Method and apparatus for ozone-free separation of components in a corona discharge zone

Abstract

A method and apparatus (10) for separating components in a corona discharge zone includes passing a stream of air containing water molecules between at least one ionizing electrode (17) and at least one non-ionizing electrode (12); applying a high voltage to the electrodes creates a corona discharge zone consisting of a plasma region where ozone is formed and a dark region where primarily hydrogen peroxide is formed. The air stream entering the corona discharge zone is split into two independent air streams, one passing through the corona discharge plasma region and the second passing through the corona dark discharge region; and applying a negative pressure gradient only to the plasma region to remove the ozone and thereby separate it from the hydrogen peroxide.

Description

[Technical field]

[0001] The present invention relates to an air treatment device that operates using corona discharge. One application relates to a method for air disinfection using hydrogen peroxide as disinfectant and to a disinfection device designated for disinfection of manned facilities. [Background technology]

[0002] Bipolar ion generators have become the most common type used for air disinfection in manned facilities, with typical examples being disclosed in U.S. Patent Nos. 9,071,040, 10,020,180, 10,128,075, and 9,843,169.

[0003] The principle of operation of such bipolar ion generating devices is based on the generation of a corona discharge region by passing a flow of air containing water molecules (moisture) between ionizing electrodes of opposite polarity, either in whole or in part. In known devices, the air flow is either parallel to the axis of the ionizing electrodes, running from the non-ionizing part of the electrodes to the ionizing tip of the electrodes (see, for example, US Pat. No. 9,843,169), or perpendicular to the axis of the electrodes (see, for example, US Pat. No. 10,020,180).

[0004] In the corona discharge region, two processes occur due to the decomposition of the oxygen molecule O2 into two oxygen atoms O+O: the conversion of the water molecule H2O into hydrogen peroxide H2O2 and the formation of ozone O3, i.e. H2O+O=H2O2(1) O2+O=O3(2) occur simultaneously.

[0005] Therefore, the air stream at the outlet of the bipolar ion generator simultaneously contains hydrogen peroxide, ozone, and positive and negative ions captured by the air stream exiting the corona discharge region. The H2O2 molecules used as a liquid disinfectant have a longer contact time with bacteria and viruses, as well as spores, compared to gaseous ozone.

[0006] A notable drawback of bipolar ionizers is their low disinfection efficiency, limited by the maximum permissible ozone concentration in occupied facilities, which is equal to 100 ppb.

[0007] As mentioned above, H2O2 and O3 are produced as a result of two processes that occur simultaneously during corona discharge. The process of O3 production is much more efficient than the process of H2O2 production. In fact, with the current state of the art corona discharge method, the electrical energy required to produce 1 kg of ozone is 7-10 kW / h, whereas to produce 1 kg of H2O2, 250 kW / h of electrical energy is required. However, the maximum permissible ozone concentration in a manned facility is only 100 ppb, which determines the maximum permissible discharge current. However, the maximum permissible ozone concentration in a manned facility is only 100 ppb, which determines the maximum permissible discharge current. In practice, this means that, taking into account the respective chemical reactions (1) and (2) that produce H2O2 and O3 by corona discharge, the energy consumption that results in an ozone concentration of 100 ppb results in a concentration of H2O2 of about 7 ppb, whereas the maximum permissible concentration of H2O2 in a manned facility is 1000 ppm or 1 ppm.

[0008] US Patent No. 6,373,680 discloses an ionizer that reduces the emission of ozone generated simultaneously with the ionization process. The ionizer comprises a split housing having front and rear sections separated by an activated carbon filter and defining front and rear openings. An ionizing electrode is disposed in the front section, with its tip facing axially forward toward the front opening surrounded by a non-ionizing annular electrode. When a high voltage DC is applied between the two electrodes, a corona discharge is generated between the tip of the ionizing electrode and the non-ionizing electrode, resulting in a combined flow of ions and ozone. A ventilation fan disposed in the rear section applies a negative pressure to the interior of the housing, which draws ozone toward the rear opening, where it is neutralized by the activated carbon filter while allowing ions to exit only through the front opening.

