Compositions and methods for odor reduction and bacterial control on textiles

Abstract

Compositions and methods for durable odor control on textiles are provided. The compositions include benzoic acid, a salt of benzoic acid, a non-benzoic acid, a salt of said non-benzoic acid, or combinations thereof. The compositions may further include an optional binder. Methods for applying the compositions include padding and exhaustion.

Description

[Technical Field]

[0001] (CROSS-REFERENCE TO RELATED APPLICATIONS) This application claims priority from U.S. Provisional Patent Application No. 63 / 216,321, filed with the U.S. Patent and Trademark Office on June 29, 2021, and U.S. Provisional Patent Application No. 17 / 845,924, filed with the U.S. Patent and Trademark Office on June 21, 2022, the disclosures of which are incorporated herein by reference in their entireties.

[0002] The present invention relates to compositions and methods for odor control, and more particularly to compositions and methods for durable odor control on fabrics. [Background technology]

[0003] Current bacterial control in textiles and clothing relies heavily on the use of metal-containing active agents such as zinc. The presence of these "heavy metals" in textile mill process wastewater has been a concern for environmental policy and regulatory agencies. Eventually, zinc pyrithione will no longer be available to reduce odor- and stain-causing bacteria on textile surfaces.

[0004] Alternatively, organic molecules such as quaternary ammonium silanes, phenols, and azoles can be used to treat fiber surfaces. The use of these chemicals requires extensive formulation efforts to reduce hydrophobicity and increase durability.

[0005] The present invention provides an antimicrobial solution for textile substrates that meets new regulatory requirements, does not impart hydrophobicity, and provides good durability. Summary of the Invention

[0006] The present invention relates to compositions and methods for durable odor control on fabrics.

[0007] In an embodiment of the present invention, a composition is provided that includes benzoic acid, a salt of benzoic acid, a non-benzoic acid, or a combination of a non-benzoic acid and a salt of a non-benzoic acid, and an optional binder.

[0008] In one embodiment of the present invention, a composition is provided, the composition comprising sodium benzoate and citric acid.

[0009] In one embodiment of the present invention, a composition is provided, the composition comprising: a component selected from the group consisting of benzoic acid, salts of benzoic acid, and combinations thereof; and a binder.

[0010] In one embodiment of the present invention, there is provided a method comprising mixing benzoic acid and / or a salt of benzoic acid with an optional binder, and optionally, the method may further comprise exhausting the mixture into fibers using an exhaustion bath.

[0011] In one embodiment of the present invention, a method is provided comprising mixing sodium benzoate, a non-benzoic acid and / or a salt of a non-benzoic acid, and an optional binder, and may further comprise using the mixture in an exhaustion bath to exhaust the fibers.

[0012] In one embodiment of the present invention, a method is provided comprising mixing benzoic acid and / or a salt of benzoic acid with an optional binder, and optionally padding the mixture onto fibers.

[0013] In one embodiment of the present invention, a method is provided, the method comprising mixing sodium benzoate, a non-benzoic acid and / or a salt of a non-benzoic acid, and an optional binder, and may further comprise padding the mixture onto fibers.

[0014] Further scope of applicability of the present invention will become apparent from the detailed description provided hereinafter. It should be understood that the detailed description and specific examples, while indicating preferred embodiments of the invention, are intended for purposes of illustration only and are not intended to limit the scope of the invention. DETAILED DESCRIPTION OF THE INVENTION

[0015] The following description of embodiments of the present invention is merely exemplary in nature and is not intended to limit the invention, its application, or uses. The following description is provided herein by way of example only, for the purpose of providing an enabling disclosure of the invention, but not to limit the scope or substance of the invention.

[0016] Furthermore, the term "or," as used in this disclosure and the appended claims, is intended to mean an inclusive "or," rather than an exclusive "or." That is, unless otherwise specified or clear from the context, the phrase "X employs A or B" is intended to mean any of the natural inclusive permutations. That is, the phrase "X employs A or B" is satisfied by any of the following: X employs A; X employs B; or X employs both A and B. Furthermore, the articles "a" and "an," as used in this specification and the appended claims, should generally be construed to mean "one or more" unless otherwise specified or unless the context clearly directs to the singular form. Throughout this specification and the claims, the following terms shall have at least the meaning expressly associated therewith herein, unless the context dictates otherwise. The meanings specified below do not necessarily limit the terms, but merely provide illustrations of the terms. The meanings of "a," "an," and "the" may include plural references, and the meaning of "in" may include "in," "at," and / or "on," unless the context clearly indicates otherwise. The phrase "in one embodiment" as used herein does not necessarily refer to the same embodiment, although it may.

[0017] The present invention provides compositions suitable for withstanding the demands of fiber processing temperatures, water dispersibility, compatibility with acetic acid, and a low skin toxicity profile.

[0018] In one embodiment of the present invention, the composition comprises a component selected from the group consisting of benzoic acid, a salt of a benzoic acid, a non-benzoic acid, a salt of a non-benzoic acid, and combinations thereof. The composition may further comprise an optional binder.

