Amino-functional polyorganosiloxane additives for aqueous coating compositions

Abstract

An aqueous coating composition comprising: a) a pigment; b) a binder; c) a surfactant; and d) an amino-functional polyorganosiloxane comprising at least one pendant amino group.

Description

Technical Field

[0001] Cross - reference to related applications: This application claims the benefit of U.S. Provisional Patent Application No. 63 / 241,119, filed on September 7, 2021, under 35 U.S.C. § 119(e). U.S. Provisional Patent Application No. 63 / 241,119 is hereby incorporated by reference into this specification.

[0002] The present invention relates to an amino - functional polyorganosiloxane additive useful for reducing surfactant leaching in aqueous coating compositions used for both indoor and outdoor applications.

Background Art

[0003] "Snail trail" is a common visual effect observed after applying an aqueous coating composition to a substrate. This effect appears as a series of vertical lines or "trails" on the coating after partial drying. This effect is particularly prominent when using compositions with a high percent Pigment Volume Concentration (%PVC). Snail trail is thought to be caused by surfactants and other water - soluble components leaching from the coating. Past efforts to reduce surfactant leaching have included the use of "reactive" surfactants that bind to other components of the composition. See, for example, U.S. Patent No. 9,102,848. Another approach involves the use of carbosiloxane dendrimer - grafted vinyl copolymers as described in International Publication No. 2019 / 060614. Yet another approach involves the addition of an alkoxy(3 - aminopropyl)siloxy - terminated polydimethylsiloxane fluid, a DOWSIL (trademark) 904H coating additive, to an aqueous coating composition. The industry continues to seek improved technical solutions for reducing surfactant leaching in aqueous coating compositions.

Summary of the Invention

[0004] The inventors of the present invention have discovered that when an aqueous coating composition is formulated with a specific type of amino-functional polyorganosiloxane, snail trails are unexpectedly reduced. In particular, the inventors have found that including an amino-functional polyorganosiloxane containing amino groups located at pendant positions along the polysiloxane skeleton results in a significant reduction in snail trails compared to the corresponding amino-functional polyorganosiloxane containing amino groups located only at terminal positions.

[0005] The present invention includes aqueous coating compositions comprising the aforementioned amino-functional polyorganosiloxanes, as well as their preparation and use. Numerous embodiments are described.

[0006] In one embodiment, the present invention provides an aqueous coating composition comprising: a) a pigment; b) an acrylic binder; c) a surfactant; and d) an amino-functional polyorganosiloxane having a molecular weight (Mw) of 10,000 to 50,000 AMU (Daltons), wherein the amino-functional polyorganosiloxane comprises at least one pendant amino group. In another embodiment, the amino-functional polyorganosiloxane has an amino neutral equivalent (ANE) number of 1,000 to 8,000. [Modes for carrying out the invention]

[0007] As used herein, the term “aqueous coating composition” refers to water-based (also called “waterborne”) building, industrial, and wood coatings used in both indoor and outdoor applications. Such coating compositions comprise an aqueous mixture of a) a pigment, b) a binder, and c) a surfactant. As is common in the industry, such coatings may optionally include additional components such as fillers, rheological modifiers, wetting agents, dispersants, defoamers, preservatives, fusion agents, pH stabilizers, and bulking agents. As is known in the art, many of the individual components may have overlapping functions, such as dispersants and surfactants. Pigments, fillers, binders, and surfactants are described in more detail below. Other typical examples of components include rheological modifiers: ACRYSOL® RM-8W and ACRYSOL® RM-2020; dispersants: OROTAN® 731A ER and TAMOL® 1124; defoamers: DOWSIL® 108F, DOWSIL® 8590 and DOWSIL® 74; bonding agents: UCAR® Filmer IBT and Texanol® ester alcohol; and fillers: ROPAQUE® Ultra E Organic Opacifier, all of which are available from The Dow Chemical Company. A typical aqueous coating composition contains the following components in the following amounts. [Table 1]