[0009] The device disclosed in U.S. Pat. No. 6,373,680 separates the ozone flow from the ion flow so that only ions are released, and neutralizes the ozone, but this device does not separate hydrogen peroxide from the ozone. Therefore, any hydrogen peroxide generated in the corona discharge area will also be drawn toward the rear opening by the exhaust fan and neutralized by the activated carbon filter, and will not escape to the atmosphere through the rear opening. Furthermore, most of the ions generated in the corona discharge area will also be drawn toward the rear opening by the influence of the exhaust fan, but this pull by the influence of the exhaust fan is stronger than the force of the ion wind, which induces the ions to escape through the front opening. However, in any case, any ions that escape from the corona discharge area toward the front opening will not form H2O2 molecules, since there is no secondary emission, which is only within the electric field of the corona discharge. Therefore, no hydrogen peroxide is generated downstream of the ionizing electrode, and the only hydrogen peroxide generated is transported upstream by the exhaust fan and neutralized.

[0010] As a result, only very few ions are released into the atmosphere, making the device an inefficient ion generator and completely unusable as a sterilization device.

[0011] WO 2010 / 123579 discloses a corona gas ionization device in which pollutant by-products are separated from the ions generated by the corona. The device comprises an ion emitting device and a non-ionizing reference electrode with two different intermediate regions: (a) a plasma region where a corona discharge is formed; and b) a dark region, which is an ion drift region between the plasma region with the glow and the non-ionizing reference electrode. The ions and pollutant particles are separated by providing at least one non-ionized gas stream with a pressure flowing in a downstream direction while maintaining a lower pressure in the plasma region at the ionizing electrode. An air outlet transports clean air in a direction opposite to the ion flow.

[0012] EP 2192662 A1 discloses an electrostatic eliminator comprising a discharge section and a casing in which the discharge section for emitting ions is arranged in front of the discharge section. The casing comprises an ion discharge opening and an ozone suction opening. Ozone generated in the discharge section is sucked through the suction opening, so that air exiting from the ion discharge opening is sucked in a direction opposite to the direction of ion emission through the ion discharge opening.

[0013] US Patent No. 6,508,982 discloses an air purification device and method for purifying air with a flow of air containing ions and ozone produced by corona discharge. The device has a wind tunnel, in which air is drawn in from the distal end of the wind tunnel and discharged from the opposite end. A needle electrode is disposed in front of the wind tunnel, near the axis of the wind tunnel, and a corona discharge is induced by applying a high voltage between the needle and an annular electrode surrounding the wind tunnel, generating an air flow containing ions and ozone, thereby purifying the air. The wind tunnel functions to enhance the air flow, thereby improving the purification effect. [Prior art documents] [Patent documents]

[0014] [Patent Document 1] U.S. Patent No. 9,071,040 [Patent Document 2] U.S. Patent No. 10,020,180 [Patent Document 3] U.S. Patent No. 10,128,075 [Patent Document 4] U.S. Pat. No. 9,843,169 [Patent Document 5] U.S. Patent No. 6,373,680 [Patent Document 6] International Publication No. 2010 / 123579 Brochure [Patent Document 7] European Patent Application Publication No. 2192662 [Patent Document 8] U.S. Patent No. 6,508,982 Summary of the Invention [Problem to be solved by the invention]

[0015] The main objective of the present invention is to remove the ozone generated within the corona discharge area to prevent its release into the enclosed atmosphere, in order to significantly increase the corona discharge current and improve the disinfection efficiency by more than 10 times using an ion generator, an H2O2 generator and an electrostatic filter.

[0016] The present invention achieves this objective using a "tip plane" corona discharge, which, according to known corona discharge theory, consists of a plasma ionization region, which is the light-emitting space near the tip of the ionizing electrode, and a dark space region, which is between the ionizing electrode or "tip" and the non-ionizing electrode or "plate" and where secondary ion emissions occur within the corona discharge electric field. It should be understood that the above principles also apply to corona discharge and wire-plane systems.

