Battery and battery manufacturing method

Abstract

This method for producing a battery comprises: a preparation step (S11) for preparing an electric power generation element (30) wherein a first collector (11, 21) that contains a first metal, a first active material layer (12), a solid electrolyte layer (15), a second active material layer (14) and a second collector (13) that contains a second metal that is harder than the first metal are sequentially stacked in this order; and a pressing step (S12) for pressing the electric power generation element (30) by the intermediary of a plate-like member (18) that is configured from a first material that is harder than the first metal, while having a roughened surface (18a). In the pressing step, the electric power generation element (30) is pressed by bringing the roughened surface (18a) of the plate-like member into contact with a main surface (11a) of the first collector.

Description

[Technical Field]

[0001] The present disclosure relates to batteries and methods for manufacturing batteries. [Background technology]

[0002] A battery made entirely of solid materials, a so-called all-solid-state battery, can be constructed by disposing a solid electrolyte layer containing an ionically conductive solid electrolyte between a positive electrode active material layer and a negative electrode active material layer and pressing them under high pressure. Patent Document 1, for example, discloses a multi-layered battery in which multiple all-solid-state batteries are arranged one above the other and bonded under pressure. Patent Document 2 also discloses a multi-layered all-solid-state battery in which two all-solid-state batteries are arranged symmetrically above and below each other and pressed under high pressure. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] Japanese Patent Application Publication No. 2018-181451 [Patent Document 2] Japanese Patent Application Laid-Open No. 2017-157271 Summary of the Invention [Problem to be solved by the invention]

[0004] In conventional technologies, for example, when an all-solid-state battery is made larger and / or thinner, deformation such as warping may occur in the all-solid-state battery. Therefore, the present disclosure provides a battery manufacturing method and the like that can suppress deformation. [Means for solving the problem]

[0005] A method for manufacturing a battery according to one embodiment of the present disclosure includes a preparation step of preparing a power generating element in which a first current collector containing a first metal, a first active material layer, a solid electrolyte layer, a second active material layer, and a second current collector containing a second metal harder than the first metal are stacked in this order, and a pressing step of pressing the power generating element via a plate-like member made of a first material harder than the first metal and having a roughened surface, wherein the pressing step presses the power generating element by contacting the roughened surface of the plate-like member with a main surface of the first current collector.

[0006] A battery according to one embodiment of the present disclosure includes a power generating element in which a first current collector containing a first metal, a first active material layer, a solid electrolyte layer, a second active material layer, and a second current collector containing a second metal harder than the first metal are stacked in this order, and a plurality of attachments attached to a main surface of the first current collector opposite to the first active material layer side and made of a first material harder than the first metal. [Effects of the Invention]

[0007] According to the present disclosure, it is possible to provide a method for manufacturing a battery that can suppress deformation. [Brief explanation of the drawings]

[0008] [Figure 1] FIG. 1 is a cross-sectional view and a plan view showing a schematic configuration of a battery according to an embodiment. [Figure 2] FIG. 2 is an enlarged cross-sectional view and an enlarged plan view of a positive electrode current collector of a battery according to an embodiment. [Figure 3] FIG. 3 is a flowchart of a method for manufacturing a battery according to an embodiment. [Figure 4A] FIG. 4A is a schematic view illustrating a pressing step in the battery manufacturing method according to the embodiment. [Figure 4B] FIG. 4B is a schematic view showing the plate-like member and the positive electrode current collector at the initial stage of pressing in the pressing step in the manufacturing method for the battery according to the embodiment. [Figure 4C]FIG. 4C is a schematic view showing the plate-like member and the positive electrode current collector after being pressed in the pressing step in the manufacturing method of the battery according to the embodiment. [Figure 5] FIG. 5 is a cross-sectional view and a plan view showing a schematic configuration of a battery according to a first modification of the embodiment. [Figure 6] FIG. 6 is a cross-sectional view and a plan view showing a schematic configuration of a battery according to Modification 2 of the embodiment. [Figure 7] FIG. 7 is a cross-sectional view and a plan view showing a schematic configuration of a battery according to a third modification of the embodiment. [Figure 8] FIG. 8 is a cross-sectional view and a plan view showing a schematic configuration of a battery according to a fourth modification of the embodiment. [Figure 9] FIG. 9 is a cross-sectional view and a plan view showing a schematic configuration of a battery according to a fifth modification of the embodiment. DETAILED DESCRIPTION OF THE INVENTION

[0009] (Summary of the Disclosure) A method for manufacturing a battery according to one embodiment of the present disclosure includes a preparation step of preparing a power generating element in which a first current collector containing a first metal, a first active material layer, a solid electrolyte layer, a second active material layer, and a second current collector containing a second metal harder than the first metal are stacked in this order, and a pressing step of pressing the power generating element via a plate-like member made of a first material harder than the first metal and having a roughened surface, wherein the pressing step presses the power generating element by contacting the roughened surface of the plate-like member with a main surface of the first current collector.

[0010] This allows for suppression of deformation of the manufactured battery, even in the case of a large-sized and / or thin battery. Specifically, during pressing in the pressing process, the roughened surface of the plate-shaped member made of a first material harder than the first metal bites into the first current collector, restraining the first current collector. This restraint suppresses elongation of the first current collector, which is more easily elongated than the second current collector made of a second metal harder than the first metal, due to the pressure of the press in the pressing process. Therefore, the difference between the elongation of the first current collector and the elongation of the second current collector in the pressing process is reduced, and deformation such as warping of the manufactured battery can be suppressed.

[0011] Furthermore, when a plate-shaped member made of the first material is pressed, the pressure applied can cause multiple protrusions on the roughened surface to separate, leaving multiple deposits on the main surface of the first current collector. The presence of these hard deposits can reduce the difference in stress between the first and second current collectors caused by temperature changes (e.g., thermal cycling) of the battery. This allows for the realization of a battery that can suppress deformation due to thermal cycling.

[0012] Furthermore, for example, in the pressing step, the roughened surface may be brought into contact with the entire main surface of the first current collector and pressed.

[0013] As a result, the entire main surface of the first current collector from the outer periphery to the center in plan view is constrained by the plate-like member, and the effect of suppressing elongation of the first current collector is applied to the entire first current collector, thereby further suppressing deformation such as warping of the manufactured battery.

[0014] Furthermore, for example, in the pressing step, the plate-like member may be pressed so as to come into contact with a pressing member.

[0015] This allows the force of the pressing member to be transmitted directly to the plate-like member, thereby increasing the restraining force of the plate-like member on the first current collector.

[0016] Furthermore, for example, the method for manufacturing a battery may include, after the pressing step, a peeling step of peeling the plate-shaped member from the power-generating element.

[0017] This removes the plate-like members that do not contribute to power generation by the battery, thereby increasing the volumetric energy density of the battery.

[0018] Furthermore, for example, the method for manufacturing a battery may include, after the pressing step, a cutting step of cutting the power generating element.

[0019] This allows the outer periphery of the pressed power generating element, which is prone to distortion and deformation, to be removed, thereby suppressing warping and enabling batteries with high shape precision to be obtained in any shape (i.e., capacity). Furthermore, if the size of the power generating element prepared in the preparation process is increased, a large number of batteries with highly precise shapes can be manufactured from a series of manufacturing processes.

[0020] Furthermore, for example, the roughened surface may be rougher than the main surface of the first current collector that is in contact with the roughened surface.

[0021] This makes it easier for the roughened surface of the plate-like member to bite into the main surface of the first current collector in the pressing step.

[0022] Furthermore, for example, the surface roughness Rz of the roughened surface may be 1 μm or more and 10 μm or less.

[0023] This makes it possible to effectively restrain the first current collector by the plate-like member while preventing the first current collector from being damaged by the roughened surface of the plate-like member during the pressing process.

[0024] Furthermore, for example, the first material may include a metal.

[0025] This makes it difficult for the protrusions of the plate-like member to impede electrical conduction in the first current collector even if they remain on the first current collector.

[0026] Furthermore, for example, the first material may include the second metal.

[0027] This reduces the difference in hardness between the plate-like member and the second current collector, thereby reducing the difference in elongation between the first current collector restrained by the plate-like member and the second current collector.

[0028] Furthermore, for example, the first metal may be aluminum, and the second metal may be copper.

[0029] Even when aluminum and copper, which have a large difference in hardness, are contained in the first current collector and the second current collector, respectively, deformation such as warping of the battery can be suppressed.

[0030] Furthermore, for example, the thermal expansion coefficient of the first material may be smaller than the thermal expansion coefficient of the first metal.

[0031] As a result, even when the solid electrolyte layer and the active material layer are heated in the pressing process to densify them, the plate-like member has a smaller amount of thermal expansion than the first current collector, thereby enhancing the effect of restraining the first current collector that tends to expand.

[0032] Furthermore, a battery according to one embodiment of the present disclosure includes a power generating element in which a first current collector containing a first metal, a first active material layer, a solid electrolyte layer, a second active material layer, and a second current collector containing a second metal harder than the first metal are stacked in this order, and a plurality of attachments attached to a main surface of the first current collector opposite to the first active material layer side and made of a first material harder than the first metal.

[0033] As a result, for example, when the battery is subjected to a temperature change (e.g., a thermal cycle), the difference in stress caused by the difference in thermal expansion between the first and second current collectors, which are made of different materials, can be alleviated by the presence of a hard attachment attached to the first current collector, thereby realizing a battery that can suppress deformation such as warping.

[0034] Furthermore, for example, the average maximum width of the plurality of attachments in a plan view may be 10 μm or less.

[0035] As a result, even if the battery is subjected to temperature changes such as thermal cycling, the size of the deposits is small, so the occurrence of structural defects is suppressed.

[0036] Furthermore, for example, the first material may include the second metal.

[0037] This allows, for example, a plurality of attachments to be attached to the first current collector using the same material as the second current collector, making it possible to easily manufacture a battery.

[0038] Furthermore, for example, the main surface of the first current collector to which the plurality of attachments are attached may be rougher than the main surface of the second current collector opposite to the second active material layer side.

[0039] As a result, the surface area is increased by the uneven structure of the main surface of the soft first current collector to which multiple attachments are attached, which disperses and absorbs the stress caused by thermal cycles, thereby suppressing structural defects and deformation such as warping of the battery and improving thermal shock resistance.

[0040] Furthermore, for example, the first metal may be aluminum, and the second metal may be copper.

[0041] This makes it possible to suppress deformation such as warping of the battery even when the first current collector and the second current collector contain aluminum and copper, which have a large difference in hardness.

