Fibrous amino acid-based substrates, especially high molecular weight fatty acid compounds for hair treatment.

Abstract

The present invention relates to mono-, di-, or polyquaternary ammonium compounds of the formula: R 1 (-F) x (I) where x is between 1 and 50, and F may be the same or different and is represented by general formula (II), [Formula 1] JPEG2023506846000373.jpg50164 wherein the optionally substituted and optionally functionalized hydrocarbon radical R 1 , R 2 , R 3 , R 4 or R 5 at least one of which comprises at least one estolide moiety containing two or more ester or amide moieties. The present invention also relates to methods for the synthesis of such compounds, their use in cosmetic skin and hair care formulations, cosmetic compositions for the treatment of fibers, and compositions comprising one or more of the compounds for the treatment of hair.

Description

[Technical Field]

[0001] The present invention relates to high molecular weight fatty acid compounds, methods for producing them, compositions containing the compounds, the use of the compounds in skin and hair care, particularly in cosmetic compositions containing them for hair care, and the use of the compounds for hair treatment. [Background technology]

[0002] Hair can generally be straight, wavy, curly, twisted, or kinky. Human hair consists of three main morphological elements: the cuticle (the outermost thin shell of several concentric layers), the cortex (the body of the hair), and, in the case of larger diameter hair, the medulla (a thin central nucleus). The cuticle and cortex give rise to the mechanical properties of the hair, namely its tendency to be wavy, curly, or twisted. Straight hair may resemble a rod with a circular cross-section, wavy hair may appear compressed into an oval cross-section, curly hair may appear even more compressed into an elongated oval cross-section, and the cross-section of twisted hair may be even flatter.

[0003] The main component of hair is the cross-linked alpha-helix protein keratin. Keratin is an intermediate filament protein specifically found in epithelial cells, such as human skin and hair, wool, feathers, and nails. Alpha-helix type I and type II keratin intermediate filament proteins (KIFs), with molecular weights of approximately 45-60 kDa, are embedded in an amorphous matrix of keratin-related proteins (KAPs), with molecular weights of 20-30 kDa (MA Rogers, L. Langbein, S. Praetzel-Wunder, H. Winter, J. Schweizer, J. Int Rev Cytol. 2006; 251:209-6); both intramolecular and intermolecular disulfide bonds provided by cystine contribute to the cytoskeletal protein network that maintains the cytoskeleton. In addition to disulfide crosslinks, ionic bonds or salt bridges pairing various amino acids found in hair proteins contribute to the outward shape of the hair.

[0004] It is known in the art that hair can be treated with functionalized silicones and hydrocarbons that provide one or more cosmetic benefits, such as conditioning, shine, UV protection, and color retention. Typically, these silicone and hydrocarbon-based derivatives physically deposit on the surface of the fibers (cuticle) and thus contribute to the appearance of the hair, namely its smoothness, silky feel, friction resistance, alignment, and combability.

[0005] Advanced silicone derivatives are generally considered high-performance materials with respect to attributes such as a smooth, silky hair feel, reduced friction, easy combability, and protection of hair color. Representative quaternary silicones are described in the prior art disclosures, namely US4891166, EP282720, US2008027202, US6730766, US6240929, WO02 / 10257, WO02 / 10259, WO2004 / 069137, WO2013 / 148629, WO2013 / 148635, and WO2013 / 148935.

[0006] Hydrocarbon-based conditioning agents are also widely used. Typically, monoquaternary ammonium compounds are monolong alkyl-trishort alkylquaternary ammonium salts or dilong alkyl-dishort alkylquaternary ammonium salts, where one or two alkyl substituents are selected from aliphatic groups of about 8 to about 30 carbon atoms, or aromatic, alkoxy, polyoxyalkylene, alkylamide, hydroxyalkyl, aryl or alkylaryl groups having up to about 30 carbon atoms; the other alkyl group is independently selected from aliphatic groups of about 1 to about 8 carbon atoms, or aromatic, alkoxy, polyoxyalkylene, alkylamide, hydroxyalkyl, aryl or alkylaryl groups having up to about 8 carbon atoms; and the counterion is a salt-forming anion selected from halogens (e.g., chlorides, bromides), acetates, citrates, lactates, glycolates, phosphates, nitrates, sulfonates, sulfates, alkyl sulfates, glutamates, and alkyl sulfonate radicals. Alternatively, these monoquaternary ammonium compounds are mono-fatty acid esters and di-fatty acid ester quats based on saturated or unsaturated fatty acids, as well as fatty amide quats having 10 to 24 carbon atoms in the alkyl chain. Details of these materials containing quaternary ammonium groups are disclosed, for example, in US2009 / 0000638, WO2012 / 027369, US2013 / 259820 and US5880086, US6465419, US6462014, US6323167, US6037315, US5854201, US5750490, US5463094, and US2003 / 013627.

[0007] Diquaternated hydrocarbons are also known. Typically, these geminquats are based on C8 to C20 alkyl or fatty chains (D. Shukla et. al., Cationic Gemini Surfactants: A Review, Journal of Oleo Science 2006, Vol. 55, Nr. 8, 381-390; MJ Rosen et. al. Langmuir (2001), 17, 6148-6154).

[0008] Diquaternary hydrocarbons based on alternating copolyesters of castor oil and different dicarboxylic acids are described in US2003 / 0007950 and US6972123.

[0009] We have synthesized materials containing 3-quat groups using castor oil precursors (EP 0283994, A. Baydar et. al., International Journal of Cosmetic Science (1991), 13(4), 169-90). We have also synthesized polyquaternary fatty acid dimer copolymers using fatty acid dimers (US 6982078).

[0010] WO2004 / 093834 describes hydrocarbon-based monoquaternary compounds for personal care applications. These compounds have the structure -CH2CH2O-EO x -PO y It must contain a bond with a -. Polymerized fatty acids have been proposed as hydrophobic tails.

[0011] There is a growing need for fibrous amino acid-based substrates, particularly efficient compounds for treating hair, that can be synthesized in a simple, cost-effective, and flexible manner, primarily based on sustainable raw materials, are easy to formulate and use, provide long-term stable formulations even in the presence of other functional ingredients, and are useful for hair conditioning, improving combability in both dry and wet hair, and achieving smooth and pleasant hair texture. In particular, there is a need to achieve the improved wet and dry combability advantages of silicone-based conditioning agents.

[0012] The inventors have found that novel high-molecular-weight fatty acid-based mono, di, and polyquaternary compounds, namely mono, di, and polyquaternary compounds containing an estolide structure, and aqueous compositions containing such compounds are suitable for meeting the above needs. Accordingly, the present invention provides novel high-molecular-weight fatty acid-based mono, di, and polyquaternary estolide compounds, aqueous compositions containing the same, cosmetic compositions containing the same, in particular hair care compositions, and their use for hair treatments. High-molecular-weight fatty acid-based mono, di, and polyquaternary estolide compounds can be synthesized in a simple, cost-effective, and flexible manner, mainly based on sustainable raw materials, are easy to formulate and use, and are useful for hair conditioning and improved combability, smoothness, and pleasant alignment of dry and wet hair. [Overview of the Initiative]

[0013] According to the present invention, a compound of the following formula is provided: R 1 (-F) x (I) Here x is 1 to 50, preferably 2 to 50. R 1has from 1 to 1000 carbon atoms, preferably from 2 to 300 carbon atoms, more preferably from 3 to 200 carbon atoms, still more preferably from 3 to 150 carbon atoms, specifically from 3 to 50 carbon atoms, and more specifically from 3 to 20 carbon atoms, and optionally contains one or more groups selected from -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups

Chemical formula

Chemical formula

Chemical formula

Chemical formula

[0014] According to the present invention, estolids are natural and synthetic compounds, derived in particular from oils and fats, and more specifically from fatty acid compounds typically obtained by the hydrolysis of oils and fats.

[0015] The estrid structure is identified by a secondary ester bond between one fatty acid acyl molecule and the alkyl skeleton of another fatty acid fragment. The terms “fatty acid” and “fatty acid molecule” may seem to imply that the individual residues must be derived from fatty components, but this is not the case. In this specification, the term “fatty acid” refers to carboxylic acids having a chain-like organyl group, particularly unbranched aliphatic monocarboxylic acids. Fatty acids differ from one another by the number of carbon atoms (chain length), and, if referring to unsaturated fatty acids, by the number and position of double bonds. Fatty acids can be classified into short-chain fatty acids with up to 7 carbon atoms, medium-chain fatty acids with 8 to 12 carbon atoms, long-chain fatty acids with 13 to 21 carbon atoms, and very long-chain fatty acids with more than 22 carbon atoms.

[0016] According to the present invention, the group "-O-" generally represents an ether group, which also includes the presence of an epoxide moiety that is a three-membered cyclic ether group. Therefore, the group defined above as optionally containing the group "-O-" may include an epoxy group. In particular, the residue R defined above may include a terminal epoxy group. 3 , R 4 , and R 5 This applies.

[0017] According to the present invention, residue R 1 This is the x-valence, where x is from 1 to 50, preferably from 2 to 50, and this is the residue R 1 This shows that it has x residues F as defined by general formula (II). Therefore, the term "x-valent" can be hydroxyl groups and halide groups, and residue R 1 This does not refer to or limit the number of any further substituents other than F.

[0018] According to the present invention, the expression “optionally substituted hydrocarbon radical” may optionally contain one or more specific groups and may be substituted with one or more specific groups, meaning an organyl radical linked to one or more further groups via at least one of its carbon atoms, where the hydrocarbyl structure of the radical may be interrupted by the specific groups included as defined, and one or more hydrogen atoms of the hydrocarbyl group may be substituted with substituents as shown.

[0019] R 1 In this case, for example, one or more hydrogen atoms may be substituted by a hydroxyl group or by a halide substituent, i.e., by a fluoro, chloro, bromo, or iodo substituent.

[0020] Furthermore, optionally substituted hydrocarbon radicals R 1 Specifically, these are -O-, -NH-, -C(O)-, -C(S)- and tertiary amino groups. [ka] Since it may contain one or more groups selected from R 1 The hydrocarbyl structure of the group can be interrupted by these groups or combinations thereof. Therefore, residues may include ester groups, carboxyl groups, amide groups, ether groups, amino groups, carbonyl groups, thione groups, thiocarboxylate groups, thioester groups, carbamate groups, urethane groups, epoxide groups, and all other groups identified for this radical, and combinations thereof. The same principle applies to optionally substituted hydrocarbon radicals R 2 , R 3 , R 4 , R 5 , R 6 , and R 11 This applies.

[0021] R, which is x-valent with respect to residue F 1The hydrocarbyl structure is preferably selected from the group consisting of linear, branched or cyclic alkyl or alkylene groups, linear, branched or cyclic alkenyl or alkenylene groups, linear, branched or cyclic alkynyl or alkynylene groups, linear, branched or cyclic alkaryl or alkarylene groups, linear, branched or cyclic aralkyl or aralkylene groups, and linear, branched or cyclic aryl or arylene groups, such as phenyl or phenylene, benzyl or benzylene, or tolyl or torylene groups, particularly such groups having 1 to 30 carbon atoms.

[0022] Comfortably, x-valent R 1 The radical can be selected from the group consisting of linear, branched, and cyclic alkyl or alkylene groups, or groups combining linear and cyclic alkyl or alkylene structures, or groups combining branched and cyclic structures, and is selected from alkyl or alkylene groups, in particular linear C1-C22 alkyl groups, e.g., methyl and methylene, ethyl and ethylene, n-propyl and n-propylene, n-butyl and n-butylene, n-pentyl and n-pentylene, n-hexyl and n-hexylene, n-heptyl and n-heptylene, or n-octyl and n-octylene groups, branched C1-C22 alkyl Selected from chloropropyl and alkylene groups, such as isopropyl and isopropylene, isobutyl and isobutylene, tert-butyl and tert-butylene, isopentyl and isobutylene, tert-pentyl and tert-pentylene, neopentyl and neopentylene, and 2-ethylhexyl and 2-ethylhexylene groups, and cyclic C3-C22 alkyl groups, such as cyclopropyl or cyclopropylene, cyclobutyl and cyclobutylene, cyclopentyl and cyclopentylene, cyclohexyl and cyclohexylene, and cycloheptyl or cycloheptylene groups.

[0023] If x > 1, then which C atom of the hydrocarbyl radical has the F group R 1 There are no restrictions on whether to bind to R. 1Regarding the presence of optional functional groups and optional substituents, R 1 This includes glycidyl compounds, glycerol and glycerol derivatives, particularly glycidol, glycerol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds, or R 1 In the case of a linear alkylene group, it is particularly preferable that it originates from an alkylene group that does not have any further substituents in addition to the F group.

[0024] As mentioned above, R 1 It is particularly preferable that it is derived from glycerol diglycidyl ether, which is R 2 However, the N atom opens the epoxide ring of glycerol diglycidyl ether, and then R in the compound according to the present invention 1 This means that it is formed by forming a quaternary N atom adjacent to the base. Similarly, R 1 However, it is preferable when the compounds are derived from diglycidyl ethers, diglycerol diglycidyl ethers, triglycerol diglycidyl ethers, polyglycerols terminated with glycidyl units, and poly(alkylene oxide) compounds terminated with glycidyl units, particularly poly(ethylene oxide) terminated with glycidyl units, poly(propylene oxide) terminated with glycidyl units, and poly(butylene oxide) terminated with glycidyl units.

[0025] R 1 However, it is also preferable that the compounds are derived from polyols, particularly diol compounds, such as α,ω-diols or α,ω-dihydroxy polyethers, more specifically, compounds obtained by esterification of dihydroxy-terminated poly(ethylene oxide), dihydroxy-terminated poly(propylene oxide), or dihydroxy-terminated poly(butylene oxide) with ω-halocarboxylic acids, particularly ω-chloroacetic acid or ω-chloropropanoic acid. The latter compounds are R 1 By substitution of the chloro substituent by the N atom of the F group adjacent to the group, R 1 It forms.

[0026] According to this, R1 Preferably, R is a C3-C50 alkylene group containing one or more internal ethers or ester groups, and 1 It is particularly preferred when such an alkylene group has a hydroxyl substituent.

[0027] R 1 If is a linear C1-C8 alkylene group without further substituents or functional groups, or R 2 It is most preferable that the group is a linear C3 to C50 alkylene group derived from diglycidyl ether, glycerol diglycidyl ether, diglycerol diglycidyl ether, diethylene glycol diglycidyl ether, or ethylene glycol diglycidyl ether having 3 to 10 (ethylene oxide) repeating units.

[0028] According to the present invention, the term “optionally substituted hydrocarbon residues” does not impose further restrictions on radicals, and therefore they are limited by the groups that may optionally be included or present as substituents, the number of carbon atoms in the identified residues, and the manner in which they are bonded to other structural parts of the compound according to the present invention as defined by formula (I), formula (II), formula (III), formula (IV), or any further formula used to define embodiments according to the present invention.

[0029] For example, R 2 In this case, the term "divalent" refers to the R bonded to two quaternary N atoms according to formula (II). 2 It refers to R 2 This does not limit the existence of any further substituents defined for this purpose.

[0030] Therefore, residue R 2 , R 3 , R 4 , R 5 , R 6 , and R 11 R can be optionally substituted with linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, where R 2 and R 6It is a divalent radical, while R 3 , R 4 , R 5 , R 11 It is a monovalent radical.

[0031] R 2 It is bonded to two different quaternary N atoms according to formula (II), and R 6 For example, by definition of formula (III) or (IV), and by further formulas according to further embodiments of the present invention, one side is bonded to the carbonyl group of the carboxylate or amide moiety, and the other side is bonded to, for example, the O atom of the carboxylate group or the NR of the amide group. 11 It is bonded to a possible group X.

[0032] Radical R 3 , R 4 , R 5 , R 11 is a monovalent radical, which may be the same or different, selected from optionally substituted linear, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radicals having hydrogen and up to 1000 carbon atoms, and thus can represent linear, i.e., linear, cyclic or branched alkyl groups, linear, cyclic or branched alkenyl groups, linear, cyclic or branched alkynyl groups, linear, cyclic or branched alkaryl groups, linear, cyclic or branched aralkyl groups and aryl groups, such as phenyl, benzyl or tolyl groups, in particular groups having 1 to 30 carbon atoms, and optionally the aforementioned groups may be substituted with OH or halide groups, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, [ka] and quaternary ammonium groups [ka] It may include one or more elements selected from the following.

[0033] Preferably, radical R 3 , R 4 , R 5 and R 11 are selected from alkyl groups, which are straight-chain, branched and cyclic alkyl groups, or groups combining straight-chain and cyclic alkyl motifs, or structures combining branched and cyclic structures, especially from the group consisting of straight-chain C1-C22 alkyl groups such as methyl, ethyl, n-propyl, n-butyl, n-pentyl, n-hexyl, n-hexyl, n-heptyl or n-octyl groups, branched C1-C22 alkyl groups such as isopropyl, isobutyl, tert-butyl, isopentyl, tert-pentyl, neopentyl and 2-ethylhexyl groups, and cyclic C3-C22 alkyl groups such as cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl and cycloheptyl groups, more preferably, radical R 3 , R 4 , R 5 and R 11 are selected from methyl, ethyl, isopropyl, tert-butyl, cyclopentyl or cyclohexyl groups, most preferably from methyl.

[0034] The radical R according to the present invention 2 may be the same or different and has up to 1000 carbon atoms and optionally, -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group

Chemical formula

[0035] Comfortable, R 2 The radical is selected from alkylene groups, which can be selected from the group consisting of linear, branched, and cyclic alkylene groups, or groups combining linear and cyclic alkylene structures, or groups combining branched and cyclic structures, in particular from linear C1-C50 alkylene groups, e.g., methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene, or n-octylene groups; branched C4-C50 alkylene groups, e.g., isopropylene, isobutylene, tert-butylene, tert-pentene, neopentene, and 2-ethylhexylene groups; and cyclic C3-C22 alkyl groups, e.g., cyclopropene, cyclobutylene, cyclopentylene, cyclohexylene, and cycloheptylene groups.

[0036] Which C atom of the hydrocarbyl radical is the quaternary N atom? 2 There are no restrictions on whether it should be combined with other elements.

[0037] R 2 Regarding the presence of optional functional groups and optional substituents, R 2 This includes glycidyl compounds, glycerol and glycerol derivatives, particularly glycidol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds, or R 2When the group is a linear alkylene group, it is particularly preferable that it is derived from an alkylene group that does not have any further substituents in addition to the quaternary N atom.

[0038] As mentioned above, R 2 If it is derived from glycerol diglycidyl ether, this is particularly preferable, and this is R 2 However, the N atom opens the epoxide ring of glycerol diglycidyl ether, and then R in the compound according to the present invention 2 This means that it is formed by the formation of a quaternary N atom adjacent to the base. Similarly, R 2 However, it is preferable that these compounds be derived from diglycidyl ethers, diglyceroldyl diglycidyl ethers, triglycidyl diglycidyl ethers, glycidyl-terminated polyglycerols, and glycidyl-terminated poly(alkylene oxide) compounds, particularly glycidyl-terminated poly(ethylene oxide), glycidyl-terminated poly(propylene oxide), and glycidyl-terminated poly(butylene oxide).

[0039] R 2 However, it is also preferable that the compound be formed from a diol compound, for example, an α,ω-diol or α,ω-dihydroxy polyether, particularly a dihydroxy-terminated poly(ethylene oxide), dihydroxy-terminated poly(propylene oxide), or dihydroxy-terminated poly(butylene oxide), and a compound obtained by esterification with an ω-halocarboxylic acid, particularly ω-chloroacetic acid or ω-chloropropanoic acid. The latter compound is R 2 By substitution of the chloro substituent by an adjacent N atom, R 2 It forms.

[0040] According to this, R 2 Preferably, R is a C3-C50 alkylene group containing one or more internal ethers or ester groups, and 2 It is particularly preferred when such an alkylene group has a hydroxyl substituent.

[0041] R2 If is a C1-C8 alkylene group that does not have further substituents or functional groups, or R 2 However, the most preferred case is a linear C3 to C50 alkylene group derived from diglycidyl ether, glycerol diglycidyl ether, diglycerol diglycidyl ether, diethylene glycol diglycidyl ether, or ethylene glycol diglycidyl ether having 3 to 10 (ethylene oxide) repeating units.

[0042] Radical R 6 This can be the same or different, selected from optionally substituted linear, cyclic or branched, saturated or unsaturated hydrocarbon radicals having 1 to 36 carbon atoms, and thus can represent a hydrocarbyl group selected from the group consisting of linear, branched or cyclic alkylene groups, linear, branched or cyclic alkenylene groups, linear, branched or cyclic alkynylene groups, linear, branched or cyclic alkalylene groups, linear, branched or cyclic aralkylene groups, and linear, branched or cyclic arylene groups, such as phenylene, benzylene or torylene groups, in particular from such groups having 1 to 100 carbon atoms, each optionally containing one or more of the above functional groups.

[0043] Comfortable, R 6The radicals are selected from linear alkylene groups and linear alkenylene groups, in particular linear C6-C24 alkyne groups, e.g., hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecylen, octadecylene, nonadecylen, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene, or linear C6-C24 alkenylene groups, e.g. For example, selected from hexenylene, heptenylene, octenylene, nonenylene, decenylene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicocenylene, henicocenylene, doicocenylene, tricocenylene, and tetraicocenylene, where these groups are most preferably bonded to adjacent C(O) groups by terminal C atoms.

[0044] In the hydrocarbyl radical, at which C atom is the adjacent C(O) group and X group R 6 There are no restrictions on whether it should be combined with other elements.

[0045] However, R 6 It is preferably derived from a hydroxycarboxylic acid having one or more hydroxyl groups, more preferably from a monohydroxycarboxylic acid, and most preferably from a C7-C25 fatty acid having one hydroxyl group as a substituent. Therefore, R 6 R preferably represents the alkylene or alkenylene chain of such a carboxylic acid. For example, R 6 If it is derived from ricinoleic acid, [ka] And, R 6 This represents the 1,11-heptadeca-8-enyl radical, [ka] Here, "1,11" indicates the positions where the radical is bonded to adjacent groups X and C(O).

[0046] R of at least one part present in the cationic structure of general formula (I) as defined by formula (III) or formula (IV) 6 Containing repeating units (-XC(O)-R 6 ), or (-C(O)-XR 6 The number of m is 1 to 20, preferably 1 to 15, 1 to 12, 1 to 10, 1 to 8, or 2 to 20, 3 to 20, 4 to 20, 5 to 20, specifically 1, 2, 3, 4, 5, 6, 7, 8, 9, or 10.

[0047] residue R 1 Preferred examples include C3-C18 hydroxyl group-substituted polyether radicals, particularly glycerol-based polyether radicals, and C1-C8 linear alkyl or alkylene groups.

[0048] In this specification, the term polyether includes, in particular, compounds derived from poly(alkylene oxide), where the repeating alkylene group is independently selected from C1-C8 alkylenes.

[0049] residue R 2 Preferred examples include linear C1-C8 alkylene radicals, more preferably ethylene, propylene, butylene, pentylene, hexylene, and heptylene, most preferably propylene and hexylene.

[0050] residue R 3 , R 4 and R 5 Preferred examples include linear C1-C8 alkyl groups and linear alkyl groups comprising one or more parts of formula (III) or (IV), where m is preferably 2 to 6, and most preferably R 3 , R 4 and R 5 This is independently selected from a methyl group and an alkyl group containing one or more parts of formula (III).

[0051] R 6 A preferred example is a structure derived from the corresponding hydroxylcarboxylic acid by subtracting a carboxylic acid group and one OH group, where the hydroxylcarboxylic acid is preferably selected from ricinoleic acid, reskerolic acid, 10-hydroxyoctadecanoic acid, 12-hydroxyoctadecanoic acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or dihydroxycarboxylic acid, particularly 2,2'-di-hydroxymethylpropanoic acid, 9,10-dihydroxystearic acid, or polyhydroxycarboxylic acid, particularly gluconic acid. Most preferably, R 6 The compounds are derived from reskerolic acid or ricinoleic acid by the methods described above. In both cases, naturally occurring enantiomers of the compound, namely (9Z,12R)-12-hydroxyoctadeca-9-enoic acid obtained by saponification or fractional distillation of castor oil, which is hydrolyzed castor seed oil, and (11Z,14R)-14-hydroxyicos-11-enoic acid isolated from Paysonia and Physaria species, are particularly preferred. However, racemates, S enantiomers, and E constituent isomers, racemates, enantiomers, and any possible mixtures thereof of the compound are also preferred according to the present invention.

[0052] R 11 Preferred examples include C1-C10 alkyl groups, particularly methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, n-pentane and n-hexane groups, cyclopentyl and cyclohexane groups, C2-C10 alkenyl groups, particularly vinyl and allyl groups, and C6-C12 aromatic groups, particularly phenyl, tolyl and benzyl groups, each of which may be substituted with a hydroxyl or halide group.

[0053] According to the present invention, the counterion A of the ammonium ion according to the present invention - The ion is selected from monovalent to trivalent inorganic or monovalent to 30,000-valent, preferably monovalent to 1,000-valent organic anions.

[0054] Among them, against Anion A - Preferably, the following are halogenated anions, e.g., chlorides, bromides, iodides; inorganic oxoate anions, e.g., sulfates and phosphates; phosphonates; sulfonates; methosulfates; carboxylate anions, e.g., acetates, propionates, lactates, octanoates, 2-ethyl-hexanoates, dodecanoates, hexadecanoates, octadecanoates, oleates, ricinolates, 12-hydroxy-octadecanoates, succinates, maleates, tartrates, polyether carboxylates, and polymer fatty acid carboxylates of the types listed below. R 1 [(-C(O)-XR 6 ) m -C(O)-XR 7 ] x ,or R 1 [(XC(O)-R 6 ) m -XC(O)-R 7 ] x , Here R 1 or R 7 At least one of the following, or R 1 and R 7 At least one of them has one or more carboxylate groups, Preferably, here X=O, especially The following types of linear polymer carboxylates, - OC(O)-R 6 (-XC(O)-R 6 ) m-1 -XC(O)-R 7 Preferably - OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , In other words, it originates from the following linear polyfatty acid structure, [ka] [ka] Branched linear polymer fatty acid carboxylates, In other words, it originates from the following branched polyfatty acid structure, [ka] Here R= [ka] Here R= [ka] Here R= [ka] or Here R= [ka] Alternatively, branched linear polymeric fatty acid carboxylates derived from polyfunctional carboxylic acids, particularly dicarboxylic acids, succinic acid, and maleic acid, with castor oil or rescherella oil. for example, [ka] Here, one R = [ka] And the remaining two R groups = [ka] Dendrimer-like high molecular weight fatty acid carboxylate, In other words, it originates from the following dendrimer-like polyfatty acid structure, [ka] Here R= [ka] Or the following types, XR 6 (-C(O)-XR 6 ) m-1 -C(O)-XR 7 ,or R 6 (-C(O)-XR 6 ) m-1 -C(O)-XR 7 , Here, in the latter two types, R 7 The group has at least one anionic carboxylate group, Or the following types, R 1 [(-C(O)-X-R6) m -C(O)O - ] x ,for example, [ka] Here X, R 1 , R 6 , m and x are as defined above, and R 7 It has 1 to 36 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, [ka] Quaternary ammonium group [ka] A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical, independently selected from, where radical R, comprising one or more groups selected from, and which may be substituted with an OH group or a halide group, wherein radical R is the radical. 7 It cannot contain internal carboxyl groups or amides, i.e., R 7 It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group. And here is the counterion A of this group - The anion is preferably monovalent to 50valent, more preferably monovalent to 10valent, even more preferably monovalent to 5valent, most preferably pentavalent, tetravalent, trivalent, divalent, or monovalent. Selected from the group consisting of, Alternatively, the counter anion is a carboxylate anion based on poly(acrylic acid) homopolymers and copolymers. In other words, carboxylate derived from polyacrylic acid homopolymer [ka] Here, p = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Carboxylate anions derived from polyacrylic acid copolymers, In other words, substances containing non-reactive comonomers, for example. [ka] Here a = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. b = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000 (effective for all comonomers), where Copolymers can have a block-like or random distribution of comonomer units. Alternatively, a carboxylate anion derived from a polyacrylic acid copolymer, for example, comprising a comonomer that provides OH and amine functional groups that can be functionalized via further ester or amide bonds with fatty acids or polyfatty acids, [ka] Here, c = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Alternatively, a carboxylate anion derived from a polyacrylic acid copolymer containing a carboxylic acid functional group comonomer, where Copolymers can have a block-like or random distribution of comonomer units. for example, [ka] Here d = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. e = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000 (effective for all comonomers). Carboxylates based on maleic acid copolymers, particularly those derived from maleic anhydride copolymers, here Copolymers can have a block-like or random distribution of comonomer units. for example, [ka] Here f = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, even more preferably 1000 to 10000 (effective for all comonomers), and g = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Carboxylates based on poly(itaconic acid) homo and copolymers, In other words, it is derived from polyitaconate homopolymer, [ka] Here, h = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Alternatively, that is, derived from polyitaconate copolymers containing non-reactive comonomers, Here Copolymers can have a block-like or random distribution of comonomer units. for example [ka] Here i = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000 (effective for all comonomers). j = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Alternatively, a polyitaconic acid copolymer, for example, derived from a 2-hydroxyethyl methacrylate-itaconic acid copolymer, comprising a comonomer that provides OH and amine functional groups that can be functionalized via further ester or amide bonds with fatty acids or polyfatty acids, Alternatively, derived from a polyitaconic acid copolymer containing a carboxylic acid functional group-containing comonomer, where Copolymers can have a block-like or random distribution of comonomer units. for example, [ka] Here k = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000 (effective for all comonomers). l = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Here, the anion of this group is preferably a valency of 2 to 30,000, more preferably 1,000, even more preferably 10 to 1,000, even more preferably 50 to 1,000, and most preferably a valency of 100 to 1,000. It is selected from the group consisting of the following.

[0055] According to the present invention, any cationic structure according to the present invention can be combined with any anion according to the present invention.

[0056] It is preferable to combine a cation containing a small number of quaternary nitrogen atoms, i.e., 1 to 20, particularly 1 to 10, more specifically 1 to 6, and even more specifically 1 or 2 quaternary nitrogen atoms, with a monovalent or decavalent anion, preferably a monovalent to hexavalent anion, more preferably a monovalent to trivalent anion, and even more preferably a monovalent or divalent anion.

[0057] Alternatively, polyanions with a valency of 11 to 30,000, particularly those with a valency of 11 to 100 or 101 to 1,000, can be used.

[0058] Polyquat cations containing 21 or more quaternary nitrogen atoms are typically combined with low-valence counterions, i.e., monovalent to pentavalent anions, more preferably monovalent to decadal anions, even more preferably monovalent to pentavalent anions, and most preferably monovalent and divalent counteranions, particularly chloride anions, monocarboxylate and dicarboxylate anions. Here, the use of anions with a valency of more than 50 is less preferred.

[0059] As mentioned above, R 7 It has 1 to 36 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, [ka] Quaternary ammonium group [ka] A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical, independently selected from, where radical R, comprising one or more groups selected from, and which may be substituted with an OH group or a halide group, wherein radical R is the radical. 7 It cannot contain internal carboxyl groups or amides, i.e., R 7 It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group.

[0060] According to the present invention, radical R 7These may be the same or different and can be selected from optionally substituted linear, cyclic or branched, saturated or unsaturated hydrocarbon radicals having 1 to 36 carbon atoms, and thus can represent a hydrocarbyl group selected from the group consisting of linear, branched or cyclic alkyl groups, linear, branched or cyclic alkenyl groups, linear, branched or cyclic alkynyl groups, linear, branched or cyclic alkaryl groups, linear, branched or cyclic aralkyl groups, and linear, branched or cyclic aryl groups, such as phenyl, benzyl or tolyl, particularly such groups having 6 to 24 carbon atoms, each optionally containing one or more of the above functional groups.

[0061] Comfortable, R 7 The radicals are selected from linear alkyl groups and linear alkenyl groups, in particular linear C6-C24 alkyl groups, for example hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or linear C6-C24 alkenyl groups, for example Selected from hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where these groups are most preferably bonded to an adjacent C(O) or X group by a terminal C atom.

[0062] Which of the C atoms in the hydrocarbyl radical is adjacent to the C(O) group or X group R 7 There are no restrictions on whether it should be combined with other elements.

[0063] However, R 7It is preferably derived from a carboxylic acid or hydroxycarboxylic acid having one or more hydroxyl groups, more preferably from a carboxylic acid or monohydroxycarboxylic acid, and most preferably from a C7-C25 fatty acid that does not have a hydroxyl group as a substituent. Therefore, R 7 Preferably, R represents the alkyl or alkenyl chain of such a carboxylic acid. For example, R 7 If it is derived from ricinoleic acid [ka] At that time R 7 This represents the 11-hydroxyheptadeca-8-enyl radical, [ka] Or, R 7 If it originates from oleic acid, [ka] At that time R 7 This represents the heptadeca-8-enyl radical. [ka]

[0064] R 7A preferred example is a structure derived from the corresponding carboxylic acid or hydroxylcarboxylic acid from which the carboxylate group has been removed, where the carboxylic acid is acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, enanthic acid, caprylic acid, pelargonic acid, capric acid, undecanoic acid, lauric acid, tridecanoic acid, myristic acid, pentadecanoic acid, palmitic acid, margaric acid, stearic acid, linoleic acid, α-linolenic acid, γ-linolenic acid, nonadecylic acid, arachidonic acid, meadic acid, arachidonic acid, heneicosanoic acid, doco From sanic acid, tricosylic acid, and lignoceric acid, a selection can be made from hydroxyl carboxylic acids, such as reskerolic acid, ricinoleic acid, 10-hydroxyoctadecanoic acid, 12-hydroxyoctadecanoic acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or dihydroxycarboxylic acids, in particular 2,2'-dihydroxymethylpropanoic acid, 9,10-dihydroxystearic acid, or polyhydroxycarboxylic acids, in particular gluconic acid.

[0065] Radical R 7 The following are optional: -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, [ka] Quaternary ammonium group [ka] It may contain one or more groups selected from and may be substituted with an OH group or a halide group, but radical R 7 It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group, that forms an internal carboxylate group, i.e., an internal ester group or an internal amide group.

[0066] Structure of formulas (I) and (II), and R 1 , R 2 , R 3 , R4 , R 5 Considering the definition, in some cases the substructure of a given compound according to the present invention is represented by formulas (I) and (II), and the residue R defined above is expressed in multiple ways. 1 , R 2 , R 3 , R 4 and R 5 It is clear that it can be assigned to.

[0067] Only in such cases shall the following rules apply, in a clear manner to the above term R 1 -R 5 This applies to the assignment of the substructure to: - R 1 This is the subscript x, that is, R 1 The group will be selected in such a way that the number of -F groups that bond to it is as large as possible; - R 1 The base F will be chosen such that the number of non-zero bases F for n is as small as possible; - If there are several options that satisfy the aforementioned requirements, R 1 R 1 This will be selected; - If there are two or more substructures that similarly satisfy the above requirements, R 1 The substructure will be selected such that, among the possible substructures, it will have the highest total atomic weight of the atoms it contains.

[0068] According to the present invention, residue R 2 , R 3 , R 4 , R 5 , R 6 or R 7 If any of the following are present in the compound according to the present invention, each residue can represent another substructure as defined above, i.e., each R 2 , R 3 , R 4 , R 6 and R 7 The base is independently selected according to the definitions provided for in this invention.

[0069] In a preferred embodiment of the present invention, a compound of the following formula as defined above is used. R 1 (-F) x (I) Provided Here, x ranges from 2 to 50.

[0070] More preferably, according to this embodiment, x is in the range of 3 to 50, 4 to 50, 5 to 50, 6 to 50, 7 to 50, 8 to 50, 9 to 50, 10 to 50, 2 to 40, 2 to 35, 2 to 30, 2 to 25, 2 to 20, 2 to 15, or 2 to 10.

[0071] In another preferred embodiment of the present invention, the compound of the following general formula, as defined above, is: R 1 (-F) x (I) Does not contain poly(ethylene oxide) or poly(propylene oxide) units.

[0072] According to the present invention, the poly(ethylene oxide) unit is given by the formula (CH2CH2O) where x≧2. x The unit is defined as the expression (CH2CH(CH3)O) where x≧2, and or the poly(propylene oxide) unit is the expression (CH2CH(CH3)O) where x≧2. x It is defined as a unit represented by .

[0073] In a more preferred embodiment of the present invention, the general formula defined above is R 1 (-F) x (I) In the compound, R 1 This is the general formula (IIIa), (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) Or general formula (IVa) (-C(O)-XR 6 )m -C(O)-XR 7 (IVa) Here X and R 6 And m is as defined above. It includes at least one part of, Here R 7 It has 1 to 36 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, [ka] Quaternary ammonium group [ka] A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical, independently selected from, where radical R, comprising one or more groups selected from, and which may be substituted with an OH group or a halide group, wherein radical R is the radical. 7 It cannot contain internal carboxyl groups or amides, i.e., R 7 It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group.

[0074] According to this embodiment, radical R 7 This can be the same or different and can be selected from optionally substituted linear, cyclic or branched, saturated or unsaturated hydrocarbon radicals having 1 to 36 carbon atoms, and thus can represent a hydrocarbyl group selected from the group consisting of linear, branched or cyclic alkyl groups, linear, branched or cyclic alkenyl groups, linear, branched or cyclic alkynyl groups, linear, branched or cyclic alkaryl groups, linear, branched or cyclic aralkyl groups, and linear, branched or cyclic aryl groups, such as phenyl, benzyl or tolyl, in particular such groups having 6 to 24 carbon atoms, each optionally containing one or more of the above functional groups.

