Secondary batteries

Abstract

This secondary battery is formed by staking multiple battery cells, each containing a lithium metal or a lithium-containing alloy in a negative electrode layer as a negative-electrode active material. The battery cell has a positive electrode tab which is connected to a positive-electrode current collector and exposed to the outside and a negative electrode tab which is connected to a negative-electrode current collector and exposed to the outside. The positive electrode tab and the negative electrode tab are disposed on the opposite sides across a centerline in the thickness direction of the battery cell, and the positive electrode tab and the negative electrode tab of adjoining battery cells are arranged to face each other and connected together.

Description

[Technical Field]

[0001] The present invention relates to a secondary battery. [Background technology]

[0002] JP2019-185976A discloses a battery pack in which a plurality of battery cells (single cells) are stacked and connected in series using bus bars. Summary of the Invention

[0003] In JP2019-185976A, when lithium metal or a lithium-containing alloy is used for the negative electrode, the battery cell may expand and contract during charging and discharging. When the battery cell expands and contracts, stress acts on the connection between the battery cell electrode and the bus bar, etc. When such stress acts, there is a risk of performance and reliability deteriorating, such as damage to the connection between the battery cell electrode and the bus bar.

[0004] The present invention has been made in consideration of these technical challenges, and aims to provide a secondary battery that can prevent damage to the connections between adjacent battery cells and suppress deterioration of the performance and reliability of the battery cells even when the battery cells expand and contract during charging and discharging.

[0005] According to one aspect of the present invention, a secondary battery includes a battery module formed by stacking multiple battery cells, each of which includes a negative electrode layer containing lithium metal or a lithium-containing alloy as a negative electrode active material. Each battery cell expands and contracts in the stacking direction during charging and discharging. The battery cells have a positive electrode tab connected to a positive electrode current collector and exposed to the outside, and a negative electrode tab connected to a negative electrode current collector and exposed to the outside. The positive electrode tab and the negative electrode tab are located on opposite sides of the center line in the thickness direction of the battery cell, and the positive electrode tab and the negative electrode tab of adjacent battery cells are arranged so as to face each other and are connected by being bent in the stacking direction. The battery module further includes a first terminal and a second terminal electrically connected to an external device, a first plate that is immovable and to which one end of the battery module in the stacking direction of the battery cells is fixed, and a second plate that is fixed to the other end of the battery module in the stacking direction of the battery cells and that is movable in accordance with the expansion and contraction of the battery cells when the battery cells expand and contract, wherein one of the first terminal and the second terminal is provided on the first plate and is connected to the positive electrode tab or negative electrode tab that is located closest to the first plate among the positive electrode tabs and negative electrode tabs that are provided on the multiple battery cells, and the other of the first terminal and the second terminal is provided on the second plate and is connected to the positive electrode tab or negative electrode tab that is located closest to the second plate among the positive electrode tabs and negative electrode tabs that are provided on the multiple battery cells. [Brief explanation of the drawings]

[0006] [Figure 1]FIG. 1 is a top view of an all-solid-state battery according to a first embodiment of the present invention. [Figure 2] FIG. 2 is a cross-sectional view of the structure of a battery cell according to the first embodiment of the present invention. [Figure 3] FIG. 3 is a diagram comparing the battery cell according to the comparative example before and after expansion. [Figure 4] FIG. 4 is a diagram comparing the battery cell according to the first embodiment of the present invention before and after expansion. [Figure 5] FIG. 5 is a cross-sectional view showing the structure of a battery cell according to a modified example of the first embodiment of the present invention. [Figure 6] FIG. 6 is a side view of an all-solid-state battery according to a second embodiment of the present invention. [Figure 7] FIG. 7 is a structural diagram of a battery cell according to a second embodiment of the present invention. DETAILED DESCRIPTION OF THE INVENTION

[0007] First Embodiment An all-solid-state battery 100 as a secondary battery according to a first embodiment of the present invention will be described with reference to Figures 1 and 2. Figure 1 is a top view of the all-solid-state battery 100 according to the first embodiment. Figure 2 is a cross-sectional view of the structure of a battery cell 1.