[0008] The preparation of applicable aqueous coating compositions is not particularly limited, and well-known techniques can be used. A classic preparation technique involves two steps: i) pigment dispersion (so-called "grinding") and ii) letdown. During the grinding step, clusters of pigment are ground to obtain a fine particle pigment dispersion. This operation may be carried out at high speed (e.g., ≥1200 rpm) in a bead mill until the desired particle size is achieved. Grinding can be controlled by Hegman fineness measurement. The preferred particle size varies depending on the application, but is generally in the range of 0.3 to 5 μm when measured by laser diffraction using a Malvern 3000. Friction generated during the grinding process may raise the temperature of the system, and therefore cooling may be required before initiating the letdown step to avoid degradation or alteration of subsequently added components. During the letdown process, the pulverized pigment (typically provided as a pulverized paste) is combined and mixed with an aqueous dispersion of the binder and surfactant, along with any other optional components mentioned above (e.g., using a mechanical mixer at low speed, e.g., 500–1100 rpm). The final viscosity of the resulting composition can be adjusted by adding additional water or rheological modifiers (thickeners). The specific order of addition and selection of individual components can be easily determined by routine experimentation.

[0009] In one embodiment of a class, the aqueous coating composition has a percent pigment volume concentration (%PVC) of at least 40, more preferably at least 50. The term “percent pigment volume concentration” or “%PVC” refers to the amount calculated by the following formula: %PVC = (Volume of pigment(s) with any fillers and extenders, if used) ÷ Total dry volume of paint * 100.

[0010] a) Pigments The types of pigments applicable to use in the present invention are not particularly limited, but are preferably selected from inorganic pigments containing one or more metal oxides such as titanium dioxide, iron oxide, and zinc oxide, with titanium dioxide being the most preferred. Applicable commercial products include TiPure® R-706 available from Chemours and TIOXIDE® TR92 available from Huntsman. Less expensive materials such as calcium carbonate, clay, talc, and mica can also be used and are generally called "fillers" when used in combination with metal oxides. Applicable commercial products include DURCAL® 2 and DURCAL® 2 available from Omya.

[0011] b) Binder The types of binders applicable for use in the present invention are not particularly limited and are preferably selected from organic polymers. Preferred types of polymers can be prepared by polymerization (e.g., free radical polymerization) of monoethylene unsaturated organic monomers and polyethylene unsaturated organic monomers. Such organic polymers include both homopolymers and copolymers. As used herein, “monoethylene unsaturated organic monomers” (preferably α-monoethylene unsaturated monomers) are compounds containing a single polymerizable carbon-carbon double bond that undergoes free radical polymerization under suitable reaction conditions. Examples include monoethylene unsaturated monocarboxylic acids, dicarboxylic acids and their corresponding esters. Typical “acrylates” include methacrylates, substituted acrylates, substituted methacrylates, fluorinated acrylates and fluorinated methacrylates. Specific examples include acrylic acid esters and methacrylic acid esters such as methyl acrylate, ethyl acrylate, butyl acrylate, t-butyl acrylate, 2-ethylhexyl acrylate, methyl methacrylate, decyl acrylate, lauryl acrylate, isodecyl methacrylate, lauryl methacrylate, and butyl methacrylate; and substituted acrylates and methacrylates such as hydroxyethyl acrylate, perfluorooctyl acrylate, hydroxypropyl acrylate, hydroxypropyl methacrylate, and hydroxyethyl methacrylate. Representative "acrylic acids" include acrylic acid, methacrylic acid, ethylacrylic acid, and their corresponding salts. Representative "vinyl halides" include vinyl chloride, vinylidene chloride, and chloroprene. Additional examples of applicable monomers include vinyl esters such as maleic anhydride, vinyl acetate and vinyl butyrate; vinylpyrrolidone; conjugated dienes such as butadiene and isoprene; vinyl aromatic compounds such as styrene and divinylbenzene; vinyl monomers such as ethylene; acrylonitrile and methacrylonitrile; acrylamide, methacrylamide and N-methylolacrylamide; and vinyl esters of monocarboxylic acids having up to 10 carbon atoms.Preferred types of organic binders are selected from polymers derived from acrylic acid and / or acrylate monomers, collectively referred to herein as “acrylic” or “acrylic polymer.” As used herein, the terms “acrylic” and “acrylic polymer” include both homopolymers and copolymers (e.g., styrene-acrylic copolymer, vinyl acetate-propenoic acid copolymer, etc.). A commercially available example of such products is the PRIMAL® brand acrylic binder available from The Dow Chemical Company. Such binders are often supplied as aqueous emulsions containing surfactants.