[0075] Comfortable, R 7 Radicals are derived from linear alkyl and linear alkenyl groups, particularly linear C6-C24 alkyl groups, such as hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or linear C6-C24 alkenyl groups. For example, selected from hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where the group is most preferably bonded to an adjacent X group by a terminal C atom.

[0076] Which C atom of the hydrocarbyl radical has an adjacent X group R 7 There are no restrictions on whether it should be combined with other elements.

[0077] However, R 7 It is preferably derived from a carboxylic acid or a hydroxycarboxylic acid having one or more hydroxyl groups, more preferably from a carboxylic acid or monohydroxycarboxylic acid, and most preferably from a C7-C25 fatty acid that does not have a hydroxyl group as a substituent. Therefore, R 7 Preferably, R 7 The group represents the alkyl or alkenyl chain of such carboxylic acids, as shown in the example given above.

[0078] R according to this embodiment 7A preferred example is a structure derived from the corresponding carboxylic acid or hydroxylcarboxylic acid by removing a carboxylate group, where the carboxylic acid is acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, enanthic acid, capric acid, pelargonic acid, capric acid, undecanoic acid, lauric acid, tridecanoic acid, myristic acid, pentadecanoic acid, palmitic acid, margaric acid, stearic acid, linoleic acid, α-linolenic acid, γ-linolenic acid, oleic acid, nonadecyl acid, arachidic acid, meadic acid, arachidic acid, henicosacral acid The following can be selected from nonacids, docosanoic acid, tricosylic acid and lignoceric acid; hydroxylcarboxylic acids, such as reskerolic acid, ricinoleic acid, 10-hydroxyoctadecanoic acid, 12-hydroxyoctadecanoic acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid; or dihydroxycarboxylic acids, particularly 2,2'-dihydroxymethylpropanoic acid and 9,10-dihydroxystearic acid; or polyhydroxycarboxylic acids, particularly gluconic acid.

[0079] More preferably, R according to this embodiment 7 The radicals are derived from palmitic acid, margaric acid, stearic acid, linoleic acid, alpha-linolenic acid, gamma-linolenic acid, oleic acid, nonadesylic acid, arachidic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, ricinoleic acid, reskerolic acid, or 2,2'-dihydroxymethylpropanoic acid.

[0080] The most preferred R in this embodiment 7 The radicals are oleic acid, stearic acid, reskerolic acid, and ricinoleic acid.

[0081] Radical R 7 The following are optional: -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, [ka] Quaternary ammonium group [ka] It may contain one or more groups selected from and may be substituted with an OH group or a halide group, but radical R 7 It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group, that forms an internal ester group or an internal amide group.

[0082] In a more preferred embodiment of the present invention, in a compound of the following general formula as defined above, R 1 (-F) x (I) residue R 1 or R 2 One or more of these include at least one part of general formula (III) or (IV), (-XC(O)-R 6 ) m -XC(O)- (III), or (-C(O)-XR 6 ) m -C(O)-X- (IV), Preferably, residue R 1 or R 2 One or more of these include at least one part of general formula (IIIa) or general formula (IVa), (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa), or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Here, X, R 6 , R 7 , and m are as defined above.

[0083] According to this embodiment, residue R 1 or R 2 In part (IIIa) or (Iva) of the equation, X=O, R 6 These are optionally hydroxylated hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecilen, octadecylene, nonadecilen, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene, or hexenylene, heptenylene, octenylene, nonenilen Independently selected from decenylene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicocenylene, henicocenylene, doicocenylene, tricocenylene, and tetraicocenylene, where the group is most preferably bonded to an adjacent C(O) or O group by a terminal C atom. R 7 The group is independently selected from hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where the group is most preferably bonded to an adjacent C(O) group by a terminal C atom. And m is preferably 1-10, more preferably 1, 2, 3, 4, or 5.

[0084] X=O, R 6 It is selected from hexadecirine, heptadecirene, octadecirene, nonadecirine, eicocirine, hexadecenirene, heptadecenirene, octadecenirene, nonadecenirene, and eicocenirene. R 7It is selected from hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosylhexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, and eicocenyl. Furthermore, it is even more preferable that m is 1, 2, 3, 4, or 5.

[0085] According to this embodiment, X=O, R 6 It is derived from ricinoleic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or reskerolic acid. R 7 It is derived from oleic acid, ricinoleic acid, or stearic acid. And it is most preferable that m is 1, 2, 3, 4, or 5.

[0086] In another preferred embodiment of the present invention, the general formula R as defined above is used. 1 (-F) x In compound (I), at least 1% of all groups F comprises at least one part of general formula (III) or (IV), more preferably at least 10% of all groups F comprises at least one part of general formula (III) or (IV), even more preferably at least 50% of all groups F comprises at least one part of general formula (III) or (IV), and most preferably at least 100% of all groups F comprises at least one part of general formula (III) or (IV), or here at least 1% of all groups F comprises at least one part of general formula (IIIa) or (IVa), more preferably at least 10% of all groups F comprises at least one part of general formula (IIIa) or (IVa), even more preferably at least 50% of all groups F comprises at least one part of general formula (IIIa) or (IVa), and most preferably at least 100% of all groups F comprises at least one part of general formula (IIIa) or (IVa).

[0087] According to this embodiment, each part of general formula (III) or (IV) of group F is optionally hydroxyl-substituted with hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecilen, octadecylene, nonadecilen, eicosilene, henicosilene, doicosilene, tricosilene, and tetradecylene. Lycosilene, or at least one R selected from hexenylene, heptenylene, octenylene, nonenylene, decenylene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicosenylene, henicosenylene, doicosenylene, trichosenylene, and tetraicosenylene 6 It is preferable that it includes, More preferably, each part of general formula (III) or (IV) of group F is optionally hydroxyl-substituted with at least one R selected from hexadecylene, heptadecylene, octadecylene, nonadecylene, eicosylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, and eicocenylene. 6 Includes, And m is 1, 2, 3, 4, or 5; And most preferably, R of each part of general formula (III) or (IV) of base F 6 It is derived from ricinoleic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or reskerolic acid. And m is 1, 2, 3, 4, or 5.

[0088] In a more preferred embodiment of the present invention, the general formula R as defined above is used. 1 (-F) x In compound (I), all groups R 2 At least 1% of the compound comprises at least one part of general formula (III) or (IV), and more preferably all of the base R 2At least 10% of the compound comprises at least one part of general formula (III) or (IV), and more preferably all of the base R 2 At least 50% of it comprises at least one part of general formula (III) or (IV), and most preferably all of the base R 2 100% of the formula contains at least one part of general formula (III) or (IV), or where all base R 2 At least 1% of the compound comprises at least one part of general formula (IIIa) or (IVa), and more preferably all of the base R 2 At least 10% of the compound comprises at least one part of general formula (IIIa) or (IVa), and more preferably all of the base R 2 At least 50% of the compound comprises at least one part of general formula (IIIa) or (IVa), and most preferably all of the base R 2 100% of it contains at least one part of general formula (IIIa) or (IVa).

[0089] According to this embodiment, base R 2 Each part of general formula (III) or (IV) is optionally hydroxylated with hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecilen, octadecylene, nonadecilen, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene. , or at least one R selected from hexenylene, heptenylene, octenylene, nonenylene, decenylene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicosenylene, henicosenylene, doicosenylene, trichosenylene, and tetraisenylene 6 If it includes, preferably, base R 2Each part of general formula (III) or (IV) is optionally hydroxyl-substituted with at least one R selected from hexadecylene, heptadecylene, octadecylene, nonadecylene, eicosylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, and eicocenylene. 6 Includes, And m is more preferably 1, 2, 3, 4, or 5. Most preferably, base R 2 R in each part of the general formula (III) or (IV) 6 It is derived from ricinoleic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or reskerolic acid. And m is 1, 2, 3, 4, or 5.

[0090] In another preferred embodiment of the present invention, the general formula R as defined above is used. 1 (-F) x In compound (I), all groups R 3 , R 4 and R 5 At least 1% of the compound comprises at least one part of general formula (III) or (IV), and more preferably all of the base R 3 , R 4 and R 5 At least 10% of the compound comprises at least one part of general formula (III) or (IV), and more preferably all of the base R 3 , R 4 and R 5 At least 50% of the compound comprises at least one part of general formula (III) or (IV), and most preferably all of the base R 3 , R 4 , and R 5 100% of the formula contains at least one part of general formula (III) or (IV), or all of the base R 3 , R 4 and R 5 At least 1% of the compound comprises at least one part of general formula (IIIa) or (IVa), and more preferably all of the base R 3 , R4 and R 5 At least 10% of the compound comprises at least one part of general formula (IIIa) or (IVa), and more preferably all of the group R 3 , R 4 and R 5 At least 50% of the compound comprises at least one part of general formula (IIIa) or (IVa), and most preferably all of the base R 3 , R 4 and R 5 100% of it contains at least one part of general formula (IIIa) or (IVa).

[0091] According to this embodiment, base R 3 , R 4 and R 5 Each part of general formula (III) or (IV) is optionally hydroxylated with hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecilen, octadecylene, nonadecilen, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene. , or at least one R selected from hexenylene, heptenylene, octenylene, nonenylene, decenylene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicosenylene, henicosenylene, doicosenylene, trichocenylene, and tetraicosenylene 6 If it includes, preferably, base R 3 , R 4 and R 5 Each part of general formula (III) or (IV) is optionally hydroxyl-substituted with at least one R selected from hexadecylene, heptadecylene, octadecylene, nonadecylene, eicosylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, and eicocenylene. 6 Includes, And m is more preferably 1, 2, 3, 4, or 5, and Most preferably, base R 3 , R 4 and R 5 R in each part of the general formula (III) or (IV) 6 It is derived from ricinoleic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or reskerolic acid. And m is 1, 2, 3, 4, or 5.

[0092] In yet another preferred embodiment of the present invention, the general formula R as defined above is used. 1 (-F) x In compound (I), x is 2, and the compound is of formula (V), [ka] Here R 1 , R 2 , R 3 , R 4 , R 5 , and n are as defined above.

[0093] In a preferred embodiment of the present invention, the general formula R as defined above is used. 1 (-F) x Compound (I) is provided, and here R 1 It has a maximum of 1000 carbon atoms, preferably 2 to 300 carbon atoms, more preferably 3 to 200 carbon atoms, even more preferably 3 to 150 carbon atoms, more specifically 3 to 50 carbon atoms, and more specifically 3 to 20 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from optionally substituted monovalent to pentavalent hydrocarbon radicals, which may comprise one or more groups selected from and may be substituted with -OH groups and halide groups, preferably R 1These are C3-C18 glycerol-based polyether radicals or C1-C8 linear alkylene radicals. F has a general formula (VI) that corresponds to formula (II) where n is equal to 0, [ka] And the base F is R 1 Bonded to the carbon atom, Here R 3 , R 4 , R 5 It has hydrogen and up to 300 carbon atoms, preferably 1 to 200 carbon atoms, more preferably 1 to 150 carbon atoms, even more preferably 1 to 50 carbon atoms, specifically 1 to 20 carbon atoms, more specifically 1 to 10 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, [ka] Quaternary ammonium group [ka] A optionally substituted linear, cyclic, or branched, saturated, unsaturated, or aromatic hydrocarbon radical comprising one or more groups selected from and which may be substituted with OH, preferably R 3 From R 5 This is a C1-C8 linear alkyl group, for example, methyl, ethyl, propyl, or butyl, or a linear alkyl group comprising one or more parts of general formula (III) or (IV), more preferably a linear alkyl group ending with a group of general formula (IIIa) or (IVa). Counterion A -The anions are selected from monovalent to trivalent inorganic anions and monovalent to 30,000-valent, preferably monovalent to 1,000-valent organic anions, preferably halogenated anions, such as chlorides, bromides, iodides, sulfates, phosphates, phosphonates, sulfonates, methosulfates, carboxylate anions, such as acetates, propionic acid, lactates, octanoates, 2-ethyl-hexanoates, dodecanoates, hexadecanoates, octadecanoates, oleates, ricinolates, 12-hydroxy-octadecanoates, succinates, maleates, tartrates, polyether carboxylates, and polymer fatty acid carboxylates of the following types. R 1 [(-C(O)-XR 6 ) m -C(O)-XR 7 ] x ,or R 1 [(XC(O)-R 6 ) m -XC(O)-R 7 ] x , Here R 1 or R 7 At least one of the following, or R 1 and R 7 At least one of them has one or more carboxylate groups, Preferably X = O, especially, - The following types of linear polymer fatty acid carboxylates, -OC(O)-R 6 (-XC(O)-R 6 ) m-1 -XC(O)-R 7 Preferably -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , In other words, it originates from a linear polyfatty acid structure, - Branched linear polymer fatty acid carboxylates, In other words, it originates from a branched polyfatty acid structure, In particular, branched linear polymer fatty acid carboxylates derived from partial esters of polyfunctional carboxylic acids, especially dicarboxylic acids, succinic acid, and maleic acid with castor oil or rescera oil, for example, [ka] Here, one R = [ka] And the remaining two R groups = [ka] - Dendrimer-like high molecular weight fatty acid carboxylate, In other words, it originates from a dendrimer-like polyfatty acid structure, Or the following types, XR 6 (-C(O)-XR 6 ) m-1 -C(O)-XR 7 ,or R 6 (-C(O)-XR 6 ) m-1 -C(O)-XR 7 , Here, in the latter two types, R 7 The group has at least one anionic carboxylate group, Or the following types, R 1 [(-C(O)-X-R6) m -C(O)O - ] x , And here are X and R 1 , R 6 , R 7 m and x are as defined above, Here, the counterion A of this group -The anion is preferably monovalent to 50valent, more preferably monovalent to 10valent, even more preferably monovalent to 5valent, most preferably pentavalent, tetravalent, trivalent, divalent, or monovalent. Selected from, Alternatively, the counter anion is a carboxylate anion based on poly(acrylic acid) homopolymers and copolymers. In other words, carboxylate derived from polyacrylic acid homopolymer [ka] Here, p = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Carboxylate anions derived from polyacrylic acid copolymers, That is, those containing non-reactive comonomers, for example [ka] Here a = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. b = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000 (effective for all comonomers), where Copolymers can have a block-like or random distribution of comonomer units. Alternatively, a carboxylate anion derived from a polyacrylic acid copolymer, for example, comprising a comonomer that provides OH and amine functional groups that can be functionalized via further ester or amide bonds with fatty acids or polyfatty acids, [ka] Here, c = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Alternatively, a carboxylate anion derived from a polyacrylic acid copolymer containing a carboxylic acid functional group comonomer, where Copolymers can have a block-like or random distribution of comonomer units. for example, [ka] Here d = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. e = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000 (effective for all comonomers). Carboxylates based on maleic acid copolymers, particularly those derived from maleic anhydride copolymers, here Copolymers can have a block-like or random distribution of comonomer units. for example, [ka] Here f = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, even more preferably 1000 to 10000 (effective for all comonomers), and g = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Carboxylates based on poly(itaconic acid) homo and copolymers, In other words, it is derived from polyitaconate homopolymer, [ka] Here, h = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Alternatively, that is, derived from poly(itaconic acid) copolymers containing non-reactive comonomers, Here Copolymers can have a block-like or random distribution of comonomer units. for example [ka] Here i = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000 (effective for all comonomers). j = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Alternatively, a polyitaconic acid copolymer, for example, derived from a 2-hydroxyethyl methacrylate-itaconic acid copolymer, comprising a comonomer that provides OH and amine functional groups that can be functionalized via further ester or amide bonds with fatty acids or polyfatty acids, Alternatively, derived from a polyitaconic acid copolymer containing a carboxylic acid functional group-containing comonomer, where Copolymers can have a block-like or random distribution of comonomer units. for example [ka] Here k = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000 (effective for all comonomers). l = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Here, the anion of this group is preferably an anion with a valency of 2 to 30,000, more preferably 2 to 1,000, even more preferably 10 to 1,000, even more preferably 50 to 1,000, and most preferably 100 to 1,000. Selected from the group consisting of, However, the cationic radical R of general formulas (I) and (II) 1 , R 3 , R 4 , R 5 The condition is that at least one of them contains at least one part of general formula (IIIa) or (IVa), (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Here, X is as defined above, m=1 to 20, preferably 1 to 10, more preferably 1 to 6, even more preferably 2 to 6, specifically 1, 2, 3, 4, 5, 6, and R 11 Preferably, hydrogen, n-, iso-, or tert.-C1-C 22 -alkyl, C2-C 22 -Alkoxyalkyl, C5-C 30 -Cycloalkyl, C6-C 30 -Aryl, C6-C 30 -Aryl (C1-C6)alkyl, C6-C 30 -Alkylaryl, C2-C 22 -Alkenyl, C2-C 22 - Alkenyloxyalkyl groups that may be optionally substituted with hydroxyl and halogen groups, respectively, and may optionally contain one or more ether groups (-O-), preferably hydrogen, or n-, iso-, or tert.-C1-C 22 - Selected from the group consisting of alkyl groups, R 6is independently selected from optionally substituted linear, cyclic, or branched saturated or unsaturated hydrocarbon radicals having 1 to 36 carbon atoms, preferably 1 to 24 carbon atoms, more preferably 1 to 18 carbon atoms, and even more preferably 8 to 18 carbon atoms, preferably R 6 This is a linear alkylene or alkenylene group from C6 to C24, most preferably derived from ricinoleic acid or reskerolic acid. R 7 It has 1 to 36 carbon atoms, preferably 1 to 24 carbon atoms, more preferably 1 to 18 carbon atoms, and even more preferably 8 to 18 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, [ka] Quaternary ammonium group [ka] A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical, independently selected from, where radical R, comprising one or more groups selected from, and which may be substituted with an OH group or a halide group, wherein radical R is the radical. 7 It cannot include a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group that forms an internal carboxylate group or an internal amide group, preferably R 7 is a C6 to C24 alkyl or alkenyl group, more preferably a linear C12 to C24 alkyl or C12 to C24 alkenyl group, most preferably derived from linolenic acid, linolenic acid or oleic acid, However, at least one R 6 It has more than six carbon atoms, and For x=1 R 1 , R 3 , R 4 , R 5 is -OCH2CH2 - Does not bond to the nitrogen atom of the following group via These are the conditions. [ka]

[0094] In a more preferred embodiment of the present invention, the following compound R 1 (-F) x (I) It is provided here R 1 It has a maximum of 1000 carbon atoms, preferably 2 to 300 carbon atoms, more preferably 3 to 200 carbon atoms, even more preferably 3 to 150 carbon atoms, specifically 3 to 50 carbon atoms, and more specifically 3 to 20 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, [ka] Quaternary ammonium group [ka] A hydrocarbon radical that may comprise one or more groups selected from and may be substituted with -OH, having a valency of 1 to 50, preferably 1 to 30, more preferably 1 to 20, and even more preferably 1 to 10, specifically selected from hydrocarbon radicals optionally substituted with 1, 2, 3, 4, 5, 6, 7, 8, 9, and 10, and F has the general formula (VI), [ka] And the base F is R 1 Bonded to the carbon atom, Here R 3 , R 4 , R 5It has a maximum of 300 carbon atoms, preferably 1 to 200 carbon atoms, more preferably 1 to 150 carbon atoms, even more preferably 1 to 50 carbon atoms, specifically 1 to 20 carbon atoms, and more specifically 1 to 10 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, [ka] Quaternary ammonium group [ka] Selected from optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with OH groups, Counterion A - The anions are selected from monovalent to trivalent inorganic anions and monovalent to 30,000valent, particularly monovalent to 1,000valent organic anions, preferably halogenated anions, such as chlorides, bromides, iodides, sulfates, phosphates, phosphonates, sulfonates, methosulfates, carboxylate anions, such as acetates, propionates, lactates, octanoates, 2-ethylhexanoates, dodecanoates, hexadecanoates, octadecanoates, oleates, ricinolates, 12-hydroxyoctadecanoates, succinates, maleates, tartrates, and polyether carboxylates. The following types of high molecular weight fatty acid carboxylates, R 1 [(-C(O)-XR 6 ) m -C(O)-XR 7 ] x ,or R 1 [(XC(O)-R 6 ) m -XC(O)-R 7 ] x Here, R 1 or R 7 At least one of the following, or R1 and R 7 At least one of them has one or more carboxylate groups, Preferably X=O, especially, - The following types of linear polymer fatty acid carboxylates - OC(O)-R 6 (-XC(O)-R 6 ) m-1 -XC(O)-R 7 Preferably, - OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , In other words, it originates from a linear polyfatty acid structure, - Branched linear polymer fatty acid carboxylates, In other words, branched linear polymer fatty acid carboxylates derived from branched polyfatty acid structures, and in particular from partial esters of polyfunctional carboxylic acids, especially dicarboxylic acids, succinic acid, and maleic acid, with castor oil or rescera oil, for example, [ka] Here, one R = [ka] And the remaining two R groups = [ka] - Dendrimer-like high molecular weight fatty acid carboxylate, In other words, it originates from a dendrimer-like polyfatty acid structure, Or the following types: XR 6 (-C(O)-XR 6 ) m-1 -C(O)-XR 7 ,or R6 (-C(O)-XR 6 ) m-1 -C(O)-XR 7 , Here, in the latter two types, R 7 The group has at least one anionic carboxylate group, Or the following types: R 1 [(-C(O)-X-R6) m -C(O)O - ] x , And here are X and R 1 , R 6 , R 7 , m, and x are as defined above, and Here, the counterion A of this group - The anion is preferably monovalent to 50valent, more preferably monovalent to 10valent, even more preferably monovalent to 5valent, most preferably 5valent, 4valent, 3valent, 2valent, or monovalent. Alternatively, the counterion is selected from the group consisting of carboxylate anions based on poly(acrylic acid) homopolymers and copolymers. In other words, carboxylate derived from polyacrylic acid homopolymer [ka] Here, p = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Carboxylate anions derived from polyacrylic acid copolymers, That is, those containing non-reactive comonomers, for example [ka] Here a = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. b = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000 (effective for all comonomers), where Copolymers can have a block-like or random distribution of comonomer units. Alternatively, a carboxylate anion derived from an acrylic acid copolymer, for example, comprising a comonomer that provides OH and amine functional groups that can be functionalized via further ester or amide bonds with fatty acids or polyfatty acids, [ka] Here, c = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Alternatively, a carboxylate anion derived from a polyacrylic acid copolymer containing a carboxylic acid functional group comonomer, where Copolymers can have a block-like or random distribution of comonomer units. for example [ka] Here d = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. e = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000 (effective for all comonomers). Carboxylates based on maleic acid copolymers, particularly those derived from maleic anhydride copolymers, here Copolymers can have a block-like or random distribution of comonomer units. for example [ka] Here f = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, even more preferably 1000 to 10000 (effective for all comonomers), and g = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Carboxylates based on poly(itaconic acid) homo and copolymers, In other words, it is derived from polyitaconate homopolymer, [ka] Here, h = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Alternatively, that is, derived from polyitaconate copolymers containing non-reactive comonomers, Here Copolymers can have a block-like or random distribution of comonomer units. for example, [ka] Here i = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000 (effective for all comonomers). j = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Alternatively, a polyitaconic acid copolymer, for example, derived from a 2-hydroxyethyl methacrylate-itaconic acid copolymer, comprising a comonomer that provides OH and amine functional groups that can be functionalized via further ester or amide bonds with fatty acids or polyfatty acids, Alternatively, derived from a polyitaconic acid copolymer containing a carboxylic acid functional group-containing comonomer, where Copolymers can have a block-like or random distribution of comonomer units. for example [ka] Here k = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000 (effective for all comonomers). l = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Here, the anion of this group is preferably an anion with a valency of 2 to 30,000, more preferably 2 to 1,000, even more preferably 10 to 1,000, and most preferably 100 to 1,000. However, the radical R of the cationic structure of formulas (I) and (II) 1 , R 3 , R 4 , R 5 The condition is that at least one of them contains at least one part of general formula (VII) or (VIII), -XC(O)-R x -(XC(O)-R x ) m-1 -XC(O)-R 7 (VII) or -XC(O)-R x -(XC(O)-R x ) m -XC(O)-R 7 (VIII) Here X is O or NR 11 And, m=1 to 20, preferably 1 to 10, more preferably 1 to 6, even more preferably 2 to 6, specifically 1, 2, 3, 4, 5, 6, and R x +R 7 The total number of carbon atoms (Σ carbon atoms R x , R 7) is 19 to 300, preferably 25 to 300, more preferably 35 to 300, even more preferably 50 to 300, specifically 35 to 200, more specifically 35 to 150, and even more specifically 50 to 150, R 11 is preferably selected from hydrogen, n-, iso-, or tert.-C1-C22-alkyl, and more preferably hydrogen. R x The following are optional: OH, -OC(O)-R 7 -OC(O)-R 6 -(OC(O)-R 6 ) 0-19 -OC(O)-R 7 A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical having 1 to 36 carbon atoms, preferably 1 to 24 carbon atoms, more preferably 1 to 18 carbon atoms, and even more preferably 8 to 18 carbon atoms, preferably derived from monohydroxycarboxylic acids, particularly glycolic acid, lactic acid, 2-hydroxybutyric acid, 3-hydroxy-butyric acid, 4-hydroxybutyric acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, reskerolic acid, ricinoleic acid, or dihydroxycarboxylic acids, particularly 2,2'-dihydroxymethylpropanoic acid, 9,10-dihydroxystearic acid, or polyhydroxycarboxylic acids, particularly gluconic acid. R 6 This is defined as above, R 7This is an optionally substituted linear, cyclic, or branched saturated or unsaturated hydrocarbon radical having 1 to 36 carbon atoms, preferably 1 to 24 carbon atoms, more preferably 1 to 18 carbon atoms, and even more preferably 8 to 18 carbon atoms, preferably derived from acetic acid, octanoic acid, nonanoic acid, decanoic acid, dodecanoic acid, tetradecanoic acid, hexadecanoic acid, octadecanoic acid, eicosanoic acid, docosanoic acid, 2-ethylhexanoic acid, 2,2-dimethylpropionic acid, 2,2-dimethylheptanoic acid, 2,2-dimethyloctanoic acid, neodecanoic acid, undecyl-10-enoic acid, oleic acid, linoleic acid, linolenic acid, or erucic acid. Selected from.

[0095] According to this embodiment, R 6 These are optionally hydroxyl-substituted hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecilen, octadecylene, nonadecilen, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene, or hexenylene, heptenylene, octenylene, nonenilen, decenylene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecene Preferably, each R is independently selected from nylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicocenylene, henicocenylene, doicocenylene, tricocenylene, and tetraicocenylene, more preferably, optionally hydroxyl-substituted, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicocenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, and eicocenylene, most preferably, each R 6 It is derived independently from ricinoleic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or reskerolic acid.

[0096] In a more preferred embodiment of the present invention, a compound of the following formula as defined above is used. R1 (-F) x (I) It is provided here R 1 teeth, - A tertiary amine having at least 3, preferably more than 3 carbon atoms, which is optionally OH or amide-substituted, linear, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon group, which is univalent to 18-valent, preferably divalent to 18-valent, more preferably divalent to 6-valent, and even more preferably divalent, trivalent and tetravalent, and which is tertiary amine in which at least 3, preferably more than 3 carbon atoms, particularly trimethylamine, triethylamine, tributylamine, N,N-dimethylethanolamine, N,N-dimethylpropanolamine, N-methylimidazole, N,N,N',N'-tetramethyl-1,2-diaminoethane, N,N,N',N'-tetramethyl-1,4-diaminobutane, N,N,N',N'-tetramethyl-1,6-diaminohexane, N,N,N',N'',N''-pentamethyl-diethylenetriamine, N,N,N',N'',N''- Pentamethyl-dipropylenetriamine, bis-(2-dimethylaminoethyl) ether, bis-(2-dimethylaminopropyl) ether, 2,2'-dimorpholinodiethyl ether, N,N-bis-(3-dimethylaminopropyl)-N-isopropanolamine, N,N,N'-trimethylaminoethyl-ethanolamine, 1,3,5-tris(3-(dimethylamino)propyl)-hexahydro-s-triazine, epoxy compounds, especially glycidyl ethers, and alcohols, especially methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-Hexanediol, glycerol, diglycerol, triglycerol, and higher-order linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), pentaerythritol, sorbitol, poly(alkylene oxides), e.g., (ethylene oxide)-, (propylene oxide)- and / or (butylene oxide)-based polyethers, e.g., derived from polyethylene glycol, e.g., diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol, etc., or derived from polypropylene glycol, e.g., dipropylene glycol (e.g., 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol) Derived from condensation products of panol, tripropylene glycol, tetrapropylene glycol, pentapropylene glycol, mixed (ethylene oxide) and (butylene oxide)-based copolyethers, mixed (propylene oxide) and (butylene oxide)-based copolyethers, and mixed (ethylene oxide) and (propylene oxide) and (butylene oxide)-based copolyethers, or preferably derived from glycidyl esters of primary or secondary amino-functionalized amines, particularly N,N-dimethylpropylenediamine, N,N,N',N'-tetramethyl-diethylenetriamine, N,N,N',N'-tetramethyl-dipropylenetriamine, N-methylmorpholine, N-methylpiperazine, with an acid, particularly neodecanoic acid; and, - Linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon groups optionally substituted with OH, amino, or amide, having a valency of 1 to 18, preferably 2 to 18, more preferably 2 to 6, and even more preferably 2, 3, and 4, derived from alkyl halides having one or more carbon atoms, preferably two or more, such as alkyl chlorides, bromides, and iodides, e.g., 1,3-dichloropropane, 1,3-dichlorobutane, 1,4-dichlorobutane, dichloro-monohydroxypropane isomers, 1,2,3-trichloropropane, 1,2-dichlorohexanediol, 1,2-dichlorohexane, or their respective bromide and iodide derivatives; - Linear, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon groups optionally substituted with OH, amino or amide, having a valency of 1 to 18, preferably 2 to 18, more preferably 2 to 6, and even more preferably 2, 3 and 4, wherein the valency is 1 to 18, preferably 2 to 18, more preferably 2 to 6, and even more preferably 2, 3 and 4, and are halogenated carboxylic acids, preferably chlorocarboxylic acids, having a total of more than 2, preferably more than 3 carbon atoms, for example, chloroacetic acid, 3-chloropropionic acid, 4-chlorobutanoic acid or esters of the respective bromocarboxylic acids, alcohols, particularly methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycero Derived from polyethers, diglycerols, triglycerols, and higher-order linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), pentaerythritol, sorbitol, poly(alkylene oxides), e.g., (ethylene oxide)-, (propylene oxide)- and / or (butylene oxide)-based polyethers, e.g., polyethylene glycol, e.g., diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol, or derived from mixed (ethylene oxide) and (butylene oxide)-based copolyethers, mixed (propylene oxide)- and (butylene oxide)-based copolyethers, and mixed (ethylene oxide)- and (propylene oxide)- and (butylene oxide)-based copolyethers, - Epoxy compounds, preferably glycidyl ethers, having a total of three or more carbon atoms, preferably four or more carbon atoms, comprising optionally OH-substituted linear, cyclic or branched saturated, unsaturated or aromatic hydrocarbon groups, preferably glycidyl ethers, alcohols, particularly methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, for example, (ethylene oxide)-, (propylene oxide)- and / or (butylene oxide)-based polyethers, for example, diethylene glycol, triethylene glycol, tetraethylene glycol Derived from polyethylene glycols such as glycidyl glycol and pentaethylene glycol, or from polypropylene glycols such as dipropylene glycol (e.g., derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol, derived from mixed (ethylene oxide)- and (butylene oxide)-based copolyethers, derived from mixed (propylene oxide)- and (butylene oxide)-based copolyethers, and derived from mixed (ethylene oxide)- and (propylene oxide)- and (butylene oxide)-based copolyethers, or from ethers or esters, preferably from acids of glycidyl esters, particularly neodecanoic acid. - A linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon group optionally substituted with OH, amino, or amide, having a total of two or more carbon atoms, preferably three or more, halogenated carboxylic acids, preferably chlorocarboxylic acids, such as chloroacetic acid, 3-chloropropionic acid, 4-chlorobutanoic acid, or their respective bromocarboxylic acids, ether or ester of an epoxy compound, preferably glycidyl ether According to the tel, alcohols, especially methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol, and higher-order linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), pentae Lithritol, sorbitol, poly(alkylene oxide), e.g., (ethylene oxide)-, (propylene oxide)- and / or (butylene oxide)-based polyethers, in particular derived from polyethylene glycol such as diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol, or dipropylene glycol (in particular derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), Formed from esters derived from polypropylene glycols such as repropylene glycol, tetrapropylene glycol, and pentapropylene glycol, from mixed (ethylene oxide) and (butylene oxide)-based copolyethers, from mixed (propylene oxide) and (butylene oxide)-based copolyethers, and from mixed (ethylene oxide) and (propylene oxide) and (butylene oxide)-based copolyethers, or from glycidyl esters with an acid, particularly neodecanoic acid, - A linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon group optionally substituted with OH, having a total of more than 7, preferably more than 8 carbon atoms, formed from an epoxy compound, preferably a glycidyl ether, with divalent to hexavalent carboxylic acids, particularly maleic acid, succinic acid, adipic acid, sebacic acid, itaconic acid, tartaric acid, trimellitic acid, fatty dimer acids, or carboxyl(-C(O)OH) functionalized polyester, and particularly preferably divalent to hexavalent carboxylic acids, for example maleic acid, succinic acid, adipic acid, sebacic acid, itaconic acid, tartaric acid, trimellitic acid, fatty dimer acids, as described above. Formed by condensation products of divalent to hexavalent alcohols or alkylene oxides described, such as ethylene oxide, propylene oxide, butylene oxide, and compounds containing at least one glycidoxy group, such as glycidol, diglycidyl ether, glycerol diglycidyl ether, glycerol triglycidyl ether, and oligomerized glycerol glycidyl ether, and butanediol diglycidyl ether, particularly succinic acid, maleic acid and tartaric acid, fatty dimeric acids, glycerol diglycidyl ether, polyesters, especially preferably oligomerized hydroxycarboxylic acids, particularly oligomerized lactic acid, 12-hydroxystearic acid, reskerolic acid, and ricinoleic acid, - Optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon groups having a total of five or more carbon atoms, preferably six or more, halogenated carboxylic acids, preferably chlorocarboxylic acid esters, e.g., chloroacetic acid, 3-chloropropionic acid, 4-chlorobutanoic acid, or bromocarboxylic acid esters derived from OH-functionalized polyesters, particularly preferably divalent to hexavalent carboxylic acids, e.g., maleic acid, succinic acid, adipic acid, sebaciac acid Condensation of succinic acid, itaconic acid, tartaric acid, trimellitic acid, and fatty dimer acids with divalent to hexavalent alcohols as described above, or alkylene oxides, such as ethylene oxide, propylene oxide, butylene oxide, and compounds containing at least one glycidoxy group, such as glycidol, diglycidyl ether, glycerol diglycidyl ether, glycerol triglycidyl ether, and oligomeric glycerol glycidyl ether, and butanediol diglycidyl ether, in particular, succinic acid, maleic acid, tartaric acid, or fatty dimer acids, formed by condensation products with glycerol diglycidyl ether, It is selected from the group consisting of the following.

[0097] In a more preferred embodiment of the present invention, the compound of the following formula defined above is used. R 1 (-F) x (I) It is provided here R 1 This is selected from poly(alkylene oxide) groups, preferably poly(alkylene oxide) groups of general formula (IX), -[CH2CH2O] q1 -[CH2CH(CH3)O] r1 -[CH2CH(C2H5)O] s1 -{[CH2CH2] q2 -[CH2CH(CH3)] r2 -[CH2CH(C2H5)] s2}- (IX) Here q1 = 0 to 49, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, r1 = 0 to 32, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5. s1 = 0 to 24, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, q2 = 0 or 1, r² = 0 or 1, s2 = 0 or 1, and Σ(q²+r²+s²)=1, However, the total number of carbon atoms in such poly(alkylene oxide) groups is 2 to 100, preferably 2 to 50, more preferably 2 to 30, even more preferably 2 to 20, specifically 2 to 15, or R 1 It is selected from divalent hydrocarbon groups derived from oligoglycerol of general formula (X), -[CH2CH(R 8 )CH2O] t1 -[CH2CH(R 8 )CH2)] t2 - (X) Here t1 = 0 to 32, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, specifically 1 and 2. t2=1, R 8 =OH or -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 -OC(O)-R 6 -N + (R 3 ,R 4 ,R 5 ), Here, m, X, R 3 , R 4 , R 5 , R 6 , and R 7 This is as defined above, However, this is subject to the condition that the total number of carbon atoms is 2 to 100, preferably 2 to 50, more preferably 2 to 30, even more preferably 2 to 20, specifically 2 to 15. or R 1 This is the general formula (XI) -[CH2CH2O] q1 -R 9 -[CH2CH2O] q1 -[CH2CH2] q2 - (XI) Here, q1 is either the same or different, as defined above, and q2 = 1. and equation (XII) -[CH2CH(R 8 )CH2O] t1 -R 9 -[CH2CH(R 8 )CH2O] t1 -[CH2CH(R 8 )CH2)] t2 - (XII) Here, t1, t2, and R 8 This is as defined above, and R 9 is -C(O)C(O)O-, -C(O)(CH2) 1-8 C(O)O-, for example, derived from succinic acid, adipic acid, sebacic acid, or -C(O)(C6H4)C(O)O-, i.e., derived from phthalic acid and terephthalic acid, selected from -C(O)CH=CHC(O)O-, -C(O)C(=CH2)-CH2C(O)O-, and -C(O)CH(OH)CH(OH)C(O)O-. However, R 9 The condition is that the total number of carbon atoms is 2 to 100, preferably 2 to 50, more preferably 2 to 30, even more preferably 2 to 20, specifically 2 to 15. Selected from divalent hydrocarbon groups containing at least one ester group.

