Lithium secondary battery

Abstract

The present invention provides a lithium secondary battery which has a high energy density and excellent cycle characteristics. The present invention pertains to a lithium secondary battery comprising a positive electrode, a negative electrode that does not include negative electrode active material, and an electrolyte, the negative electrode being coated, on at least a portion of the surface facing the positive electrode, with a compound that contains an aromatic ring in which two or more elements selected from the group consisting of N, S, and O are independently bonded, and the electrolyte comprising a lithium salt and a solvent represented by formula (1).

Description

[Technical Field]

[0001] The present invention relates to a lithium secondary battery. [Background technology]

[0002] In recent years, technology for converting natural energy such as solar or wind power into electrical energy has been attracting attention. Accordingly, various secondary batteries have been developed as energy storage devices that are highly safe and can store large amounts of electrical energy.

[0003] Among these, lithium secondary batteries, which charge and discharge by transferring lithium ions between a positive electrode and a negative electrode, are known to exhibit high voltage and high energy density. A typical lithium secondary battery is the lithium-ion secondary battery (LIB), which has active materials capable of retaining lithium elements in the positive electrode and negative electrode, and charges and discharges by transferring lithium ions between the positive electrode active material and the negative electrode active material.

[0004] Furthermore, in order to achieve a high energy density, lithium secondary batteries (lithium metal batteries; LMBs) have been developed that use lithium metal as the negative electrode active material instead of materials that can insert lithium ions, such as carbon materials. For example, Patent Document 1 discloses a rechargeable battery that uses a lithium metal-based electrode as the negative electrode.

[0005] Furthermore, with the aim of achieving even higher energy density and improving productivity, lithium secondary batteries have been developed that use negative electrodes that do not have negative electrode active materials such as carbon materials or lithium metal. For example, Patent Document 2 discloses a lithium secondary battery that includes a positive electrode, a negative electrode, a separator membrane interposed between them, and an electrolyte, in which metal particles are formed on the negative electrode current collector of the negative electrode, and these particles are transferred from the positive electrode upon charging to form lithium metal on the negative electrode current collector within the negative electrode. Patent Document 2 discloses that such a lithium secondary battery can solve problems caused by the reactivity of lithium metal and problems that arise during the assembly process, thereby providing a lithium secondary battery with improved performance and lifespan. [Prior art documents] [Patent documents]

[0006] [Patent Document 1] Special Publication No. 2006-500755 [Patent Document 2] Special Publication No. 2019-505971 Summary of the Invention [Problem to be solved by the invention]

[0007] However, the present inventors have conducted detailed studies of conventional batteries, including those described in the above patent documents, and have found that at least one of the energy density and cycle characteristics is insufficient.

[0008] For example, it is difficult to achieve a sufficiently high energy density in a lithium secondary battery equipped with a negative electrode having a negative electrode active material due to the volume and mass occupied by the negative electrode active material. Furthermore, in conventional anode-free lithium secondary batteries equipped with a negative electrode without a negative electrode active material, repeated charge and discharge easily causes dendritic lithium metal to form on the surface of the negative electrode, which easily leads to short circuits and / or capacity reduction, resulting in insufficient cycle characteristics.

[0009] The present invention has been made in view of the above problems, and has as its object to provide a lithium secondary battery having high energy density and excellent cycle characteristics. [Means for solving the problem]

[0010] A lithium secondary battery according to one embodiment of the present invention comprises a positive electrode, a negative electrode having no negative electrode active material, and an electrolyte, wherein at least a portion of the surface of the negative electrode facing the positive electrode is coated with a compound containing an aromatic ring to which two or more elements selected from the group consisting of N, S, and O are independently bonded, and the electrolyte contains a lithium salt and a solvent represented by the following formula (1): 1 is an n-valent atomic group containing at least one nitrogen atom and 1 to 30 carbon atoms, and R 2 are each independently a fluorine atom or an alkyl group having a fluorine atom, n is an integer of 1 or more and 5 or less, and each of the n [-SO2R 2 ] group is R 1 is bonded to by an N-S bond. [ka]

[0011] The lithium secondary battery of the above embodiment uses a negative electrode that does not have a negative electrode active material, and therefore has a smaller overall volume and mass and, in principle, a higher energy density than a lithium secondary battery that has a negative electrode active material. The lithium secondary battery of the above embodiment is charged and discharged by depositing lithium metal on the surface of the negative electrode and electrolytically dissolving the deposited lithium metal.

[0012] Furthermore, by using a negative electrode in which at least a portion of the surface facing the positive electrode is coated with a compound containing an aromatic ring to which two or more elements selected from the group consisting of N, S, and O are independently bonded, deposition of lithium metal on the negative electrode surface and its dissolution are assisted, and it is presumed that the lithium secondary battery of the above embodiment has excellent cycle characteristics.

[0013] Furthermore, the present inventors have found that, in addition to the above-mentioned configuration, the above-mentioned lithium secondary battery can achieve both high energy density and excellent cycle characteristics when the electrolyte solution contains a solvent represented by the above formula (1) and a lithium salt. Although the reasons for this are not clear, it is presumed that the inclusion of the compound represented by formula (1) in the electrolyte solution suppresses deterioration of the positive electrode material, improves the reversibility of lithium metal deposition and dissolution on the negative electrode surface during repeated charge and discharge of the battery, facilitates the formation of a solid electrolyte interface layer (hereinafter also referred to as an "SEI layer") on the negative electrode surface, and / or improves the quality of the SEI layer. However, the reasons for this are not limited to those mentioned above.

[0014] In the lithium secondary battery according to one embodiment of the present invention, preferably, 1 In [-SO2R 2 According to such an embodiment, the nitrogen atom bonded to the [—SO R 2 The reactivity of the ] group tends to be more favorable, and the lithium secondary battery tends to have more excellent cycle characteristics.

[0015] In the lithium secondary battery according to one embodiment of the present invention, 1 may contain a chain structure containing at least one nitrogen atom.

[0016] In the lithium secondary battery according to one embodiment of the present invention, 1 may contain a ring structure containing at least one nitrogen atom.

[0017] In the lithium secondary battery according to one embodiment of the present invention, preferably, 2 are each independently a fluorine atom or an alkyl group having a ratio (F / (F+H)) of the number of fluorine atoms (F) to the total number of fluorine atoms and hydrogen atoms (F+H) of 0.70 or more and 1.0 or less. 2The reactivity of the ] group tends to be more favorable, and the lithium secondary battery tends to have more excellent cycle characteristics.

[0018] In the lithium secondary battery according to one embodiment of the present invention, preferably, 2 are each independently a fluorine atom or a trifluoromethyl group. According to such an embodiment, the lithium secondary battery tends to have even more excellent cycle characteristics.

[0019] In the lithium secondary battery according to one embodiment of the present invention, the electrolyte solution preferably further contains an ether compound having no fluorine atoms or a carbonyl compound having no fluorine atoms, which tends to further improve the cycle characteristics of the lithium secondary battery in a synergistic manner with the compound represented by formula (1).

[0020] In the lithium secondary battery according to one embodiment of the present invention, the electrolyte solution preferably further contains a chain fluorine compound represented by the following formula (A) or formula (B). Such a compound tends to further improve the cycle characteristics of the lithium secondary battery in a synergistic manner with the compound represented by formula (1). In formula (A), R 6 is an alkyl group which may contain an ether bond, and R 7 is a fluorine-substituted alkylene group, and R 8 is an alkyl group which may contain an ether bond. 9 is a fluorine-substituted alkyl group, and R 10 is an alkylene group which may contain an ether bond, and R 11 represents an alkyl group which may be substituted with fluorine. [ka] [ka]

[0021] In the lithium secondary battery according to one embodiment of the present invention, the lithium salt preferably contains at least LiN(SOF). According to such an embodiment, the lithium secondary battery tends to have even more excellent energy density and cycle characteristics.

[0022] In the lithium secondary battery according to one embodiment of the present invention, preferably, in the compound coating the negative electrode, one or more nitrogen atoms are bonded to the aromatic ring. In this embodiment, the strength of the interaction between the negative electrode coating agent and lithium ions becomes more favorable, and the cycle characteristics of the lithium secondary battery tend to be more excellent.

[0023] In the lithium secondary battery according to one embodiment of the present invention, the compound coated on the negative electrode is preferably at least one selected from the group consisting of benzotriazole, benzimidazole, benzimidazole thiol, benzoxazole, benzoxazole thiol, benzothiazole, mercaptobenzothiazole, polyimide, polyimidazole, and derivatives thereof. According to such an embodiment, the lithium secondary battery has a better electrical connection between the negative electrode and the lithium ions coordinated by the negative electrode coating agent, which tends to further improve the cycle characteristics of the lithium secondary battery.

[0024] In the lithium secondary battery according to one embodiment of the present invention, the positive electrode preferably includes a positive electrode active material and a lithium-containing compound that undergoes an oxidation reaction and does not substantially undergo a reduction reaction in the charge-discharge potential range of the positive electrode active material. According to such an embodiment, the lithium secondary battery tends to have even better cycle characteristics. [Effects of the Invention]

[0025] According to the present invention, it is possible to provide a lithium secondary battery having high energy density and excellent cycle characteristics. [Brief explanation of the drawings]

[0026] [Figure 1] 1 is a schematic cross-sectional view of a lithium secondary battery according to an embodiment of the present invention. [Figure 2] 1 is a schematic cross-sectional view of a lithium secondary battery according to an embodiment of the present invention; DETAILED DESCRIPTION OF THE INVENTION

[0027] Hereinafter, an embodiment of the present invention (hereinafter referred to as "the present embodiment") will be described in detail with reference to the drawings as necessary. In the drawings, the same elements will be given the same reference numerals, and duplicate explanations will be omitted. Furthermore, unless otherwise specified, positional relationships such as up, down, left, and right will be based on the positional relationships shown in the drawings. Furthermore, the dimensional ratios of the drawings are not limited to those shown in the drawings.

[0028] [Present embodiment] (lithium secondary battery) Fig. 1 is a schematic cross-sectional view of a lithium secondary battery according to this embodiment. As shown in Fig. 1, the lithium secondary battery 100 of this embodiment includes a positive electrode 120, a negative electrode 140 that does not have a negative electrode active material, a separator 130 disposed between the positive electrode 120 and the negative electrode 140, and an electrolyte solution not shown in Fig. 1. The positive electrode 120 has a positive electrode current collector 110 on the surface opposite to the surface facing the separator 130. Each component of the lithium secondary battery 100 will be described below.

[0029] (Negative electrode) The negative electrode 140 does not have a negative electrode active material. In this specification, the term "negative electrode active material" refers to a material that causes an electrode reaction, i.e., an oxidation reaction and a reduction reaction, at the negative electrode. Specifically, the negative electrode active material of this embodiment includes lithium metal and a host material of lithium element (lithium ion or lithium metal). The host material of lithium element refers to a material provided to hold lithium ion or lithium metal in the negative electrode. The mechanism of such holding includes, but is not limited to, intercalation, alloying, and metal cluster occlusion, and is typically intercalation.