[0017] Water molecules are converted to H2O2 molecules during both the plasma ionization process and the secondary emission process, i.e., in the entire corona discharge region consisting of both the plasma ionization region and the dark region, but in reality, the total amount of ozone is contained in a very small volume (2-3 mm2) compared to the entire ozone discharge region. 3 ) is formed within the plasma ionization region.

[0018] However, due to the high speed of ions in the electric field of the corona discharge, neutral ozone molecules generated in the plasma ionization region are attracted by the regular movement of ions along the lines of force of the electric field and reach the dark region of the corona discharge. This phenomenon is called ionic wind, the speed of which is 1-5 m / s depending on the speed of the corona discharge current, which is itself a function of the magnitude of the corona discharge current. The essence of the invention is based on the removal or destruction of ozone after the separation of H2O2 molecules from O3 molecules during the corona discharge.

[0019] The above object of the invention is achieved by a method and an arrangement having the features of the respective independent claims.

[0020] The principle of the invention is to split the air flow entering the corona discharge region into two flows, the first of which is passed through the plasma region of the corona discharge and an ozone filter, and the second of which is passed through the dark space region of the corona discharge.

[0021] In order to efficiently separate H2O2 and O3 molecules, the effect of the ionic wind should be neutralized, and therefore one of the requirements for implementing this method is that the velocity of the air flow that has passed through the plasma region of the corona discharge is higher than the ionic wind velocity.

[0022] In one embodiment of the present invention, the above requirements are met by mounting ionizing electrodes at specific locations within the overall air flow.

[0023] According to the invention, the air flow passing through the corona discharge area is parallel to the axis of the ionizing electrode, but is guided from the tip of the ionizing electrode to the non-ionizing part of the electrode. This causes the ionic wind vector to be in the opposite direction to the air flow vector, reducing the ionic wind velocity and therefore the required negative pressure gradient to separate the air flow. In practice, this means that a lower power suction device can be used.

[0024] Since the ionic wind velocity is directly proportional to the magnitude of the corona discharge current and inversely proportional to the volume of the corona discharge region, a second requirement for efficient separation of H2O2 and O3 is to increase the volume of the corona discharge region.

[0025] To meet the above requirements, the non-ionizing electrode is formed as a hollow cylinder having inlet and outlet openings for the air flow therein, and inside the hollow cylinder the ionizing electrode is mounted such that the axis of the ionizing electrode is coaxial with the geometrical axis of the cylinder.

[0026] The above solution results in the maximum possible volume of the corona discharge region and, consequently, the minimum possible ionic wind velocity.

[0027] The method described above can be applied both to the generation of unipolar negative or positive corona discharges using a single ionizing electrode, and to the generation of bipolar corona discharges using two ionizing electrodes of opposite polarity, in which case the corona discharge has two plasma corona discharge regions from which ozone is removed.

[0028] The disinfection device according to the invention is based on the proposed method comprising the following elements: a non-ionizing cylindrical electrode having inlet and outlet openings for the air flow, an ionizing electrode having an axis coaxial with the geometric axis of the non-ionizing electrode, a high voltage generator configured to generate a corona discharge region between the electrodes, and a suction device with inlet and outlet air flow paths for generating a negative pressure gradient region with the purpose of forming a plasma region of the corona discharge and an air flow passing through an ozone filter to prevent the leakage of ozone.

[0029] The inlet opening of the inlet air passage of the aspirator is positioned adjacent the ionizing tip of the ionizing electrode, and the outlet air passage of the aspirator is connected to the inlet of the ozone filter.

[0030] At the same time, the high voltage output of the high voltage generator is connected to the ionizing electrode and the low voltage output of the high voltage generator is connected to the non-ionizing electrode.

[0031] In order to understand the invention and to see how it may be carried into practice, embodiments will now be described, by way of non-limiting example only, with reference to the accompanying drawings, in which: [Brief description of the drawings]

[0032] [Figure 1] 1 is a schematic diagram of an apparatus according to the present invention; DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0033] 1 shows diagrammatically a sterilization apparatus 10 comprising a generally hollow cylindrical chamber 11 having an electrically conductive interior wall 12. The cylinder 11 defines at least one inlet opening 15 for air at a lower end 13 of the cylinder 11 and an outlet opening 16 for air at an upper end 14 of the cylinder 11. An ionizing electrode 17 is supported by a non-ionizing portion 18 at the upper end 14 of the chamber such that a tip of the electrode 17 projects into the interior of the chamber.