[0008] The all-solid-state battery 100 of this embodiment is a secondary battery capable of multiple charge and discharge cycles. While the following description will be given using the all-solid-state battery 100 as an example of a secondary battery, any battery configured by stacking multiple battery cells each containing lithium metal or a lithium-containing alloy as the negative electrode active material in the negative electrode layer may be used, such as a semi-solid battery or a battery using an organic solvent (electrolytic solution) as the electrolyte. As shown in FIG. 1 , the all-solid-state battery 100 includes: a plurality of battery modules M each configured by stacking multiple battery cells 1 in a housing (not shown); an immovable first plate 2 to which one end of the battery module M in the stacking direction of the battery cells 1 is fixed; a guide rod 3 having one end fixed to the first plate 2 and extending in the stacking direction of the battery cells 1; a second plate 4 to which the other end of the battery module M in the stacking direction of the battery cells 1 is fixed and which is movable in accordance with the battery cells 1 when the battery cells 1 expand and contract; a first terminal 8 attached to the first plate 2 and electrically connected to an external device (not shown); and a second terminal 9 attached to the second plate 4 and electrically connected to the external device.

[0009] The battery module M is fixed inside the housing (not shown) by fixing the first plate 2 to the housing. The stacked battery cells 1 are held in a compressed state between the first plate 2 and the second plate 4 by an elastic band (not shown) or the like.

[0010] For example, four guide rods 3 are provided, and support the second plate 4 so that it can move in the stacking direction of the battery cells 1.

[0011] Next, the specific structure of the battery cell 1 will be described with reference to FIG.

[0012] The battery cell 1 of this embodiment is formed in a substantially rectangular shape in plan view (see FIG. 1). The electrode structure of the battery cell 1 shown in FIG. 2 is a so-called non-bipolar type (internal parallel connection type), but it may also be a bipolar type (internal series connection type). The shape of the battery cell 1 is not limited to a rectangular shape and may be any shape, such as a circle or an oval.

[0013] The battery cell 1 includes alternately stacked positive electrode current collectors 11 and negative electrode current collectors 12, a power generation element portion provided between the positive electrode current collectors 11 and negative electrode current collectors 12 adjacent to each other in the stacking direction, and a laminate material 10 that is a battery exterior material that covers these. The power generation element portion includes a positive electrode layer 13, a solid electrolyte layer 14, and a negative electrode layer 15.

[0014] As shown in FIG. 2, the battery cell 1 is configured by stacking a plurality of laminated structures, each of which has a positive electrode current collector 11, a positive electrode layer 13, a solid electrolyte layer 14, a negative electrode layer 15, and a negative electrode current collector 12 stacked on top of each other.

[0015] The positive electrode current collector 11 and the negative electrode current collector 12 are formed in the shape of a rectangular thin plate and made of a metal material such as aluminum, nickel, iron, stainless steel, titanium, or copper. The positive electrode current collector 11 and the negative electrode current collector 12 each have a flexible lead electrode 11a, 12a extending from one side forming the outer edge. The lead electrodes 11a, 12a are provided to protrude in the same direction perpendicular to the stacking direction of the battery cells 1 (the height direction when the lead electrodes 11a, 12a are oriented vertically). A positive electrode tab 5 and a negative electrode tab 6, which serve as rigid terminals, are attached to the tips of the lead electrodes 11a, 12a, respectively. As a result, the positive electrode tab 5 and the negative electrode tab 6 are provided to protrude in the same direction perpendicular to the stacking direction of the battery cells 1.

[0016] The positive electrode layer 13 is disposed on both main surfaces of the positive electrode current collector 11 (only on the main surface of the positive electrode current collector 11 facing the negative electrode current collector 12 at the end). The positive electrode layer 13 contains, as a positive electrode active material, a substance that can release lithium ions during charging and absorb lithium ions during discharging using an oxidation-reduction reaction. Examples of materials for the positive electrode active material include lithium-transition metal composite oxides such as LiMnO, LiCoO, LiNiO, and Li(Ni-Mn-Co)O, as well as those in which part of the transition metal is substituted with other elements, lithium-transition metal phosphate compounds, and lithium-transition metal sulfate compounds.

[0017] The solid electrolyte layer 14 contains a solid electrolyte as a main component and is a layer interposed between the positive electrode layer 13 and the negative electrode layer 15. Examples of the solid electrolyte material include sulfide solid electrolytes and oxide solid electrolytes, with sulfide solid electrolytes being preferred. Examples of sulfide solid electrolytes include LPS-based (e.g., argyrodite (Li6PS5Cl)), LGPS-based (e.g., Li 10 GeP2S 12 ) materials are preferred.