[0030] In the lithium secondary battery of this embodiment, the negative electrode does not have a negative electrode active material before the initial charge of the battery, so that lithium metal is deposited on the negative electrode and the deposited lithium metal is electrolytically dissolved, thereby performing charge and discharge. Therefore, compared with a lithium secondary battery having a negative electrode active material, the lithium secondary battery of this embodiment has a reduced volume occupied by the negative electrode active material and a reduced mass of the negative electrode active material, resulting in a smaller overall volume and mass of the battery, and therefore has a higher energy density in principle.

[0031] In the lithium secondary battery 100 of this embodiment, the negative electrode 140 does not contain a negative electrode active material before initial charging of the battery, and lithium metal is deposited on the negative electrode upon charging of the battery, and the deposited lithium metal is electrolytically dissolved upon discharging of the battery. Therefore, in the lithium secondary battery of this embodiment, the negative electrode functions as a negative electrode current collector. In other words, the lithium secondary battery of this embodiment has a negative electrode made of a negative electrode current collector that does not contain a negative electrode active material.

[0032] In this specification, "lithium metal is deposited on the negative electrode" means that lithium metal is deposited on at least one of the surface of the negative electrode coated with the negative electrode coating agent and the surface of a solid electrolyte interface layer (SEI layer) (described later) formed on the surface of the negative electrode. Therefore, in the lithium secondary battery 100, lithium metal may be deposited on, for example, the surface of the negative electrode 140 coated with the negative electrode coating agent (the interface between the negative electrode 140 and the separator 130).

[0033] The lithium secondary battery 100 of this embodiment differs from a lithium ion battery (LIB) and a lithium metal battery (LMB) in the following respects. In a lithium ion battery (LIB), the negative electrode has a host material of lithium element (lithium ion or lithium metal), and when the battery is charged, the material is filled with lithium element, and when the host material releases the lithium element, the battery is discharged. LIBs differ from the lithium secondary battery 100 of this embodiment in that the negative electrode has a host material of lithium element. A lithium metal battery (LMB) is manufactured using an electrode having lithium metal on its surface or elemental lithium metal as the negative electrode. That is, an LMB differs from the lithium secondary battery 100 of this embodiment in that the negative electrode has lithium metal as the negative electrode active material immediately after the battery is assembled, i.e., before the initial charge of the battery. While an LMB uses an electrode containing highly flammable and reactive lithium metal in its manufacture, the lithium secondary battery 100 of this embodiment uses a negative electrode that does not contain lithium metal, and therefore is safer and more manufacturable.

[0034] In this specification, the anode "has no anode active material" means that the anode 140 has no or substantially no anode active material. The anode 140 has substantially no anode active material means that the content of the anode active material in the anode 140 is 10 mass% or less relative to the entire anode. The content of the anode active material in the anode is preferably 5.0 mass% or less relative to the entire anode 140, and may be 1.0 mass% or less, 0.1 mass% or less, or 0.0 mass% or less. When the anode 140 has no anode active material or the content of the anode active material in the anode 140 is within the above range, the energy density of the lithium secondary battery 100 becomes high.

[0035] In this specification, the term "before initial charging" refers to the state of the battery from assembly to the first charging, and the term "at the end of discharging" refers to the state of the battery when the voltage is between 1.0 V and 3.8 V, preferably between 1.0 V and 3.0 V.

[0036] As used herein, a "lithium secondary battery having a negative electrode that does not have a negative electrode active material" means that the negative electrode 140 does not have a negative electrode active material before the initial charge of the battery. Therefore, the phrase "negative electrode that does not have a negative electrode active material" may be rephrased as "a negative electrode that does not have a negative electrode active material before the initial charge of the battery," "a negative electrode that does not have a negative electrode active material other than lithium metal regardless of the state of charge of the battery and that does not have lithium metal before the initial charge," or "a negative electrode current collector that does not have lithium metal before the initial charge," etc. Furthermore, a "lithium secondary battery having a negative electrode that does not have a negative electrode active material" may be rephrased as an anode-free lithium battery, a zero-anode lithium battery, or an anode-less lithium battery.

[0037] In the negative electrode 140 of this embodiment, regardless of the state of charge of the battery, the content of negative electrode active materials other than lithium metal is 10% by mass or less relative to the entire negative electrode, and may preferably be 5.0% by mass or less, 1.0% by mass or less, 0.1% by mass or less, 0.0% by mass or less, or even 0% by mass. Furthermore, in the negative electrode 140 of this embodiment, before initial charging, the lithium metal content is 10% by mass or less relative to the entire negative electrode, and may preferably be 5.0% by mass or less, 1.0% by mass or less, 0.1% by mass or less, 0.0% by mass or less, or even 0% by mass.

[0038] In the lithium secondary battery 100 of this embodiment, when the battery voltage is 1.0 V or more and 3.5 V or less, the lithium metal content may be 10 mass % or less (preferably 5.0 mass % or less, and may be 1.0 mass % or less) with respect to the entire negative electrode 140; when the battery voltage is 1.0 V or more and 3.0 V or less, the lithium metal content may be 10 mass % or less (preferably 5.0 mass % or less, and may be 1.0 mass % or less) with respect to the entire negative electrode 140; or when the battery voltage is 1.0 V or more and 2.5 V or less, the lithium metal content may be 10 mass % or less (preferably 5.0 mass % or less, and may be 1.0 mass % or less) with respect to the entire negative electrode 140.

[0039] In the lithium secondary battery 100 of this embodiment, the mass M of lithium metal deposited on the negative electrode when the battery voltage is 4.2 V is 4.2 The mass M of lithium metal deposited on the negative electrode when the battery voltage is 3.0 V 3.0 Ratio of M 3.0 / M 4.2 is preferably 40% or less, more preferably 38% or less, and even more preferably 35% or less. 3.0 / M 4.2 may be 1.0% or more, 2.0% or more, 3.0% or more, or 4.0% or more.

[0040] Examples of the negative electrode active material of this embodiment include lithium metal and alloys containing lithium metal, carbon-based materials, metal oxides, and metals that alloy with lithium and alloys containing such metals. Examples of the carbon-based materials include, but are not limited to, graphene, graphite, hard carbon, mesoporous carbon, carbon nanotubes, and carbon nanohorns. Examples of the metal oxides include, but are not limited to, titanium oxide compounds, tin oxide compounds, and cobalt oxide compounds. Examples of the metals that alloy with lithium include silicon, germanium, tin, lead, aluminum, and gallium.

[0041] The negative electrode 140 of this embodiment is not particularly limited as long as it does not contain a negative electrode active material and can be used as a current collector. Examples include at least one selected from the group consisting of Cu, Ni, Ti, Fe, and other metals that do not react with Li, their alloys, and stainless steel (SUS). Preferably, the negative electrode is made of at least one selected from the group consisting of Cu, Ni, their alloys, and stainless steel (SUS). Use of such a negative electrode tends to improve the energy density and productivity of the battery. When SUS is used for the negative electrode, various types of SUS known in the art can be used. The above-mentioned negative electrode materials can be used alone or in combination. In this specification, the term "metal that does not react with Li" refers to a metal that does not react with lithium ions or lithium metal to form an alloy under the operating conditions of a lithium secondary battery.

[0042] The capacity of the negative electrode 140 is sufficiently smaller than the capacity of the positive electrode 120, and may be, for example, 20% or less, 15% or less, 10% or less, or 5% or less. The capacities of the positive electrode 120 and the negative electrode 140 can be measured by a conventionally known method.

[0043] The average thickness of the negative electrode 140 is preferably 4 μm or more and 20 μm or less, more preferably 5 μm or more and 18 μm or less, and even more preferably 6 μm or more and 15 μm or less. According to such an embodiment, the volume occupied by the negative electrode 140 in the lithium secondary battery 100 is reduced, and therefore the energy density of the lithium secondary battery 100 is further improved.

[0044] (negative electrode coating agent) The lithium secondary battery 100 has a high energy density because it includes a negative electrode 140 that does not include a negative electrode active material. However, the inventors have discovered that simply using a negative electrode that does not include a negative electrode active material can cause dendritic lithium metal to deposit on the negative electrode during battery charge and discharge, resulting in a short circuit of the battery, or when the dendritic lithium metal dissolves, the base of the dendritic lithium metal dissolves, causing some of the lithium metal to peel off from the negative electrode and become inactive, resulting in a decrease in battery capacity. In the lithium secondary battery 100, a specific compound is coated on the surface of the negative electrode 140, which prevents the lithium metal deposited on the negative electrode from growing into a dendritic shape.

[0045] In the lithium secondary battery 100, at least a portion of the surface of the negative electrode 140 facing the positive electrode 120 (and the separator 130) is coated with a compound (hereinafter also referred to as the "negative electrode coating agent") containing an aromatic ring to which two or more elements selected from the group consisting of N, S, and O are independently bonded. The negative electrode coating agent is presumably held on the negative electrode 140 by at least one element selected from the group consisting of N, S, and O coordinating to a metal atom constituting the negative electrode 140. Therefore, even if the battery is repeatedly charged and discharged, it is presumed that the negative electrode coating agent will not detach and / or decompose. Note that the phrase "at least a portion of the surface facing the positive electrode" with respect to the portion coated with the negative electrode coating agent means that the negative electrode coating agent is coated on at least a portion of the negative electrode surface where lithium metal can deposit and dissolve. Therefore, it is not necessary for the negative electrode coating agent to be physically exactly coated on "at least a portion of the surface facing the positive electrode."

[0046] It is believed that the anode coating agent coordinated to the metal atoms constituting the anode interacts with lithium ions present on the surface of the anode at at least one element selected from the group consisting of N, S, and O. That is, since the anode coating agent can serve as a starting point or scaffold for the lithium metal deposition reaction on the surface of the anode, it is presumed that using an anode 140 coated with the anode coating agent can suppress the non-uniform deposition reaction of lithium metal on the surface, thereby suppressing the lithium metal deposited on the anode from growing into a dendritic shape.

[0047] Therefore, the negative electrode coating agent is not particularly limited as long as it is a compound containing an aromatic ring to which two or more elements selected from the group consisting of N, S, and O are independently bonded, i.e., a compound having a structure in which two or more N, S, or O are independently bonded to an aromatic ring. Examples of aromatic rings include aromatic hydrocarbons such as benzene, naphthalene, azulene, anthracene, and pyrene, and heteroaromatic compounds such as furan, thiophene, pyrrole, imidazole, pyrazole, pyridine, pyridazine, pyrimidine, and pyrazine. Among these, aromatic hydrocarbons are preferred, with benzene and naphthalene being more preferred, and benzene being even more preferred.