[0042] Furthermore, for example, at least one of the plurality of attachments may be attached to an end portion of the first current collector in a plan view.

[0043] This causes the sidewall of the first current collector to be covered with hard deposits, thereby preventing burrs from forming when cutting or polishing the sidewall of the first current collector, which is one of the causes of short circuits, and thereby preventing short circuits in the battery.

[0044] Furthermore, for example, the first current collector may have at least one linear step formed in a convex or concave shape, with a width of the convex or concave being 1 mm or more in plan view.

[0045] As a result, the flat surface of the main surface of the first current collector is divided by the steps. Therefore, when stress such as hardening stress occurs in a layer in contact with the main surface of the first current collector where the steps are formed, the stress is dispersed and alleviated by the presence of the convex or concave portions of the steps and the divided flat surfaces. As a result, deformation such as peeling and warping at the joint between the first current collector and the layer in contact with the surface of the first current collector where the steps are formed is suppressed. Furthermore, because the width of the convex or concave portion in a plan view of the steps is 1 mm or more, stress generated in the layer in contact with the surface of the first current collector where the steps are formed is easily dispersed.

[0046] Furthermore, for example, the step may be formed in a convex shape, and the number of the multiple attachments attached per unit area of ​​the first current collector may be greater at locations other than the location where the step is located on the main surface of the first current collector opposite the first active material layer side than at the location where the step is located.

[0047] As a result, a large amount of hard deposits adhere to the thin portions of the first current collector where no steps are formed, and the deposits effectively relieve stress on the thin portions of the first current collector which are prone to deformation.

[0048] Furthermore, for example, the solid electrolyte layer may include a solid electrolyte having lithium ion conductivity.

[0049] This makes it possible to realize a small, large-capacity battery that can suppress deformation.

[0050] Hereinafter, the embodiments will be specifically described with reference to the drawings.

[0051] The embodiments described below are all comprehensive or specific examples. The numerical values, shapes, materials, components, arrangement positions and connection forms of the components shown in the following embodiments are merely examples and are not intended to limit the present disclosure. Furthermore, among the components in the following embodiments, components that are not described in the independent claims are described as optional components.

[0052] Furthermore, in this specification, terms indicating the relationship between elements, such as parallelism, terms indicating the shape of elements, such as rectangle, and numerical ranges are not expressions that only express a strict meaning, but are expressions that also include a substantially equivalent range, for example, a difference of about a few percent.

[0053] In addition, the drawings are not necessarily strict illustrations, and the same reference numerals are used to designate substantially the same components in the drawings, and redundant explanations are omitted or simplified.

[0054] In this specification and drawings, the x-axis, y-axis, and z-axis represent the three axes of a three-dimensional Cartesian coordinate system. In each embodiment, the z-axis direction is the thickness direction of the battery. In this specification, the "thickness direction" refers to the direction perpendicular to the surface on which each layer is stacked. In other words, the direction in which each layer is stacked is the thickness direction of each layer.

[0055] In addition, in this specification, "plan view" means a view of the battery along the stacking direction of the battery, and "thickness" in this specification means the length of the battery and each layer in the stacking direction.

[0056] In addition, in this specification, the terms "inside" and "outside" refer to the inside and outside when the battery is viewed along the stacking direction of the battery.

[0057] Furthermore, in this specification, the terms "upper" and "lower" in the battery configuration do not refer to the upper direction (vertically upper) and lower direction (vertically lower) in absolute spatial recognition, but are used as terms defined by a relative positional relationship based on the stacking order in the stacking configuration. Furthermore, the terms "upper" and "lower" are applied not only to a case where two components are arranged with a gap between them and another component exists between the two components, but also to a case where two components are arranged closely together and the two components are in contact with each other.

[0058] In this specification, the term "principal surface" refers to the surface of each component in a direction perpendicular to the thickness direction.

[0059] (Embodiment) [Battery configuration] First, the battery according to the present embodiment will be described.

[0060] FIG. 1 is a cross-sectional view and a plan view showing a schematic configuration of a battery according to the present embodiment. Specifically, FIG. 1(a) is a cross-sectional view of a battery 100 according to the present embodiment, and FIG. 1(b) is a plan view of the battery 100 as seen from above in the z-axis direction. FIG. 1(a) shows a cross section taken along line Ia-Ia in FIG. 1(b). FIG. 2 is an enlarged cross-sectional view and an enlarged plan view of a positive electrode current collector according to the present embodiment. Specifically, FIG. 2(a) is an enlarged cross-sectional view of a positive electrode current collector 11, and FIG. 2(b) is an enlarged plan view of region II in FIG. 1(b). FIG. 2(a) shows a cross section taken along line IIa-IIa in FIG. 2(b).

[0061] As shown in FIGS. 1 and 2 , the battery 100 has a thin rectangular parallelepiped structure. The battery 100 includes a power generating element 30 including a positive electrode current collector 11 containing a first metal, a positive electrode active material layer 12, a solid electrolyte layer 15, a negative electrode active material layer 14, and a negative electrode current collector 13 containing a second metal harder than the first metal, stacked in this order. The battery 100 also includes a plurality of attachments 16 attached to a main surface 11a of the positive electrode current collector 11 opposite the positive electrode active material layer 12. The attachments 16 are made of a first material harder than the first metal. The positive electrode current collector 11 is an example of a first current collector, and the negative electrode current collector 13 is an example of a second current collector. The positive electrode active material layer 12 is an example of a first active material layer, and the negative electrode active material layer 14 is an example of a second active material layer. The attachments 16 are not shown in FIG. 1 due to their small size. In addition, in Fig. 2, the plurality of attachments 16 are shown with dotted patterns for ease of understanding, but the plurality of attachments 16 do not actually have dotted patterns. The same applies to the subsequent figures.

[0062] The power generating element 30 includes, for example, a positive electrode current collector 11, a positive electrode active material layer 12 arranged in contact with the positive electrode current collector 11, a negative electrode current collector 13, a negative electrode active material layer 14 arranged in contact with the negative electrode current collector 13, and a solid electrolyte layer 15 arranged between the positive electrode active material layer 12 and the negative electrode active material layer 14 and containing a solid electrolyte. The positive electrode active material layer 12 and the negative electrode active material layer 14 are arranged between the positive electrode current collector 11 and the negative electrode current collector 13.

[0063] The positive electrode current collector 11, the positive electrode active material layer 12, the solid electrolyte layer 15, the negative electrode active material layer 14, and the negative electrode current collector 13 are each, for example, rectangular in plan view. The shapes of the positive electrode current collector 11, the positive electrode active material layer 12, the solid electrolyte layer 15, the negative electrode active material layer 14, and the negative electrode current collector 13 in plan view are not particularly limited, and may be shapes other than rectangular, such as circular, elliptical, or polygonal.

[0064] In this specification, the positive electrode current collector 11 and the negative electrode current collector 13 may be collectively referred to simply as "current collectors." In addition, in this specification, the positive electrode active material layer 12 and the negative electrode active material layer 14 may be collectively referred to simply as "active material layers."

[0065] The positive electrode current collector 11 contains a first metal as a main component, and is composed of, for example, the first metal. The negative electrode current collector 13 contains a second metal as a main component, and is composed of, for example, the second metal. The first metal used in the positive electrode current collector 11 and the second metal used in the negative electrode current collector 13 may be metals in which the second metal is harder than the first metal. The current collector may be, for example, a foil or plate made of stainless steel, nickel, aluminum, iron, titanium, copper, palladium, gold, platinum, or an alloy of two or more of these metals. In this specification, hardness refers to, for example, Young's modulus; the higher the Young's modulus, the harder the material, and the lower the Young's modulus, the softer the material. The Young's modulus of the second metal may be, for example, 15% or more greater than that of the first metal and 30% or more greater than that of the first metal.

[0066] The hardness of the current collector material, for example, its elastic modulus such as Young's modulus, can be measured in the same way as Vickers hardness measurement by applying a rigid indenter and comparing the size of the traces. The hardness of the current collector material can be estimated, for example, if the metal composition is known, but it can also be compared by pressing an indenter with the same force against each part of the battery cross section and comparing the state of the indentation.

[0067] In this embodiment, for example, aluminum is used as the first metal and copper is used as the second metal. The Young's modulus of aluminum is, for example, about 70×10 9 Pa, and the thermal expansion coefficient of aluminum is, for example, about 24×10 -6 / K. The Young's modulus of copper is, for example, about 120×10 9 Pa, and the thermal expansion coefficient of copper is, for example, about 16×10 -6 / K. Even when aluminum and copper, which have a large difference in hardness and thermal expansion coefficient, are contained in positive electrode current collector 11 and negative electrode current collector 13, respectively, deformation such as warping of battery 100 can be suppressed by using the configuration of battery 100 according to the present embodiment or the manufacturing method described below.

[0068] The material of the current collector may be appropriately selected in consideration of the fact that it does not melt or decompose during the manufacturing process, the temperature and pressure used, and the operating potential and electrical conductivity of the battery applied to the current collector. The material of the current collector may also be selected according to the required tensile strength and heat resistance.

[0069] The thickness of the current collector is, for example, in the range of 10 μm or more and 100 μm or less, but even if it is less than 10 μm, it can be used as long as it satisfies the handling requirements during the manufacturing process, characteristics such as current flow, and reliability. For example, a metal foil having a general roughened surface is used as the current collector. The surface roughness Rz (maximum height) of the roughened surface is, for example, 1 μm or more and 10 μm or less. When a metal foil having a roughened surface is used as the current collector, for example, the roughened surface contacts the active material layer. This allows the roughened surface to penetrate into the active material constituting the active material layer, thereby increasing the bonding strength between the current collector and the active material layer through an anchor effect.

[0070] A plurality of attachments 16 are embedded in and directly adhere to a main surface 11a of the positive electrode current collector 11 opposite to the main surface in contact with the positive electrode active material layer 12. A portion of each of the plurality of attachments 16 is exposed. The main surface 11a of the positive electrode current collector 11 to which the plurality of attachments 16 are attached is rougher than, for example, the main surface of the negative electrode current collector 13 opposite to the negative electrode active material layer 14 side. For example, the surface roughness Rz of the main surface of the negative electrode current collector 13 is 0 μm or more and 0.5 μm or less, whereas the surface roughness Rz of the main surface 11a of the positive electrode current collector 11 to which the plurality of attachments 16 are attached is 1 μm or more and 5 μm or less. On the main surface 11a of the positive electrode current collector 11 to which multiple attachments 16 are attached, the convex portions are mainly areas where the multiple attachments 16 are directly fixed and attached to the positive electrode current collector 11, and the concave portions are mainly areas where the positive electrode current collector 11 is exposed.

