Dry and wet cleaner care agent composition and manufacturing method thereof

Abstract

Disclosed in the present invention are a dry and wet cleaner care agent composition and a manufacturing method thereof, wherein a glycol solvent, a cationic surfactant, and a non-ionic surfactant are added as active ingredients so that the dry and wet cleaner care agent composition exhibits excellent sterilizing power compared to conventional cleaning agent compositions for robot cleaners. In addition, according to the dry and wet cleaner care agent composition and the manufacturing method thereof of the present invention, the cleaning performance of a mop is improved by 5% or more, thus making the removal of contaminants highly effective, and cleaning a floor with a diluent does not make the floor slippery, thus enabling clean, safe, and hygienic usage.

Description

Dry and wet combined cleaner management composition and method for producing the same

[0001] The present invention relates to a dry and wet combined vacuum cleaner management composition having excellent odor suppressing properties generated from wastewater of a dry and wet combined vacuum cleaner, and a method for producing the same.

[0002] In general, a dry and wet combination vacuum cleaner is a vacuum cleaner that performs dry and wet cleaning simultaneously by vacuuming and mopping the floor, and washes the mop that was used to clean the floor during or after cleaning. It is a home appliance market that has been growing rapidly recently.

[0003] These dry and wet vacuum cleaners have seen rapid growth due to their convenience. However, after mopping the floor, the wastewater collected in the mop can become contaminated with various foreign substances and microorganisms, resulting in a foul odor resembling a sewer even after just one day. Therefore, if these vacuum cleaners are left unattended, they can develop biofilms, causing odors and decomposition, potentially leading to hygiene issues within the home.

[0004] In the past, a detergent consisting of methylisothiazolinone (MIT) and chloromethylisothiazolinone (CMIT), which were used in humidifier disinfectants, was diluted in a ratio of about 200 to 300 times in a water purifier tank and used. However, the 200 to 300-fold dilution had almost no sterilizing power, so a foul odor continued to be emitted from the wastewater tank where the mop was washed.

[0005] In addition, since conventional detergents contain raw materials for humidifier disinfectants, there may be controversy over their harmfulness to the human body if detergent residue remains on the floor.

[0006] Therefore, there is a need to develop a cleaner management composition that can provide excellent microbial inhibition at low concentrations (diluted solution of 300 times or more) without using biocides used in humidifier disinfectants.

[0007]

[0008] (Patent Document 1) KR Patent Publication No. 10-1999-0075142 (Published on October 15, 1999)

[0009] The purpose of the present invention is to provide a dry and wet combined cleaner management composition having an excellent odor reduction effect and an excellent ability to inhibit microbial growth at a dilution ratio of 300 times or more without using methylisothiazolin (MIT) or chloromethylisothiazolin (CMIT) components, and a method for producing the same.

[0010] In addition, the purpose of the present invention is to provide a dry and wet combined vacuum cleaner management composition having excellent mop cleaning performance and non-slip properties even when the floor is cleaned with a diluted solution, and a method for manufacturing the same.

[0011] In addition, the purpose of the present invention is to provide a dry and wet combined cleaner management composition and a method for manufacturing the same, which improves the cleaning performance of a mop by 5% or more, exhibits an excellent effect in removing contamination, and can be used safely and hygienically without making the floor slippery even when wiping it with a diluted solution.

[0012] The objectives of the present invention are not limited to those mentioned above. Other objectives and advantages of the present invention not mentioned above can be understood through the following description and will be more clearly understood through the embodiments of the present invention. Furthermore, it will be readily apparent that the objectives and advantages of the present invention can be realized by the means and combinations thereof set forth in the claims.

[0013] The dry and wet combined vacuum cleaner management composition and the method for manufacturing the same according to an embodiment of the present invention have an excellent odor reduction effect through inhibition of microbial growth in wastewater in a dry and wet combined vacuum cleaner.

[0014] To this end, a dry and wet combined cleaner management composition according to an embodiment of the present invention comprises 2 to 30 wt% of a glycol solvent; 2 to 15 wt% of a cationic surfactant; 1 to 10 wt% of a nonionic surfactant; and the remaining amount of water.

