Engine oil composition

Abstract

The present invention provides an engine oil composition, i) in the range of 70 to 95 weight percent of a base oil, based on the total weight of the engine oil composition; ii) a dispersant comb polymer in the range of 0.01 to 15 weight percent, based on the total weight of the engine oil composition; The dispersant comb polymer is a. 13.7 wt. % macromonomer, which is the ester of methacrylic acid and hydroxylated hydrogenated polybutadiene having a Mn of 4750 g / mol; b. 51.5 wt. % n-butyl methacrylate; c. 17.3 wt% LMA; d.11.2 wt.% styrene; e. 0.2 wt. % methyl methacrylate; f.6.1 wt.% N,N-dimethylaminoethyl methacrylate; the modified dispersant suppressor package contains 30 wt. % or less of a succinimide-type dispersant, based on the total weight of the modified dispersant suppressor additive package; The engine oil composition has an SAE viscosity grade of 0W-X, where X is 30 or less.

Description

[Technical Field]

[0001]

[0001] The present invention relates to an engine oil composition, and more specifically to an engine oil composition that provides improved fuel efficiency. [Background technology]

[0002]

[0002] Engine oil formulation is often a balance between the positive effects and limitations of specific additives and base oils. There is a continuous demand for improved fuel efficiency in all types of vehicles, and part of the solution to this can be found in improving the engine oil used.

[0003]

[0003] Lower viscosity engine oils generally result in improved fuel efficiency. However, there are limits to how much viscosity can be reduced while maintaining a suitable lubricant film thickness. Without a suitable lubricant film thickness, increased wear occurs, leading to material fatigue and ultimately shortening the lifespan of the machine in use.

[0004]

[0004] Fuel efficiency can be improved by increasing the viscosity index (VI) of a lubricant. The VI of a lubricant is one way of measuring the temperature dependence of the viscosity of a lubricant. A higher viscosity index indicates a lower temperature dependence of viscosity changes. An increase in viscosity index at a constant viscosity at a particular temperature means that the viscosity is lower at lower temperatures than that of an equivalent lubricant with a lower viscosity index.

[0005]

[0005] Another important parameter of engine oil is High Temperature High Shear (HTHS) viscosity. HTHS viscosity is an indicator of engine oil viscosity under harsh engine operating conditions of high engine speed or shear rate and high temperature. It causes a temporary viscosity loss of the lubricant under high shear and high temperature conditions that represent typical engine operation. The lower the HTHS viscosity of the oil, the greater the expected fuel efficiency benefit. The ASTM D4683 standard HTHS viscosity is 1.10°C and 150°C. 6s -1 The shear rate is measured by a tapered bearing simulator. The ASTM D6616 test method also measures HTHS viscosity, but at lower temperatures of 100°C and 80°C, which more accurately reflects the bearing conditions in automotive engines operating in this temperature range.

[0006]

[0006] Reducing the engine oil viscosity grade according to the J300 specification results in lower viscosity values ​​for kinematic viscosity (KV) at 100°C (measured at low shear rates) and HTHS viscosity at 150°C. If HTHS 150°C is not controlled, it may be beneficial for fuel efficiency, but it may result in insufficient engine protection, leading to reduced engine life and potential damage.

[0007]

[0007] Viscosity index improvers (VII), also known as viscosity modifiers (VM), are well known in the art to increase fluid viscosity at high temperatures. Typical VMs include olefin copolymers, polymethacrylates, styrene-hydrogenated diene blocks, and star polymers, which are referred to as conventional VMs. Some viscosity index improvers are specifically designed to provide the necessary HTHS 150°C performance required at high temperatures and high shear rates for engine protection, while maintaining low or even zero viscosity increase at intermediate temperatures such as 80°C, 60°C, and 40°C. Comb-type viscosity index improvers containing polymethacrylate main chains with substituted and / or unsubstituted side chains have been described in the prior art and may provide lower HTHS viscosity values ​​at temperatures of 80°C and 100°C according to ASTM 6616 for the same HTHS 150°C performance according to ASTM D4683 compared to their conventional hydrocarbon VM counterparts. The relatively lower values ​​for HTHS80 and HTHS100 compared to the same HTHS150 performance are an important indicator of improved fuel efficiency.