[0071] The multiple attachments 16 are, for example, portions peeled off from a plate-like member 18 made of a first material used in the manufacturing method of the battery 100 described below. Therefore, the attachments 16 are made of the first material. The first material contains, for example, a metal as a main component. The first material is made of, for example, a metal. This makes it less likely that the attachments 16 will hinder electrical conduction in the positive electrode current collector 11. Examples of metals include stainless steel, nickel, aluminum, iron, titanium, copper, palladium, gold, platinum, and alloys of two or more of these metals.

[0072] The first material may contain the second metal as a main component or may be composed of the second metal, which allows the attachments 16 to be attached to the positive electrode current collector 11 using the same material as the negative electrode current collector 13, for example, and thus makes it possible to easily manufacture the battery 100.

[0073] The shape of the attachment 16 is shown schematically as a disk in Fig. 2, but is not particularly limited thereto. The shape of the attachment 16 may be a shape other than a disk, such as a square disk, a cylindrical shape, a rectangular pillar shape, or a gourd shape. The shape of the attachment 16 may also be an irregular shape composed of multiple curved surfaces or multiple flat surfaces.

[0074] The average maximum width of the multiple attachments 16 in a planar view is, for example, 10 μm or less. This reduces the size of the attachments 16, and suppresses the occurrence of structural defects even if the battery 100 is subjected to temperature changes such as thermal cycling. The maximum width in a planar view is, for example, the maximum Feret diameter.

[0075] The multiple attachments 16 are dispersed in an island shape on the main surface 11a of the positive electrode current collector 11. The average or median thickness of the multiple attachments 16 is, for example, equal to or less than the surface roughness Rz of the main surface 11a of the positive electrode current collector 11 to which the multiple attachments 16 are attached, for example, 5 μm or less. The multiple attachments 16 may be continuous with some of them overlapping each other.

[0076] With this configuration, the uneven structure caused by the deposits 16, which are harder than the soft first metal and adhere in large numbers in an island shape to the main surface 11a of the positive electrode current collector 11, can disperse and absorb stresses generated by thermal cycling of the battery 100. Furthermore, the presence of the deposits 16 made of a hard component can alleviate the difference in stress between the positive electrode current collector 11 and the negative electrode current collector 13, which contains a second metal harder than the first metal. These effects suppress deformation of the battery 100 and improve durability against thermal shock and thermal cycling.

[0077] Furthermore, due to the uneven structure of the main surface 11a of the positive electrode current collector 11 to which the multiple deposits 16 are attached, when, for example, a conductive paste or the like is applied to the main surface 11a of the positive electrode current collector 11, the surface energy is dispersed, reducing the influence of surface tension and improving the wettability of the coating film. This improves the accuracy of the coating film thickness and coating pattern shape. Therefore, when the battery 100 is joined to another battery using a conductive paste or the like, the joining interface is made uniform, the oozing of the coating film onto the sidewalls is suppressed, and warping and structural defects due to curing stress are suppressed. Therefore, by stacking the batteries 100, a highly reliable stacked battery can be formed.

[0078] Furthermore, at least one of the multiple attachments 16 is attached to, for example, an end of the positive electrode current collector 11 in a plan view. The attachment 16, which is harder than the first metal, forms part of the side wall of the battery 100, thereby suppressing the generation of burrs, elongation, cutting debris (i.e., metal dust), and the like during processing, which are likely to occur with the soft positive electrode current collector 11, and mainly suppressing short circuits on the side wall.

[0079] The positive electrode active material layer 12 is laminated in contact with one main surface of the positive electrode current collector 11, specifically, the main surface that faces the main surface 11a to which a plurality of deposits 16 are attached. The positive electrode active material layer 12 contains at least a positive electrode active material. The positive electrode active material layer 12 is mainly a layer composed of a positive electrode material such as a positive electrode active material. The positive electrode active material is a substance in which metal ions such as lithium (Li) ions or magnesium (Mg) ions are inserted into or detached from the crystal structure at a potential higher than that of the negative electrode, and oxidation or reduction is performed accordingly. The type of the positive electrode active material can be appropriately selected according to the type of the battery, and known positive electrode active materials can be used.

[0080] Examples of the positive electrode active material include compounds containing lithium and transition metal elements, such as oxides containing lithium and transition metal elements, and phosphate compounds containing lithium and transition metal elements. Examples of the oxide containing lithium and transition metal elements include lithium nickel composite oxides such as LiNi x M 1-x O2 (where M is at least one element among Co, Al, Mn, V, Cr, Mg, Ca, Ti, Zr, Nb, Mo, and W, and x satisfies 0 < x ≤ 1), such as lithium nickel composite oxides, layered oxides such as lithium cobalt oxide (LiCoO2), lithium nickel oxide (LiNiO2), and lithium manganate (LiMn2O4), and lithium manganate having a spinel structure (LiMn2O4, Li2MnO3, LiMnO2) are used. Examples of the phosphate compound containing lithium and transition metal elements include lithium iron phosphate (LiFePO4) having an olivine structure. In addition, sulfides such as sulfur (S) and lithium sulfide (Li2S) can also be used as the positive electrode active material. In that case, a material obtained by coating or adding lithium niobate (LiNbO3) or the like to the positive electrode active material particles can be used as the positive electrode active material. Note that only one type of these materials may be used as the positive electrode active material, or two or more types of these materials may be combined and used.

[0081] As described above, the positive electrode active material layer 12 may contain at least a positive electrode active material. The positive electrode active material layer 12 may be a mixture layer composed of a mixture of a positive electrode active material and other additive materials. Examples of other additive materials include solid electrolytes such as inorganic solid electrolytes or sulfide solid electrolytes, conductive additives such as acetylene black, and adhesive binders such as polyethylene oxide or polyvinylidene fluoride. By mixing the positive electrode active material and other additive materials, such as a solid electrolyte, in a predetermined ratio, the positive electrode active material layer 12 can improve both lithium ion conductivity and electronic conductivity. Examples of solid electrolytes that can be used include those exemplified as the solid electrolyte of the solid electrolyte layer 15 described below.

[0082] The thickness of the positive electrode active material layer 12 is, for example, not less than 5 μm and not more than 300 μm.

[0083] Next, the negative electrode active material layer 14 is laminated in contact with one main surface of the negative electrode current collector 13, specifically, the main surface of the negative electrode current collector 13 facing the positive electrode current collector 11. The negative electrode active material layer 14 includes at least a negative electrode active material. The negative electrode active material layer 14 is a layer mainly composed of a negative electrode material such as a negative electrode active material. The negative electrode active material is a material in which metal ions such as lithium (Li) ions or magnesium (Mg) ions are inserted or extracted into or from the crystal structure at a potential lower than that of the positive electrode, and oxidation or reduction occurs accordingly. The type of negative electrode active material can be appropriately selected depending on the type of battery, and known negative electrode active materials can be used.

[0084] Examples of the negative electrode active material include carbon materials such as natural graphite, artificial graphite, graphite carbon fiber, and resin-baked carbon, as well as alloy materials that are mixed with a solid electrolyte. Examples of alloy materials include LiAl, LiZn, Li3Bi, Li3Cd, Li3Sb, Li4Si, and Li 4.4 Pb, Li 4.4 Sn, Li 0.17 C, lithium alloys such as LiC6, lithium titanate (Li4Ti5O 12), oxides of lithium and transition metal elements such as zinc oxide (ZnO) and silicon oxide (SiO x ) and other metal oxides can be used. The negative electrode active material may be made of only one of these materials, or a combination of two or more of these materials.

[0085] As described above, the anode active material layer 14 may contain at least a negative electrode active material. The anode active material layer 14 may be a mixture layer composed of a mixture of a negative electrode active material and other additive materials. Examples of other additive materials include solid electrolytes such as inorganic solid electrolytes or sulfide solid electrolytes, conductive additives such as acetylene black, and adhesive binders such as polyethylene oxide or polyvinylidene fluoride. By mixing the anode active material with other additive materials, such as a solid electrolyte, in a predetermined ratio, the anode active material layer 14 can improve both lithium ion conductivity and electronic conductivity. Examples of solid electrolytes that can be used include those exemplified as the solid electrolyte of the solid electrolyte layer 15 described below.

[0086] The thickness of the negative electrode active material layer 14 is, for example, not less than 5 μm and not more than 300 μm.

[0087] The positive electrode active material layer 12 and the negative electrode active material layer 14 have the same shape, position and size in a plan view. However, the size and shape may be changed depending on the adjustment of the capacity ratio between the positive electrode and the negative electrode.

[0088] The solid electrolyte layer 15 is disposed between the positive electrode active material layer 12 and the negative electrode active material layer 14 and is in contact with the positive electrode active material layer 12 and the negative electrode active material layer 14 .

[0089] The solid electrolyte layer 15 includes at least a solid electrolyte. The solid electrolyte layer 15 includes, for example, a solid electrolyte as a main component. The solid electrolyte may be any known solid electrolyte for batteries that does not have electronic conductivity but has ionic conductivity. For example, a solid electrolyte that conducts metal ions such as lithium ions or magnesium ions may be used. The type of solid electrolyte may be selected appropriately depending on the type of conductive ions. For example, an inorganic solid electrolyte such as a sulfide-based solid electrolyte or an oxide-based solid electrolyte may be used. For example, a lithium-containing sulfide such as a Li2S-P2S5-based, Li2S-SiS2-based, Li2S-B2S3-based, Li2S-GeS2-based, Li2S-SiS2-LiI-based, Li2S-SiS2-Li3PO4-based, Li2S-Ge2S2-based, Li2S-GeS2-P2S5-based, or Li2S-GeS2-ZnS-based solid electrolyte may be used as the sulfide-based solid electrolyte. Examples of oxide-based solid electrolytes include lithium-containing metal oxides such as Li2O-SiO2 and Li2O-SiO2-P2O5; x P y O 1-z N z Lithium-containing metal nitrides such as lithium phosphate (LiPO), lithium-containing transition metal oxides such as lithium titanium oxide, etc. As the solid electrolyte, only one of these materials may be used, or two or more of these materials may be used in combination.

[0090] In addition to the solid electrolyte, the solid electrolyte layer 15 may contain a binder such as polyethylene oxide or polyvinylidene fluoride.