[0048] In the negative electrode coating agent, it is preferable that one or more nitrogen atoms are bonded to the aromatic ring. Furthermore, it is more preferable that the negative electrode coating agent is a compound having a structure in which a nitrogen atom is bonded to the aromatic ring and, in addition to the nitrogen atom, one or more elements selected from the group consisting of N, S, and O are each independently bonded. When such a compound in which a nitrogen atom is bonded to an aromatic ring is used as the negative electrode coating agent, the cycle characteristics of the battery tend to be further improved.

[0049] The negative electrode coating agent is preferably at least one selected from the group consisting of compounds represented by the following formula (C) and derivatives thereof. According to such an embodiment, the cycle characteristics of the battery tend to be further improved. In the formula, X 1 is X 3represents either C or N bonded to X 2 is X 4 represents any of N, S, and O to which X is bonded; 3 -R 12 , -NR 12 2, -OR 12 , or -SR 12 indicates an X 4 -R 13 , -CO-X, -CS-NX2, -SO2-X, -SiX3, and -OX; R 12 represents a hydrogen atom, an unsubstituted monovalent hydrocarbon group, or a pyridyl group; R 13 represents a hydrogen atom or an optionally substituted monovalent hydrocarbon group; and X represents an arbitrary monovalent substituent. [ka]

[0050] In formula (C), X 1 is X 3 represents either C or N to which X is bonded. 3 The C to which is bonded is CR 12 , C-NR 12 2. C-OR 12 , or C-SR 12 In this case, the leftmost C is N and X 2 where R 12 is a hydrogen atom, an unsubstituted monovalent hydrocarbon group, or a pyridyl group. 12 In R, the unsubstituted monovalent hydrocarbon group is not particularly limited, but examples thereof include linear or branched, saturated or unsaturated hydrocarbon groups having 1 to 10 carbon atoms, and preferably a methyl group or an ethyl group. 12 In the formula, the pyridyl group is not particularly limited, but examples thereof include a 2-pyridyl group, a 3-pyridyl group, and a 4-pyridyl group, and a 2-pyridyl group is preferred. 1 Preferred embodiments include N, CH, C—SH, C—C5H4N, and C—CH3.

[0051] In formula (C), X2 is X 4 represents any of N, S, and O to which X is bonded. 4 The N bonded to NR 13 , N-CO-X, N-CS-NX2, N-SO2-X, N-SiX3, and N-OX, in which the leftmost N is the C and X of the benzene ring. 1 where R 13 is a hydrogen atom or an optionally substituted monovalent hydrocarbon group, and X is any monovalent substituent.

[0052] R 13 In the formula (I), the optionally substituted monovalent hydrocarbon group is not particularly limited, and examples thereof include linear or branched, saturated or unsaturated hydrocarbon groups having 1 to 10 carbon atoms which may be substituted. Here, the substituent on the optionally substituted monovalent hydrocarbon group is not particularly limited, and examples thereof include a nitrile group, a halogen group, a silyl group, a hydroxy group, an alkoxy group, an aryl group, and an aryloxy group. X is not particularly limited, and examples thereof include a hydrogen atom, an unsubstituted linear or branched, saturated or unsaturated hydrocarbon group having 1 to 10 carbon atoms, an optionally substituted amino group, an optionally substituted aryl group, an optionally substituted heteroaromatic group, an alkylcarbonyl group, and an arylcarbonyl group. X may also be a substituent that does not have an active hydrogen atom.

[0053] X 2 Preferred embodiments of the above include S, O, NH, N-CH2-C(CH), N-CH2-Cl, N-CH2-Si(CH3)3, N-CH2-O-CH3, N-CH2-C(=CH2)-CH3, N-CH3, N-CS-NH-C3HC5, N-CS-NH-C3H2NS, N-CS-NH-CH2-C6H5, N-CS-NC4H8, N-CO-CH3, N-CO-C6H5, N-CO-C5H4N, N-CO-NH2, N-CO-C6H4Cl, N-CO-C 10H7, N—CO—NH—C6H5, N—SO2—CH3, N—SO2—C6H5, N—SO2—C3H2N2(CH3), N—SO2—C4H3S, N—SO2—C5H4N, and NO—CO—C6H5.

[0054] The compound represented by formula (C) may be a multimer such as a dimer or trimer, such as Tris-(1-benzotriazolyl)methane or 2,6-bis[(1H-benzotriazole-1-yl)methyl]-4-methylphenol, but it is preferable that the compound represented by formula (C) is a monomer.

[0055] Among these, the negative electrode coating agent is more preferably at least one selected from the group consisting of benzotriazole, benzimidazole, benzimidazole thiol, benzoxazole, benzoxazole thiol, benzothiazole, mercaptobenzothiazole, and derivatives thereof. According to such an embodiment, the electrical connection between the negative electrode and the lithium ions coordinated by the negative electrode coating agent is further improved, which tends to further improve the cycle characteristics of the battery.

[0056] From the same viewpoint, among these, the negative electrode coating agent is more preferably at least one selected from the group consisting of benzotriazole, benzimidazole, benzoxazole, mercaptobenzothiazole, and derivatives thereof.

[0057] Furthermore, it is also preferable to use, as the negative electrode coating agent, at least one selected from the group consisting of a polymer containing a structural unit derived from the compound represented by the above formula (C), polyimide, polyimidazole, and derivatives thereof. According to such an embodiment, the cycle characteristics of the battery tend to be further improved. From the same viewpoint, it is preferable to use polybenzimidazole or a derivative thereof as the polymer containing a structural unit derived from the compound represented by the above formula (C).

[0058] Derivatives of the compound represented by formula (C) above, or derivatives of benzotriazole, benzimidazole, benzimidazole thiol, benzoxazole, benzoxazole thiol, benzothiazole, mercaptobenzothiazole, polymers containing structural units derived from the compound represented by formula (C), polyimides, and polyimidazoles are not particularly limited as long as they are derived from these compounds and have a substituent bonded to a portion of these compounds. Examples of such derivatives include compounds in which the aromatic ring of the above compound is independently bonded to one or more substituents selected from the group consisting of an optionally substituted hydrocarbon group, an optionally substituted amino group, a carboxy group, a sulfo group, a halogen group, and a silyl group. Furthermore, such derivatives are preferably derivatives containing fluorine atoms.

[0059] Specific examples of the negative electrode coating agent include, for example, 1H-benzotriazole, 5-methyl-1H-benzotriazole, 4-methyl-1H-benzotriazole, 1-benzoyl-1H-benzotriazole, 1-(2-pyridylcarbonyl)benzotriazole, 1-acetyl-1H-benzotriazole, 5-amino-1H-benzotriazole, 2-mercaptobenzothiazole, 6-amino-2-mercaptobenzothiazole, benzimidazole, 2-(2-pyridyl)benzimidazole, benzoxazole, 2-methylbenzoxazole, benzotriazole-5-carboxylic acid, benzotriazole-1-carboxamide, N-(2-propenyl)-1H-benzotriazole-1-carbothioamide, 1-(methoxymethyl)-1H-benzotriazole, 1-(2-thienylsulfonyl)-1H-benzotriazole, 1-(3-pyridinylsulfonyl)-1H-benzotriazole, 5-(trifluoromethyl)-1H-1,2,3-benzotriazole, bis(1-benzotriazolyl)methanethione, benzotriazol-1-ylpyrrolidin-1-ylmethanethione, 1-(1-naphthylcarbonyl)-1H-benzotriazole, 1-(2-methyl-allyl)-1H-benzotriazole, 1-(benzoyloxy)-1H-1,2,3-benzotriazole, N-phenyl-1H-1,2,3-benzotriazole-1-carboxamide, and 2,6-bis[(1H-benzotriazole-1-yl)methyl]-4-methylphenol, etc.

[0060] Among these, 1H-benzotriazole, 5-methyl-1H-benzotriazole, 4-methyl-1H-benzotriazole, 1-benzoyl-1H-benzotriazole, 1-(2-pyridylcarbonyl)benzotriazole, 2-mercaptobenzothiazole, 6-amino-2-mercaptobenzothiazole, benzimidazole, 2-(2-pyridyl)benzimidazole, 2-methylbenzoxazole, 1-(methoxymethyl)-1H-benzotriazole, 1-(1-naphthylcarbonyl)-1H-benzotriazole, 1-(2-methyl-allyl)-1H-benzotriazole, 1-(benzoyloxy)-1H-1,2,3-benzotriazole, and 2,6-bis[(1H-benzotriazole-1-yl)methyl]-4-methylphenol are preferred as the negative electrode coating agent, and 1H-benzotriazole is more preferred.

[0061] The anode coating agent is coated on at least a portion of the surface of the anode 140 facing the positive electrode 120. "Coated" on at least a portion of the surface of the anode with the anode coating agent means that 10% or more of the surface area of the anode is covered with the anode coating agent. The anode 140 is preferably covered with the anode coating agent on an area ratio of 20% or more, 30% or more, 40% or more, or 50% or more, more preferably 70% or more, and even more preferably 80% or more.

[0062] A method for coating the surface of the negative electrode 140 with the negative electrode coating agent will be described later in the method for manufacturing a lithium secondary battery. The above-mentioned negative electrode coating agents may be used alone or in combination of two or more.

[0063] (electrolyte) The electrolyte solution is an ionically conductive solution containing an electrolyte and a solvent, and acts as a conductive path for lithium ions. The electrolyte solution may be impregnated into the separator 130, or may be enclosed in a sealed container together with a laminate of the positive electrode 120, the separator 130, and the negative electrode 140.

[0064] The electrolyte solution of this embodiment contains a lithium salt and a solvent represented by the following formula (1): 1 is an n-valent atomic group containing at least one nitrogen atom and 1 to 30 carbon atoms, and R 2 are each independently a fluorine atom or an alkyl group having a fluorine atom, n is an integer of 1 or more and 5 or less, and each of the n [-SO2R 2 ] group is R 1 is bonded to by an N-S bond. [ka]

[0065] In anode-free lithium secondary batteries containing an electrolyte, it is necessary to suppress an increase in internal resistance due to side reactions in the positive electrode active material, negative electrode, etc., as well as the deterioration of each component. Furthermore, when such lithium secondary batteries are charged and discharged, a solid electrolyte interfacial layer (SEI layer) formed on the surface of the negative electrode, etc., serves to suppress irreversible reduction of lithium ions and gas generation, which are caused by further decomposition of components in the electrolyte within the battery. Therefore, preventing deterioration due to side reactions in the positive electrode active material, negative electrode, etc., and promoting the formation of a high-quality SEI layer are extremely important for improving the performance of anode-free lithium secondary batteries.

