ENERGY STORAGE PLANT AND ENERGY STORAGE METHOD

Abstract

The energy storage plant (1) comprises a casing (5) for storing a working fluid different from the atmosphere in a gaseous phase in pressure equilibrium with the atmosphere, and a tank (9) for storing the working fluid in a liquid or supercritical phase having a temperature close to a critical temperature, the critical temperature being close to ambient temperature. The plant (1) is configured to perform a closed cyclic thermodynamic conversion (CTT) between the casing (5) and the tank (9), first in one direction in a charging configuration and then in the opposite direction in a discharging configuration, so that the plant (1) stores heat and pressure in the charging configuration and generates mechanical energy in the discharging configuration to drive a driven machine.

Description

[Technical field]

[0001] The object of the present invention is a plant and a method for energy storage. More precisely, the object of the present invention is a system capable of absorbing / using energy, maintaining the stored energy over time, reconverting it into mechanical energy for the operation of one or more driven machines, and possibly also converting it into electrical energy and reinjecting it into the grid when said electrical energy is required. Preferably, but not exclusively, the system is capable of absorbing / using electrical energy from the grid or the system during periods of excess or underconsumption of power and / or from electric motors or heat engines (e.g. from gas or steam turbines) or even from other types of motors (e.g. hydraulic or wind). More particularly, the present invention relates to a system for storing electrical energy in the form of potential energy (pressure) and thermal / thermodynamic energy. The present invention is typically located in the field of medium and large-scale energy storage systems for both land and marine applications, with powers ranging from hundreds of kW up to tens of MW (e.g. 20-25 MW) and even hundreds of MW, with storage capacities from hundreds of kWh up to hundreds of MWh and even various GWh. The invention is also situated in the field of small scale energy storage systems, both land and marine, domestic and commercial, typically with power ranging from a few kW to hundreds of kW, and with storage capacities from a few kWh up to hundreds of kWh.

[0002] In this specification and the appended claims, reference is made to the following definitions. Thermodynamic cycle (TC): a thermodynamic transformation from point X to point Y, where X coincides with Y. A TC, unlike a CTT (cyclic thermodynamic transformation) described below, does not have a mass accumulation (significant for energy purposes) within the cycle, but a CTT typically operates between two stores of working fluid, an initial store on one side and a final store on the other. Cyclic Thermodynamic Transformation (CTT): A thermodynamic transformation from point X to point Y and from point Y to point X, without necessarily passing through the same intermediate points. Closed TC and / or CTT: no mass exchange (important for energy purposes) with the atmosphere. · Open TC and / or CTT: involving mass exchange (important for energy purposes) with the atmosphere. [Background technology]

[0003] Recently, electrical energy storage systems have become increasingly important due to the increasing popularity of systems for producing energy from renewable resources, in particular from wind and solar generating sources, which are characterized by unpredictability and variability in production.

[0004] Electrical energy storage systems can perform different essential functions on the grid, whether the grid is isolated or interconnected, including providing frequency regulation / dynamic inertia, providing a "flexible ramping" system i.e. allowing emergency production systems to be put into operation, "energy shifting" from times of high production and low demand to times of high demand and shortfall in production, seasonal compensation, etc.

[0005] In parallel with systems that operate according to electrochemical principles (batteries), which are usually expensive and have a limited life span, or mechanical principles (flywheels), which are only suitable for small amounts of stored energy, systems that are currently in use, are under development, or in any case are known, include:

[0006] The main system used is the Pumped Hydro Storage (PHS) system, which currently covers more than 90% of the installed storage capacity worldwide. Said system is suitable for both long-term and short-term storage and is quite competitive in terms of cost, but has the drawback that it can only be made in places with specific topographical conditions. Said PHS systems are listed under Energy Storage Systems in their positional form, in particular in their gravitational form. The family of gravitational systems also includes the system according to GB 2518125 A1.

[0007] The second system used is the so-called CAES (Compressed Air Energy Storage) system, consisting of an open CTT that stores potential energy (pressure) and (possibly) by conversion into thermal energy. Such CAES systems are both known in their basic configuration (non-adiabatic) in the state of the art AA-CAES (Advanced Adiabatic CAES, see Compressed Air Storage Installation in US Pat. No. 4,147,205). Said system is adapted for both long-term and short-term storage, is quite competitive in terms of cost, is less efficient than PHS systems in terms of "round trip efficiency", and the system also has the disadvantage that it can only be achieved in places with specific topographical conditions.

[0008] CAES systems have an additional drawback due to the fact that the tank / cavity pressure changes with changes in its charge level, which affects both the efficiency of the CTT and the efficiency of the turbomachine that runs the CTT.

[0009] Systems are also known to avoid the presence of underground cavities for CAES systems. In particular, solutions are known that seek to make the storage of energy in aboveground tanks economically advantageous without the need to have underground cavities. An example is described in US Patent Application Publication No. 2011 / 0204064 to LIGHTSAIL, where a special construction of the tank is proposed to limit the cost of aboveground storage tanks that would otherwise make the cost of said aboveground CAES systems excessively high. These solutions also belong to systems that operate according to the Open CTT.

[0010] Systems that combine the two previous systems are also known (see US Pat. No. 7,663,255), where the combination of CAES with PHS also allows the CAES system to operate at a constant compression pressure, and these systems operate according to the Open CTT.

[0011] In the document "Novel concept of compressed air energy storage and thermo-electric energy storage - THESE N.5525(2012) - Ecole Polytechnique Federale de Lousanne" all types of CAES energy storage systems are described. Among others, non-adiabatic, adiabatic and isothermal CAES systems are presented, combined with a PHS to allow a constant compression pressure, said systems being called constant pressure CAES combined with a PHS. These are also systems operating according to the open CTT.

[0012] The same document also describes the so-called TEES (Thermo Electric Energy Storage) proposed by the ABB Corporate Research Center (see also EP 2 532 843 A and EP 2 698 506 A). It belongs to the systems operating according to closed TC and is listed among the PHES systems. A PHES system (Pumped Thermoelectric Storage) is a system for storing electrical / mechanical energy by conversion into thermal energy, for example by Rankine, Brayton or Kalina TC.

[0013] In addition to the above-mentioned systems that realize the use of transcritical and supercritical cycles with CO2 or other fluids, and thus reversible transsupercritical Rankine cycles, PHES systems with Brayton cycles, typically using argon, but also air, are also known (see EP 2220343 and US 2010 / 0257862 to Isoentropic and US 2016 / 0298455 to Laughlin). This belongs to the systems that operate according to closed TC and can be listed among PHES systems.

[0014] Another system that can be mentioned in the PHES / TEES system is the Siemens-Gamesa system (see US 2014 / 0223910 and US 8,991,183 and US 8,966,902), which combines two different cycles for the charging and discharging processes, in particular the system realizing a Brayton cycle or simple dissipation by heating elements for the charging process of the thermal storage tank at high temperature and a steam Rankine cycle for the electrical energy discharging / production process. This type of solution can be mentioned in the PHES system. This is achieved by several open and / or closed TCs.

[0015] It is recognized that all PHES systems, also called TEES, are based on the principle of a "closed" reversible thermodynamic cycle. Depending on the various solutions proposed, a "closed" Rankine or Brayton cycle can be proposed, but in all cases the working fluid of a nearly reversible thermal motor / pump carries out the transformation according to a "closed" thermodynamic cycle without intermediate storage, sized in relation to the required storage capacity.