[0008]

[0008] Functionalized comb polymers, such as those described in U.S. Patent Publication No. 2016 / 0097017, U.S. Patent Publication No. 2011 / 0306533, U.S. Patent Publication No. 2010 / 0190671, U.S. Patent Publication No. 2008 / 0194443, and U.S. Patent No. 5,597,871, may be used to provide one or more additional functions, as well as improvements in viscosity index. This may reduce the need to add further additives to the lubricant formulation or to enhance specific performance characteristics such as sludge or deposit control.

[0009]

[0009] Typical engine oil formulations include a dispersant inhibitor (DI) package containing an ashless dispersant. The active ingredients of the DI package typically consist of about 50–60 weight percent of the ashless dispersant, with the remainder being other components such as detergents, anti-wear agents, antioxidants, and various other trace additives. An example of typical components of a DI package is shown in U.S. Patent No. 5512192. Ashless dispersants are included to prevent varnish or sludge in the oil from accumulating on the engine's working surfaces. While this protection is desirable in engine oil, typical ashless dispersants are considered particularly "heavy." That is, they exhibit low VI properties and do not reduce viscosity or temporarily reduce viscosity at high shear rates. Therefore, such dispersants may impair fuel efficiency. In general, fuel efficiency deteriorates with increasing treatment rates of dispersants in engine oil formulations. [Overview of the project]

[0010]

[0010] The object of the present invention is to provide an engine oil composition that has improved fuel efficiency over a wide range of operating conditions.

[0011]

[0012] The present invention relates to an engine oil composition, i) Based on the total weight of the engine oil composition, a base oil in the range of 70-95 weight percent, ii) Based on the total weight of the engine oil composition, a dispersant comb-type polymer in the range of 0.01 to 15 weight percent, iii) A package of modifiers, dispersants, inhibitors, and additives in the range of 4.99 to 15 weight percent based on the total weight of the engine oil composition, The dispersant comb-type polymer, a. A macromonomer, 13.7% by weight, which is an ester of methacrylic acid and hydroxylated hydrogenated polybutadiene having Mn (4750 g / mol), b.5 1.5 wt% n-butyl methacrylate, c.17.3% by weight of LMA and d. 11.2% by weight of styrene, e.0.2 wt% methyl methacrylate, It consists of 6.1% by weight of N,N-dimethylaminoethyl methacrylate. The modified dispersant inhibitor package contains 30% by weight or less of succinimide-type dispersant, based on the total weight of the modified dispersant inhibitor additive package. The present invention provides an engine oil composition having an SAE viscosity grade of 0W-X (wherein X is 30 or less).

[0012]

[0013] The present invention also provides the use of such engine oil compositions within the engine crankcase to reduce motored friction torque.

[0013]

[0014] The present invention further provides the use of such engine oil compositions in the crankcase of an engine to improve fuel efficiency and viscosity characteristics. [Brief explanation of the drawing]

[0014]

[0011] [Figure 1] This graph shows the results of the examples included in this specification. [Figure 2] This graph shows the results of the examples included in this specification.

Mode for Carrying Out the Invention

[0015]

[0015] The inventors of the present invention have surprisingly found that an engine oil composition containing a specific dispersant-comb polymer in combination with a modified dispersant inhibitor (DI) package with reduced ashless dispersant treat provides improved fuel economy characteristics. The engine oil composition has been shown to result in a reduction in motoring friction torque in a motored friction engine test, an increase in viscosity index, and improvements in HTHS100, HTHS80, and KV40°C viscosity characteristics at low temperatures, all of which indicate an improvement in fuel economy over a range of operating temperatures.

[0016]

[0016] The engine oil composition of the present invention comprises a base oil, a specific dispersant-comb polymer, and a modified DI package.

[0017]

[0017] The base oil can be a single base oil or a blend of suitable base oils. Preferably, the base oil contains one or more Fischer-Tropsch derived base oils. The term "Fischer-Tropsch derived" means that the base oil is a synthetic product of the Fischer-Tropsch process or is derived therefrom. Fischer-Tropsch derived base oils can be referred to as XTL (X-to-Liquid) base oils. In the term "XTL", X represents the source of carbon atoms, for example, gas to liquid (GTL), biomass to liquid (BTL).