[0091] The thickness of the solid electrolyte layer 15 is, for example, not less than 5 μm and not more than 150 μm.

[0092] The solid electrolyte material may be composed of an aggregate of particles or a sintered structure.

[0093] The above-described configuration of the battery 100 makes it possible to realize an all-solid-state battery with excellent performance that can suppress the occurrence of deformation such as warping.

[0094] [Battery manufacturing method] Next, an example of a method for manufacturing the battery 100 according to this embodiment will be described.

[0095] The method for manufacturing the battery 100 includes, for example, a preparation step, a pressing step, a peeling step, and a cutting step. Fig. 3 is a flowchart of the method for manufacturing the battery 100 according to this embodiment.

[0096] (1) Preparation process First, a preparation step is performed in the manufacturing method of the battery 100. As shown in Fig. 3, in the preparation step, a power generating element 30 is prepared in which a positive electrode current collector 11 containing a first metal, a positive electrode active material layer 12, a solid electrolyte layer 15, a negative electrode active material layer 14, and a negative electrode current collector 13 containing a second metal harder than the first metal are laminated in this order (step S11).

[0097] In the preparation step, for example, the power generating element 30 is prepared by laminating a positive electrode current collector 11, a positive electrode active material layer 12, a solid electrolyte layer 15, a negative electrode active material layer 14, and a negative electrode current collector 13 to form the power generating element 30. Specifically, first, pastes to be used for printing the positive electrode active material layer 12 and the negative electrode active material layer 14 are prepared. As the solid electrolyte raw material to be used for the mixture of the positive electrode active material layer 12 and the negative electrode active material layer 14, for example, a glass powder of Li2S-P2S5-based sulfide having an average particle size of about 10 μm and containing triclinic crystals as the main component is prepared. This glass powder may have a density of, for example, 2 to 3 × 10 -3 A glass powder having a high ionic conductivity of about 1000 s / cm can be used as the positive electrode active material. For example, a Li·Ni·Co·Al composite oxide (LiNi 0.8 Co 0.15 Al 0.05A powder of O2) is used. A paste for a positive electrode active material layer is prepared by dispersing a mixture containing the above-mentioned positive electrode active material and the above-mentioned glass powder in an organic solvent or the like. In addition, as the negative electrode active material, for example, a powder of natural graphite having an average particle size of about 10 μm is used. Similarly, a paste for a negative electrode active material layer is prepared by dispersing a mixture containing the above-mentioned negative electrode active material and the above-mentioned glass powder in an organic solvent or the like.

[0098] Next, for example, aluminum foil with a thickness of approximately 30 μm is prepared as the material used for the positive electrode current collector 11. Furthermore, for example, copper foil with a thickness of approximately 30 μm is prepared as the material used for the negative electrode current collector 13. For example, foils with one surface roughened are used as the aluminum foil and copper foil. A paste for the positive electrode active material layer and a paste for the negative electrode active material layer are printed by screen printing onto one surface of each foil, for example, the roughened surface, in a predetermined shape and with a thickness of approximately 50 μm to 100 μm. The paste for the positive electrode active material layer and the paste for the negative electrode active material layer are dried at 80°C to 130°C to a thickness of 30 μm to 60 μm. This results in a current collector having a positive electrode active material layer 12 and a negative electrode active material layer 14 formed on the roughened surface, respectively. Hereinafter, the positive electrode current collector 11 on which the positive electrode active material layer 12 is formed may be referred to as the "positive electrode layer," and the negative electrode current collector 13 on which the negative electrode active material layer 14 is formed may be referred to as the "negative electrode layer."

[0099] Next, a paste for a solid electrolyte layer is prepared by dispersing a mixture containing the glass powder of the solid electrolyte raw material in an organic solvent or the like. The paste for a solid electrolyte layer is printed, for example, to a thickness of about 100 μm on the surfaces of the active material layers of the positive electrode layer and the negative electrode layer using a metal mask. Thereafter, the positive electrode layer and the negative electrode layer on which the paste for a solid electrolyte layer is printed are dried at a temperature of 80° C. or higher and 130° C. or lower.

[0100] Next, the solid electrolyte layer 15 printed on the positive electrode active material layer 12 of the positive electrode layer and the solid electrolyte layer 15 printed on the negative electrode active material layer 14 of the negative electrode layer are laminated so as to contact and face each other. This forms a power generating element 30 in which the positive electrode current collector 11, the positive electrode active material layer 12, the solid electrolyte layer 15, the negative electrode active material layer 14, and the negative electrode current collector 13 are laminated in this order.

[0101] In the preparation step, the power generating element 30 may be formed by a method different from those described above, as long as the power generating element 30 is prepared by laminating the positive electrode current collector 11, the positive electrode active material layer 12, the solid electrolyte layer 15, the negative electrode active material layer 14, and the negative electrode current collector 13 in this order. For example, the power generating element 30 may be formed by sequentially laminating the positive electrode current collector 11, the positive electrode active material layer 12, the solid electrolyte layer 15, the negative electrode active material layer 14, and the negative electrode current collector 13 in this order.

[0102] (2) Pressing process Next, in the manufacturing method of the battery 100, a pressing step is performed. FIG. 4A is a schematic diagram illustrating the pressing step in the manufacturing method of the battery 100. FIG. 4A illustrates a state immediately before pressing the power generating element 30 via the plate-shaped member 18. FIG. 4B is a schematic diagram illustrating the plate-shaped member 18 and the positive electrode current collector 11 at the initial stage of pressing in the pressing step in the manufacturing method of the battery 100. FIG. 4C is a schematic diagram illustrating the plate-shaped member 18 and the positive electrode current collector 11 after pressing in the pressing step in the manufacturing method of the battery 100. FIGS. 4B and 4C are enlarged cross-sectional views illustrating the vicinity of the contact interface between the positive electrode current collector 11 and the plate-shaped member 18. As shown in FIGS. 3 and 4A, in the pressing step, the power generating element 30 is pressed via the plate-shaped member 18, which has a roughened surface 18a and is made of a first material harder than the first metal (step S12). In the pressing step, the roughened surface 18a of the plate-shaped member 18 is brought into contact with the main surface of the positive electrode current collector 11, and the power generating element 30 is pressed. As a result, the power generating element 30 is pressed while the positive electrode current collector 11 is restrained by the plate-like member 18, as will be described in detail later.

[0103] The plate-shaped member 18 is a metal foil or metal plate made of a metal harder than the first metal, the surface of which has been roughened by, for example, a known mechanical, physical, electrochemical, or chemical roughening treatment. The plate-shaped member 18 is not particularly limited as long as it is made of a first material harder than the first metal and has a roughened surface 18a. The plate-shaped member 18 may be a relatively thin foil, for example, approximately 5 μm to 100 μm thick, or a relatively thick plate, for example, 100 μm or thicker. In addition, the size of the plate-shaped member 18 in a plan view is, for example, equal to or larger than the size of the positive electrode current collector 11. Both surfaces of the plate-shaped member 18 may be roughened. For example, if the surface that comes into contact with the pressing surface of the pressing member during pressing, as described below, is roughened, friction with the pressing surface increases, thereby further enhancing the effect of restraining the positive electrode current collector 11.

[0104] Specifically, in the pressing step, first, a copper foil having one surface 18a roughened is prepared as plate-like member 18 for restraining positive electrode current collector 11. The copper foil may be the same as the copper foil used for negative electrode current collector 13. This makes plate-like member 18 and negative electrode current collector 13 the same in thickness and hardness, effectively suppressing the occurrence of warpage, which will be described later.

[0105] 4A, the plate-shaped member 18 is placed on the power generating element 30 so that the roughened surface 18a of the plate-shaped member 18 contacts the main surface 11a of the positive current collector 11 of the power generating element 30. At this time, for example, the plate-shaped member 18 is placed so that it completely covers the outer periphery of the positive current collector 11 in a plan view. In other words, the roughened surface 18a contacts the entire main surface 11a of the positive current collector 11. This allows the plate-shaped member 18 to effectively suppress outward elongation and deformation of the positive current collector 11. The suppression of elongation of the positive current collector 11 will be described in detail below.

[0106] Next, the power generating element 30 on which the plate-like member 18 is placed is placed between the upper and lower pressing mold plates 40, for example, in an orientation such that the plate-like member 18 is placed on the upper side of the power generating element 30. For example, a sheet having an elastic modulus of 5×10 is placed between the plate-like member 18 and the upper pressing mold plate 40.6 An elastic sheet 41 having a pressure of about 100 Pa and a thickness of 50 μm to 100 μm is inserted, and the elastic sheet 41 is placed so as to be in contact with the plate-like member 18. The pressure mold plate 40 and the elastic sheet 41 are an example of a pressing member. Thus, in the pressing process, the plate-like member 18 is pressed so as to be in contact with the elastic sheet 41. The pressing member is a member used for press processing, and is, for example, a dedicated member used for pressing that is different from the material constituting the battery 100. The plate-like member 18 is pressed in direct contact with the elastic sheet 41, and the pressing force is transmitted directly to the plate-like member 18.

[0107] The elastic sheet 41 may be embossed so that the surface of the elastic sheet 41 that comes into contact with the plate-like member 18 has a surface roughness Rz of approximately 1 μm or more and 10 μm or less. As described above, the surface of the plate-like member 18 that comes into contact with the elastic sheet 41 may be roughened. By roughening the surfaces of the elastic sheet 41 and the plate-like member 18 that come into contact with each other in this manner, the air discharge properties at the interface between the elastic sheet 41 and the plate-like member 18 are improved. Remaining air at the interface between the elastic sheet 41 and the plate-like member 18 is suppressed, and the adhesion between the elastic sheet 41 and the plate-like member 18 is also improved, resulting in a stronger restraining effect.

[0108] Then, the power generating element 30 on which the plate-like member 18 is placed is pressurized using the upper and lower pressure mold plates 40 for approximately 90 seconds while heating at a temperature of 50°C to 80°C under a pressure of 300 MPa to 350 MPa.

