite layer structure 150, and a second composite layer structure 160. The substrate 102 has a first surface 102a and a second surface 102b facing each other. The first composite layer structure 150 can be disposed on the first surface 102a of the substrate 102. The first composite layer structure 150 can include a photocurable layer 108 and a light-transmitting layer 154. The material of the light-transmitting layer 154 includes polymethacrylic resin having a decorative layer effect with chemical resistance. The light-transmitting layer 154 may contact the first surface 102a of the substrate 102, and the photocurable layer 108 is disposed on the light-transmitting layer 154. In this embodiment, the top surface 108a of the photocurable layer 108 may be a visual surface, so that consumers can see the visual effect of the formed film 100E from the top surface 108a of the photocurable layer 108. Furthermore, besides the coating method, the photocurable layer 108 may be formed using a lamination method, an embossing method, a 3D printing method, or a jet printing method.

[0077] Furthermore, the second composite layer structure 160 can be disposed on the second surface 102b of the substrate 102. Specifically, the second composite layer structure 160 can include an impact-resistant adhesive layer 118 and a fourth decorative layer 146. The fourth decorative layer 146 can be in contact with the second surface 102b of the substrate 102, and the impact-resistant adhesive layer 118 can be disposed below the fourth decorative layer 146, so that the fourth decorative layer 146 is sandwiched between the second surface 102b of the substrate 102 and the impact-resistant adhesive layer 118. In this embodiment, the fourth decorative layer 146 can be formed by a second coating, and can be formed on the second surface 102b of the substrate 102 by a physical vapor deposition method (e.g., evaporation method, sputtering method, etc.), an electroplating method, etc. For example, the light-transmitting layer 154 may be a translucent black layer, and the fourth decorative layer 146 may have a vapor-deposited metal layer with a transparency of 25%, so that the molded film 100E displays a black metal color with a transparency of 25%. In addition to the coating method, the impact-resistant adhesive layer 118 may be formed using a lamination method, an embossing method, a 3D printing method, or a jet printing method.

[0078] It should be noted that the decorated molded product 50 further includes a groove 105 formed in the first composite layer structure 150, and the groove 105 can be filled with a protective layer 512 using 3D printing technology or jet printing technology. The material and forming method of the protective layer 512 are the same as the protective layers 112A and 112B described above, and will not be described again here. In this embodiment, the protective layer 512 may extend downward from the upper surface 108a of the photocurable layer 108 into the light-transmitting layer 154. The bottom surface 160b of the second composite layer structure 160 may contact the outer surface 200a of the workpiece 200, and can be attached to the outer surface 200a of the workpiece 200 via the impact-resistant adhesive layer 118.

[0079] FIG. 11 is a schematic cross-sectional view of a decorated molded product according to a sixth embodiment of the present invention.

[0080] Referring to FIG. 11, the decorated molded product 60 of the sixth embodiment may include a workpiece 200 and a formed film 100F. The formed film 100F may be disposed on the outer surface 200a of the workpiece 200, and the light source 300 may be disposed on the inner surface 200b of the workpiece 200. Specifically, the formed film 100F may include a substrate 102 and a composite layer structure 170. The substrate 102 has a first surface 102a and a second surface 102b facing each other. The composite layer structure 170 may be disposed on the first surface 102a of the substrate 102. The composite layer structure 170 may include a fourth decorated layer 146 and a photocurable layer 108. The fourth decorated layer 146 may contact the first surface 102a of the substrate 102, and the photocurable layer 108 is disposed on the fourth decorated layer 146. In this embodiment, the upper surface 108a of the photocurable layer 108 may be a visual surface, so that consumers can see the visual effect of the molded film 100F from the upper surface 108a of the photocurable layer 108. In this embodiment, the fourth decorative layer 146 may be formed by a second coating, and can be formed on the first surface 102a of the substrate 102 by a physical vapor deposition method (e.g., deposition method, sputtering method, etc.), electroplating method, etc. The photocurable layer 108 has a protective effect and can prevent the fourth decorative layer 146 from being scratched or damaged. In addition, besides the coating method, the photocurable layer 108 may be formed using a lamination method, an embossing method, a 3D printing method, a jet printing method.

[0081] It should be noted that the decorated molded product 60 further includes a groove 105 formed in the composite layer structure 170, and the groove 105 can be filled with a protective layer 612 using 3D printing technology or jet printing technology. The material and forming method of the protective layer 612 are the same as those of the protective layers 112A and 112B described above, and therefore will not be repeated here. In this embodiment, the protective layer 512 may extend downward from the upper surface 108a of the photocurable layer 108 into the fourth decorative layer 146.

