Method for manufacturing electronic device

Abstract

This method for manufacturing an electronic device comprises: a step for preparing a structure (100) including an adhesive film (10) provided with a base material layer (A), an adhesive resin layer (B), and an adhesive resin layer (C), a to-be-processed object (20) temporarily fixed to the adhesive resin layer (B), and a support member (30) temporarily fixed to the adhesive resin layer (C); and a step for processing the to-be-processed object (20) temporarily fixed to the adhesive resin layer (B). The base material layer (A) is positioned between the adhesive resin layer (B) and the adhesive resin layer (C). The adhesive resin layer (C) contains thermally expansive microspheres, and the sphericity R, calculated by a prescribed formula, of the thermally expansive microspheres is 0.93 or greater.

Description

Method of manufacturing electronic devices

[0001] This invention relates to a method for manufacturing an electronic device.

[0002] Examples of technologies that use adhesive films in the manufacturing process of electronic devices include the technologies described in Patent Documents 1 to 3.

[0003] Patent Document 1 describes a dicing tape and a DDAF that are suitable for increasing the separation distance between the semiconductor chip with a die bond film (DDAF) after it has been cut on the dicing tape while suppressing lifting from the dicing tape, and are also suitable for achieving good pick-up performance in the pick-up process, with the objective being to provide a dicing tape and a DDAF that are suitable for increasing the separation distance between the semiconductor chip with a die bond film (DDAF) after it has been cut on the dicing tape, while suppressing lifting from the dicing tape, and are also suitable for achieving good pick-up performance in the pick-up process. The dicing tape has a laminated structure including a base material and an adhesive layer, and the ratio of the second tensile stress that occurs at a strain value of 20% in a tensile test performed on a 20 mm wide dicing tape test piece under the conditions of an initial chuck distance of 100 mm, 23°C, and tensile speed of 10 mm / min to the first tensile stress that occurs at a strain value of 20% in a tensile test performed on a 20 mm wide dicing tape test piece under the conditions of an initial chuck distance of 100 mm, 23°C, and tensile speed of 1000 mm / min is 1.4 or more.

[0004] Patent Document 2 describes a heat-resistant adhesive sheet for semiconductor device manufacturing, which is used to adhere to a substrate-less semiconductor chip when resin encapsulating it, with the aim of solving the problems of the chip not being held in place by the pressure during resin encapsulation and shifting from the designated position, or the package being damaged when peeling off the heat-resistant adhesive sheet for semiconductor device manufacturing due to the hardening of the encapsulating material or the strong adhesion to the chip surface due to heat. The heat-resistant adhesive sheet has a base layer and an adhesive layer, and the adhesive layer has an adhesive strength to SUS304 after bonding of 0.5 N / 20 mm or more, and hardens due to the stimuli received by the time the resin encapsulation process is completed, resulting in a package peeling strength of 2.0 N / 20 mm or less.

[0005] Patent Document 3 describes a method for manufacturing an organic EL panel using an ultrathin glass substrate, in which the ultrathin glass substrate does not "crack" or "chip" during the manufacturing process, organic EL elements can be efficiently formed by vacuum deposition, and the organic EL panel can be recovered after the manufacturing process without damaging the ultrathin glass substrate, and there is no need to include a step to clean the back surface of the ultrathin glass substrate. The method for manufacturing an organic electroluminescent panel in which organic electroluminescent elements are formed on an ultrathin glass substrate by vacuum deposition involves temporarily fixing the ultrathin glass substrate to a support plate via a double-sided adhesive tape having a heat-release adhesive layer containing heat-expandable microspheres that begin to expand and / or foam at a temperature higher than the vacuum deposition temperature on at least one side of the substrate layer, and forming electrodes on the ultrathin glass substrate.