[0018] The negative electrode layer 15 is disposed on both main surfaces of the negative electrode current collector 12 (only on the surface of the negative electrode current collector 12 facing the positive electrode current collector 11 at the end). The negative electrode layer 15 is configured to contain at least lithium metal or a substance that forms an alloy with lithium as a negative electrode active material. "The negative electrode layer 15 contains lithium metal as the active material" includes cases where lithium metal foil or lithium metal particles are disposed on the main surface of the negative electrode current collector 12, and cases where lithium metal is deposited on the main surface of the negative electrode current collector 12 using a positive electrode that contains a positive electrode active material such as a lithium-transition metal composite oxide, a lithium-transition metal phosphate compound, or a lithium-transition metal sulfate compound. "The negative electrode layer 15 contains a substance that forms an alloy with lithium as an active material" means that the negative electrode layer 15 contains at least one substance selected from the group consisting of In, Al, Si, and Sn.

[0019] 2, in the battery cell 1 of this embodiment, the lead electrode 11a of the positive electrode current collector 11 located outermost in the thickness direction is provided on the same plane as the main body of this lead electrode 11a, and a positive electrode tab 5 is connected to its tip end. The lead electrodes 11a of the other positive electrode current collectors 11 are bent toward and connected to the lead electrode 11a of the positive electrode current collector 11 located outermost in the thickness direction. The lead electrode 12a of the negative electrode current collector 12 located outermost in the thickness direction is provided on the same plane as the main body of this lead electrode 12a, and a positive electrode tab 5 is connected to its tip end. The lead electrode 12a of the other negative electrode current collector 12 is bent toward and connected to the lead electrode 12a of the negative electrode current collector 12 located outermost.

[0020] Next, the arrangement and connection of the positive electrode tab 5 and the negative electrode tab 6 will be described.

[0021] 1 and 2, in the all-solid-state battery 100 (battery module M), the positive electrode tab 5 and the negative electrode tab 6 are provided on opposite sides of the center line O in the thickness direction of the battery cell 1. The positive electrode tab 5 and the negative electrode tab 6 are also arranged to be offset in the width direction of the battery cell 1 (see FIG. 1). As described above, by connecting the positive electrode tab 5 and the negative electrode tab 6 to the positive electrode current collector 11 and the negative electrode current collector 12 located on the outermost sides, the positive electrode tab 5 and the negative electrode tab 6 can be provided at positions close to the end faces in the thickness direction of the battery cell 1.

[0022] As shown in FIG. 1 , in an all-solid-state battery 100 (battery module M), the positive electrode tabs 5 and negative electrode tabs 6 of adjacent battery cells 1 are arranged to face each other and are electrically connected via a bus bar 7. The positive electrode tabs 5 and bus bar 7, and the negative electrode tabs 6 and bus bar 7, are each connected by welding or the like. By connecting the positive electrode tabs 5 and negative electrode tabs 6 of adjacent battery cells 1 in this manner, multiple battery cells 1 are electrically connected in series. The positive electrode tabs 5 and negative electrode tabs 6 located at both ends of the stacked battery cells 1 are arranged to face a first terminal 8 and a second terminal 9 provided on the first plate 2 and the second plate 4, respectively, and are electrically connected to the first terminal 8 and the second terminal 9 via the bus bar 7.

[0023] In the all-solid-state battery 100, the negative electrode active material contains at least lithium metal or a material that forms an alloy with lithium, and therefore the battery cells 1 expand and contract in the stacking direction as lithium ions are absorbed and released during charge and discharge. Here, with reference to FIGS. 3 and 4, the change in the distance between the positive electrode tab 5 and the negative electrode tab 6 of adjacent battery cells 1 when the battery cells 1 expand will be described. FIG. 3(A) shows a comparative battery cell 101 before expansion, and FIG. 3(B) shows the comparative battery cell 101 after expansion. Furthermore, FIG. 4(A) shows the battery cell 1 of this embodiment before expansion, and FIG. 4(B) shows the battery cell 1 of this embodiment after expansion. For ease of explanation, the bus bar 7 is not shown in FIGS. 3 and 4.