[0016] All CAES systems of all types are instead systems that carry out the conversion first in one direction and then in the other according to an "open" thermodynamic cycle, i.e. by taking in air and returning it to the atmosphere.

[0017] Another known method for storing energy is the so-called LAES (Liquid Air Energy Storage, see US 2009 / 0282840) system. The LAES method realizes an "open" thermodynamic conversion, i.e. taking air from the atmosphere / returning it to the atmosphere. In addition, such a system operates at extremely low temperatures close to -200°C, which entails high technical difficulties. It also belongs to the systems operating according to the open CTT.

[0018] The paper "Analysis of the exergy efficiency of a super-critical compressed carbon dioxide energy-storage system based on the orthogonal method" by Qing He, Yinping Hao, Hui Liu and Wenyi Liu also proposed the use of CO2 as a working fluid for an energy storage system. The proposed system (called SC-CCES (Super Critical-Compressed Carbon dioxide Energy Storage)) uses "two saline aquifers as reservoirs" as specified. In the SC-CCES system, the CO2 from the compressor's delivery is sent directly to the reservoirs without any intervening heat exchanger and / or thermal energy storage system. In addition, during the discharge cycle, the CO2 discharged from the turbine heats, via a recuperator, the same CO2 entering the turbine. This solution belongs to systems that operate according to the closed CTT, i.e. between two closed tanks.

[0019] Also, the paper "Green Energy Storage:''The Potential Use of Compressed Liquid CO2 and Large Sub-Terrain Cavities to Help Maintain a Constant Electricity Supply''-Dalgaard JZ" mentions the use of CO2 in underground cavities (in both the title and abstract, as well as in the main text of the paper). Summary of the Invention

[0020] Applicant recognizes that current energy accumulation / storage systems do not have characteristics that allow for cost-effective use in different contexts.

[0021] In particular, in some cases (e.g. PHS and CAES), the systems require very specific geological conditions that are difficult to find, and in some cases (e.g. PHS), the implementation of the systems requires the creation of artificial reservoirs, with significant environmental impacts.

[0022] In another case (AA-CAES), the achievement of a thermal energy storage system is a difficult problem to solve at low cost, plus there is still the need to identify suitable underground cavities. The above also entails the difficulty of obtaining a satisfactory round trip efficiency (RTE). In both cases, there remains the problem of operating at variable pressures in storage tanks suitable for combining the CAES system with the PHS system, obviously with costs and further complexities to identify the correct geological conditions.

[0023] Applicant further recognizes that attempts to achieve a surface CAES system will run into the practical impossibility of producing tanks for storing pressurized air at a competitive cost to enable the system itself to be achieved.

[0024] The applicant further recognizes that current attempts to create LAES systems have not been able to develop inexpensive systems, in part due to the inherent problems of operating at cryogenic conditions: problems storing cryogenic energy in double-layer tanks with a vacuum between the layers, and other costly means, make it difficult to optimize the technology from a cost perspective.

[0025] Applicant further recognizes that attempts to create a PHES system with a nearly reversible Rankine cycle have substantial difficulties in obtaining a satisfactory round trip efficiency (RTE) (i.e., greater than 60%) at a reasonable cost, and the RTE is bound by the temperature differential within the device.

[0026] Similarly, PHES systems based on the Brayton cycle have to face the fact that they use compressors and turbines for each cycle, both charging and discharging, which entails higher investment costs but also higher irreversibilities that can only be compensated for by maintaining a very high temperature difference between the hot and cold storages in order to obtain a high RTE.

[0027] In such a situation, the applicant has set himself the objective of devising and creating an energy storage method and an energy storage plant, i.e. an energy storage system, which: ·Does not require specific geographic or land conditions to be achieved and is achievable in a variety of topographical situations that may possibly be used for marine / offshore applications with specific sizes. In both cases, high RTE of over 70% and up to 75% and even up to 80% or more can be obtained. The various systems described below allow operation with adjustable pressure in the storage tank. Simple and inexpensive, preferably with an implementation cost of less than 100 USD / kWh, in particular (m 3 storage / kWh stored This allows for the storage of high energy densities under pressure (measured in units of gas). Ambient temperature fluctuations can be used to increase the RTE itself. · Safe and environmentally compatible, e.g. no particularly hazardous fluids are used. Modular. -Compact. -Has a long life or durability of 30 years. Flexible and quick to start operation. -Easy and cheap to maintain. -Corrosion resistant (especially for naval applications). -Low vibration and low noise.

[0028] The applicant has also set as an objective to drive a driven machine with stored energy that would otherwise be lost, and to utilize the mechanical energy produced by the method and energy storage plant directly (i.e. without converting the mechanical energy into electrical energy).

[0029] The applicant has found that the above and further objects can be achieved by an energy storage system operating by cyclic thermodynamic conversion (CTT), first in one direction and then in the opposite direction, between two accumulations of working fluid in two separate tanks, one of which (the one at low pressure) is not atmospheric but is an atmosphere constituted by another gas in pressure equilibrium with the atmosphere. The system is also characterized in that it stores energy to convert the working fluid from an initial gas / vapor state to a final liquid or supercritical state at a temperature close to the critical temperature (for example less than 1.2 times the critical temperature in Kelvin, preferably between 0.5 and 1.2 times). The system is also characterized in that the critical temperature is preferably not far from, preferably close to, the ambient temperature (preferably between 0° and 200° C., more preferably between 0° and 100° C.).

[0030] The working fluid is preferably carbon dioxide (CO2), but in order to improve the performance of the system, the critical temperature T of the fluid may also be determined in relation to the particular environmental conditions in which it is set to operate. c Mixtures of CO2 with other substances can also be used to correct for other fluids such as SF6, N2O, etc. can be used either pure or mixed with other fluids.

[0031] In the system proposed in this invention there is a storage of heat recovered from the compressor's delivery. The tanks operate at both high and low pressure, at constant pressure or in each case with pressure regulated within certain well-defined ranges, both possibly with different regulation strategies when the system operates in sub- and supercritical conditions.

[0032] In particular, the stated objects and further objects are substantially achieved by a plant and a method for energy storage of the type set out in the appended claims and / or described in the following aspects.

[0033] In an independent aspect, the invention relates to an energy storage plant.

[0034] Preferably, the plant comprises: A working fluid different from the atmosphere, a casing configured to store a working fluid in a gas phase and in pressure equilibrium with the atmosphere; A tank for storing the working fluid in a liquid or supercritical phase having a temperature close to a critical temperature (e.g. less than 1.2 times the critical temperature between 0.5 and 1.2 Kelvin), the critical temperature being comprised between 0°C and 200°C, more preferably between 0°C and 100°C, and preferably close to ambient temperature; At least one driven machine other than the generator Equipped with The plant is configured to perform a closed cyclic thermodynamic conversion (CTT) between the casing and the tank, first in one direction in a charge configuration / phase and then in the opposite direction in a discharge configuration / phase, where in the charge configuration the plant stores heat and pressure and in the discharge configuration the plant generates mechanical energy and transfers the mechanical energy to a driven machine to drive the driven machine.

[0035] Preferably, the working fluid has a critical temperature comprised between 0°C and 100°C, a viscosity of 0.5 kg / m at 25°C, 3 ~10Kg / m 3 Preferably within 1 kg / m 3 ~2Kg / m 3 It has the chemical and physical properties of density contained in

[0036] Preferably, the working fluid is selected from the group comprising CO2, SF6, N2O, or mixtures thereof, or mixtures thereof with other components acting, for example, mainly as additives to modify the parameters of the critical temperature of the resulting mixture to optimize the performance of the system.