[0066] The compound represented by the formula (1) has low reactivity with the positive electrode material and can prevent chain cracking of the positive electrode active material. In addition, the compound represented by the formula (1) has a structure similar to that of [-SO2R 2 ] group, and each [-SO2R 2 ] group is R 1In particular, since the lithium secondary battery of this embodiment is bonded by an N-S bond, an SEI layer containing fluorine (F), sulfur (S), nitrogen (N), etc. is likely to be formed during charging. Such an SEI layer is presumed to suppress deterioration of the electrolyte and / or gas generation in the negative electrode, and further to further improve the reversibility of deposition and dissolution of lithium metal formed on the negative electrode. It is presumed that this makes it possible to suppress deterioration of each component of the lithium secondary battery of this embodiment even when it is repeatedly charged and discharged, resulting in even more excellent cycle characteristics.

[0067] Furthermore, in the lithium secondary battery of this embodiment, as described above, at least a portion of the surface of the negative electrode facing the positive electrode is coated with a negative electrode coating agent, which is presumed to synergistically enhance the energy density and cycle characteristics of the lithium secondary battery with the effects of the electrolyte solution described above, although the reason for this is not limited to this.

[0068] Hereinafter, in this specification, the compound represented by the above formula (1) may also be simply referred to as "a compound of formula (1)". Also, "R 2 are each independently" means that n is 2 or more, i.e., [-SO2R 2 When multiple [-SO2R 2 ] group 2 are independently selected. That is, in the present specification, a plurality of [-SO2R 2 ] group 2 The structures may be the same or different from each other. Furthermore, when n is 2 or more in the compound of formula (1), one nitrogen atom may have one or two [-SO2R 2 ] group may be bonded. The compound of formula (1) is a compound containing 1 to 30 carbon atoms, and at least one carbon atom is substituted with a divalent [-N(SO2R 2 )-] group and monovalent [-N(SO2R 2)2] group, etc., and the substitution is made at one to five carbon atoms.

[0069] In formula (1), R 1 The elements constituting the atomic group are not particularly limited, and may be, for example, H, C, N, O, F, B, S, P, Al, Si, Cl, As, Bi, etc. From the viewpoint of further improving the cycle characteristics of the lithium secondary battery of this embodiment, R 1 The elements constituting the atomic group are preferably selected from the group consisting of H, C, N, O, F, B, S, P, and Si, and more preferably selected from the group consisting of H, C, N, O, and F.

[0070] In formula (1), R 1 [-SO2R 2 Preferably, the nitrogen atom bonded to the [—SO 2 R ] group is bonded to two carbon atoms. 2 It is preferable that the nitrogen atom bonded to the [—SO2R] group does not have an active hydrogen atom. By using a compound of formula (1) having such a structure, 2 The reactivity of the ] group tends to be more favorable, and the lithium secondary battery tends to have more excellent cycle characteristics.

[0071] In formula (1), R 1 The number of carbon atoms in R may be, for example, 1 or more and 15 or less. From the viewpoint of improving the stability of the electrolyte and further improving the cycle characteristics of the battery, 1 The number of carbon atoms is preferably 2 or more and 12 or less, more preferably 3 or more and 10 or less, even more preferably 4 or more and 9 or less, and even more preferably 5 or more and 8 or less.

[0072] The molecular weight of the compound of formula (1) contained in the electrolyte solution of the present embodiment is not particularly limited and is, for example, from 100 to 1000. From the viewpoint of further improving the cycle characteristics of the lithium secondary battery, the molecular weight of the compound of formula (1) is preferably from 120 to 900, more preferably from 160 to 700, and even more preferably from 180 to 500.

[0073] The compound of formula (1) may, in one embodiment, be R 1 contains a chain structure containing at least one nitrogen atom. According to such an embodiment, the cycle characteristics of the battery tend to be even better. In addition, in this specification, the term "chain structure containing at least one nitrogen atom" refers to a structure formed by carbon atom groups each containing at least one nitrogen atom being bonded in a chain shape.

[0074] The compound of formula (1) may, in one embodiment, be R 1 includes a cyclic structure containing at least one nitrogen atom. According to such an embodiment, the cycle characteristics of the battery tend to be even better. In addition, in this specification, the term "cyclic structure containing at least one nitrogen atom" refers to a structure formed by carbon atom groups containing at least one nitrogen atom being bonded in a ring shape.

[0075] In one embodiment, the compound of formula (1) is a compound represented by the following formula (2) or (3): From the viewpoint of further improving the cycle characteristics of the battery, in one embodiment, the compound of formula (1) is preferably a compound represented by the following formula (2): Here, in equation (2), R 3 are each independently an alkyl group having one or more carbon atoms, the hydrogen atom of which may be substituted with a fluorine atom. 3 In formula (3), R preferably has 2 or more carbon atoms. 4 are each independently an alkyl group having one or more carbon atoms, the hydrogen atom of which may be substituted with a fluorine atom, and R 5R is an alkenyl group having one or more carbon atoms, the hydrogen atoms of which may be substituted with fluorine atoms. 3 , R 4 and R 5 The upper limit of the number of carbon atoms in each of R is not particularly limited, and is, for example, 5, 4, or 3. 2 is R in Eq. (1) 2 is synonymous with. [ka] [ka]

[0076] The compound of formula (1) may, in one embodiment, be R 1 contains a cycloalkane structure containing at least one nitrogen atom (a ring structure consisting of at least one nitrogen atom and carbon atoms). According to such an embodiment, the cycle characteristics of the battery tend to be more excellent. From the same viewpoint, the number of carbon atoms in the cycloalkane structure is preferably 3 or more and 8 or less, more preferably 4 or more and 6 or less. In this embodiment, the nitrogen atom and [-SO2R] bonded to the nitrogen atom 2 The number of ] groups is preferably 1 or 2. The number of nitrogen atoms in the cycloalkane structure is preferably 1 or 2.

[0077] The compound of formula (1) may, in one embodiment, be R 1 includes an aromatic ring structure containing at least one nitrogen atom (an aromatic ring structure consisting of at least one nitrogen atom and a carbon atom). According to such an embodiment, the cycle characteristics of the battery tend to be further improved. From the same viewpoint, the number of carbon atoms in the aromatic ring structure is preferably 3 or more and 8 or less, more preferably 4 or more and 6 or less. The aromatic ring structure is, for example, a pyrrole ring. In this embodiment, the nitrogen atom and [-SO2R] bonded to the nitrogen atom 2 The number of ] groups is preferably 1 or 2, and more preferably 1. The number of nitrogen atoms in the aromatic ring structure is, for example, 1 or 2, and preferably 1.

[0078] The compound of formula (1) may, in one embodiment, be R 1 includes both a chain structure containing at least one nitrogen atom and a cyclic structure containing at least one nitrogen atom.

[0079] In formula (1), R 1 R may have a fluorine atom. 1 The number of fluorine atoms in R is not particularly limited, and is, for example, 0 to 15. 1 The number of fluorine atoms in is preferably 0 or more and 12 or less, and more preferably 0 or more and 9 or less. According to such an embodiment, the cycle characteristics of the battery tend to be further improved.

[0080] In formula (1), R 2 The number of carbon atoms in R is not particularly limited, and is, for example, 0 to 10. From the viewpoint of further improving the cycle characteristics of the lithium secondary battery, 2 The number of carbon atoms is preferably 0 or more and 8 or less, more preferably 0 or more and 6 or less, even more preferably 0 or more and 4 or less, still more preferably 0 or more and 2 or less, and particularly preferably 0 or 1.

[0081] In formula (1), R 2 are each preferably independently a fluorine atom or an alkyl group in which the ratio (F / (F+H)) of the number of fluorine atoms (F) to the total number of fluorine atoms and hydrogen atoms (F+H) is 0.70 or more and 1.0 or less. 2 The reactivity of the ] group becomes more favorable, and the cycle characteristics of the battery tend to be more excellent. From the same viewpoint, the ratio (F / (F+H)) is more preferably 0.75 or more and 1.0 or less, and further preferably 0.80 or more and 1.0 or less.

[0082] In formula (1), R 2are each preferably independently a fluorine atom or a trifluoromethyl group. According to such an embodiment, the properties of the formed SEI layer tend to be more favorable, and the cycle characteristics of the battery tend to be further improved.

[0083] In formula (1), n is an integer of 1 or more and 5 or less. From the viewpoint of further improving the cycle characteristics of the lithium secondary battery in this embodiment, n in formula (1) is preferably 1 or more and 4 or less, more preferably 1 or more and 3 or less, and even more preferably 1 or 2.

[0084] The compound of formula (1) in this embodiment is not particularly limited as long as it is a compound represented by formula (1), and examples thereof include those shown in Tables 1 and 2 below. From the viewpoint of further improving the cycle characteristics of the lithium secondary battery, it is preferable to use at least one of the compounds (4) to (25) in Tables 1 and 2 below as the compound of formula (1), and it is more preferable to use at least one of the compounds (4) to (8), (13), and (14). Furthermore, as the compound of formula (1), one type may be used alone, or two or more types may be used in combination.

[0085] [Table 1]

[0086] [Table 2]

[0087] The electrolyte solution of this embodiment preferably further contains at least one of chain fluorine compounds (hereinafter also referred to as "fluorine co-solvents") represented by the following formula (A) or formula (B). When the electrolyte solution further contains a fluorine co-solvent, the cycle characteristics of the lithium secondary battery tend to be further improved due to a synergistic effect with the compound of formula (1). In formula (A), R 6 is an alkyl group which may contain an ether bond, and R 7is a fluorine-substituted alkylene group, and R 8 is an alkyl group which may contain an ether bond. 9 is a fluorine-substituted alkyl group, and R 10 is an alkylene group which may contain an ether bond, and R 11 represents an alkyl group which may be substituted with fluorine. [ka] [ka]

[0088] The number of carbon atoms in the fluorine co-solvent is not particularly limited, but is, for example, 3 to 20. From the viewpoint of further improving the solubility of the electrolyte in the electrolytic solution, the number of carbon atoms in the fluorine co-solvent is preferably 4 to 18, more preferably 5 to 15, and even more preferably 6 to 12.

[0089] The molecular weight of the fluorine co-solvent is not particularly limited and is, for example, from 100 to 500. From the viewpoint of further improving the cycle characteristics of the lithium secondary battery, the molecular weight of the fluorine co-solvent is preferably from 110 to 400, more preferably from 120 to 350, even more preferably from 130 to 300, and still more preferably from 140 to 250.

[0090] In the above formula (A), R 7 In the above, the ratio (F / (F+H)) of the number of fluorine atoms (F) to the total number of fluorine atoms and hydrogen atoms (F+H) is preferably 0.30 or more and 0.80 or less. According to such an embodiment, the cycle characteristics of the battery tend to be further improved. From the same viewpoint, the ratio (F / (F+H)) is preferably 0.40 or more and 0.75 or less, more preferably 0.45 or more and 0.70 or less, and even more preferably 0.50 or more and 0.67 or less.

[0091] In the above formula (A), R7 In the formula (A), it is preferable that at least one of the carbon atoms bonded to the oxygen atoms at both ends does not have a fluorine atom. When the fluorine co-solvent represented by formula (A) has such a structure, the properties of the SEI layer formed become more favorable, and the cycle characteristics of the lithium secondary battery tend to be further improved. From the same viewpoint, R 7 In the formula (I), it is more preferable that neither of the carbon atoms bonded to the oxygen atom has a fluorine atom.