[0098] According to the embodiment, preferably q2 = 0, and one or two of q1, r1 and s1 are 0, and more preferably, q2=0, r1 and s1 are 0, or q2=0, and q1 and s1 are 0.

[0099] In a more preferred embodiment of the present invention, the compound of general formula (I) is as defined in the above embodiment, and R 1 It contains one or more groups, for example, 1 to 5 -O- groups. These -O- groups are preferably ether groups, but can also form ester groups with carbonyl groups, and preferably group R 1 It is substituted with one or more hydroxyl groups.

[0100] In a more preferred embodiment of the present invention, the compound of the following formula defined above is used. R 1 (-F) x (I) Provided Here N + The radical R that is bound to it 1 , R 3 , R 4 , R 5 One or more of these are general formulas (III) or (IV), (-XC(O)-R 6 ) m -XC(O)- (III), or (-C(O)-XR 6 ) m -C(O)-X- (IV), Preferably, general formula (IIIa) or (IVa) (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa), or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Here, m = 1-20, and X, R 6 and R 7 This is as defined above. If it includes at least one part of, At least one part is general formula (XIII) or (XIV), -R 10 (-XC(O)-R 6 ) m -XC(O)- (XIII) -R 10 (-C(O)-XR 6 ) m -C(O)-X- (XIV), Preferably, general formulas (XIIIa) and (XIVa), -R 10 (-XC(O)-R 6 ) m -XC(O)-R 7 (XIIIa) -R 10 (-C(O)-XR 6 ) m -C(O)-XR 7 (XIVa) It has a structure, Here R 10 It has a maximum of 200 carbon atoms, preferably 2 to 200 carbon atoms, more preferably 2 to 100 carbon atoms, even more preferably 2 to 50 carbon atoms, specifically 2 to 20 carbon atoms, more specifically 2 to 10 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, [ka] Quaternary ammonium group [ka] A hydrocarbon radical selected from which one or more groups may be selected from and may be substituted with -OH or a halide group, having a valency of divalent to 18, preferably divalent to decavalent, more preferably divalent to decavalent, specifically selected from hydrocarbon radicals optionally substituted with divalent, trivalent, tetravalent, pentavalent, hexavalent, heptavalent, octavalent, notavalent, and decavalent, where radical R 10It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group, which form an internal carboxylate group or an internal amide group. And preferably R 10 teeth, - Divalent radicals, particularly -CH2-, -CH2CH2-, -CH2CH2CH2-, preferably derived from monochlorocarboxylic acids such as chloroacetic acid, chloropropionic acid, and chlorobutanoic acid, or preferably derived from tertiary amino alcohols such as N,N-dimethylethanolamine and N,N-dimethylpropanolamine. - Derived from a trivalent radical, preferably a trivalent alcohol, particularly glycerol, trimethylolpropane, or castor oil (ricinoleic acid triglyceride), a partial ester of the monochlorocarboxylic acid, particularly ester with chloroacetic acid, or preferably derived from a tertiary amino alcohol such as N,N,N'-trimethylaminoethyl-ethanolamine, or preferably derived from a dihydroxycarboxylic acid, particularly 2,2-hydroxymethylpropanoic acid, a tertiary amino alcohol, particularly ester of N,N-dimethylethanolamine or N,N-dimethylpropanolamine, - Derived from partial esters of the monochlorocarboxylic acid, particularly esters of chloroacetic acid, by tetravalent to hexavalent radicals, preferably tetravalent alcohols, particularly erythritol, pentaerythritol, diglycerol, pentavalent alcohols, particularly xylitol, triglycerol, and hexavalent alcohols, particularly sorbitol, tetraglycerol, or preferably from dendrimer oligomers of dihydroxycarboxylic acid oligomers, particularly dendrimer oligomers of 2,2-hydroxymethylpropanoic acid, derived from esters of tertiary amino alcohols, particularly N,N-dimethylethanolamine and N,N-dimethylpropanolamine, Derived from the partial esters of the monochlorocarboxylic acid, particularly esters of chloroacetic acid, by radicals with 7- to 18 valencies, alcohols with 7- to 18 valencies, especially pentaglycerol to hexadecaglycerol, Represented by, However, R 10 N is formed by a single bond. + A portion is bonded to and at least one radical of the structure of general formula (III) or (IV), preferably 1, 2, 3, or 4 radicals, (-XC(O)-R 6 ) m -XC(O)- (III), or (-C(O)-XR 6 ) m -C(O)-X- (IV), And more preferably, 1, 2, 3, or 4 radicals of general formula (IIIa) or (IVa), (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) It is connected, Here, X, m, R 11 , R 6 , R 7 This is the condition that it is as defined above.

[0101] According to the above embodiment, X=O, R 6These are optionally hydroxylated hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecylene, octadecylene, nonadesilene, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene, or hexenylene, heptenylene, octenylene, nonenilen, decene A group independently selected from nylene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicocenylene, henicocenylene, doicocenylene, tricocenylene, and tetraicocenylene, where the group is most preferably bonded to an adjacent C(O) or O group by a terminal C atom, and present, R 7 The group is independently selected from hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where the group is most preferably bonded to an adjacent C(O) group by a terminal C atom. and m is preferably 1-10, more preferably 1, 2, 3, 4, or 5.

[0102] X=O, R 6 is selected from hexadecirine, heptadecirene, octadecirene, nonadecirine, eicocirine, hexadecenirene, heptadecenirene, octadecenirene, nonadecenirene, eicocenirene, and if present, R 7It is selected from hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosylhexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, and eicocenyl. Furthermore, it is even more preferable that m is 1, 2, 3, 4, or 5.

[0103] According to this embodiment, X=O, R 6 It is derived from ricinoleic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or reskerolic acid, and if present, R 7 It is derived from oleic acid, ricinoleic acid, or stearic acid, and m is most preferably 1, 2, 3, 4, or 5.

[0104] In a more preferred embodiment of the present invention, the compound of the following formula defined in the above embodiment is R 1 (-F) x (I) Provided Regarding this part, -R 10 (-XC(O)-R 6 ) m -XC(O)- (XIII), or preferably -R 10 (-XC(O)-R 6 ) m -XC(O)-R 7 (XIIIa) Here R 10 The adjacent X is O, R 10 It is derived from mono- or di-(chloroacetic acid) esters of glycerol or castor oil (ricinoleic acid triglyceride), and in total, one or two parts (-XC(O)-R 6 ) m -XC(O)-, preferably (-XC(O)-R) 6 ) m -OC(O)-R 7 It is connected, or R 10 It is derived from tertiary amino alcohols, particularly esters of N,N-dimethylethanolamine, N,N-dimethylpropanolamine, and N,N,N'-trimethylaminoethylethanolamine, and in total, one part (-XC(O)-R 6 ) m -OC(O)-R 7 Preferably (-XC(O)-R 6 ) m -OC(O)-R 7 It is connected, or R 10 It is derived from esters of tertiary amino alcohols, particularly N,N-dimethylethanolamine and N,N-dimethylpropanolamine, by dihydroxycarboxylic acids, especially 2,2-hydroxymethylpropanoic acid, and in total, two parts (-XC(O)-R 6 ) m -XC(O)-, preferably (-XC(O)-R) 6 ) m -OC(O)-R 7 It is connected, or R 10 These are derived from tertiary amino alcohols, particularly esters of N,N-dimethylethanolamine and N,N-dimethylpropanolamine, by dendrimer oligomers of dihydroxycarboxylic acid, especially dendrimer oligomers of 2,2-hydroxymethylpropanoic acid, and in total, more than two, preferably three or four parts (-XC(O)-R 6 ) m -XC(O)-, preferably (-XC(O)-R) 6 ) m -OC(O)-R 7 It is connected, And regarding the parts, -R 10 (-XC(O)-R 6 ) m -XC(O)- (XIII) or preferably -R 10 (-XC(O)-R 6 ) m -XC(O)-R7 (XIIIa) Here R 10 The adjacent X is N, R 10 These are derived from tertiary-primary amines, particularly N,N-dimethyl-1,3-propanediamine, N-methyl-N'-aminopropyl-piperazine, and tertiary-secondary amines, particularly N-methylpiperazine, and For both types of parts, R 6 These are as defined above, and are preferably derived from lactic acid, ricinoleic acid, reskerolic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, 14-hydroxytetradecanoic acid, and most preferably derived from ricinoleic acid or reskerolic acid. R 7 These are as defined above, and are preferably derived from octadecanoic acid, eicosanoic acid, docosanoic acid, 2-ethylhexanoic acid, 2,2-dimethylpropionic acid, neodecanoic acid, and oleic acid. m = 1 to 20, preferably 1 to 10, more preferably 1 to 6, even more preferably 2 to 6, specifically 1, 2, 3, 4, 5, 6, 7, and R 6 +R 7 The total number of carbon atoms (ΣR 6 and R 7 The carbon atoms are 19 to 300, preferably 25 to 300, more preferably 35 to 300, even more preferably 50 to 300, specifically 35 to 200, more specifically 35 to 150, and even more specifically 50 to 150. R 11 The element is preferably selected from the group consisting of hydrogen or ring-forming alkylenes, and is particularly derived from a piperazine ring.

[0105] In a more preferred embodiment of the present invention, as defined in the two embodiments above, a compound of the following formula, R 1 (-F) x (I) Provided Here R6 These are as defined above, and are preferably derived from lactic acid, ricinoleic acid, reskerolic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, 14-hydroxytetradecanoic acid, and most preferably derived from ricinoleic acid or reskerolic acid. R 7 These are as defined above, and are preferably derived from octadecanoic acid, eicosanoic acid, docosanoic acid, 2-ethylhexanoic acid, 2,2-dimethylpropionic acid, neodecanoic acid, and oleic acid. And as for the parts, -R 10 (-XC(O)-R 6 ) m -XC(O)- (XIII) and -R 10 (-C(O)-XR 6 ) m -C(O)-X- (XIV), Preferably, for the part, -R 10 (-XC(O)-R 6 ) m -XC(O)-R 7 (XIIIa) and -R 10 (-C(O)-XR 6 ) m -C(O)-XR 7 (XIVa) Radical R within the ester segment 6 , and R if present 7 The sequence is either random or blocky, and for blocky sequences, the compound has the general formula (XV) or (XVI), -R 10 -XC(O)-R 6 (-XC(O)-R 61 ) m1 (-XC(O)-R 62 ) m2 -XC(O)- (XV) -R 10 -C(O)-XR 6 (-C(O)-XR 61 ) m1(-C(O)-XR 62 ) m2 -C(O)-X- (XVI), Preferably, the general formula is (XVa) or (XVIa), -R 10 -XC(O)-R 6 (-XC(O)-R 61 ) m1 (-XC(O)-R 62 ) m2 -XC(O)-R 7 (XVa) -R 10 -C(O)-XR 6 (-C(O)-XR 61 ) m1 (-C(O)-XR 62 ) m2 -C(O)-XR 7 (XVIa) It includes the structure, Here R 61 and R 62 is R 6 Selected from, m1 = 0 to 20, preferably 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6. m2 = 0 to 20, preferably 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6. m=(m1+m2)+1, m=1 to 20, preferably 1 to 10, more preferably 1 to 6, even more preferably 1 to 6, specifically 1, 2, 3, 4, 5, 6, 7, and R 6 +R 7 The total number of carbon atoms (ΣR 6 and R 7 The carbon atoms are 19 to 300, preferably 25 to 300, more preferably 35 to 300, even more preferably 50 to 300, specifically 35 to 200, more specifically 35 to 150, and even more specifically 50 to 150. Here, the arrangement of the structures of general formulas (XV) and (XVI) is preferably selected from the following: [Table 1] The arrangement of the structures of general formulas (XVa) and (XVIa) is preferably selected from the following. [Table 2]

[0106] According to this embodiment, R 6 , R 61 , R 62 , or R 6 , R 61 , R 62 , and R 7 The combination is particularly preferred if it is selected according to the specific compound listed in one of the rows of the table above.

[0107] part (-XC(O)-R 6 ) m -XC(O)- (III) and (-C(O)-XR 6 ) m -C(O)-X- (IV) R is either unimodal or multimodal in terms of molecular weight distribution. 6 Incorporating ester segments is generally within the scope of this invention. In the context of this invention, the term "monomodal" means that ≥80% of the ester segments have the same molecular weight. The term "multimodal" means that none of the individual ester segments constitute 80% of the total composition.

[0108] In the section, (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) and (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) R is either unimodal or multimodal in terms of molecular weight distribution. 6 and R 7 Incorporating the contained ester segment is also generally within the scope of the present invention.

[0109] In the section, -R 10 (-XC(O)-R 6 ) m -XC(O)- (XIII) and -R 10 (-C(O)-XR 6 ) m -C(O)-X- (XIV), In particular, -R 10 (-XC(O)-R 6 ) m -XC(O)-R 7 (XIIIa) and -R 10 (-C(O)-XR 6 ) m -C(O)-XR 7 (XIVa) Regarding molecular weight distribution, R is either unimodal or multimodal. 6 and R 7 Incorporating (if present) contained ester segments is particularly within the scope of the present invention. The terms "unimodal" and "multimodal" have the meanings defined above.

[0110] In this embodiment, X=O, R 6These are optionally hydroxylated hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecilen, octadecylene, nonadecilen, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene, or hexenylene, heptenylene, octenylene, noneniylene, decenylene A group independently selected from lene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicocenylene, henicocenylene, doicocenylene, tricocenylene, and tetraicocenylene, where the group is most preferably bonded to an adjacent C(O) or O group by a terminal C atom, and present, R 7 These are independently selected from hydroxyl-substituted hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where these groups are most preferably bonded to adjacent C(O) groups by a terminal C atom. And m is preferably 1-10, more preferably 1, 2, 3, 4, or 5.

[0111] X=O, R 6 is selected from hexadecirine, heptadecirene, octadecirene, nonadecirine, eicocirine, hexadecenirene, heptadecenirene, octadecenirene, nonadecenirene, eicocenirene, and if present, R 7It is selected from hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosylhexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, and eicocenyl. Furthermore, it is even more preferable that m is 1, 2, 3, 4, or 5.

[0112] According to this embodiment, X=O, R 6 It is derived from ricinoleic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or reskerolic acid, and if present, R 7 It is derived from oleic acid, ricinoleic acid, or stearic acid. And it is most preferable that m is 1, 2, 3, 4, or 5.

[0113] In the part of the present invention, The compounds according to the present invention, which may be mono, di, and polyquaternary compounds, include a partial (-XC(O)-R 6 ) m -XC(O)- (III) and (-C(O)-XR 6 ) m -C(O)-X- (IV) Incorporating parts of one or more types (a mixture of different structures) is also within the scope of the present invention.

[0114] Therefore, the compound according to the present invention, (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) and (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Incorporating parts of one or more types (a mixture of different structures) is also within the scope of the present invention. And the compound according to the present invention, -R10 (-XC(O)-R 6 ) m -XC(O)- (XIII) and -R 10 (-C(O)-XR 6 ) m -C(O)-X- (XIV), Incorporating one or more types (a mixture of different structures) of a compound according to the present invention is also within the scope of the present invention, and in particular, the compound according to the present invention -R 10 (-XC(O)-R 6 ) m -XC(O)-R 7 (XIIIa) and -R 10 (-C(O)-XR 6 ) m -C(O)-XR 7 (XIVa) Incorporating one or more types (a mixture of different structures) of parts of the present invention is within the scope of this invention.

[0115] According to the present invention, the R of a portion 6 Containing ester elements, (-XC(O)-R 6 ) m -XC(O)- (III), (-C(O)-XR 6 ) m -C(O)-X- (IV), And in particular, the R of the part 6 and R 7 Containing ester elements, (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) and (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) And even more particularly in part -R 10 (-XC(O)-R 6 )m -XC(O)- (XIII), -R 10 (-C(O)-XR 6 ) m -C(O)-X- (XIV) -R 10 (-XC(O)-R 6 ) m -XC(O)-R 7 (XIIIa) and -R 10 (-C(O)-XR 6 ) m -C(O)-XR 7 (XIVa) For example, in a part -R 10 -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-, -R 10 -NR 1 -C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-, -R 10 -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 and -R 10 -NR 1 -C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , These can be synthesized from the corresponding carboxylic acids by esterification using methods known in the prior art. In preferred embodiments, these esterifications can be carried out thermally under reduced pressure at 180 to 250°C, preferably 150 to 350°C (US2011 / 0282084, GB841554, DE694943). Furthermore, esterification can be carried out using a catalyst (EP3009494, WO2012069386, DD150064, CH151317, TA Isbell, Grasas y Aceites, 2011, 62(1), 8-20). In another preferred embodiment, the enzyme is used to condense the carboxylic acid (JP05304966,JP05211878,JP01016591, A. Bodalo et al., Biochem. Eng. J., 2008, 39(3), 450-456, A. Bodalo et al., Biochem. Eng. J. 2005, 26(2-3), 155-158, Y. Yasuko et al., J. Am. Oil Chem. Soc., 1997, 74(3), 261-267). Generally, the above method yields a multimodal condensate.

[0116] Generally, monomodal condensates can be synthesized by condensation sequences based on stepwise esterification of carboxylic acid anhydrides (K. Meier, Farbe und Lack, 1951, 57, 437-439, FHH Valentin, J. South African Chem. Inst. 1949, 2, 59-61), or preferably carboxylic acid chlorides (KD Pathak et al., J. Scientific & Industrial Research, 1955, 14B, 637-639), hydroxylated carboxylic acids, and their derivatives with the OH group.

[0117] The repeated cycles based on esterification and acid chloride synthesis generally yield monomodal ester condensates. Further details are outlined in the examples section.

[0118] The following is a schematic diagram of the synthesis sequence of ester condensates based on the stepwise esterification of the OH groups of carboxylic acid chlorides, hydroxylated carboxylic acids, and their derivatives. [ka]

[0119] Here, the arrows indicate that the product obtained by the esterification of the acyl chloride of fatty acid R1-C(O)Cl by reaction with hydroxylcarboxylic acid HO-R2-C(O)OH, followed by the formation of the acyl chloride by reaction with SOCl2, can be resubmitted to such a reaction sequence. Thus, in the following reaction sequence, R1 of the starting material R1-C(O)Cl is "R1-C(O)O-R2" from the previous reaction sequence. Thus, the estolide structure can be obtained iteratively, and the number of fatty acid residues in the final estolide moiety is determined by the number of iterative steps in the cyclic process.

[0120] Carboxylic acids that do not contain an OH group terminate the chain of the ester condensate. Monohydroxycarboxylic acids extend the chain of the ester condensate. Generally, dihydroxycarboxylic acids and polyhydroxycarboxylic acids provide branching and dendrimer (self-repeating) elements within the ester condensate.

[0121] In a more preferred embodiment of the present invention, the compound of the following formula defined above is used. R 1 (-F) x (I) It is provided here Low-melting point and high-melting point fatty acids ≥ C5 are R of general formulas (III) and (IV). 6 Within the contained ester elements, (-XC(O)-R 6 ) m -XC(O)- (III) (-C(O)-XR 6 ) m -C(O)-X- (IV), especially R in general formulas (IIIa) and (IVa)6 and R 7 Within the contained ester elements, (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) and (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa), or R of general formulas (XIII) and (XIV) 6 Among the contained ester elements, -R 10 (-XC(O)-R 6 ) m -XC(O)- (XIII) -R 10 (-C(O)-XR 6 ) m -C(O)-X- (XIV), especially R of general formulas (XIIIa) and (XIVa) 6 and R 7 Among the contained ester elements, -R 10 (-XC(O)-R 6 ) m -XC(O)-R 7 (XIIIa) -R 10 (-C(O)-XR 6 ) m -C(O)-XR 7 (XIVa) It is specifically placed in [location].

[0122] It is within the scope of the present invention that low-melting point and high-melting point fatty acids ≥ C5 are independently and specifically arranged for individual ester groups of parts selected from parts of general formula (III), (IV), (IIIa), (IVa), (XIII), (XIV), (XIIIa), and (XIVa) present in a compound of general formula (I). For example, if some parts of general formula (III) indicate a specific arrangement of low-melting point and high-melting point fatty acid scaffolds, as described below, while other parts of general formula (III) do not, this embodiment of the present invention applies in particular to different residues R as defined above. 1 , R 2 , R 3 , R 4 and R 5 This may apply to the part that exists in [location].

[0123] Within the framework of this invention, low-melting-point fatty acids ≥ C5 are defined by a melting point of 40°C or less. Preferred examples include, in particular, oleic acid, reskerolic acid, ricinoleic acid, octanoic acid, decanoic acid, pivalic acid, and neodecanoic acid.

[0124] Furthermore, within the framework of this invention, high melting point fatty acids ≥ C5 are defined by a melting point greater than 40°C. Preferred examples include, in particular, dodecanoic acid, tetradecanoic acid, hexadecanoic acid, octadecanoic acid, arachidic acid, behenic acid, 10-hydroxyoctadecanoic acid, 12-hydroxyoctadecanoic acid, and 14-hydroxytetradecanoic acid.

[0125] The corresponding melting points can be obtained from the literature (G. Knothe et al., J Am Oil ChemSoc, 2009, 86, 844-856).

[0126] In a more preferred embodiment of the present invention, a compound of the following formula, as defined above. R 1 (-F) x (I) It is provided here At least one, preferably more than one, more preferably one, two or three, each being a base R 6 Low melting point fatty acids ≥ C5 that form are R of formula (III) or (IV). 6 One end of the contained ester element, while at least one, preferably more than one, more preferably one, two, or three high melting point fatty acids ≥ C5, are located at the opposite end of the ester element of formula (III) or (IV), with one or more radicals R 6 Forming, or in such a manner, at least one, preferably more than one, more preferably one, two or three, each being a base R 6 High melting point fatty acids ≥ C5 that form are R of formula (III) or (IV). 6 One end of the contained ester element, while at least one, preferably more than one, more preferably one, two, or three low-melting-point fatty acids ≥ C5, are located at the opposite end of the ester element of formula (III) or (IV), with one or more radicals R 6 to form, or - At least one, preferably more than one, more preferably one, two or three, each based R 6 Low melting point fatty acids ≥ C5 that form R 7 One or more radicals adjacent to R 6 Included in, on the other hand, at least one, preferably more than one, more preferably one, two or three, high melting point fatty acids ≥ C5 are R of formula (IIIa) or (IVa). 6 and R 7 At the opposite end of the contained ester element, one or more radicals R 6 Forming, or in such a manner, at least one, preferably more than one, more preferably one, two or three, each R 6 High melting point fatty acids ≥ C5 that form R 7 One or more radicals adjacent to R 6 It forms a low-melting-point fatty acid ≥ C5 of formula (IIIa) or (IVa) 6and R 7 At the opposite end of the ester element-containing side, one or more radicals R 6 are formed, or - At least one, preferably more than one, more preferably one, two or three, each group R 6 The low melting point fatty acid ≥C5 that forms is adjacent to the radical R 10 On the other hand, at least one, preferably more than one, more preferably one, two or three high melting point fatty acids ≥C5 are at the opposite end of the ester element of formula (XIII) or (XIV), forming one or more radicals R 6 Or in such a way that at least one, preferably more than one, more preferably one, two or three, each R 6 The high melting point fatty acid ≥C5 that forms is adjacent to the radical R 10 One or more radicals R adjacent to 6 are formed, while on the other hand, at least one, preferably more than one, more preferably one, two, or three low melting point fatty acids ≥5 are R of formula (XIII) or (XIV) 6 and R 7 At the opposite end of the ester element-containing side, one or more radicals R 6 are formed, or - At least one, preferably more than one, more preferably one, two or three, each group R 6 The low melting point fatty acid ≥C5 that forms is adjacent to the radical R 10 On the other hand, at least one, preferably more than one, more preferably one, two or three high melting point fatty acids ≥C5 are in the part of formula (XIIIa) or (XIVa), forming one or more radicals R adjacent to R 7 Or in such a way that at least one, preferably more than one, more preferably one, two or three, each R 6 The high melting point fatty acid ≥C5 that forms is adjacent to R 6 One or more radicals R adjacent to 10 are formed 6is formed, while on the other hand, at least one, preferably more than one, more preferably one, two or three fatty acids with a low melting point ≧ C5 are in the moiety of formula (XIIIa) or (XIVa), R 7 forms one or more radicals R 6 adjacent to

[0127] As already described above, the specific arrangement of the high-melting and low-melting fatty acids can be changed independently for each of the individual R 6 -containing ester moieties.

[0128] The preferred embodiments outlined above are in the moiety of the following general formula (-X-C(O)-R 6 ) m -X-C(O)- (III), (-C(O)-X-R 6 ) m -C(O)-X- (IV), (-X-C(O)-R 6 ) m -X-C(O)-R 7 (IIIa), and (-C(O)-X-R 6 ) m -C(O)-X-R 7 (IVa), -R 10 (-X-C(O)-R 6 ) m -X-C(O)- (XIII), -R 10 (-C(O)-X-R 6 ) m -C(O)-X- (XIV), -R 10 (-X-C(O)-R 6 ) m -X-C(O)-R 7 (XIIIa) and -R 10 (-C(O)-X-R 6 ) m -C(O)-X-R 7 (XIVa), In particular, -R10 -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-, -R 10 -NR 1 -C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-, -R 10 -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 and -R 10 -NR 1 -C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , R tends to change locally with respect to crystallization, viscosity increase, and phase formation throughout the entire length of these ester elements. 6 - and R 6 -and R 7 This enables the incorporation of contained ester elements.

[0129] The combination of the carboxylic acid described above and the target synthetic concept makes it possible to obtain ester condensates with specified properties such as molecular weight, molecular weight distribution, carboxylic acid arrangement, and viscosity.

[0130] Generally, radical R 10 teeth, -R 10 (-XC(O)-R 6 ) m -XC(O)-R 7 (XIII) -R 10 (-C(O)-XR 6 ) m -C(O)-XR 7 (XIV) -R 10 (-XC(O)-R 6 )m -X-C(O)-R 7 (XIIIa) and -R 10 (-C(O)-X-R 6 ) m -C(O)-X-R 7 (XIVa), in particular -R 10 -O-C(O)-R 6 -(O-C(O)-R 6 ) m -O-C(O)- and -R 10 -NR 1 -C(O)-R 6 -(O-C(O)-R 6 ) m -O-C(O)-, -R 10 -O-C(O)-R 6 -(O-C(O)-R 6 ) m -O-C(O)-R 7 and -R 10 -NR 1 -C(O)-R 6 -(O-C(O)-R 6 ) m -O-C(O)-R 7 wherein, R 6 as well as R 6 and R 7 can be bonded in different ways to the ester-containing element.

[0131] In a preferred embodiment according to the present invention, a compound of general formula (I) defined in the foregoing embodiment is provided, where preferably, -R 10 (-X-C(O)-R 6 ) m -X-C(O)- (XIII), -R 10 (-X-C(O)-R 6 ) m -X-C(O)-R 7 (XIIIa), more preferably, -R10 -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-, -R 10 -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , In R 10 This is two or more parts -OC(O)-R 6 -(OC(O)-R 6 ) m Derived from mono- or di-(chloroacetic acid) esters of glycerol or castor oil (ricinoleic acid triglyceride) containing -OC(O)-, or comprising one or two parts -OC(O)-R in total. 6 -(OC(O)-R 6 ) m -OC(O)-R 7 Combine.

[0132] According to this embodiment, X=O, R 6 , optionally hydroxylated hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecilen, octadecylene, nonadecilen, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene, or hexenylene, heptenylene, octenylene, nonenilen, decenylene, Undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicocenylene, henicocenylene, doicocenylene, tricocenylene, and tetraicocenylene are independently selected, where these groups are most preferably bonded to an adjacent C(O) or O group by a terminal C atom, and if present, R 7The group is independently selected from hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where the group is most preferably bonded to an adjacent C(O) group by a terminal C atom. And m is preferably 1-10, more preferably 1, 2, 3, 4, or 5.

[0133] X=O, R 6 is selected from hexadecirine, heptadecirene, octadecirene, nonadecirine, eicocirine, hexadecenirene, heptadecenirene, octadecenirene, nonadecenirene, eicocenirene, and if present, R 7 It is selected from hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosylhexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, and eicocenyl. Furthermore, it is even more preferable that m is 1, 2, 3, 4, or 5.

[0134] According to this embodiment, X=O, R 6 It is derived from ricinoleic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or reskerolic acid, and if present, R 7 It is derived from oleic acid, ricinoleic acid, or stearic acid. And it is most preferable that m is 1, 2, 3, 4, or 5.

[0135] The esterification of hydroxylated fatty acids or hydroxylated glycerol fatty acid derivatives with chloroacetic acid (R. Oda, Kogyo KagakuZasshi, 1933, 36, suppl. Binding 496-497) or chloroacetic acid chloride (EP0283994, A. Baydar et al., Int. J. Cosmet. Sci., 1991, 13(4), 169-190) is described in the prior art. Further details are outlined in the examples section.

[0136] Another preferred embodiment of the present invention provides a compound of the general formula (I) defined above, -R 10 (-XC(O)-R 6 ) m -XC(O)- (XIII) and -R 10 (-XC(O)-R 6 ) m -XC(O)-R 7 (XIIIa) more, -R 10 -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)- and -R 10 -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , In R 10 These are derived from esters of tertiary amino alcohols, particularly N,N-dimethylethanolamine, N,N-dimethylpropanolamine, and N,N,N'-trimethylaminoethyl-ethanolamine, which have an ester of a hydroxylated carboxylic acid.

[0137] The esterification of tertiary amino group-containing alcohols with carboxylic acid chlorides is described in prior art (US2460182). Further details are provided in the examples section.

[0138] In another preferred embodiment, -R 10 (-XC(O)-R 6 ) m -XC(O)- (XIII) and -R 10 (-XC(O)-R 6 ) m -XC(O)-R 7 (XIIIa), comfort -R 10 -NR 1 -C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)- or -R 10 -NR 1 -C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , In R 10 These are derived from tertiary-primary amines, particularly N,N-dimethyl-1,3-propanediamine, N-methyl-N'-aminopropyl-piperazine, and tertiary-secondary amines, particularly N-methylpiperazine amides.

[0139] The synthesis of tertiary amino group-containing fatty amides starting from fatty acid esters (US4221733) or free fatty acids (US3768646) is described in the prior art. Further details are provided in the examples section.

[0140] In a preferred embodiment of the present invention, a compound of general formula (I) is provided, wherein a portion of the compound of general formula (I) as defined above is R 1These are formed by the reaction of a halogenated carboxylic acid, preferably chloroacetic acid, with an OH-functionalized hydrocarbon. The synthesis of chloroacetic acid esters starting from chloroacetic acid or chloroacetic acid chloride and OH-functionalized hydrocarbons is described in the prior art (R. Oda, Kogyo KagakuZasshi, 1933, 36, suppl. Binding 496-497, WO0210257).

[0141] In another preferred embodiment of the present invention, R of the compound of general formula (I) defined above 1 These are formed by the reaction of hydrocarbons, epoxy derivatives, preferably glycidyl ethers or glycidyl ester derivatives, with bifunctional carboxylic acids. These glycidyl ethers or glycidyl ester derivatives are commercially available or can be synthesized from corresponding alcohol or carboxylic acid precursors. Preferred commercially available epoxy derivatives are Denacol type (Nagase) or Heloxy modifiers (Hexion), namely corresponding derivatives based on 1,4-butanediol, glycerol, oligoglycerol, castor oil, and dimer acids. The synthesis of glycidyl ethers or glycidyl esters is described in the prior art (GB763559, US3766221, US5420312, WO2012041816).

[0142] In another preferred embodiment of the present invention, a compound of general formula (I) is provided, wherein R of the compound of general formula (I) as defined above is provided. 1 These are formed by the reaction of an epoxy-functionalized hydrocarbon with a halogenated carboxylic acid, preferably an ester of chloroacetic acid, or an epoxy ester based on an epoxy-functionalized hydrocarbon with a difunctional carboxylic acid. The synthesis of this type of ester is described in US2018 / 0016397.

[0143] In general, the counterion A of the ammonium anion of the compound of general formula (I) defined above. -These are selected from monovalent to trivalent inorganic anions and monovalent to 30,000-valent, preferably monovalent to 1,000-valent organic anions, which are preferably halides, e.g., chlorides, bromides, iodides, sulfates, phosphates, phosphonates, sulfonates, methosulfates, carboxylates, e.g., acetates, propionates, lactates, octanoates, 2-ethyl-hexanoates, dodecanoates, hexadecanoates, octadecanoates, oleates, ricinoleates, 12-hydroxy-octadecanoates, succinates, maleates, tartrates, polyether carboxylates, and polymer fatty acid carboxylates of the following types. R 1 [(-C(O)-XR 6 ) m -C(O)-XR 7 ] x or R 1 [(XC(O)-R 6 ) m -XC(O)-R 7 ] x , Here R 1 or R 7 At least one of the following, or R 1 and R 7 At least one of them has one or more carboxylate groups, Preferably, here X=O, especially, The following types of linear polymer fatty acid carboxylates, -OC(O)-R 6 (-XC(O)-R 6 ) m-1 -XC(O)-R 7 Preferably, -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , Branched linear polymer fatty acid carboxylates, That is, branched linear polymer fatty acid carboxylates derived from branched polyfatty acid structures, particularly polyfunctional carboxylic acids, especially dicarboxylic acids, succinic acid and maleic acid, and partial esters of castor oil or rescera oil, for example [ka] Here, one R = [ka] And the remaining two R groups = [ka] Dendrimer-like high molecular weight fatty acid carboxylate, In other words, it originates from a dendrimer-like polyfatty acid structure, Or the following types, XR 6 (-C(O)-XR 6 ) m-1 -C(O)-XR 7 or R 6 (-C(O)-XR 6 ) m-1 -C(O)-XR 7 , Here, in the latter two types, R 7 The group has at least one anionic carboxylate group, Or the following types, R 1 [(-C(O)-X-R6) m -C(O)O - ] x ,for example, Here, X, R 1 , R 6 , R 7 , m, and x are as defined above, and Here, the counterion A of this group -The anion is preferably monovalent to 50valent, more preferably monovalent to 10valent, even more preferably monovalent to 5valent, most preferably pentavalent, tetravalent, trivalent, divalent, or monovalent. Selected from the group consisting of, Alternatively, the counter anion is selected from the group consisting of carboxylate anions based on poly(acrylic acid) homopolymers and copolymers and poly(itaconic acid) homopolymers and copolymers. Here, the anion of this group is preferably an anion with a valency of 2 to 30,000, more preferably 2 to 1,000, even more preferably 10 to 1,000, even more preferably 50 to 1,000, and most preferably 100 to 1,000, and Preferably, the following types of high molecular weight fatty acid carboxylates are used: - OC(O)-R 6 (-XC(O)-R 6 ) m-1 -XC(O)-R 7 Here, the esterified OH substituent is absent in the single-chain molecule. Preferably, the following types of high molecular weight fatty acid carboxylates are used: R 1 [(-C(O)-X-R6) m -C(O)O - ] x As defined above, Here, the carboxylate contains a branched or dendrimer (self-repeating) motif, and in particular, it is derived from 2,2'-dihydroxymethylpropanoic acid.

[0144] The synthesis of the dendrimer structure of 2,2'-dihydroxymethylpropanoic acid is described in US2016 / 0102179.