[0012] c) Surfactants The types of surfactants applicable for use in preparing the subject composition are not particularly limited and include a wide range of commercially available materials. Preferred surfactants may be anionic, cationic, nonionic, or mixtures thereof, with nonionic surfactants being preferred.

[0013] Examples of applicable anionic surfactants include, but are not limited to, alkali metals of higher fatty acids, amines or ammonium salts, alkylaryl sulfonates such as sodium dodecylbenzenesulfonate, long-chain aliphatic alcohol sulfates, olefin sulfates and olefin sulfonates, sulfated monoglycerides, sulfated esters, sulfonated ethoxylated alcohols, sulfosuccinates, alkanesulfonates, phosphate esters, alkyl isethionates, alkyl taurates, alkyl sarcosinates, and mixtures thereof. Further examples of applicable anionic surfactants include carboxylates (sodium 2-(2-hydroxyalkyloxy)acetate), amino acid derivatives (N-acyl glutamate, N-acylglycinate, or acyl sarcosinate), alkyl sulfates, alkyl ether sulfates and their oxyethylene derivatives, sulfonates, isethionates and N-acyl isethionates, taurates and N-acyl N-methyl taurates, sulfosuccinates, alkyl sulfoacetates, phosphates and alkyl phosphates, polypeptides, anionic derivatives of alkyl polyglycosides (acyl-D-galactosidouronates), fatty acid soaps, and mixtures thereof. Commercially available examples of applicable anionic surfactants include POLYSTEP® B25-E from Stepan, MARLON® A 323 from Sasol, and HOSTAPUR® SAS 30 from Clariant.

[0014] Examples of applicable nonionic surfactants include ethylene oxide and C 12~16Examples of nonionic surfactants include, but are not limited to, condensates of long-chain aliphatic alcohols such as alcohols or fatty acids, condensates of ethylene oxide with amines or amides, condensation products of ethylene and propylene oxide, esters of glycerol, sucrose, sorbitol, fatty acid alkylolamides, sucrose esters, fluorosurfactants, aliphatic amine oxides, and mixtures thereof. Further examples of nonionic surfactants include polyoxyethylene aliphatic alcohols, e.g., polyoxyethylene(23) lauryl ether, polyoxyethylene(4) lauryl ether, ethoxylated alcohols, e.g., ethoxylated trimethylnonanol, C 12~C14Examples include secondary alcohol ethoxylates, ethoxylated C10 Guerbet alcohols, ethoxylated iso-C13 alcohols; poly(oxyethylene)-poly(oxypropylene)-poly(oxyethylene) triblock copolymers (also known as poloxamers); tetrafunctional poly(oxyethylene)-poly(oxypropylene) block copolymers (also known as poloxamines) derived from the sequential addition of propylene oxide and ethylene oxide to ethylenediamine; silicone polyethers, polyoxyethylene alkyl ethers, polyoxyethylene alkylphenol ethers, polyoxyethylene lauryl ethers, polyoxyethylene sorbitan monooleate, polyoxyethylene alkyl esters, polyoxyethylene sorbitan alkyl esters, polyethylene glycol, polypropylene glycol, diethylene glycol, ethoxylated trimethylnonanol, and polyoxyalkylene glycol-modified polysiloxane surfactants, as well as combinations thereof. Further examples of applicable nonionic surfactants include polyoxyethylene alkyl ethers, polyoxyethylene alkylphenol ethers, polyoxyethylene lauryl ethers, linear primary alcohol alkoxylates, linear secondary alcohol alkoxylates, alkylphenol alkoxylates, olefin alkoxylates, branched alkoxylates, polyoxyethylene sorbitan monooleate, polyoxyethylene alkyl esters, polyoxyethylene sorbitan alkyl esters, polyethylene glycol, polypropylene glycol, diethylene glycol, ethoxylated trimethylnonanol, polyoxyalkylene-substituted silicones (lake or ABn type), silicone alkanolamides, silicone esters, silicone glycosides, and mixtures thereof.Further examples of applicable nonionic surfactants include dimethicone copolyols, fatty acid esters of polyols, e.g., sorbitol or glyceryl mono-, di-, tri-, or sesquioleate or stearate, glyceryl or polyethylene glycol laurate, fatty acid esters of polyethylene glycol (polyethylene glycol monostearate or monolaurate), polyoxyethylene fatty acid esters of sorbitol (stearate or oleate); and polyoxyethylene alkyl (lauryl, cetyl, stearyl, or octyl) ethers. Examples of applicable commercially available nonionic surfactants include TERGITOL™ TMN-10 available from The Dow Chemical Company, ADUXOL™ TRD6 available from Sharer & Schlapfer AG, and BRIJ™ L23 and BRIJ™ LT3, both available from Croda.