[0024] 3(A) and 3(B), in the comparative example of a battery cell 101 in which the positive electrode tab 5 and the negative electrode tab 6 are located on the center line O in the thickness direction of the battery cell 101, when the battery cell 1 expands due to charging, the distance between the positive electrode tab 5 and the negative electrode tab 6 increases from L1 to L2. The difference between the distances L1 and L2 corresponds to the expansion of the region S1 between the positive electrode tab 5 and the negative electrode tab 6 of adjacent battery cells 1.

[0025] In the all-solid-state battery 100 (battery module M) of this embodiment, as described above, the positive electrode tab 5 and the negative electrode tab 6 are provided on opposite sides of the center line O in the thickness direction of the battery cell 1, and are arranged to face each other. This makes it possible to shorten the distance L (area S) between the positive electrode tab 5 and the negative electrode tab 6 of adjacent battery cells 1, as shown in Fig. 4, and therefore makes it possible to reduce the amount of change in the distance between the positive electrode tab 5 and the negative electrode tab 6 (distance L3 - distance L) when the battery cell 1 expands.

[0026] For this reason, in the battery module M, as shown in FIG. 1 , the positive electrode tabs 5 and the negative electrode tabs 6 are provided on opposite sides of the center line O in the thickness direction of the battery cell 1, and the positive electrode tabs 5 and the negative electrode tabs 6 of adjacent battery cells 1 are stacked so as to face each other. This makes it possible to reduce the amount of change in the distance L between the positive electrode tabs 5 and the negative electrode tabs 6 when the battery cell 1 expands and contracts, thereby reducing the stress acting on the connection between the positive electrode tabs 5 and the negative electrode tabs 6 due to expansion and contraction. Therefore, the all-solid-state battery 100 of this embodiment can prevent damage to the connection between the positive electrode tabs 5 and the negative electrode tabs 6 of adjacent battery cells 1. This makes it possible to suppress impairment of the performance and reliability of the all-solid-state battery 100.

[0027] In the above embodiment, the positive electrode tab 5 and the negative electrode tab 6 are connected via the bus bar 7, but the bus bar 7 is not necessarily provided. Specifically, as shown in FIG. 5 , the positive electrode tab 5 and the negative electrode tab 6 may be formed by bending them so that the connection portions 5a, 6a of the positive electrode tab 5 and the negative electrode tab 6 are located on the end faces in the stacking direction of the battery cells 1, respectively. This allows the connection portions 5a, 6a of the positive electrode tabs 5 of adjacent battery cells 1 to be directly connected. This eliminates the need for the bus bar 7, thereby reducing costs and reducing the number of connection portions, such as welding, thereby improving the performance and reliability of the all-solid-state battery 100 (battery module M).

[0028] The all-solid-state battery 100 according to the first embodiment described above has the following advantages.

[0029] In the all-solid-state battery 100, the positive electrode tab 5 and the negative electrode tab 6 are provided on opposite sides of the center line O in the thickness direction of the battery cell 1. Furthermore, the positive electrode tabs 5 and the negative electrode tabs 6 of adjacent battery cells 1 are arranged to face each other and connected. This reduces the amount of change in the distance between the positive electrode tab 5 and the negative electrode tab 6 when the battery cell 1 expands, thereby reducing the stress acting on the connection portion between the positive electrode tab 5 and the negative electrode tab 6 of the battery cell 1. This prevents damage to the connection portion between the positive electrode tab 5 and the negative electrode tab 6, and prevents deterioration in the performance and reliability of the all-solid-state battery 100.

[0030] Furthermore, in the all-solid-state battery 100, the positive electrode tab 5 and the negative electrode tab 6 are provided so as to protrude in the same direction perpendicular to the stacking direction of the battery cells 1. This allows electrical connection parts to be concentrated on one surface of the all-solid-state battery 100, making wiring work and maintenance easier.

[0031] In the all-solid-state battery 100, the positive electrode tab 5 and the negative electrode tab 6 located at both ends of the battery module M are electrically connected to a first terminal 8 and a second terminal 9 provided on the first plate 2 and the second plate 4, respectively, via a bus bar 7. For example, the positive electrode tab 5 or the negative electrode tab 6 of the battery cell 1 located closest to the second plate 4 is electrically connected to a first terminal 8 or a second terminal 9 provided on the first plate 2. 1st terminal 8 If the battery module M is connected to the second plate 4, the amount of change due to expansion and contraction of all stacked battery cells 1 will affect the connection between them. Therefore, by connecting the positive electrode tab 5 or the negative electrode tab 6 located at the end of the battery module M on the second plate 4 side to the second terminal 9 provided on the second plate 4, the amount of change in the distance L between the second terminal 9 and the negative electrode tab 6 connected to the second terminal 9 can be reduced when the battery cell 1 expands. This reduces the stress acting on the connection between the second terminal 9 and the negative electrode tab 6 connected to the second terminal 9. This prevents damage to the connection between the second terminal 9 and the negative electrode tab 6 connected to the second terminal 9.