[0092] The fluorine co-solvent is not particularly limited, but examples thereof include the following: Examples of the compound represented by the formula (A) include 2,2,3,3-tetrafluoro-1,4-dimethoxybutane (TFDMB), 2,2,3,3-tetrafluoro-1,4-diethoxybutane, 1,2,2,3-tetrafluoro-1,3-dimethoxypropane, 1,1,2,2-tetrafluoro-1,2-dimethoxyethane, 2-methyl-2,3,3-trifluoro-1,4-dimethoxybutane, 2-methyl-2,3,3-trifluoro-1,4-methoxyethoxybutane, 2,3-methyl-2,3-difluoro-1,4-dimethoxybutane, 2,3-methyl-2,3-difluoro-1,4-methoxyethoxybutane, 2,2,3,3-tetrafluoromethoxyisopropionyloxybutane, and 2,2,3,3-tetrafluorodiisopropionyloxybutane. Examples of the compound represented by the above formula (B) include 2,2,3,3-tetrafluoropropyl-2(2-methoxyethoxy)ethyl ether, 1,2-bis(1,1,2,2-tetrafluoroethoxy)ethane, and 2,2,3,3-tetrafluoropropyl-2-methoxyethyl ether. From the viewpoint of improving the cycle characteristics of a lithium secondary battery, the fluorine co-solvent is preferably 2,2,3,3-tetrafluoro-1,4-dimethoxybutane (TFDMB).

[0093] The electrolytic solution of the present embodiment may also contain a compound containing a fluorine atom (hereinafter also referred to as a "third fluorine compound") other than the compound of formula (1) and the fluorine co-solvent. That is, the electrolytic solution of the present embodiment may contain a fluorine compound that does not have the structure represented by formula (1), formula (A), or formula (B).

[0094] The content of the compound of formula (1) in the electrolyte solution is not particularly limited. The compound of formula (1) may account for the entire solvent component of the electrolyte, i.e., 100% by volume of the total amount of the solvent component of the electrolyte. When the entire solvent is the compound of formula (1), phase separation of the electrolyte is less likely to occur even when the lithium secondary battery is repeatedly charged and discharged, and cycle stability tends to be further improved. The content of the compound of formula (1) is preferably, for example, 10% by volume or more, 20% by volume or more, 50% by volume or more, 70% by volume or more, 80% by volume or more, or 90% by volume or more relative to the total amount of the solvent components of the electrolyte solution. The content of the compound of formula (1) is preferably 100% by volume, 99% by volume or less, or 95% by volume or less. By keeping the content of the compound of formula (1) within the above range, the cycle characteristics of the lithium secondary battery tend to be further improved.

[0095] The content of the fluorine co-solvent in the electrolyte is not particularly limited, but is, for example, 0.0% by volume or more and 95% by volume or less, or 1.0% by volume or more and 90% by volume or less, relative to the total amount of the solvent components of the electrolyte. The content of the fluorine co-solvent is preferably 3.0% by volume or more, 5.0% by volume or more, 8.0% by volume or more, or 10% by volume or more. The content of the fluorine co-solvent is also preferably 90% by volume or less, 80% by volume or less, 60% by volume or less, 50% by volume or less, 40% by volume or less, or 30% by volume or less. When the content of the fluorine co-solvent is within the above range, the cycle characteristics of the lithium secondary battery tend to be further improved.

[0096] The total content of the fluorine atom-containing solvents in the electrolyte is not particularly limited, but is, for example, 10% by volume or more and 100% by volume or less relative to the total amount of the solvent components in the electrolyte. The total content of the fluorine atom-containing compounds is preferably 20% by volume or more, 30% by volume or more, 40% by volume or more, 50% by volume or more, or 60% by volume or more. When the total content of the fluorine atom-containing compounds is within the above range, the cycle characteristics of the lithium secondary battery tend to be further improved. In addition, the total content of the fluorine atom-containing compounds may be 95% by volume or less, 90% by volume or less, or 85% by volume or less.

[0097] The electrolyte solution of this embodiment preferably further contains an ether compound having no fluorine atoms (hereinafter also referred to as a "non-fluorine ether compound") or a carbonyl compound having no fluorine atoms (hereinafter also referred to as a "non-fluorine carbonyl compound"). According to such an embodiment, the solubility of the electrolyte is improved, and the synergistic effect with the compound of formula (1) further improves the cycle characteristics of the battery. From the same viewpoint, it is more preferable that the electrolyte solution contains an ether compound having no fluorine atoms.

[0098] The number of carbon atoms in the non-fluorinated ether compound is not particularly limited and is, for example, 2 or more and 20 or less. From the viewpoint of further improving the solubility of the electrolyte in the electrolytic solution, the number of carbon atoms in the non-fluorinated ether compound is preferably 3 or more, 4 or more, 5 or more, or 6 or more. From the same viewpoint, the number of carbon atoms in the non-fluorinated ether compound is preferably 15 or less, 12 or less, 10 or less, or 9 or less.

[0099] The number of ether bonds in the non-fluorine ether compound is not particularly limited and is, for example, 1 or more and 10 or less. From the viewpoint of further improving the solubility of the electrolyte in the electrolytic solution, the number of ether bonds in the non-fluorine ether compound is preferably 2 or more, or 3 or more. Furthermore, the number of ether bonds in the non-fluorine ether compound is preferably 8 or less, or 5 or less.

[0100] The non-fluorinated ether compound may be a saturated ether compound or an unsaturated ether compound. From the viewpoint of further improving the cycle characteristics of the lithium secondary battery, the electrolyte preferably contains a saturated non-fluorinated ether compound.

[0101] The non-fluorine-containing ether compound is not particularly limited as long as it is an ether compound that does not have a fluorine atom, and examples thereof include 1,2-dimethoxyethane (DME), 1,2-dimethoxypropane (DMP), diethylene glycol dimethyl ether (DGM), triethylene glycol dimethyl ether (TGM), tetraethylene glycol dimethyl ether (TetGM), 1,3-dimethoxypropane, 1,4-dimethoxybutane, 1,1-dimethoxyethane, 2,2-dimethoxypropane, 1,3-dimethoxybutane, 1,2-dimethoxybutane, 2,2-dimethoxybutane, 2,3-dimethoxybutane, 1,2-diethoxypropane, 1,2-diethoxybutane, 2,3-diethoxybutane, and diethoxyethane. From the viewpoint of further improving the solubility of the electrolyte in the electrolytic solution, the non-fluorinated ether compound is preferably selected from 1,2-dimethoxyethane (DME), 1,2-dimethoxypropane (DMP), diethylene glycol dimethyl ether (DGM), and triethylene glycol dimethyl ether (TGM).

[0102] The number of carbon atoms in the non-fluorine carbonyl compound is not particularly limited and is, for example, 2 or more and 20 or less. From the viewpoint of further improving the solubility of the electrolyte in the electrolytic solution, the number of carbon atoms in the non-fluorine carbonyl compound is preferably 3 or more, 4 or more, 5 or more, or 6 or more. From the same viewpoint, the number of carbon atoms in the non-fluorine carbonyl compound is preferably 15 or less, 12 or less, 10 or less, 9 or less, or 7 or less.

[0103] The non-fluorine carbonyl compound is not particularly limited as long as it is a carbonyl compound that does not have a fluorine atom, and examples thereof include those having a group such as a carbonate group, a ketone group, or an ester group. From the viewpoint of further improving the cycle characteristics of the battery in this embodiment, the non-fluorine carbonyl compound is preferably one having a carbonate group and / or an ester group. Examples of such compounds include diethyl carbonate, ethyl methyl carbonate, dimethyl carbonate, ethylene carbonate, propylene carbonate, chloroethylene carbonate, methyl acetate, ethyl acetate, propyl acetate, methyl propionate, and ethyl propionate.

[0104] The total content of the non-fluorine ether compound and the non-fluorine carbonyl compound in the electrolytic solution of this embodiment is not particularly limited, and is, for example, 0.0% by volume or more and 90% by volume or less, relative to the total amount of the solvent components of the electrolytic solution. From the viewpoint of further improving the cycle characteristics of the battery, the total content of the non-fluorine ether compound and the non-fluorine carbonyl compound is preferably 80% by volume or less, more preferably 70% by volume or less, even more preferably 60% by volume or less, and even more preferably 40% by volume or less, or even more preferably 20% by volume or less, relative to the total amount of the solvent components of the electrolytic solution. The total content of the non-fluorine ether compound and the non-fluorine carbonyl compound may be 5.0% by volume or more, or may be 10% by volume or more, relative to the total amount of the solvent components of the electrolytic solution.

[0105] The content of the non-fluorinated ether compound in the electrolyte solution of this embodiment is not particularly limited and is, for example, 0.0 vol% or more and 90 vol% or less relative to the total amount of the solvent components of the electrolyte solution. From the viewpoint of further improving the solubility of the electrolyte in the electrolyte solution, the content of the non-fluorinated ether compound is preferably 3.0 vol% or more, more preferably 5.0 vol% or more, and even more preferably 10 vol% or more relative to the total amount of the solvent components of the electrolyte solution. Furthermore, from the viewpoint of further improving the cycle characteristics of the battery, the content of the non-fluorinated ether compound is preferably 80 vol% or less, more preferably 50 vol% or less, even more preferably 40 vol% or less, and even more preferably 30 vol% or less, or even more preferably 20 vol% or less relative to the total amount of the solvent components of the electrolyte solution.

[0106] The content of the non-fluorine carbonyl compound in the electrolytic solution of this embodiment is not particularly limited, and is, for example, 0.0% by volume or more and 90% by volume or less relative to the total amount of the solvent components of the electrolytic solution. The content of the non-fluorine carbonyl compound may also be 5.0% by volume or more, or 10% by volume or more relative to the total amount of the solvent components of the electrolytic solution. Furthermore, the content of the non-fluorine carbonyl compound may also be 40% by volume or less, 30% by volume or less, or 20% by volume or less relative to the total amount of the solvent components of the electrolytic solution.

[0107] The electrolytic solution may contain at least one compound of the formula (1) as a solvent, and may further contain other compounds of the formula (1), the fluorine co-solvent, the third fluorine compound, the non-fluorine ether compound, the non-fluorine carbonyl compound, etc. Each solvent may be used alone or in combination of two or more.