[0034] The high voltage generator 20 has a power supply terminal 21 allowing connection to a voltage source such as a mains power supply, and high voltage output terminals 22, 22' connected to the ionizing electrode 17 and the inner wall 12 of the chamber 11, which serves as a non-ionizing electrode, respectively. Application of a high voltage between these two electrodes creates a corona discharge region between the electrodes, consisting of a plasma corona discharge region 23 and a corona dark discharge region 24. The hollow air passage 25 is mounted in a spatial relationship such that it is in axial alignment with the chamber 11 and the ionizing electrode 17, and is sized to encompass the entire area of ​​the plasma corona discharge region 23. It should be understood that the drawings are schematic and are intended to demonstrate the principles of the invention. The air passage 25 may be supported in a chamber lid (not shown), which is mounted to the outer periphery of the chamber, but is perforated to allow free flow of air other than the air passing through the hollow air passage 25. Alternatively, both chamber 11 and hollow air passage 25 may be supported within an outer structure (not shown) for proper spatial alignment. Additionally, although the device is illustrated in Figure 1 as being symmetrical with hollow chamber 11 coaxial with the longitudinal axis of chamber 11, this is not a requirement. The only requirement is that the ionizing electrode be coaxial with hollow air passage 25. Similarly, although chamber 11 is described as being cylindrical, the cross section of chamber 11 may be any other polygonal shape.

[0035] A suction device 26 having a power input terminal 27 is mounted on the air passage 25 in fluid communication with the suction device 26, but is also connected through a passage 28 to a filter 29, typically an activated carbon (AC) filter. The suction device 26 may be a centrifugal fan or compressor that creates a negative pressure gradient, thereby drawing air in the plasma corona discharge region 23 through the air passage 25 and into the filter 29. The magnitude of the negative pressure gradient required to remove ozone can be determined experimentally by measuring the maximum possible concentration of ozone when the corona discharge current is at a maximum and the velocity of the undivided air flow is at a minimum. The desired maximum corona discharge current is selected depending on the use of the device, i.e., whether the primary use of the device is to release hydrogen peroxide, and if so, at what desired concentration; or whether the device is an electrostatic filter or an ionizer. Once the desired maximum corona discharge current is established, the air flow is increased and the ozone concentration is measured. The air flow is then increased slightly and the ozone concentration is measured again. This is repeated until the ozone concentration no longer increases. There is no further benefit in increasing the air flow beyond this value, but an optimum air flow for a given corona discharge current is established, where the air velocity flowing through the plasma region of the corona discharge is higher than the ionic wind velocity for the preset corona discharge current.

[0036] The operation of the disinfection device 10 is as follows.

[0037] When a high voltage source 20 is applied to the terminal 21, a corona discharge region is generated between the ionizing electrode 17 and the non-ionizing electrode constituted by the inner wall 12 of the chamber 11. A plasma corona discharge 23 is generated near the tip of the ionizing electrode 17, and the remaining volume of the corona discharge forms a corona dark discharge region 24. At the same time, power is supplied to the power terminal 27 of the suction device 26, which generates a negative pressure gradient in the air flow path 25, which draws the ozone formed in the plasma corona discharge region 24 through the flow path 28 into the filter 29, where it is neutralized. The ozone-free air then exits the ozone filter and reaches the air to be disinfected. As the air flows through the dark region of the corona discharge 24, some of the water molecules are converted into hydrogen peroxide molecules due to interaction with the ions in the corona discharge electric field, again creating an environment in which the air flows through the outlet opening 16 of the lid 14, as indicated by the arrow A. As a result, the ozone is separated from most of the hydrogen peroxide, but a small amount of hydrogen peroxide also passes through the air passages 25 and 28 and is neutralized by the filter 29. However, most of the hydrogen peroxide passes through the outlet opening 16 and enters the atmosphere, thus disinfecting the atmosphere, while ozone-free air enters the atmosphere through the filter outlet. Because the filter prevents ozone from escaping into the enclosed atmosphere, the corona discharge current can be safely increased to a level that produces much more hydrogen peroxide, as evidenced by the following Table 1, which shows the technical specifications of a disinfection device manufactured and tested according to the present invention.