[0032] Second Embodiment Next, an all-solid-state battery 200 as a secondary battery according to a second embodiment of the present invention will be described with reference to Fig. 6 and Fig. 7. The following description will focus on differences from the all-solid-state battery 100 according to the second embodiment, and the same components as those in the all-solid-state battery 100 according to the first embodiment will be denoted by the same reference numerals and will not be described.

[0033] Fig. 6 is a side view of an all-solid-state battery 200 according to the second embodiment. Fig. 7 is a structural cross-sectional view of a battery cell 201 according to the second embodiment. The battery cell 1 according to the first embodiment has the positive electrode tab 5 and the negative electrode tab 6 protruding in the same direction perpendicular to the stacking direction of the battery cells 1, whereas the battery cell 201 according to the second embodiment has the positive electrode tab 5 and the negative electrode tab 6 protruding in opposite directions perpendicular to the stacking direction of the battery cells 1.

[0034] 6 and 7, in the battery cell 201 as well, the positive electrode tab 5 and the negative electrode tab 6 are provided on opposite sides of the center line O in the thickness direction of the battery cell 1. In the battery cell 201, the positive electrode tab 5 and the negative electrode tab 6 are provided so as to protrude in opposite directions to each other in a direction perpendicular to the stacking direction.

[0035] As shown in FIG. 7 , in the battery cell 201 of this embodiment, the lead electrode 11a of the outermost positive current collector 11 is also provided on the same plane as the main body of this lead electrode 11a, and a positive electrode tab 5 is connected to its tip end. The lead electrodes 11a of the other positive current collectors 11 are bent toward and connected to the lead electrode 11a of the outermost positive current collector 11. The lead electrode 12a of the outermost negative current collector 12 is provided on the same plane as the main body of this lead electrode 12a, and a negative electrode tab 6 is connected to its tip end. The lead electrode 12a of the other negative current collector 12 is also bent toward and connected to the lead electrode 12a of the outermost negative current collector 12.

[0036] As shown in FIG. 6 , in an all-solid-state battery 200 (battery module M), the positive electrode tabs 5 and negative electrode tabs 6 of adjacent battery cells 201 are arranged to face each other and are electrically connected via a bus bar 7. The positive electrode tabs 5 and bus bar 7, and the negative electrode tabs 6 and bus bar 7, are each connected by welding or the like. By connecting the positive electrode tabs 5 and negative electrode tabs 6 of adjacent battery cells 201 in this manner, the multiple battery cells 201 are electrically connected in series. The positive electrode tabs 5 and negative electrode tabs 6 located at both ends of the stacked battery cells 201 are arranged to face a first terminal 8 and a second terminal 9 provided on the first plate 2 and the second plate 4, respectively, and are electrically connected to the first terminal 8 and the second terminal 9 via the bus bar 7.

[0037] According to the all-solid-state battery 200 of the second embodiment described above, in addition to the effects of the all-solid-state battery 100 of the first embodiment described above, for example, when the positive electrode tab 5 and the negative electrode tab 6 are provided at the center in the width direction of the battery cell 1, 201, the distance between the connecting portions of the positive electrode tab 5 and the negative electrode tab 6 can be made larger than in the all-solid-state battery 100 of the first embodiment, thereby achieving the effect of ensuring insulation more reliably.

[0038] In the above embodiment, the all-solid-state batteries 100 and 200 have been described as examples. However, the present invention is not limited to these, and can be applied to any type of battery, such as a semi-solid-state battery, in which the battery cells expand and contract with charging and discharging, specifically, as long as the battery has a battery cell containing lithium metal or a lithium-containing alloy as the negative electrode active material in the negative electrode layer.