[0108] The lithium salt contained in the electrolyte solution is not particularly limited, and examples thereof include inorganic and organic salts of lithium, such as LiI, LiCl, LiBr, LiF, LiBF, LiPF, LiPFO, LiPF(C0), LiPF(C0), LiAsF, LiSOCF, LiN(SOF), LiN(SOCF), LiN(SOCFCF), LiBF(C0), LiB(C0), LiB(C0), LiB(OC0), LiB(OC0), LiB(OCH), LiB(OCH)F, LiB(OCOCF), LiNO, and LiSO. From the viewpoint of further improving the energy density and cycle characteristics of the lithium secondary battery 100, it is preferable that the lithium salt contains at least LiN(SO2F)2 or LiN(SO2CF3)2, and it is more preferable that the lithium salt contains at least LiN(SO2F)2. The above lithium salts may be used alone or in combination of two or more. The electrolytic solution may further contain a salt other than a lithium salt as an electrolyte, such as salts of Na, K, Ca, and Mg.

[0109] The total concentration of lithium salts in the electrolyte is not particularly limited, but is preferably 0.30M or more, more preferably 0.40M or more, even more preferably 0.50M or more, and even more preferably 0.80M or more. When the lithium salt concentration is within the above range, the SEI layer tends to be formed more easily and the internal resistance tends to be lower. In particular, a lithium secondary battery 100 containing a fluorine compound as a solvent can have a high concentration of lithium salt in the electrolyte, thereby further improving cycle characteristics and rate performance. The upper limit of the lithium salt concentration is not particularly limited, and the lithium salt concentration may be 10.0M or less, 5.0M or less, or 2.0M or less.

[0110] The lithium secondary battery of this embodiment may contain an electrolytic solution or components of an electrolytic solution in a state other than a liquid. For example, by adding an electrolytic solution when preparing a separator, which will be described later, a battery containing the electrolytic solution in a solid or semi-solid (gel) material can be obtained. The electrolytic solution can also be referred to as an electrolyte.

[0111] The presence of the compound of formula (1) and the fluorine co-solvent in the electrolyte can be confirmed by estimating the molecular structure through measurement or analysis using known methods. Examples of such methods include NMR, mass spectrometry, elemental analysis, and infrared spectroscopy. The molecular structure of the solvent can also be estimated through theoretical calculations using molecular dynamics, molecular orbital theory, and the like.

[0112] (separator) The separator 130 is a component that prevents the battery from short-circuiting by isolating the positive electrode 120 and the negative electrode 140, while ensuring ionic conductivity of lithium ions, which serve as charge carriers between the positive electrode 120 and the negative electrode 140. That is, the separator 130 has the function of physically and / or electrically isolating the positive electrode 120 and the negative electrode 140, and the function of ensuring ionic conductivity of lithium ions. Therefore, the separator 130 is not electronically conductive and is made of a material that does not react with lithium ions. The separator 130 may also serve to retain the electrolyte. As such a separator, one kind of member having the above two functions may be used alone, or two or more kinds of members having one of the above functions may be used in combination. The separator is not particularly limited as long as it has the above function, but examples thereof include insulating porous members, polymer electrolytes, gel electrolytes, and inorganic solid electrolytes, and is typically at least one member selected from the group consisting of insulating porous members, polymer electrolytes, and gel electrolytes.

[0113] When the separator includes an insulating porous member, the pores of the member are filled with an ion-conductive substance, such as the above-mentioned electrolytic solution, polymer electrolyte, or gel electrolyte, to thereby provide the member with ion conductivity. An insulating porous material, a polymer electrolyte, or a gel electrolyte can be used singly or in combination as the separator 130. When an insulating porous material is used alone as the separator, the lithium secondary battery must further include an electrolyte solution.

[0114] The material constituting the insulating porous member is not particularly limited, but examples thereof include insulating polymer materials, specifically polyethylene (PE) and polypropylene (PP). That is, the separator 130 may be a porous polyethylene (PE) film, a porous polypropylene (PP) film, or a laminated structure thereof.

[0115] The separator 130 may be coated with a separator coating layer. The separator coating layer may coat both sides of the separator 130, or only one side. From the viewpoint of further improving the cycle characteristics of the lithium secondary battery of this embodiment, it is preferable to coat both sides of the separator. Note that the separator coating layer of this embodiment is a uniformly continuous film-like coating layer. More specifically, it is a uniformly continuous film-like coating layer over an area of 50% or more, 60% or more, 70% or more, 80% or more, 90% or more, or 100% of the surface of the separator.

[0116] The separator coating layer is preferably a layer that does not react with lithium ions and that can firmly bond the separator and the layer adjacent to the separator. By using such a coating layer, side reactions other than the deposition and electrolytic elution of lithium ions near the electrodes are suppressed, which tends to further improve the cycle characteristics of the battery. The separator coating layer preferably contains a binder. Similarly, from the viewpoint of improving adhesion between the separator and a layer adjacent to the separator, the binder is preferably at least one selected from the group consisting of polyvinylidene fluoride (PVDF), ethylene-vinyl acetate copolymer (EVA), fluorine-containing rubber, styrene-butadiene rubber (SBR), a mixture of styrene-butadiene rubber and carboxymethyl cellulose (SBR-CMC), polyacrylic acid (PAA), lithium polyacrylate (Li-PAA), polyimide (PI), polyamide-imide (PAI), and aramid, with polyvinylidene fluoride (PVDF) being more preferred. In a preferred embodiment, the separator coating layer contains a polymer having fluorine atoms. Furthermore, the separator coating layer may contain inorganic particles such as silica, alumina, titania, zirconia, yttria, ceria, magnesium oxide, zinc oxide, iron oxide, boehmite, zeolite, aluminum nitride, silicon nitride, titanium nitride, boron nitride, calcium fluoride, barium fluoride, barium sulfate, calcium carbonate, magnesium hydroxide, aluminum hydroxide, aluminum hydroxide oxide, lithium nitrate, potassium titanate, calcium silicate, magnesium silicate, etc. The inorganic particles may be used alone or in combination of two or more.

[0117] The average thickness of the separator 130, including the separator coating layer, is not particularly limited and is, for example, 3.0 μm to 50 μm. The average thickness of the separator, including the separator coating layer, is preferably 5.0 μm to 30 μm, more preferably 7.0 μm to 25 μm, and even more preferably 10 μm to 20 μm. By having the average thickness within the above range, the volume occupied by the separator can be adjusted while reliably isolating the positive electrode and the negative electrode, which tends to further improve the energy density and cycle characteristics of the battery.

[0118] (positive electrode) The positive electrode 120 is not particularly limited as long as it is a material generally used in lithium secondary batteries, and known materials can be appropriately selected depending on the application of the lithium secondary battery. From the viewpoint of improving the stability and output voltage of the battery, the positive electrode 120 preferably contains a positive electrode active material. When the positive electrode has a positive electrode active material, lithium ions are typically charged into and desorbed from the positive electrode active material by charging and discharging the battery.

[0119] In this specification, the term "positive electrode active material" refers to a material that causes an electrode reaction, i.e., an oxidation reaction and a reduction reaction, at the positive electrode. Specifically, the positive electrode active material may be a host material for lithium element (typically, lithium ion).

[0120] Such positive electrode active materials are not particularly limited, but include, for example, metal oxides and metal phosphates. Examples of the metal oxides include, but are not particularly limited, cobalt oxide-based compounds, manganese oxide-based compounds, and nickel oxide-based compounds. Examples of the metal phosphates include, but are not particularly limited, iron phosphate-based compounds and cobalt phosphate-based compounds. Typical positive electrode active materials include LiCoO2, LiNi x Co y Mn z O(x+y+z=1), LiNi x Co y Al z O(x+y+z=1), LiNi x Mn y O(x+y=1), LiNiO2, LiMn2O4, LiFePO4, LiCoPO4, LiFeOF, LiNiOF, and LiTiS2. From the viewpoint of further improving the effect of the electrolyte solution of this embodiment, nickel oxide-based compounds are preferred as the positive electrode active material, and LiNi x Co y Mn z O(x+y+z=1), LiNi x Co y Al z O(x+y+z=1), LiNi x Mn yAt least one of O(x+y=1), LiMSiOF (M=Fe, Ni, Co, Mn), and LiNiO is more preferred, and LiNi x Co y Al z More preferably, O(x+y+z=1). The above positive electrode active materials may be used singly or in combination of two or more.

[0121] The positive electrode 120 may contain components other than the above-mentioned positive electrode active material. Such components are not particularly limited, but include, for example, a sacrificial positive electrode agent, a conductive additive, a binder, a gel electrolyte, and a polymer electrolyte.

[0122] In this embodiment, the sacrificial positive electrode agent is a lithium-containing compound that undergoes an oxidation reaction and does not substantially undergo a reduction reaction within the charge / discharge potential range of the positive electrode active material. When the positive electrode contains a sacrificial positive electrode agent, some lithium metal derived from the sacrificial positive electrode agent remains on the negative electrode during initial charging of the lithium secondary battery. During subsequent charging, the remaining lithium metal serves as a scaffold for lithium metal deposition on the negative electrode, facilitating uniform deposition of lithium metal and tending to suppress the growth of dendritic lithium metal. Therefore, it is preferable that the lithium secondary battery of this embodiment contains a sacrificial positive electrode agent in the positive electrode, which tends to further improve the cycle characteristics of the battery. Furthermore, one type of sacrificial positive electrode agent may be used alone, or two or more types may be used in combination. The phrase "oxidation reaction occurs and reduction reaction does not substantially occur" means that the reaction of releasing lithium ions proceeds and the lithium-containing compound before discharge is not formed. That is, the sacrificial positive electrode agent undergoes an oxidation reaction in the charge / discharge potential range and does not substantially undergo a reduction reaction, so that at least a portion of the lithium element derived from the sacrificial positive electrode agent remains as lithium metal on the surface of the negative electrode.

[0123] The compound used as the sacrificial positive electrode agent is not particularly limited, and examples thereof include lithium oxides such as Li2O2; lithium nitrides such as Li3N; and Li6Mn x Co 1-xLithium sulfide-based solid solutions such as O4(0 < x < 1), Li2S-P2S5, Li2S-LiCl, Li2S-LiBr, and Li2S-LiI; Li 1+x (Ti 1-y Fe y ) 1-x O2(0 < x ≤ 0.25, 0.4 < y ≤ 0.9), Li 2-x Ti 1-z Fe z O 3-y (0 ≤ x < 2, 0 ≤ y ≤ 1, 0.05 ≤ z ≤ 0.95), iron-based lithium oxides such as Li5FeO4, etc. can be mentioned. From the viewpoint of more effectively and surely exerting the effect of the sacrificial cathode agent, as the sacrificial cathode agent, a lithium-containing compound containing Mn or Co is preferable, and Li6Mn x Co 1-x O4(0 < x < 1) is more preferable. Also, when using Li6Mn x Co 1-x O4(0 < x < 1) as the sacrificial cathode agent, the value of x is preferably 0.1 or more and 0.9 or less, and more preferably 0.3 or more and 0.7 or less, from the viewpoint of further improving the cycle characteristics of the lithium secondary battery.