[0018]

[0018] Suitable Fischer-Tropsch-derived base oils that can be advantageously used as the base oil in the lubricating composition of the present invention are, for example, those disclosed in European Patent No. 0776959, European Patent No. 0668342, International Publication No. 9721788, International Publication No. 0015736, International Publication No. 0014188, International Publication No. 0014187, International Publication No. 0014183, International Publication No. 0014179, International Publication No. 0008115, International Publication No. 9941332, European Patent No. 1029029, International Publication No. 0118156, and International Publication No. 0157166.

[0019]

[0019] As used herein, the term "Fischer-Tropsch-derived base oil" refers to a single base oil or a blend of base oils.

[0020]

[0020] Typically, Fischer-Tropsch-derived base oils have a kinematic viscosity at 100 °C (measured by ASTM D445) in the range of 1 to 30 mm 2 / s (cSt), preferably 1 to 25 mm 2 / s (cSt), more preferably 2 mm 2 / s to 12 mm 2 / s. Preferably, Fischer-Tropsch-derived base oils have a kinematic viscosity at 100 °C (measured by ASTM D445) of at least 2.5 mm 2 / s, more preferably at least 3.0 mm 2 / s.

[0021]

[0021] In one embodiment of the present invention, the Fischer-Tropsch-derived base oil comprises a Fischer-Tropsch base oil (e.g., "GTL 4") having a kinematic viscosity at 100 °C of up to 5.0 mm 2 / s, preferably up to 4.5 mm 2 / s, more preferably up to 4.2 mm 2 / s. In another embodiment of the present invention, the Fischer-Tropsch-derived base oil has a kinematic viscosity at 100 °C of up to 8.5 mm 2 / s, preferably up to 8 mm 2The invention comprises a Fischer-Tropsch base oil (e.g., "GTL 8") having a kinematic viscosity of 1 / second. In further embodiments of the present invention, the Fischer-Tropsch derivative base oil is provided with a kinematic viscosity of up to 3.0 mm at 100°C. 2 / second, preferably a maximum of 2.8mm 2 It contains a Fischer-Tropsch base oil (e.g., "GTL 3") having a kinematic viscosity of 1 / second.

[0022]

[0022] Furthermore, Fischer-Tropsch derivative base oils are typically 8-100 mm 2 / second (cSt), preferably 10-50 mm 2 It has a kinematic viscosity of 40°C (measured by ASTM D445) in 0.2°C.

[0023]

[0023] The Fischer-Tropsch derivative base oil preferably has a viscosity index in the range of 100 to 200 (according to ASTM D 2270). Preferably, the Fischer-Tropsch derivative base oil has a viscosity index of at least 125, preferably 130. It is also preferable that the viscosity index is less than 180, preferably less than 150.

[0024]

[0024] If the Fischer-Tropsch derivative base oil contains a blend of two or more Fischer-Tropsch derivative base oils, the above values ​​apply to the blend of two or more Fischer-Tropsch derivative base oils.

[0025]

[0025] In embodiments of the present invention where the base oil is a Fischer-Tropsch derivative base oil, the base oil preferably comprises 80% by weight or more of a Fischer-Tropsch derivative base oil based on the total weight of the base oil. However, the engine oil composition may also contain one or more other base oils in addition to the Fischer-Tropsch derivative base oil. There are no particular limitations on the other base oils used in the engine oil composition according to the present invention, and various conventional mineral oils, synthetic oils, and naturally derived esters such as vegetable oils may be conveniently used. Any base oil belonging to API (American Petroleum Institute) base oil categories Group I, Group II, Group III, Group IV, Group V, etc. may be conveniently used as long as the requirements for the engine oil composition according to this disclosure are met. Furthermore, the base oil may conveniently contain a mixture of one or more mineral oils and / or one or more synthetic oils, and therefore the term “base oil” may refer to a mixture containing two or more base oils.

[0026]

[0026] The total amount of base oil incorporated into the engine oil composition is in the range of 65 to 95% by weight, more preferably in the range of 65 to 90% by weight, and most preferably in the range of 75 to 88% by weight, relative to the total weight of the lubricant composition.

[0027]

[0027] The dispersant comb-type polymer used in the present invention is a. A macromonomer, 13.7% by weight, which is an ester of methacrylic acid and hydroxylated hydrogenated polybutadiene having Mn (4750 g / mol), b.5 1.5 wt% n-butyl methacrylate, c.17.3% by weight of LMA and d. 11.2% by weight of styrene, e.0.2 wt% methyl methacrylate, It consists of f.6.1% by weight of N,N-dimethylaminoethyl methacrylate.