[0015] In addition, the dry and wet combined vacuum cleaner management composition and the method for manufacturing the same according to the embodiment of the present invention have an excellent microbial growth inhibition effect, the floor is not slippery after use, and the mop cleaning performance for floor cleaning is excellent.

[0016] In addition, the dry and wet combined cleaner management composition and the method for manufacturing the same according to the embodiment of the present invention have an excellent odor reduction effect due to their excellent ability to inhibit microbial growth at a dilution ratio of 300 times or more without using methylisothiazolin (MIT) or chloromethylisothiazolin (CMIT) components.

[0017] As a result, the dry and wet combined vacuum cleaner management composition and the method for manufacturing the same according to the embodiment of the present invention exhibit superior sterilizing power compared to a conventional dedicated cleaning composition for a robot vacuum cleaner by adding a glycol solvent, a cationic surfactant, and a nonionic surfactant as active ingredients.

[0018] In addition, the dry and wet combined vacuum cleaner management composition and the method for manufacturing the same according to the embodiment of the present invention have excellent mop cleaning performance and do not cause slipping even when the floor is cleaned with a diluted solution.

[0019] As a result, the dry and wet combined vacuum cleaner management composition and its manufacturing method according to the embodiment of the present invention show an excellent effect in removing contamination by improving the cleaning performance of the mop by 5% or more, and can be used safely and hygienically without making the floor slippery even when wiping it with a diluted solution.

[0020] According to the present invention, even without using methylisothiazolinone (MIT) or chloromethylisothiazolinone (CMIT) components, the odor reduction effect is excellent because the ability to inhibit microbial growth is excellent at a dilution ratio of 300 times or more.

[0021] As a result, according to the present invention, by adding a glycol solvent, a cationic surfactant, and a nonionic surfactant as active ingredients, a result of superior sterilizing power is shown compared to a conventional cleaning composition for a robot cleaner.

[0022] In addition, according to the present invention, the mop has excellent cleaning performance and does not become slippery even when cleaning the floor with a diluted solution.

[0023] As a result, according to the present invention, the cleaning performance of the mop is improved by more than 5%, showing an excellent effect in removing contamination, and the floor does not become slippery even when cleaned with a diluted solution, so it can be used safely and hygienically.

[0024] In addition to the effects described above, specific effects of the present invention are described below while explaining specific details for carrying out the invention.

[0025] Figure 1 is a process flow diagram showing a method for manufacturing a dry and wet combined cleaner management composition according to an embodiment of the present invention.

[0026]

[0027] The above-described objects, features, and advantages will be described in detail below with reference to the accompanying drawings, so that those skilled in the art can easily practice the technical idea of ​​the present invention. In describing the present invention, if it is determined that a detailed description of known technologies related to the present invention may unnecessarily obscure the gist of the present invention, a detailed description thereof will be omitted. Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. In the drawings, the same reference numerals are used to indicate the same or similar components.

[0028] As used herein, singular expressions include plural expressions unless the context clearly dictates otherwise. In this application, terms such as "consisting of" or "comprising" should not necessarily be construed to include all of the components or steps described in the specification, and should be construed to mean that some of the components or steps may not be included, or that additional components or steps may be included.

[0029] Hereinafter, a dry and wet combined cleaner management composition and a method for manufacturing the same according to some embodiments of the present invention will be described.

[0030]

[0031] The dry and wet combined vacuum cleaner management composition according to an embodiment of the present invention has an excellent odor reduction effect through inhibition of microbial growth in wastewater in a dry and wet combined vacuum cleaner.

[0032] To this end, a dry and wet combined cleaner management composition according to an embodiment of the present invention comprises 2 to 30 wt% of a glycol solvent; 2 to 15 wt% of a cationic surfactant; 1 to 10 wt% of a nonionic surfactant; and the remaining amount of water.

[0033] In addition, the dry and wet combined vacuum cleaner management composition according to an embodiment of the present invention has an excellent microbial growth inhibition effect, does not make the floor slippery after use, and has excellent mop cleaning performance for floor cleaning.