[0109] In this pressing process, as shown in FIG. 4B , when pressing begins, multiple protrusions 16 a on the roughened surface 18 a of plate-shaped member 18 made of a first material harder than the first metal dig into the main surface 11 a of positive current collector 11, and the multiple protrusions 16 a are embedded in positive current collector 11. Because positive current collector 11 is softer than negative current collector 13, it is more likely to stretch in a direction perpendicular to the thickness direction due to the pressure of the press than negative current collector 13. However, because multiple protrusions 16 a of plate-shaped member 18 dig into positive current collector 11, they restrain positive current collector 11, preventing the positive current collector 11 from elongating. Therefore, even when the pressure is released after pressing, there is little difference between the elongation of positive current collector 11 due to the pressure of the press and the elongation of negative current collector 13. If the difference between the elongation of the positive electrode current collector 11 and the elongation of the negative electrode current collector 13 becomes large, warping will occur, but since the difference is unlikely to occur, the occurrence of warping is suppressed.

[0110] The surface roughness Rz of the roughened surface 18a is, for example, within a range smaller than the thickness of the positive electrode current collector 11, thereby achieving a sufficient restraint effect. Furthermore, the surface roughness Rz of the surface 18a is within a range smaller than the thickness of the positive electrode current collector 11, thereby preventing damage to the positive electrode current collector 11 during pressing. Specifically, the surface roughness Rz of the surface 18a is, for example, 1 μm or more and 10 μm or less. This allows the positive electrode current collector 11 to be effectively restrained by the plate-like member 18 while preventing damage to the positive electrode current collector 11 during pressing.

[0111] Furthermore, the surface of front surface 18a is rougher than, for example, main surface 11a of positive electrode current collector 11 that comes into contact with front surface 18a in the pressing process. This makes it easier for protrusions 16a of plate-shaped member 18 to bite into main surface 11a of positive electrode current collector 11.

[0112] In the present embodiment, for example, the thermal expansion coefficient of the first material constituting plate-shaped member 18 is smaller than the thermal expansion coefficient of the first metal. As a result, even when heated and pressed, plate-shaped member 18 has a smaller amount of thermal expansion than positive electrode current collector 11 containing the first metal, and the effect of plate-shaped member 18 in restraining positive electrode current collector 11 can be enhanced.

[0113] Furthermore, the difference in hardness between the first material and the second metal may be, for example, 20% or less, or the hardness of the first material may be the same as the hardness of the second metal. The hardness may be, for example, Young's modulus. This reduces the difference between the elongation of the plate-like member 18 due to the pressure of the press and the elongation of the negative electrode current collector 13, thereby reducing the difference between the elongation of the positive electrode current collector 11 restrained by the plate-like member 18 and the elongation of the negative electrode current collector 13.

[0114] As described above, the first material may include or be made of, for example, the second metal. This reduces the difference in hardness between the plate-shaped member 18 and the negative electrode current collector 13, thereby reducing the difference in elongation between the positive electrode current collector 11 restrained by the plate-shaped member 18 and the negative electrode current collector 13.

[0115] Furthermore, the difference in thickness between the plate-shaped member 18 and the negative electrode current collector 13 is, for example, 20% or less, and the plate-shaped member 18 and the negative electrode current collector 13 may be the same thickness. This reduces the difference between the elongation of the plate-shaped member 18 due to the pressure of the press and the elongation of the negative electrode current collector 13, and as a result, reduces the difference between the elongation of the positive electrode current collector 11 restrained by the plate-shaped member 18 and the elongation of the negative electrode current collector 13.

[0116] The shape of the protrusions 16a is not particularly limited, and may be, for example, any of the shapes exemplified for the shape of the deposit 16 described above.

[0117] As described above, during pressing, the contact interface between the positive electrode current collector 11 and the plate-shaped member 18 is in a state in which the multiple protrusions 16a of the plate-shaped member 18 are embedded in the main surface 11a of the positive electrode current collector 11. At the end of pressing, as shown in FIG. 4C , cracks 19 are generated at locations where the ductility limits of the positive electrode current collector 11 and the plate-shaped member 18 have been exceeded due to the high pressure applied during pressing. Specifically, during pressing, the plate-shaped member 18 suppresses the elongation of the positive electrode current collector 11, and layered cracks 19 with widths of, for example, approximately 0.1 μm to 3 μm are formed around the contact interface between the positive electrode current collector 11 and the plate-shaped member 18 in locations where the ductility limit is locally exceeded, as schematically shown in FIG. 4C . In general, the harder a material is, the lower its ductility limit is. For this reason, the first material is more susceptible to cracking than the first metal (i.e., the positive electrode current collector 11), which is softer than the first material (i.e., the plate-shaped member 18). Therefore, the number and degree of cracks 19 that occur correspond to the difference in hardness between the positive electrode current collector 11 and the plate-like member 18, with the relationship being: hard plate-like member 18 > soft positive electrode current collector 11. When such layered cracks 19 are formed near the surface 18a of the plate-like member 18, the multiple protrusions 16a are separated from the plate-like member 18 and become multiple deposits 16 embedded in the positive electrode current collector 11.

[0118] (3) Peeling process Next, in the manufacturing method of the battery 100, a peeling step is performed. As shown in Fig. 3, in the peeling step, after the pressing step, the plate-shaped member 18 is peeled off from the power-generating element 30 pressed in the pressing step (step S13). Specifically, the plate-shaped member 18 is carefully peeled off from a corner of the power-generating element 30 in a plan view, thereby peeling off the plate-shaped member 18 and the positive electrode current collector 11. By peeling the plate-shaped member 18 from the corner in a diagonal direction, the power-generating element 30 can be removed without damage, with fine cracks 19 near the contact interface between the positive electrode current collector 11 and the plate-shaped member 18 shown in Fig. 4C serving as the main peeling surface. After pressing, the multiple protrusions 16a on the surface 18a of the plate-like member 18 bite into the main surface 11a of the positive electrode current collector 11 and remain as multiple deposits 16 made of the first material that is harder than the first metal, and the multiple deposits 16 are fixed to the main surface 11a of the positive electrode current collector 11. Furthermore, cracks 19 may also remain near the main surface 11a of the positive electrode current collector 11.

[0119] As described above, the first material may contain or be made of, for example, a metal, which makes it less likely to impede electrical conduction in the positive electrode current collector 11 even if the protrusions 16a remain on the positive electrode current collector 11 as deposits 16.

[0120] By peeling off the plate-like members 18 in the peeling step, the plate-like members 18 that do not contribute to power generation are removed, and therefore the volumetric energy density of the battery 100 can be increased.

[0121] 2, convex portions formed by the plurality of attachments 16 and concave portions exposing the main surface 11a of the positive electrode current collector 11 are formed on the main surface 11a of the positive electrode current collector 11 to which the plurality of attachments 16 are attached. Although a small amount of layered cracks 19 may also be contained in the positive electrode current collector 11, structurally weaker portions of the positive electrode current collector 11 are peeled off together with the plate-like member 18, and therefore, portions that are not peeled off and remain in a strong state remain.

[0122] (4) Cutting process Next, in the manufacturing method of the battery 100, a cutting step is performed. As shown in FIG. 3, in the cutting step, after the pressing step, the power generating element 30 is cut (step S14). Specifically, in the cutting step, the power generating element 30 is heated to a temperature of approximately 50°C to 100°C, and then, with the positive electrode current collector 11 facing up, the vicinity of the four outer edges is cut off vertically from above along each edge using a cutter blade. This results in the battery 100. This cutting step removes the outer periphery of the pressed power generating element 30, which is prone to distortion and deformation, and therefore, a battery 100 with reduced warping and high shape accuracy can be obtained in any shape. Furthermore, if the size of the power generating element 30 prepared in the preparation step is increased, a large number of batteries with highly accurate shapes can be manufactured through a series of manufacturing steps.

[0123] In the cutting step, the attachment 16 is partially exposed on the cut surface, which is the side wall of the battery 100. The exposed attachment 16 is, for example, the attachment 16 that was cut in the cutting step, and may include components of the attachment 16 that extended downward during cutting.

[0124] The uneven structure of the main surface 11a of the positive current collector 11, to which the multiple deposits 16 are attached, distributes and reduces the difference in thermal expansion stress between the positive current collector 11 and the negative current collector 13, improving durability against temperature changes and suppressing warping and structural defects in the power generating element 30. For this reason, cutting is typically performed while heating. Power generating elements that warp upon heating and subsequent cooling are prone to breakage during cutting. However, the manufacturing method of this embodiment can also alleviate this problem. Furthermore, a configuration in which the hard deposits 16 are attached to the upper side of the cut surface, i.e., the main surface 11a of the positive current collector 11, is harder than a configuration in which only the positive current collector 11 contains a soft first metal. This suppresses elongation of the positive current collector 11 along the cut surface. Furthermore, the amount of cutting debris generated by the elongated portion being separated is reduced, thereby suppressing the occurrence of short circuits and enabling a highly reliable battery 100 to be obtained.

[0125] Furthermore, by stacking the thus obtained battery 100, which is a single cell, a stacked battery with a high voltage and / or large capacity can be realized. The stacked battery will be described in detail later.

[0126] The method and order of forming the battery 100 are not limited to the above example. In the above manufacturing method, an example is shown in which the paste for the positive electrode active material layer, the paste for the negative electrode active material layer, and the paste for the solid electrolyte layer are applied by printing, but the method is not limited to this. Examples of printing methods that may be used include doctor blade, calendar, spin coating, dip coating, inkjet, offset, die coating, and spraying.

[0127] Furthermore, in the above-described pressing step, after inserting the elastic sheet 41, pressure is applied using the pressure mold plate 40, but the pressing method is not limited to this. For example, the power generating element 30 and the plate-like member 18 may be pressed with the pressure mold plate 40 without inserting the elastic sheet 41, or the elastic sheet 41 may be attached to the surface of the pressure mold plate 40 and then pressed. Furthermore, the pressing method is not limited to flat plate pressing using the pressure mold plate 40, and other pressing methods such as roll pressing may also be used.

[0128] Furthermore, at least one of the peeling step and the cutting step may not be performed.

[0129] Comparing the configuration and manufacturing method of the battery 100 according to the present embodiment as described above with the configurations and manufacturing methods of the batteries described in Patent Documents 1 and 2, there are the following differences.

[0130] Patent Document 1 discloses a stacked battery in which multiple all-solid-state batteries are arranged one above the other and pressed together. However, by roughening the current collectors, the upper and lower cells are connected by partially fitting together while forming gaps at the bonding interface. This differs from the configuration of battery 100, which has a rough, uneven surface structure in which multiple deposits 16 harder than the first metal are attached in an island-like manner to the main surface 11a of positive electrode current collector 11 made of a first metal. Furthermore, battery 100 does not require the main surface of negative electrode current collector 13 opposite to the negative electrode active material layer 14 to be roughened.