[0028]

[0028] Preferably, the weight-average molecular weight of the dispersant comb-type polymer is 560,000 g / mol.

[0029]

[0029] The modified DI package includes at least an antioxidant additive, an anti-wear additive, and a cleaning additive. It may further include additional additives such as friction modifiers, pour point depressants, corrosion inhibitors, defoamers, and seal fixatives or seal conforming agents.

[0030]

[0030] The cleaning additive is preferably a metal-containing cleaning agent containing calcium and / or magnesium as alkaline earth metals. The content of the metal-containing cleaning agent is preferably 0.05 to 20% by weight, more preferably 1.0 to 10.0% by weight, and even more preferably 2.0 to 5.0% by weight, based on the alkaline earth metal content relative to the total amount of the engine oil composition.

[0031]

[0031] The metal-containing detergent preferably contains salicylate and / or phenate and / or carboxylate and / or sulfonate as its main component.

[0032]

[0032] The wear-resistant additive in the modified DI package is preferably zinc dialkyldithiophosphate. The content of zinc dialkyldithiophosphate is preferably 0.05 to 1.5% by weight, more preferably 0.4 to 1.4% by weight, based on the total weight of the engine oil composition. Additional or alternative wear-resistant additives may be conveniently used in the composition of the present invention.

[0033]

[0033] The antioxidant in the modified DI package is preferably a mixture of one or more phenolic antioxidants and one or more amine-based antioxidants. The antioxidant content is preferably 0.1 to 5.0% by weight, more preferably 0.3 to 3.0% by weight, and most preferably 0.5 to 1.5% by weight, based on the total weight of the engine oil composition.

[0034]

[0034] Furthermore, non-comb polymethacrylate can be conveniently used in the lubricating oil composition of the present invention as an effective pour point depressant.

[0035]

[0035] Organic molybdenum compounds such as molybdenum dialkyldithiocarbamate (MoDTC) can be conveniently used as friction modifiers in the lubricating oil composition of the present invention.

[0036]

[0036] Furthermore, compounds such as alkenyl succinic acid or its ester portion, benzotriazole compounds, and thiodiazole compounds can be conveniently used as corrosion inhibitors in the engine oil composition of the present invention.

[0037]

[0037] Compounds such as polysiloxane, dimethylpolycyclohexane, and polyacrylate can be conveniently used as defoaming agents in the engine oil composition of the present invention.

[0038]

[0038] Examples of compounds that can be conveniently used as seal fixing agents or seal compatibility agents in the engine oil composition of the present invention include commercially available aromatic esters.

[0039]

[0039] Optionally, the modified DI package contains a succinimide-type dispersant. An advantage of the present invention is that the amount of succinimide-type dispersant present in the DI package can be considerably reduced compared to the amount used in a typical engine oil package that uses a viscosity modifier that is not a dispersant comb polymer, consisting of 13.7% by weight of a macromonomer that is an ester of methacrylic acid and hydroxylated hydrogenated polybutadiene having 4750 g / mol) Mn, 51.5% by weight of n-butyl methacrylate, 17.3% by weight of LMA, 11.2% by weight of styrene, 0.2% by weight of methyl methacrylate, and 6.1% by weight of N,N-dimethylaminoethyl methacrylate.

[0040]

[0040] A typical industry-standard DI additive package would contain at least 35% by weight of a succinimide-type dispersant compound. The modified DI package of the present invention contains 30% by weight or less of a succinimide-type dispersant based on the total weight of the modified DI additive package. In embodiments of the present invention, the modified DI additive package may contain 25% by weight or less, or 20% by weight or less of a succinimide-type dispersant based on the total weight of the modified DI additive package.

[0041]

[0041] A typical engine oil composition would contain at least 4% by weight of a succinimide-type dispersant based on the total weight of the engine oil composition. In the present invention, the succinimide-type dispersant is preferably present in an amount of 3.5% by weight or less, more preferably 3.2% by weight or less, based on the total weight of the engine oil composition.

[0042]

[0042] If the engine oil composition of the present invention contains a succinimide-type dispersant, the succinimide-type dispersant is preferably present in an amount of at least 0.01% by weight based on the total weight of the engine oil composition.