[0015] d) Aminosilicone The types of amino-functional polyorganosiloxanes ("aminosilicones") applicable for use in preparing the subject composition are not particularly limited and include commercially available materials. Importantly, the aminosilicones of the subject contain at least one amino group located at a pendant position along the polysiloxane skeleton. As shown in the following examples, aminosilicones containing an amino group located at a pendant position exhibited superior performance compared to those having an amino group located only at a terminal position. The aminosilicones of the subject may contain amino groups located at both terminal and pendant positions, but in a preferred class of embodiments, the amino group is primarily located at a pendant position, i.e., 29As determined by Si NMR, more than 90% by weight, more preferably more than 95% by weight, and even more preferably more than 99% by weight of the amino groups are located at the pendant position. Examples of such polymers include linear and branched structures, with linear polymers being preferred. The applicable polymers preferably have a weight-average molecular weight (Mw) of 10,000 to 50,000 AMU (Daltons), more preferably 12,000 to 45,000 AMU (Daltons), and even more preferably 15,000 to 40,000 AMU (Daltons). The applicable polymers preferably have a viscosity of 500 to 10,000 cSt, more preferably 700 to 7,000 cSt, as measured at 25°C according to ASTM D1084-16(2021). The aminosilicone of the subject preferably has an amino neutral equivalent (ANE) value of 1000 to 8000, more preferably 1000 to 7000, as determined by ASTM D2074-07. This test method provides a total amine value that can be converted to a more commonly reported amino neutral equivalent (ANE) according to the following calculation (amino neutral equivalent = (1000 * 56.1) / (total amine value)). Different aminosilicones may be used in combination, for example, those having different chemical structures, molecular weights, and / or viscosities. Applicable techniques for preparing aminosilicones are well known. See, for example, U.S. Patent Nos. 11028229, 10245451, 7238768, and 2947771. A typical aminosilicone has the general formula: R3SiO[R2SiO] x [RR N SiO] y SiR3 (In the formula, "x" is 100 to 500, preferably 200 to 300, "y" is 1 to 10, preferably 2 to 8, and "R" may be the same or different, selected from substituted or unsubstituted monovalent hydrocarbon groups having 1 to 18 carbon atoms, more preferably 1 to 8 carbon atoms). Typical hydrocarbon groups include a) alkyl groups such as methyl, ethyl, propyl, butyl, pentyl, hexyl, cyclohexyl, and heptyl, b) aryl groups such as phenyl, tolyl, xylyl, and naphthyl, and c) aralkyl groups such as benzyl and phenethyl, with methyl and phenyl groups being preferred, and methyl being the most preferred. Typical substituents include hydroxyl, amino, and alkoxy. N " is an amino group containing one or more (preferably 1 to 3) primary or secondary amine groups, each containing 1 to 6 carbon atoms. A typical amino group is one with the general formula: -R'NR "R" (wherein R' is a divalent hydrocarbon group having 2 to 6 carbon atoms (e.g., an alkylene group), and R'' is the same or different and may be H (hydrogen), unsubstituted, or selected from i) one or more unsubstituted or substituted hydrocarbon groups, or ii) a primary amine group or secondary amine group containing an unsubstituted or substituted monovalent hydrocarbon group having 1 to 6 carbon atoms (e.g., an alkyl group)). Applicable substituents include hydroxyl and alkoxy (e.g., methoxy, ethoxy). N A typical non-restrictive example of a "base" is: Examples include (CH3O)2(CH3)Si(CH2)3NH2, (CH3O)2(CH3)Si(CH2)4NH2, (CH3O)2(CH3)Si(CH2)3NH(CH2)2NH2, (CH3O)2(CH3)SiCH2CH(CH3)CH2NH(CH2)2NH2, (CH3O)2(CH3)SiCH2CH(CH3)CH2NH(CH2)3NH2, (CH3O)2(CH3)Si(CH2)3NH(CH2)2NH(CH2)2NH2, (CH3O)2(CH3)Si(CH2)3NH(CH2)4NH2, and their corresponding ethoxy(C2H5O)silanes.