[0082] Fig. 12A is a schematic cross-sectional view of a decorated molded product according to a seventh embodiment of the present invention, Fig. 12B and Fig. 12C are schematic top views of the structure of Fig. 12A when the light source is off and when the light source is on, respectively.

[0083] Referring to FIG. 12A, the decorated molded product 70 of the seventh embodiment may include a workpiece 200 and a formed film 100G. The formed film 100G may be disposed on the outer surface 200a of the workpiece 200, and the light source 300 may be disposed on the inner surface 200b of the workpiece 200. Specifically, the formed film 100G may include a substrate 102, a composite layer structure 180, and an impact-resistant adhesive layer 118. The substrate 102 has a first surface 102a and a second surface 102b facing each other. The composite layer structure 180 may be disposed on the first surface 102a of the substrate 102. The composite layer structure 180 may include a third decorative layer 144, a fourth decorative layer 146, and a photocurable layer 108. The fourth decorative layer 146 may contact the first surface 102a of the substrate 102. The photocurable layer 108 may be disposed on the fourth decorative layer 146. The third decorative layer 144 can be disposed between the fourth decorative layer 146 and the photocured layer 108. In this embodiment, the upper surface 108a of the photocured layer 108 can be a visual surface, so that consumers can see the visual effect of the formed film 100G from the upper surface 108a of the photocured layer 108. In this embodiment, the third decorative layer 144 can be formed by a first coating and can be printed once or multiple times to display different decorative patterns, such as wood grain and geometric patterns. The fourth decorative layer 146 can be formed by a second coating and can be formed on the first surface 102a of the substrate 102 by physical vapor deposition (e.g., deposition, sputtering, etc.), electroplating, etc. The photocured layer 108 has a protective effect and can prevent the third decorative layer 144 from scratches and damage. Meanwhile, the impact-resistant adhesive layer 118 may be disposed on and contact the second surface 102b of the substrate 102. In this embodiment, the molded film 100G may be attached to the outer surface 200a of the workpiece 200 via the impact-resistant adhesive layer 118. In addition to the coating method, the photocurable layer 108 and the impact-resistant adhesive layer 118 may be formed using a lamination method, an embossing method, a 3D printing method, or a jet printing method.

[0084] It should be noted that the decorated molded product 70 further includes a first groove 105a and a second groove 105b, and the first groove 105a can be filled with the first protective layer 712A and the second groove 105b can be filled with the second protective layer 712B using 3D printing technology or jet printing technology. In one embodiment, the first protective layer 712A and the second protective layer 712B have different material compositions. Specifically, the material of the first protective layer 712A can be similar to the third coating described above, and the second protective layer 712B can be similar to the fourth coating described above. The content of the protective material of the first protective layer 712A can be higher than the content of the protective material of the second protective layer 712B, and the content of the bonding material of the second protective layer 712B can be higher than the content of the bonding material of the first protective layer 712A. As can be seen from Fig. 12A, the first protective layer 712A is formed in the composite layer structure 180. That is, the first protective layer 712A extends downward from the upper surface 108a of the light cured layer 108 into the third decorative layer 144. The second protective layer 712B is formed on the impact-resistant adhesive layer 118. That is, the first protective layer 712A and the second protective layer 712B are respectively formed on the opposite sides (i.e., the upper side and the lower side) of the decorated molded product 70 of this embodiment to increase different light transmission areas, thereby improving the visual perception of consumers.

[0085] In this embodiment, as shown in Figures 12B and 12C, the decorative molding 70 can emit light of various colors through the first protective layer 712A and the second protective layer 712B in the grooves 105a and 105b. For example, the light source 300 can be a blue light, the protective layers 712A and 712B can be a white translucent material, the third decorative layer 144 can be a wood grain layer, and the fourth decorative layer 146 can be a vapor-deposited metal layer with a transparency of 50%. When the light source 300 is turned off, as shown in Figure 12B, the consumer can see the wood grain layer with a metal edge from the visual surface 108a through the first protective layer 712A in the first groove 105a. Meanwhile, when the light source 300 is turned on, the consumer can see the wood grain layer with metal edges and blue characters from the visual surface 108a through the first protective layer 712A in the first groove 105a and the second protective layer 712B in the second groove 105b. Also, the protective layers 712A, 712B can have different colors to produce different color mixing effects in combination with the light source 300.