[0037] Preferably, the energy storage plant comprises: a compressor and a motor mechanically connected to each other; a turbine mechanically connected to a driven machine; a casing in external contact with the atmosphere and defining therein a volume configured to contain a working fluid at or near atmospheric pressure, the volume being in selective fluid communication with an inlet of a compressor or with an outlet of a turbine; a primary heat exchanger (or possibly multiple primary exchangers operating with different fluids on their own secondary sides) in selective fluid communication with the compressor outlet or with the turbine inlet; the tank in fluid communication with the primary heat exchanger for storing a working fluid; a secondary heat exchanger operable between the primary heat exchanger and the tank or within the tank; Equipped with.

[0038] Such plants are configured to operate in a charge configuration or a discharge configuration.

[0039] In the filled configuration, the casing is in fluid communication with the inlet of the compressor, the primary heat exchanger is in fluid communication with the outlet of the compressor, the turbine is stationary, the motor is running and drives the compressor to compress working fluid coming from the casing, the primary heat exchanger removes heat from the compressed working fluid and acts as a cooler to cool the working fluid and store thermal energy, the secondary heat exchanger removes further heat from the compressed working fluid and acts as a cooler to store further thermal energy, the tank receives and stores the compressed and cooled working fluid, and the working fluid accumulated in the tank has a temperature close to its own critical temperature (e.g., included within 0.5 to 1.2 of its critical temperature in Kelvin).

[0040] In the discharge configuration, the casing is in fluid communication with the outlet of the turbine, the primary heat exchanger is in fluid communication with the inlet of the turbine, the compressor is stationary, the secondary heat exchanger acts as a heater transferring heat to the working fluid coming from the tank, the primary heat exchanger acts as a heater transferring further heat to the working fluid to heat it, the turbine is rotated by the heated working fluid to drive the driven machine, and the working fluid returns into the casing at or near atmospheric pressure.

[0041] In an independent aspect, the invention relates to a method for energy storage, optionally implemented using an energy storage plant according to at least one of the preceding or following aspects.

[0042] Preferably, the method includes the steps of performing a closed cyclic thermodynamic transformation (CTT) between a casing for storing a working fluid different from the atmosphere in gas phase and in pressure equilibrium with the atmosphere, and a tank for storing said working fluid in liquid or supercritical phase having a temperature close to a critical temperature (for example included in 0.5 to 1.2 of the critical temperature in Kelvin), first in one direction in a charging configuration / phase and then in the opposite direction in a discharging configuration / phase, said critical temperature being close to the ambient temperature, preferably 0°C to 100°C, but also up to 200°C, the method comprising the steps of accumulating heat and pressure in the charging phase and generating mechanical energy in the discharging phase and transferring the mechanical energy to a driven machine different from a generator to drive said driven machine.

[0043] Preferably, said working fluid has chemical and physical properties such as a critical temperature comprised between 0° C. and 200° C., more preferably between 0° C. and 100° C., preferably close to ambient temperature.

[0044] Preferably, the working fluid is selected from the group comprising CO2, SF6, N2O, or mixtures thereof, or even mixtures of these with other components acting, for example mainly as additives, to modify the parameters of the critical temperature of the resulting mixture to optimize the performance of the system.

[0045] Preferably, the method includes an energy charging step and an energy releasing and generating step.

[0046] The filling process is compressing a working fluid, the working fluid coming from the casing defining therein a volume configured to contain the working fluid at or near atmospheric pressure, the working fluid being in external contact with the atmosphere and absorbing energy; - introducing the compressed working fluid through a primary heat exchanger (or possibly even multiple primary exchangers operating with different fluids on their secondary sides) and a secondary heat exchanger arranged in series to bring the temperature of the working fluid close to its critical temperature, the primary heat exchanger acting as a cooler to remove heat from the compressed working fluid and cool the working fluid to store thermal energy, and the secondary heat exchanger acting as a cooler to remove further heat from the compressed working fluid and store further thermal energy; accumulating a cooled working fluid in said tank, where the secondary and primary heat exchangers perform a supercritical conversion of said working fluid such that said working fluid is accumulated in said tank in a supercritical phase, or the secondary and primary heat exchangers perform a subcritical conversion of said working fluid such that said working fluid is accumulated in said tank in a liquid phase (preferably also for the purpose of regulating the pressure at a relatively minimal / low value); Includes.

[0047] The process of energy release and generation is as follows: - passing the working fluid coming from the tank through a secondary heat exchanger and a primary heat exchanger, the secondary heat exchanger acting as a heater that transfers heat to the working fluid coming from the tank (preferably also for the purpose of regulating the pressure at a relatively minimal / low value) and the primary heat exchanger acting as a heater that transfers further heat to the working fluid to heat it, passing the heated working fluid through a turbine, the turbine being rotated by the heated working fluid to drive a driven machine, the working fluid expanding and being cooled within the turbine; reintroducing into the casing the working fluid coming from the turbine at or near atmospheric pressure; Includes.

[0048] The applicant has verified that the method and device according to the invention are capable of achieving the predetermined objectives.

[0049] In particular, the applicant has verified that the present invention also allows for the operation of energy storage in marine / offshore applications in a safe manner and with reduced environmental impact, in locations without specific topographical characteristics.

[0050] The applicant has also verified that the manufacture and subsequent maintenance of an apparatus according to the invention is relatively inexpensive.

[0051] The applicant has also verified that the present invention makes it possible to obtain a high RTE.

[0052] The applicant has also verified that the present invention allows the operation of energy storage with the possibility of adjusting the pressure in the storage tank, thus improving the operability of the system and increasing the efficiency of both the turbomachine and the system with respect to the RTE.

[0053] The Applicant has also verified that in the discharge configuration, the direct transmission of mechanical energy to the driven machine (by the direct mechanical connection of the plant to said driven machine) makes it possible to utilize the previously stored energy in an efficient manner: in fact, no electrical energy is produced that must later be reconverted into mechanical energy.

[0054] The aspects of the present invention are listed below.

[0055] In one aspect, the driven machine is any one that is directly driven by the turbine and has moving parts that perform work on, for example, a fluid or another element.

[0056] In one aspect, the driven machine is a compressor or a pump, optionally for a pipeline or used to produce process gas, water or liquefied natural gas (LNG) pumps.

[0057] In one aspect, the driven machine comprises a transmission shaft mechanically connected to a shaft of the turbine.

[0058] In one aspect, a reduction gear or gear transmission box is interposed between the turbine and the driven machine.

[0059] In one aspect, a coupling device, preferably of a friction type, is interposed between the turbine and the driven machine for connecting / disconnecting the driven machine to / from the turbine.

[0060] In one aspect, the primary heat exchanger is a thermal storage device (thermal energy storage - TES) or is operatively associated with a thermal storage device.

[0061] In one aspect, a first tube extends between a casing and an inlet of a compressor and between a casing and an outlet of a turbine to place the casing in flow communication with the compressor and turbine.

[0062] In one aspect, at least one valve is operatively disposed on the first tube to alternately place the casing in flow communication with the compressor or the turbine with the casing.

[0063] In one aspect, a second tube extends between the turbine inlet and the primary heat exchanger, and between the compressor outlet and the primary heat exchanger, to place the primary heat exchanger in flow communication with the compressor and turbine.

[0064] In one aspect, at least one valve is operatively disposed on the second tube to alternately place a compressor in flow communication with the primary heat exchanger or a primary heat exchanger in flow communication with the turbine.