[0019] A non-limiting example of a salt of benzoic acid is sodium benzoate.

[0020] Non-limiting examples of non-benzoic acids are sorbic acid, citric acid, lactic acid, acetic acid, L-glutamic acid, or combinations thereof.

[0021] Non-limiting examples of salts of non-benzoic acids are potassium sorbate, trisodium citrate, and combinations thereof.

[0022] Preferably, the binder comprises an acrylic resin.

[0023] In a preferred embodiment of the present invention, the composition comprises a combination of sodium benzoate and a non-benzoic acid, such as a combination of sodium benzoate and a non-benzoic acid selected from the group consisting of sorbic acid, citric acid, lactic acid, acetic acid, L-glutamic acid, and combinations thereof.

[0024] It has been surprisingly found that a synergistic effect is achieved in terms of deodorizing effect when applied to fabrics and durability to home laundering by combining sodium benzoate and a non-benzoic acid, wherein the weight ratio of sodium benzoate to the non-benzoic acid is in the range of 1:3 to 10:1.

[0025] Preferably, the composition contains sodium benzoate and citric acid. The composition containing sodium benzoate and citric acid preferably has a mass ratio ranging from 1:3 to 10:1. For example, in the experiments performed below, the ratio of sodium benzoate to citric acid is exemplified as 1:1. The composition may be in powder form, liquid form, or a combination thereof. Preferably, the composition is in powder form, but liquid form is also applicable. The components of the composition can be added as a mixture or separately in either powder form, liquid form, or a combination thereof.

[0026] In one aspect of the present invention, methods of preparation and / or use are provided. Any number of fiber application or treatment methods can be used, including but not limited to padding or exhaustion.

[0027] The method of the present invention comprises applying the composition of the present invention to a fiber by exhaustion. For example, the method includes adding benzoic acid (and / or a salt of benzoic acid) or sodium benzoate and a non-benzoic acid (and / or a salt of a non-benzoic acid), and an optional binder, to an exhaustion bath; exhausting the fibers, such as fabrics; and drying. Exhaustion is preferably carried out at a temperature ranging from 85°C to 130°C and / or for a time ranging from 20 to 45 minutes.

[0028] The method of the present invention comprises applying a composition to a fabric by padding. For example, the method comprises adding benzoic acid (and / or a salt of benzoic acid) and / or sodium benzoate and a non-benzoic acid (and / or a salt of a non-benzoic acid), and an optional binder, to a padding bath; padding the composition onto a fabric, such as a textile; and curing at 130°C to 160°C for 45 seconds to 1 minute.

[0029] The binder is optional and can be added depending on the wash durability requirements of the final textile. Preferably, the binder is an acrylic binder. However, it has been surprisingly found that the inclusion of a binder enhances the already unexpected antimicrobial effect.

[0030] Bacterial control on textile materials can be activated and enhanced by the laundering process.An advantage of the present invention is that the compositions of the present invention are non-hazardous and applicable to most forms of textile manufacturing.

[0031] Example 1

[0032] Benzoic acid with an acrylic binder was padded onto 100% polyester. Antimicrobial efficacy was tested before and after 25 home launderings (HL) according to AATCC TM100. The bacteria tested was Kleb pneumoniae. Data are shown in Table 1. Significant log reductions were observed at both 0 HL and 25 HL, and the data were reproducible across different runs.

[0033] [Table 1]

[0034] Example 2

[0035] This example shows exhaust results using a composition consisting of sodium benzoate and a non-benzoic acid. The non-benzoic acid used was citric acid. The composition was applied to 100% polyester. Results were obtained from mill trials. Test conditions were a 16% application based on weight of fabric (owf) and a 1:1 ratio of sodium benzoate to citric acid. Data are shown in Table 2.

[0036] [Table 2]

[0037] 100% polyester was tested for exhaust efficacy according to AATCC TM100. No efficacy was detected before washing. The reduction rates of both bacteria (IgE, I ...

[0038] Thus, it will be readily apparent to those skilled in the art that the present invention is susceptible to broad utility and application. Many embodiments and adaptations of the present invention other than those described herein, as well as numerous variations, modifications, and equivalent arrangements, will be apparent from, or will be reasonably suggested by, the present invention and the foregoing description thereof, without departing from the spirit or scope of the present invention. Thus, while the present invention has been described in detail herein with reference to preferred embodiments thereof, it should be understood that this disclosure is merely exemplary and illustrative of the invention and is made solely for the purpose of providing a complete and enabling disclosure of the invention. The foregoing disclosure is not intended to, and should not be construed as, limiting the present invention or excluding other embodiments, adaptations, variations, modifications, and equivalent arrangements. This specification includes the following configuration at the time of international filing. [1] A salt of benzoic acid, a non-benzoic acid, a salt of said non-benzoic acid, or a combination of said non-benzoic acid and a salt of said non-benzoic acid; an optional binder; A composition comprising: [2] The composition according to [1], wherein the salt of benzoic acid is sodium benzoate. [3] The composition described in [1], wherein the non-benzoic acid is selected from the group consisting of sorbic acid, citric acid, lactic acid, acetic acid, L-glutamic acid, and combinations thereof. [4] The composition described in [1], wherein the salt of a non-benzoic acid is selected from the group consisting of potassium sorbate, trisodium citrate, and combinations thereof. [5] The composition according to [1], wherein the binder comprises an acrylic resin. [6] The composition described in [2], wherein the mass ratio of sodium benzoate to the non-benzoic acid, the salt of the non-benzoic acid, or the combination of the non-benzoic acid and the salt of the non-benzoic acid is 1:3 or more and 10:1 or less. [7] The composition according to [1], wherein the salt of benzoic acid is a powder or a liquid. [8] The composition according to [1], wherein the non-benzoic acid, the salt of the non-benzoic acid, or the combination of the non-benzoic acid and the salt of the non-benzoic acid is in the form of a powder or a liquid. [9] A method comprising applying the composition according to [1] to fibers by exhaustion.