[0016] The aminosilicone of the subject is preferably provided as an aqueous emulsion having a nonionic surfactant such as those described above. The emulsion preferably contains 1 to 5% by weight, more preferably 1 to 4% by weight, of the nonionic surfactant. A preferred emulsion contains 40 to 70% by weight of the aminosilicone of the subject. When provided in this manner, the emulsion may be used as an “additive” to an existing aqueous coating composition (as described in the following examples) or may be included in the letdown process as described above. Thus, in one embodiment, the present invention provides a method for producing an aqueous coating composition with improved resistance to snail trails, comprising the steps of preparing or obtaining the aqueous coating composition described above and adding an aqueous emulsion of the aminosilicone of the subject. The aminosilicone emulsion is preferably added to the aqueous coating composition in an amount that provides 1 to 10% effective content, preferably 2 to 5% effective content. As used herein, “effective content%” refers to the weight percentage of the additive in the aqueous coating composition excluding water. Once added, the resulting coating composition is highly stable and can be stored for extended periods without causing the aminosilicone to precipitate.

[0017] Silanol Although not required or desirable in most embodiments, the subject composition may include one or more polyorganosiloxanes containing at least one silanol group ("silanol"). When used, the silanol may be combined with the aforementioned aminosilicone and surfactant as part of an aqueous emulsion added to the aqueous coating composition containing the aforementioned pigment, binder and surfactant. In one class of embodiments, the subject aqueous coating composition is substantially silanol-free. In this context, "substantially silanol-free" means less than 0.5% by weight, preferably less than 0.1% by weight, more preferably less than 0.01% by weight, and even more preferably less than 0.001% by weight, based on the total weight of the aqueous coating composition. In another class of embodiments, the silanol is included in the subject aqueous coating composition in a weight ratio (silanol:aminosilicone) of ≤30:70, more preferably ≤10:90, and even more preferably ≤5:95. When used, the type of silanol is not particularly limited and includes a wide range of commercially available materials. Examples of such materials include linear and branched structures, with linear polymers being preferred. Applicable polymers preferably have a weight-average molecular weight (Mw) of 2,000 to 60,000 AMU (Daltons). Applicable polymers may have a viscosity of 50 to 5,000 cSt when measured at 25°C according to ASTM D1084-16 (2021). Different silanols may be used in combination, for example, those having different chemical structures, molecular weights, and / or viscosities. The polysiloxane of the subject contains at least one (-SiOH) group which may be located at terminal and / or pendant positions on the polysiloxane skeleton.