[0145] In a more preferred embodiment of the present invention, the counterion A of the compound according to the present invention of the general formula (I) defined above -These include monovalent to trivalent inorganic anions and monovalent to 30,000, preferably monovalent to 1,000, organic anions, including halide anions such as chlorides, bromides, iodides, sulfates, phosphates, phosphonates, sulfonates, methosulfates, carboxylate anions such as acetates, propionates, lactates, octanoates, 2-ethyl-hexanoates, dodecanoates, hexadecanoates, octadecanoates, oleates, ricinoleates, 12-hydroxy-octadecanoates, succinates, maleates, tartrates, and polyether carboxylates. Selected from the group consisting of the following types of high molecular weight fatty acid carboxylates, R 1 [(-C(O)-XR 6 ) m -C(O)-XR 7 ] x ,or, R 1 [(XC(O)-R 6 ) m -XC(O)-R 7 ] x , Here, R 1 or R 7 At least one of the following, or R 1 and R 7 At least one of them has one or more carboxylate groups, Preferably X = O, especially, The following types of linear polymer fatty acid carboxylates, -OC(O)-R 6 (-XC(O)-R 6 ) m-1 -XC(O)-R 7 Preferably -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , Branched linear polymer fatty acid carboxylates, That is, branched linear polymer fatty acid carboxylates derived from branched polyfatty acid structures, particularly polyfunctional carboxylic acids, especially dicarboxylic acids, succinic acid and maleic acid, and partial esters of castor oil or rescera oil, for example [ka] Here, one R = [ka] And the remaining two R groups = [ka] Dendrimer-like high molecular weight fatty acid carboxylate, In other words, it originates from a dendrimer-like polyfatty acid structure, Or the following types, XR 6 (-C(O)-XR 6 ) m-1 -C(O)-XR 7 or R 6 (-C(O)-XR 6 ) m-1 -C(O)-XR 7 , Here, in the latter two types, R 7 The group has at least one anionic carboxylate group, Or the following types, R 1 [(-C(O)-X-R6) m -C(O)O - ] x ,for example, Here, X, R 1 , R 6 , R 7 m and x are as defined above, and here the counterion A of this group -The anion is preferably monovalent to 50valent, more preferably monovalent to 10valent, even more preferably monovalent to 5valent, most preferably 5valent, 4valent, 3valent, 2valent, or monovalent. Alternatively, an anion is selected from the group consisting of poly(acrylic acid) homo and copolymers, poly(itaconic acid) homo and copolymers, where the anion of this group is preferably 2 to 30,000 valencies, more preferably 2 to 1,000 valencies, even more preferably 10 to 1,000 valencies, even more preferably 50 to 1,000 valencies, and most preferably 100 to 1,000 valencies. Preferably, the following types of high molecular weight fatty acid carboxylates are used: - OC(O)-R 6 (-XC(O)-R 6 ) m-1 -XC(O)-R 7 Here, the esterified OH substituent is absent in the single-chain molecule, or Preferably, the following types of high molecular weight fatty acid carboxylates are used: R 1 [(-C(O)-X-R6) m -C(O)O - ] x As defined above, Here, we have carboxylates containing branched or dendrimer (self-repeating) motifs, particularly derived from 2,2'-dihydroxymethylpropanoic acid.

[0146] The desired counterions can be incorporated into the quaternized material during the quaternization process or by anion exchange. In this context, by adding an alkali salt of a fatty acid or high molecular weight fatty acid, preferably a sodium salt or potassium salt, to an initially inorganic counterion-containing material, it is possible to exchange an inorganic counterion, such as chlorine or bromine, for an organic counterion, such as a fatty acid carboxylate or high molecular weight fatty acid carboxylate, to yield the target material and alkali metal halides, particularly NaCl, NaBr, KCl, and KBr.

[0147] In preferred embodiments of the present invention, in formula (III) and / or (IV), X=O, and preferably, the compounds of the present invention do not contain any amide groups.

[0148] Amide bonds are generally more stable against hydrolysis, while they also provide structural rigidity compared to ester groups. Therefore, according to this embodiment, group X represents the oxygen atom in all structures of formula (III) and / or (IV) present in the compound, and it is preferable that the compound does not contain any amide groups.

[0149] In another preferred embodiment, the compound according to the present invention has a cationic group R present in the cationic structure of general formulas (I) and (II). 1 , R 2 , R 3 , R 4 , R 5 At least one of them includes at least one part of the following expression: R 1* [(-OC(O)-R 6 ) m -OC(O)-]2, Here R 1* These are divalent C1-C100 hydrocarbon radicals, preferably C1-C12 alkylenes, most preferably methylene, ethylene, 1,3-propylene, 1,4-butylene, 1,6-hexylene, 1,2-propylene, and 1,3-butylene radicals. m is independently selected from 1 to 12, and R 6 This is defined as above.

[0150] Among them, the part of the following formula R 1* [(-OC(O)-R 6 ) m -OC(O)-]2, These are preferably formed by continuous or blocky ester chain formation, starting from alkylenediols, more preferably from α,ο-alkylenediols, such as 1,2-ethanediol, 1,3-propanediol, 1,4-butanediol, and 1,6-hexanediol.

[0151] Whether a single hydroxysubstituted carboxylic acid is repeatedly added or an estolide chain with a carboxylic acid group reacts with such a diol, using an excess of the carboxylic acid reactant results in a product in which the diol is mainly esterified at both ends in the same manner, i.e., a symmetric structure as shown in the formula below. R 1* [(-OC(O)-R 6 ) m -OC(O)-]2 This can be obtained.

[0152] Therefore, base R 1* Its structure directly corresponds to alkylenediols, which are typically used as starting materials.

[0153] According to the present invention, R 1* C2-C100 hydrocarbon radicals are divalent C2-C100 hydrocarbon radicals, which include all kinds of linear, branched, cyclic aliphatic and aromatic divalent hydrocarbon groups such as alkylene, alkenylene, and alkynylene, as well as aromatic structures such as phenylene.

[0154] Since C1-C12 alkylenediol is a preferred starting material, R 1* Preferably, is a C1-12 alkylene group, more preferably methylene, ethylene, n-propylene, n-butylene, n-pentylene, or n-hexylene, and even more preferably is a methylene, ethylene, n-propylene, n-butylene, or n-hexylene group.

[0155] According to this embodiment, m is selected independently, while the parts are usually symmetrical, thus the general structure R 1* [(-OC(O)-R6 ) m -OC(O)-]2, It is preferable that both m values ​​are the same.

[0156] Furthermore, m is preferably selected independently from 1-6, more preferably from 1-4, even more preferably both m are the same and selected from 1-6, and most preferably both m are the same and selected from 1-4.

[0157] According to the embodiment, R 6 As defined above, but preferably, R 6 Radicals include linear alkylene groups and linear alkenylene groups, particularly linear C6-C24 alkyne groups, such as hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecylen, octadecylene, nonadecylen, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene, or linear C6-C24 alkenylene groups, for example. Selected from hexenylene, heptenylene, octenylene, nonenylene, decenylene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicocenylene, henicocenylene, doicocenylene, tricocenylene, and tetraicocenylene, where these groups are most preferably bonded to adjacent C(O) groups by terminal C atoms.

[0158] Comfortable, R 6 It is derived from a C7-C25 fatty acid having one hydroxyl group as a substituent, and more preferably R 6 These are derived from ricinoleic acid, reskerolic acid, 10-hydroxyoctadecanoic acid, 12-hydroxyoctadecanoic acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, and 12-hydroxystearic acid.

[0159] Most preferably, R 6It is derived from ricinoleic acid.

[0160] The following general formula R 1* [(-OC(O)-R 6 ) m -OC(O)-]2, All R in the part 6 The same base is generally preferred in this embodiment and any other embodiment, as described herein.

[0161] In a more preferred embodiment, in the compound according to the present invention, The cationic structure of general formulas (I) and (II) contains the group R 1 , R 2 , R 3 , R 4 , R 5 At least one of them includes at least one part of the following expression: R 1* [(-OC(O)-R 6 ) m -OC(O)-]2, Here R 1* It is selected from methylene, ethylene, 1,3-propylene, 1,4-butylene, 1,6-hexylene, 1,2-propylene, and 1,3-butylene. R 6 m is derived from C8-C24 monocarboxy-monohydroxycarboxylic acids, particularly ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, and 11-hydroxy-undecanoic acid, and m is independently selected from 1 to 6.

[0162] According to this embodiment, all R 6 It is preferable that both elements originate from the same carboxylic acid and that both m in the structure are the same.

[0163] In a more preferred embodiment, the compound according to the present invention includes the group R present in the cationic structure of general formulas (I) and (II). 1 , R 2 , R 3 , R 4 , R5 At least one of them includes at least one part of the following expression: R 1* [(-OC(O)-R 6 ) m -OC(O)-]2, This can be represented by one of the following structural formulas: -C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-OC(O)-(mono or oligo C8-C24 hydroxy fatty acid)-OC(O)- Here - C2-C10 hydrocarbons are C2-C10 hydrocarbylene groups, and are particularly derived from ethylene glycol, 1,3-propylene glycol, 1,4-butanediol, 1,6-hexanediol, 1,2-propylene glycol, and 1,3-butanediol. - Mono- or oligo-C8-C24 hydroxy fatty acids are groups derived from C8-C24 hydroxy-substituted carboxylic acid monomers, or oligomers of up to 20 C8-C24 hydroxy-substituted carboxylic acid monomers formed by esterification with a degree of oligomerization of 2 to 20, preferably 2 to 10, more preferably 2 to 6, and even more preferably 2 to 4, and in particular, groups derived from mono- or oligo-ricinoleic acid.

[0164] Such compounds are exemplified by the following structural formulas: [ka] and [ka] Here R is as follows: [ka]

[0165] In yet another preferred embodiment, the compound according to the present invention includes the group R present in the cationic structure of general formulas (I) and (II). 1 , R 2 , R 3 , R 4 , R 5 At least one of them includes at least one part of the following expression: R 1* [(-OC(O)-R 6 ) m -OC(O)-R 7* -]2, Here R 1* , R 6 , and m are as defined above, And R 7* The group is a C1-C12 alkylene group, preferably a methylene, ethylene, propylene, or butylene group.

[0166] In this embodiment, the estolide chain portion shown above is typically bonded to an alkylene group after the formation of an estolide chain structure composed of the portion of the following general formula. R 1* [(-OC(O)-R 6 ) m -OC(O)-R 7* -]2, The terminal hydroxyl group of the chain structure is reacted with a carboxylic acid or carboxylic acid chloride having a functionalized alkyl chain, particularly a haloalkyl carboxylic acid chloride. This results in the group R 7* When the precursor binds to the structure and is further functionalized, the following general structure is formed. R 1* [(-OC(O)-R 6 ) m -OC(O)-R 7* -]2 The portion obtained is obtained.

[0167] According to this embodiment, R 7* This is a C1-C12 alkylene group, preferably a methylene, ethylene, propylene, or butylene group, most preferably a methylene group.

[0168] For example, the methylene group R 7* This can be obtained by esterifying the terminal hydroxyl group of the estolide chain with chloroacetic acid chloride and then functionalizing it, for example, by using a chloro group as a leaving group in the quaternization reaction of a tertiary amine.

[0169] In a more preferred embodiment, the compound according to the present invention includes the group R present in the cationic structure of general formulas (I) and (II). 1 , R 2 , R 3 , R 4 , R 5 At least one of them includes at least one part of the following expression: R 1* [(-OC(O)-R 6 ) m -OC(O)-R 7 *-]2, Here R 1* These are selected from methylene, ethylene, 1,3-propylene, and 1,4-butylene, and 1,6-hexylene. R 6 These are derived from C8-C24 monocarboxy-monohydroxycarboxylic acids, particularly ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, and 11-hydroxy-undecanoic acid. m is independently selected from 1 to 6, And R 7* It is selected from methylene and ethylene.

[0170] In a more preferred embodiment, the compound according to the present invention includes the group R present in the cationic structure of general formulas (I) and (II). 1 , R 2 , R 3 , R 4 , R 5 At least one of them includes at least one part of the following expression: R 1* [(-OC(O)-R 6 ) m -OC(O)-R 7*-]2 This can be represented by one of the following structural formulas: i)-CH2-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-OC(O)-(mono or oligo C8-C24 hydroxy fatty acid)-OC(O)-CH2- or ii)-CH2CH2-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-OC(O)-(mono or oligo C8-C24 hydroxy fatty acid)-OC(O)-CH2CH2-, Here - C2-C10 hydrocarbons are C2-C10 hydrocarbylene groups, particularly derived from ethylene glycol, 1,3-propylene glycol, 1,4-butanediol, 1,6-hexanediol, 1,2-propylene glycol, and 1,3-butanediol. - Mono- or oligo-C8-C24 hydroxy fatty acids are groups derived from C8-C24 hydroxy-substituted carboxylic acid monomers, or oligomers of up to 20 C8-C24 hydroxy-substituted carboxylic acid monomers formed by esterification with a degree of oligomerization of 2 to 20, preferably 2 to 10, more preferably 2 to 6, and even more preferably 2 to 4, and in particular, groups derived from mono- or oligo-ricinoleic acid.

[0171] Such compounds are exemplified by the following structural formulas. [ka] and [ka]

[0172] In a more preferred embodiment, the compound according to the present invention has the following general formula R 1* [(-OC(O)-R 6 ) m -OC(O)-R7* -]2 At least one portion of is one or both terminal R 7* It is bonded to the quaternary N atom of the group.

[0173] Therefore, according to this embodiment, the compound according to the present invention is at least one part of the following general formula, R 1* [(-OC(O)-R 6 ) m -OC(O)-R 7* -N + ]2, Here, both terminal R 7* The group is bonded to a quaternary N atom, and / or at least one part of the general formula, N + -R 7* -C(O)-O-(R 6 -C(O)-O) m -R1*- * (-OC(O)-R 6 ) m -OC(O)-R 7* -, Here, one terminal R 7* The group is bonded to a quaternary N atom. Includes.

[0174] Furthermore, it is preferable that one or two quaternary nitrogen atoms each have two groups independently selected from methyl, ethyl, propyl, and butyl groups.

[0175] More preferably, one or two quaternary nitrogen atoms each have two methyl substituents, and even more preferably, the fourth substituent is either an alkylamino group or an alkyl group substituted with an ammonium group, most preferably, the fourth substituent is selected from an ethylenedimethylammonium group, a propylenedimethylammonium group, a butylenedimethylammonium group, or a hexylenedimethylammonium group.

[0176] Preferably, these groups are derived from N,N,N',N'-tetramethyl-1,2-ethylenediamine, N,N,N',N'-tetramethyl-1,4-butylenediamine, or N,N,N',N'-tetramethyl-1,6-hexylenediamine. Alternatively, a quaternary ammonium group having one methyl group may be derived from N,N'-dimethylpiperazine.

[0177] In another preferred embodiment of the present invention, at least one part of the following general formula is: R 1* [(-OC(O)-R 6 ) m -OC(O)-R 7* -]2 One or both terminal R 7* It is bonded to the quaternary N atom of the group, and the compound is a diquat or tetraquat compound.

[0178] Among them, both terminal R 7* Preferably, the group is bonded to a quaternary N atom, and more preferably, both terminal R atoms are bonded. 7* Each group is a quaternary N atom having three alkyl substituents with 1 to 12 carbon atoms, or the formula -N + (CH3)2-ALK-N + Each quaternary N atom represented by (CH3)3 is bonded to a divalent alkylene group having 1 to 12 carbon atoms, preferably a linear alkylene group.

[0179] According to the embodiment, both terminal R 7* When the group is bonded to a quaternary N atom having three alkyl substituents, each having 1 to 12 carbon atoms, it is preferable that the alkyl substituents are selected from methyl, ethyl, propyl, and butyl groups, and most preferably all three substituents are methyl groups.

[0180] Both terminal R 7* The base is the formula -N defined above. + (CH3)2-ALK-N +When bonded to a quaternary nitrogen atom represented by (CH3)3, the group ALK is preferably a methylene group, an ethylene group, an n-propyl group, an n-butylene group, or an n-hexylene group.

[0181] In a more preferred embodiment, the compound according to the present invention comprises at least two parts of the following general formula: R 1* [(-OC(O)-R 6 ) m -OC(O)-R 7* -]2, Here, the aforementioned parts are linked to each other via diquaternary ammonium alkylene groups of the general structure shown below, -N + (CH3)2-ALK-N + (CH3)2-, Here, ALK is a divalent alkylene group having 1 to 12 carbon atoms, preferably a linear alkylene group.

[0182] Preferably, the compound includes a portion of the following formula greater than 4, more preferably greater than 6, and even more preferably greater than 8: R 1* [(-OC(O)-R 6 ) m -OC(O)-R 7* -2, these are bonded via a diammonium alkylene group.

[0183] More preferably, the group ALK is independently selected from ethylene, n-propylene, n-butylene, or n-hexylene, and more preferably, all groups ALK are alkylene groups of the same type.

[0184] In another preferred embodiment of the compound according to the present invention, the group R present in the cationic structure of general formulas (I) and (II) is present. 1 , R 2 , R 3 , R 4 , R 5 At least one of them includes at least one part of the following general formula: -([-OC(O)-R6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])- Here R 6 This is as defined above, l is an integer independently selected from 0 to 20, more preferably from 1 to 12, and even more preferably from 2 to 10, and L may have 1 to 30 carbon atoms and optionally -O-, -S-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] A divalent hydrocarbon radical which may contain one or more groups selected from, Preferably, L is a divalent alkylene or alkenylene radical having 1 to 30 carbon atoms. More preferably, L is selected from methylene, ethylene, propylene, butylene, pentylene, hexylene, heptylene, octylene, nonylene, etenylene, propenylene, butenylene, pentenylene, hexenylene, heptenylene, octenylene, nonenylene. Most preferably, L is selected from methylene, ethylene, ethenylene, or butenylene.

[0185] According to this embodiment, R 6 It is preferable that the compound is independently derived from C8-C24 monocarboxy-monohydroxycarboxylic acids, particularly ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, and 11-hydroxy-undecanoic acid.

[0186] In preferred embodiments of the compounds according to the present invention, the group R present in the cationic structure of general formulas (I) and (II) is present. 1 , R 2 , R 3 , R 4 , R5 At least one of them includes at least one part of the following general formula: -([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])-, Here, L and l are as defined above, And R 6 It is independently derived from C8-C24 monocarboxy-monohydroxycarboxylic acids, preferably ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, and 11-hydroxy-undecanoic acid, most preferably R 6 It is derived from ricinoleic acid.

[0187] More preferably, L is selected from methylene or ethylene, -CH=CH- and -C(=CH2)-CH2-, l is independently selected from an integer in the range of 0 to 6, and R 6 It is derived from ricinoleic acid.

[0188] In preferred embodiments of the compounds according to the present invention, the group R present in the cationic structure of general formulas (I) and (II) is present. 1 , R 2 , R 3 , R 4 , R 5 At least one of them includes at least one part of the following general formula: -([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])-, Here, L is selected from methylene, ethylene, and ethenylene. R 6 It is derived from ricinoleic acid, and l is independently selected from 0, 1, 2, and 3, and the sum of l is in the range of 0-4.

[0189] Preferably, L is an ethylene group, and R 6 l is derived from ricinoleic acid, and l is independently selected from 0 or 1.

[0190] In preferred embodiments of the compounds according to the present invention, the group R present in the cationic structure of general formulas (I) and (II) is present. 1 , R 2 , R 3 , R 4 , R 5 At least one of them includes at least one part of the following general formula: -([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])-, This can be represented by the following structure: -OC(O)-(mono or oligo C8-C24 hydroxy fatty acid)-OC(O)-(C1-C12 hydrocarbon)-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O- Here - The C1-C12 hydrocarbon is a C1-C12 hydrocarbylene group, preferably a C2 to C10 hydrocarbylene group, and - Mono- or oligo-C8-C24 hydroxy fatty acids are groups derived from C8-C24 hydroxy-substituted carboxylic acid monomers, or oligomers of up to 20 C8-C24 hydroxy-substituted carboxylic acid monomers formed by esterification, with a degree of oligomerization of 2 to 20, preferably 2 to 10, more preferably 2 to 6, and even more preferably 2 to 4.

[0191] The C1-C12 hydrocarbon group is preferably derived from succinic acid, maleic acid, itaconic acid, adipic acid, sebacic acid, or dodecanediic acid. The mono or oligo C8-C24 hydroxy fatty acid group is preferably derived from monoricinoleic acid, or oligoricinoleic acid having a degree of oligomerization of 2 to 20, preferably 2 to 10, more preferably 2 to 6, and even more preferably 2 to 4.

[0192] Examples of compounds with such structures are shown below. [ka]

[0193] In preferred embodiments of the compounds according to the present invention, the group R present in the cationic structure of general formulas (I) and (II) is present. 1 , R 2 , R 3 , R 4 , R 5 At least one of them includes at least one part of the following general formula: -([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])-R 12 , Here L, l, R 6 This is as defined above, And R 12 It is a C1 to C12 linear or branched hydrocarbylene group that may contain up to four -O- groups and up to four tertiary amino groups, and is bonded to an -O- group of an ester group at one end and to a quaternary N atom at the other end. Preferably R 12 It is derived from tertiary amino alcohols, particularly amino alcohols having the following structure. [ka]

[0194] Preferably, L, l, and R 6This is as defined above, and R 12 The configuration is selected from -CH2CH2- and -CH2CH2CH2-.

[0195] More preferably, l is independently selected from the range of 0 to 6, preferably 1 to 6, and more preferably 2 to 6.

[0196] R 6 It is preferably derived from ricinoleic acid, and R 12 Preferably, it is selected from -CH2CH2- and -CH2CH2CH2-.

[0197] The present invention also relates to a method for synthesizing compounds of general formula (I), as defined by all of the above embodiments of the present invention. R 1 (-F) x (I), Here, Alkyl halides are at least one part (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably at least one part (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) It has reacts with a tertiary amine, or As defined above, an ester of a halogenated carboxylic acid, preferably chloroacetic acid, with an alcohol or epoxide, is at least one part (-XC(O)-R 6 ) m-XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably at least one part (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) It has reacts with a tertiary amine, or The epoxy-functionalized ethers and esters, preferably glycidyl ethers and esters, defined above, with an alcohol or carboxylic acid, are at least one portion of (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably at least one part (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) It reacts with a tertiary amine having the following properties in the presence of an acid: or A tertiary amino group-containing hydrocarbon is defined as having at least one part as described above. (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably at least one part (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) It reacts with esters of halogenated carboxylic acids, or A tertiary amino group-containing hydrocarbon is defined as having at least one part as described above. (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably at least one part (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) It has epoxy-functionalized ethers and esters that react in the presence of an acid, Here, X, R 6 , R 7 m and x are as defined above.

[0198] According to this embodiment, X=O, R 6These are optionally hydroxylated hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecilen, octadecylene, nonadecilen, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene, or hexenylene, heptenylene, octenylene, noneniylene, decenylene A group independently selected from lene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicocenylene, henicocenylene, doicocenylene, tricocenylene, and tetraicocenylene, where the group is most preferably bonded to an adjacent C(O) or O group by a terminal C atom, and present, R 7 The group is independently selected from hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where the group is most preferably bonded to an adjacent C(O) group by a terminal C atom. And m is preferably 1-10, more preferably 1, 2, 3, 4, or 5.

[0199] X=O, R 6 is selected from hexadecirine, heptadecirene, octadecirene, nonadecirine, eicocirine, hexadecenirene, heptadecenirene, octadecenirene, nonadecenirene, eicocenirene, and if present, R 7It is selected from hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosylhexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, and eicocenyl. Furthermore, it is even more preferable that m is 1, 2, 3, 4, or 5.

[0200] According to this embodiment, X=O, R 6 It is derived from ricinoleic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or reskerolic acid, and if present, R 7 It is derived from oleic acid, ricinoleic acid, or stearic acid. And it is most preferable that m is 1, 2, 3, 4, or 5.

[0201] In a preferred embodiment of the present invention, a method for synthesizing a compound of general formula (I) is provided. R 1 (-F) x (I) Here R 1 This is a quaternary nitrogen atom N + via R 3 , R 4 , and R 5 It is coupled with R 1 (-F) x teeth, General formula (III) (-XC(O)-R 6 ) m -XC(O)- (III), Or general formula (IV) (-C(O)-XR 6 ) m -C(O)-X- (IV), It includes at least one part of, preferably, General formula (IIIa) (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) Or general formula (IVa) (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Having at least one part of, Here Alkyl halides are, (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably includes at least one part of, (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Having at least one part of, It reacts with tertiary amines, or As defined above, a halogenated carboxylic acid, preferably an ester of chloroacetic acid with an alcohol or epoxide, (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably includes at least one part of, (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Having at least one part of, It reacts with tertiary amines, or As defined above, epoxy-functionalized ethers and esters, preferably glycidyl ethers and esters, are provided with an alcohol or carboxylic acid. (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably includes at least one part of (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Having at least one part of, It reacts with a tertiary amine in the presence of an acid. or As defined above, tertiary amino group-containing hydrocarbons are (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably includes at least one part of (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Having at least one part of, It reacts with halogenated carboxylic acid esters, or As defined above, tertiary amino group-containing hydrocarbons are (-XC(O)-R 6 ) m-XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably includes at least one part of, (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Having at least one part of, Epoxy-functionalized ethers and esters react in the presence of an acid, Here, X, R 6 , R 7 m and x are as defined above.

[0202] According to this embodiment, X=O, R 6 These are optionally hydroxylated hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecilen, octadecylene, nonadecilen, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene, or hexenylene, heptenylene, octenylene, noneniylene, decenylene A group independently selected from lene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicocenylene, henicocenylene, doicocenylene, tricocenylene, and tetraicocenylene, where the group is most preferably bonded to an adjacent C(O) or O group by a terminal C atom, and present, R 7The group is independently selected from hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where the group is most preferably bonded to an adjacent C(O) group by a terminal C atom. And m is preferably 1-10, more preferably 1, 2, 3, 4, or 5.

[0203] X=O, R 6 is selected from hexadecirine, heptadecirene, octadecirene, nonadecirine, eicocirine, hexadecenirene, heptadecenirene, octadecenirene, nonadecenirene, eicocenirene, and if present, R 7 It is selected from hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosylhexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, and eicocenyl. Furthermore, it is even more preferable that m is 1, 2, 3, 4, or 5.

[0204] According to this embodiment, X=O, R 6 It is derived from ricinoleic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or reskerolic acid, and if present, R 7 It is derived from oleic acid, ricinoleic acid, or stearic acid. And it is most preferable that m is 1, 2, 3, 4, or 5.

[0205] Another preferred embodiment of the present invention provides a method for synthesizing a compound of general formula (I), R 1 (-F) x (I) Here R 1 The quaternary nitrogen atom N + It is coupled with R 1 (-F) x It has at least one part of the general formula (XIII), (XIV), (XIIIa), or (XIVa), -R 10 (-XC(O)-R 6 ) m -XC(O)- (XIII) -R 10 (-C(O)-XR 6 ) m -C(O)-X- (XIV), preferably -R 10 (-XC(O)-R 6 ) m -XC(O)-R 7 (XIIIa) -R 10 (-C(O)-XR 6 ) m -C(O)-XR 7 (XIVa) Here To obtain such a compound, the alkyl halide is reacted with a tertiary amine having at least one part of the general formula (XIII), (XIV), (XIIIa), or (XIVa), where R 1 The quaternary nitrogen atom N + It is coupled with R 1 (-F) x It has at least one part of the general formula (XIII), (XIV), (XIIIa), or (XIVa), or As described above, in order to obtain such compounds, an ester formed by an alcohol or epoxide of a halogenated carboxylic acid, preferably chloroacetic acid, is reacted with a tertiary amine having at least one part of the general formula (XIII), (XIV), (XIIIa), or (XIVa), or As described above, in order to obtain such compounds, epoxy-functionalized ethers and esters, preferably glycidyl ethers and esters, formed with an alcohol or carboxylic acid as defined above, are reacted in the presence of an acid with a tertiary amine having at least one part of general formula (XIII), (XIV), (XIIIa), or (XIVa). or As described above, in order to obtain such compounds, a tertiary amino group-containing hydrocarbon is reacted with an ester of a halogenated carboxylic acid having at least one part of the general formula (XIII), (XIV), (XIIIa), or (XIVa), or As described above, in order to obtain such compounds, a tertiary amino group-containing hydrocarbon, as defined above, is reacted in the presence of an epoxy-functionalized ether and ester having at least one part of the general formula (XIII), (XIV), (XIIIa), or (XIVa) in the presence of an acid, where R 10 X, R 6 , R 7 m and x are as defined above.

[0206] According to this embodiment, X=O, R 6 These are optionally hydroxylated hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecilen, octadecylene, nonadecilen, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene, or hexenylene, heptenylene, octenylene, noneniylene, decenylene A group independently selected from lene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicocenylene, henicocenylene, doicocenylene, tricocenylene, and tetraicocenylene, where the group is most preferably bonded to an adjacent C(O) or O group by a terminal C atom, and present, R 7 The group is independently selected from hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where the group is most preferably bonded to an adjacent C(O) group by a terminal C atom. R 1 is an unsubstituted C1-C8 alkylene group that does not contain functional groups, or R 1 This is a linear C3 to C50 alkylene group derived from diglycidyl ether, glycerol diglycidyl ether, diglycerol diglycidyl ether, diethylene glycol diglycidyl ether, or ethylene glycol diglycidyl ether having 3 to 10 (ethylene oxide) repeating units. And m is preferably 1-10, more preferably 1, 2, 3, 4, or 5.

[0207] X=O, R 6 is selected from hexadecirine, heptadecirene, octadecirene, nonadecirine, eicocirine, hexadecenirene, heptadecenirene, octadecenirene, nonadecenirene, eicocenirene, and if present, R 7 It is selected from hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosylhexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, and eicocenyl. R 1 is an unsubstituted C1-C8 alkylene group that does not contain functional groups, or R 1This is a linear C3 to C50 alkylene group derived from diglycidyl ether, glycerol diglycidyl ether, diglycerol diglycidyl ether, diethylene glycol diglycidyl ether, or ethylene glycol diglycidyl ether having 3 to 10 (ethylene oxide) repeating units. Furthermore, it is even more preferable if m is 1, 2, 3, 4, or 5.

[0208] X=O, R 6 It is derived from ricinoleic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or reskerolic acid, and if present, R 7 It is derived from oleic acid, ricinoleic acid, or stearic acid. R 1 is an unsubstituted C1-C8 alkylene group that does not contain functional groups, or R 1 These are C3 to C50 linear alkylene groups derived from diglycidyl ether, glycerol diglycidyl ether, diglycerol diglycidyl ether, and diethylene glycol diglycidyl ether. And m is most preferably 1, 2, 3, 4, or 5.

[0209] The present invention further relates to the use of the above-mentioned polymer fatty acid compound of general formula (I) in cosmetic formulations for skin and hair care, particularly in conditioners and shampoos; in abrasives for treating and coating hard surfaces; in formulations for drying automobiles and other hard surfaces; for example, as a separate softener for use after automatic washing, for finishing textiles and textile fibers, after textiles have been washed with a nonionic or anionic / nonionic detergent formulation; as a softener in formulations for washing textiles based on nonionic or anionic / nonionic surfactants; and as a means for preventing or removing wrinkles in textiles.

[0210] The present invention further relates to the use of the above-mentioned high-molecular-weight fatty acid compounds in a fiber, preferably an amino acid-based fiber, more preferably in a cosmetic composition for the treatment of human hair, which is particularly useful for strengthening hair, maintaining hair color, improving hair shine, enhancing hair color, protecting hair color, shaping hair, conditioning hair, improving hair smoothness and softness, improving hair manageability, and especially for improving hair combability, anti-friction, and anti-static properties.

[0211] A preferred composition according to the present invention is a cosmetic composition for hair treatment, selected from the group consisting of hair shampoo compositions, hair care compositions, hair conditioning compositions, hair strengthening compositions, hair coloring or dyeing compositions, hair combability improving compositions, hair frizz prevention compositions, hair rinse-off and leave-on compositions.

[0212] The present invention further relates to a composition comprising at least one polymer fatty acid compound together with at least one additional component commonly used in such compositions.