[0065] In one embodiment, a third tube extends between the primary and secondary heat exchangers to place the primary heat exchanger in fluid communication with the secondary heat exchanger.

[0066] In one aspect, additional heat exchangers are operatively disposed between the casing and the compressor, and between the casing and the turbine, in a charging configuration, to preheat the working fluid prior to compression in the compressor, or in a discharge configuration, to cool the working fluid coming from the turbine.

[0067] In one embodiment, an additional heat exchanger is operatively associated with the first tube.

[0068] In one aspect, the additional heat exchanger comprises a further thermal energy storage device.

[0069] In one aspect, in the charged configuration, the additional heat exchanger functions as a heater to preheat the working fluid.

[0070] In one aspect, in the discharge configuration, the additional heat exchanger acts as a cooler to cool the working fluid and store additional thermal energy that is used in the charge configuration to pre-heat said working fluid.

[0071] In one embodiment, the cooler is disposed at a branch of a first tube connected to the outlet of the turbine.

[0072] In one aspect, a further heat exchanger operably coupled to an additional heat source is operably disposed between the turbine and the primary heat exchanger and configured to further heat the working fluid during the discharge process prior to entering the turbine.

[0073] In one aspect, in the discharge configuration, the additional heat source supplies additional heat to the working fluid.

[0074] In one aspect, the process of releasing and producing energy involves further heating of the working fluid between the primary heat exchanger and the turbine with an additional heat source.

[0075] In one embodiment, the additional heat source is a solar source (eg, a solar field) and / or industrial waste heat recovery and / or gas turbine exhaust (GT).

[0076] In one aspect, the temperature that the working fluid is brought to just before entering the turbine in the discharge step by the additional heat source and further heat exchanger is higher than the temperature of the working fluid at the end of compression during the charging step.

[0077] In one embodiment, the temperature to which the working fluid reaches through the additional heat source and the further heat exchanger is about 100° C. higher, or even about 200° C. higher, or even about 300° C. higher, or even about 400° C. higher than the temperature of the working fluid at the end of compression.

[0078] Applicant has demonstrated that further heating of the working fluid by an additional heat source allows for a significant increase in round trip efficiency (RTE).

[0079] In one aspect, the casing is deformable.

[0080] In one embodiment, the casing has the structure of a gas tank.

[0081] In one embodiment, the casing is a pressure balloon.

[0082] In one embodiment, the casing is made of a flexible material, preferably plastic, such as a PVC coated polyester fabric.

[0083] In one aspect, a generator is also mechanically connected or connectable to the turbine, and in the discharge configuration, the turbine drives the generator, which also produces electrical energy.

[0084] In one embodiment, during the emission process, the method also produces electrical energy.

[0085] In one aspect, the motor is an electric motor.

[0086] In one aspect, the motor is a heat engine.

[0087] In one aspect, the motor is a hydraulic motor or a wind motor.

[0088] In one aspect, the motor is a turbine, optionally a gas or steam turbine, optionally hydraulic or wind.

[0089] The applicant has verified that the plant according to the invention is not only able to store excess electrical energy (absorbing electrical energy from the grid), but also directly store mechanical energy coming from a conventional motor intended as a driving machine. The plant is therefore also able to absorb and store mechanical energy and reconvert it into mechanical energy without converting it into electrical energy.

[0090] In one aspect, the motor and generator are separate elements, with the motor preferably stably connected to the compressor and the generator preferably stably connected to the turbine.

[0091] In one aspect, the motor and generator are defined by a single motor-generator.

[0092] In one aspect, the plant comprises a coupling device, preferably of the friction type, interposed between the motor-generator and the compressor and also between the motor-generator and the turbine, for mechanically and alternately connecting the motor-generator to the compressor or to the turbine.

[0093] In one aspect, the motor-generator, compressor and turbine are coaxially arranged.

[0094] In one aspect, an auxiliary motor, preferably electric, is connected to the driven machine and configured to drive said driven machine at least when the plant is in the filling configuration.

[0095] In one aspect, an auxiliary generator is mechanically interposed between the turbine and the driven machine.

[0096] In one aspect, a coupling device, preferably of a friction type, is interposed between the auxiliary generator and the turbine for selectively connecting said auxiliary generator to the turbine.

[0097] In one aspect, the auxiliary motor and auxiliary generator are defined by a single auxiliary motor-generator.

[0098] In one aspect, the compression of the working fluid in the compressor is adiabatic, intercooled, or isothermal.

[0099] In one aspect, the expansion of the working fluid in the turbine is adiabatic, intermediate heating, or isothermal.

[0100] In one embodiment, an auxiliary thermal storage (thermal energy storage TES) is connected to the compressor and turbine.

[0101] In one embodiment, the auxiliary heat storage device is configured to achieve intercooling compression with one or more intercoolings during the charging process within the compressor.

[0102] In one aspect, the auxiliary heat storage device is configured to achieve intermediate heating expansion at one or more intermediate heatings during the discharge process within the turbine.

[0103] In one embodiment, intermediate cooling is performed multiple times during the filling process, and intermediate heating is performed fewer times than the number of intermediate cooling times by using only a portion of the heat (stored in the auxiliary heat storage device) from the intermediate cooling.

[0104] In one embodiment, intermediate cooling is performed multiple times during the charging process, and intermediate heating is performed only once during the discharging process using only the heat (stored in the auxiliary heat storage device) from the final intermediate cooling.

[0105] Applicant has demonstrated that by combining further heating of the working fluid by an additional heat source, together with the intercooling and interheating described above, the round trip efficiency (RTE) can be increased to values ​​in excess of 100%.

[0106] In one aspect, the primary heat exchanger is or comprises a heat regenerator having a fixed bed or a moving bed.

[0107] In one embodiment, a heat regenerator having a fixed bed or a moving bed comprises at least one heat store against which the working fluid impinges.

[0108] In one embodiment, a heat regenerator with a fixed or moving bed comprises at least one heat store separated from the working fluid by a wall, typically metal, that is not impinged by the working fluid but is adapted to limit the pressure, so that the heat store is at atmospheric pressure.

[0109] In one aspect, the thermal mass comprises loose material, optionally gravel or metal or ceramic balls.

[0110] In one embodiment, the thermal mass comprises a cohesive material, optionally concrete or ceramic or metal.

[0111] In one aspect, the primary heat exchanger comprises a primary circuit traversed by a primary fluid, optionally water, oil or salt, or multiple primary circuits traversed by multiple primary fluids.

[0112] In one aspect, the primary circuit includes a heat exchange portion configured to exchange heat with the working fluid.

[0113] In one embodiment, the primary circuit comprises at least one primary reservoir for said primary fluid, preferably two reservoirs.

[0114] In one aspect, the primary circuit includes a hot primary storage chamber for hot primary fluid stored after removing heat from the working fluid during the charging configuration / phase of the apparatus / method, and a cold primary storage chamber for cold primary fluid stored after transferring heat to the working fluid during the discharging configuration / phase of the apparatus / method.

[0115] In one aspect, the primary circuit comprises a heat regenerator having a fixed bed against which the primary fluid impinges, preferably operating at atmospheric pressure.

[0116] In one aspect, the secondary heat exchanger comprises a secondary circuit traversed by a secondary fluid, optionally air or water.

[0117] In one aspect, the secondary circuit includes a heat exchange portion configured to be impinged by the working fluid.