[0131] As described above, Patent Document 1 does not disclose the relationship between the hardness of the current collector of battery 100 and the configuration related to the characteristics of the current collector's main surface. Therefore, Patent Document 1 does not provide a restraining effect to suppress elongation of the current collector during pressing in the manufacturing method of battery 100 when pressurizing the unit cells. Furthermore, it does not provide the effects of suppressing short circuits and improving durability against thermal cycling, as with battery 100. Therefore, the technology disclosed in Patent Document 1 is prone to warping and other deformations and structural defects in thinner and / or larger batteries, which can easily result in short circuits and durability issues against thermal cycling. Therefore, it is clear that stacking unit cells and pressing them together as in Patent Document 1 does not provide the effects of the present embodiment.

[0132] Furthermore, Patent Document 2 discloses the roughness of the main surface of the current collector opposite the active material layer side, but the current collectors connected by pressure from above and below have the same polarity and are made of the same material. Furthermore, there is no mention of a configuration in which multiple hard deposits 16 are attached to the main surface 11a of the positive electrode current collector 11. Even if such single-material current collectors are stacked and pressurized, the upper and lower current collectors simply stretch and deform toward the periphery, and the current collector restraint effect, which is an advantage of the manufacturing method of the battery 100 of this embodiment, is not achieved. Furthermore, because no hard deposits are attached to the current collectors, the effects of improving resistance to short circuits caused by processing burrs and thermal cycling are not achieved. Furthermore, only parallel-connected stacked batteries can be constructed.

[0133] In contrast to these, a battery 100 including a power generating element 30 in which a positive electrode current collector 11 including a first metal, a positive electrode active material layer 12, a solid electrolyte layer 15, a negative electrode active material layer 14, and a negative electrode current collector 13 including a second metal harder than the first metal are stacked in this order, and a plurality of attachments 16 made of a first material harder than the first metal, and a manufacturing method thereof, suppresses elongation and burr formation in the positive electrode current collector 11 during manufacturing of the battery 100, and improves durability of the battery 100 against thermal cycles, so it is clear that the above-mentioned problems do not occur. Furthermore, Patent Documents 1 and 2 do not disclose or suggest the battery 100 including a power generating element 30 in which a positive electrode current collector 11 including a second metal, a positive electrode active material layer 12, a solid electrolyte layer 15, a negative electrode active material layer 14, and a negative electrode current collector 13 including a second metal harder than the first metal are stacked in this order, and a plurality of attachments 16, as described in the present embodiment.

[0134] [Variation 1] The following describes Modification 1 of the embodiment. In the following description of Modification 1, differences from the embodiment will be mainly described, and descriptions of commonalities will be omitted or simplified.

[0135] Figure 5 is a cross-sectional view and a plan view showing a schematic configuration of a battery according to Modification 1 of the embodiment. Specifically, Figure 5(a) is a cross-sectional view of a battery 110 according to the present embodiment, and Figure 5(b) is a plan view of the battery 110 as seen from above in the z-axis direction. Figure 5(a) shows a cross section taken along line Va-Va in Figure 5(b).

[0136] As shown in Fig. 5, battery 110 according to the first modification of the embodiment differs from battery 100 according to the embodiment in that power generating element 30 is not a single cell, but a stacked battery in which cells 100, which are cells, are connected in series one above the other. As in the first embodiment, multiple attachments 16 are attached to main surface 11a of positive electrode current collector 11, but are not shown in Fig. 5 because they are so small. In this modification, the configuration of multiple attachments 16 is the same as in the first embodiment.

[0137] The battery 110 includes a plurality of batteries 100 and a conductive connection layer 17 located between adjacent batteries 100 of the plurality of batteries 100. The battery 110 has a structure in which the plurality of batteries 100 are stacked. The plurality of batteries 100 are stacked so that the top and bottom of the batteries 100 are oriented in the same direction. The number of batteries 100 included in the battery 110 is two in the illustrated example, but may be three or more.

[0138] In adjacent batteries 100, the smooth main surface of the negative electrode current collector 13, which is the negative electrode of the upper battery 100, is electrically connected to and fixed via a connecting layer 17 to the main surface 11a of the positive electrode current collector 11, which is the positive electrode of the lower battery 100 and has a plurality of attachments 16 attached thereto, thereby forming a so-called bipolar electrode structure.

[0139] The connection layer 17 connecting adjacent batteries 100 in the vertical direction is made of, for example, a conductive resin. The material of the connection layer 17 is not limited to conductive resin, as long as it can ensure electrical connection between adjacent batteries 100 and strength for handling. The material of the connection layer 17 may be, for example, a conductor such as solder, or may be a conductive tape if the application does not require a certain degree of conductivity. Furthermore, adjacent batteries 100 may be directly connected by bonding, welding, or the like, without the connection layer 17 interposed therebetween.

[0140] By connecting a plurality of the above-described batteries 100 in series in this configuration, a high-voltage, high-energy stacked battery 110 that can suppress deformation such as warping can be realized.

[0141] Next, a method for manufacturing the battery 110 will be described.

[0142] In manufacturing the battery 110, first, a plurality of batteries 100 obtained by the manufacturing method of the battery 100 according to the first embodiment are prepared. Next, a thermosetting conductor paste containing silver particles, which is a conductive resin, is applied by screen printing to a thickness of about 5 μm as a connection layer 17 on the main surface 11a of the positive electrode current collector 11 of the lower battery 100 to which the plurality of attachments 16 are attached. Then, the upper battery 100 is placed on the lower battery 100 so that the negative electrode current collector 13 of the upper battery 100 is in contact with the connection layer 17 to form a series connection. Then, a pressure of about 10 kg / cm is applied. 2 At this time, the bumpy structure of the main surface 11a of the positive electrode current collector 11 to which the multiple attachments 16 are attached increases the bonding area with the connection layer 17, thereby obtaining high bonding strength. Furthermore, if cracks 19 are formed in the positive electrode current collector 11, high bonding strength can also be obtained due to the anchor effect of the conductive resin component that has penetrated into the cracks 19. To increase the number of series connections, this process is repeated for the number of batteries 100 to be multi-layered. After this, the upper battery 100 and the lower battery 100 are pressed together at a pressure of, for example, about 1 kg / cm 2 While the paste is held stationary under a pressure of 0.1 MPa, it is subjected to a heat curing treatment at approximately 100°C to 130°C for 40 to 100 minutes, and then slowly cooled to room temperature. In this way, a multilayered battery 110 is obtained. The conductive resin used in the conductor paste can be selected from conductive resins with a curing temperature and conductive particles appropriate for the purpose. For example, when forming a thin coating film, a conductive resin containing conductive particles such as fine silver particles or a conductive resin containing scaly conductive particles can be used. Furthermore, a conductive resin containing a low-melting-point metal can be used to form an alloy with the current collector during heat curing.

[0143] In the above-described manufacturing method, a thermosetting conductive paste containing silver metal particles is used as an example of the conductive paste, but this is not limited thereto. The conductive paste may be a thermosetting conductive paste containing high-melting-point highly conductive metal particles, low-melting-point metal particles, and a resin. The melting point of the high-melting-point highly conductive metal particles is, for example, 400°C or higher. The melting point of the low-melting-point metal particles is below the hardening temperature of the conductive paste, for example, 300°C or lower. Examples of materials for the high-melting-point highly conductive metal particles include silver, copper, nickel, zinc, aluminum, palladium, gold, platinum, and alloys of these metals. Examples of materials for low-melting-point metal particles with a melting point of 300°C or less include tin, tin-zinc alloy, tin-silver alloy, tin-copper alloy, tin-aluminum alloy, tin-lead alloy, indium, indium-silver alloy, indium-zinc alloy, indium-tin alloy, bismuth, bismuth-silver alloy, bismuth-nickel alloy, bismuth-tin alloy, bismuth-zinc alloy, and bismuth-lead alloy. By using a conductive paste containing such low-melting-point metal particles, solid- and liquid-phase reactions occur at the contact points between the metal particles in the conductive paste and the metal constituting the current collector, even at curing temperatures lower than the melting point of the high-melting-point highly conductive metal particles. As a result, a diffusion region formed by solid- and liquid-phase reactions is formed around the contact points at the interface between the conductive paste and the main surface of the current collector. An example of the alloy formed is a highly conductive silver-copper alloy when silver or a silver alloy is used for the conductive metal particles and copper is used for the current collector. Furthermore, by combining conductive metal particles with a current collector, a silver-nickel alloy or a silver-palladium alloy can be formed. This configuration provides an effect of more firmly bonding the conductive paste and the current collector, for example, of suppressing peeling of the bonded portion between the connection layer 17 and the current collector due to thermal cycling or impact.

[0144] The shapes of the high-melting-point highly conductive metal particles and the low-melting-point metal particles may be any shape, such as spherical, scaly, or needle-like. The particle sizes of the high-melting-point highly conductive metal particles and the low-melting-point metal particles are not particularly limited. For example, the smaller the particle size, the more the alloy reaction and diffusion proceed at low temperatures. Therefore, the particle size and shape are appropriately selected taking into account the process design and the influence of thermal history on battery characteristics.

[0145] The resin used in the thermosetting conductive paste may be any resin that functions as a binder for bonding, and may be selected appropriately depending on the manufacturing process to be employed, such as printability and applicability. Examples of resins used in the thermosetting conductive paste include thermosetting resins. Examples of thermosetting resins include: (i) amino resins such as urea resins, melamine resins, and guanamine resins; (ii) epoxy resins such as bisphenol A, bisphenol F, phenol novolac, and alicyclic epoxy resins; (iii) oxetane resins; (iv) phenolic resins such as resol and novolac resins; and (v) silicone-modified organic resins such as silicone epoxy and silicone polyester. Only one of these materials may be used as the resin, or two or more of these materials may be used in combination.

[0146] [Variation 2] The following describes Modification 2 of the embodiment. In the following description of Modification 2, differences from the embodiment and Modification 1 of the embodiment will be mainly described, and descriptions of commonalities will be omitted or simplified.

[0147] Figure 6 is a cross-sectional view and a plan view showing a schematic configuration of a battery according to Modification 2 of the embodiment. Specifically, Figure 6(a) is a cross-sectional view of a battery 120 according to the present embodiment, and Figure 6(b) is a plan view of the battery 120 as seen from above in the z-axis direction. Figure 6(a) shows a cross section taken along line VIa-VIa in Figure 6(b).