[0086] Fig. 13A is a schematic cross-sectional view of a decorated molded product according to an eighth embodiment of the present invention, Fig. 13B and Fig. 13C are schematic top views of the structure of Fig. 13A when the light source is off and when the light source is on, respectively.

[0087] As shown in FIG. 13A, the decorated molded product 80 of the eighth embodiment can include a workpiece 200 and a formed film 100H. The formed film 100H can be disposed on the inner surface 200b of the workpiece 200, and the light source 300 can be disposed below the formed film 100H, so that the formed film 100H is sandwiched between the workpiece 200 and the light source 300. Specifically, the formed film 100H can include a substrate 102 and a composite layer structure 190. The substrate 102 has a first surface 102a and a second surface 102b facing each other. The composite layer structure 190 can be disposed on the first surface 102a of the substrate 102. The composite layer structure 190 can include a third decorative layer 144, a fourth decorative layer 146, and an impact-resistant adhesive layer 118. The fourth decorative layer 146 may contact the first surface 102a of the substrate 102. The impact-resistant adhesive layer 118 can be disposed on the fourth decorative layer 146. The third decorative layer 144 can be disposed between the fourth decorative layer 146 and the impact-resistant adhesive layer 118. In this embodiment, the outer surface 200a of the workpiece 200 can be a visual surface, so that consumers can see the visual effect of the formed film 100H from the outer surface 200a of the workpiece 200. In this embodiment, the third decorative layer 144 can be formed by a first coating, and can be printed once or multiple times to display different decorative patterns, such as wood grain and geometric patterns. The fourth decorative layer 146 can be formed by a second coating, and can be formed on the first surface 102a of the substrate 102 by physical vapor deposition (e.g., deposition, sputtering, etc.), electroplating, etc. The impact-resistant adhesive layer 118 can have an adhesive function, so that the formed film 100H can be attached to the inner surface 200b of the workpiece 200 through the impact-resistant adhesive layer 118. In addition to the coating method, the impact-resistant adhesive layer 118 may also be formed using a lamination method, an embossing method, a 3D printing method, or a jet printing method.

[0088] It should be noted that the decorated molding 80 further includes a first groove 105a and a second groove 105b, and the first groove 105a can be filled with a first protective layer 812A and the second groove 105b can be filled with a second protective layer 812B using 3D printing technology or jet printing technology. In one embodiment, the first protective layer 812A and the second protective layer 812B have the same material composition. Specifically, the materials of the first protective layer 812A and the second protective layer 812B can be similar to those of the above-mentioned fourth coating for forming an impact-resistant adhesive layer, and will not be described again here. As can be seen from FIG. 13A, the first protective layer 812A is formed in the composite layer structure 190. That is, the first protective layer 812A extends downward from the upper surface 118a of the impact-resistant adhesive layer 118 into the third decorative layer 144. The second protective layer 812B is formed in the substrate 102 and extends from the first surface 102a to the second surface 102b. That is, the decorative molded product 80 of this embodiment has grooves formed on the opposite sides (i.e., the upper and lower sides) to increase different light transmission areas, thereby improving the visual perception of consumers.

[0089] In this embodiment, as shown in Figures 13B and 13C, the decorative molding 80 can emit light of various colors through the first protective layer 812A and the second protective layer 812B in the grooves 105a and 105b. For example, the light source 300 can be a blue light, the protective layers 812A and 812B can be a white translucent material, the third decorative layer 144 can be a wood grain layer, and the fourth decorative layer 146 can be a vapor-deposited metal layer with a transparency of 50%. When the light source 300 is turned off, as shown in Figure 13B, the consumer can see the wood grain layer with a metal edge from the visual surface 200a through the first protective layer 812A in the first groove 105a. Meanwhile, when the light source 300 is turned on, the consumer can see the wood grain layer with metal edges and blue characters from the visual surface 200a through the first protective layer 812A in the first groove 105a and the second protective layer 812B in the second groove 105b. Also, the protective layers 812A, 812B can have different colors to produce different color mixing effects in combination with the light source 300.

[0090] Fig. 14 is a flow chart showing a method for producing a decorated molded product according to a ninth embodiment of the present invention.Fig. 15A to Fig. 15E are schematic cross-sectional views showing the process for producing a decorated molded product according to the ninth embodiment of the present invention.

[0091] 14 and 15A, the ninth embodiment of the present invention provides a manufacturing method S40 for a decorated molded product 90 as follows. First, perform step S100 to form a composite layer structure 110 (shown in FIG. 15A). Step S100 has been described in detail in the above paragraphs, so will not be repeated here. After forming the composite layer structure 110, perform step S120. A blister molding process is performed to form a molded film 100I.