[0038] In practice, the filter 29 neutralizes the ozone with the aim of lowering the concentration of ozone released into the enclosed atmosphere in which the device is placed below an acceptable upper limit, but the same aim can also be achieved without a filter, by simply extracting the ozone from the enclosed atmosphere through an outlet tube or conduit, which can also be considered as a continuation of the flow path 28. [Table 1]

[0039] The H2O2 and O3 concentrations were measured using the following equipment: a) H2O2 concentration: Portable gas detector OC-905 Resolution - 0.01ppm, accuracy ±3% O3 concentration: Ozone analyzer Dasibi Model 1008. Resolution - 1ppb, accuracy ±2%.

[0040] Although the invention has been described with particular reference to disinfection devices and methods, it will be understood that the principles of the invention can be applied just as well to other devices based on corona discharge, where the maximum permissible concentration of ozone imposes a limit on efficiency. The same principles can therefore also be applied to electrostatic filters and ionizers. The same principles can therefore also be applied to electrostatic filters and ionizers.

[0041] It should also be noted that although ozone filters have been described in the context of activated carbon filters, the term "filter" should be interpreted in its broadest sense as a device that separates ozone from air and prevents it from escaping into the atmosphere. Whether the ozone is simply captured or destroyed is not critical to the present invention, since once the passage of ozone into the atmosphere has been prevented, the corona discharge current can be safely increased. Other techniques for preventing ozone from escaping into the atmosphere include chemical oxidation, where the ozone is passed through a titanium reaction chamber. It is also known to use catalytic processes, involving reaction with chlorine gas, bromine gas, nitrogen gas, hydrogen gas, and oxygen gas, or a destruction catalyst such as a mixture of copper and manganese dioxide.

Claims

1. (a) passing a stream of air containing water molecules between at least one ionizing electrode (17) and at least one non-ionizing electrode (12); (b) applying a high voltage to the at least one ionizing electrode (17) and the at least one non-ionizing electrode (12) to create a corona discharge region consisting of a plasma ionization region (23) where ozone is formed and a dark space region (24) where primarily hydrogen peroxide is formed; (c) splitting the air stream entering the corona discharge region into two separate air streams, a first air stream passing through the plasma ionization region (23) and a second air stream passing through the dark space region (24); (d) preventing said ozone in said first air stream from escaping into the enclosed atmosphere by applying a negative pressure gradient only in said plasma ionization region (23) to remove said ozone; 1. A method for efficiently generating unipolar ions in a corona discharge region, comprising: (e) supporting the ionizing electrode (17) at an upper end of a chamber (11) having an inner wall surface that functions as the non-ionizing electrode (12), and axially aligning a non-ionizing portion (18) of the ionizing electrode (17) with a hollow air passage (25) sized to encompass the entire area of ​​the plasma ionization region (23) such that a tip of the ionizing electrode (17) projects into the chamber (11) from an open lower end of the hollow air passage (25); (f) applying a unipolar negative or positive corona discharge between the ionizing electrode (17) and the non-ionizing electrode (12); method.

2. 2. The method of claim 1, wherein the velocity of air flowing through the plasma ionization region (23) of the corona discharge region is higher than the ionic wind velocity of a preset corona discharge current.

3. 3. The method of claim 1 or 2, wherein the air flow through the plasma ionization region (23) is generally parallel to the axis of the ionizing electrode (17) and flows from the tip of the ionizing electrode (17) towards the non-ionizing portion (18) of the ionizing electrode (17).

4. The method according to any one of claims 1 to 3, wherein the direction of the first air flow and the direction of the second air flow are coincident.

5. 5. The method according to claim 4, wherein the chamber (11) is cylindrical and the first air flow is coaxial with the geometric axis of the chamber (11).