[0034] In addition, the dry and wet combined cleaner management composition according to an embodiment of the present invention has an excellent odor reduction effect due to its excellent ability to inhibit microbial growth at a dilution ratio of 300 times or more without using methylisothiazolin (MIT) or chloromethylisothiazolin (CMIT) components.

[0035] As a result, the dry and wet combined cleaner management composition according to the embodiment of the present invention exhibits superior sterilizing power compared to a conventional dedicated cleaning composition for robot cleaners by adding a glycol solvent, a cationic surfactant, and a nonionic surfactant as active ingredients.

[0036] In addition, the dry and wet combined vacuum cleaner management composition according to an embodiment of the present invention has excellent mop cleaning performance and does not cause slipping when cleaning the floor with a diluted solution.

[0037] As a result, the dry and wet combined vacuum cleaner management composition according to the embodiment of the present invention shows an excellent effect in removing contamination by improving the cleaning performance of the mop by 5% or more, and can be used safely and hygienically without making the floor slippery even when wiping it with a diluted solution.

[0038]

[0039] Hereinafter, the role and content of each component of the dry and wet combined vacuum cleaner management composition according to an embodiment of the present invention will be described in detail.

[0040]

[0041] The glycol solvent is added to effectively reduce odor by preventing the growth of microorganisms in the wastewater of a dry and wet combined vacuum cleaner, and may include at least one selected from the group consisting of compounds represented by the following chemical formulas 1 and 2.

[0042]

[0043] [Chemical Formula 1]

[0044]

[0045] Here, R1 is alkyl having 1 to 10 carbon atoms.

[0046]

[0047] [Chemical Formula 2]

[0048]

[0049] Here, R1 is an alkyl or ether having 1 to 10 carbon atoms, or a carboxyl having 4 to 10 carbon atoms.

[0050] Thus, glycol solvents exhibit excellent affinity for a wide range of polar and nonpolar substances and have low minimum inhibition concentrations (MICs), demonstrating superior microbial growth inhibition. Furthermore, glycol solvents exhibit excellent affinity for both polar and nonpolar substances, making them ideal for cleaning and sterilization when mixed with nonionic surfactants and polar anionic and cationic surfactants.

[0051] The glycol compound represented by the above chemical formula 1 may be at least one selected from the group consisting of 1,2-pentanediol, 1,2-hexanediol, 1,2-heptanediol, 1,2-octanediol, 1,2-decanediol, 1,2-dodecanediol, etc. In addition, the glycol compound represented by the above chemical formula 2 may be at least one selected from the group consisting of glycerin caprylate, ethylhexylglycerin, etc.

[0052] It is preferable that the glycol solvent be added in a content ratio of 2 to 30 wt% of the total weight of the dry and wet combined cleaner management composition, and a more preferable range is 10 to 30 wt%. If the amount of the glycol solvent added is less than 2 wt% of the total weight of the dry and wet combined cleaner management composition, the ability to inhibit microbial growth is reduced, resulting in a lower odor reduction effect. Conversely, if the amount of the glycol solvent added exceeds 30 wt% of the total weight of the dry and wet combined cleaner management composition, the solution of the dry and wet combined cleaner management composition becomes suspended or separated. The reason why the suspension or separated is caused by the hydrophobic and nonionic and cationic surfactants among the raw materials of the composition not being sufficiently solubilized in water, resulting in the dispersion of the cationic surfactants that are solubilized in water into large particles. If such a suspended or layered liquid composition is used as a dry and wet combined cleaner management composition, the odor reduction effect may be reduced due to uneven sterilization performance.

[0053]

[0054] It is preferable that the cationic surfactant include at least one selected from the group consisting of compounds represented by the following chemical formulas 3, 4 and 5.

[0055]

[0056] [Chemical Formula 3]

[0057]

[0058] Here, R1 and R2 are each alkyl or alkenyl having 8 to 22 carbon atoms, and X is any one of Cl, CH3OSO3, and CH3CH2OSO3.

[0059]

[0060] [Chemical Formula 4]

[0061]

[0062] Here, R1 is alkyl or alkenyl having 8 to 22 carbon atoms, R2 is H or alkyl or alkenyl having 1 to 4 carbon atoms, and X is any one of Cl, CH3OSO3, and CH3CH2OSO3.