[0039] In the above embodiment, the negative electrode layer 15 is always present, but the present invention is not limited to this. The negative electrode layer 15 may be formed as a deposition layer on the surface of the negative electrode current collector 12 facing the positive electrode current collector 11 when the battery cell 1, 201 is charged, and may disappear when the battery cell 1 is discharged. Furthermore, the battery may be a bipolar all-solid-state battery or a semi-solid-state battery.

[0040] In the above embodiment, an example was described in which the positive electrode tab 5 is connected to the first terminal 8 provided on the first plate 2, which is the fixed side, and the negative electrode tab 6 is connected to the second terminal 9 provided on the second plate 4, which is the movable side. However, this is not limited to this, and the negative electrode tab 6 may be connected to the first terminal 8, and the positive electrode tab 5 may be connected to the second terminal 9.

[0041] The configuration, operation, and effects of the embodiment of the present invention configured as above will be described below.

[0042] The all-solid-state batteries 100, 200 (secondary batteries) have a battery module M configured by stacking a plurality of battery cells 1,201, each of which includes lithium metal or a lithium-containing alloy as the negative electrode active material in its negative electrode layer. The battery cells 1,201 have a positive electrode tab 5 connected to a positive electrode current collector 11 and exposed to the outside, and a negative electrode tab 6 connected to a negative electrode current collector 12 and exposed to the outside. The positive electrode tab 5 and the negative electrode tab 6 are provided on opposite sides of a center line O in the thickness direction of the battery cell 1,201, and the positive electrode tabs 5 and the negative electrode tabs 6 of adjacent battery cells 1,201 are arranged to face each other and are connected.

[0043] In this configuration, the distance L between the positive electrode tab 5 and the negative electrode tab 6 of adjacent battery cells 1, 201 can be reduced, thereby reducing the amount of change in the distance L between the positive electrode tab 5 and the negative electrode tab 6 due to expansion and contraction. This reduces the stress acting on the connection portion between the positive electrode tab 5 and the negative electrode tab 6, preventing damage to the connection portion between the positive electrode tab 5 and the negative electrode tab 6 of adjacent battery cells 1, 201 and suppressing impairment of the performance and reliability of the all-solid-state batteries 100, 200 (secondary batteries).

[0044] In the all-solid-state battery 100 (secondary battery), the positive electrode tab 5 and the negative electrode tab 6 are provided so as to protrude in the same direction perpendicular to the stacking direction of the battery cells 1.

[0045] In this configuration, the electrical connection portions are concentrated on one surface of the all-solid-state battery 100, so the layout of the bus bars 7 in the battery module M can be simplified.

[0046] In the all-solid-state battery 200 (secondary battery), the positive electrode tab 5 and the negative electrode tab 6 are provided so as to protrude in opposite directions in a direction perpendicular to the stacking direction of the battery cells 201.

[0047] In this configuration, for example, when the positive electrode tab 5 and the negative electrode tab 6 are provided at the center of the width of the battery cell 201, the distance between the connection portions of the positive electrode tab 5 and the negative electrode tab 6 is greater than when the positive electrode tab 5 and the negative electrode tab 6 are provided protruding in the same direction perpendicular to the stacking direction of the battery cells 1. This makes it possible to ensure insulation more reliably.

[0048] In the all-solid-state batteries 100, 200 (secondary batteries), the battery cell 1, 201 is formed by stacking a plurality of laminated structures each including a stacked positive electrode current collector 11, a positive electrode layer 13, a solid electrolyte layer 14 (electrolyte layer), and a negative electrode current collector 12. The positive electrode tab 5 and the negative electrode tab 6 are connected to the positive electrode current collector 11 and the negative electrode current collector 12 that are located on the outermost sides in the stacking direction of the battery cell 1, 201.

[0049] In this configuration, the positive electrode tabs 5 and negative electrode tabs 6 are positioned on the outermost sides in the stacking direction of the battery cells 1,201, so the distance between the positive electrode tabs 5 and negative electrode tabs 6 of adjacent battery cells 1,201 can be shortened.

[0050] In the all-solid-state batteries 100, 200 (secondary batteries), the battery cells 1, 201 are bipolar type battery cells.