[10] A method comprising applying the composition according to [1] to fibers by padding.

[11] Sodium benzoate, Citric acid and A composition comprising:

[12] The composition according to

[11] , further comprising a binder.

[13] The composition according to

[12] , wherein the binder comprises an acrylic resin.

[14] The composition described in

[11] , wherein the mass ratio of the sodium benzoate to the citric acid is 1:3 or more and 10:1 or less.

[15] The composition described in

[11] , wherein the sodium benzoate is a powder or liquid.

[16] The composition described in

[11] , wherein the citric acid is a powder or liquid.

[17] A method comprising applying the composition according to

[11] to fibers by exhaustion.

[18] A method comprising applying the composition according to

[11] to fibers by padding.

[19] A component selected from the group consisting of benzoic acid, salts of benzoic acid, and combinations thereof; A binder and A composition comprising:

[20] The composition according to

[19] , wherein the binder comprises an acrylic resin.

[21] A method comprising applying the composition according to

[19] to fibers by exhaustion.

[22] A method comprising applying the composition according to

[19] to the fibers by padding.

[23] A method comprising mixing benzoic acid and / or a salt of said benzoic acid with an optional binder.

[24] The method further comprising using the blended mixture to exhaust fibers in an exhaustion bath.

[25] The method of

[24] , further comprising drying the exhausted fibers.

[26] The method according to

[24] , wherein the exhaustion is carried out at a temperature in the range of 85°C or higher and 130°C or lower.

[27] The method according to

[24] , wherein the exhaustion is carried out for a period of time ranging from 20 minutes to 45 minutes.

[28] A method comprising mixing sodium benzoate, a non-benzoic acid and / or a salt of said non-benzoic acid, and an optional binder.

[29] The method according to

[28] , wherein the non-benzoic acid is selected from the group consisting of sorbic acid, citric acid, lactic acid, acetic acid, L-glutamic acid, and combinations thereof.

[30] The method of

[28] , further comprising exhausting the blended mixture onto fibers in an exhaustion bath.

[31] The method of

[30] , further comprising drying the exhausted fibers.

[32] The method according to

[30] , wherein the exhaustion is carried out at a temperature in the range of 85°C or higher and 30°C or lower.

[33] The method according to

[30] , wherein the evacuation is carried out for a period of time ranging from 20 minutes to 45 minutes.

[34] A method comprising mixing benzoic acid and / or a salt of said benzoic acid with an optional binder.

[35] The method of

[34] , further comprising padding the blended mixture onto fibers.

[36] The method of

[35] , further comprising curing.

[37] The method according to

[35] , wherein the curing is carried out at 130°C or higher and 160°C or lower for 45 seconds or longer and 1 minute or shorter.

[38] Mixing sodium benzoate with a non-benzoic acid and / or a salt of said non-benzoic acid and an optional binder; A method comprising:

[39] The method according to

[38] , wherein the non-benzoic acid is selected from the group consisting of sorbic acid, citric acid, lactic acid, acetic acid, L-glutamic acid, and combinations thereof.

[40] The method of

[38] , further comprising padding the blended mixture onto fibers.

[41] The method of

[40] , further comprising curing.

[42] The method according to

[41] , wherein the curing is carried out at 130°C or higher and 160°C or lower for 45 seconds or longer and 1 minute or shorter.

Claims

1. 1. A method for reducing bacteria and odor on textiles or textile materials, comprising: the fibers or textile material consist of 100% polyester; A method for applying a composition containing sodium benzoate and citric acid, wherein the weight ratio of the sodium benzoate to the citric acid is 1:1, to the fibers or fiber material by exhaustion or padding.

2. 2. The method of claim 1, wherein the exhaustion is carried out by adding the composition to an exhaustion bath prior to the exhaustion and applying the composition to the fibers or fiber material.

3. 2. The method of claim 1, wherein the exhaustion is carried out at a temperature in the range of from 85°C to 130°C.

4. 10. The method of claim 1, wherein the exhaustion is carried out for a time period ranging from 20 minutes to 45 minutes.

5. 10. The method of claim 1, wherein the padding further comprises curing at 130°C to 160°C for 45 seconds to 1 minute after the padding.

Images