[0213] Below are some typical examples of compositions of these types in which the polymer fatty acid compounds of the present invention can be advantageously used. Case 1 Compounds of general formula (I), R 1 (-F) x (I) Here x ranges from 1 to 50. R 1It is selected from x-valent, optionally substituted hydrocarbon radicals having up to 1000 carbon atoms, preferably 2 to 300 carbon atoms, more preferably 3 to 200 carbon atoms, even more preferably 3 to 150 carbon atoms, specifically 3 to 50 carbon atoms, more specifically 3 to 20 carbon atoms, and optionally comprising one or more groups selected from -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups, and may be substituted with one or more groups selected from OH groups and halide groups, and F may be the same or different, and can be represented by the general formula (II) shown in Chemical Formula 2. Here, the base F is R 1 Bonded to the carbon atom, and n is independently between 0 and 100. R 2 These are selected from divalent, optionally substituted hydrocarbon radicals, which may be identical or different, have up to 1000 carbon atoms, and optionally contain one or more groups selected from -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups, and may be substituted with one or more groups selected from OH groups and halide groups. R 3 , R 4 , R 5 These may be the same or different, and are selected from optionally substituted linear, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radicals having hydrogen and up to 1000 carbon atoms, and optionally comprising one or more groups selected from -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, quaternary ammonium groups, and may be substituted with one or more groups selected from OH groups and halide groups. Here R 3 , R 4 , R 5 Each of them is bonded to a nitrogen atom by a carbon atom, And preferably R 3 , R 4 , R 5 It is not hydrogen, Ammonium ion counterion A- These are selected from monovalent to trivalent inorganic and monovalent to 30,000-valent, preferably monovalent to 1,000-valent organic anions, and R present in the cationic structure of general formulas (I) and (II) 1 , R 2 , R 3 , R 4 , R 5 At least one of these includes at least one part of formula (III) or (IV), (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), Here m=1 to 20, X is O or NR 11 And, R 11 This is independently selected from the group consisting of optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, which have hydrogen or up to 100 carbon atoms and optionally contain one or more groups selected from -O-, -NH-, -C(O)-, -C(S)-, or tertiary amino groups, and may be substituted with one or more hydroxyl groups and halide groups. R 6 These are independently selected from optionally substituted linear, cyclic, or branched saturated or unsaturated hydrocarbon radicals having 1 to 36 carbon atoms. However, at least one R 6 It has more than six carbon atoms, and For x=1 R 1 , R 3 , R 4 , R 5 is -OCH2CH 2 A compound that does not bond to the nitrogen atom of the group shown in chemical formula 7 via the -. Case Study 2 The compound according to claim 1, wherein x is between 2 and 50. Case Study 3 The compound according to claim 1 or 2, which does not contain poly(ethylene oxide) or poly(propylene oxide) units. Case 4 R 1 This is the general formula (IIIa) (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) Or general formula (IVa) (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) It includes at least one part of, Here, X and R 6 and m are as defined in claim 1, R 7 R is independently selected from optionally substituted linear, cyclic or branched, saturated or unsaturated hydrocarbon radicals having 1 to 36 carbon atoms, optionally comprising one or more groups selected from -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, or quaternary ammonium groups, and which may be substituted with an OH group or a halide group, where radical R 7 The compound according to any one of claims 1 to 3, which may not include a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group, that forms an internal carboxylate group or an internal amide group. Case Study 5 residue R 1 or R 2 Only one or more of these include at least one part of general formula (III) or (IV), (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), Preferably, residue R 1 or R 2Only one or more of these include at least one part of general formula (IIIa) or general formula (IVa), (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Here, X, R 6 , R 7 The compound according to any of the above claims, wherein m is as defined above. Case 6 The compound according to any of the above claims, wherein at least 1% of all groups F comprises at least one part of general formula (III) or (IV), more preferably at least 10% of all groups F comprises at least one part of general formula (III) or (IV), even more preferably at least 50% of all groups F comprises at least one part of general formula (III) or (IV), and most preferably 100% of all groups F comprises at least one part of general formula (III) or (IV), or wherein at least 1% of all groups F comprises at least one part of general formula (IIIa) or (IVa), more preferably at least 10% of all groups F comprises at least one part of general formula (IIIa) or (IVa), even more preferably at least 50% of all groups F comprises at least one part of general formula (IIIa) or (IVa), and most preferably 100% of all groups F comprises at least one part of general formula (IIIa) or (IVa). Case 7 All base R 2 At least 1% of the compound comprises at least one part of general formula (III) or (IV), and more preferably all of the base R 2 At least 10% of the compound comprises at least one part of general formula (III) or (IV), and more preferably all of the base R 2At least 50% of it comprises at least one part of general formula (III) or (IV), and most preferably all of the base R 2 100% of the formula contains at least one part of general formula (III) or (IV), or where all base R 2 At least 1% of the compound comprises at least one part of general formula (IIIa) or (IVa), and more preferably all of the base R 2 At least 10% of the compound comprises at least one part of general formula (IIIa) or (IVa), and more preferably all of the base R 2 At least 50% of the compound comprises at least one part of general formula (IIIa) or (IVa), and most preferably all of the base R 2 100% of the compound according to any of the above claims comprises at least one part of general formula (IIIa) or (IVa). Case Study 8 All base R 3 , R 4 and R 5 At least 1% of the compound comprises at least one part of general formula (III) or (IV), and more preferably all of the base R 3 , R 4 and R 5 At least 10% of the compound comprises at least one part of general formula (III) or (IV), and more preferably all of the base R 3 , R 4 and R 5 At least 50% of the compound comprises at least one part of general formula (III) or (IV), and most preferably all of the base R 3 , R 4 , and R 5 100% of the formula contains at least one part of general formula (III) or (IV), or all of the base R 3 , R 4 and R 5 At least 1% of the compound comprises at least one part of general formula (IIIa) or (IVa), and more preferably all of the base R 3 , R 4 and R 5At least 10% of the compound comprises at least one part of general formula (IIIa) or (IVa), and more preferably all of the group R 3 , R 4 and R 5 At least 50% of the compound comprises at least one part of general formula (IIIa) or (IVa), and most preferably all of the base R 3 , R 4 and R 5 100% of the compound according to any of the above claims comprises at least one part of general formula (IIIa) or (IVa). Case 9 In equation (I), x is 2, which is the same as the general equation (V) shown in chemical formula 49, where R 1 , R 2 , R 3 , R 4 , R 5 The compound according to any of the above claims, wherein n is as defined above. Case Study 10 F has the general formula (VI) shown in chemical formula 51, and the base F is R 1 Bonded to the carbon atom, here R 3 , R 4 , R 5 This is independently selected from optionally substituted linear, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radicals, having hydrogen and up to 300 carbon atoms, preferably 1 to 200 carbon atoms, more preferably 1 to 150 carbon atoms, even more preferably 1 to 50 carbon atoms, specifically 1 to 20 carbon atoms, and more specifically 1 to 10 carbon atoms, and optionally comprising one or more groups selected from -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, and quaternary ammonium groups, and which may be substituted with OH. Counterion A -The anions are selected from monovalent to trivalent inorganic anions and monovalent to 30,000 valent, preferably 1,000 valent organic anions, preferably halogenated anions, e.g., chlorides, bromides and iodides, sulfates, phosphates, phosphonates, sulfonates, methosulfates, carboxylate anions, e.g., acetate, propionate, lactate, octanoate, 2-ethyl-hexanoate, dodecanoate, hexadecanoate, octadecanoate, oleate, ricinolate, 12-hydroxy-octadecanoate, succinate, maleate, tartrate, polyethercarboxylate, The following types of high molecular weight fatty acid carboxylates, R 1 [(-C(O)-XR 6 ) m -C(O)-XR 7 ] x or R 1 [(XC(O)-R 6 ) m -XC(O)-R 7 ] x , Here R 1 or R 7 At least one of the following, or R 1 and R 7 At least one of them has one or more carboxylate groups, Preferably, here X=O, especially, - The following types of linear polymer fatty acid carboxylates, - OC(O)-R 6 (-XC(O)-R 6 ) m-1 -XC(O)-R 7 Preferably - OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , In other words, it originates from a linear polyfatty acid structure, - Branched linear polymer fatty acid carboxylates, In other words, it is a branched linear polymer fatty acid carboxylate derived from a branched polyfatty acid structure, and in particular from a partial ester of a polyfunctional carboxylic acid, especially dicarboxylic acid, succinic acid, and maleic acid, with castor oil or rescera oil, for example, the compound of formula 54. Here, one R is as shown in chemical formula 55, and the remaining two R groups are as shown in chemical formula 56. - Dendrimer-like high molecular weight fatty acid carboxylate, In other words, it originates from a dendrimer-like polyfatty acid structure, Or the following types, XR 6 (-C(O)-XR 6 ) m-1 -C(O)-XR 7 or R 6 (-C(O)-XR 6 ) m-1 -C(O)-XR 7 , Here, in the latter two types, R 7 The group has at least one anionic carboxylate group, Or the following types: R 1 [(-C(O)-X-R6) m -C(O)O - ] x , And here are X and R 1 , R 6 , R 7 m and x are as defined above, Here, the counterion A of this group - The anion is preferably monovalent to 50valent, more preferably monovalent to 10valent, even more preferably monovalent to 5valent, most preferably pentavalent, tetravalent, trivalent, divalent, or monovalent. Selected from, Alternatively, the counter anion is a carboxylate anion based on poly(acrylic acid) homopolymers and copolymers. That is, carboxylate derived from the polyacrylic acid homopolymer of formula 57 Here, p = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. That is, a carboxylate anion derived from a polyacrylic acid copolymer containing a non-reactive comonomer, where Copolymers can have a block-like or random distribution of comonomer units. Alternatively, a carboxylate anion derived from a polyacrylic acid copolymer, comprising a comonomer that provides OH and amine functional groups that can be functionalized via further ester or amide bonds with fatty acids or polyfatty acids, Alternatively, a carboxylate anion derived from a polyacrylic acid copolymer containing a carboxylic acid functional group comonomer, where Copolymers can have a block-like or random distribution of comonomer units. Carboxylates based on maleic acid copolymers, particularly those derived from maleic anhydride copolymers, here Copolymers can have a block-like or random distribution of comonomer units. Carboxylates based on poly(itaconic acid) homo and copolymers, In other words, it is derived from the polyitaconate homopolymer of formula 62, Here, h = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Alternatively, derived from polyitaconic acid copolymer, i.e., itaconic acid copolymer containing non-reactive comonomers, Here Copolymers can have a block-like or random distribution of comonomer units. Alternatively, a polyitaconic acid copolymer, for example, derived from a 2-hydroxyethyl methacrylate-itaconic acid copolymer, comprising a comonomer that provides OH and amine functional groups that can be functionalized via further ester or amide bonds with fatty acids or polyfatty acids, Alternatively, derived from a polyitaconic acid copolymer containing a carboxylic acid functional group-containing comonomer, where Copolymers can have a block-like or random distribution of comonomer units. Here, the anion of this group is preferably an anion with a valency of 2 to 30,000, more preferably 2 to 1,000, even more preferably 10 to 1,000, even more preferably 50 to 1,000, and most preferably 100 to 1,000. Selected from the group consisting of, However, the radical R of the cationic structure of formulas (I) and (II) 1 , R 3 , R 4 , R 5 The condition is that at least one of them contains at least one part of general formula (IIIa) or (IVa), (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Here, X is as defined above, m=1 to 20, preferably 1 to 10, more preferably 1 to 6, even more preferably 2 to 6, specifically 1, 2, 3, 4, 5, 6, and R 11 Preferably, hydrogen, n-, iso-, or tert.-C1-C 22 -alkyl, C2-C 22 -Alkoxyalkyl, C5-C 30 -Cycloalkyl, C6-C 30 -Aryl, C6-C 30 -Aryl (C1-C6)alkyl, C6-C 30 -Alkylaryl, C2-C 22 -Alkenyl, C2-C 22- Alkenyloxyalkyl groups that may be optionally substituted with hydroxyl and halogen groups, respectively, and may optionally contain one or more ether groups (-O-), preferably hydrogen, or n-, iso-, or tert.-C1-C 22 - Selected from the group consisting of alkyl groups, R 6 These are independently selected from optionally substituted linear, cyclic, or branched saturated or unsaturated hydrocarbon radicals having 1 to 36 carbon atoms, preferably 1 to 24 carbon atoms, more preferably 1 to 18 carbon atoms, and even more preferably 8 to 18 carbon atoms. R 7 R is independently selected from optionally substituted linear, cyclic or branched saturated or unsaturated hydrocarbon radicals, where radical R is the radical, and R is the radical, which has 1 to 36 carbon atoms, preferably 1 to 24 carbon atoms, more preferably 1 to 18 carbon atoms, even more preferably 8 to 18 carbon atoms, and optionally comprises one or more groups selected from -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, and quaternary ammonium groups, and may be substituted with an OH group or a halide group. 7 It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group, which form an internal carboxylate group or an internal amide group. However, at least one R 6 It has more than six carbon atoms, and For x=1 R 1 , R 3 , R 4 , R 5 is -OCH2CH 2 The compound according to any of the above claims, provided that it is not bonded to the nitrogen atom of the group in formula 67 via -. Case 11 R 1This is selected from hydrocarbon radicals that are optionally substituted with -OH, and which have up to 1000 carbon atoms, preferably 2 to 300 carbon atoms, more preferably 3 to 200 carbon atoms, even more preferably 3 to 150 carbon atoms, specifically 3 to 50 carbon atoms, more specifically 3 to 20 carbon atoms, and optionally contain one or more groups selected from -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, and quaternary ammonium groups, and may be substituted with -OH, and which are optionally substituted with monovalent to 50-valent, preferably 1 to 30-valent, more preferably 1 to 20-valent, even more preferably 1 to 10-valent, specifically monovalent, divalent, trivalent, tetravalent, pentavalent, hexavalent, heptavalent, octavalent, notavalent, and decavalent hydrocarbon radicals, and F has the general formula (VI) shown in chemical formula 70, and the base F is R 1 Bonded to the carbon atom, Here R 3 , R 4 , R 5 This is independently selected from optionally substituted linear, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radicals, having up to 300 carbon atoms, preferably 1 to 200 carbon atoms, more preferably 1 to 150 carbon atoms, even more preferably 1 to 50 carbon atoms, specifically 1 to 20 carbon atoms, and more specifically 1 to 10 carbon atoms, and optionally comprising one or more groups selected from -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, and quaternary ammonium groups, and which may be substituted with OH. Counterion A - The anions are selected from monovalent to trivalent inorganic anions and monovalent to 30,000-valent, particularly monovalent to 1,000-valent organic anions, preferably halogenated anions, e.g., chlorides, bromides and iodides, sulfates, phosphates, phosphonates, sulfonates, methosulfates, carboxylate anions, e.g., acetate, propionate, lactate, octanoate, 2-ethyl-hexanoate, dodecanoate, hexadecanoate, octadecanoate, oleate, ricinolate, 12-hydroxy-octadecanoate, succinate, maleate, tartrate, polyethercarboxylate, The following types of high molecular weight fatty acid carboxylates, R 1 [(-C(O)-XR 6 ) m -C(O)-XR 7 ] x or R 1 [(XC(O)-R 6 ) m -XC(O)-R 7 ] x , Here R 1 or R 7 At least one of the following, or R 1 and R 7 At least one of them has one or more carboxylate groups, Preferably, here X=O, especially - The following types of high molecular weight fatty acid carboxylates - OC(O)-R 6 (-XC(O)-R 6 ) m-1 -XC(O)-R 7 Preferably - OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , In other words, it originates from a linear polysaturated acid structure, - Branched linear polymer fatty acid carboxylates, In other words, it is a branched linear polymer fatty acid carboxylate derived from a branched polyfatty acid structure, and in particular from a partial ester of a polyfunctional carboxylic acid, especially dicarboxylic acid, succinic acid and maleic acid, with castor oil or rescera oil, for example, the compound of formula 73. Here, one R is shown by chemical formula 74, The remaining two R groups are shown by chemical formula 75. - Dendrimer-like high molecular weight fatty acid carboxylate, In other words, it originates from a dendrimer-like polyfatty acid structure, Or the following types, XR 6 (-C(O)-XR 6 ) m-1 -C(O)-XR 7 or R 6 (-C(O)-XR 6 ) m-1 -C(O)-XR 7 , Here, in the latter two types, R 7 The group has at least one anionic carboxylate group, Or the following types: R 1 [(-C(O)-X-R6) m -C(O)O - ] x , And here are X and R 1 , R 6 , R 7 m and x are as defined above, Here, the counterion A of this group - The anion is preferably monovalent to 50valent, more preferably monovalent to 10valent, even more preferably monovalent to 5valent, most preferably pentavalent, tetravalent, trivalent, divalent, or monovalent. Selected from, Alternatively, the counter anion is a carboxylate anion based on poly(acrylic acid) homopolymers and copolymers as defined above. Carboxylate anions derived from polyacrylic acid copolymers, In other words, it contains a non-reactive comonomer, Here Copolymers can have a block-like or random distribution of comonomer units. Alternatively, a carboxylate anion derived from an acrylic acid copolymer, comprising a comonomer that provides OH and amine functional groups that can be functionalized via further ester or amide bonds with fatty acids or polyfatty acids, Alternatively, a carboxylate anion derived from a polyacrylic acid copolymer containing a carboxylic acid functional group comonomer, where Copolymers can have a block-like or random distribution of comonomer units. Carboxylates based on maleic acid copolymers, particularly those derived from maleic anhydride copolymers, here Copolymers can have a block-like or random distribution of comonomer units. As defined above, derived from polyitaconic acid copolymers containing carboxylates based on poly(itaconic acid) homo and copolymers, or, i.e., non-reactive monomer monomers. Here Copolymers can have a block-like or random distribution of comonomer units. Alternatively, itaconic acid copolymers, for example, derived from 2-hydroxyethyl methacrylate-itaconic acid copolymers, comprising comonomers that provide OH and amine functional groups that can be functionalized via further ester or amide bonds with fatty acids or polyfatty acids, Alternatively, derived from a polyitaconic acid copolymer containing a carboxylic acid functional group-containing comonomer, where Copolymers can have a block-like or random distribution of comonomer units. Here, the anion of this group is preferably an anion with a valency of 2 to 30,000, more preferably 2 to 1,000, even more preferably 10 to 1,000, and most preferably 100 to 1,000. Selected from the group consisting of, However, the radical R of the cationic structure of formulas (I) and (II) 1 , R 3 , R 4 , R 5 The condition is that at least one of them contains at least one part of general formula (VII) or (VIII), -XC(O)-R x -(XC(O)-R x ) m-1 -XC(O)-R 7(VII) or -XC(O)-R x -(XC(O)-R x ) m -XC(O)-R 7 (VIII) Here X is O or NR 11 And, m=1 to 20, preferably 1 to 10, more preferably 1 to 6, even more preferably 2 to 6, specifically 1, 2, 3, 4, 5, 6, and R x +R 7 The total number of carbon atoms (Σ carbon atoms R x , R 7 ) is 19 to 300, preferably 25 to 300, more preferably 35 to 300, even more preferably 50 to 300, specifically 35 to 200, more specifically 35 to 150, and even more specifically 50 to 150, R 11 is preferably selected from hydrogen, n-, iso-, or tert.-C1-C22-alkyl, and more preferably hydrogen. R x The following are optional: OH, -OC(O)-R 7 -OC(O)-R 6 -(OC(O)-R 6 ) 0-19 -OC(O)-R 7 A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical having 1 to 36 carbon atoms, preferably 1 to 24 carbon atoms, more preferably 1 to 18 carbon atoms, and even more preferably 8 to 18 carbon atoms, preferably derived from monohydroxycarboxylic acids, particularly glycolic acid, lactic acid, 2-hydroxybutyric acid, 3-hydroxy-butyric acid, 4-hydroxybutyric acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, reskerolic acid, ricinoleic acid, or dihydroxycarboxylic acids, particularly 2,2'-dihydroxymethylpropanoic acid, 9,10-dihydroxystearic acid, or polyhydroxycarboxylic acids, particularly gluconic acid. R 6This is defined as described above, R 7 The compound according to any of the above claims, which is an optionally substituted linear, cyclic or branched saturated or unsaturated hydrocarbon radical having 1 to 36 carbon atoms, preferably 1 to 24 carbon atoms, more preferably 1 to 18 carbon atoms, and even more preferably 8 to 18 carbon atoms, preferably derived from acetic acid, octanoic acid, nonanoic acid, decanoic acid, dodecanoic acid, tetradecanoic acid, hexadecanoic acid, octadecanoic acid, eicosanoic acid, docosanoic acid, 2-ethylhexanoic acid, 2,2-dimethylpropionic acid, 2,2-dimethylheptanoic acid, 2,2-dimethyloctanoic acid, neodecanoic acid, undecyl-10-enoic acid, oleic acid, linoleic acid, linolenic acid, and erucic acid. Case Study 12 R 1 teeth, A linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radical, optionally substituted with OH or amide, having a valency of 1 to 18, preferably 2 to 18, more preferably 2 to 6, and even more preferably 2, 3, and 4, Tertiary amines having at least three, preferably more than three, carbon atoms, particularly trimethylamine, triethylamine, tributylamine, N,N-dimethylethanolamine, N,N-dimethylpropanolamine, N-methylimidazole, N,N,N',N'-tetramethyl-1,2-diaminoethane, N,N,N',N'-tetramethyl-1,4-diaminobutane, N,N,N',N'-tetramethyl-1,6-diaminohexane, N,N,N',N'',N''-pentame Tyl-diethylenetriamine, N,N,N',N'',N''-pentamethyl-dipropylenetriamine, bis-(2-dimethylaminoethyl) ether, bis-(2-dimethylaminopropyl) ether, 2,2'-dimorpholinodiethyl ether, N,N-bis-(3-dimethylaminopropyl)-N-isopropanolamine, N,N,N'-trimethylaminoethyl-ethanolamine, 1,3,5-tris(3-(dimethylamino)propyl)-hexahydro-s-triazine; Epoxy compounds, especially glycidyl ethers, alcohols, especially methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol and higher-order linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), pentaerythritol, sorbitol, poly(alkylene oxide), e.g., (ethylene oxide)-, (propylene oxide)- and / or (butylene oxide)-based polyethers, e.g., derived from polyethylene glycol such as diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol, Dipropylene glycol (e.g., derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol, and other polypropylene glycols. Condensation products derived from a mixed (ethylene oxide)- and (butylene oxide)-based copolyether, a mixed (propylene oxide)- and (butylene oxide)-based copolyether, and a mixed (ethylene oxide), (propylene oxide), and (butylene oxide)-based copolyether; Derived from, or preferably from, an acid, particularly neodecanoic acid, a primary or secondary amino-functionalized amine, particularly N,N-dimethylpropylenediamine, N,N,N',N'-tetramethyl-diethylenetriamine, N,N,N',N'-tetramethyl-dipropylenetriamine, N-methylmorpholine, N-methylpiperazine, a glycidyl ester; and - Linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon groups optionally substituted with OH, amino, or amide, having a valency of 1 to 18, preferably 2 to 18, more preferably 2 to 6, and even more preferably 2, 3, and 4, wherein the alkyl halides have one or more, preferably two or more, carbon atoms, e.g., alkyl chlorides, bromides, iodides, e.g., 1,3-dichloropropane, 1,3-dichlorobutane, 1,4-dichlorobutane, dichloro-monohydroxypropane isomers, 1,2,3-trichloropropane, 1,2-dichlorohexanediol, 1,2-dichlorohexane, or their respective bromide and iodide derivatives; - A linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon group optionally substituted with OH, amino, or amide, having a total of two or more carbon atoms, preferably a chlorocarboxylic acid, chloroacetic acid, 3-chloropropionic acid, 4-chlorobutanoic acid, or their respective bromocarboxylic acids, alcohols, particularly methanol, ethanol, etc. 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol and higher-order linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), pentaerythritol, sorbitol Derived from esters formed by condensation of poly(alkylene oxide), for example, (ethylene oxide)-, (propylene oxide)-, and / or (butylene oxide)-based polyethers, for example, derived from polyethylene glycols such as diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol, or derived from polypropylene glycols such as dipropylene glycol (for example, derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, and pentapropylene glycol, derived from mixed (ethylene oxide)- and (butylene oxide)-based copolyethers, derived from mixed (propylene oxide)- and (butylene oxide)-based copolyethers, and derived from mixed (ethylene oxide)- and (propylene oxide)- and (butylene oxide)-based copolyethers. - Epoxy compounds, preferably glycidyl ethers, alcohols, i.e., methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol Oligoglycerols, triglycerols and higher-order linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), pentaerythritol, sorbitol, poly(alkylene oxides), e.g., (ethylene oxide)-, (propylene oxide)- and / or (butylene oxide)-based polyethers, e.g., derived from polyethylene glycol such as diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol, or dipropylene glycol (e.g., derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene Ethers or esters derived from reactions with polypropylene glycols such as glycols, tetrapropylene glycol, and pentapropylene glycol; ethers derived from mixed (ethylene oxide)- and (butylene oxide)-based copolyethers; ethers derived from mixed (propylene oxide)- and (butylene oxide)-based copolyethers; and ethers derived from mixed (ethylene oxide)- and (propylene oxide)- and (butylene oxide)-based copolyethers; or glycidyl esters derived from acids, particularly neodecanoic acid. - A linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon group optionally substituted with OH, amino, or amide, having a valency of 1 to 18, preferably 2 to 18, more preferably 2 to 6, and even more preferably 2, 3, and tetravalent, wherein the group is a halogenated carboxylic acid, preferably a chlorocarboxylic acid having a total of more than 2, preferably more than 3, carbon atoms, such as chloroacetic acid, 3-chloropropionic acid, 4-chlorobutanoic acid, or their respective bromocarboxylic acids, and is an ether or ester of an epoxy compound, preferably a glycidyl ether, of an alcohol, particularly methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2- Propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol, and higher-order linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), pentaerythritol, sorbitol, poly(alkylene oxide), e.g., (ethylene oxide)-, (propylene oxide)- and / or (butylene oxide)-based polyethers, in particular those derived from polyethylene glycol such as diethylene glycol, triethylene glycol, tetraethylene glycol, pentaethylene glycol, or dipropylene glycol (especially 2,2'-oxydi-1-propanol, 1,Esters derived from 1'-oxydi-2-propanol and 2-(2-hydroxypropoxy)-1-propanol, polypropylene glycols such as tripropylene glycol, tetrapropylene glycol, and pentapropylene glycol, mixed (ethylene oxide)- and (butylene oxide)-based copolyethers, mixed (propylene oxide)- and (butylene oxide)-based copolyethers, and mixed (ethylene oxide)- and (propylene oxide)- and (butylene oxide)-based copolyethers, preferably formed from glycidyl esters with acids, particularly neodecanoic acid, - A linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon group optionally substituted with OH, having a total of more than 7, preferably more than 8 carbon atoms, formed from an epoxy compound, preferably a glycidyl ether, having a divalent to hexavalent carboxylic acid, particularly maleic acid, succinic acid, adipic acid, sebacic acid, itaconic acid, tartaric acid, trimellitic acid, fatty dimer acid, or ether made of a carboxyl(-C(O)OH) functionalized polyester, and particularly preferably a divalent to hexavalent carboxylic acid, for example maleic acid, succinic acid, adipic acid, sebacic acid, itaconic acid, tartaric acid, trimellitic acid, fatty dimer acid, Formed by condensation with divalent to hexavalent alcohols or alkylene oxides described above, such as ethylene oxide, propylene oxide, butylene oxide, and compounds containing at least one glycidoxy group, such as glycidol, diglycidyl ether, glycerol diglycidyl ether, glycerol triglycidyl ether, and oligomer glycerol glycidyl ether, and butanediol diglycidyl ether, particularly succinic acid, maleic acid, tartaric acid, fatty dimeric acids, glycerol diglycidyl ether, polyester, and especially preferably oligomerized hydroxycarboxylic acids, particularly oligomerized lactic acid, 12-hydroxystearic acid, ricinoleic acid, and reskerolic acid, - Linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon groups optionally substituted with OH, having a valency of 1 to 18, preferably 2 to 18, more preferably 2 to 6, and even more preferably 2, 3, and 4, esters of halogenated carboxylic acids, preferably chlorocarboxylic acids, having a total of more than 5, preferably more than 6 carbon atoms, for example, esters of chloroacetic acid, 3-chloropropionic acid, 4-chlorobutanoic acid, or their respective bromocarboxylic acids, derived from OH-functionalized polyesters, particularly carboxylic acids with a valency of 2 to 6, for example, maleic acid, succinic acid, adipic acid, sebacic acid, itaconic acid, tartaric acid, A compound according to any of the above claims, selected from the group consisting of a compound comprising a limellitic acid, a fatty dimer acid, a divalent to hexavalent alcohol or alkylene oxide as described above, for example, ethylene oxide, propylene oxide, butylene oxide, and at least one glycidoxy group, for example, formed by condensation with glycidol, diglycidyl ether, glycerol diglycidyl ether, glycerol triglycidyl ether and oligomeric glycerol glycidyl ether, and butanediol diglycidyl ether, in particular by a condensation product of succinic acid, maleic acid, tartaric acid, or a fatty dimer acid with glycerol diglycidyl ether. Case Study 13 R 1 This is selected from poly(alkylene oxide) groups, preferably poly(alkylene oxide) groups of general formula (IX), -[CH2CH2O] q1 -[CH2CH(CH3)O] r1 -[CH2CH(C2H5)O] s1 -{[CH2CH2] q2 -[CH2CH(CH3)] r2 -[CH2CH(C2H5)] s2}- (IX) Here q1 = 0 to 49, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, r1 = 0 to 32, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5. s1 = 0 to 24, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, q2 = 0 or 1, r² = 0 or 1, s2 = 0 or 1, and Σ(q²+r²+s²)=1, However, the total number of carbon atoms in such poly(alkylene oxide) groups is 2 to 100, preferably 2 to 50, more preferably 2 to 30, even more preferably 2 to 20, specifically 2 to 15, or R 1 It is selected from divalent hydrocarbon groups derived from oligoglycerol of general formula (X), -[CH2CH(R 8 )CH2O] t1 -[CH2CH(R 8 )CH2)] t2 - (X) Here t1 = 0 to 32, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, specifically 1 and 2. t2=1, R 8 =OH or (-XC(O)-R 6 ) m -XC(O)-R 7 -OC(O)-R 6 -N + (R 3 ,R 4 ,R 5 ), Here, m, X, R 3 , R 4 , R 5 , R 6 , and R 7 This is as defined above, However, the total number of carbon atoms is 2 to 100, preferably 2 to 50, more preferably 2 to 30, even more preferably 2 to 20, specifically 2 to 15, or R1 This is the general formula (XI) -[CH2CH2O] q1 -R 9 -[CH2CH2O] q1 -[CH2CH2] q2 - (XI) Here, q1 is either the same or different, and as defined above, and q2=1, and formula (XII) -[CH2CH(R 8 )CH2O] t1 -R 9 -[CH2CH(R 8 )CH2O] t1 -[CH2CH(R 8 )CH2)] t2 - (XII) Here, t1, t2, and R 8 This is as defined above, and R 9 is -C(O)C(O)O-, -C(O)(CH2) 1-8 C(O)O-, for example, derived from succinic acid, adipic acid, sebacic acid, or -C(O)(C6H4)C(O)O-, derived from phthalic acid and terephthalic acid, -C(O)CH=CHC(O)O-, -C(O)C(=CH2)-CH2C(O)O-, -C(O)CH(OH)CH(OH)C(O)O-, selected from these. However, R 9 The condition is that the total number of carbon atoms is 2 to 100, preferably 2 to 50, more preferably 2 to 30, even more preferably 2 to 20, specifically 2 to 15. Selected from divalent hydrocarbon groups containing at least one ester group, And preferably, R 1 It comprises one or more -O- groups, for example, 1 to 5, where these -O- groups are preferably ether groups, but can also form ester groups with carbonyl groups, and preferably group R 1 The compound according to any one of claims 1 to 2 and 4 to 12, wherein is substituted with one or more hydroxyl groups. Case Study 14 N+ The radical R that is bound to it 1 , R 3 , R 4 , R 5 One or more of these are general formulas (III) or (IV), (-XC(O)-R 6 ) m -XC(O)- (III), or (-C(O)-XR 6 ) m -C(O)-X- (IV), Preferably, general formula (IIIa) or (IVa) (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa), or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Here, m = 1-20, and X, R 6 and R 7 This is as defined above. If it includes at least one part of, At least one part is general formula (XIII) or (XIV), -R 10 (-XC(O)-R 6 ) m -XC(O)- (XIII) -R 10 (-C(O)-XR 6 ) m -C(O)-X- (XIV), Preferably, general formulas (XIIIa) and (XIVa), -R 10 (-XC(O)-R 6 ) m -XC(O)-R 7 (XIIIa) -R 10 (-C(O)-XR 6 ) m -C(O)-XR 7 (XIVa) It has a structure, Here R 10 Here, radical R is selected from hydrocarbon radicals that are optionally substituted with divalent to 18valent, preferably divalent to 10valent, more preferably divalent to 20valent, more preferably divalent to 6valent, more preferably divalent to 10valent, specifically divalent, trivalent, tetravalent, pentavalent, hexavalent, heptapastic, octavalent, quaternary, and decapitative, where radical R is the most abundant of the three 10 It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group, which form an internal carboxylate group or an internal amide group. And preferably R 10 teeth, - Divalent radicals, particularly -CH2-, -CH2CH2-, -CH2CH2CH2-, preferably derived from monochlorocarboxylic acids such as chloroacetic acid, chloropropionic acid, and chlorobutanoic acid, or preferably derived from tertiary amino alcohols such as N,N-dimethylethanolamine and N,N-dimethylpropanolamine. - Derived from a trivalent radical, preferably a trivalent alcohol, particularly glycerol, trimethylolpropane, or castor oil (ricinoleic acid triglyceride), a partial ester of the monochlorocarboxylic acid, particularly ester with chloroacetic acid, or preferably derived from a tertiary amino alcohol such as N,N,N'-trimethylaminoethyl-ethanolamine, or preferably derived from a dihydroxycarboxylic acid, particularly 2,2-hydroxymethylpropanoic acid, a tertiary amino alcohol, particularly ester of N,N-dimethylethanolamine or N,N-dimethylpropanolamine, - Derived from partial esters of the monochlorocarboxylic acid, particularly esters of chloroacetic acid, by tetravalent to hexavalent radicals, preferably tetravalent alcohols, particularly erythritol, pentaerythritol, diglycerol, pentavalent alcohols, particularly xylitol, triglycerol, and hexavalent alcohols, particularly sorbitol, tetraglycerol, or preferably from dendrimer oligomers of dihydroxycarboxylic acid oligomers, particularly dendrimer oligomers of 2,2-hydroxymethylpropanoic acid, derived from esters of tertiary amino alcohols, particularly N,N-dimethylethanolamine and N,N-dimethylpropanolamine, Derived from the partial esters of the monochlorocarboxylic acid, particularly esters of chloroacetic acid, by radicals with 7- to 18 valencies, alcohols with 7- to 18 valencies, especially pentaglycerol to hexadecaglycerol, Represented by, However, R 10 N is formed by a single bond. + A portion is bonded to and at least one radical of the structure of general formula (III) or (IV), preferably 1, 2, 3, or 4 radicals, (-XC(O)-R 6 ) m -XC(O)- (III), or (-C(O)-XR 6 ) m -C(O)-X- (IV), And more preferably, 1, 2, 3, or 4 radicals of general formula (IIIa) or (IVa), (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) It is connected, Here, X, m, R 11 , R 6 , R 7 The compound according to any of the above claims, provided that it is as defined above. Case Study 15 Regarding the part, -R 10 (-XC(O)-R 6 ) m -XC(O)- (XIII), or preferably -R 10 (-XC(O)-R 6 ) m -XC(O)-R 7 (XIIIa) Here R 10 The adjacent X is O, R 10 It is derived from mono- or di-(chloroacetic acid) esters of glycerol or castor oil (ricinoleic acid triglyceride), and in total, one or two parts (-XC(O)-R 6 ) m -XC(O)-, preferably (-XC(O)-R) 6 ) m -OC(O)-R 7 It is connected, or R 10 It is derived from tertiary amino alcohols, particularly esters of N,N-dimethylethanolamine, N,N-dimethylpropanolamine, and N,N,N'-trimethylaminoethylethanolamine, and in total, one part (-XC(O)-R 6 ) m -OC(O)-R 7 Preferably (-XC(O)-R 6 ) m -OC(O)-R 7 It is connected, or R 10 It is derived from esters of tertiary amino alcohols, particularly N,N-dimethylethanolamine and N,N-dimethylpropanolamine, by dihydroxycarboxylic acids, especially 2,2-hydroxymethylpropanoic acid, and in total, two parts (-XC(O)-R 6 ) m -XC(O)-, preferably (-XC(O)-R) 6 ) m -OC(O)-R 7 It is connected, or R 10 These are derived from tertiary amino alcohols, particularly esters of N,N-dimethylethanolamine and N,N-dimethylpropanolamine, by dendrimer oligomers of dihydroxycarboxylic acid, especially dendrimer oligomers of 2,2-hydroxymethylpropanoic acid, and in total, more than two, preferably three or four parts (-XC(O)-R 6 ) m -XC(O)-, preferably (-XC(O)-R) 6 ) m -OC(O)-R 7 It is connected, And regarding the parts, -R 10 (-XC(O)-R 6 ) m -XC(O)- (XIII) or preferably -R 10 (-XC(O)-R 6 ) m -XC(O)-R 7 (XIIIa) Here R 10 The adjacent X is N, R 10 These are derived from tertiary-primary amines, particularly N,N-dimethyl-1,3-propanediamine, N-methyl-N'-aminopropyl-piperazine, and tertiary-secondary amines, particularly N-methylpiperazine, and For both types of parts, R 6 These are as defined above, and are preferably derived from lactic acid, reskerol acid, ricinoleic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, and 14-hydroxytetradecanoic acid. R 7 These are as defined above, and are preferably derived from octadecanoic acid, eicosanoic acid, docosanoic acid, 2-ethylhexanoic acid, 2,2-dimethylpropionic acid, neodecanoic acid, and oleic acid. m=1 to 20, preferably 1 to 10, more preferably 1 to 6, even more preferably 2 to 6, specifically 1, 2, 3, 4, 5, 6, 7, and R 6 +R 7 The total number of carbon atoms (Σ carbon atoms R 6 , R 7 ) is 19 to 300, preferably 25 to 300, more preferably 35 to 300, even more preferably 50 to 300, specifically 35 to 200, more specifically 35 to 150, and even more specifically 50 to 150, R 11 The compound according to claim 14, wherein the compound is preferably selected from the group consisting of hydrogen or ring-forming alkylenes, and in particular derived from a piperazine ring. Case 16 R 6 These are as defined above, and are preferably derived from lactic acid, reskerol acid, ricinoleic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, and 14-hydroxytetradecanoic acid. R 7 These are as defined above, and are preferably derived from octadecanoic acid, eicosanoic acid, docosanoic acid, 2-ethylhexanoic acid, 2,2-dimethylpropionic acid, neodecanoic acid, and oleic acid. And regarding the parts, -R 10 (-XC(O)-R 6 ) m -XC(O)- (XIII) and -R 10 (-C(O)-XR 6 ) m -C(O)-X- (XIV), Preferably, for the part, -R 10 (-XC(O)-R 6 ) m -XC(O)-R 7 (XIIIa) and -R 10 (-C(O)-XR 6 ) m -C(O)-XR 7 (XIVa) Radical R within the ester segment 6 , and R if present 7The sequence is either random or blocky, and for blocky sequences, the compound has the general formula (XV) or (XVI), -R 10 -XC(O)-R 6 (-XC(O)-R 61 ) m1 (-XC(O)-R 62 ) m2 -XC(O)- (XV) -R 10 -C(O)-XR 6 (-C(O)-XR 61 ) m1 (-C(O)-XR 62 ) m2 -C(O)-X- (XVI), Preferably, the general formula is (XVa) or (XVIa), -R 10 -XC(O)-R 6 (-XC(O)-R 61 ) m1 (-XC(O)-R 62 ) m2 -XC(O)-R 7 (XVa) -R 10 -C(O)-XR 6 (-C(O)-XR 61 ) m1 (-C(O)-XR 62 ) m2 -C(O)-XR 7 (XVIa) It includes the structure, Here R 61 and R 62 is R 6 Selected from, m1 = 0 to 20, preferably 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6. m2 = 0 to 20, preferably 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6. m=(m1+m2)+1, m=1 to 20, preferably 1 to 10, more preferably 1 to 6, even more preferably 1 to 6, specifically 1, 2, 3, 4, 5, 6, 7, and R 6 +R 7 The total number of carbon atoms (Σ carbon atoms R 6 , R 7 ) is 19 to 300, preferably 25 to 300, more preferably 35 to 300, even more preferably 50 to 300, specifically 35 to 200, more specifically 35 to 150, and even more specifically 50 to 150, The compounds according to either of 14 and 15, wherein the structural sequences of general formulas (XV) and (XVI) are preferably selected from the sequences listed in Table 1, and the structural sequences of general formulas (XVa) and (XVIa) are preferably selected from the sequences listed in Table 2. Case Study 17 Low-melting point and high-melting point fatty acids ≥ C5 are R of general formulas (III) and (IV). 6 Within the contained ester elements, (-XC(O)-R 6 ) m -XC(O)- (III) (-C(O)-XR 6 ) m -C(O)-X- (IV), especially R in general formulas (IIIa) and (IVa) 6 and R 7 Within the contained ester elements, (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) and (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa), or R of general formulas (XIII) and (XIV) 6 Among the contained ester elements, -R 10 (-XC(O)-R 6 ) m -XC(O)- (XIII) -R10 (-C(O)-XR 6 ) m -C(O)-X- (XIV), especially R of general formulas (XIIIa) and (XIVa) 6 and R 7 Among the contained ester elements, -R 10 (-XC(O)-R 6 ) m -XC(O)-R 7 (XIIIa) -R 10 (-C(O)-XR 6 ) m -C(O)-XR 7 (XIVa) It is specifically placed in Here, low-melting-point fatty acids ≥ C5 are defined as those with a melting point ≥ 40°C, and in particular include oleic acid, reskerolic acid, ricinoleic acid, octanoic acid, decanoic acid, pivalic acid, and neodecanoic acid. High melting point fatty acids ≥ C5 are defined as those with a melting point > 40°C, and include, in particular, dodecanoic acid, tetradecanoic acid, hexadecanoic acid, octadecanoic acid, arachidic acid, behenic acid, 10-hydroxyoctadecanoic acid, 12-hydroxyoctadecanoic acid, and 14-hydroxytetradecanoic acid. - At least one, preferably more than one, more preferably one, two or three, each being base R 6 Low melting point fatty acids ≥ C5 that form are R of formula (III) or (IV). 6 One end of the contained ester element, while at least one, preferably more than one, more preferably one, two, or three high melting point fatty acids ≥ C5, are located at the opposite end of the ester element of formula (III) or (IV), with one or more radicals R 6 A configuration that forms, or at least one, preferably more than one, more preferably one, two or three, each of which is a base R 6 High melting point fatty acids ≥ C5 that form are R of formula (III) or (IV). 6One end of the contained ester element, while at least one, preferably more than one, more preferably one, two, or three low-melting-point fatty acids ≥ C5, are located at the opposite end of the ester element of formula (III) or (IV), with one or more radicals R 6 A method that forms, or - At least one, preferably more than one, more preferably one, two or three, each based R 6 Low melting point fatty acids ≥ C5 that form R 7 One or more radicals adjacent to R 6 Included in, on the other hand, at least one, preferably more than one, more preferably one, two or three, high melting point fatty acids ≥ C5 are R of formula (IIIa) or (IVa). 6 and R 7 At the opposite end of the contained ester element, one or more radicals R 6 A manner that forms, or at least one, preferably more than one, more preferably one, two or three, each R 6 High melting point fatty acids ≥ C5 that form R 7 One or more radicals adjacent to R 6 It forms a low-melting-point fatty acid ≥ C5 of formula (IIIa) or (IVa) 6 and R 7 At the opposite end of the contained ester element, one or more radicals R 6 A method of forming, or - At least one, preferably more than one, more preferably one, two or three, each based R 6 Low melting point fatty acids ≥ C5 that form radicals R 10 Adjacent to it, and on the other hand, at least one, preferably more than one, more preferably one, two or three high-melting-point fatty acids ≥ C5 are arranged at the opposite end of the ester element of formula (XIII) or (XIV), with one or more radicals R 6This is a method of forming R, or at least one, preferably more than one, more preferably one, two or three, each R 6 High melting point fatty acids ≥ C5 that form radicals R 10 One or more radicals adjacent to R 6 It forms a compound, while at least one, preferably more than one, more preferably one, two, or three low-melting-point fatty acids ≥ 5 are R of formula (XIII) or (XIV). 6 and R 7 At the opposite end of the contained ester element, one or more radicals R 6 A method of forming, or - At least one, preferably more than one, more preferably one, two or three, each based R 6 Low melting point fatty acids ≥ C5 that form radicals R 10 Adjacent to it, and on the other hand, at least one, preferably more than one, more preferably one, two or three, high melting point fatty acids ≥ C5 are arranged in the part of formula (XIIIa) or (XIVa), R 7 One or more radicals adjacent to R 6 This is a method of forming R, or at least one, preferably more than one, more preferably one, two or three, each R 6 High melting point fatty acids ≥ C5 that form R 10 One or more radicals adjacent to R 6 It forms a low melting point fatty acid ≥ C5, on the other hand, at least one, preferably more than one, more preferably one, two or three, in the part of formula (XIIIa) or (XIVa), R 7 One or more radicals adjacent to R 6 This is a method of forming The compound according to any of the above claims. Case Study 18 R 10 teeth, - Two or more parts -OC(O)-R 6 -(OC(O)-R 6 ) mDerived from mono- or di-(chloroacetic acid) esters of glycerol or castor oil (ricinoleic acid triglyceride) containing -OC(O)-, or comprising one or two parts -OC(O)-R in total. 6 -(OC(O)-R 6 ) m -OC(O)-R 7 Join, - Derived from esters of tertiary amino alcohols, particularly N,N-dimethylethanolamine, N,N-dimethylpropanolamine, and N,N,N'-trimethylaminoethyl-ethanolamine having an ester of a hydroxylated carboxylic acid. - Compounds according to any one of claims 14 to 17, derived from tertiary-primary amines, in particular N,N-dimethyl-1,3-propanediamine, N-methyl-N'-aminopropyl-piperazine, or tertiary-secondary amines, in particular N-methylpiperazine amides. Case 19 R 1 teeth, - By reaction of a halogenated carboxylic acid, preferably chloroacetic acid, with an OH-functionalized hydrocarbon, - A reaction between a halogenated carboxylic acid, preferably chloroacetic acid, and an epoxy-functionalized hydrocarbon or epoxy ester, based on the epoxy-functionalized hydrocarbon by a difunctional carboxylic acid, - By reaction of an epoxy derivative, preferably a glycidyl ether or glycidyl ester derivative, with a difunctional carboxylic acid, A compound formed according to any of the above claims. Case Study 20 Counterion A -These include monovalent to trivalent inorganic anions and monovalent to 30,000 valent, preferably monovalent to 1,000 valent organic anions, such as halide anions, for example, chlorides, bromides, iodides, sulfates, phosphates, phosphonates, sulfonates, methosulfates, carboxylate anions, for example, acetates, propionates, lactates, octanoates, 2-ethyl-hexanoates, dodecanoates, hexadecanoates, octadecanoates, oleates, ricinoleates, 12-hydroxy-octadecanoates, succinates, maleates, tartrates, polyethercarboxylates, The following types of high molecular weight fatty acid carboxylates, R 1 [(-C(O)-XR 6 ) m -C(O)-XR 7 ] x or R 1 [(XC(O)-R 6 ) m -XC(O)-R 7 ] x Here, R 1 or R 7 At least one of the following, or R 1 and R 7 At least one of them has one or more carboxylate groups, Preferably, here X=O, especially The following types of linear polymer fatty acid carboxylates, - OC(O)-R 6 (-XC(O)-R 6 ) m-1 -XC(O)-R 7 Preferably - OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , Branched linear polymer fatty acid carboxylates, In other words, it is a branched linear polymer fatty acid carboxylate derived from a branched polyfatty acid structure, and in particular from a partial ester of a polyfunctional carboxylic acid, especially dicarboxylic acid, succinic acid and maleic acid, with castor oil or rescera oil, for example, the compound of formula 73. Here, one R is chemical formula 74, The remaining two R groups are dendrimer-like high molecular weight fatty acid carboxylates, as shown in formula 75. In other words, it originates from a dendrimer-like polyfatty acid structure, Or the following types, XR 6 (-C(O)-XR 6 ) m-1 -C(O)-XR 7 or R 6 (-C(O)-XR 6 ) m-1 -C(O)-XR 7 , Here, in the latter two types, R 7 The group has at least one anionic carboxylate group, Or the following types, R 1 [(-C(O)-X-R6) m -C(O)O - ] x ,for example, Here, X, R 1 , R 6 , R 7 m and x are as defined above, and here the counterion A of this group - The anion is preferably monovalent to 50valent, more preferably monovalent to 10valent, even more preferably monovalent to 5valent, most preferably pentavalent, tetravalent, trivalent, divalent, or monovalent. Selected from the group consisting of, Alternatively, an anion is selected from the group consisting of poly(acrylic acid) homo and copolymers, poly(itaconic acid) homo and copolymers, where the anion of this group is preferably 2 to 30,000 valencies, more preferably 2 to 1,000 valencies, even more preferably 10 to 1,000 valencies, even more preferably 50 to 1,000 valencies, and most preferably 100 to 1,000 valencies. Preferably, the following types of polymer fatty acid carboxylates, - OC(O)-R 6 (-XC(O)-R 6 ) m-1 -XC(O)-R 7 Here, the esterified OH substituent is absent in the single-chain molecule, or Preferably, the following types of high molecular weight fatty acid carboxylates are used: R 1 [(-C(O)-X-R6) m -C(O)O - ] x As defined above, The compound according to any of the above claims, wherein the carboxylate contains a branched or dendrimer (self-repeating) motif, and is particularly derived from 2,2'-dihydroxymethylpropanoic acid. Case Study 21 The compound according to any of the above claims, wherein in formula (III) and / or (IV), X=O, and preferably the compound does not contain any amide group. Case Study 22 The cationic structure of general formulas (I) and (II) contains the group R 1 , R 2 , R 3 , R 4 , R 5 At least one of them includes at least one part of the following expression: R 1* [(-OC(O)-R 6 ) m -OC(O)-]2, Here R 1*These are divalent C1-C100 radicals, preferably C1-C12 alkylenes, most preferably methylene, ethylene, 1,3-propylene, 1,4-butylene, 1,6-hexylene, 1,2-propylene, and 1,3-butylene radicals. m is independently selected from 1 to 12. R 6 The compound according to any of the above claims, as defined above. Case Study 23 In at least one part of the following general formula, R 1* [(-OC(O)-R 6 ) m -OC(O)-]2, R 1* It is selected from methylene, ethylene, 1,3-propylene, 1,4-butylene, 1,6-hexylene, 1,2-propylene, and 1,3-butylene. R 6 These are derived from C8-C24 monocarboxy-monohydroxycarboxylic acids, particularly ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, and 11-hydroxy-undecanoic acid. The compound according to any of the above claims, wherein m is independently selected from 1 to 6. Case Study 24 The cationic structure of general formulas (I) and (II) contains the group R 1 , R 2 , R 3 , R 4 , R 5 At least one of them includes at least one part of the following general formula: R 1* [(-OC(O)-R 6 ) m -OC(O)-]2, This is represented by the following structural formula: -C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-OC(O)-(mono or oligo C8-C24 hydroxy fatty acid)-OC(O)-, Here C2-C10 hydrocarbons are C2-C10 hydrocarbylene groups, and The compound according to claim 22 or 23, wherein the mono or oligo C8-C24 hydroxy fatty acid is a group derived from a C8-C24 hydroxy-substituted carboxylic acid monomer, or an oligomer of up to 20 C8-C24 hydroxy-substituted carboxylic acid monomers formed by esterification, with a degree of oligomerization of 2 to 20, preferably 2 to 10, more preferably 2 to 6, and even more preferably 2 to 4. Case Study 25 The cationic structure of general formulas (I) and (II) contains the group R 1 , R 2 , R 3 , R 4 , R 5 At least one of them includes at least one part of the following expression: R 1* [(-OC(O)-R 6 ) m -OC(O)-R 7* -]2, Here R 1* , R 6 , and m are as defined above, And R 7* The compound according to claim 22, wherein is a C1-C12 alkylene group, preferably a methylene, ethylene, propylene, or butylene group, most preferably a methylene group. Case Study 26 In at least one part of the following general formula, R 1* [(-OC(O)-R 6 ) m -OC(O)-R 7* -]2 R 1* These are selected from methylene, ethylene, 1,3-propylene, and 1,4-butylene, and 1,6-hexylene. R 6 These are derived from C8-C24 monocarboxy-monohydroxycarboxylic acids, particularly ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, and 11-hydroxy-undecanoic acid. m is independently selected from 1 to 6, And R 7* The compound according to claim 25, selected from methylene and ethylene. Case Study 27 At least one part of the following general formula is: R 1* [(-OC(O)-R 6 ) m -OC(O)-R 7* -]2 It is represented by one of the following structural formulas, i) -CH2-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-OC(O)-(mono or oligo C8-C24 hydroxy fatty acid)-OC(O)-CH2- or ii) -CH2CH2-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-OC(O)-(mono or oligo C8-C24 hydroxy fatty acid)-OC(O)-CH2CH2-, Here C2-C10 hydrocarbons are C2-C10 hydrocarbylene groups, and The compound according to any one of claims 25 and 26, wherein the mono or oligo C8-C24 hydroxy fatty acid is a group derived from a C8-C24 hydroxy-substituted carboxylic acid monomer, or an oligomer of up to 20 C8-C24 hydroxy-substituted carboxylic acid monomers formed by esterification, wherein the degree of oligomerization is 2 to 20, preferably 2 to 10, more preferably 2 to 6, and even more preferably 2 to 4, and is particularly a group derived from mono or oligosilinoleic acid. Case Study 28 At least one part of the following general formula is: R 1* [(-OC(O)-R 6 ) m -OC(O)-R 7* -]2 One or both terminal R 7*The compound according to any one of claims 25, 26, and 27, wherein a quaternary N atom of the group is bonded to it. Case Study 29 Both terminal groups R 7* Each of them is bonded to a quaternary N atom, The compound is a diquat or tetraquat compound, as described in claim 28 above. Case Study 30 The compound comprises at least two parts of the following general formula: R 1* [(-OC(O)-R 6 ) m -OC(O)-R 7* -]2, And here The aforementioned parts are linked to each other via diquaternary ammonium alkylene groups of the general structure shown below. -N + (CH3)2-ALK-N + (CH3)2-, The compound according to claim 28, wherein ALK is a divalent alkylene group having 1 to 12 carbon atoms, preferably a linear alkylene group. Case Study 31 The cationic structure of general formulas (I) and (II) contains the group R 1 , R 2 , R 3 , R 4 , R 5 At least one of them includes at least one part of the following general formula: -([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])- Here R 6 This is as defined above, l is an integer independently selected from 0 to 20, more preferably from 1 to 12, and even more preferably from 2 to 10, and L is a divalent hydrocarbon radical that may have 1 to 30 carbon atoms and may optionally contain one or more groups selected from -O-, -S-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. Preferably, L is a divalent alkylene or alkenylene radical having 1 to 30 carbon atoms. More preferably, L is selected from methylene, ethylene, propylene, butylene, pentylene, hexylene, heptylene, octylene, nonylene, etenylene, propenylene, butenylene, pentenylene, hexenylene, heptenylene, octenylene, nonenylene. Most preferably, L is selected from methylene, ethylene, ethenylene, or butenylene, the compound according to any of the above claims. Case Study 32 In at least one part of the following general formula, -([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])- L and l are as defined above, And R 6 The compound according to claim 31, wherein the compound is independently derived from a C8-C24 monocarboxy-monohydroxycarboxylic acid. Case Study 33 In at least one part of the following general formula, ([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])- L is selected from methylene, ethylene, and ethenylene. R 6 It is derived from ricinoleic acid, and The compound according to either of the aforementioned claims 31 or 32, wherein l is independently selected from 0, 1, 2, and 3, and the sum of l is in the range of 0-4. Case Study 34 The cationic structure of general formulas (I) and (II) contains the group R 1 , R 2 , R 3 , R 4 , R 5 At least one of them includes at least one part of the following general formula: -([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])- This can be represented by the following structure: -OC(O)-(mono or oligo C8-C24 hydroxy fatty acid)-OC(O)-(C1-C12 hydrocarbon)-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O- - C1-C12 hydrocarbons are C1-C12 hydrocarbylene groups, and - The compound according to any of the above claims, wherein the mono or oligo C8-C24 hydroxy fatty acid is a group derived from a C8-C24 hydroxy-substituted carboxylic acid monomer, or an oligomer of up to 20 C8-C24 hydroxy-substituted carboxylic acid monomers formed by esterification, with a degree of oligomerization of 2 to 20, preferably 2 to 10, more preferably 2 to 6, and even more preferably 2 to 4. Case Study 35 The cationic structure of general formulas (I) and (II) contains the group R 1 , R 2 , R 3 , R 4 , R 5 At least one of them includes at least one part of the following general formula: -([-OC(O)-R 6 (-OC(O)-R 6 ) l-OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])-R 12 -, Here L, l, R 6 This is as defined above, And R 12 It is a C1 to C12 linear or branched hydrocarbylene group that may contain up to four -O- groups and up to four tertiary amino groups, and is bonded to an -O- group of an ester group at one end and to a quaternary N atom at the other end. Preferably R 12 The compound according to any of the above claims, which is derived from a tertiary amino alcohol, particularly an amino alcohol having the structure shown in chemical formula 100. Case Study 36 A method for synthesizing a compound of general formula (I) according to any of the above claims, R 1 (-F) x (I) Here Alkyl halides are at least one part (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably at least one part (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) It has reacts with a tertiary amine, or As defined above, a halogenated carboxylic acid, preferably an ester of chloroacetic acid with an alcohol or epoxide, is at least one part (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably at least one part (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) It has reacts with a tertiary amine, or As defined above, epoxy-functionalized ethers and esters with alcohols or carboxylic acids, preferably glycidyl ethers and esters, are at least one portion (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably at least one part (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) It reacts with a tertiary amine having the following properties in the presence of an acid: or As defined above, a tertiary amino group-containing hydrocarbon is at least one part (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m-C(O)-X- (IV), preferably at least one part (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) It reacts with esters of halogenated carboxylic acids, or As defined above, a tertiary amino group-containing hydrocarbon is at least one part (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably at least one part (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) It has epoxy-functionalized ethers and esters that react in the presence of an acid, Here, X, R 6 , R 7 The method is as defined above, where m and x are , m and x. Case 37 A method for synthesizing a compound of general formula (I) as described in claim 36, Regarding compounds of general formula (I), R 1 (-F) x (I), Here R 1 This is a quaternary nitrogen atom N + via R 3 , R 4 , and R 5It is coupled with R 1 (-F) x teeth, General formula (III) (-XC(O)-R 6 ) m -XC(O)- (III), Or general formula (IV) (-C(O)-XR 6 ) m -C(O)-X- (IV), It includes at least one part of, preferably, General formula (IIIa) (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) Or general formula (IVa) (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Having at least one part of, Alkyl halides are, (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably includes at least one part of, (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Having at least one part of, It reacts with tertiary amines, or As defined above, a halogenated carboxylic acid, preferably an ester of chloroacetic acid with an alcohol or epoxide, (-XC(O)-R6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably includes at least one part of, (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Having at least one part of, It reacts with tertiary amines, or As defined above, epoxy-functionalized ethers and esters, preferably glycidyl ethers and esters, are provided with an alcohol or carboxylic acid. (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably includes at least one part of (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Having at least one part of, It reacts with a tertiary amine in the presence of an acid. or As defined above, tertiary amino group-containing hydrocarbons are (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6) m -C(O)-X- (IV), preferably includes at least one part of (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Having at least one part of, It reacts with halogenated carboxylic acid esters, or As defined above, tertiary amino group-containing hydrocarbons are (-XC(O)-R 6 ) m -XC(O)- (III) or (-C(O)-XR 6 ) m -C(O)-X- (IV), preferably includes at least one part of, (-XC(O)-R 6 ) m -XC(O)-R 7 (IIIa) or (-C(O)-XR 6 ) m -C(O)-XR 7 (IVa) Having at least one part of, A method for reacting epoxy-functionalized ethers and esters with an acid. Case Study 38 A method for synthesizing a compound of general formula (I) as described in claim 36, Regarding compounds of general formula (I), R 1 (-F) x (I) Here R 1 The quaternary nitrogen atom N + It is coupled with R 1 (-F) xIt has at least one part of the general formula (XIII), (XIV), (XIIIa), or (XIVa), -R 10 (-XC(O)-R 6 ) m -XC(O)- (XIII) -R 10 (-C(O)-XR 6 ) m -C(O)-X- (XIV), preferably -R 10 (-XC(O)-R 6 ) m -XC(O)-R 7 (XIIIa) -R 10 (-C(O)-XR 6 ) m -C(O)-XR 7 (XIVa) Alkyl halides react with tertiary amines having at least one part of the general formula (XIII), (XIV), (XIIIa), or (XIVa). or Esters formed from halogenated carboxylic acids, preferably chloroacetic acid, with alcohols or epoxides react with tertiary amines having at least one part of general formula (XIII), (XIV), (XIIIa), or (XIVa). or As defined above, epoxy-functionalized ethers and esters formed with alcohols or carboxylic acids, preferably glycidyl ethers and esters, react with tertiary amines having at least one part of general formula (XIII), (XIV), (XIIIa), or (XIVa) in the presence of an acid. or As defined above, tertiary amino group-containing hydrocarbons react with esters of halogenated carboxylic acids having at least one part of general formula (XIII), (XIV), (XIIIa), or (XIVa). or As defined above, tertiary amino group-containing hydrocarbons react with epoxy-functionalized ethers and esters having at least one part of general formula (XIII), (XIV), (XIIIa), or (XIVa) in the presence of an acid. Here R 10 This is as defined above. method. Case Study 39 Use of the compound according to any one of claims 1 to 35 in cosmetic formulations for skin and hair care, particularly in conditioners and shampoos; in abrasives for treating and coating hard surfaces; in formulations for drying automobiles and other hard surfaces; for example, as a separate softener for use after automatic washing, for finishing textiles and textile fibers, after textiles have been washed with a nonionic or anionic / nonionic detergent formulation; as a softener in formulations for washing textiles based on nonionic or anionic / nonionic surfactants; and as a means for preventing or removing wrinkles in textiles. Case Study 40 Use of the compound according to any one of claims 1 to 35 in a cosmetic composition, particularly useful for strengthening hair, maintaining hair color, improving hair shine, enhancing hair color, protecting hair color, shaping hair, conditioning hair, improving hair smoothness and softness, improving hair manageability, and especially for improving combability, anti-friction, and anti-static properties of hair, for fibers, preferably amino acid-based fibers, more preferably for the treatment of human hair. Case 41 A composition for hair treatment comprising a compound according to any one of claims 1 to 35, selected from the group consisting of hair shampoo compositions, hair conditioning compositions, hair strengthening compositions, hair coloring or dyeing compositions, hair combability improving compositions, hair frizz prevention compositions, hair rinse-off and leave-on compositions.