[0092] Next, proceed to step S130. An in-mold decoration technique or an out-mold decoration technique is performed to attach the molded film 100I to the outer surface 200a of the workpiece 200 to form the decorated molded product 90 shown in Fig. 15A. The in-mold decoration technique and the out-mold decoration technique have been described in detail in the above paragraphs, so they will not be described again here.

[0093] 14, after the decorated molded article 90 is formed, the process proceeds to step S140, in which a second curing process is carried out to increase the hardness of the composite layer structure 110.

[0094] Next, proceed to step S142. A mask layer 902 is formed on the composite layer structure 110. In one embodiment, the mask layer 902 covers the upper surface 110a of the composite layer structure 110, as shown in Figure 15A.

[0095] Next, proceed to step S150. A laser engraving process is performed to form a groove 905 in the mask layer 902 and the composite layer structure 110. As shown in FIG. 15B, the groove 905 can extend downward from the upper surface 110a of the composite layer structure 110 until it penetrates the mask layer 902 and exposes the upper surface 104t of the first decorated layer 104. However, the present invention is not limited thereto, and in another embodiment, the groove 905 may have a different depth. That is, the bottom surface 905bt of the groove 905 may be higher or lower than the upper surface 104t of the first decorated layer 104, or the bottom surface 905bt of the groove 905 may be higher, lower, or equal to the upper surface 106t of the second decorated layer 106. Also, although FIG. 15B shows only one groove 905, the present invention is not limited thereto. In an alternative embodiment, the decorative molding 90 may have a plurality of recessed grooves to form a laser engraved pattern, which can improve the visual perception of the consumer.

[0096] Then, proceed to step S152. The plating layer 904 is formed by using a deposition method or a sputtering method. Specifically, the plating layer 904 can fill the grooves 905 and cover the upper surface of the mask layer 902. It should be noted that the plating layer 904 does not completely fill the grooves 905. That is, the plating layer 904 covers the bottom surface 905bt of the grooves 905, as shown in FIG. 15C, and at the same time, exposes a part of the side wall 905sw of the grooves 905. In one embodiment, the material of the plating layer 904 includes a metal material. In this embodiment, the plating layer 904 may be a sputtered metal layer.

[0097] Next, proceed to step S154. The mask layer 902 is removed. Specifically, the mask layer 902 is removed, and at the same time, the plating layer 904 on the mask layer 902 can also be removed. That is, after the mask layer 902 is removed, the remaining plating layer 904 is disposed only in the grooves 905, as shown in FIG. 15D.

[0098] Then, proceed to step S160. The protective layer 912 is formed in the groove 905, so that the protective layer 912 covers and seals the plating layer 904. Specifically, the protective layer 912 may be formed by 3D printing technology. The material and forming method of the protective layer 912 are the same as the above-mentioned protective layers 112A and 112B, so they will not be described again here. It should be noted that in this embodiment, the protective layer 912 can partially protect the laser-engraved texture. That is, it can prevent the plating layer 904 and the second decorative layer 106 exposed by the groove 905 from being damaged, so that the protective effect of the composite layer structure 110 can be further improved and the service life can be extended.

[0099] 15E is located only in the groove 905, the present invention is not limited thereto. In another embodiment, the protective layer (not shown) may extend from the groove 905 to cover the upper surface 108a of the light curable layer 108. The range or area of ​​the extending portion of the protective layer can be adjusted according to design requirements.

[0100] Referring again to FIG. 15E, the decorative molding 90 is placed on the light source 300, and can emit various colors of light through the protective layer 912 in the groove 905. For example, the light source 300 can be a blue light, the plating layer 904 can be a sputtered silver layer with a transparency of 50%, the protective layer 912 can be a white translucent material, and the second decorative layer 106 can be a wood grain layer. When the light source 300 is turned off, the consumer can see the laser engraved pattern of the metallic silver color on the wood grain layer from the visual surface 110a. Meanwhile, when the light source 300 is turned on, the consumer can see the laser engraved pattern of the metallic effect of silver blue from the visual surface 110a through the protective layer 912 in the groove 905.

[0101] FIG. 16 is a schematic cross-sectional view of a decorated molded article according to an alternative embodiment of the present invention.