[0118] In one embodiment, the secondary circuit comprises at least one secondary reservoir for said secondary fluid.

[0119] In one aspect, the secondary circuit includes a hot secondary storage chamber for hot secondary fluid stored after removing heat from the working fluid during the charging configuration / phase of the apparatus / method, and a cold secondary storage chamber for cold secondary fluid stored after transferring heat to the working fluid during the discharging configuration / phase of the apparatus / method.

[0120] In one embodiment, a secondary heat exchanger is interposed between the primary heat exchanger and the tank.

[0121] In one embodiment, the secondary heat exchanger is integrated into the tank.

[0122] In one aspect, the secondary heat exchanger comprises a system for regulating the flow rate and / or temperature of a secondary fluid, typically water or air, which is capable of regulating the pressure in the storage tank within certain limits when the system operates at subcritical conditions.

[0123] Temperature regulation can be achieved by supplying heat from or removing heat to the atmosphere, and also by taking advantage of normal ambient air and water temperature oscillations at different times of the day.

[0124] In one aspect, the heat exchange portion of the secondary heat exchanger is housed within the tank.

[0125] In one aspect, the secondary circuit is configured to remove heat from the working fluid in a charging configuration, or to transfer heat to the working fluid in a discharging configuration, optionally at temperatures below 100°C, optionally comprised between 0°C and 50°C, and optionally close to ambient temperature.

[0126] In one embodiment, in a charging configuration / process, the secondary heat exchanger operates at near ambient conditions such that the fluid has a critical temperature close to ambient temperature, allowing the heat removal process by the secondary heat exchanger to be assisted by a direct or indirect exchange process with the atmosphere.

[0127] In one embodiment, in the discharge configuration / process, the secondary heat exchanger operates at conditions close to ambient temperature, so that the fluid has a critical temperature close to ambient temperature, allowing the heat supply process by the secondary heat exchanger to be assisted by a direct or indirect exchange process with the atmosphere.

[0128] In one aspect, the tank is spherical or approximately spherical.

[0129] In one aspect, the tank is cylindrical or approximately cylindrical.

[0130] In one embodiment, the outer wall of the tank is made of metal.

[0131] In one embodiment, the temperature of the working fluid stored in the tank is comprised between 0°C and 100°C.

[0132] In one embodiment, the pressure of the working fluid stored in the tank is comprised between 10 bar and 150 bar, preferably between 10 bar and 150 bar, preferably between 50 bar and 100 bar, preferably between 65 bar and 85 bar.

[0133] In one embodiment, the ratio of the density of the working fluid when contained in the tank to the density of the same working fluid when contained in the casing is included in the range of 200-500.

[0134] In one aspect, the secondary heat exchanger and the primary heat exchanger are configured to operate a supercritical transformation of the working fluid such that the working fluid is accumulated in the tank in a supercritical phase.

[0135] In one embodiment, heat is removed from the working fluid in a primary exchanger to bring the working fluid to a temperature above the critical temperature and above the Andrews curve on the TS diagram.

[0136] In one embodiment, heat is removed from the working fluid in a secondary heat exchanger to cause the working fluid to be in the supercritical phase and follow the right portion of the Andrews curve.

[0137] In one aspect, the secondary heat exchanger and the primary heat exchanger are configured to operate a subcritical transformation of the working fluid such that the working fluid is accumulated in the tank in a liquid phase.

[0138] In one embodiment, heat is removed from the working fluid in a primary exchanger to bring the working fluid to a temperature on the TS diagram that is below the critical temperature and is at a point on the left portion of the Andrews curve.

[0139] In one aspect, heat is removed from the working fluid in a secondary heat exchanger by passing the working fluid through a saturated vapor zone, causing the working fluid to enter a liquid phase.

[0140] Further features and advantages will become more apparent from the detailed description of preferred, but not exclusive, embodiments of the plant and method for energy storage according to the invention.

[0141] Such an illustration is given below with reference to the accompanying drawings, given by way of non-limiting example only, in which: [Brief description of the drawings]

[0142] [Figure 1] FIG. 1 shows a schematic diagram of an embodiment of an energy storage plant according to the invention. [Diagram 2] FIG. 2 is a TS diagram showing the method according to the invention operated in the plant of FIG. 1; [Diagram 3] FIG. 2 shows a variant of the embodiment of the plant of FIG. 1. [Figure 4]FIG. 2 shows a further embodiment variant of the plant of FIG. 1. [Diagram 5] FIG. 1 shows a part of a plant according to the invention. [Figure 6] FIG. 2 shows a further embodiment of an energy storage plant according to the invention. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0143] With reference to the accompanying drawings, the reference number 1 indicates as a whole an energy storage plant according to the invention.

[0144] The plant 1 operates with a working fluid which is different from, for example, the atmosphere.

[0145] For example, the plant 1 operates with a working fluid selected from the group including carbon dioxide CO2, sulfur hexafluoride SF6, nitrous oxide N2O. In the following description, the working fluid used with the described plant 1 is carbon dioxide CO2.

[0146] The plant 1 is configured to perform a closed cyclic thermodynamic transformation (CTT) first in one direction in a charging configuration / process and then in the opposite direction in a discharging configuration / process, where in the charging configuration the plant 1 stores heat and pressure and in the discharging configuration the plant 1 generates electrical energy.

[0147] With reference to Fig. 1, the plant 1 comprises a turbine 2 and a compressor 3 mechanically connected to the shaft of a single motor-generator 4. The motor-generator 4, the compressor 3 and the turbine 2 are arranged coaxially. The shaft of the turbine 2 is coupled, for example by a frictional coupling device, to one end of the shaft of the motor-generator 4, which allows the turbine 2 to be connected to / disconnected from the motor-generator 4 on command. Similarly, the shaft of the compressor 3 is coupled, for example by a frictional coupling device, to the opposite end of the shaft of the motor-generator 4, which allows the compressor 3 to be connected to / disconnected from the motor-generator 4 on command.

[0148] The turbine is also mechanically connected to a driven machine 300, different from an electric generator or motor-generator, represented diagrammatically in Fig. 1, by a transmission element 301, represented only diagrammatically. Such a driven machine 300 may be, for example, an air or natural gas or process gas compressor for a pipeline or for liquefied natural gas (LNG), a pump for water or process gas, or in any case a general driving machine.

[0149] In a variant of the embodiment shown in Fig. 3, the motor 4a and the generator 4b are separate elements. In such a case, the motor is stably connected to the compressor 3 and the generator is stably connected to the transmission element 301 and to the turbine 2. The motor 4a is an electric motor.

[0150] In a further variation of Figure 4, an auxiliary motor-generator 302 is installed between the driven machine 300 and the turbine 2, and a friction-type connecting device 303 is interposed between the auxiliary motor-generator 302 and the turbine 2 to selectively connect the auxiliary motor-generator 302 and the driven machine 300 to the turbine 2.

[0151] In a further variant, the turbine 2 is mechanically connected only to one or more driven machines, and is not connected or connectable to a generator or motor-generator. For example, FIG. 5 shows the turbine 2 directly connected to the shaft of a compressor used to compress the process fluid "F". The compressor constitutes the driven machine 300. In this illustrative example, the shaft of the turbine 2 and the shaft of the compressor 300 are integral and the two machines rotate at the same speed. In a further variant, a reducer or gear transmission box can be provided interposed between the turbine 2 and the compressor 300.

[0152] In a further variant, not shown in detail in the attached figures, the motor 4a connected to the compressor 3 is not an electric motor but a driving machine that does not use electricity to be driven, for example the motor 4a is a turbine, such as a gas turbine, a steam turbine, a wind turbine or a water turbine.