[0214] Typical adjuvants in these types of compositions are, for example, A. Domsch: Die kosmetischenPraeparate [Cosmetic Preparations] Vol. I and II, 4th Edition, Verl. fuer chem. Industrie [Publishers for the Chemical Industry], U. Ziolkowsky KG, Augsburg, and the International Cosmetic Ingredient Dictionary and Handbook 7. th These materials are described in *Ed. 1997* by JA Wenninger and GN McEwen, Vol. 1–4, by The Cosmetic, Toiletry and Fragrance Association, Washington DC.

[0215] In particular, the present invention relates to compositions for hair treatment as defined above, selected from the group consisting of hair shampoo compositions, hair conditioning compositions, hair strengthening compositions, hair coloring or dyeing compositions, hair combability improving compositions, hair frizz prevention compositions, hair rinse-off and leave-on compositions. In subsequent formulations, the term "high molecular weight fatty acid compounds of the present invention" is used to refer to the compounds defined above.

[0216] Formulation example

[0217] Anionic shampoo This example formulation is intended for basic formulations. Anionic shampoos typically contain, but are not limited to, the following ingredients: alkyl sulfates, alkyl ether sulfates, sodium lauryl sulfate, sodium lauryl ether sulfate, ammonium lauryl sulfate, ammonium lauryl ether sulfate, TEA-lauryl sulfate, TEA-lauryl ether sulfate, alkylbenzene sulfonates, α-olefin sulfonates, paraffin sulfonates, sulfosuccinates, N-acyl taurides, sulfate glycerides, sulfated alkanolamides, carboxylates, N-acyl amino acid salts, silicones, etc. [Table 3]

[0218] Non-ionic shampoo This example formulation is intended for basic formulations. Nonionic shampoos typically contain, but are not limited to, the following ingredients: monoalkanolamides, monoethanolamides, monoisopropanolamides, polyhydroxy derivatives, sucrose monolaurate, polyglycerin ethers, amine oxides, polyethoxylated derivatives, sorbitol derivatives, silicones, etc. [Table 4]

[0219] Amphoteric shampoo This example formulation is intended for basic formulations. Formulations in this category are not limited to but typically include the following ingredients: N-alkyl-iminodipropionates, N-alkyl-iminopropionates, amino acids, amino acid derivatives, amidebetaines, imidazolinium derivatives, sulfobetaines, sultaines, betaines, silicones, etc. [Table 5]

[0220] Cationic shampoo This example is intended for basic formulations only. Formulations in this category are not limited to but typically include the following ingredients: bis-quaternary ammonium compounds, bis-(trialkylammoniumacetyl)diamines, amidoamines, ammonium alkyl esters, silicones, etc. [Table 6]

[0221] Setting agent This example is intended for basic formulations only. Formulations in this category are not limited to but typically include the following ingredients: fatty acids, fatty acid esters, ethoxylated fatty acids, ethoxylated fatty acid esters, fatty alcohols, ethoxylated fatty alcohols, glycols, glycol esters, glycerin, glycerin esters, lanolin, lanolin derivatives, mineral oil, petrolatum, lecithin, lecithin derivatives, waxes, wax derivatives, cationic polymers, proteins, protein derivatives, amino acids, amino acid derivatives, humectants, thickeners, silicones, etc. [Table 7]

[0222] "Clear Rinse Off" Setting Agent This example formulation is intended for basic formulations. Formulations in this category are not limited to but typically include the following ingredients: fatty acids, fatty acid esters, ethoxylated fatty acids, ethoxylated fatty acid esters, fatty alcohols, ethoxylated fatty alcohols, glycols, glycol esters, glycerin, glycerin esters, lanolin, lanolin derivatives, mineral oil, petrolatum, lecithin, lecithin derivatives, waxes, wax derivatives, cationic polymers, proteins, protein derivatives, amino acids, amino acid derivatives, humectants, thickeners, silicones, etc. [Table 8]

[0223] Hair foam setting agent This example formulation is intended for basic formulations. Formulations in this category include, but are not limited to, the following ingredients: fatty acids, fatty acid esters, ethoxylated fatty acids, ethoxylated fatty acid esters, fatty alcohols, ethoxylated fatty alcohols, glycols, glycol esters, glycerin, glycerin esters, lanolin, lanolin derivatives, mineral oil, petrolatum, lecithin, lecithin derivatives, waxes, wax derivatives, cationic polymers, proteins, protein derivatives, amino acids, amino acid derivatives, humectants, thickeners, silicones, solvents, ethanol, isopropanol, isoparaffin solvents, butane, propane, isobutane, fluorinated aerosol propellants for CFCs, dimethyl ether, compressed gases, etc. [Table 9]

[0224] Hair setting spray (pump spray) This example is intended for basic formulations only. Formulations in this category are not limited to but typically include the following ingredients: fatty acids, fatty acid esters, ethoxylated fatty acids, ethoxylated fatty acid esters, fatty alcohols, ethoxylated fatty alcohols, glycols, glycol esters, glycerin, glycerin esters, lanolin, lanolin derivatives, mineral oil, petrolatum, lecithin, lecithin derivatives, waxes, wax derivatives, cationic polymers, proteins, protein derivatives, amino acids, amino acid derivatives, humectants, thickeners, silicones, solvents, ethanol, isopropanol, isoparaffin solvents, etc. [Table 10]

[0225] Hair setting spray This example formulation is intended for basic formulations. Formulations in this category are not limited to but typically include the following ingredients: fatty acids, fatty acid esters, ethoxylated fatty acids, ethoxylated fatty acid esters, fatty alcohols, ethoxylated fatty alcohols, glycols, glycol esters, glycerin, glycerin esters, lanolin, lanolin derivatives, mineral oil, petrolatum, lecithin, lecithin derivatives, waxes, wax derivatives, cationic polymers, proteins, protein derivatives, amino acids, amino acid derivatives, humectants, thickeners, silicones, solvents, ethanol, isopropanol, isoparaffin solvents, butane, propane, isobutane, fluorinated aerosol propellants for CFCs, dimethyl ether, compressed gases, etc. [Table 11]

[0226] Hair gel setting agent This example formulation is intended for basic formulations. Formulations in this category are not limited to but typically include the following ingredients: thickeners, cellulose derivatives, acrylic acid derivatives, fixative polymers, conditioning chemicals, glycols, glycol esters, glycerin, glycerin esters, lanolin, lanolin derivatives, mineral oil, petrolatum, lecithin, lecithin derivatives, waxes, wax derivatives, cationic polymers, proteins, protein derivatives, amino acids, amino acid derivatives, humectants, silicones, solvents, ethanol, isopropanol, isoparaffin solvents, etc. [Table 12]

[0227] Rinse-off conditioner This example formulation is intended for basic formulations. Formulations in this category typically include, but are not limited to, the following ingredients: hydrocarbon-based cationic conditioning agents, silicone-based cationic conditioning agents, high-melting-point fatty compounds, low-melting-point oils such as ester compounds, thickeners, cellulose derivatives, fixed polymers, ethylene glycol, propylene glycol, glycol esters, glycerin, glycerin esters, monohydric alcohols, polyhydric alcohols, cationic polymers, nonionic and betaine coemulsifiers, silicones, complexing agents, solvents, fragrances, vitamins, etc. [Table 13]

[0228] Hair styling gel This example formulation is intended for basic formulations. Formulations in this category are not limited to, but typically include: fixed polymers, lacquers, acrylic acid derivatives, cellulose derivatives, vinyl derivatives, conditioning chemicals, glycols, glycol esters, glycerin, glycerin esters, lanolin, lanolin derivatives, mineral oil, petrolatum, lecithin, lecithin derivatives, waxes, wax derivatives, cationic polymers, proteins, protein derivatives, amino acids, amino acid derivatives, humectants, thickeners, silicones, solvents, ethanol, isopropanol, isoparaffin solvents, etc. [Table 14]

[0229] Hair styling spray This example formulation is intended for basic formulations. Formulations in this category are not limited to but typically include the following ingredients: fixed polymers, lacquers, vinyl derivatives, fatty acids, fatty acid esters, ethoxylated fatty acids, ethoxylated fatty acid esters, fatty alcohols, ethoxylated fatty alcohols, glycols, glycol esters, glycerin, glycerin esters, lanolin, lanolin derivatives, mineral oil, petrolatum, lecithin, lecithin derivatives, waxes, wax derivatives, cationic polymers, proteins, protein derivatives, amino acids, amino acid derivatives, humectants, thickeners, silicones, solvents, ethanol, isopropanol, isoparaffin solvents, butane, propane, isobutane, fluorinated aerosol propellants for CFCs, dimethyl ether, compressed gases, etc. [Table 15]

[0230] Hair styling spray (pump spray) This example formulation is intended for basic formulations. Formulations in this category are not limited to but typically include the following ingredients: vinyl derivatives, fixed polymers, lacquers, fatty acids, fatty acid esters, ethoxylated fatty acids, ethoxylated fatty acid esters, fatty alcohols, ethoxylated fatty alcohols, glycols, glycol esters, glycerin, glycerin esters, lanolin, lanolin derivatives, mineral oil, petrolatum, lecithin, lecithin derivatives, waxes, wax derivatives, cationic polymers, proteins, protein derivatives, amino acids, amino acid derivatives, humectants, thickeners, silicones, solvents, ethanol, isopropanol, isoparaffin solvents, butane, propane, isobutane, fluorinated aerosol propellants for CFCs, dimethyl ether, compressed gases, etc. [Table 16]

[0231] The use of the high molecular weight fatty acid derivatives identified in this invention for applications in the hair care field yields favorable results in terms of strengthening, shine, fixation (holding), body, volume, moisture regulation, color retention, protection against environmental factors (UV, saltwater, etc.), manageability, combability, anti-frizzy properties, anti-static properties, and dyeing ability.

[0232] Further formulation examples: In the following formulation examples, unless otherwise specified, all values ​​listed represent amounts expressed as "wt-% of the total composition". [Table 17]

[0233] procedure Polyquta 400 KC was added to a vortex of water and mixed until completely dispersed and clear. Phase A was heated to 40-45°C. Pureact WS Conc, Pureact Gluco L, and Pureact MS-CG were homogenized by heating to 40-45°C and mixing the products before adding them to the main container. Subsequently, the components of Phase B were added and mixed until homogeneous and clear. Slowly, Surfac SB09 and the high molecular weight fatty acid compound of the present invention (Phase C) were added to the main container and mixed until homogeneous. The container was cooled below 40°C, then the preservative was added and mixed until the mixture was clear and homogeneous. The flavoring was added and mixed until completely emulsified and clear. The pH was adjusted to 4.2-4.7 with citric acid solution (50% w / w) as needed. Small aliquots of sodium chloride (0.2% w / w) were added as needed until the desired viscosity was achieved.

[0234] [Table 18]

[0235] procedure Phase A was added to the container with gentle stirring. It was mixed until clear. Phase B was added to Phase A with stirring at room temperature. It was mixed until homogeneous. While continuing to stir, Phase C was slowly added to Phase A / B using a fitting mixer. Once the mixture was homogeneous, the pH was adjusted to 5.00-5.50 with Phase D.

[0236] [Table 19]

[0237] procedure In the main container, the components of phase A were combined in the order of formulation by shear mixing and then heated to 140°F to 149°F (60-65°C). Phase B was added to phase A in the order of formulation while continuously mixing. The solution thickened when it was neutralized to the desired pH. In a separate container, the components of phase C were combined and heated to 140°F to 149°F (60-65°C). Once homogenized, phase C was added to phases A and B under propeller mixing. Phase D was combined in a separate container and then added to the main container under continuous mixing. The mixture was transferred to the final container.

[0238] [Table 20]

[0239] procedure The components of Phase A were mixed with moderate propeller stirring while heating to 70°C until homogeneous. Phase B was added to Phase A and mixed until homogeneous. The deionized water of Phase C was heated to 65-70°C and Quatrisoft Polymer LM-200 was dissolved. Once Quatrisoft Polymer LM-200 was completely dissolved, Tauranol I-78 was slowly added. Phase C was slowly added to Phases A and B. Mixed until homogeneous and cooled to 50°C. Phase D was added to Phases A, B and C in the order listed with moderate propeller stirring. The mixture was cooled to room temperature.

[0240] [Table 21]

[0241] procedure The components of Phase A were gently mixed and added to the main container, and heated to 70-75°C. Phase B was added to Phase A, and mixing continued while maintaining the temperature at 70-75°C. Phase C was added to Phases A and B, and mixing continued while maintaining the temperature at 70-75°C. Once the batch was homogenized, it was cooled. Phase D was added to the batch. Once the batch had cooled to 45°C, the preheated sticks were filled. The sticks were placed in the freezer for 12-24 hours before first use.

[0242] [Table 22]

[0243] procedure In the main beaker, the weight of phase A was measured and heated to 75°C. Phase B was sprinkled into the aqueous phase, and it was allowed to hydrate completely with Carbopol. Homogenization was performed, phase C was added and neutralized, and homogenization was performed again. In a separate container, the weight of phase D was measured and heated to 75°C. Phase D was slowly added to the aqueous phase under high agitation. The emulsion was then cooled with moderate agitation. At 35°C, phases E and F were added and homogenized.

[0244] [Table 23]

[0245] procedure Water was added to a suitable container. While heating the water to 80-85°C, Hostapon SCI, Glucotain Plus, and Amphosol CS-50 were added. The mixture was mixed until homogeneous at 80-85°C and then removed from the heat. In a separate beaker, Celquat 240C, Glucquat 125, and deionized water were mixed until homogeneous. Once homogeneous, the Celquat / Gluquat blend was added to the main batch (Phase A). The components of Phase C were added one by one and mixed well. The pH of the solution was adjusted to pH 6.0 to 6.5 with 20% citric acid or 20% NaOH. The batch was filled to 100% with deionized water.

[0246] [Table 24]

[0247] procedure In a separate container, the components of phase A were mixed while being heated to 50°C and added separately. Mixing was carried out until uniform and homogeneous. The mixture was cooled to a temperature of <35°C. In separate containers, the components of phase B and phase C were added separately while being mixed and added until uniform. When the main container had cooled to 35°C, phases B and C were added to phase A. Mixing was carried out until uniform. Phase D was added to the main container to adjust the pH to 4.80-5.40. Phase E was added to the main container with gentle stirring and mixed until uniform.

[0248] [Table 25]

[0249] procedure In a separate container, the components of Phase A were mixed while being heated to 50°C and added separately. They were mixed until homogeneous and uniform, and the mixture was cooled to a temperature below 35°C. In separate containers, the components of Phase B and Phase C were added while being mixed separately and mixed until homogeneous. Once the main container had cooled to 35°C, Phase B and Phase C were added to Phase A and mixed until homogeneous. Phase D was added to the main container to adjust the pH to 4.80-5.40. Phase E was added to the main container with gentle stirring and mixed until homogeneous.

[0250] [Table 26]

[0251] procedure The components of Phase A were combined in the main container using a propeller mixer in the order of formulation and heated to 60-70°C. In a separate container, the components of Phase B were combined in the propeller mixer in the order of formulation and heated to 60-70°C. Once both Phase A and Phase B were completely homogenized, Phase B was continuously added to Phase A while mixing. Heating was stopped once the mixture was completely dispersed. When the temperature reached 35-40°C, Phase C was continuously added to Phases A and B while mixing. Phase D was added to Phases A, B, and C, mixing was stopped, and the process was switched to a homogenizer. The mixture was homogenized for 10-30 seconds. Once completed, the mixture was transferred to a holding container.

[0252] [Table 27]

[0253] procedure In the main container, the components of Phase A were added separately while gently mixing until the mixture was homogeneous. Phase B was dispersed in the container by high-shear mixing. Once the batch was homogeneous, the components of Phase C were added individually and mixed until homogeneous before the next addition. The pH was adjusted to 5.40-6.00 with sodium hydroxide and mixed until the gel was homogeneous.

[0254] [Table 28]

[0255] procedure Phase A was heated to 75°C with stirring. In a separate container, the components of Phase B were heated to 75°C with stirring. Phase B was added to Phase A, and mixing continued for 10 minutes. The mixture was removed from the heat, and stirring continued until the product reached 40°C. The components of Phase C were combined and thoroughly mixed under moderate stirring. Phase C was added to Phase A / B at 40°C, and stirring continued until the product reached room temperature.

[0256] [Table 29]

[0257] procedure Water was placed in a mixing container, and polyquaternium-10 (B) was sprinkled into the water and mixed until clear. Iselux Ultra Mild (C) was poured into the main container while mixing moderately. Phase (D) was mixed into the batch. After mixing until clear, the desired fragrance and preservative were added, and the pH was adjusted using citric acid (50% w / w solution) (G).

[0258] [Table 30]

[0259] procedure The components of Phase A were mixed and heated to 80°C. The components of Phase B were blended at 80°C. Phase B was added to Phase A. It was cooled to 40°C, and then Phase C was added. It was cooled further, Phase D was added, and the mixture was adjusted to pH 4.3-4.7.

[0260] [Table 31]

[0261] procedure Phase A was added to the main container and mixed until homogeneous. Phase B was added to Phase A. In the secondary container, Phase C was combined and then slowly added to Phases A and B, where the pH must be >4. The preservative was added to Phases A, B and C. The batch was initially discontinuous, but mixing continued. The surfactant was slowly added to Phases A, B, C and D. The batch became homogeneous and increased in viscosity. Finally, the fragrance was added.

[0262] [Table 32]

[0263] procedure The components of phase B were added to phase A while mixing. Next, the components of phase C were added to phase AB. The components of phase D were added to phase ABC under high shear. Finally, phase E was added.

[0264] [Table 33]

[0265] procedure Phase A was heated to 75-80°C. Phase B was pre-mixed and added to Phase A with medium-speed mixing. It was cooled to 40°C, and Phase C was added. The pH was checked and adjusted as needed using citric acid solution.