[0063]

[0064] [Chemical Formula 5]

[0065]

[0066] Here, R1, R2, R3 and R4 are each alkyl or alkenyl having 1 to 22 carbon atoms, and X is any one of Cl, CH3OSO3 and CH3CH2OSO3.

[0067]

[0068] In the above chemical formula 2, chemical formula 3 and chemical formula 4, each of the quaternary ammonium salt compounds may be at least one selected from monostearyl amino ethylene imidazoline ammonium salt, monooleic amino ethylene imidazoline ammonium salt, monolauryl amino ethylene imidazoline distearic ester ammonium salt, dioleic ester ammonium salt, dilauric ester ammonium salt, lautrimonium salt, cetrimonium salt, stearimonium salt, benzenetrimonium salt, etc.

[0069] It is preferable that such cationic surfactants be added in a content ratio of 2 to 15 wt% of the total weight of the dry and wet combined cleaner management composition, and a more preferable range may be 10 to 15 wt%. If the amount of the cationic surfactant added is less than 2 wt% of the total weight of the dry and wet combined cleaner management composition, there may be a problem of reduced sterilizing performance. Conversely, if the amount of the cationic surfactant added exceeds 15 wt% of the total weight of the dry and wet combined cleaner management composition, sufficient emulsification and dispersion may be difficult during the manufacture of the dry and wet combined cleaner management composition, and there may be a problem of generation of a suspension.

[0070]

[0071] It is preferable that the nonionic surfactant include at least one selected from the group consisting of compounds represented by the following chemical formula 6.

[0072]

[0073] [Chemical Formula 6]

[0074] C m H 2m+1 -O-(CH2CH2O) n -H

[0075] Here, m is an integer from 5 to 21, and n is an integer from 1 to 10.

[0076]

[0077] More preferably, the nonionic surfactant may include at least one selected from polyoxyethylene dodecanyl ether, polyoxyethylene tetradecanyl ether, polyoxy hexadecanyl ether, and polyoxyethylene heptadecanyl ether. Among these, it is most preferable to use polyoxyethylene dodecanyl ether having 7 mol of added moles of EO as the nonionic surfactant.

[0078] It is preferable that such nonionic surfactants be added in a content ratio of 1 to 10 wt% of the total weight of the dry and wet combined cleaner management composition, and a more preferable range is 5 to 10 wt%. If the amount of the nonionic surfactant added is less than 1 wt% of the total weight of the dry and wet combined cleaner management composition, there may be a problem of reduced ability to remove oily and aqueous stains from fibers. On the contrary, if the amount of the nonionic surfactant added is more than 10 wt% of the total weight of the dry and wet combined cleaner management composition, a residue may remain on the mop when cleaning the mop, which may remain on the floor during the next cleaning, causing problems of staining and slipping when walking.

[0079]

[0080] Hereinafter, a method for manufacturing a dry and wet combined vacuum cleaner management composition according to an embodiment of the present invention will be described with reference to the attached drawings.

[0081] Figure 1 is a process flow diagram showing a method for manufacturing a dry and wet combined cleaner management composition according to an embodiment of the present invention.

[0082] As illustrated in FIG. 1, a method for manufacturing a dry and wet combined cleaner management composition according to an embodiment of the present invention includes a mixing step (S110) and a stirring step (S120).

[0083]

[0084] mix

[0085] In the mixing step (S110), a glycol solvent, a cationic surfactant, and a nonionic surfactant are mixed in water.

[0086] In this mixing, the glycol solvent, cationic surfactant, and nonionic surfactant can be mixed in any order. For example, water can be mixed into the glycol solvent first, and then the cationic surfactant and nonionic surfactant can be mixed sequentially.

[0087]

[0088] Stirring

[0089] In the stirring step (S120), the mixed mixture is stirred to form a dry and wet combined cleaner management composition.

[0090] At this stage, stirring is preferably performed at a speed of 300 to 1,500 rpm at room temperature. At this time, the room temperature is preferably 5 to 40°C, but is not limited thereto. In addition, if the stirring speed is less than 300 rpm, there is a concern that the glycol solvent, cationic surfactant, and nonionic surfactant may not be sufficiently solubilized in water. Conversely, if the stirring speed exceeds 1,500 rpm, it may only increase the manufacturing cost without any further effect, making it uneconomical.