[0018] Many embodiments of the present invention are described, and in some cases, specific embodiments, selections, ranges, components, or other features are characterized as "preferred." The designation of such "preferred" features should never be construed as an essential or important aspect of the present invention. The recited ranges include the specifically recited endpoints. As used herein, the terms "molecular weight" and "Mw" refer to the weight-average molecular weight measured by gel permeation chromatography (GPC). Particle size measurements were determined by laser diffraction using Malvern 3000. The present specification includes the following embodiments. Item 1. An aqueous coating composition comprising: a) a pigment, b) a binder, and c) a surfactant, wherein the composition contains an amino-functional polyorganosiloxane having a molecular weight (Mw) of 10,000 to 50,000 AMU (dalton) in an effective content of 1 to 10%, and the amino-functional polyorganosiloxane contains at least one pendant amino group. Item 2. The coating composition according to Item 1, wherein the amino-functional polyorganosiloxane has an amino neutral equivalent (ANE) value of 1000 to 8000. Item 3. The pendant amino group is represented by at least one of the following formulas (CH3O)2(CH3)Si(CH2)3NH2, (CH3O)2(CH3)Si(CH2)4NH2, (CH3O)2(CH3)Si(CH2)3NH(CH2)2NH2, (CH3O)2(CH3)SiCH2CH(CH3)CH2NH(CH2)2NH2, (CH3O)2(CH3)SiCH2CH(CH3)CH2NH(CH2)3NH2, (CH3O)2(CH3)Si(CH2)3NH(CH2)2NH(CH2)2NH2, (CH3O)2(CH3)Si(CH2)3NH(CH2)4NH2, and (CH3O)2(CH3)Si(CH2)3NH(CH2)2NH2, and the coating composition according to Item 1 or 2. Item 4. The coating composition according to any one of items 1 to 3, wherein the amino-functional polyorganosiloxane has a molecular weight (Mw) of 12,000 to 45,000 AMU (dalton). Item 5. The coating composition according to any one of items 1 to 4, wherein the binder contains an acrylic binder. Item 6. The coating composition according to any one of items 1 to 5, wherein the pigment contains a metal oxide. Item 7. The coating composition according to any one of items 1 to 6, wherein the surfactant contains a nonionic surfactant. Item 8. The coating composition according to any one of items 1 to 7, further characterized by having at least 50% pigment volume concentration (%PVC). Item 9. The coating composition according to any one of items 1 to 8, further characterized by containing a polyorganosiloxane containing at least one silanol group at a weight ratio of 10:90 or less with respect to the amino-functional polyorganosiloxane. Item 10. The coating composition according to item 1, wherein the composition substantially does not contain a polyorganosiloxane containing at least one silanol group.

Examples

[0019] Unless otherwise specified, all preparations and tests are carried out at room temperature (RT) at standard pressure (1 atm or 760 mmHg), and all ratios are expressed as weight percentages.

[0020] Aqueous coating formulations of four different samples were prepared as described below to obtain one sample (i.e., Jotashield Colourlast from Jotun). Aqueous emulsions of various additive formulations were then mixed with the aqueous coating composition of each sample as described below, and subsequently tested according to D7190-10 (2015). Specifically, the aqueous coating composition of each sample was applied to a black scrub panel (P121-10N plastic-vinyl chloride / acetate copolymer paper) to a wet thickness of 200 μm using a metal gap applicator and allowed to dry for 8–24 hours. Three drops of water were then applied to each coated panel, left for 30 minutes, and then the panel was tilted to remove the water. The traces left by the water on the panel after evaporation were then evaluated according to tests A–E provided below. The combination of scores from tests A–E best indicates the performance. [Table 2] [Table 3] [Table 4] [Table 5] [Table 6] [Table 7] [Table 8]

[0021] The following series of aqueous emulsion additive formulations were prepared, mixed (in the specified effective content %) with the indicated aqueous coating formulations, and subsequently tested. The results are shown below. As used herein, "effective content %" refers to the weight percentage of the additive excluding water.