[0266] [Table 34]

[0267] procedure Phase A was prepared and heated to 75-80°C. Phase B was prepared and heated to 70-75°C. Phase B was added to Phase A and homogenized for several minutes using a suitable dispersion unit (e.g., Silverson, Ultra Turrax). It was cooled to 40°C, and then Phases C and D were added and mixed for several minutes. The mixture was cooled to room temperature.

[0268] [Table 35]

[0269] procedure Phase A was added to a container while being heated to 45-50°C and gently stirred. It was mixed until homogeneous. While stirring, Phase B was added to Phase A. It was mixed until homogeneous. While continuing to stir, Phase C was added to Phases A / B. Once homogeneous, the components of Phase D were added individually to Phases A / B / C while being gently stirred. Mixing was performed between each addition.

[0270] [Table 36]

[0271] procedure Water was added to the main container and mixed by propeller stirring. Styleze ES-1 was added to the vortex and dispersed. Citric acid was added and mixed for about 10-15 minutes. Benecel E4M was added and mixed until no particles were visible. The teolimeric fatty acid compound of the present invention, Amphosol CA, glycerin, and Optiphen BSB-W were added one by one and mixed until homogeneous.

[0272] [Table 37]

[0273] procedure Polyquaternium-10 was slowly added to water. Next, glycerin was added to the main container and mixed until completely dispersed and clear. Then, the components of phase (B) were added and heated to 65-70°C, and mixed until homogeneous. The components of phase (C) were added and the temperature was maintained at 65-70°C, and mixed until homogeneous. The pH was adjusted to 5.5-6.0 with citric acid (50% w / w solution). The components of phase (E) were added and mixed until homogeneous. Phase (F) was added while maintaining the temperature at approximately 65°C, and mixed until the structure was obtained. Heating was stopped, and the mixture was cooled to 30°C, and the components of phase (G) were added while mixing.

[0274] [Table 38]

[0275] procedure In the main container, the components of Phase A were added separately, gently mixing until the mixture was homogeneous and clear. The remaining phases were added individually, and mixed until homogeneous before each subsequent addition.

[0276] [Table 39]

[0277] procedure The components of phase B were added to phase A and mixed under low to moderate shear. The components of phase C were then added and added to phases A and B.

[0278] example (Percentages are weight percentages unless otherwise specified.) As used herein, the term “castor oil” generally refers to ricinoleic acid triglyceride.

[0279] Notes on the nomenclature used herein for estolide moieties and estolide compounds In the nomenclature used to indicate the structure of the estolide group used in the following examples, which refers to compounds in which the estolide moiety is obtained at least formally by esterification, the carboxylic acids from which the estolide moiety is at least formally derived are shown in order in parentheses (). When there are several subunits in the estolide moiety that are consecutively derived from the same acid and are shown in parentheses (), the subscript integer indicates the number of repeating units, and the carboxylic acid is shown in brackets [].

[0280] Note that the specific carboxylic acids indicated in parentheses () or brackets [] are not combined in random structures, but each has a precise sequence of hydroxyl-carboxylic acid-derived residues and carboxylic acid-derived residues, as indicated by the terminology used. In each case, the last carboxylic acid indicated in the term within parentheses () or brackets [] is the terminal carboxylic acid of the estride moiety. From the beginning to the end of the term within parentheses () or brackets [], the order of carboxylic acid residues linked by the ester group is shown in the precise order and number of residues included.

[0281] For example, the term "(12-hydroxystearic acid-ricinoleic acid-oleic acid)" formally refers to an estolide moiety in which the 12-hydroxystearic acid molecule is bonded to the carboxylic acid group of the ricinoleic acid molecule via its OH group by forming an ester group. The hydroxyl group of the ricinoleic acid group is bonded to the oleic acid molecule by forming an ester group with the carboxylic acid group of the oleic acid molecule. In this example, oleic acid is considered the terminal group of this particular estolide moiety, and when the estolide moiety is a substituent at a higher level of structure (i.e., a more complex molecule), the estolide moiety is generally bonded to the whole structure via the bond to the carboxylic acid group of the residue first mentioned in the term used for the estolide moiety. In this case, this is the 12-hydroxystearic acid residue first mentioned, and the oleic acid residue is the terminal group of the estolide moiety.

[0282] Therefore, when the term used refers to a carboxylic acid chloride of the estolide structure, the acylchloride group is necessarily formed from the carboxylic acid group of the first carboxylic acid residue mentioned in parentheses, i.e., the one furthest from the terminal group.

[0283] When terms such as "dimer" or "trimer" are used, this refers to the number of lower units derived from the carboxylic acid in the estolide moiety.

[0284] Similarly, the term "[(ricinoleic acid)2-oleic acid]estolide" formally refers to an estolide moiety or compound in which a ricinoleic acid molecule or residue is bonded to yet another carboxylic acid group of the ricinoleic acid molecule via its OH group, forming an ester group. The hydroxyl group of the latter ricinoleic acid group mentioned is bonded to the oleic acid molecule by forming an ester group with the carboxylic acid group of the oleic acid molecule. Oleic acid is considered the terminal group of this particular estolide moiety, and if the estolide moiety is a substituent at a higher level of structure (i.e., a more complex molecule), the estolide moiety is bonded to the whole structure via the bond to the carboxylic acid group of the ricinoleic acid residue mentioned earlier, and the oleic acid residue is the terminal group of the estolide moiety.

[0285] If the estolide moiety is bonded via an ester or amide group by a binding group, for example, by a succinic acid-derived residue in [(ricinoleic acid)6-succinic acid-(ricinoleic acid)6], and bonded to two ricinoleic acid estolide groups by ester groups on each side, this is indicated by incorporating the name of the parent compound into the terminology applicable to the overall estolide structure. Thus, a comprehensive terminology is provided to indicate the sequence of carboxylic acid residues.

[0286] It should also be noted that the precise structure of estolide is revealed primarily by the fully provided structural formula for the exemplary compound, and that the structure of the exemplary compound can also be clearly derived by those skilled in the art from the detailed experimental procedures provided.

[0287] The term “commercially available polyglycerol-polyricinolate” refers to Palsgaard® PGPR4150, a commercially available polyglycerol-polyricinolate manufactured by Palsgaard A / S, which is identified as follows: Polyglycerol-polyricinolate (E476) is a yellowish, viscous liquid; viscosity-reducing force: 74-87; maximum acid value: 3 mg KOH / g; hydroxyl value: 80-100 mg KOH / g; refractive index at 65°C: 1.4630-1.4665; iodine value: 72-103 g I2 / 100g; saponification number: 170-210 mg KOH / g; polyglycerol composition: diglycerin, triglycerin, and tetraglycerin, at least 75%; polyglycerols greater than heptaglycerol, present as up to 10%.

[0288] Synthesis Example 1 Synthesis of (ricinoleic acid-oleic acid) estrido dimer 225 g (0.75 mol) of ricinoleic acid was placed at room temperature under a nitrogen atmosphere in a 1000 ml four-necked bottle equipped with a reflux condenser, thermometer and magnetic stirrer, dropping funnel and gas outlet tube. 226.85 g (0.75 mol) of oleic acid chloride was slowly added over 1.5 hours with stirring. The temperature rose from 22°C to 32°C. The temperature increase was accompanied by the formation of bubbles indicating the formation of HCl. The temperature was maintained at 32°C for a further 2 hours, then raised to 50°C and maintained for 1 hour. Volatile substances were removed under reduced pressure (40°C / 2h / 20 mmHg). The conversion of the OH group was as follows: 1 This was determined by 1HNMR spectroscopy. The conversion rate of the OH group was 100%.

[0289] A brownish, transparent oil with essentially the following structure was obtained. [ka]

[0290] Synthesis Example 2 Synthesis of [(ricinoleic acid)2-oleic acid]estrido trimer 34.87 g (0.293 mol) SOCl2 was added at room temperature under a nitrogen atmosphere to a 250 ml four-neck bottle equipped with a reflux condenser, thermometer, magnetic stirrer, dropping funnel, and gas outlet tube. 110 g (0.195 mol) of the estolide dimer from Synthesis Example 1 was slowly added over 1 hour with stirring. After the addition was complete, the temperature was raised to 80°C. The temperature was maintained at 80°C for 1 hour. Volatile substances were removed under reduced pressure (80°C / 2h / 20 mmHg). The vacuum was released using nitrogen, and 57.75 g (0.195 mol) of ricinoleic acid was added to the carboxylic acid chloride intermediate over 45 minutes at 80°C. The temperature was maintained for 2 hours. Volatile substances were removed under reduced pressure (40°C / 2h / 20 mmHg). The OH group conversion was performed as follows: 1 This was determined by 1HNMR spectroscopy. The conversion rate of the OH group was 100%.

[0291] A brownish, transparent oil with essentially the following structure was obtained. [ka]

[0292] Synthesis example 2a Synthesis of [(ricinoleic acid)2-stearic acid]estrido trimer Two 250 ml three-neck bottles, A and B, equipped with reflux condensers, thermometers and magnetic stirrers, dropping funnels and gas outlet tubes, were flushed with nitrogen.

[0293] Using bottle A, fatty acid chloride was reacted with ricinoleic acid to produce chain-extended fatty acid esters. Subsequently, SOCl2 was added to obtain the corresponding fatty acid ester chloride.

[0294] Using bottle B, the formed fatty acid ester chloride was reacted with ricinoleic acid to produce a chain-extended fatty acid ester. Subsequently, SOCl2 was added to obtain the corresponding fatty acid ester chloride. This fatty acid chloride was returned to bottle A and reacted with fresh ricinoleic acid. The above cycle can be repeated until the hexameric estolide [(ricinoleic acid)5-stearic acid] is prepared.

[0295] General procedure for the synthesis of chain-extended fatty acid esters: The calculated amount of ricinoleic acid was placed in the bottle. Equimolar amounts of fatty acid chloride were slowly added at room temperature. To complete the reaction, the temperature was raised to 80°C for 3 hours. Complete conversion of the OH group occurred. 1 This was determined by HNMR spectroscopy.

[0296] General procedure for the synthesis of fatty acid ester chlorides: The calculated amount of fatty acid ester was placed in a bottle. SOCl2 (3x molar excess) was slowly added at room temperature. The mixture was then heated to 80°C. The temperature was maintained for 3 hours. After that, the excess SOCl2 was removed under reduced pressure (80°C / 2h / 20mmHg). Complete conversion of C(O)OH groups to C(O)Cl groups was performed. 1 This was determined by HNMR spectroscopy.

[0297] The table below summarizes the materials and quantities used. [Table 40]

[0298] The formula for [(rici)2-stearic acid] is as follows: [ka]

[0299] Synthesis example 2b Synthesis of (ricinoleic acid-12-hydroxystearate-oleic acid) estrido trimer The procedure outlined for synthesis example 2a was repeated.

[0300] The table below summarizes the materials and quantities used. [Table 41]

[0301] The formula for rici-(12-hydroxystea)-oleic acid is as follows: [ka]

[0302] Synthesis Example 2c Synthesis of (12-hydroxystearic acid-ricinoleic acid-oleic acid) estrido trimer The procedure outlined for synthesis example 2a was repeated.

[0303] The table below summarizes the materials and quantities used. [Table 42]

[0304] The formula for (12-hydroxystea-rici-oleic acid) is as follows: [ka]

[0305] Synthesis Example 3 Synthesis of [(ricinoleic acid)5-oleic acid]estrido hexamer and the corresponding [(ricinoleic acid)5-oleic acid]chloride hexamer Two 100 ml three-neck bottles, A and B, equipped with reflux condensers, thermometers and magnetic stirrers, dropping funnels and gas outlet tubes, were flushed with nitrogen.

[0306] Using bottle A, fatty acid chloride was reacted with ricinoleic acid to produce chain-extended fatty acid esters. Subsequently, SOCl2 was added to obtain the corresponding fatty acid ester chloride.

[0307] Using bottle B, the formed fatty acid ester chloride was reacted with ricinoleic acid to produce a chain-extended fatty acid ester. SOCl2 was then added to obtain the corresponding fatty acid ester chloride. This fatty acid chloride was returned to bottle A and reacted with fresh ricinoleic acid. The above cycle was repeated until the hexameric estolide [(ricinoleic acid)5-oleic acid] was prepared.

[0308] General procedure for the synthesis of chain-extended fatty acid esters: The calculated amount of ricinoleic acid was placed in a bottle. Equimolar amounts of fatty acid ester chloride were slowly added at room temperature. To complete the reaction, the temperature was raised to 80°C for 3 hours. The complete conversion of the OH group of ricinoleic acid to the ester occurred. 1 This was determined by HNMR spectroscopy.

[0309] General procedure for the synthesis of fatty acid ester chlorides: The calculated amount of fatty acid ester was placed in a bottle. SOCl2 (3x molar excess) was slowly added at room temperature. The mixture was then heated to 80°C. The temperature was maintained for 3 hours. After that, the excess SOCl2 was removed under reduced pressure (80°C / 2h / 20mmHg). Complete conversion of C(O)OH groups to C(O)Cl groups was performed. 1 This was determined by HNMR spectroscopy.

[0310] The table below summarizes the materials and quantities used. [Table 43]

[0311] Essentially, a brownish, transparent oil with the following structure [(rici)5-oleic acid] was obtained. [ka]

[0312] The corresponding [(rici)5-oleic acid] chloride has the following structure. [ka]

[0313] Synthesis Example 4 Synthesis of branched bis-[(ricinoleic acid)2-oleic acid]estolide based on bis-2,2-hydroxymethylpropionic acid In a 100 ml three-necked bottle equipped with a reflux condenser, thermometer, magnetic stirrer, dropping funnel, and gas outlet tube, 48.88 g (0.0567 mol) of [(ricinoleic acid)2-oleic acid] chloride from Synthesis Example 3 was mixed with 3.80 g (0.0284 mol) of bis-2,2-hydroxymethylpropionic acid. The mixture was heated at 100 °C for 8 hours. Volatile substances were removed under reduced pressure (80 °C / 1 h / 20 mmHg). Complete conversion of the OH group of 2,2-hydroxymethylpropionic acid was observed. 1 This was determined by HNMR spectroscopy.

[0314] A brownish, transparent oil with essentially the following structure was obtained. [ka] Here R= [ka]

[0315] Synthesis example 4a Synthesis of dendrimar bis-[(ricinoleic acid)2-oleic acid]estolide In a 100 ml three-necked bottle equipped with a reflux condenser, thermometer, magnetic stirrer, dropping funnel, and gas outlet tube, 64.57 g (0.03617 mol) of branched bis-[(ricinoleic acid)2-oleic acid]estolide based on bis-2,2-hydroxymethylpropionic acid of Synthesis Example 4 was heated at 80 °C. 8.61 g (0.0723 mol) of SOCl2 was added within 10 minutes. The reaction was maintained for 4 hours. Volatile substances were removed under reduced pressure (80 °C / 1 h / 20 mmHg). Complete conversion of C(O)OH groups to C(O)Cl groups occurred. 1 The reaction was determined by 1H NMR spectroscopy. 2.42 g (0.01808 mol) of bis-2,2-hydroxymethylpropionic acid was added at 80°C, and the reaction was maintained for a further 5 hours. Volatile substances were removed under reduced pressure (80°C / 0.5 h / 20 mmHg). Complete conversion of the terminal OH group of bis-2,2-hydroxymethylpropionic acid was observed. 1 This was determined by HNMR spectroscopy.

[0316] A viscous, brownish, transparent oil was obtained that essentially had the following dendrimer structure. [ka] Here R= [ka]

[0317] Synthesis Example 4b Synthesis of branched bis-[(ricinoleic acid)2-stearic acid]estolide based on bis-2,2-hydroxymethylpropionic acid In a 250 ml three-necked bottle equipped with a reflux condenser, thermometer, magnetic stirrer, dropping funnel, and gas outlet tube, 95.06 g (0.1124 mol) of [(ricinoleic acid) 2-stearic acid] estolide from Synthesis Example 2a was heated to 80 °C. 33.8 g (0.28 mol) of SOCl2 was added within 10 minutes. The reaction was maintained for 4 hours. Volatile substances were removed under reduced pressure (80 °C / 1 h / 20 mmHg). Complete conversion of C(O)OH groups to C(O)Cl groups occurred. 1This was determined by HNMR spectroscopy.

[0318] In a 250 ml three-necked bottle equipped with a reflux condenser, thermometer, mechanical stirrer, dropping funnel, and gas outlet tube, 92.88 g (0.1075 mol) of (ricinoleic acid) 2-stearate chloride intermediate and 7.22 g (0.0538 mol) of bis-2,2-hydroxymethylpropionic acid were mixed at 80°C, and the reaction was maintained for a further 5 hours. Volatile substances were removed under reduced pressure (80°C / 0.5 h / 20 mmHg). Complete conversion of the OH group of bis-2,2-hydroxymethylpropionic acid was observed. 1 This was determined by HNMR spectroscopy.

[0319] A viscous, brownish, transparent oil with essentially the following structure was obtained. [ka] Here R= [ka]

[0320] Synthesis example 4c Synthesis of branched bis-(ricinoleic acid-12-hydroxystearate-oleic acid) estolide based on bis-2,2-hydroxymethylpropionic acid In a 250 ml three-necked bottle equipped with a reflux condenser, thermometer, magnetic stirrer, dropping funnel, and gas outlet tube, 102.95 g (0.1218 mol) of (ricinoleic acid-12-hydroxystearate-oleic acid) estolide from Synthesis Example 2b was heated to 80°C. 42.8 g (0.36 mol) of SOCl2 was added within 10 minutes. The reaction was maintained for 4 hours. Volatile substances were removed under reduced pressure (80°C / 1h / 20 mmHg). Complete conversion of C(O)OH groups to C(O)Cl groups occurred. 1 This was determined by HNMR spectroscopy.

[0321] In a 250 ml three-necked bottle equipped with a reflux condenser, thermometer, mechanical stirrer, dropping funnel, and gas outlet tube, 104.22 g (0.1206 mol) of bis-(ricinoleic acid-12-hydroxystearate-oleic acid) chloride intermediate and 8.09 g (0.0603 mol) of bis-2,2-hydroxymethylpropionic acid were mixed at 80°C, and the reaction was maintained for a further 5 hours. Volatile substances were removed under reduced pressure (80°C / 0.5 h / 20 mmHg). Complete conversion of the OH group from bis-2,2-hydroxymethylpropionic acid was observed. 1 This was determined by HNMR spectroscopy.

[0322] A viscous, brownish, transparent oil with essentially the following structure was obtained. [ka] Here R= [ka]

[0323] Synthesis example 4d Synthesis of branched (12-hydroxystearic acid-ricinoleic acid-oleic acid) estolides based on bis-2,2-hydroxymethylpropionic acid In a 250 ml three-necked bottle equipped with a reflux condenser, thermometer, magnetic stirrer, dropping funnel, and gas outlet tube, 98.05 g (0.116 mol) of (12-hydroxystearate-ricinoleic acid-oleic acid) estolide of Synthesis Example 2c was heated to 80 °C. 30.08 g (0.25 mol) of SOCl2 was added within 10 minutes. The reaction was maintained for 4 hours. Volatile substances were removed under reduced pressure (80 °C / 1 h / 20 mmHg). Complete conversion of C(O)OH groups to C(O)Cl groups occurred. 1 This was determined by HNMR spectroscopy.

[0324] In a 250 ml three-necked bottle equipped with a reflux condenser, thermometer, mechanical stirrer, dropping funnel, and gas outlet tube, 97.4 g (0.1127 mol) of (12-hydroxystearate-ricinoleic acid-oleic acid) chloride intermediate and 7.56 g (0.0564 mol) of bis-2,2-hydroxymethylpropionic acid were mixed at 80°C, and the reaction was maintained for a further 5 hours. Volatile substances were removed under reduced pressure (80°C / 0.5 h / 20 mmHg). Complete conversion of the hydroxymethyl group to the OH group was observed. 1 This was determined by HNMR spectroscopy.

[0325] A viscous, brownish, transparent oil with essentially the following structure was obtained. [ka] Here R= [ka]

[0326] Synthesis Example 5 Synthesis of alpha-branched bis-[(ricinoleic acid)5-oleic acid]estolide based on bis-2,2-hydroxymethylpropionic acid In a 100 ml three-necked bottle equipped with a reflux condenser, thermometer, magnetic stirrer, dropping funnel, and gas outlet tube, 29.53 g (0.0173 mol) of [(ricinoleic acid) 5-oleic acid] chloride from Synthesis Example 3 was mixed with 1.16 g (0.00866 mol) of bis-2,2-hydroxymethylpropionic acid. The mixture was heated at 105 °C for 5 hours. Volatile substances were removed under reduced pressure (80 °C / 10 min / 20 mmHg). Complete conversion of the OH group of bis-2,2-hydroxymethylpropionic acid was observed. 1 This was determined by HNMR spectroscopy.

[0327] A brownish, transparent oil with essentially the following structure was obtained. [ka] Here R= [ka]

[0328] Synthesis Example 6 Synthesis of glycerol-based estolide chloroacetate derivatives 40 g (0.434 mol) of glycerol was placed at room temperature in a 100 ml three-necked bottle equipped with a reflux condenser, thermometer, mechanical stirrer, dropping funnel, and gas outlet tube. 49.05 g (0.434 mol) of chloroacetic acid chloride was added over 45 minutes while stirring. The temperature rose to 83°C during the addition. The temperature was then raised to 120°C for 2 hours. The formation of the chloroacetic acid ester occurred as follows: 1 This was confirmed by HNMR spectroscopy.

[0329] 5.72 g (0.034 mol) of glycerol monochloroacetate was mixed with 39.50 g (0.068 mol) of [(ricinoleic acid)1-oleic acid] chloride from Synthesis Example 3 at room temperature. The mixture was heated at 100°C for 8 hours. Volatile substances were removed under reduced pressure (80°C / 1h / 20 mmHg). Complete conversion of the OH group and formation of additional ester moieties occurred. 1 This was confirmed by HNMR spectroscopy.

[0330] A brownish, transparent oil with essentially the following approximate structure was obtained. [ka] Here R= [ka]

[0331] Synthesis Example 7 Synthesis of castor oil-based estolide chloroacetate derivatives 40 g (0.0428 mol) of castor oil was placed at room temperature in a 100 ml three-necked bottle equipped with a reflux condenser, thermometer, mechanical stirrer, dropping funnel, and gas outlet tube. 4.84 g (0.0428 mol) of chloroacetic acid chloride was added over 10 minutes while stirring. The temperature rose to 34°C during the addition. The temperature was then raised to 80°C for 3 hours. The formation of chloroacetic acid esters occurred as follows: 1 This was confirmed by HNMR spectroscopy.

[0332] 49.83 g (0.0856 mol) of the chloride [(ricinoleic acid)1-oleic acid] from Synthesis Example 3 was added. The temperature was maintained at 80°C for 8 hours. Volatile substances were removed under reduced pressure (80°C / 2h / 20mmHg). Complete conversion of the OH groups of the castor oil molecule and formation of additional ester moieties occurred. 1 This was confirmed by HNMR spectroscopy.

[0333] A brownish, transparent oil with essentially the following approximate structure was obtained. [ka] Here R1 = [ka] And here R2= [ka]

[0334] Synthesis example 7a Synthesis of castor oil-based estolide chloroacetate derivatives 80 g (0.0857 mol) of castor oil was placed in a 250 ml three-necked bottle equipped with a reflux condenser, thermometer, mechanical stirrer, dropping funnel, and gas outlet tube, and heated to 60°C. While stirring, 9.68 g (0.0857 mol) of chloroacetic acid chloride was added over 10 minutes. During the addition, the temperature rose to 80°C. The temperature was then maintained at 80°C for a further 1.5 hours. The formation of the chloroacetic acid ester occurred as follows: 1This was confirmed by 1H NMR spectroscopy.

[0335] 100 g (0.1714 mol) of the chloride [(ricinoleic acid)1-stearic acid] from synthesis example 2a was added. The temperature was maintained at 80°C for 4 hours. Volatile substances were removed under reduced pressure (90°C / 2 hours / 20 mmHg). Complete conversion of the OH groups of the castor oil molecule and formation of further ester moieties occurred. 1 This was confirmed by HNMR spectroscopy.

[0336] A brownish, waxy material with essentially the following approximate structure was obtained. [ka] Here R1 = [ka] And here R2= [ka]

[0337] Example 1 Synthesis of amine salts of tertiary amino alcohol esters of [(ricinoleic acid)2-oleic acid]estolide In a 500 ml four-necked bottle equipped with a reflux condenser, thermometer, mechanical stirrer, dropping funnel, and gas outlet tube, 300 ml of n-heptane was mixed with 49.69 g (0.0577 mol) of [(ricinoleic acid) 2-oleic acid] chloride from Synthesis Example 3 at room temperature. 5.95 g (0.0577 mol) of (CH3)2NCH2CH2CH2OH was added over 20°C. The temperature rose to 37°C. The temperature was maintained for 30 minutes. The n-heptane was removed under reduced pressure (30°C / 2h / 20 mmHg). The conversion of the OH group of (CH3)2NCH2CH2CH2OH and the formation of the ester occurred. 1 This was confirmed by 1H NMR spectroscopy.

[0338] A brownish wax having the following structure was obtained. [ka] Here R= [ka]

[0339] Example 2 Synthesis of amine salts of tertiary amino alcohol esters of [(ricinoleic acid)5-oleic acid]estolide In a 250 ml four-necked bottle equipped with a reflux condenser, thermometer, mechanical stirrer, dropping funnel, and gas outlet tube, 40 ml of n-heptane was mixed with 49.19 g (0.0289 mol) of (ricinoleic acid) 5-oleoyl chloride from Synthesis Example 3 at 40°C. 2.89 g (0.0289 mol) of (CH3)2NCH2CH2CH2OH was added over 5 minutes. The temperature rose to 43°C. The temperature was maintained for 1 hour. The n-heptane was removed under reduced pressure (30°C / 2h / 20 mmHg). The conversion of the OH group of (CH3)2NCH2CH2CH2OH and the formation of the ester occurred. 1 This was confirmed by 1H NMR spectroscopy.

[0340] A brownish wax having the following structure was obtained. [ka] Here R= [ka]

[0341] Example 3 Synthesis of amine salts of tertiary amino alcohol esters of branched bis-[(ricinoleic acid)2-oleic acid]estolide In a 100 ml three-necked bottle equipped with a reflux condenser, thermometer, magnetic stirrer, dropping funnel, and gas outlet tube, 25 g (0.014 mol) of alpha-branched bis-[(ricinoleic acid)2-oleic acid]estolide from Synthesis Example 4 was mixed with 11 g (0.092 mol) of SOCl2 at 50°C. The mixture was heated to 80°C for 2.5 hours. Then, excess SOCl2 was removed under reduced pressure (80°C / 1h / 20 mmHg). The formation of the acid chloride was observed. 1 This was confirmed by HNMR spectroscopy.

[0342] 22.4 g (0.0124 mol) of the acid chloride was transferred to a 250 ml four-necked bottle equipped with a reflux condenser, thermometer, mechanical stirrer, and dropping funnel. 140 ml of n-heptane and 1.28 g (0.00825 mol) of (CH3)2NCH2CH2CH2OH were added over 5 minutes. The temperature was raised to 28 °C and maintained for 1 hour. The n-heptane was removed under reduced pressure (30 °C / 3 h / 20 mmHg). The conversion of the OH group of (CH3)2NCH2CH2CH2OH and the formation of the ester occurred. 1 This was confirmed by 1H NMR spectroscopy.

[0343] A brownish wax having the following structure was obtained. [ka] Here R= [ka]

[0344] Example 3a Synthesis of amine salts of tertiary amino alcohol esters of dendrimar vis-[(ricinoleic acid)2-oleic acid]estolide In a 100 ml three-necked bottle equipped with a reflux condenser, thermometer, magnetic stirrer, dropping funnel, and gas outlet tube, 25 g (0.014 mol) of branched bis-[(ricinoleic acid)2-oleic acid]estolide from Synthesis Example 4a was mixed with 11 g (0.092 mol) of SOCl2 at 50°C. The mixture was heated to 80°C for 2.5 hours. Then, excess SOCl2 was removed under reduced pressure (80°C / 1h / 20 mmHg). The formation of the acid chloride was observed. 1 This was confirmed by HNMR spectroscopy.

[0345] 22.4 g (0.0124 mol) of the acid chloride was transferred to a 250 ml four-necked bottle equipped with a reflux condenser, thermometer, mechanical stirrer, and dropping funnel. 140 ml of n-heptane and 1.28 g (0.00825 mol) of (CH3)2NCH2CH2CH2OH were added for 5 minutes. The temperature was raised to 28°C and maintained for 1 hour. The n-heptane was removed under reduced pressure (30°C / 3h / 20 mmHg). The conversion of the OH group of (CH3)2NCH2CH2CH2OH and the formation of the ester occurred. 1 This was confirmed by 1H NMR spectroscopy.

[0346] A brownish wax having the following structure was obtained. [ka] Here R= [ka]

[0347] Example 3b Synthesis of amine salts of tertiary amino alcohol esters of alpha-branched bis-[(ricinoleic acid)2-stearic acid]estolide In a 250 ml three-necked bottle equipped with a reflux condenser, thermometer, magnetic stirrer, dropping funnel, and gas outlet tube, 77 g (0.0430 mol) of alpha-branched bis-[(ricinoleic acid)2-stearic acid]estolide from Synthesis Example 4b was mixed with 34.5 g (0.29 mol) of SOCl2 at 50°C. The mixture was heated to 80°C for 2.5 hours. Then, excess SOCl2 was removed under reduced pressure (80°C / 1h / 20 mmHg). The formation of the acid chloride was observed. 1 This was confirmed by HNMR spectroscopy.

[0348] 71.5 g (0.0396 mol) of the acid chloride was transferred to a 500 ml four-necked bottle equipped with a reflux condenser, thermometer, mechanical stirrer, and dropping funnel. 190 g of n-heptane and 4.09 g (0.0396 mol) of (CH3)2NCH2CH2CH2OH were added over 5 minutes. The temperature was raised to 30°C and maintained for 1 hour. The n-heptane was removed under reduced pressure (30°C / 3h / 20 mmHg). The conversion of the OH group of (CH3)2NCH2CH2CH2OH and the formation of the ester occurred. 1 This was confirmed by HNMR spectroscopy.

[0349] A brownish wax having the following structure was obtained. [ka] Here R= [ka]

[0350] Example 3c Synthesis of amine salts of tertiary amino alcohol esters of alpha-branched bis-(ricinoleic acid-12-hydroxystearate-oleic acid)estolide In a 250 ml three-necked bottle equipped with a reflux condenser, thermometer, magnetic stirrer, dropping funnel, and gas outlet tube, 89.4 g (0.05 mol) of alpha-branched bis-(ricinoleic acid-12-hydroxystearate-oleic acid) estolide from Synthesis Example 4c was mixed with 40.4 g (0.34 mol) of SOCl2 at 50°C. The mixture was heated to 80°C for 2.5 hours. Then, excess SOCl2 was removed under reduced pressure (80°C / 1h / 20 mmHg). The formation of the acid chloride was observed. 1 This was confirmed by HNMR spectroscopy.

[0351] 85.11 g (0.0471 mol) of the above acid chloride was transferred to a 500 ml four-necked bottle equipped with a reflux condenser, thermometer, mechanical stirrer, and dropping funnel. 187 g of n-heptane and 4.86 g (0.0471 mol) of (CH3)2NCH2CH2CH2OH were added over 5 minutes. The temperature was raised to 32°C and maintained for 1 hour. The n-heptane was removed under reduced pressure (30°C / 3h / 20 mmHg). The convers...

Claims

1. Compounds of general formula (I), R １ (-F) ｘ (I) Here x ranges from 2 to 50, R １ It has a maximum of 1,000 carbon atoms, preferably 2 to 300 carbon atoms, more preferably 3 to 200 carbon atoms, even more preferably 3 to 150 carbon atoms, more specifically 3 to 50 carbon atoms, and more specifically 3 to 20 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. 【Chemistry 1】 Selected from x-valent, optionally substituted hydrocarbon radicals, which may contain one or more groups selected from and may be substituted with one or more groups selected from OH groups and halide groups, and F may be the same or different, and can be expressed by general formula (II), 【Chemistry 2】 Here, the base F is R １ Bonded to the carbon atom, and n is 0, R ３ , R ４ , R ５ These may be the same or different, and may have hydrogen and up to 1000 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, 【Chemistry 4】 Selected from optionally substituted linear or branched saturated or unsaturated hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with one or more groups selected from OH groups and halide groups, Here, R ３ , R ４ , R ５ is each bonded to the nitrogen atom by a carbon atom, And preferably R ３ , R ４ , R ５ It is not hydrogen, Ammonium ion counterion A － These are selected from monovalent to trivalent inorganic and monovalent to 30,000-valent, preferably monovalent to 1,000-valent organic anions, and R present in the cationic structure of general formulas (I) and (II) １ , R ２ , R ３ , R ４ , R ５ At least one of these includes at least one part of formula (III) or (IV), (-X-C(O)-R ６ ) ｍ -X-C(O)- (III) or (-C(O)-E-R ６ ) ｍ -C(O)-X-(IV) Here m = 2 to 20, X is O, R ６ These are independently selected from optionally substituted linear or branched saturated or unsaturated hydrocarbon radicals having 1 to 36 carbon atoms. However, at least one R ６ A compound is defined as having more than six carbon atoms.

2. R １ This is the general formula (IIIa) (-E-C(O)-R ６ ) ｍ -E-C(O)-R ７ (IIa) Or general formula (IVa) (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (IVa) Including at least one part of, Here, X and R ６ and m are as defined in claim 1, R ７ It has 1 to 36 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, 【Transformation 8】 A optionally substituted linear or branched saturated or unsaturated hydrocarbon radical, independently selected from, where radical R, comprising one or more groups selected from, and which may be substituted with an OH group or a halide group, wherein radical R is present. ７ The compound according to claim 1, wherein it may not contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group, that forms an internal carboxylate group or an internal amide group.

3. In equation (I), x is 2, which is the same as in the general equation (V). 【Chemistry 10】 Here R １ , R ３ , R ４ , R ５ The compound according to claim 1 or 2, wherein n is as defined above.