[0153] The plant 1 comprises a casing 5 defined by a pressure balloon, preferably made of a flexible material, for example a PVC-coated polyester fabric. The pressure balloon is placed on the surface and is in external contact with the atmosphere. The pressure balloon defines in its interior a volume adapted to accommodate a working fluid at or near atmospheric pressure, i.e. in pressure equilibrium with the atmosphere. The casing 5 can also be realised as a gas tank or any other system for storing gas at low or zero overpressure.

[0154] Between the casing 5 and the inlet 3a of the compressor 3, and between the casing 5 and the outlet 2b of the turbine 2, a first pipe 6 extends in order to place the interior volume of the casing 5 in fluid communication with said compressor 3 and turbine 2. A valve or valve system (not shown) can be operatively arranged on the first pipe 6 in order to place the casing 5 alternately in fluid communication with the inlet 3a of the compressor 3 or the outlet 2b of the turbine 2 with the casing 5.

[0155] The plant 1 comprises a primary heat exchanger 7 which can be selectively placed in fluid communication with the outlet 3b of the compressor 3 or with the inlet 2a of the turbine 2. For such purpose, second tubes 8 extend between the inlet 2a of the turbine 2 and the primary heat exchanger 7 and between the outlet 3b of the compressor 3 and the primary heat exchanger 7. For alternately placing the primary heat exchanger 7 in fluid communication with the inlet 2a of the turbine 2 or the outlet 3b of the compressor 3 with the primary heat exchanger 7, a valve or valve system (not shown) is operatively arranged on the second tube 8. In a preferred embodiment, there is only a valve or valve system arranged on the second tube 8.

[0156] A tank 9 is in fluid communication with the primary heat exchanger 7 and is configured to store the working fluid in the liquid or supercritical phase.

[0157] The tank 9 is preferably made of metal with a spherical outer wall.

[0158] A secondary heat exchanger 10 is operable between the primary heat exchanger 7 and the tank 9 or within said tank 9 and is configured to operate on accumulated working fluid or during a filling process within the tank 9. According to the embodiment shown in FIG. 1, the secondary heat exchanger 10 is integrated into the tank 9 in the sense that it has its own heat exchange part 11 housed within said tank 9 and configured to be impinged by the working fluid. A third tube 12 extends between the primary heat exchanger 7 and the tank 9 to place said primary heat exchanger 7 in fluid communication with said tank 9 and said secondary heat exchanger 10.

[0159] In the schematic diagram of FIG. 1, the plant 1 may also comprise additional heat exchangers 13 operatively arranged between the casing 5 and the compressor 2 and between the casing 5 and the turbine 2, and optionally a cooler 13a arranged in a branch of the first tube 6 connected to the outlet 2b of the turbine 2.

[0160] The plant 1 also comprises a control unit, not shown, operatively connected to the various elements of the plant 1 itself and configured / programmed to manage their operation.

[0161] The plant 1 is configured to operate in a charging configuration or in a discharging configuration, i.e. to carry out a method comprising processes of energy charging and processes of energy discharging and production.

[0162] In the charging configuration, the plant 1 starts from a first state (point A on the TS diagram in FIG. 2) where the gaseous working fluid (CO2) is fully contained in the casing 5 at atmospheric or near atmospheric pressure and at a temperature approximately equal to the ambient temperature. The casing 5 is placed in communication with the inlet 3a of the compressor 3 while the communication with the outlet 2b of the turbine 2 is blocked by the valve system. In addition, the primary heat exchanger 7 is placed in fluid communication with the outlet 3b of the compressor 3 and the communication with the inlet 2a of the turbine 2 is blocked by the valve system. The motor-generator 4 is coupled to the sole compressor 3 and is decoupled from the turbine 2 (which is in a stationary state) and the driven machine 300. The motor-generator 4 serves as a motor that drives the compressor 3 to compress the working fluid coming from the casing 5. The driven machine 300 may for example be driven by a dedicated respective auxiliary motor operating independently and not shown in the attached figures.

[0163] Before entering the compressor 3, the working fluid crosses an additional heat exchanger 13 acting as a heater to preheat the working fluid (point B on the TS diagram of FIG. 2). The working fluid is then compressed and heated in the compressor 3 (point C on the TS diagram of FIG. 2). The working fluid then flows through the primary heat exchanger 7 acting as a cooler to remove heat from the compressed working fluid to cool it (point D on the TS diagram of FIG. 2) and to store the thermal energy removed from said working fluid. At point D, the working fluid is at a temperature below the critical temperature of said fluid, being at a point on the left part of the Andrews curve, or slightly outside the curve in a slightly superheated state. The compression can be adiabatic, intercooled or isothermal.

[0164] The working fluid enters the tank 9 where the secondary heat exchanger 10, which in this configuration acts as a cooler, removes further heat from the working fluid and stores further thermal energy. The working fluid crosses the saturated vapor zone to reach the liquid phase (point E on the TS diagram in FIG. 2). The tank 9 thus stores the working fluid in liquid phase at a temperature lower than its own critical temperature Tc. In this second state, the liquid working fluid (CO2, Tc=31°C), for example at 20°C, is fully contained within the tank 9. The secondary heat exchanger 10 and the primary heat exchanger 9 are therefore configured to operate a subcritical transformation of said working fluid such that the working fluid is accumulated in the tank 9 in liquid phase.

[0165] In the discharge configuration, the plant 1 starts in a second state (point F on the TS diagram of FIG. 2). The casing 5 is placed in communication with the outlet 2b of the turbine 2 while the communication with the inlet 3a of the compressor 3 is blocked by the valve system. In addition, the primary heat exchanger 7 is placed in fluid communication with the inlet 2a of the turbine 2 and the communication with the outlet 3b of the compressor 3 is blocked by the valve system. The motor-generator 4 is coupled to the turbine 2 and the driven machine 300 and acts as a generator decoupled from the compressor 3 (which is in a stationary state) and rotated by the turbine 2 driven by the expanding working fluid. The turbine 2 also drives the driven machine 300, which receives energy from said turbine and can thus be driven by pre-stored energy.

[0166] The secondary heat exchanger 10 acts as a heater and transfers part of the heat previously stored in the filling configuration to the working fluid in the tank 9. The working fluid crosses the saturated vapor zone and reaches the vapor phase (point G on the TS diagram of FIG. 2). The working fluid crosses the primary heat exchanger 7, which now acts as a heater and transfers further heat previously stored in the filling configuration to the working fluid, heating it up (point H on the TS diagram of FIG. 2).

[0167] The heated working fluid enters the turbine 2, expands and cools (point I on the TS diagram in FIG. 2), causing the rotation of the turbine 2. The turbine 2 is rotated by the heated working fluid and drives the driven machine 300 and the motor-generator 4, which acts as a generator and produces electrical energy. The expansion of the working fluid in the turbine can be adiabatic, intermediate heating, or isothermal.

[0168] The working fluid leaving the turbine 2 is cooled in an additional heat exchanger 13 (point J on the TS diagram in FIG. 2) and returns to the casing 5 at atmospheric or near atmospheric pressure. The additional heat exchanger 13 in the process stores additional thermal energy in a respective further thermal energy storage device which is used in the subsequent charging process to pre-heat the working fluid.