[0022] Example 1: This series of examples demonstrates the improved performance resulting from the addition of the subject aminosilicones (number 2, number 3, and a blend of numbers 2 and 3) compared to a control example that does not contain such additives. [Table 9]

[0023] Example 2: This series of examples demonstrates the improved performance resulting from the addition of the subject aminosilicone (number 3, a blend of numbers 3 and 2) compared to a control example that does not contain such additives. [Table 10]

[0024] Example 3: This series of examples demonstrates the effect of including silanols of different molecular weights (No. 1 and No. 3) in the additive formulation, in addition to the subject aminosilicone (No. 3). [Table 11]

[0025] Example 4: This series of examples demonstrates the effects of various weight ratios of silanol (2) to the subject aminosilicone (2). [Table 12]

[0026] Example 5: DOWSIL® 904H coating additive promotes the reduction of snail trails in aqueous coating compositions. While this additive (an aminosilicone with terminal amino groups) is effective when added to the coating composition immediately before application, it is not provided as an emulsion, and therefore its stability in the coating composition is too short for many applications. To improve stability, the additive should be incorporated into the coating composition as an emulsion. However, emulsion preparation of 904H requires a much higher level of surfactant than the aminosilicone in question. This added surfactant causes increased surfactant leaching. Although we do not wish to be bound by theory, the relatively low molecular weight of the aminosilicone species 904H (3200 AMU) is thought to facilitate its movement within the coating composition, which in turn interferes with surfactants similarly present in the composition. As shown by the results below, the DOWSIL® 904H coating additive did not result in any improvement over a control example without the aminosilicone additive. [Table 13]

[0027] Example 6: This series of examples demonstrates the effect of the position (pendant vs. terminal) of the amino group in aminosilicone. [Table 14] [Table 15]

[0028] Example 7: This series of examples demonstrates the effects of using various different surfactants together with the subject aminosilicone (No. 2). [Table 16]

[0029] Example 8: This series of examples demonstrates the effect of adding the subject aminosilicones (Nos. 1 and 5) to Jotashield Colourlast aqueous paint (3% effective content) from Jotun, compared to a control example without the addition of aminosilicones. [Table 17]

Claims

1. An aqueous coating composition comprising a) a pigment, b) a binder, and c) a surfactant, characterized in that the composition contains an amino-functional polyorganosiloxane having a molecular weight (Mw) of 10,000 to 50,000 AMU (Daltons) in an effective fraction of 1 to 10 percent, wherein the amino-functional polyorganosiloxane contains at least one pendant amino group, and the amino-functional polyorganosiloxane has an amino-neutral equivalent (ANE) value of 1,000 to 8,000.

2. The coating composition according to claim 1, wherein the amino-functional polyorganosiloxane has a molecular weight (Mw) of 12,000 to 45,000 AMU (Daltons).

3. The coating composition according to claim 1, wherein the binder comprises an acrylic binder.

4. The coating composition according to claim 1, wherein the pigment comprises a metal oxide.

5. The coating composition according to claim 1, wherein the surfactant includes a nonionic surfactant.

6. The coating composition according to claim 1, further characterized by having at least 50% percent pigment volume concentration (%PVC).

7. The coating composition according to claim 1, further characterized by containing a polyorganosiloxane having at least one silanol group in a weight ratio of 10:90 or less to the amino-functional polyorganosiloxane.

8. The coating composition according to claim 1, wherein the composition substantially does not contain a polyorganosiloxane comprising at least one silanol group.

9. An aqueous coating composition comprising a) a pigment, b) an acrylic binder, and c) a surfactant, characterized in that the composition contains an amino-functional polyorganosiloxane having a molecular weight (Mw) of 10,000 to 50,000 AMU (Daltons) in an effective fraction of 1 to 10 percent, wherein the amino-functional polyorganosiloxane contains at least one pendant amino group.

Images