[0091] After this stirring step (S120), the dry and wet combined cleaner management composition comprises 2 to 30 wt% of a glycol solvent, 2 to 15 wt% of a cationic surfactant, 1 to 10 wt% of a nonionic surfactant, and the remaining amount of water.

[0092] Here, it is preferable that the glycol solvent includes at least one selected from the group consisting of compounds represented by the following chemical formulas 1 and 2.

[0093]

[0094] [Chemical Formula 1]

[0095]

[0096] Here, R1 is alkyl having 1 to 10 carbon atoms.

[0097]

[0098] [Chemical Formula 2]

[0099]

[0100] Here, R1 is an alkyl or ether having 1 to 10 carbon atoms, or a carboxyl having 4 to 10 carbon atoms.

[0101] It is preferable that such glycol solvents be added in a content ratio of 2 to 30 wt% of the total weight of the dry and wet combined cleaner management composition, and a more preferable range is 10 to 30 wt%.

[0102] It is preferable that the cationic surfactant include at least one selected from the group consisting of compounds represented by the following chemical formulas 3, 4 and 5.

[0103]

[0104] [Chemical Formula 3]

[0105]

[0106] Here, R1 and R2 are each alkyl or alkenyl having 8 to 22 carbon atoms, and X is any one of Cl, CH3OSO3, and CH3CH2OSO3.

[0107]

[0108] [Chemical Formula 4]

[0109]

[0110] Here, R1 is alkyl or alkenyl having 8 to 22 carbon atoms, R2 is H or alkyl or alkenyl having 1 to 4 carbon atoms, and X is any one of Cl, CH3OSO3, and CH3CH2OSO3.

[0111]

[0112] [Chemical Formula 5]

[0113]

[0114] Here, R1, R2, R3 and R4 are each alkyl or alkenyl having 1 to 22 carbon atoms, and X is any one of Cl, CH3OSO3 and CH3CH2OSO3.

[0115] It is preferable that these cationic surfactants be added in a content ratio of 2 to 15 wt% of the total weight of the dry and wet combined cleaner management composition, and a more preferable range is 10 to 15 wt%.

[0116] It is preferable that the nonionic surfactant include at least one selected from the group consisting of compounds represented by the following chemical formula 6.

[0117]

[0118] [Chemical Formula 6]

[0119] C m H 2m+1 -O-(CH2CH2O) n -H

[0120] Here, m is an integer from 5 to 21, and n is an integer from 1 to 10.

[0121] More preferably, the nonionic surfactant may include at least one selected from polyoxyethylene dodecanyl ether, polyoxyethylene tetradecanyl ether, polyoxy hexadecanyl ether, and polyoxyethylene heptadecanyl ether. Among these, it is most preferable to use polyoxyethylene dodecanyl ether having 7 mol of added moles of EO as the nonionic surfactant.

[0122] It is preferable that such nonionic surfactants be added in a content ratio of 1 to 10 wt% of the total weight of the dry and wet combined cleaner management composition, and a more preferable range is 5 to 10 wt%.

[0123]

[0124] A dry and wet combined cleaner management composition according to an embodiment of the present invention can be manufactured by the above process (S110 to S120).

[0125] A dry and wet combined cleaner management composition manufactured by a method according to an embodiment of the present invention has an excellent odor reduction effect due to its excellent ability to inhibit microbial growth at a dilution ratio of 300 times or more without using methylisothiazolin (MIT) or chloromethylisothiazolin (CMIT) components.

[0126] As a result, the dry and wet combined cleaner management composition manufactured by the method according to the embodiment of the present invention exhibits superior sterilizing power compared to a conventional dedicated cleaning composition for robot cleaners by adding a glycol solvent, a cationic surfactant, and a nonionic surfactant as active ingredients.

[0127] In addition, the dry and wet combined cleaner management composition manufactured by the method according to the embodiment of the present invention has excellent mop cleaning performance and does not cause slipping when cleaning the floor with a diluted solution.