[0169] In the conversion shown in FIG. 2, the secondary circuit 20 is configured to remove heat from the working fluid in a charge configuration, or to transfer heat to the working fluid in a discharge configuration up to a temperature close to ambient temperature, for example about 20° C.

[0170] In both the charging configuration / process and the discharging configuration / process, because the secondary heat exchanger 10 operates at conditions close to ambient temperature, the step of removing heat and / or the step of supplying heat by the secondary heat exchanger can be assisted by a direct or indirect exchange process with the atmosphere, due to the fluid having a critical temperature close to ambient temperature.

[0171] For example, the temperature of the working fluid (CO2) stored in the tank 9 is 24°C, and the pressure of the working fluid stored in the tank 9 is 65 bar. The density of CO2 at 25°C and atmospheric pressure is approximately 1.8 kg / m 3 The density of the CO2 in the tank 9 is about 730 kg / m 3 Therefore, the ratio of the density of the working fluid when contained in the tank 9 under the stated conditions to the density of the same working fluid when contained in the casing 5 under atmospheric conditions is approximately 400. In this regard, if, instead of CO2, atmospheric air stored at 65 bar and 24°C is used in the tank 9, its density is only 78 kg / m 3It is recognized that the theoretically necessary volume of the tank 9 is about 10 times larger.

[0172] As an example, for a plant 1 according to the invention capable of storing 100 MWh of energy, the volume of the pressure balloon is approximately 400,000 m 3 The tank volume is approximately 1000m 3 It is.

[0173] The primary heat exchanger 7 may be a heat regenerator with a fixed bed with a heat store constituted, for example, by metal spheres. In a charging configuration / process, a compressed hot working fluid hits the heat store, which transfers heat to the metal spheres that store thermal energy. In a discharging configuration / process, the heat store is hit by a cold working fluid, which absorbs heat from the metal spheres and is heated. In a variant not shown, the heat regenerator may be of the type with a moving bed. The primary heat exchanger 7 is therefore a heat store (thermal energy storage TES).

[0174] Instead of a heat regenerator with a fixed bed, other types may also be provided.

[0175] In a variant of the embodiment, the secondary heat exchanger 10 and the primary heat exchanger 7 are configured to operate the supercritical transformation of the working fluid so that said working fluid accumulates in the tank in the supercritical phase. Different from the one shown in Fig. 2, the primary exchanger 7 removes heat from the working fluid to bring it to a temperature higher than the critical temperature and above the Andrews curve. The secondary exchanger 10 then conveys the working fluid in the supercritical phase by making it follow the right part of the Andrews curve.

[0176] For example, the temperature of the working fluid (CO2) stored in the tank 9 in the supercritical phase is 25° C., and the pressure of the working fluid stored in the tank 9 is 100 bar. The density of CO2 at 25° C. and atmospheric pressure is approximately 1.8 kg / m 3 The density of the CO2 in the tank 9 is about 815 kg / m 3The ratio of the density of the working fluid when contained in the tank 9 at the conditions described to the density of the same working fluid when contained in the casing 5 at atmospheric conditions is therefore approximately 450.

[0177] In addition, the secondary heat exchanger may be equipped with a system for regulating the flow rate and / or temperature of the secondary fluid, typically water or air, which allows the pressure in the storage tank to be regulated within certain limits when the system operates at subcritical conditions. Temperature regulation can be performed, for example, by supplying heat from the atmosphere or removing heat to the atmosphere, but also by taking advantage of normal ambient air and water temperature oscillations at different times of the day.

[0178] In the exemplary embodiment using CO2 as the working fluid, it is also preferred that a CO2 dehydration system, e.g., a zeolite-based dehumidifier, is present to prevent the potential formation of carbonic acid within the circuit.

[0179] A further variant of the plant 1 is shown in Fig. 6. The main elements in common with Fig. 1 are shown therein: turbine 2, compressor 3, motor-generator 4, casing 5, primary heat exchanger 7 (thermal accumulator TES), tank 9 and secondary heat exchanger 10. The plant 1 illustrated here also comprises an additional heat exchanger 13. As in the embodiment of Fig. 4, the secondary heat exchanger 10 is interposed between the primary heat exchanger 7 and the tank 9, i.e. is not integrated in the tank 9. As in the plant of Fig. 2, the secondary heat exchanger 10 comprises a secondary circuit 20 traversed by a secondary fluid, for example water. In addition to the heat exchange section 11, the secondary circuit 20 also comprises a secondary storage chamber 200 for the hot secondary fluid accumulated after removing heat from the working fluid during the charging arrangement / process of the device / method and for the cold secondary fluid accumulated after transferring heat to the working fluid during the discharging arrangement / process of the device / method. Said secondary storage chamber 200 is also coupled to a radiator 23, for example equipped with one or more fans 24 arranged on a recirculation duct, which cools the secondary fluid during the night and heats it during the day. Said secondary storage chamber 200 is also connected to an additional heat exchanger 13 by a respective circuit 210.

[0180] In a variant of this embodiment, the plant 1 also comprises at least one further heat exchanger 220 which receives heat from an additional heat source 230. The additional heat exchanger 220 is arranged on the second tube 8 between the inlet 2a of the turbine 2 and the primary heat exchanger 7. The additional heat source 230 is, by way of non-limiting example, a solar source (e.g. a solar field), industrial waste heat recovery, gas turbine exhaust heat, etc. The additional heat source 230 provides additional heat during the discharge process. The temperature to which the working fluid reaches by the additional heat source 230 and the further heat exchanger 220 just before entering the turbine 2 in the discharge process is higher than the temperature of the working fluid obtained at the end of compression during the charging process. For example, the temperature to which the working fluid reaches by the additional heat source 230 and the further heat exchanger 220 is about 100° C. higher than the temperature of the working fluid at the end of compression, but it can also be about 200° C., or even about 300° C., or even about 400° C. higher.

[0181] The plant 1 also comprises an auxiliary heat accumulator (thermal energy storage TES) 240 connected by a suitable circuit to the compressor 2 and the turbine 2 so as to achieve (during the charging process) an intercooling compression (with one or more intercoolings) in the compressor 3 and (during the discharging process) an interheating expansion (with one or more interheatings) in the turbine 2. The heat stored in the auxiliary heat accumulator 240 during the intercooling compression is used completely or partly to perform the interheating expansion. [Explanation of symbols]

[0182] 1. Energy storage plant 2. Turbine 2a Inlet turbine 2b Exit turbine 3. Compressor 3a Inlet compressor 3b outlet compressor 4 Motor generator 4a Motor 4b Generator 5 Casing 6 First Tube 7 Primary heat exchanger 8 Second Tube 9. Tank 10 Secondary heat exchanger 11 Heat exchange section of secondary heat exchanger 12 Third Tube 13 Additional Heat Exchanger 13a Cooler 20 Secondary circuit 200 Secondary Storage Room 210 Additional heat exchanger circuit 220 More Heat Exchangers 230 Additional Heat Source 240 Auxiliary heat storage 300 Driven Machine 301 Transmission Elements 302 Auxiliary motor generator 303 Connection Device

Claims

1. A working fluid different from the atmosphere, a casing (5) storing the working fluid, the casing (5) being a pressure balloon or having the structure of a gas tank or other gas storage system with low or zero overpressure such that the working fluid is in gas phase and in pressure equilibrium with the atmosphere; a tank (9) storing the working fluid in a liquid or supercritical phase having a temperature close to a critical temperature, the critical temperature being between 0°C and 100°C; At least one driven machine (300) different from the generator; An energy storage plant comprising: said energy storage plant being configured to perform a closed cyclic thermodynamic transformation (CTT) first in one direction from said casing (5) to said tank (9) in a charging configuration and then in the opposite direction from said tank (9) to said casing (5) in a discharging configuration, the energy storage plant storing heat and pressure in the charging configuration; The energy storage plant, in the discharging configuration, generates mechanical energy and transfers the mechanical energy to a driven machine to drive the driven machine.