[0051] The all-solid-state batteries 100, 200 (secondary batteries) further include a first terminal 8 and a second terminal 9 electrically connected to an external device, an immovable first plate 2 to which one end of a battery module M in the stacking direction of the battery cells 1, 201 is fixed, and a second plate 4 to which the other end of the battery module M in the stacking direction of the battery cells 1, 201 is fixed and which is movable in accordance with the battery cells 1, 201 when the battery cells 1, 201 expand or contract. The first terminal 8 is provided on the first plate 2 and connected to the positive electrode tab 5 or the negative electrode tab 6 located closest to the first plate 2 among the positive electrode tabs 5 and the negative electrode tab 6 located closest to the second plate 4 among the positive electrode tabs 5 and the negative electrode tab 6 located closest to the second plate 4.

[0052] With this configuration, when the battery cell 1, 201 expands, it is possible to reduce the amount of change in the distance between the second terminal 9 provided on the second plate 4, which is the movable side, and the positive electrode tab 5 or negative electrode tab 6 connected to the second terminal 9. This reduces the stress acting on the connection portion between the second terminal 9 and the positive electrode tab 5 or negative electrode tab 6 connected to the second terminal 9. This prevents damage to the connection portion between the second terminal 9 and the positive electrode tab 5 or negative electrode tab 6 connected to the second terminal 9, and prevents deterioration in the performance and reliability of the all-solid-state batteries 100, 200 (secondary batteries).

[0053] Although the embodiments of the present invention have been described above, the above embodiments merely illustrate some of the application examples of the present invention, and the technical scope of the present invention is not intended to be limited to the specific configurations of the above embodiments. Furthermore, the above embodiments can be combined as appropriate.

[0054] In the above embodiment, an example has been described in which the positive electrode tab 5 and the negative electrode tab 6 are configured to be connected to the positive electrode collector 11 and the negative electrode collector 12 located on the outermost sides in the stacking direction of the battery cell 1, 201, but they may also be connected to the positive electrode collector 11 and the negative electrode collector 12 located on the inner side than the positive electrode collector 11 and the negative electrode collector 12 located on the outermost sides.

Claims

1. A secondary battery having a battery module configured by stacking a plurality of battery cells each containing lithium metal or a lithium-containing alloy as a negative electrode active material in a negative electrode layer, The battery cell is It expands and contracts in the stacking direction during charging and discharging. a positive electrode tab connected to the positive electrode current collector and exposed to the outside; a negative electrode tab connected to the negative electrode current collector and exposed to the outside, the positive electrode tab and the negative electrode tab are provided on opposite sides of a center line in a thickness direction of the battery cell, the positive electrode tabs and the negative electrode tabs of adjacent battery cells are arranged to face each other and are connected by being bent in the stacking direction, Furthermore, a first terminal and a second terminal electrically connected to an external device; a first plate that is immovable and to which one end of the battery module in the stacking direction of the battery cells is fixed; a second plate to which the other end of the battery module in the stacking direction of the battery cells is fixed, and which is movable in accordance with the expansion and contraction of the battery cells when the battery cells expand and contract; one of the first terminal and the second terminal is provided on the first plate and is connected to the positive electrode tab or the negative electrode tab that is located closest to the first plate among the positive electrode tabs and the negative electrode tabs that are provided on the plurality of battery cells; the other of the first terminal and the second terminal is provided on the second plate and is connected to the positive electrode tab or the negative electrode tab that is located closest to the second plate among the positive electrode tabs and the negative electrode tabs that are provided on the plurality of battery cells; Secondary battery.

2. The secondary battery according to claim 1, The positive electrode tab and the negative electrode tab are provided to protrude in the same direction perpendicular to the stacking direction of the battery cells.

3. The secondary battery according to claim 1, The positive electrode tab and the negative electrode tab are provided so as to protrude in opposite directions perpendicular to the stacking direction of the battery cells.

4. 4. The secondary battery according to claim 1, the battery cell is configured by stacking a plurality of stacked structures, each of which has a stack of the positive electrode current collector, a positive electrode layer, an electrolyte layer, the negative electrode layer, and the negative electrode current collector; the positive electrode tab and the negative electrode tab are connected to the positive electrode current collector and the negative electrode current collector positioned outermost in a stacking direction of the battery cell.

5. 4. The secondary battery according to claim 1, The secondary battery, wherein the battery cell is a bipolar battery cell.

6. A secondary battery according to any one of claims 1 to 5, A secondary battery, wherein the positive electrode tabs and the negative electrode tabs of adjacent battery cells are directly connected without using a bus bar.

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