[0043]

[0043] Preferably, the amount of succinimide-type dispersant present in the modified dispersant inhibitor package is at least 50% less than the amount that would have been present if a viscosity modifier other than a dispersant comb polymer had been used, which consists of 13.7% by weight of a macromonomer that is an ester of methacrylic acid and hydroxylated hydrogenated polybutadiene having 4750 g / mol) Mn, 51.5% by weight of n-butyl methacrylate, 17.3% by weight of LMA, 11.2% by weight of styrene, 0.2% by weight of methyl methacrylate, and 6.1% by weight of N,N-dimethylaminoethyl methacrylate.

[0044]

[0044] If present, the ashless dispersant is preferably selected from the group consisting of borated or non-borated alkyl succinimide or alkenyl succinimide, borated or non-borated alkyl succinate ester or alkenyl succinate ester, borated or non-borated alkyl succinimide or alkenyl succinimide, borated or non-borated alkyl succinamide or alkenyl succinamide, or any combination thereof.

[0045]

[0045] Examples of ashless succinimide dispersants and boron-modified ashless succinimide dispersants include the substances listed below. Examples of succinimide dispersants include nitrogen-containing compounds such as polyolefins, benzylamines, polyamines, and alkenyl group-containing or alkyl group-containing succinimides derived from Mannich bases. Succiniimide dispersants may also be derivatives obtained by reacting these nitrogen-containing compounds with phosphorus compounds such as thiophosphate or thiophosphate salts, organic acids, hydroxypolyoxyalkylene carbonates, etc. Examples of boron-modified ashless succinimide dispersants include derivatives obtained by reacting these nitrogen-containing compounds with boron compounds such as boric acid or borate salts.

[0046]

[0046] The dispersant in this embodiment should consist of a single dispersant arbitrarily selected from those listed above, or two or more of them. Furthermore, the ashless dispersant is particularly preferably a bis-type polybutenyl succinimide, a derivative of a bis-type polybutenyl succinimide, or a mixture thereof.

[0047]

[0047] Here, the alkenyl group and alkyl group can be linear or branched. Specifically, the alkenyl group and alkyl group are alkenyl groups and alkyl groups derived from olefin oligomers such as propylene, 1-butene, and isobutylene, as well as co-oligomers of ethylene and propylene. The branched alkyl group and branched alkenyl group are preferably derived from polyisobutene, a type of polybutene, having a number average molecular weight of 500 to 5000, more preferably 700 to 4000, and even more preferably 900 to 3000. The molecular weight of polymer additives can be obtained, for example, by using a Shodex GPC-101 high-performance liquid chromatograph manufactured by Showa Denko K.K., setting the temperature to 40°C, using a differential refractive index (RI) detector, using THF as the carrier gas at a flow rate of 1.0 ml / min (Ref 0.3 ml / min), setting the sample injection volume to 100 μL, using a combination of {KF-G (Shodex) × 1 and KF-805L (Shodex × 2)} as the column, using the range corresponding to the peak molecular weight, and calculating the average molecular weight (weight-average molecular weight and number-average molecular weight in polystyrene terms).

[0048]

[0048] The weight-average molecular weight of the ashless dispersant is preferably 1,000 to 20,000, more preferably 1,500 to 10,000, and even more preferably 5,000 to 10,000.

[0049]

[0049] Typically, the modified DI package will also contain a suitable carrier fluid. Antioxidant additives, anti-wear additives, cleaning additives, and succinimide-based dispersants, if present, as well as any other additives, will be dispersed in the carrier fluid before being added to the base oil. The carrier fluid is typically a base oil such as a Group 1 type mineral oil.

[0050]

[0050] The engine oil composition of the present invention has an SAE viscosity grade of 0W-X (wherein X is 30 or less). Preferably, X may be 30, 20, 12, 8, or 4. Preferably, X is 20 or less.

[0051]

[0051] To aid in a better understanding of the present invention, the following examples of specific aspects of several embodiments are given. The following examples should not be read in any way as limiting or defining the entire scope of the present invention.

[0052] [Examples]

[0052] Example 1 A fully formulated engine oil with viscosity grade SAE 0W-20 was blended according to Table 1. The amounts of each component are shown in weight percent based on the total weight of the composition.

[0053]

[0053] The ingredients used are as follows:

[0054] A Fischer-Tropsch derivative base oil having a kinematic viscosity (ASTM D445) of about 4 cSt at 100°C, which can be conveniently prepared by the process described in GTL 4 - International Publication No. 02070631.