[0148] As shown in FIG. 6, the battery 120 according to the second modification of the embodiment differs from the battery 110 according to the first modification in that the orientation of the upper battery 100 is reversed. As a result, in the battery 110, the plurality of batteries 100 are connected with the same polarity, i.e., with the positive electrodes facing each other in the example of FIG. 6, forming a stacked battery connected in parallel. Note that, as in the first embodiment, a plurality of attachments 16 are attached to the main surface 11a of the positive electrode current collector 11; however, in FIG. 6, the plurality of attachments 16 are not shown because they are so small. In this modification, the configuration of the plurality of attachments 16 is the same as in the first embodiment.

[0149] The battery 120 includes a plurality of batteries 100 and a conductive connection layer 17 located between adjacent batteries 100 of the plurality of batteries 100. The battery 120 has a structure in which a plurality of batteries 100 are stacked. The plurality of batteries 100 are stacked with the top and bottom orientations of the batteries 100 alternately reversed in the stacking order. The number of batteries 100 included in the battery 120 is two in the illustrated example, but may be three or more.

[0150] The vertically adjacent batteries 100 are electrically connected and fixed together via the connection layer 17 at the main surfaces 11a of the positive electrode current collectors 11 to which the plurality of attachments 16 are attached.

[0151] In this way, a parallel connection can be achieved by connecting the same polarities of vertically adjacent batteries 100 facing each other. For example, the positive electrode can be drawn out using a conductor inserted into the connection interface of vertically adjacent batteries 100, such as a lead made of copper or aluminum foil used for the current collector, or a lead terminal made of a current collector formed in the outer region of the battery 100.

[0152] With this configuration, by connecting a plurality of the above-described batteries 100 in parallel, it is possible to realize a large-capacity stacked battery 120 that can suppress deformation such as warping.

[0153] Battery 120 can be manufactured using the same method as battery 110, except that, for example, when stacking multiple batteries 100, they are oriented so that they can be connected in parallel.

[0154] The negative electrode current collectors 13 of adjacent batteries 100 in the vertical direction may be connected to each other via a connection layer 17 .

[0155] [Variation 3] The following describes Modification 3 of the embodiment. In the following description of Modification 3, differences from the embodiment will be mainly described, and descriptions of commonalities will be omitted or simplified.

[0156] Fig. 7 is a cross-sectional view and a plan view showing a schematic configuration of a battery according to Modification 3 of the embodiment. Specifically, Fig. 7(a) is a cross-sectional view of a battery 130 according to the present embodiment, and Fig. 7(b) is a plan view of the battery 130 as seen from above in the z-axis direction. Fig. 7(a) shows a cross section taken along line VIIa-VIIa in Fig. 7(b).

[0157] As shown in Fig. 7, battery 130 according to the third modification of the embodiment differs from battery 100 according to the embodiment in that plate-like member 18 made of the first material is integrated into and in contact with positive electrode current collector 11. As in the first embodiment, multiple attachments 16 are attached to main surface 11a of positive electrode current collector 11; however, in Fig. 7, multiple attachments 16 are not shown because they are so small. In this modification, the configuration of multiple attachments 16 is the same as in the first embodiment.

[0158] The battery 130 has a configuration in which the plate-shaped member 18 is not peeled off but remains as part of the current collector. That is, in addition to the configuration of the battery 100, the battery 130 includes a plate-shaped member 18 in contact with the main surface 11a of the positive electrode current collector 11 opposite the positive electrode active material layer 12. The battery 130 is, for example, a battery obtained by manufacturing a battery without performing the peeling step in the manufacturing method of the battery 100 described above. In this modification, the first material constituting the plate-shaped member 18 is made of a conductive material such as a metal. As described above, the first material may contain a second metal as a main component or may be made of the second metal.

[0159] As described with reference to FIG. 4C in the description of the manufacturing method of the battery 100 according to the above embodiment, the bonding interface between the positive electrode current collector 11 and the plate-shaped member 18 is in a state in which a plurality of deposits 16 originating from the plate-shaped member 18 are embedded in the main surface 11a of the positive electrode current collector 11. In addition, cracks 19 are formed in the positive electrode current collector 11 and the plate-shaped member 18 due to the pressure applied during pressing. The formation of these cracks 19 allows the plate-shaped member 18 and the positive electrode current collector 11 to absorb stress caused by temperature changes and stress.

[0160] This configuration also makes it possible to realize a highly reliable battery 130 that can suppress deformation such as warping. Furthermore, during processing such as cutting, the battery 130 functions as a support for the soft positive electrode current collector 11, thereby reducing cracks during handling and suppressing short circuits.

[0161] [Variation 4] The following describes Modification 4 of the embodiment. In the following description of Modification 4, differences between the embodiment and Modifications 1 to 3 of the embodiment will be mainly described, and descriptions of commonalities will be omitted or simplified.

[0162] Fig. 8 is a cross-sectional view and a plan view showing a schematic configuration of a battery according to Modification 4 of the embodiment. Specifically, Fig. 8(a) is a cross-sectional view of a battery 140 according to the present embodiment, and Fig. 8(b) is a plan view of the battery 140 as seen from above in the z-axis direction. Fig. 8(a) shows a cross section taken along line VIIIa-VIIIa in Fig. 8(b).

[0163] As shown in Fig. 8, the battery 140 according to the fourth modification is different from the battery 130 according to the third modification in that the power generating element 30 is not a single cell, but is a battery in which the cells 130 are connected in series one above the other. As in the first embodiment, a plurality of attachments 16 are attached to the main surface 11a of the positive electrode current collector 11, but in Fig. 8, the plurality of attachments 16 are not shown because they are so small. In this modification, the form of the plurality of attachments 16 is the same as in the first embodiment.

[0164] The battery 140 includes a plurality of batteries 130 and a conductive connection layer 17 located between adjacent batteries 130 of the plurality of batteries 130. The battery 140 has a structure in which the plurality of batteries 130 are stacked. The plurality of batteries 130 are stacked so that the top and bottom of the batteries 130 are oriented in the same direction. The battery 140 is configured as a stacked battery in which the batteries 130 according to Modification 3 are connected in series in the same arrangement and connection as in Modification 1. Specifically, in vertically adjacent batteries 130, the surface of the plate-like member 18 on the positive electrode current collector 11 of the lower battery 130 is electrically connected and fixed to the main surface of the negative electrode current collector 13 of the upper battery 130 via the connection layer 17.

[0165] With such a structure, a high-voltage, high-energy stacked battery 140 that can suppress deformation such as warping can be realized.

[0166] The plurality of batteries 130 may be stacked as stacked batteries connected in parallel in the same arrangement and connection as in the second modification.

[0167] [Variation 5] The following describes Modification 5 of the embodiment. In the following description of Modification 5, differences between the embodiment and Modifications 1 to 4 of the embodiment will be mainly described, and descriptions of commonalities will be omitted or simplified.

[0168] Fig. 9 is a cross-sectional view and a plan view showing a schematic configuration of a battery according to Modification 5 of the embodiment. Specifically, Fig. 9(a) is a cross-sectional view of a battery 150 according to the present embodiment, and Fig. 9(b) is a plan view of the battery 150 as seen from above in the z-axis direction. Fig. 9(a) shows a cross section taken along line IXa-IXa in Fig. 9(b).

[0169] As shown in FIG. 9, the battery 150 according to the fifth variation of the embodiment differs from the battery 100 according to the embodiment in that it includes a power generating element 31 having a positive electrode current collector 21 on which a step 22 is formed, instead of the power generating element 30 having a positive electrode current collector 11.

[0170] The same attachments 16 as in the first embodiment are attached to the main surface 21a of the positive electrode current collector 21 opposite to the positive electrode active material layer 12 side. Note that the illustration of the multiple attachments 16 is omitted in Fig. 9 because they are small. In this modification, the aspect of the multiple attachments 16 is the same as in the first embodiment.

[0171] The positive electrode current collector 21 also has a protruding step 22 that is linear in plan view and has a width of 1 mm or more. The step 22 may also be formed in a concave shape. In this specification, a convex shape refers to a shape that protrudes from the flat surface of the current collector, and a concave shape refers to a shape that is recessed from the flat surface of the current collector.

[0172] The step 22 is formed on the main surface 21a of the positive electrode current collector 21 opposite the positive electrode active material layer 12 side. The step 22 is a localized step formed on the flat surface of the positive electrode current collector 21. In addition, in FIG. 9 , two step portions 22 are formed along the short side of the positive electrode current collector 21 so as to divide the longitudinal direction of the positive electrode current collector 21 into thirds. The extending direction of the step portions 22 is not particularly limited. The ends of the step portions 22 are formed so as to extend to the outer periphery of the positive electrode current collector 21 in a planar view. Specifically, both longitudinal ends of the step portions 22 coincide with the outer periphery of the positive electrode current collector 21 in a planar view. The outer periphery of the positive electrode current collector 21 is a portion that defines the outline of the positive electrode current collector 21 in a planar view. The two step portions 22 are formed so as to be positioned point-symmetrically with respect to the center point of the positive electrode current collector 21 in a planar view.

[0173] Because the positive electrode current collector 21 has the step 22, when a layer in contact with the surface of the positive electrode current collector 21 where the step 22 is formed begins to slide, the layer that is sliding is subjected to stress by the step 22 and is therefore less likely to slide. As a result, misalignment between the positive electrode current collector 21 and the layer in contact with the surface of the positive electrode current collector 21 where the step 22 is formed is suppressed. For example, when another battery is stacked on the positive electrode current collector 21 via the connection layer 17 as in Modifications 1 and 2 of the embodiment, misalignment due to sliding of the stacked batteries is suppressed. Furthermore, when stress such as hardening stress occurs in a layer in contact with the surface of the positive electrode current collector 21 where the step 22 is formed, the step 22 divides the flat surface of the positive electrode current collector 21, distributing the stress among the divided flat surfaces and thereby mitigating the stress. This suppresses deformation such as warping of the battery 150. This suppresses peeling or deformation of the positive electrode current collector 21 and the connection layer 17. As a result, it becomes easier to build a large-sized thin-layer battery with multiple layers.

[0174] The width of the protrusion or recess in plan view of the protruding or recessed step 22 (the length in the direction perpendicular to the extending direction of the step 22) is 1 mm or more. Hereinafter, the width of the protrusion or recess in plan view may be simply referred to as "width." Furthermore, the height of the protruding or recessed step may be simply referred to as "height." In this specification, the depth of the step when the step has a recessed shape is also referred to as "height." In other words, the height is the length of the protrusion or recess from the flat surface of the positive electrode current collector 21 in the stacking direction.