2. The working fluid is CO ２ , S.F. ６ , N ２ 2. The energy storage plant of claim 1, wherein the nitrogen is selected from the group consisting of:

3. A compressor (3) and a motor mechanically connected to each other; A turbine (2) mechanically connected to the driven machine (300); a casing (5) in external contact with the atmosphere and defining internally a volume configured to contain the working fluid at or near atmospheric pressure, the volume being in selective fluid communication with an inlet (3a) of the compressor (3) or with an outlet (2b) of the turbine (2); a primary heat exchanger (7) in selective fluid communication with an outlet (3b) of the compressor (3) or with an inlet (2a) of the turbine (2); a tank (9) in fluid communication with the primary heat exchanger (7) for storing the working fluid; a secondary heat exchanger (10) operable between said primary heat exchanger (7) and said tank (9) or within said tank (9); Equipped with the energy storage plant is configured to operate in the charging configuration or the discharging configuration; In said charged configuration, the casing (5) is in fluid communication with the inlet (3a) of the compressor (3), the primary heat exchanger (7) is in fluid communication with the outlet (3b) of the compressor (3), the turbine (2) is stationary, the motor (4a) is in operation and drives the compressor (3) to compress the working fluid coming from the casing (5), the primary heat exchanger (7) removes heat from the compressed working fluid and acts as a cooler to cool the working fluid and store thermal energy, the secondary heat exchanger (10) removes further heat from the compressed working fluid and acts as a cooler to store further thermal energy, the tank (9) receives and stores the compressed and cooled working fluid, the working fluid stored in the tank (9) has a temperature close to the critical temperature of the working fluid itself, In the discharge configuration, the casing (5) is in fluid communication with the outlet (2b) of the turbine (2), the primary heat exchanger (7) is in fluid communication with the inlet (2a) of the turbine (2), the compressor (3) is stationary, the secondary heat exchanger (10) functions as a heater to transfer heat to the working fluid coming from the tank (9), the primary heat exchanger (7) functions as a heater to transfer further heat to the working fluid to heat it, the turbine (2) is rotated by the heated working fluid to drive the driven machine (300), and the working fluid returns into the casing (5) at atmospheric pressure or near atmospheric pressure.

3. An energy storage plant according to claim 1 or 2.

4. The energy storage plant according to any one of claims 1 to 3, wherein the driven machine is a compressor or a pump used to produce a process gas.

5. 4. Energy storage plant according to claim 3, wherein the motor (4a) is an electric motor or a heat engine.

6. 4. The energy storage plant of claim 3, further comprising a further heat exchanger (220) operably coupled to an additional heat source (230) and operably arranged between the turbine (2) and the primary heat exchanger (7), the further heat exchanger (220) configured to further heat the working fluid in the discharge configuration before entering the turbine (2).

7. The energy storage plant of claim 6, wherein the additional heat source (230) is selected from the group consisting of a solar source, industrial recovered waste heat, and gas turbine exhaust heat.

8. 8. The energy storage plant according to claim 3 or any one of claims 5 to 7, further comprising a generator (4b) mechanically connected or connectable to the turbine (2), wherein in the discharge configuration, the turbine (2) drives the generator (4b) to also produce electrical energy.

9. 9. An energy storage plant according to claim 8, wherein the motor (4a) and the generator (4b) are separate elements or the motor (4a) and the generator (4b) are defined by a single motor-generator (4), the energy storage plant comprising a connection device interposed between the motor-generator (4), the compressor (3) and the turbine (2) for mechanically and alternately connecting the motor-generator (4) to the compressor (3) or to the turbine (2).

10. The energy storage plant according to claim 3 or any one of claims 5 to 9, further comprising an auxiliary motor connected to the driven machine (300) and configured to drive the driven machine (300) at least when the energy storage plant (1) is in the charging configuration, an auxiliary generator mechanically interposed between the turbine (2) and the driven machine (300), and a connection device (303) interposed between the auxiliary generator and the turbine (2) for selectively connecting the auxiliary generator to the turbine (2).

11. A method for energy storage comprising: carrying out a closed thermodynamic cyclic transformation (CTT) from a casing (5) for storing a working fluid different from the atmosphere to a tank (9) for storing said working fluid in a liquid or supercritical phase having a temperature close to a critical temperature, first in one direction during a charging configuration / process, and then from said tank (9) to said casing (5) in the opposite direction during a discharging configuration / process, said casing (5) being a pressure balloon or having the structure of a gas tank or other gas storage system having a low or zero overpressure such that said working fluid is in gas phase and in pressure equilibrium with said atmosphere, said critical temperature being between 0°C and 100°C, said method comprising: storing heat and pressure during the charging process, generating mechanical energy during the discharging process, and transferring said mechanical energy to a driven machine (300) different from a generator to drive said driven machine (300). A method comprising:

12. The filling process comprises: - compressing the working fluid, the working fluid coming from the casing (5) externally in contact with the atmosphere and absorbing energy, the casing (5) defining internally a volume configured to contain the working fluid at or near atmospheric pressure; directing the compressed working fluid through a primary heat exchanger (7) and a secondary heat exchanger (10) arranged in series to bring the temperature of the working fluid close to its own critical temperature, the primary heat exchanger (7) acting as a cooler to remove heat from the compressed working fluid and cool the working fluid to store thermal energy, and the secondary heat exchanger (10) acting as a cooler to remove further heat from the compressed working fluid and store further thermal energy; storing the cooled working fluid in the tank (9), wherein the secondary heat exchanger (10) and the primary heat exchanger (7) perform a supercritical transformation of the working fluid such that the working fluid is stored in the tank (9) in a supercritical phase, or the secondary heat exchanger (10) and the primary heat exchanger (7) perform a subcritical transformation of the working fluid such that the working fluid is stored in the tank (9) in a liquid phase, the temperature of the working fluid stored in the tank (9) being between 0°C and 100°C, and the pressure of the working fluid stored in the tank (9) being between 10 bar and 150 bar; The method of claim 11 , comprising:

13. The working fluid is CO ２ , S.F. ６ , N ２ 13. The method of claim 11 or 12, wherein the alkyl group is selected from the group including O.

14. Said process of release and production of mechanical energy comprises: - passing the working fluid coming from the tank (9) through the secondary heat exchanger (10) and the primary heat exchanger (7), the secondary heat exchanger (10) acting as a heater to transfer heat to the working fluid coming from the tank (9) and the primary heat exchanger (7) acting as a heater to transfer further heat to the working fluid to heat it; passing the heated working fluid through a turbine (2) mechanically connected to the driven machine (300), the turbine (2) being rotated by the heated working fluid to drive the driven machine (300), the working fluid expanding and cooling within the turbine (2); reintroducing into said casing (5) a working fluid coming from said turbine (2) at atmospheric or near atmospheric pressure; The method of claim 12, comprising:

15. 15. The method according to claim 14, wherein in the process of releasing and generating mechanical energy, between the primary heat exchanger (7) and the turbine (2), the working fluid is further heated via an additional heat source (230) selected from among a solar source, industrial recovered waste heat, and gas turbine exhaust heat.

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