[0055]

[0054] Full DI package 1 - Full SAPS additive package containing a polyisobutylene succinimide dispersant, together with an anti-wear additive, a detergent, a non-succinimide type dispersant, and an antioxidant, wherein the polyisobutylene succinimide dispersant is present in an amount that provides 5.5% by weight of the dispersant based on the total engine oil composition.

[0056]

[0055] Modified DI package 1-Polyisobutylene succinimide This is the same additive package as Full DI Package 1, except that it does not contain a dispersant.

[0057]

[0056] Modified DI package 2 - Polyisobutylene succinimide dispersant, the same additive package as full DI package 1, except that it contains a polyisobutylene succinimide dispersant, which is present in an amount that provides 2.75% by weight of the dispersant based on the total engine oil composition.

[0058]

[0057] Viscoplex 3-201-Evonik is a commercially available viscosity modifier.

[0059]

[0058] Dispersant comb-type polymer - Dispersant comb-type polymer comprising 13.7% by weight of a macromonomer which is an ester of methacrylic acid and hydroxylated hydrogenated polybutadiene having Mn (4750 g / mol), 51.5% by weight of n-butyl methacrylate, 17.3% by weight of LMA, 11.2% by weight of styrene, 0.2% by weight of methyl methacrylate, and 6.1% by weight of N,N-dimethylaminoethyl methacrylate.

[0060]

[0059] A polyalkyl methacrylate pour point depressant commercially available from Viscoplex 1-180-Evonik.

[0061] [Table 1]

[0062]

[0061] The rheological properties were tested using the following industry standard tests: kinematic viscosity (KV) and viscosity index (VI) in centistoke (cSt) units at 100°C and 40°C, as measured by ASTM D445. HTHS150 is the high-temperature high-shear viscosity in centipoise (cP) units at a temperature of 150°C, as measured by ASTM D4683. HTHS100 and HTHS80 are the high-temperature high-shear viscosity in centipoise (cP) units at temperatures of 100°C and 80°C, respectively, as measured by ASTM D6616.

[0063]

[0062] The hot tube test is a laboratory screener test developed to simulate high-temperature piston deposit formation in ASTM Sequence IIIG engine testing and to rank oils for weighted piston deposit formation tendencies. The hot tube deposit test provides a good correlation with gasoline piston deposit formation in ASTM Sequence IIIG engine testing. In this test, oil is drawn from a small bulk reservoir maintained at 150°C into a hot glass tube heated to 275°C by vacuum suction. The oil is drawn into the inside of the tube with residence times of 2-3 seconds every 60 seconds over a period of 6 hours. This action creates conditions for a thin oil film inside the hot tube to oxidize and form deposits. At the end of the 6 hours, an optical "in situ" deposit merit grade is assigned to the tube according to the Sequence IIIG evaluation procedure, on a scale from 10 to 1. A grade of 10 indicates a clean tube with no deposit formation, while a grade of 1 indicates excessive deposit formation.

[0064]

[0063] All the results of these measurements are shown in Table 2.

[0065] [Table 2]

[0066]

[0065] These results show an improvement in VI of the candidate oils compared to the baseline oil. While all oils were thickened to the same HTHS150, the candidate oils containing the dispersant comb polymer showed improvements in HTHS100 and HTHS80 values ​​compared to the baseline formulation blended using commercially available unfunctionalized COMB VM VP 3-201. This example demonstrates that engine oils containing the dispersant comb polymer and reduced levels of dispersant provide improved low-temperature viscosity and viscosity index compared to the baseline oil containing standard comb viscosity modifier and full DI package. Favorable results in the hot tube test were also achieved with reduced dispersant, and excellent results were demonstrated for test oil 2.

[0067]

[0066] Example 2 Four fully formulated engine oils with viscosity grade SAE 0W-12 were blended according to Table 3. The amounts of each component are shown in weight percent based on the total weight of the composition.

[0068]

[0067] In Example 2, the following components were used.

[0069] A Fischer-Tropsch derivative base oil having a kinematic viscosity (ASTM D445) of about 4 cSt at 100°C, which can be conveniently prepared by the process described in GTL 4 - International Publication No. 02070631.