[0124] The positive electrode 120 may contain a gel electrolyte or may be a gel electrolyte. According to such an aspect, the adhesion force between the positive electrode and the positive electrode current collector is improved by the function of the gel electrolyte, and it becomes possible to attach a thinner positive electrode current collector, making the energy density of the battery more excellent. When attaching the positive electrode current collector to the surface of the positive electrode, the positive electrode current collector formed on the release paper may be used.

[0125] The conductive assistant in the positive electrode 120 is not particularly limited, and examples include carbon black, single-walled carbon nanotube (SWCNT), multi-walled carbon nanotube (MWCNT), carbon nanofiber (CF), and acetylene black. Also, the binder is not particularly limited, and examples include polyvinylidene fluoride, polytetrafluoroethylene, styrene-butadiene rubber, acrylic resin, and polyimide resin.

[0126] The content of the positive electrode active material in the positive electrode 120 may be, for example, 50% by mass or more and 100% by mass or less, based on the entire positive electrode 120. From the viewpoint of further improving the cycle characteristics of the lithium secondary battery of this embodiment, the content of the positive electrode active material is preferably 60% by mass or more, more preferably 80% by mass or more, and even more preferably 90% by mass or more. The content of the sacrificial positive electrode agent may be, for example, 0.5% by mass or more and 40% by mass or less, based on the entire positive electrode 120. From the viewpoint of further improving the cycle characteristics of the lithium secondary battery, the content of the sacrificial positive electrode agent is preferably 1.0% by mass or more and 30% by mass or less, more preferably 2.0% by mass or more and 20% by mass or less, and even more preferably 3.0% by mass or more and 15% by mass or less. The content of the conductive additive may be, for example, 0.50% by mass or more and 30% by mass or less, based on the entire positive electrode 120. The content of the binder may be, for example, 0.50% by mass or more and 30% by mass or less, based on the entire positive electrode 120. The content of the gel electrolyte or polymer electrolyte may be, for example, 0.50% by mass or more and 30% by mass or less, based on the entire positive electrode 120, preferably 5.0% by mass or more and 20% by mass or less, and more preferably 8.0% by mass or more and 15% by mass or less.

[0127] The contents of the positive electrode active material and the sacrificial positive electrode agent in the positive electrode 120 can be measured by a conventionally known method, for example, by X-ray diffraction measurement (XRD).

[0128] The average thickness of the positive electrode 120 is preferably 20 μm or more and 100 μm or less, more preferably 30 μm or more and 80 μm or less, and even more preferably 40 μm or more and 70 μm or less, although the average thickness of the positive electrode can be adjusted appropriately depending on the desired battery capacity.

[0129] (Positive electrode current collector) A positive electrode current collector 110 is disposed on one side of the positive electrode 120. The positive electrode current collector is not particularly limited as long as it is a conductor that does not react with lithium ions in the battery. An example of such a positive electrode current collector is aluminum. The positive electrode current collector 110 may not be provided, in which case the positive electrode itself functions as a current collector. The positive electrode current collector functions to donate and receive electrons to the positive electrode (particularly the positive electrode active material). The positive electrode current collector 110 is in physical and / or electrical contact with the positive electrode 120.

[0130] In this embodiment, the average thickness of the positive electrode current collector is preferably 1.0 μm or more and 15 μm or less, more preferably 2.0 μm or more and 10 μm or less, and even more preferably 3.0 μm or more and 6.0 μm or less. According to such an embodiment, the volume occupied by the positive electrode current collector in the lithium secondary battery 100 is reduced, and therefore the energy density of the lithium secondary battery 100 is further improved.

[0131] (Use of lithium secondary batteries) 2 shows one usage mode of the lithium secondary battery of this embodiment. In the lithium secondary battery 200, a positive electrode terminal 210 and a negative electrode terminal 220 for connecting the lithium secondary battery 200 to an external circuit are joined to a positive electrode current collector 110 and a negative electrode 140, respectively. The lithium secondary battery 200 is charged and discharged by connecting the negative electrode terminal 220 to one end of the external circuit and the positive electrode terminal 210 to the other end of the external circuit.

[0132] The lithium secondary battery 200 is charged by applying a voltage between the positive electrode terminal 210 and the negative electrode terminal 220 such that a current flows from the negative electrode terminal 220 (negative electrode 140) through an external circuit to the positive electrode terminal 210 (positive electrode 120). The lithium secondary battery 200 may have a solid electrolyte interface layer (SEI layer) formed on the surface of the negative electrode 140 (the interface between the negative electrode 140 and the separator 130) coated with the negative electrode coating agent by the first charge (initial charge) after assembly of the battery. The SEI layer to be formed is not particularly limited, and may include, for example, an inorganic compound containing lithium, an organic compound containing lithium, or the like. The SEI layer typically has an average thickness of 1.0 nm or more and 10 μm or less.

[0133] When the positive electrode terminal 210 and the negative electrode terminal 220 of the charged lithium secondary battery 200 are connected, the lithium secondary battery 200 is discharged. As a result, the lithium metal deposited on the negative electrode is electrolytically dissolved.

[0134] (Lithium secondary battery manufacturing method) The method for manufacturing the lithium secondary battery 100 as shown in FIG. 1 is not particularly limited as long as it is a method that can manufacture a lithium secondary battery having the above-described configuration, and examples thereof include the following methods.

[0135] The positive electrode current collector 110 and the positive electrode 120 are manufactured, for example, as follows. The above-described positive electrode active material, conductive additive, and binder are mixed to obtain a positive electrode mixture. The compounding ratios may be, for example, 50% by mass to 99% by mass of the positive electrode active material, 0.5% by mass to 30% by mass of the conductive additive, and 0.5% by mass to 30% by mass of the binder, relative to the total positive electrode mixture. The obtained positive electrode mixture is applied to one side of a metal foil (e.g., Al foil) having a predetermined thickness (e.g., 5.0 μm to 1.0 mm) as a positive electrode current collector, and press-molded. The obtained molded body is punched to a predetermined size by a punching process to obtain the positive electrode current collector 110 and the positive electrode 120.

[0136] Next, a negative electrode 140 is manufactured in which at least a portion of one or both sides is coated with the negative electrode coating agent. First, the above-mentioned negative electrode material, for example, a metal foil (e.g., electrolytic Cu foil) having a thickness of 1.0 μm to 1.0 mm, is washed with a solvent containing sulfamic acid. Next, the negative electrode material is washed with water, and then immersed in a solution containing the above-mentioned negative electrode coating agent (e.g., a solution containing 0.010 vol % to 10 vol % of the negative electrode coating agent), and further dried in the atmosphere to coat the negative electrode coating agent. At this time, one side of the negative electrode material may be masked so that the negative electrode coating agent is coated on only one side. The negative electrode material coated with the negative electrode coating agent in this manner is punched to a predetermined size to obtain the negative electrode 140.

[0137] In the manufacturing process of the anode 140, the order of coating the anode coating agent and punching the anode material may be reversed. That is, the anode 140 may be manufactured by punching a cleaned anode material to a predetermined size and then coating the anode coating agent on its surface using the method described above. However, a manufacturing method of an anode in which the anode material is punched after coating with the anode coating agent is preferred because it allows the anode material coated with the anode coating agent to be easily manufactured using a roll-to-roll method.

[0138] Next, the separator 130 having the above-described configuration is prepared. The separator 130 may be manufactured by a conventionally known method, or a commercially available product may be used. The separator coating layer may be formed, for example, by applying a mixture containing the binder and inorganic particles of the separator coating layer to one or both surfaces of the separator member.

[0139] Next, an electrolyte solution is prepared by dissolving a lithium salt in a solution obtained by mixing at least one compound of formula (1) and, if necessary, other compounds. The mixing ratio of the solvent and the lithium salt may be appropriately adjusted so that the content or concentration of each solvent and lithium salt in the electrolyte solution falls within the above-mentioned ranges.

[0140] Next, the positive electrode current collector 110 on which the positive electrode 120 is formed, the separator 130, and the negative electrode 140 coated with the negative electrode coating agent obtained as described above are stacked in this order to obtain a laminate as shown in FIG. 1. If only one side of the negative electrode 140 is coated with the negative electrode coating agent, the negative electrode 140 is stacked so that this surface faces the positive electrode 120 (and the separator 130). The laminate obtained as described above is enclosed in a sealed container together with an electrolyte solution to obtain a lithium secondary battery 100. The sealed container is not particularly limited, but examples thereof include laminate films.

[0141] [Variations] The above-described embodiment is an example for explaining the present invention, and is not intended to limit the present invention to only this embodiment. The present invention can be modified in various ways without departing from the gist of the invention.

[0142] For example, the separator 130 may be omitted from the lithium secondary battery 100. In that case, it is preferable to fix the positive electrode 120 and the negative electrode 140 in a state where they are sufficiently separated so that they do not come into physical or electrical contact with each other.

[0143] The lithium secondary battery of this embodiment may also have a current collector disposed on the surface of the negative electrode so as to be in contact with the negative electrode. Such a current collector is not particularly limited, but examples thereof include those that can be used as negative electrode materials. When the lithium secondary battery does not have a positive electrode current collector or a negative electrode current collector, the positive electrode or the negative electrode itself functions as a current collector, respectively.

[0144] In the lithium secondary battery of this embodiment, terminals for connecting to an external circuit may be attached to the positive electrode current collector and / or the negative electrode. For example, metal terminals (e.g., Al, Ni, etc.) having a thickness of 10 μm to 1.0 mm may be bonded to one or both of the positive electrode current collector and the negative electrode. A conventionally known method may be used as the bonding method, and ultrasonic welding may be used, for example.

[0145] In this specification, "high energy density" or "having a high energy density" means that the capacity per total volume or mass of the battery is high, and is preferably 700 Wh / L or more or 300 Wh / kg or more, more preferably 800 Wh / L or more or 350 Wh / kg or more, and even more preferably 900 Wh / L or more or 400 Wh / kg or more.

[0146] In addition, in this specification, "excellent cycle characteristics" means that the rate of decrease in battery capacity is low before and after a number of charge-discharge cycles that can be expected in normal use. That is, when comparing the first discharge capacity after initial charge-discharge with the capacity after a number of charge-discharge cycles that can be expected in normal use, the capacity after charge-discharge cycles is almost no decrease compared to the first discharge capacity after initial charge-discharge. Here, "the number of cycles that can be expected in normal use" refers to, for example, 30, 50, 70, 100, 300, or 500 cycles, depending on the application of the lithium secondary battery. Furthermore, "the capacity after charge-discharge cycles is almost no decrease compared to the first discharge capacity after initial charge-discharge" refers to, for example, 60% or more, 65% or more, 70% or more, 75% or more, 80% or more, or 85% or more of the first discharge capacity after initial charge-discharge, depending on the application of the lithium secondary battery.