4. F has a general formula (VI), 【Chemistry 11】 And the base F is R １ Bonded to the carbon atom, Here R ３ , R ４ , R ５ It has hydrogen and up to 300 carbon atoms, preferably 1 to 200 carbon atoms, more preferably 1 to 150 carbon atoms, even more preferably 1 to 50 carbon atoms, specifically 1 to 20 carbon atoms, more specifically 1 to 10 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, 【Chemistry 12】 A linear or branched, saturated or unsaturated hydrocarbon radical, independently selected from optionally substituted linear or branched, saturated or unsaturated hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with OH groups, Counterion A － The anions are selected from monovalent to trivalent inorganic anions and monovalent to 30,000 valent, preferably 1,000 valent organic anions, preferably halogenated anions, such as chlorides, bromides and iodides, sulfates, phosphates, phosphonates, sulfonates, methosulfates, carboxylate anions, such as acetates, propionates, lactates, octanoates, 2-ethyl-hexanoates, dodecanoates, hexadecanoates, octadecanoates, oleates, ricinolates, 12-hydroxy-octadecanoates, succinates, maleates, tartrates, polyethercarboxylates, The following types of high molecular weight fatty acid carboxylates, R １ [(-C(O)-X-R ６ ) ｍ* - C (O) - X - R ７ ] ｘ または R １ [(X-C(O)-R ６ ) ｍ* -X-C(O)-R ７ ] ｘ 、 Here R １ or R ７ At least one of the above, or R １ and R ７ Both of at least one of them have one or more carboxylate groups, Preferably, here X = O, especially, - The following types of linear polymer fatty acid carboxylates, － O-C(O)-R ６ (-X-C(O)-R ６ ) ｍ*－１ -X-C(O)-R ７ Preferably － O-C(O)-R ６ -(O-C(O)-R ６ ) ｍ* -O-C(O)-R ７ 、 In other words, it originates from a linear polyfatty acid structure, - Branched linear polymer fatty acid carboxylates, That is, branched linear polymer fatty acid carboxylates derived from branched polyfatty acid structures, particularly polyfunctional carboxylic acids, especially dicarboxylic acids, succinic acid and maleic acid, and partial esters of castor oil or rescera oil, for example 【Chemistry 14】 Here, one R = 【Chemistry 15】 And the remaining two R groups = 【Chemistry 16】 - Dendrimer-like polymeric fatty acid carboxylate, In other words, it originates from a dendrimer-like polyfatty acid structure, Or the following types, 6-R ６ (-C(O)-X-R ６ ) ｍ*－１ - C (O) - X - R ７ または、 R ６ (-C(O)-X-R ６ ) ｍ*－１ -C(O)-X-R ７ 、 Here, in the latter two types, R ７ The group has at least one anionic carboxylate group, Or the following types: R １ [(-C(O)-X-R ６ ) ｍ* -C(O)O － ] ｘ 、 And here, X, R １ , R ６ , R ７ , and x are as defined above, m* is between 1 and 20. Here, the counterion A of this group － The anion is preferably monovalent to 50valent, more preferably monovalent to 10valent, even more preferably monovalent to 5valent, and most preferably 5valent, 4valent, 3valent, 2valent, or monovalent. Selected from, Alternatively, the counter anion is a carboxylate anion based on poly(acrylic acid) homopolymers and copolymers. In other words, carboxylate derived from polyacrylic acid homopolymer 【Chemistry 17】 Here, p = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. That is, a carboxylate anion derived from a polyacrylic acid copolymer containing a non-reactive comonomer, where Copolymers can have a block-like or random distribution of comonomer units. Alternatively, a carboxylate anion derived from a polyacrylic acid copolymer, comprising a comonomer that provides OH and amine functional groups that can be functionalized via further ester or amide bonds with fatty acids or polyfatty acids, Alternatively, a carboxylate anion derived from a polyacrylic acid copolymer containing a carboxylic acid functional group comonomer, where Copolymers can have a block-like or random distribution of comonomer units. Carboxylates based on maleic acid copolymers, particularly those derived from maleic anhydride copolymers, here Copolymers can have a block-like or random distribution of comonomer units. Carboxylates based on poly(itaconic acid) homo and copolymers, In other words, it is derived from polyitaconate homopolymer, [Chemistry 18] Here, h = 2 to 10000, preferably 10 to 10000, more preferably 100 to 10000, and even more preferably 1000 to 10000. Alternatively, derived from an itaconic acid copolymer containing a polyitaconic acid copolymer, i.e., a non-reactive comonomer. Here Copolymers can have a block-like or random distribution of comonomer units. Alternatively, a polyitaconic acid copolymer, for example, derived from 2-hydroxyethyl methacrylate-itaconic acid copolymer, comprising a comonomer that provides OH and amine functional groups that can be functionalized via further ester or amide bonds with fatty acids or polyfatty acids, Alternatively, derived from a polyitaconic acid copolymer containing a carboxylic acid functional group-containing comonomer, where Copolymers can have a block-like or random distribution of comonomer units. Here, the anion of this group is preferably an anion with a valency of 2 to 30,000, more preferably 2 to 1,000, even more preferably 10 to 1,000, even more preferably 50 to 1,000, and most preferably 100 to 1,000. Selected from the group consisting of, However, the radicals R of the cationic structures of formulas (I) and (II) １ , R ３ , R ４ , R ５ are subject to the condition that at least one of them contains at least one moiety of general formula (IIIa) or (IVa). (-E-C(O)-R ６ ) ｍ -E-C(O)-R ７ (IIa) (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (IVa) Here, X is as defined above, m = 2 to 20, preferably up to 10, more preferably up to 6, even more preferably 2 to 6, specifically 2, 3, 4, 5, 6, and R ６ is independently selected from optionally substituted linear or branched, saturated or unsaturated hydrocarbon radicals having from 1 to 36 carbon atoms, preferably from 1 to 24 carbon atoms, more preferably from 1 to 18 carbon atoms, and still more preferably from 8 to 18 carbon atoms, R ７ It has 1 to 36 carbon atoms, preferably 1 to 24 carbon atoms, more preferably 1 to 18 carbon atoms, and even more preferably 8 to 18 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, 【Chemistry 19】 A optionally substituted linear or branched saturated or unsaturated hydrocarbon radical, independently selected from, where radical R, comprising one or more groups selected from, and which may be substituted with an OH group or a halide group, wherein radical R is present. ７ It may not contain a combination of a -C(O)- group and an -O- group that forms an internal carboxylate group or an internal amide group, or a combination of a -C(O)- group and an -NH- or tertiary amino group. However, at least one R ６ It has more than six carbon atoms, or R １ It has a maximum of 1000 carbon atoms, preferably 2 to 300 carbon atoms, more preferably 3 to 200 carbon atoms, even more preferably 3 to 150 carbon atoms, specifically 3 to 50 carbon atoms, and more specifically 3 to 20 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, 【Chemistry 22】 A hydrocarbon radical that may comprise one or more groups selected from and may be substituted with -OH, and which is monovalent to 50-valent, preferably monovalent to 30-valent, more preferably monovalent to 20-valent, and even more preferably monovalent to 10-valent, specifically selected from hydrocarbon radicals optionally substituted with monovalent, divalent, trivalent, tetravalent, pentavalent, hexavalent, heptavalent, octavalent, xanavalent, and 10-valent, and F has a general formula (VI), 【Chemistry 24】 And the base F is R １ Bonded to the carbon atom, Here R ３ , R ４ , R ５ It has a maximum of 300 carbon atoms, preferably 1 to 200 carbon atoms, more preferably 1 to 150 carbon atoms, even more preferably 1 to 50 carbon atoms, specifically 1 to 20 carbon atoms, and more specifically 1 to 10 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, 【Chemistry 25】 A counterion A is independently selected from optionally substituted linear or branched, saturated or unsaturated hydrocarbon radicals comprising one or more groups selected from and which may be substituted with OH. － The anions are selected from monovalent to trivalent inorganic anions and monovalent to 30,000 valent, particularly monovalent to 1,000 valent organic anions, preferably halogenated anions, such as chlorides, bromides and iodides, sulfates, phosphates, phosphonates, sulfonates, methosulfates, carboxylate anions, such as acetates, propionates, lactates, octanoates, 2-ethyl-hexanoates, dodecanoates, hexadecanoates, octadecanoates, oleates, ricinolates, 12-hydroxy-octadecanoates, succinates, maleates, tartrates, polyethercarboxylates, The following types of high molecular weight fatty acid carboxylates, R １ [(-C(O)-X-R ６ ) ｍ* - C (O) - X - R ７ ] ｘ または R １ [(X-C(O)-R ６ ) ｍ* -X-C(O)-R ７ ] ｘ 、 Here R １ or R ７ At least one of the following, or R １ and R ７ Both of at least one of them have one or more carboxylate groups, Preferably, here X = O, especially - The following types of high molecular weight fatty acid carboxylates － O-C(O)-R ６ (-X-C(O)-R ６ ) ｍ*－１ -X-C(O)-R ７ Preferably － O-C(O)-R ６ -(O-C(O)-R ６ ) ｍ* -O-C(O)-R ７ 、 In other words, it originates from a linear polysaturated acid structure, - Branched linear polymer fatty acid carboxylates, That is, branched linear polymer fatty acid carboxylates derived from branched polyfatty acid structures, particularly polyfunctional carboxylic acids, especially dicarboxylic acids, succinic acid and maleic acid, and partial esters of castor oil or rescera oil, for example 【Chemistry 27】 Here, one R = 【Chemistry 28】 And the remaining two R groups = 【Chemistry 29】 - Dendrimer-like polymeric fatty acid carboxylate, In other words, it originates from a dendrimer-like polyfatty acid structure, Or the following types, 6-R ６ (-C(O)-X-R ６ ) ｍ*－１ - C (O) - X - R ７ または、 R ６ (-C(O)-X-R ６ ) ｍ*－１ -C(O)-X-R ７ 、 Here, in the latter two types, R ７ The group has at least one anionic carboxylate group, Or the following types: R １ [(-C(O)-X-R ６ ) ｍ* -C(O)O － ] ｘ 、 And here, X, R １ , R ６ , R ７ , and x are as defined above, m* is between 2 and 20. Here, the counterion A of this group － The anion is preferably monovalent to 50valent, more preferably monovalent to 10valent, even more preferably monovalent to 5valent, and most preferably 5valent, 4valent, 3valent, 2valent, or monovalent. Selected from, Alternatively, the counter anion is a carboxylate anion based on poly(acrylic acid) homopolymers and copolymers as defined above. Carboxylate anions derived from polyacrylic acid copolymers, In other words, it contains a non-reactive comonomer, Here Copolymers can have a block-like or random distribution of comonomer units. Alternatively, a carboxylate anion derived from an acrylic acid copolymer, comprising a comonomer that provides OH and amine functional groups that can be functionalized via further ester or amide bonds with fatty acids or polyfatty acids, Alternatively, a carboxylate anion derived from a polyacrylic acid copolymer containing a carboxylic acid functional group comonomer, where Copolymers can have a block-like or random distribution of comonomer units. Carboxylates based on maleic acid copolymers, particularly those derived from maleic anhydride copolymers, here Copolymers can have a block-like or random distribution of comonomer units. As defined above, derived from polyitaconic acid copolymers containing carboxylates based on poly(itaconic acid) homo and copolymers, or, i.e., non-reactive monomer monomers. Here Copolymers can have a block-like or random distribution of comonomer units. Alternatively, itaconic acid copolymers, for example, derived from 2-hydroxyethyl methacrylate-itaconic acid copolymers, that include comonomers providing OH and amine functional groups that can be functionalized via further ester or amide bonds with fatty acids or polyfatty acids, Alternatively, derived from a polyitaconic acid copolymer containing a carboxylic acid functional group-containing comonomer, where Copolymers can have a block-like or random distribution of comonomer units. Here, the anion of this group is preferably an anion with a valency of 2 to 30,000, more preferably 2 to 1,000, even more preferably 10 to 1,000, and most preferably 100 to 1,000. Selected from the group consisting of, However, the cationic radical R of formulas (I) and (II) １ , R ３ , R ４ , R ５ The condition is that at least one of them contains at least one part of general formula (VII) or (VIII), -X-C(O)-R ｘ -(X-C(O)-R ｘ ) ｍ－１ -X-C(O)-R ７ (VII) or ︁!() ｘ !!! ｘ ) ｍ ︁!() ７ (().|) Here X is O, m = 2 to 20, preferably up to 10, more preferably up to 6, even more preferably 2 to 6, specifically 2, 3, 4, 5, 6, and R ｘ +R ７ The total number of carbon atoms (Σ carbon atoms R) ｘ , R ７ ) is 19 to 300, preferably 25 to 300, more preferably 35 to 300, even more preferably 50 to 300, specifically 35 to 200, more specifically 35 to 150, and even more specifically 50 to 150, R x is optional, and can be OH, -O-C(O)-R ７ , -O-C(O)-R ６ -(OC(O)-R ６ ) ０－１９ -O-C(O)-R ７ A linear or branched saturated or unsaturated hydrocarbon radical having 1 to 36 carbon atoms, preferably 1 to 24 carbon atoms, more preferably 1 to 18 carbon atoms, and even more preferably 8 to 18 carbon atoms, preferably derived from monohydroxycarboxylic acids, particularly glycolic acid, lactic acid, 2-hydroxybutyric acid, 3-hydroxy-butyric acid, 4-hydroxybutyric acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, reskerolic acid, ricinoleic acid, or dihydroxycarboxylic acids, particularly 2,2'-dihydroxymethylpropanoic acid, 9,10-dihydroxystearic acid, or polyhydroxycarboxylic acids, particularly gluconic acid. R ６ This is defined as described above, R ７ The compound according to any one of claims 1 to 3, wherein is an optionally substituted linear or branched saturated or unsaturated hydrocarbon radical having 1 to 36 carbon atoms, preferably 1 to 24 carbon atoms, more preferably 1 to 18 carbon atoms, and even more preferably 8 to 18 carbon atoms, preferably derived from acetic acid, octanoic acid, nonanoic acid, decanoic acid, dodecanoic acid, tetradecanoic acid, hexadecanoic acid, octadecanoic acid, eicosanoic acid, docosanoic acid, 2-ethylhexanoic acid, 2,2-dimethylpropionic acid, 2,2-dimethylheptanoic acid, 2,2-dimethyloctanoic acid, neodecanoic acid, undecyl-10-enoic acid, oleic acid, linoleic acid, linolenic acid, and erucic acid.

5. R １ This is selected from poly(alkylene oxide) groups, preferably poly(alkylene oxide) groups of general formula (IX), -[CH ２ CH ２ O] ｑ１ -[CH ２ CH(CH ３ )O] ｒ１ -[CH ２ CH(C ２ H ５ )O] ｓ１ -{[CH ２ CH ２ ] ｑ２ -[CH ２ CH(CH ３ )] ｒ２ -[CH ２ CH(C ２ H ５ )] ｓ２ }- (IX) Here q1 = 0 to 49, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, r1 = 0 to 32, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5. s1 = 0 to 24, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, q2 = 0 or 1, r² = 0 or 1, s² = 0 or 1, and Σ(q2+r2+s2)=1, However, the total number of carbon atoms in such poly(alkylene oxide) groups is 2 to 100, preferably 2 to 50, more preferably 2 to 30, even more preferably 2 to 20, specifically 2 to 15, or R １ It is selected from divalent hydrocarbon groups derived from oligoglycerol of general formula (X), -[CH ２ CH(R ８ )CH ２ O] ｔ１ -[CH ２ CH(R ８ )CH ２ )] ｔ２ - (X) Here t1 = 0 to 32, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, specifically 1 and 2. t² = 1, R ８ =OH or (-X-C(O)-R ６ ) ｍ -X-C(O)-R ７ , Here, m, X, R 6, and R ７ This is as defined above, However, the total number of carbon atoms is 2 to 100, preferably 2 to 50, more preferably 2 to 30, even more preferably 2 to 20, specifically 2 to 15, or R １ This is the general formula (XI) -[CH ２ CH ２ O] ｑ１ -R ９ -[CH ２ CH ２ O] ｑ１ -[CH ２ CH ２ ] ｑ２ - (XI) Here, q1 is either the same or different, and as defined above, and q2 = 1, and equation (XII) -[CH ２ CH(R ８ )CH ２ O] ｔ１ -R ９ -[CH ２ CH(R ８ )CH ２ O] ｔ１ -[CH ２ CH(R ８ )CH ２ )] ｔ２ - (XII) Here, t1, t2, and R ８ This is as defined above, and R ９ is -C(O)C(O)O-, -C(O)(CH ２ ) １－８ C(O)O-, for example, derived from succinic acid, adipic acid, sebacic acid, or -C(O)(C ６ H ４ )C(O)O-, derived from phthalic acid and terephthalic acid, -C(O)CH=CHC(O)O-, -C(O)C(=CH ２ ) - CH ２ Selected from C(O)O-, -C(O)CH(OH)CH(OH)C(O)O-, However, R ９ The condition is that the total number of carbon atoms is 2 to 100, preferably 2 to 50, more preferably 2 to 30, even more preferably 2 to 20, specifically 2 to 15. Selected from divalent hydrocarbon groups containing at least one ester group, And preferably, R １ It comprises one or more -O- groups, for example, 1 to 5, where these -O- groups are preferably ether groups, but can also form ester groups with carbonyl groups, and preferably group R １ The compound according to any one of claims 1 to 4, wherein is substituted with one or more hydroxyl groups.

6. N ＋ The radical R bonded to it １ , R ３ , R ４ , R ５ One or more of these are general formulas (III) or (IV), (-X-C(O)-R ６ ) ｍ -X-C(O)-(III), or (-C(O)-E-R ６ ) ｍ -C(O)-X-(IV) Preferably, general formula (IIIa) or (IVa) (-X-C(O)-R ６ ) ｍ -X-C(O)-R ７ (IIIa), or (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (IVa)、 Here, m = 1 - 20, and X, R ６ and R ７ This is as defined above. If it includes at least one part of, At least one part is general formula (XIII) or (XIV), -R １０ (-X-C(O)-R ６ ) ｍ -X-C(O)- (XIII) or -R １０ (-C(O)-X-R ６ ) ｍ -C(O)-X- (XIV)、 Preferably, general formulas (XIIIa) and (XIVa),  １０ (. ６ ) ｍ ︁!() ７ (︩|)) -R １０ (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (XIVa) It has a structure, Here R １０ It has a maximum of 200 carbon atoms, preferably 2 to 200 carbon atoms, more preferably 2 to 100 carbon atoms, even more preferably 2 to 50 carbon atoms, more specifically 2 to 20 carbon atoms, and more specifically 2 to 10 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, 【Transformation 30】 A hydrocarbon radical selected from which one or more groups may be selected from and may be substituted with an -OH or halide group, having a valency of divalent to 18, preferably divalent to 10, more preferably divalent to 6, and even more preferably divalent to 10, specifically selected from hydrocarbon radicals optionally substituted with divalent, trivalent, tetravalent, pentavalent, hexavalent, heptavalent, octavalent, 9valent, and 10valent, where radical R １０ It may not contain a combination of a -C(O)- group and an -O- group that forms an internal carboxylate group or an internal amide group, or a combination of a -C(O)- group and an -NH- or tertiary amino group. And preferably R １０ teeth, - Divalent radicals, especially -CH ２ -ien-CH ２ CH ２ -ien-CH ２ CH ２ CH ２ - Preferably derived from monochlorocarboxylic acids such as chloroacetic acid, chloropropionic acid, and chlorobutanoic acid, or preferably derived from tertiary amino alcohols such as N,N-dimethylethanolamine and N,N-dimethylpropanolamine. - Derived from a trivalent radical, preferably a trivalent alcohol, particularly glycerol, trimethylolpropane, or castor oil (ricinoleic acid triglyceride), specifically from a partial ester of the monochlorocarboxylic acid, particularly from chloroacetic acid, or preferably from a tertiary amino alcohol such as N,N,N'-trimethylaminoethyl-ethanolamine, or preferably from a dihydroxycarboxylic acid, particularly 2,2-hydroxymethylpropanoic acid, specifically from a tertiary amino alcohol, particularly from esters of N,N-dimethylethanolamine or N,N-dimethylpropanolamine. - Derived from partial esters of the monochlorocarboxylic acid, particularly esters of chloroacetic acid, by tetravalent to hexavalent radicals, preferably tetravalent alcohols, particularly erythritol, pentaerythritol, diglycerol, pentavalent alcohols, particularly xylitol, triglycerol, and hexavalent alcohols, particularly sorbitol, tetraglycerol, or preferably dendrimer oligomers of dihydroxycarboxylic acid oligomers, particularly dendrimer oligomers of 2,2-hydroxymethylpropanoic acid, by tertiary amino alcohols, particularly esters of N,N-dimethylethanolamine and N,N-dimethylpropanolamine, Derived from the partial esters of the monochlorocarboxylic acid, particularly esters of chloroacetic acid, by radicals with 7- to 18 valencies, alcohols with 7- to 18 valencies, especially pentaglycerol to hexadecaglycerol, Represented by, However, R １０ N is formed by a single bond. ＋ A portion is bonded to and at least one radical of the structure of general formula (III) or (IV), preferably 1, 2, 3, or 4 radicals, (-X-C(O)-R ６ ) ｍ -X-C(O)-(III), or (-C(O)-E-R ６ ) ｍ -C(O)-X-(IV) And more preferably, one, two, three, or four radicals of general formula (IIIa) or (IVa), (-E-C(O)-R ６ ) ｍ -E-C(O)-R ７ (IIa) (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (IVa) It is connected, Here, X, m, R 6, R ７ The compound according to any one of claims 1 to 5, wherein the compound is as defined above.

7. Low-melting point and high-melting point fatty acids ≥ C5 are R of general formulas (III) and (IV). ６ Within the contained ester elements, (-X-C(O)-R ６ ) ｍ -X-C(O)- (III) (-C(O)-X-R ６ ) ｍ -C(O)-X- (IV), especially R in general formulas (IIIa) and (IVa) ６ and R ７ Within the contained ester elements, (-X-C(O)-R ６ ) ｍ -X-C(O)-R ７ (IIIa) and (-C(O)-X-R ６ ) ｍ - C (O) - X - R ７ (IVa)、または R in general formulas (XIII) and (XIV) ６ Among the contained ester elements, -R １０ (-X-C(O)-R ６ ) ｍ -X-C(O)- (XIII) -R １０ (-C(O)-X-R ６ ) ｍ -C(O)-X- (XIV), especially R of general formulas (XIIIa) and (XIVa) ６ and R ７ Among the contained ester elements,  １０ (. ６ ) ｍ ︁!() ７ (︩|)) -R １０ (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (XIVa) It is specifically placed in Here, low-melting-point fatty acids ≥ C5 are defined as those with a melting point ≤ 40°C, and in particular include oleic acid, reskerolic acid, ricinoleic acid, octanoic acid, decanoic acid, pivalic acid, and neodecanoic acid. High melting point fatty acids ≥ C5 are defined as those with a melting point > 40°C, and in particular include dodecanoic acid, tetradecanoic acid, hexadecanoic acid, octadecanoic acid, arachidic acid, behenic acid, 10-hydroxyoctadecanoic acid, 12-hydroxyoctadecanoic acid, and 14-hydroxytetradecanoic acid. - At least one, preferably more than one, more preferably one, two or three, each being base R ６ Low melting point fatty acids ≥ C5 that form are R of formula (III) or (IV). ６ One end of the contained ester element is located, while at least one, preferably more than one, more preferably one, two, or three high-melting-point fatty acids ≥ C5 are located at the opposite end of the ester element of formula (III) or (IV), with one or more radicals R ６ A method that forms, or at least one, preferably more than one, more preferably one, two or three, each of which is a base R ６ The high melting point fatty acids ≥ C5 that form are R of formula (III) or (IV). ６ One end of the contained ester element, on the other hand, at least one, preferably more than one, more preferably one, two or three low-melting-point fatty acids ≥ C5, at the opposite end of the ester element of formula (III) or (IV), one or more radicals R ６ A method that forms, or - At least one, preferably more than one, more preferably one, two or three, each of the base R ６ The low melting point fatty acids ≥ C5 that form R ７ One or more radicals R adjacent to it ６ Included in, on the other hand, at least one, preferably more than one, more preferably one, two or three, high melting point fatty acids ≥ C5 are R of formula (IIIa) or (IVa). ６ and R ７ At the opposite end of the contained ester element, one or more radicals R ６ A manner that forms, or at least one, preferably more than one, more preferably one, two or three, each R ６ The high melting point fatty acids ≥ C5 that form R ７ One or more radicals adjacent to R ６ It forms a low-melting-point fatty acid ≥ C5 of formula (IIIa) or (IVa) ６ and R ７ At the opposite end of the contained ester element, one or more radicals R ６ A method of forming, or - At least one, preferably more than one, more preferably one, two or three, each of the base R ６ Low melting point fatty acids ≥ C5 that form radicals R １０ Adjacent to it, and on the other hand, at least one, preferably more than one, more preferably one, two or three high-melting-point fatty acids ≥ C5 are arranged at the opposite end of the ester element of formula (XIII) or (XIV), with one or more radicals R ６ A method of forming R, or at least one, preferably more than one, more preferably one, two or three, each R ６ High melting point fatty acids ≥ C5 that form radicals R １０ One or more radicals adjacent to R ６ It forms a compound, while at least one, preferably more than one, more preferably one, two, or three low-melting-point fatty acids ≥ 5 are R of formula (XIII) or (XIV). ６ and R ７ At the opposite end of the contained ester element, one or more radicals R ６ A method of forming, or - At least one, preferably more than one, more preferably one, two or three, each of the base R ６ Low melting point fatty acids ≥ C5 that form radicals R １０ Adjacent to it, and on the other hand, at least one, preferably more than one, more preferably one, two or three, high melting point fatty acids ≥ C5 are arranged in the part of formula (XIIIa) or (XIVa), R ７ One or more radicals R adjacent to it ６ A method of forming R, or at least one, preferably more than one, more preferably one, two or three, each R ６ The high melting point fatty acids ≥ C5 that form R １０ One or more radicals R adjacent to it ６ It forms a low melting point fatty acid ≥ C5, on the other hand, at least one, preferably more than one, more preferably one, two or three, in the part of formula (XIIIa) or (XIVa), R ７ One or more radicals R adjacent to it ６ The compound according to any one of claims 1 to 6, which is a method of forming [the compound].

8. The compound according to any one of claims 1 to 7, wherein the compound does not contain any amide group.

9. The cationic group R present in the cationic structure of general formulas (I) and (II) １ , R ２ , R ３ , R ４ , R ５ At least one of them includes at least one part of the following formula: R １＊ [(-O-C(O)-R ６ ) ｍ -O-C(O)-] ２ 、 Here R １＊ These are divalent C1-C100 radicals, preferably C1-C12 alkylenes, most preferably methylene, ethylene, 1,3-propylene, 1,4-butylene, 1,6-hexylene, 1,2-propylene, and 1,3-butylene radicals. m is selected independently from 12, R ６ This is as defined above, Preferably, in at least one part of the following general formula, R １＊ [(-O-C(O)-R ６ ) ｍ -O-C(O)-] ２ 、 R １＊ It is selected from methylene, ethylene, 1,3-propylene, 1,4-butylene, 1,6-hexylene, 1,2-propylene, and 1,3-butylene. R ６ These are derived from C8-C24 monocarboxy-monohydroxycarboxylic acids, particularly ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, and 11-hydroxy-undecanoic acid. And m is independently selected up to 6, and / or preferably, The cationic group R present in the cationic structure of general formulas (I) and (II) １ , R ２ , R ３ , R ４ , R ５ At least one of them includes at least one part of the following general formula: R １＊ [(-O-C(O)-R ６ ) ｍ -O-C(O)-] ２ 、 This is represented by the following structural formula: -C(O)-O-(Oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-O-C(O)-(Oligo C8-C24 hydroxy fatty acid)-O-C(O)-, Here C2-C10 hydrocarbons are C2-C10 hydrocarbylene groups, and The compound according to any one of claims 1 to 8, wherein the oligo C8-C24 hydroxy fatty acid is a group derived from an oligomer of up to 20 C8-C24 hydroxysubstituted carboxylic acid monomers formed by esterification, the degree of oligomerization being 2 to 20, preferably 2 to 10, more preferably 2 to 6, and even more preferably 2 to 4.

10. The cationic group R present in the cationic structure of general formulas (I) and (II) １ , R ２ , R ３ , R ４ , R ５ At least one of them includes at least one part of the following formula: R １＊ [(-O-C(O)-R ６ ) ｍ -O-C(O)-R ７＊ -] ２ 、 Here R １＊ , R ６ , and m are as defined above, And R ７＊ This is a C1-C12 alkylene group, preferably a methylene, ethylene, propylene, or butylene group, most preferably a methylene group. Preferably In at least one part of the following general formula, R １＊ [(-O-C(O)-R ６ ) ｍ -O-C(O)-R ７＊ -] ２ R １＊ It is selected from methylene, ethylene, 1,3-propylene, and 1,4-butylene, 1,6-hexylene. R ６ These are derived from C8-C24 monocarboxy-monohydroxycarboxylic acids, particularly ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, and 11-hydroxy-undecanoic acid. m is selected independently from up to 6. And R ７＊ It is selected from methylene and ethylene, and / or preferably at least one part of the following general formula: R １＊ [(-O-C(O)-R ６ ) ｍ -O-C(O)-R ７＊ -] ２ It is represented by one of the following structural formulas, i) -CH ２ -C(O)-O-(Oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-O-C(O)-(Oligo C8-C24 hydroxy fatty acid)-O-C(O)-CH ２ - or ii) -CH ２ CH ２ -C(O)-O-(Oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-O-C(O)-(Oligo C8-C24 hydroxy fatty acid)-O-C(O)-CH ２ CH ２ - Here C2-C10 hydrocarbons are C2-C10 hydrocarbylene groups, and The compound according to claim 9, wherein the oligo C8-C24 hydroxy fatty acid is a group derived from an oligomer of up to 20 C8-C24 hydroxysubstituted carboxylic acid monomers formed by esterification, with a degree of oligomerization of 2 to 20, preferably 2 to 10, more preferably 2 to 6, and even more preferably 2 to 4, and is particularly a group derived from mono or oligosilinoleic acid.

11. At least one part of the following general formula is: R １＊ [(-O-C(O)-R ６ ) ｍ -O-C(O)-R ７＊ -] ２ One or both terminal R ７＊ The group is bonded to a quaternary N atom, Preferably both terminal groups R ７＊ However, each is bonded to a quaternary N atom, The compound is a diquat or tetraquat compound. A more preferred compound comprises at least two parts of the following general formula: R １＊ [(-O-C(O)-R ６ ) ｍ -O-C(O)-R ７＊ -] ２ 、 And here The aforementioned parts are linked to each other via diquaternary ammonium alkylene groups of the general structure described below. -N ＋ (CH ３ ) ２ -ALK-N ＋ (CH ３ ) ２ -、 The compound according to claim 10, wherein ALK is a divalent alkylene group having 1 to 12 carbon atoms, preferably a linear alkylene group.

12. The cationic group R present in the cationic structure of general formulas (I) and (II) １ , R ２ , R ３ , R ４ , R ５ At least one of them includes at least one part of the following general formula: -([-O-C(O)-R ６ (-O-C(O)-R ６ ) ｌ -O-C(O)-L-C(O)-O-(R ６ -C(O)-O) ｌ -R ６ -C(O)O])- Here R ６ This is as defined above, l is an integer independently selected from 0 to 20, more preferably from 1 to 12, and even more preferably from 2 to 10, and L may have 1 to 30 carbon atoms and optionally include -O-, -S-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. 【Chemistry 35】 A divalent hydrocarbon radical which may contain one or more groups selected from, Preferably, L is a divalent alkylene or alkenylene radical having 1 to 30 carbon atoms. More preferably, L is selected from methylene, ethylene, propylene, butylene, pentylene, hexylene, heptylene, octylene, nonylene, etenylene, propenylene, butenylene, pentenylene, hexenylene, heptenylene, octenylene, nonenylene, Most preferably, L is selected from methylene, ethylene, ethenylene, or butenylene. Here, preferably, in at least one part of the following general formula, -([-O-C(O)-R ６ (-O-C(O)-R ６ ) ｌ -O-C(O)-L-C(O)-O-(R ６ -C(O)-O) ｌ -R ６ -C(O)O])- L and l are as defined above, And R ６ These are independently derived from C8-C24 monocarboxy-monohydroxycarboxylic acids, and / or preferably in at least one part of the following general formula, ([-O-C(O)-R ６ (-O-C(O)-R ６ ) ｌ -O-C(O)-L-C(O)-O-(R ６ -C(O)-O) ｌ -R ６ -C(O)O])- L is selected from methylene, ethylene, and ethenylene. R ６ It is derived from ricinoleic acid, and The compound according to any one of claims 1 to 11, wherein l is independently selected from 0, 1, 2, and 3, and the sum of l is in the range of 0–4.

13. A method for synthesizing a compound of general formula (I) according to any one of claims 1 to 12, R １ (-F) ｘ (I) Here Alkyl halides are at least one part (-X-C(O)-R ６ ) ｍ -X-C(O)- (III) or (-C(O)-E-R ６ ) ｍ -C(O)-X-(IV) preferably at least one part (-X-C(O)-R ６ ) ｍ -X-C(O)-R ７ (IIIa) or (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (IVa)、 It reacts with a tertiary amine, or As defined above, a halogenated carboxylic acid, preferably an ester of chloroacetic acid with an alcohol or epoxide, is at least one part (-X-C(O)-R ６ ) ｍ -X-C(O)- (III) or (-C(O)-E-R ６ ) ｍ -C(O)-X-(IV) preferably at least one part (-X-C(O)-R ６ ) ｍ -X-C(O)-R ７ (IIIa) or (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (IVa)、 It reacts with a tertiary amine, or As defined above, epoxy-functionalized ethers and esters with alcohols or carboxylic acids, preferably glycidyl ethers and esters, are at least one portion (-X-C(O)-R ６ ) ｍ -X-C(O)- (III) or (-C(O)-E-R ６ ) ｍ -C(O)-X-(IV) preferably at least one part (-X-C(O)-R ６ ) ｍ -X-C(O)-R ７ (IIIa) or (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (IVa)、 A tertiary amine having reacts with an acid, or As defined above, a tertiary amino group-containing hydrocarbon is at least one part (-X-C(O)-R ６ ) ｍ -X-C(O)- (III) or (-C(O)-E-R ６ ) ｍ -C(O)-X-(IV) preferably at least one part (-X-C(O)-R ６ ) ｍ -X-C(O)-R ７ (IIIa) or (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (IVa)、 It reacts with esters of halogenated carboxylic acids, or As defined above, a tertiary amino group-containing hydrocarbon is at least one part (-X-C(O)-R ６ ) ｍ -X-C(O)- (III) or (-C(O)-E-R ６ ) ｍ -C(O)-X-(IV) preferably at least one part (-X-C(O)-R ６ ) ｍ -X-C(O)-R ７ (IIIa) or (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (IVa)、 It has epoxy-functionalized ethers and esters that react in the presence of an acid, Here, X, R ６ , R ７ m and x are as defined above, Preferably, for compounds of general formula (I), R １ (-F) ｘ (I)、 Here R １ This is a quaternary nitrogen atom N ＋ via R ３ , R ４ , and R ５ It is linked to and R １ (-F) ｘ teeth, General formula (III) (-X-C(O)-R ６ ) ｍ -X-C(O)- (III)、 Or general formula (IV) (-C(O)-E-R ６ ) ｍ -C(O)-X-(IV) It includes at least one part of, preferably, General formula (IIIa) (-E-C(O)-R ６ ) ｍ -E-C(O)-R ７ (IIa), Or general formula (IVa) (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (IVa)、 Having at least one part of, Alkyl halides are, (-X-C(O)-R ６ ) ｍ -X-C(O)- (III) or (-C(O)-E-R ６ ) ｍ -C(O)-X-(IV) preferably includes at least one part of, (-X-C(O)-R ６ ) ｍ -X-C(O)-R ７ (IIIa) or (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (IVa)、 Having at least one part of, It reacts with tertiary amines, or As defined above, a halogenated carboxylic acid, preferably an ester of chloroacetic acid with an alcohol or epoxide, (-X-C(O)-R ６ ) ｍ -X-C(O)- (III) or (-C(O)-E-R ６ ) ｍ -C(O)-X-(IV) preferably includes at least one part of, (-X-C(O)-R ６ ) ｍ -X-C(O)-R ７ (IIIa) or (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (IVa)、 Having at least one part of, It reacts with tertiary amines, or As defined above, epoxy-functionalized ethers and esters, preferably glycidyl ethers and esters, are provided with an alcohol or carboxylic acid. (-X-C(O)-R ６ ) ｍ -X-C(O)- (III) or (-C(O)-E-R ６ ) ｍ -C(O)-X-(IV) preferably includes at least one part of (-X-C(O)-R ６ ) ｍ -X-C(O)-R ７ (IIIa) or (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (IVa)、 Having at least one part of, It reacts with a tertiary amine in the presence of an acid. or As defined above, tertiary amino group-containing hydrocarbons are (-X-C(O)-R ６ ) ｍ -X-C(O)- (III) or (-C(O)-E-R ６ ) ｍ -C(O)-X-(IV) preferably includes at least one part of (-X-C(O)-R ６ ) ｍ -X-C(O)-R ７ (IIIa) or (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (IVa)、 Having at least one part of, It reacts with halogenated carboxylic acid esters, or As defined above, tertiary amino group-containing hydrocarbons are (-X-C(O)-R ６ ) ｍ -X-C(O)- (III) or (-C(O)-E-R ６ ) ｍ -C(O)-X-(IV) preferably includes at least one part of, (-X-C(O)-R ６ ) ｍ -X-C(O)-R ７ (IIIa) or (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (IVa)、 Having at least one part of, Epoxy-functionalized ethers and esters react in the presence of an acid, Or, preferably, for compounds of general formula (I), R １ (-F) ｘ (I) Here R １ The quaternary nitrogen atom N ＋ It is linked to and R １ (-F) ｘ It has at least one part of the general formula (XIII), (XIV), (XIIIa), or (XIVa), -R １０ (-X-C(O)-R ６ ) ｍ -X-C(O)- (XIII) -R １０ (-C(O)-X-R ６ ) ｍ -C(O)-X-(XIV), preferably  １０ (. ６ ) ｍ ︁!() ７ (︩|)) -R １０ (-C(O)-X-R ６ ) ｍ -C(O)-X-R ７ (XIVa)、 Alkyl halides react with tertiary amines having at least one part of the general formula (XIII), (XIV), (XIIIa), or (XIVa), or Esters formed from halogenated carboxylic acids, preferably chloroacetic acid, with alcohols or epoxides react with tertiary amines having at least one part of the general formula (XIII), (XIV), (XIIIa), or (XIVa), or As defined above, epoxy-functionalized ethers and esters formed with alcohols or carboxylic acids, preferably glycidyl ethers and esters, react with tertiary amines having at least one part of general formula (XIII), (XIV), (XIIIa), or (XIVa) in the presence of an acid. or As defined above, a tertiary amino group-containing hydrocarbon reacts with an ester of a halogenated carboxylic acid having at least one part of the general formula (XIII), (XIV), (XIIIa), or (XIVa), or As defined above, tertiary amino group-containing hydrocarbons react with epoxy-functionalized ethers and esters having at least one part of general formula (XIII), (XIV), (XIIIa), or (XIVa) in the presence of an acid. Here R １０ The method is as defined above.

14. In cosmetic formulations for skin and hair care, particularly in conditioners and shampoos; in abrasives for treating and coating hard surfaces; in formulations for drying automobiles and other hard surfaces; for example, as a separate softener for finishing textiles and textile fibers after automatic washing; for use after textiles have been washed with nonionic or anionic / nonionic detergent formulations; as a softener in formulations for washing textiles based on nonionic or anionic / nonionic surfactants; and as a means for preventing or removing wrinkles in textiles, Use of the compound according to any one of claims 1 to 12 in a cosmetic composition, particularly useful for strengthening hair, maintaining hair color, improving hair shine, enhancing hair color, protecting hair color, shaping hair, conditioning hair, improving hair smoothness and softness, improving hair manageability, and especially for improving combability, anti-friction, and anti-static properties of hair, for fibers, preferably amino acid-based fibers, more preferably for the treatment of human hair.

15. A composition for hair treatment, comprising a compound according to any one of claims 1 to 12, selected from the group consisting of hair shampoo compositions, hair conditioning compositions, hair strengthening compositions, hair coloring or dyeing compositions, hair combability improving compositions, hair frizz prevention compositions, hair rinse-off and leave-on compositions.

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