[0128] As a result, the dry and wet combined vacuum cleaner management composition manufactured by the method according to the embodiment of the present invention shows an excellent effect in removing contamination by improving the cleaning performance of the mop by 5% or more, and can be used safely and hygienically without making the floor slippery even when wiping it with a diluted solution.

[0129]

[0130] Example

[0131] Hereinafter, the structure and operation of the present invention will be described in more detail through preferred embodiments of the present invention. However, these are presented as preferred examples of the present invention and should not be construed as limiting the present invention in any way.

[0132] Anything not described here will be omitted as it is technically feasible for those skilled in this field to infer.

[0133]

[0134] 1. Preparation of a composition for managing a dry and wet vacuum cleaner

[0135] Table 1 shows the components and component ratios of the dry and wet combined cleaner management compositions according to Examples 1 to 6, and Table 2 shows the components and component ratios of the dry and wet combined cleaner management compositions according to Comparative Examples 1 to 7. In this case, in Examples 1 to 6 and Comparative Examples 1 to 5, a glycol solvent, a cationic surfactant, and a nonionic surfactant were mixed with water in the content ratios shown in Tables 1 and 2, and the mixed mixture was stirred at a speed of 1,100 rpm at room temperature until it became a transparent liquid, thereby preparing a dry and wet combined cleaner management composition. In addition, in Comparative Examples 6 and 7, commercial cleaner management compositions from Ecovacs and Roborock were obtained, respectively.

[0136]

[0137] Ingredients Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 1,2-Hexanediol 11510 1515 1,2-Octanediol 0.5 1510 10 12.5 Glycerin caprylate 0.5 0.1 155 2.5 Cationic surfactant (CT) 1155 10 5 Cationic surfactant (IMQ) 1155 5 10 Nonionic surfactant (LA-7) 1155 10 10 Water Balance Balance Balance Balance Balance Balance

[0138]

[0139] (Unit: weight%)

[0140]

[0141] Ingredients Comparison Example 1 Comparison Example 2 Comparison Example 3 Comparison Example 4 Comparison Example 5 Comparison Example 6 Comparison Example 7 1,2-Hexanediol 15-10 10 Ecovacs Roborock 1,2-Octanediol 0.5 10-55 Glycerin caprylate 0.5 25-2 Cationic surfactant (CT) 15 5 5 5 Cationic surfactant (IMQ) 0.5 5 1 1 1 Nonionic surfactant (LA-7) 0.5 0.9 0.9 18 Water Balance Balance Balance Balance Balance

[0142]

[0143] (Unit: weight%)

[0144]

[0145] In Tables 1 and 2, CT is cetrimonium chloride, IMQ is monooleic aminoethylene imidazoline ammonium salt, and LA-7 is polyoxyethylene dodecanyl ether.

[0146]

[0147] 2. Physical property evaluation

[0148] Table 3 shows the results of property evaluations for washing machine tub cleaning compositions according to Examples 1 to 6 and Comparative Examples 1 to 7. In this case, in Table 3, the “>” sign means that the minimum measured value is indicated, and the “<” sign means that the maximum measured value is indicated.

[0149]

[0150] 1) Sterilizing power

[0151] Each dry and wet combined vacuum cleaner management agent composition was diluted 300 times and its sterilizing power was evaluated against four types of bacteria (Staphylococcus aureus (ATCC 6538), Escherichia coli (ATCC 8739), Pseudomonas aeruginosa (ATCC 15442), and Klebsiella pneumoniae (ATCC 4352). If the sterilizing power for all four types of bacteria was 99.999% or higher, it was marked as good, and if it was less than 99.999%, it was marked as poor.

[0152]

[0153] 2) Washing rate

[0154] In order to evaluate the cleaning rate for each dry and wet combined cleaner management composition, P-H011 contamination cloth with milk coffee contamination applied to polyester, which is the same material as the mop, was used, and each dry and wet combined cleaner management composition original solution was diluted 300 times and washed by stirring for 5 minutes using a magnetic stirrer.