[0147] In this specification, numerical ranges described as preferred ranges, etc. may be replaced with numerical ranges obtained by arbitrarily combining the described upper and lower limits. For example, if a certain parameter is preferably 50 or more, more preferably 60 or more, and preferably 100 or less, more preferably 90 or less, the parameter may be any of 50 or more and 100 or less, 50 or more and 90 or less, 60 or more and 100 or less, or 60 or more and 90 or less. [Example]

[0148] The present invention will be explained in more detail below using examples and comparative examples, but the present invention is not limited to the following test examples.

[0149] [Example 1] The lithium secondary battery of Example 1 was fabricated as follows.

[0150] (Preparing the negative electrode) First, an 8.0 μm thick electrolytic Cu foil was washed with a solvent containing sulfamic acid and then rinsed with water. The electrolytic Cu foil was then immersed in a solution containing 1H-benzotriazole as an anode coating agent, dried, and then rinsed with water to obtain a Cu foil coated with the anode coating agent. The resulting Cu foil was punched to a specified size (45 mm × 45 mm) to obtain an anode.

[0151] (Preparation of positive electrode) Next, a positive electrode was fabricated. LiNi was used as the positive electrode active material. 0.85 Co 0.12 Al 0.03 A mixture of 96 parts by mass of O2, 2.0 parts by mass of carbon black as a conductive additive, and 2.0 parts by mass of polyvinylidene fluoride (PVDF) as a binder was applied to one side of a 12 μm Al foil and press-molded. The resulting molded body was punched out to a specified size (40 mm × 40 mm) to obtain a positive electrode with a positive electrode current collector on one side.

[0152] (Preparing the separator) A separator of a predetermined size (50 mm x 50 mm) was prepared, in which both sides of a 12 μm polyethylene microporous film were coated with a 2.0 μm polyvinylidene fluoride (PVDF) film.

[0153] (Preparation of Electrolyte) The electrolyte solution was prepared as follows: Only the compound corresponding to chemical formula (4) in Table 1 was used, and the electrolyte solution was obtained by dissolving LiN(SO2F2)2 so that the molar concentration was 0.80M.

[0154] (Battery assembly) The positive electrode current collector with the positive electrode formed thereon, the separator, and the negative electrode were stacked in this order, with the positive electrode facing the separator, to obtain a laminate. Furthermore, a 100 μm Al terminal and a 100 μm Ni terminal were joined to the positive electrode current collector and the negative electrode, respectively, by ultrasonic welding, and then inserted into a laminate outer casing. The electrolyte solution obtained as described above was then poured into the outer casing. The outer casing was sealed to obtain a lithium secondary battery.

[0155] [Examples 2 to 46] A lithium secondary battery was obtained in the same manner as in Example 1, except that the electrolyte solution was prepared using the electrolyte, electrolyte concentration, and solvent composition shown in Tables 3 to 5. In Tables 3 to 5, (4) to (8), (13), and (14) representing compounds of formula (1) refer to the compounds (4) to (8), (13), and (14) shown in Tables 1 and 2.

[0156] [Comparative Examples 1 and 2] Lithium secondary batteries were obtained in the same manner as in Example 1, except that the electrolyte solution was prepared using the electrolyte concentration and solvent composition shown in Table 5. That is, the batteries of Comparative Examples 1 and 2 were produced using an electrolyte solution that did not contain the solvent represented by formula (1).

[0157] Comparative Example 3 An 8.0 μm thick electrolytic Cu foil was washed with a solvent containing sulfamic acid, then washed with water, and punched out to a predetermined size (45 mm × 45 mm) to obtain a negative electrode for Comparative Example 3. That is, in Comparative Example 3, a lithium secondary battery was obtained in the same manner as in Example 1, except that the composition of the electrolyte solution shown in Table 6 was used and furthermore, no negative electrode coating agent was used.

[0158] In Tables 3 to 6, compounds having the structures shown in Tables 1 and 2 were used as the compounds represented by formula (1). In addition, in Tables 3 to 6, "DME" represents 1,2-dimethoxyethane, "DMP" represents 1,2-dimethoxypropane, "DGM" represents diethylene glycol dimethyl ether, "TGM" represents triethylene glycol dimethyl ether, and "TFDMB" represents 2,2,3,3-tetrafluoro-1,4-dimethoxybutane. In addition, "LiFSI" represents LiN(SO2F)2 as a lithium salt.

[0159] In Tables 3 to 6, each solvent is classified as either a compound represented by the structural formula (1) or a co-solvent, and the content (volume %) relative to the total amount of solvent is listed along with the type. The concentration of each lithium salt is listed in terms of volume molar concentration (M (mol / L)) along with the type. For example, Example 1 means that the solvent contains 100 volume % of the compound represented by the structural formula (4), and the electrolyte contains 0.80 M LiFSI.

[0160] [Evaluation of cycle characteristics] The cycle characteristics of the lithium secondary batteries prepared in each of the Examples and Comparative Examples were evaluated as follows.

[0161] The fabricated lithium secondary batteries were CC charged at 3.2 mA until the voltage reached 4.2 V (initial charge), and then CC discharged at 3.2 mA until the voltage reached 3.0 V (hereinafter referred to as "initial discharge"). The batteries were then CC charged at 13.6 mA until the voltage reached 4.2 V, and then CC discharged at 13.6 mA until the voltage reached 3.0 V. This cycle was repeated in an environment at a temperature of 25°C. For each example, the capacity determined from the initial discharge (hereinafter referred to as "initial capacity" and referred to as "capacity (mAh)" in the tables) is shown in Tables 3 to 6. For each example, the number of cycles at which the discharge capacity reached 80% of the initial capacity (referred to as "cycles" in the tables) is also shown in Tables 3 to 6.

[0162] [Table 3]

[0163] [Table 4]

[0164] [Table 5]

[0165] [Table 6]

[0166] In Tables 3 to 5, "-" indicates that the corresponding component is not present.

[0167] Tables 3 to 6 show that Examples 1 to 46, which use a negative electrode coated at least in part with a compound containing an aromatic ring to which two or more elements selected from the group consisting of N, S, and O are independently bonded, and which use an electrolyte containing a compound represented by the above formula (1), have a significantly higher number of cycles and superior cycle characteristics than the comparative examples, which do not use such an electrolyte.

[0168] [Example 47] As Example 47, a lithium secondary battery was produced using a positive electrode containing a sacrificial positive electrode agent. The positive electrode was produced as follows, and the other procedures were the same as in Example 1 above to obtain a lithium secondary battery. A mixture of 97 parts by mass of a mixture of a positive electrode active material (92 parts by mass) and a sacrificial positive electrode agent (5 parts by mass), 1.5 parts by mass of carbon black as a conductive additive, and 1.5 parts by mass of polyvinylidene fluoride (PVDF) as a binder was applied to one side of a 12 μm Al foil as a positive electrode current collector and press-molded. The resulting molded body was punched to a predetermined size by a punching process to obtain a positive electrode. At this time, LiNi was used as the positive electrode active material. 0.85 Co 0.12 Al 0.03 O2 as a sacrificial cathode and Li6Mn 0.5 Co 0.5 O4 was used.

[0169] The cycle characteristics of the lithium secondary battery of Example 47 were evaluated in the same manner as in Example 1. The results are shown in Table 7.

[0170] [Table 7]

[0171] From Table 7, it can be seen that Example 47, which uses a negative electrode coated with a compound containing an aromatic ring to which at least two elements selected from the group consisting of N, S, and O are independently bonded, an electrolyte containing a compound represented by the above formula (1), and a positive electrode containing a sacrificial positive electrode agent, has a very high cycle number and is even more excellent in cycle characteristics.

[0172] The lithium secondary battery of the present invention has high energy density and excellent cycle characteristics, and therefore has industrial applicability as an electricity storage device for a variety of uses. [Explanation of symbols]

[0173] 100, 200... lithium secondary battery, 110... positive electrode current collector, 120... positive electrode, 130... separator, 140... negative electrode, 210... positive electrode terminal, 220... negative electrode terminal.

Claims

1. A battery comprising a positive electrode, a negative electrode having no negative electrode active material, and an electrolyte solution, The negative electrode has a surface facing the positive electrode coated with a compound containing an aromatic ring to which two or more elements selected from the group consisting of N, S, and O are independently bonded, and The electrolyte solution is A lithium salt and a solvent represented by the following formula (1): Lithium secondary battery. 【Chemical 1】 (In formula (1), R 1 is an n-valent atomic group containing at least one nitrogen atom and 1 to 30 carbon atoms, R 2 each independently represents a fluorine atom or an alkyl group having a fluorine atom, n represents an integer of 1 or more and 5 or less, Each of n [-SO 2 R 2 ] group is R 1 is bonded to the carbon atom by an N-S bond.)

2. The R 1 In the formula, [-SO 2 R 2 2. The lithium secondary battery according to claim 1, wherein the nitrogen atom bonded to the ] group is bonded to two carbon atoms.

3. The R 1 The lithium secondary battery according to claim 1 or 2, wherein the carbon atom (C) contains a chain structure containing at least one nitrogen atom.

4. The R 1 The lithium secondary battery according to claim 1 or 2, wherein the cyclic structure includes at least one nitrogen atom.

5. The R 2 are each independently a fluorine atom, or an alkyl group in which the ratio (F / (F+H)) of the number of fluorine atoms (F) to the total number of fluorine atoms and hydrogen atoms (F+H) is 0.70 or more and 1.0 or less.

6. The R 2 6. The lithium secondary battery according to claim 1, wherein each independently represents a fluorine atom or a trifluoromethyl group.

7. 7. The lithium secondary battery according to claim 1, wherein the electrolyte solution further contains an ether compound having no fluorine atoms or a carbonyl compound having no fluorine atoms.

8. 8. The lithium secondary battery according to claim 1, wherein the electrolyte solution further contains a chain fluorine compound represented by the following formula (A) or (B): 【Chemistry 2】 【Chemistry 3】 (In formula (A), R 6 is an alkyl group which may contain an ether bond, and R 7 is a fluorine-substituted alkylene group, and R 8 is an alkyl group which may contain an ether bond. 9 is a fluorine-substituted alkyl group, and R 10 is an alkylene group which may contain an ether bond, and R 11 represents an alkyl group which may be substituted with fluorine.

9. The lithium salt is at least LiN(SO 2 F) 2 The lithium secondary battery according to any one of claims 1 to 8, comprising:

10. 10. The lithium secondary battery according to claim 1, wherein in the compound coating the negative electrode, one or more nitrogen atoms are bonded to the aromatic ring.

11. 11. The lithium secondary battery according to claim 1, wherein the compound coated on the negative electrode is at least one selected from the group consisting of benzotriazole, benzimidazole, benzimidazole thiol, benzoxazole, benzoxazole thiol, benzothiazole, mercaptobenzothiazole, polyimide, polyimidazole, and derivatives thereof.

12. The positive electrode comprises a positive electrode active material and a lithium-containing compound that undergoes an oxidation reaction and does not substantially undergo a reduction reaction in a charge / discharge potential range of the positive electrode active material. The lithium secondary battery according to any one of claims 1 to 11.

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