[0175] The width of the step 22 may be 2 mm or more, or may be 4 mm or more. Furthermore, when the step 22 is formed along the short direction of the battery 150, the width of the step 22 may be 1% or more, or may be 3% or more of the longitudinal length of the battery 150. There is no particular upper limit to the width of the step 22, but it may be, for example, 15 mm or less, or 10% or less of the longitudinal length of the battery 150. Furthermore, the height of the step 22 is, for example, 2 μm or more, or 6 μm or more. Furthermore, the height of the step 22 may be 1% or more, or may be 3% or more of the thickness of the battery 150.

[0176] The step 22 is a step that rises or falls vertically. The step 22 may be a step that rises or falls in an oblique direction. The step may also be a step that rises or falls in a curved direction.

[0177] As described above, the end of the step 22 is formed so as to extend to the outer periphery of the positive electrode current collector 21 in a plan view. In other words, at least one of the ends of the step 22 is disposed so as to coincide with the outer periphery of the positive electrode current collector 21. As a result, the end of the step 22 is exposed to the side surface of the battery 150. Therefore, the step 22 serves as a path for discharging air when the positive electrode current collector 21 and a layer in contact with the surface of the positive electrode current collector 21 where the step 22 is formed are joined together, thereby improving the adhesion between the positive electrode current collector 21 and the layer in contact with the surface of the positive electrode current collector 21 where the step 22 is formed.

[0178] Two steps 22 are formed on the upper surface of the positive electrode current collector 21. The number of steps 22 is not limited to two, and may be one, or three or more. From the viewpoint of achieving both the effect of the steps 22 and ease of formation, the number of steps 22 may be three or less, three, or two.

[0179] 9, a plurality of steps 22 may be formed so as to extend parallel to one another in a plan view. As a result, even when a plurality of steps 22 are formed, the distance between adjacent steps 22 is constant. Therefore, when stress such as hardening stress occurs in a layer in contact with the surface of the positive electrode current collector 21 where the steps 22 are formed, the stress is alleviated uniformly in the direction in which the steps 22 extend.

[0180] Furthermore, a plurality of steps 22 may be formed so as not to intersect with each other. This makes it difficult for air to accumulate at the bonding interface between positive electrode current collector 21 and the layer in contact with the surface of positive electrode current collector 21 where steps 22 are formed, thereby further improving air discharge properties.

[0181] Furthermore, when a plurality of steps 22 are formed, the steps 22 may have the same width, height, and formation direction, or may have at least one of the width, height, and formation direction different from each other.

[0182] Furthermore, a step may also be formed on the surface of the positive electrode current collector 21 that is in contact with the positive electrode active material layer 12. This suppresses peeling at the interface between the positive electrode current collector 21 and the positive electrode active material layer 12. For example, when a convex step 22 is formed on the upper surface of the positive electrode current collector 21, a concave step may be formed on the lower surface of the positive electrode current collector 21.

[0183] The battery 150 is manufactured, for example, by pressing the positive electrode current collector 21 using an elastic sheet 41 of a size that divides the positive electrode current collector 21 into three parts in the longitudinal direction in the pressing step of the manufacturing method of the battery 100 according to the above-described embodiment. Specifically, the elastic sheet 41 is placed on the plate-like member 18 and pressed repeatedly so as to avoid the area where the step 22 is desired to be formed, thereby forming the positive electrode current collector 21 on which the step 22 is formed.

[0184] By manufacturing the battery 150 using this manufacturing method, the number of multiple attachments 16 attached per unit area of ​​the positive electrode current collector 21 is greater, for example, at locations other than the locations where the steps 22 are located on the main surface 21a opposite the positive electrode active material layer 12 side of the positive electrode current collector 21. As a result, many hard attachments 16 are attached to the thin locations of the positive electrode current collector 11 where no steps are formed, and the attachments can effectively alleviate stress on the thin locations of the positive electrode current collector 11 that are prone to deformation.

[0185] (Other embodiments) While the battery according to the present disclosure has been described above based on the embodiments, the present disclosure is not limited to these embodiments. As long as they do not deviate from the gist of the present disclosure, various modifications conceivable by those skilled in the art to the embodiments and other forms constructed by combining some of the components of the embodiments are also included in the scope of the present disclosure.

[0186] For example, the batteries in the above-described variants 1, 2, and 4 of the embodiment are stacked type batteries connected in series or in parallel, but they may also be stacked batteries that combine stacked type batteries connected in series and stacked type batteries connected in parallel.

[0187] Furthermore, for example, in the pressing step in the above embodiment, a plate-shaped member is placed on the power-generating element and pressed, but this is not limited thereto. In the pressing step, the power-generating element may be placed on a plate-shaped member and pressed. In this case, the plate-shaped member is placed so that the main surface of the positive electrode current collector is in contact with the roughened surface of the plate-shaped member.

[0188] In addition, for example, in the above-described embodiment and each modification, the first material constituting the plate-like member includes a metal, but is not limited to this. The first material may be any material that is harder than the first metal, and may be, for example, an inorganic material such as ceramics or metal oxide.

[0189] In addition, for example, in the above-described embodiment and each modification, the power generating element is composed of a positive electrode current collector, a positive electrode active material layer, a solid electrolyte layer, a negative electrode active material layer, and a negative electrode current collector, but is not limited thereto. For example, within the range of allowable battery characteristics, a bonding layer or the like may be provided between each layer of the power generating element for reducing electrical resistance and improving bonding strength.

[0190] Furthermore, for example, in the above-described embodiment and each modified example, multiple attachments are attached to the positive electrode current collector, but this is not limited thereto. When the negative electrode current collector includes a first metal and the positive electrode current collector includes a second metal harder than the first metal, multiple attachments may be attached to the negative electrode current collector. Therefore, it is sufficient that one of the positive electrode active material layer and positive electrode current collector and the negative electrode active material layer and negative electrode current collector is the first active material layer and first current collector, and the other is the second active material layer and second current collector.

[0191] Furthermore, the above-described embodiments and modifications can be subject to various changes, substitutions, additions, omissions, etc. within the scope of the claims or their equivalents. [Industrial Applicability]

[0192] The battery according to the present disclosure can be used, for example, as a secondary battery such as an all-solid-state battery used in various electronic devices or automobiles. [Explanation of symbols]

[0193] 11, 21 Positive electrode current collector 11a, 21a main surface 12 Cathode active material layer 13 Negative electrode current collector 14 Negative electrode active material layer 15 Solid electrolyte layer 16. Adhesion 16a Convex part 17 Connectivity Layer 18 Plate-shaped member 18a surface 19 Crack 22 steps 30, 31 Power generation elements 40 Pressure mold plate 41 Elastic sheet 100, 110, 120, 130, 140, 150 batteries

Claims

1. a preparation step of preparing a power generating element in which a first current collector containing a first metal, a first active material layer, a solid electrolyte layer, a second active material layer, and a second current collector containing a second metal harder than the first metal are laminated in this order; a pressing step of pressing the power generating element via a plate-like member made of a first material harder than the first metal and having a roughened surface, In the pressing step, the roughened surface of the plate-like member is brought into contact with the main surface of the first current collector to press the power generating element so that the first material constituting the plate-like member adheres as a plurality of deposits to the main surface of the first current collector opposite to the first active material layer side. How batteries are manufactured.

2. A preparation step of preparing a power generating element in which a first current collector containing a first metal, a first active material layer, a solid electrolyte layer, a second active material layer, and a second current collector containing a second metal harder than the first metal are stacked in this order; a pressing step of pressing the power generating element via a plate-like member made of a first material harder than the first metal and having a roughened surface, In the pressing step, the roughened surface of the plate-like member is brought into contact with a main surface of the first current collector to press the power generating element. A method for manufacturing a battery, comprising: a peeling step of peeling the plate-shaped member from the power-generating element after the pressing step, How batteries are manufactured.

3. In the pressing step, the roughened surface is brought into contact with the entire main surface of the first current collector and pressed. The method for manufacturing the battery according to claim 1 or 2.

4. In the pressing step, the plate-like member is pressed so as to come into contact with a pressing member. A method for manufacturing the battery according to any one of claims 1 to 3.

5. a cutting step of cutting the power generating element after the pressing step, A method for manufacturing the battery according to any one of claims 1 to 4.

6. the roughened surface is rougher than the main surface of the first current collector that is in contact with the roughened surface; A method for manufacturing the battery according to any one of claims 1 to 5.

7. The surface roughness Rz of the roughened surface is 1 μm or more and 10 μm or less. A method for manufacturing the battery according to any one of claims 1 to 6.

8. the first material comprises a metal; A method for manufacturing the battery according to any one of claims 1 to 7.

9. the first material includes the second metal; A method for manufacturing the battery according to any one of claims 1 to 8.

10. the first metal is aluminum; the second metal is copper; A method for manufacturing the battery according to any one of claims 1 to 9.

11. The thermal expansion coefficient of the first material is smaller than the thermal expansion coefficient of the first metal. A method for manufacturing the battery according to any one of claims 1 to 10.

12. a power generating element including a first current collector containing a first metal, a first active material layer, a solid electrolyte layer, a second active material layer, and a second current collector containing a second metal harder than the first metal, stacked in this order; a plurality of deposits attached to a main surface of the first current collector opposite to the first active material layer side, the deposits being made of a first material harder than the first metal; battery.

13. The average maximum width of the plurality of attachments in a planar view is 10 μm or less. The battery of claim 12.

14. the first material includes the second metal; 14. The battery of claim 12 or 13.

15. the main surface of the first current collector to which the plurality of deposits are attached is rougher than the main surface of the second current collector opposite to the second active material layer side; 15. The battery of any one of claims 12 to 14.

16. the first metal is aluminum; the second metal is copper; 16. The battery of any one of claims 12 to 15.

17. At least one of the plurality of attachments is attached to an end portion of the first current collector in a plan view.

17. The battery of any one of claims 12 to 16.

18. the first current collector has at least one linear step formed in a convex or concave shape in a plan view, the protrusion or depression having a width of 1 mm or more; 18. The battery of any one of claims 12 to 17.

19. The step is formed in a convex shape, the number of the plurality of attachments per unit area of ​​the first current collector is greater at a location other than the step than at a location where the step is located, on the main surface of the first current collector opposite to the first active material layer side; 20. The battery of claim 18.

20. The solid electrolyte layer contains a solid electrolyte having lithium ion conductivity.

20. The battery of any one of claims 12 to 19.

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