[0070]

[0068] A Fischer-Tropsch derivative base oil having a kinematic viscosity (ASTM D445) at 40°C of about 9.8 cSt, which can be conveniently prepared by the method described in GTL 3 - International Publication No. 02070631.

[0071]

[0069] Full DI Package 2 - Additive package containing a polyisobutylene succinimide dispersant, together with an anti-wear additive, a detergent, a non-succinimide type dispersant, and an antioxidant, wherein the polyisobutylene succinimide dispersant is present in an amount that provides 5.74% by weight of the dispersant based on the total engine oil composition.

[0072]

[0070] Modified DI package 3-Polyisobutylene succinimide This is the same additive package as Full DI Package 2, except that it does not contain a dispersant.

[0073]

[0071] Modified DI package 4 - Polyisobutylene succinimide dispersant, the same additive package as full DI package 2, except that it contains a polyisobutylene succinimide dispersant, which is present in an amount that provides 2.87% by weight of the dispersant based on the total engine oil composition.

[0074]

[0072] Viscoplex 3-201-Evonik is a commercially available viscosity modifier.

[0075]

[0073] Dispersant comb-type polymer - Dispersant comb-type polymer comprising 13.7% by weight of a macromonomer which is an ester of methacrylic acid and hydroxylated hydrogenated polybutadiene having Mn (4750 g / mol), 51.5% by weight of n-butyl methacrylate, 17.3% by weight of LMA, 11.2% by weight of styrene, 0.2% by weight of methyl methacrylate, and 6.1% by weight of N,N-dimethylaminoethyl methacrylate.

[0076]

[0074] As shown in Table 3, test oil 3 (comparative example) is formulated using a dispersant comb polymer and an unmodified DI package. Test oil 4 is formulated using a dispersant comb polymer and a modified DI package, which contains 50% less ashless dispersant by weight compared to the unmodified DI package. Test oil 5 contains the same dispersant comb polymer, but has a modified DI package, which contains 0% by weight of ashless dispersant compared to the unmodified DI package. Baseline 0W-12 oil is formulated using an unmodified DI package and VP 3-201 as a viscosity modifier.

[0077] [Table 3]

[0078]

[0076] The rheological properties of each oil in Table 3 were measured, and the results are shown in Table 4.

[0079] [Table 4]

[0080]

[0078] Example 3 In accordance with the new JASO GLV-1 specification, JASO M 365:2019 (Automobile gasoline engine oils - Motored Fuel Economy Test procedure), a Motored Fuel Economy test was conducted to measure motored friction torque and estimate the percentage fuel economy improvement for several test oils. This test estimates the fuel economy improvement under operation under the Japanese WLTC and European WLTC test cycles, based on motored friction torque measured at 50°C and 80°C. In this test, the contribution of the oil to the fuel economy improvement is calculated based on the reduction in motored friction torque for the test oil compared to the standard reference oil. This torque change is confirmed before and after each test using the reference oil. The engines and test conditions used in the motored torque test are shown in Table 5.

[0081] [Table 5]

[0082]

[0080] Motoring friction torque tests were conducted on four 0W-12 candidates (baseline, test oil 3, test oil 4, and test oil 5). Figures 1 and 2 show the motoring friction torque reduction rates for the four oils compared to the reference 0W-20 oil at 50°C and 80°C, respectively. The dispersant comb polymers containing test oils 3, 4, and 5 showed greater torque reduction than the baseline oil at both temperatures. These results demonstrate that the continuous reduction of ashless dispersant treatment in the additive package, made possible by the use of dispersant comb polymers, leads to improved friction torque reduction.

[0083]

[0081] Fuel efficiency improvements were evaluated based on the established correlation between motoring fuel efficiency tests and real-world fuel efficiency tests. Table 6 shows the fuel efficiency improvements of baseline oils and test oil candidates for two modes: 1. LMH (low, medium, and high speed) modes suitable for actual driving conditions in Japan or the Japanese WLTC, and 2. LMHExH (low, medium, high, and very high speed) modes simulating European driving conditions or the European WLTC.