[0155] After stirring, the reflectance before and after washing was observed using a colorimeter (Minolta CR-300 Chroma-meter) to calculate the washing rate. At this time, the washing rate was {(R w -R s ) / (R o -R s )} Х 100(%) was calculated by the formula, where R o is the surface reflectance value of the circle, and R s is the surface reflectance value of the contaminated cloth before washing, and R w is the surface reflectance value of the contaminated cloth after washing.

[0156]

[0157] 3) Phase stability

[0158] After leaving the original solution of each dry and wet combined cleaner management composition under harsh conditions (50℃ oven and -5℃ incubator, 7 days), the discoloration and phase separation of each dry and wet combined cleaner management composition were visually observed and evaluated. After one week, if the original solution of each dry and wet combined cleaner management composition showed discoloration or the phase was suspended and separated, it was marked as defective, and if the phase was normal, it was marked as good.

[0159]

[0160] 4) Slip resistance

[0161] Each dry and wet combined vacuum cleaner management agent composition was diluted 300 times and tested at the Korea Testing & Research Institute for Construction Research using KS F2375-2016 (Test Method for Slip Resistance of Road Surfaces). If the test results were similar to those of untreated and tap water treated surfaces, they were marked as good. If there were differences, they were marked as bad.

[0162]

[0163] Distinction Sterilization power (%)Cleaning rate (%)Stability (50℃)Stability (-5℃)Slip resistanceExample 1 Poor <60 Poor Good Good Example 2 Poor <60 Poor Good Good Example 3 Good >80 Good Good Good Example 4 Good >84 Good Good Good Example 5 Good >85 Good Good Good Example 6 Good >90 Good Good Good Comparative Example 1 Poor <50 Good Good Good Comparative Example 2 Poor <60 Good Good Good Good Comparative Example 3 Poor <60 Poor Bad Good Good Comparative Example 4 Poor <60 Good Good Good Good Comparative Example 5 Good >80 Poor Bad Good Comparative Example 6 Poor <80 Good Good Good Good Comparative Example 7 Poor <80 Good Good Good Good

[0164]

[0165] As shown in Tables 1 to 3, it was confirmed that the dry and wet combined cleaner management compositions according to Examples 1 to 6 exhibited excellent sterilizing power, cleaning power, stability, and anti-slip properties, even though they did not use biocides with controversial toxicity.

[0166] In particular, the dry and wet combined cleaner management compositions according to Examples 3 to 6 exhibited the best characteristics in terms of sterilizing power, cleaning power, stability, and anti-slip properties.

[0167] On the other hand, it was confirmed that the dry and wet combined vacuum cleaner management compositions according to Comparative Examples 1 to 7 showed at least one of sterilizing power, cleaning power, surface stability, and anti-slip properties as being defective.

[0168] As can be seen from the above experimental results, the dry and wet combined cleaner management compositions according to Examples 1 to 6, which are manufactured by adding a glycol solvent, a cationic surfactant, and a nonionic surfactant as active ingredients, exhibit superior sterilizing power compared to commercial products without using a biocide with controversial toxicity, exhibit an equivalent or higher cleaning rate, have excellent phase stability at high temperatures (50°C) and low temperatures (-5°C), and have no abnormalities in slip resistance.

[0169]

[0170] Although the present invention has been described with reference to the drawings exemplified above, it is to be understood that the present invention is not limited to the embodiments and drawings disclosed herein, and that various modifications may be made by those skilled in the art within the scope of the technical idea of ​​the present invention. Furthermore, even if the operational effects according to the configuration of the present invention have not been explicitly described while describing the embodiments of the present invention, it is natural that the effects predictable by the corresponding configuration should also be acknowledged.

Claims

1. 2 to 30 wt% of glycol solvent; 2 to 15 wt% cationic surfactant; 1 to 10 wt% of nonionic surfactant; and The remaining water; A dry and wet combined cleaner management composition comprising:

2. In paragraph 1, The above glycol solvent A dry and wet combined cleaner management composition comprising at least one compound selected from the group consisting of compounds represented by the following chemical formulas 1 and 2. [Chemical Formula 1] (Here, R1 is alkyl having 1 to 10 carbon atoms.) [Chemical formula 2] (Here, R1 is alkyl or ether having 1 to 10 carbon atoms, or carboxyl having 4 to 10 carbon atoms.) 3. In paragraph 1, The above cationic surfactant A dry and wet combined cleaner management composition comprising at least one compound selected from the group consisting of compounds represented by the following chemical formulas 3, 4 and 5. [Chemical Formula 3] (Here, R1 and R2 are each alkyl or alkenyl having 8 to 22 carbon atoms, and X is any one of Cl, CH3OSO3, and CH3CH2OSO3.) [Chemical Formula 4] (Here, R1 is alkyl or alkenyl having 8 to 22 carbon atoms, R2 is H or alkyl or alkenyl having 1 to 4 carbon atoms, and X is any one of Cl, CH3OSO3, and CH3CH2OSO3.) [Chemical Formula 5] (Here, R1, R2, R3 and R4 are each alkyl or alkenyl having 1 to 22 carbon atoms, and X is any one of Cl, CH3OSO3 and CH3CH2OSO3.) 4. In paragraph 1, The above nonionic surfactant A dry and wet combined cleaner management composition comprising at least one compound selected from the group consisting of compounds represented by the following chemical formula 6. [Chemical formula 6] C m H 2m+1 -O-(CH2CH2O) n -H (Here, m is an integer from 5 to 21, and n is an integer from 1 to 10.) 5. In paragraph 4, The above nonionic surfactant A dry and wet combined cleaner management composition comprising at least one selected from polyoxyethylene dodecanyl ether, polyoxyethylene tetradecanyl ether, polyoxy hexadecanyl ether and polyoxyethylene heptadecanyl ether.

6. A step of mixing a glycol solvent, a cationic surfactant and a nonionic surfactant into water; and A step of forming a dry and wet combined cleaner management composition by stirring the above-mentioned mixed mixture; A method for producing a dry and wet combined cleaner management composition, wherein the dry and wet combined cleaner management composition comprises 2 to 30 wt% of a glycol solvent, 2 to 15 wt% of a cationic surfactant, 1 to 10 wt% of a nonionic surfactant, and the remaining amount of water.

7. In paragraph 6, The above stirring A method for manufacturing a washing machine drum detergent composition, the method comprising: performing the process at room temperature and at a speed of 300 to 1,500 rpm.

8. In paragraph 6, The above glycol solvent A method for producing a dry and wet combined cleaner management composition comprising at least one compound selected from the group consisting of compounds represented by the following chemical formulas 1 and 2. [Chemical Formula 1] (Here, R1 is alkyl having 1 to 10 carbon atoms.) [Chemical formula 2] (Here, R1 is alkyl or ether having 1 to 10 carbon atoms, or carboxyl having 4 to 10 carbon atoms.) 9. In paragraph 6, The above cationic surfactant A method for producing a dry and wet combined cleaner management agent composition comprising at least one compound selected from the group consisting of compounds represented by the following chemical formulas 3, 4 and 5. [Chemical Formula 3] (Here, R1 and R2 are each alkyl or alkenyl having 8 to 22 carbon atoms, and X is any one of Cl, CH3OSO3, and CH3CH2OSO3.) [Chemical Formula 4] (Here, R1 is alkyl or alkenyl having 8 to 22 carbon atoms, R2 is H or alkyl or alkenyl having 1 to 4 carbon atoms, and X is any one of Cl, CH3OSO3, and CH3CH2OSO3.) [Chemical Formula 5] (Here, R1, R2, R3 and R4 are each alkyl or alkenyl having 1 to 22 carbon atoms, and X is any one of Cl, CH3OSO3 and CH3CH2OSO3.) 10. In paragraph 6, The above nonionic surfactant A method for producing a dry and wet combined cleaner management composition comprising at least one compound selected from the group consisting of compounds represented by the following chemical formula 6. [Chemical formula 6] C m H 2m+1 -O-(CH2CH2O) n -H (Here, m is an integer from 5 to 21, and n is an integer from 1 to 10.) 11. In paragraph 10, The above nonionic surfactant A method for producing a dry and wet combined cleaner management composition comprising at least one selected from polyoxyethylene dodecanyl ether, polyoxyethylene tetradecanyl ether, polyoxy hexadecanyl ether and polyoxyethylene heptadecanyl ether.

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