6. A method according to any one of claims 1 to 5, wherein preventing the ozone in the first air flow from escaping into the enclosed atmosphere includes filtering the ozone.

7. A method according to any one of claims 1 to 5, wherein preventing the ozone in the first air flow from leaking into the enclosed atmosphere includes extracting the ozone from the enclosed atmosphere.

8. The method according to any one of claims 1 to 7, comprising disinfecting the air in the enclosed atmosphere by releasing hydrogen peroxide formed in the dark space area (24) of the corona discharge area into the enclosed atmosphere via the hollow air channel (25).

9. The method according to any one of claims 1 to 7, comprising purifying the air in the enclosed atmosphere by releasing ions formed in the dark space area (24) of the corona discharge region into the enclosed atmosphere via the hollow air passage (25).

10. a chamber (11) having a first end (13) and a second end (14) opposite the first end (13); a first outlet (16) and a second outlet (25); at least one ionizing electrode (17) supported within said second outlet (25) and having a tip; at least one non-ionizing electrode (12) inside said chamber (11); a high voltage generator (20) connected to the at least one ionizing electrode (17) and the at least one non-ionizing electrode (12), for generating a corona discharge region between the electrodes, the corona discharge region having a plasma ionization region (23) in which ozone is formed and a dark region (24) in which mainly hydrogen peroxide is formed; an air inlet (15) formed in the first end (13) of the chamber (11) for transporting a flow of air through the corona discharge region; a suction device (26) connected to the second outlet (25) for generating a negative pressure gradient in the plasma ionization region (23); An apparatus (10) comprising: the first outlet (16) is fluidly connected to the dark space area (24); The suction device (26) has an outlet (28), and ozone is exhausted through the outlet (28) to prevent the ozone from leaking into the enclosed atmosphere; the first outlet (16) and the second outlet (25) are formed at the second end (14) of the chamber (11); the second outlet (25) being a hollow air passage (25) mounted in a predetermined spatial relationship with the chamber (11) and sized to encompass the entire area of ​​the plasma ionization region (23); the ionizing electrode (17) is supported by a non-ionizing portion (18) at the upper end of the chamber (11) in axial alignment with the hollow air passage (25) such that the tip of the ionizing electrode (17) projects into the chamber (11) from the open lower end of the hollow air passage (25); the inner wall of the chamber (11) acts as the non-ionizing electrode (12) and the corona discharge region extends from the tip of the ionizing electrode (17) to the inner wall of the chamber (11); the high voltage generator (20) is configured to apply a unipolar negative or positive corona discharge between the ionizing electrode (17) and the non-ionizing electrode (12); Apparatus (10).

11. 11. The apparatus of claim 10, wherein the air flow through the corona discharge region is generally parallel to the axis of the ionizing electrode (17) and flows from the tip of the ionizing electrode (17) toward a non-ionizing portion (18) of the ionizing electrode (17).

12. 12. Apparatus according to claim 10 or 11, wherein the first outlet (16) is adjacent to the ionizing electrode (17) outside the corona discharge region.

13. 13. Apparatus according to any one of claims 10 to 12, wherein the first outlet (16) and the second outlet (25) are arranged on opposite sides of the air inlet (15).

14. 14. The apparatus according to any one of claims 10 to 13, wherein the chamber (11) is cylindrical, the non-ionizing electrode (12) is an inner wall (12) of the chamber (11), and the ionizing electrode (17) is mounted inside the chamber (11) so as to be coaxial with the axis of the chamber (11).

15. Disinfection device comprising a device according to any one of claims 10 to 14.

16. A unipolar ion generating device comprising a device according to any one of claims 10 to 14.

17. Electrostatic filter comprising a device according to any one of claims 10 to 14.

18. 18. Apparatus according to any one of claims 10 to 17, wherein the outlet (28) of the suction device (26) is fluidly connected to a filter (29) to prevent the ozone from escaping into an enclosed atmosphere.

19. 18. Apparatus according to any one of claims 10 to 17, wherein the outlet (28) of the suction device (26) is fluidly connected to an outlet tube or pipe for exhausting the ozone outside the enclosed atmosphere.

Images