[0084] [Table 6]

[0085]

[0083] These results demonstrate that the reduction of succinimide-type dispersants made possible by the use of the dispersant comb polymer of the present invention certainly provides an improvement in fuel efficiency in actual vehicles. Embodiments are described below. Appearance 1 An engine oil composition, i) Based on the total weight of the engine oil composition, a base oil in the range of 70 to 95 weight percent, ii) Based on the total weight of the engine oil composition, a dispersant comb-type polymer in the range of 0.01 to 15 weight percent, iii) A package of modifiers and dispersants containing an additive in the range of 4.99 to 15 weight percent based on the total weight of the engine oil composition, The aforementioned dispersant comb-type polymer a. A macromonomer, 13.7% by weight, which is an ester of methacrylic acid and hydroxylated hydrogenated polybutadiene having 4750 g / mol of Mn, b.5 1.5 wt% n-butyl methacrylate, c.17.3% by weight of LMA and d. 11.2% by weight of styrene, e.0.2 wt% methyl methacrylate, It consists of 6.1% by weight of N,N-dimethylaminoethyl methacrylate. The aforementioned modified dispersant inhibitor package contains 30% by weight or less of a succinimide-type dispersant, based on the total weight of the modified dispersant inhibitor additive package. The engine oil composition is an engine oil composition having an SAE viscosity grade of 0W-X (wherein X is 30 or less). Appearance 2 The engine oil composition according to embodiment 1, wherein the base oil is a Fischer-Tropsch derivative base oil. Appearance 3 The engine oil composition according to Embodiment 1 or Embodiment 2, wherein the succinimide-type dispersant is present in the modified dispersant inhibitor package in an amount at least 50% less than the amount that would have been present if a viscosity modifier other than a dispersant comb-type polymer had been used, comprising 13.7% by weight of a macromonomer that is an ester of methacrylic acid and hydroxylated hydrogenated polybutadiene having 4750 g / mol) Mn, 51.5% by weight of n-butyl methacrylate, 17.3% by weight of LMA, 11.2% by weight of styrene, 0.2% by weight of methyl methacrylate, and 6.1% by weight of N,N-dimethylaminoethyl methacrylate. Pattern 4 The engine oil composition according to any one of embodiments 1 to 3, wherein the succinimide-type dispersant is present in an amount ranging from 0.01 to 3.5% by weight of the engine oil composition. Appearance 5 The engine oil composition according to any one of embodiments 1 to 4, wherein the succinimide-type dispersant is a polyolefin-substituted succinimide-type dispersant. Appearance 6 Use of an engine oil composition according to any one of embodiments 1 to 5 within the crankcase of an engine to reduce motoring friction torque. Appearance 7 Use of the engine oil composition according to any one of embodiments 1 to 5 in the crankcase of an engine to improve fuel efficiency and viscosity characteristics.

Claims

1. An engine oil composition, i) Based on the total weight of the engine oil composition, a base oil in the range of 70 to 95 weight percent, ii) Based on the total weight of the engine oil composition, a dispersant comb-type polymer in the range of 0.01 to 15 weight percent, iii) A package of modifier dispersant inhibitor additives in the range of 4.99 to 15 weight percent based on the total weight of the engine oil composition, The aforementioned dispersant comb-type polymer a. A macromonomer, 13.7% by weight, which is an ester of methacrylic acid and hydroxylated hydrogenated polybutadiene having 4750 g / mol of Mn, b. 51.5% by weight of n-butyl methacrylate, c. 17.3% by weight of LMA and d. 11.2% by weight of styrene and e. 0.2% by weight of methyl methacrylate and f. Consists of 6.1% by weight of N,N-dimethylaminoethyl methacrylate, The aforementioned modified dispersant inhibitor package contains an anti-wear additive, a detergent, an antioxidant, and a succinimide-type dispersant, and contains 3.5% by weight or less of the succinimide-type dispersant based on the total weight of the engine oil composition. The engine oil composition is an engine oil composition having an SAE viscosity grade of 0W-X (wherein X is 30 or less).

2. The engine oil composition according to claim 1, wherein the base oil is a Fischer-Tropsch derived base oil.

3. The engine oil composition according to claim 1 or 2, wherein the succinimide-type dispersant is present in an amount ranging from 0.01 to 3.5% by weight of the engine oil composition.

4. The engine oil composition according to any one of claims 1 to 3, wherein the succinimide-type dispersant is a polyolefin-substituted succinimide-type dispersant.

5. Use of the engine oil composition according to any one of claims 1 to 4 in the crankcase of an engine to reduce motoring friction torque.

6. Use of the engine oil composition according to any one of claims 1 to 4 in the crankcase of an engine to improve fuel efficiency and viscosity characteristics.

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