[0102] As shown in FIG. 16, the decorative molded product 70' may include a workpiece 200 and a molded film 100G'. The molded film 100G' may be disposed on the outer surface 200a of the workpiece 200, and the light source 300 may be disposed on the inner surface 200b of the workpiece 200. Specifically, the molded film 100G' may include a substrate 102, a composite layer structure 780, and an impact-resistant adhesive layer 118. Basically, the decorative molded product 70' in FIG. 16 is similar to the decorative molded product 70 in FIG. 12A, and the similar components have been described in the above-mentioned embodiments, so details will be omitted here. The main difference between the two is that the composite layer structure 780 includes a nonwoven fabric layer 744, a real wood grain sheet layer 746, and a photocured layer 108. The nonwoven fabric layer 744 may be attached to the first surface 102a of the substrate 102 via an adhesive layer 742. The real wood grain sheet layer 746 can be disposed between the nonwoven fabric layer 744 and the photocurable layer 108. In this embodiment, the top surface 108a of the photocurable layer 108 can be a visual surface, so that a consumer can see the visual effect of the formed film 100G' from the top surface 108a of the photocurable layer 108.

[0103] It should be noted that the decorated molding 70' also includes a first groove 105a and a second groove 105b, and the first groove 105a can be filled with a first protective layer 712A and the second groove 105b can be filled with a second protective layer 712B using 3D printing or jet printing technology. In one embodiment, the first protective layer 712A and the second protective layer 712B have different material compositions. As can be seen from FIG. 16, the first protective layer 712A is formed in a composite layer structure 780. That is, the first protective layer 712A extends downward from the upper surface 108a of the photocured layer 108 into the real wood grain sheet layer 746. The second protective layer 712B is formed in the impact-resistant adhesive layer 118. That is, the first protective layer 712A and the second protective layer 712B are formed on the opposite sides (i.e., the upper side and the lower side) of the decorated molded product 70' of this embodiment, respectively, to increase different light transmission areas, thereby improving the visual perception of consumers. In this case, the decorated molded product 70' can emit light of various colors through the first protective layer 712A and the second protective layer 712B in the grooves 105a and 105b.

[0104] The process of performing steps S142 to S160 to partially form a plating layer and a protective layer in the groove can be applied to any of the above-mentioned decorated molded products 20, 30, 40, 50, 60, 70, 70', and 80. For example, after performing steps S142 to S160 to form a plating layer and a protective layer in the groove, step S170 is performed, that is, an in-mold decoration technique or an out-mold decoration technique is performed to attach the molding film to the inner surface of the workpiece. In such an embodiment, since the protective layer is attached to the inner surface of the workpiece, the material of the protective layer is a material similar to that of the fourth coating to form an impact-resistant adhesive layer. That is, the process of partially forming a plating layer and a protective layer in the groove can be applied to the structures of various decorated molded products according to the requirements of the product.

[0105] Also, any one of the decorative molded products 10, 20, 30, 40, 50, 60, 70, 70', 80, and 90 can be applied to vehicle lighting. That is, any one of the decorative molded products 10, 20, 30, 40, 50, 60, 70, 70', 80, and 90 can be attached to the plastic shell of a car lamp to display various different color effects through the laser engraving pattern (e.g., the groove 105). For example, the present invention can correspond to a plurality of grooves 105 corresponding to lamp bodies of different colors, so that the brake lamp can be displayed with red light through the first groove, the left turn lamp can be displayed with yellow light through the second groove, and the head lamp can be displayed with white light through the third groove.

[0106] It should be noted that the disclosed method S40 of FIG. 14 is shown and described as a series of acts and events, but is not limited by the order of these acts and events. That is, some acts may occur in a different order and / or simultaneously with other acts or events than shown and / or described herein. For example, the steps of mask layer formation, laser engraving process, and 3D printing are covered by the present invention regardless of the order of the processes. Also, not all acts shown are necessarily required to practice one or more aspects or embodiments of the present specification. Furthermore, one or more acts described herein may be performed in one or more separate acts and / or phases.

[0107] As described above, the present invention forms an all-in-one coating on a substrate, and then performs a curing process to form a composite layer structure having protective, coloring and bonding effects. This composite layer structure can form a formed film with excellent physical properties (e.g., high hardness and good protective effect) after the blister molding process. Therefore, the formed film of this embodiment can be applied to a laser engraving process to form various translucent decorative molded products. In addition, the present invention further partially forms a protective layer in the groove to protect the texture from damage after laser engraving, thereby improving the protective effect of the composite layer structure and extending its life. Furthermore, the present invention performs the laser engraving process after the blister molding process. Therefore, the present invention can solve the alignment problem of the prior art, thereby improving the yield and reducing the manufacturing cost.

[0108] On the other hand, while the conventional INS requires that the ink layer or the printing layer be matched to the bonding process of the substrate, the multiple laminated decorative layers in the present embodiment not only provide a variety of coloring effects, but also have a protective effect and a bonding effect, and no additional bonding process is required. Furthermore, while the conventional IML technology requires that an additional 3 to 10 adhesive layers be formed to attach to the workpiece, the present embodiment does not require the formation of an additional adhesive layer. That is, the present invention can effectively simplify the manufacturing process of the composite layer structure and provide a composite layer structure with better protective and bonding effects. Furthermore, compared with the conventional spray technology, INS technology, or IML technology, the decorated molded product of the present invention can further simplify the manufacturing process, thereby effectively reducing the manufacturing cost.

Claims

1. providing a coating including at least a uniformly mixed protective material, an ink material, and a bonding material; forming said coating on a substrate using a coating or printing method; performing a first curing step to form a composite layer structure; performing a blister molding process to form a formed film; Carrying out a second curing step to increase the hardness of the formed film; Carrying out a laser engraving process to form a recess; forming a protective layer in the groove, the protective layer including at least the protective material, the ink material, and the bonding material that are uniformly mixed, and a content of the protective material in the protective layer is higher than a content of the protective material in the coating; applying the molded film to a surface of a workpiece to form a decorated molded article; A method for producing a decorated molded product comprising the steps of:

2. 2. The method for manufacturing a decorated molded product according to claim 1, wherein the protective material comprises polymethyl methacrylate (PMMA), an aliphatic urethane diacrylate, an epoxy acrylate (EA), a polyester polyol, or a combination thereof, the ink material comprises polyurethane (PU), and the bonding material comprises thermoplastic polyurethane (TPU), an aromatic urethane diacrylate, or a combination thereof.

3. The method for manufacturing a decorated molded product according to claim 1 , wherein the protective layer is formed using a 3D printing method or a jet printing method.

4. the step of applying the formed film to the surface of the workpiece comprises: The method for manufacturing the decorated molded product according to claim 1, further comprising: performing an in-mold decoration or out-mold decoration technique on the molded film after performing the blister molding process, and attaching the molded film to the outer surface of the workpiece to form the decorated molded product.

5. the step of applying the formed film to the surface of the workpiece comprises: The method for manufacturing the decorated molded product according to claim 1, further comprising: performing an in-mold decoration or out-mold decoration technique on the molded film after performing the blister molding process, and attaching the molded film to the inner surface of the workpiece to form the decorated molded product.

6. Providing a substrate having opposing first and second surfaces; forming a second coating on the second surface of the substrate using a painting or printing method; forming the first coating on the second coating using a painting or printing method; Carry out the first curing step, The substrate; A first decorative layer disposed on the second surface of the base material; A second decorative layer disposed between the second surface of the base material and the first decorative layer; forming a composite layer structure including at least performing a blister molding process to form a formed film; Carrying out a laser engraving process to form a recess; forming a protective layer in the groove, the protective layer including at least a uniformly mixed protective material, an ink material, and a bonding material, the content of the bonding material in the protective layer being higher than the content of the bonding material in the first coating or the second coating layer; applying the molded film to a surface of a workpiece to form a decorated molded article; A method for producing a decorated molded product comprising the steps of:

7. The method for manufacturing a decorated molded product according to claim 6 , wherein the first coating and the second coating each contain the protective material, the ink material, and the bonding material that are uniformly mixed.

8. The method for manufacturing a decorated molded product according to claim 6 , wherein the protective layer is formed using a 3D printing method or a jet printing method.

9. providing a coating including at least a uniformly mixed protective material, an ink material, and a bonding material; forming said coating on a substrate using a coating or printing method; performing a first curing step to form a composite layer structure; performing a blister molding process to form a formed film; Carrying out a second curing step to increase the hardness of the formed film; forming a mask layer over the composite layer structure; performing a laser engraving process to form recessed grooves in the mask layer and the composite layer structure; forming a plating layer on the mask layer by using a vapor deposition method or a sputtering method, and filling a part of the plating layer in the groove; removing the mask layer and the plating layer thereon; forming a protective layer in the groove, the protective layer covering the plating layer; applying the molded film to a surface of a workpiece to form a decorated molded article; A method for producing a decorated molded product comprising the steps of:

10. The method for manufacturing a decorated molded product according to claim 9 , wherein the protective layer is formed using a 3D printing method or a jet printing method.

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