[0006] Patent Document 4 describes an adhesive sheet that achieves both surface smoothness and thin adhesive layer thickness, resulting in less deformation of the adhesive layer during processing, enabling high-precision processing and significantly improving product characteristics and productivity, and is useful as a support sheet for processing electronic components such as small ceramic capacitors. The objective is to provide an adhesive sheet having an adhesive layer containing thermally expandable microspheres on at least one side of a substrate, or an adhesive layer consisting of a resin layer containing thermally expandable microspheres and an adhesive layer, wherein the adhesive layer is laminated on the side opposite to the substrate of the resin layer, and the thickness of the adhesive layer is 10 to 38 μm, and the maximum particle size of the thermally expandable microspheres is less than or equal to the thickness of the adhesive layer, and the mode diameter is 5 to 30 μm.

[0007] Japanese Patent Publication No. 2019-16634, Japanese Patent Publication No. 2011-134811, International Publication No. 2010 / 004703, Japanese Patent Publication No. 2008-45011

[0008] This invention provides a method for manufacturing an electronic device with improved object retention.

[0009] The present invention provides a method for manufacturing an electronic device as shown below: [1] A method for manufacturing an electronic device comprising: a step of preparing a structure including an adhesive film having a base layer (A), an adhesive resin layer (B), and an adhesive resin layer (C), a workpiece temporarily fixed to the adhesive resin layer (B), and a support member temporarily fixed to the adhesive resin layer (C); and a step of processing the workpiece temporarily fixed to the adhesive resin layer (B), wherein the base layer (A) is located between the adhesive resin layer (B) and the adhesive resin layer (C), the adhesive resin layer (C) includes thermally expandable microspheres, and the sphericity R of the thermally expandable microspheres, calculated by the following formula (1), is 0.93 or more. (In formula (1) above, n represents the total number of thermally expandable microspheres, i represents an integer between 1 and n, X ｉ represents the equivalent circular diameter of the i-th thermally expandable microsphere, Y ｉ (wherein this indicates the circularity of the i-th thermally expandable microsphere.) [2] In the volume-based cumulative frequency distribution curve of the thermally expandable microspheres measured by a laser diffraction scattering particle size distribution analyzer, the particle size D when the cumulative frequency is 50% ５０ A method for manufacturing an electronic device according to [1], wherein the particle size D is 1 μm or more and 30 μm or less. [3] In the volume-based cumulative frequency distribution curve of the thermally expandable microspheres measured by a laser diffraction scattering particle size distribution analyzer, the particle size D when the cumulative frequency is 99.9% ９９．９A method for manufacturing an electronic device according to [1] or [2], wherein the diameter of the microspheres is 10 μm or more and 50 μm or less. [4] A method for manufacturing an electronic device according to any one of [1] to [3], wherein the foaming temperature of the thermally expandable microspheres is 160°C or higher. [5] A method for manufacturing an electronic device according to any one of [1] to [4], wherein the adhesive resin layer (C) is a layer whose adhesive strength decreases with heat treatment. [6] A method for manufacturing an electronic device according to any one of [1] to [5], wherein the adhesive resin layer (C) contains one or more selected from the group consisting of (meth)acrylic adhesive resins, silicone adhesive resins, urethane adhesive resins, olefin adhesive resins, and styrene adhesive resins. [7] A method for manufacturing an electronic device according to any one of [1] to [6], wherein the content of the thermally expandable microspheres in the adhesive resin layer (C) is 5% by mass or more and 50% by mass or less when the total amount of the adhesive resin layer (C) is 100% by mass. [8] The method for manufacturing an electronic device according to any one of [1] to [7], wherein the base layer (A) comprises one or more selected from the group consisting of polypropylene, polyethylene terephthalate, polyethylene naphthalate, polyamide, polyimide, and polyether ether ketone. [9] The method for manufacturing an electronic device according to any one of [1] to [8], wherein the thickness of the adhesive resin layer (C) is 10 μm or more and 100 μm or less.

[10] The method for manufacturing an electronic device according to any one of [1] to [9], wherein the thickness of the adhesive resin layer (B) is 1 μm or more and 40 μm or less.

[11] The method for manufacturing an electronic device according to any one of [1] to

[10] , further comprising an intermediate layer (D) between the base layer (A) and the adhesive resin layer (B), and between the base layer (A) and the adhesive resin layer (C).

[12] The method for manufacturing an electronic device according to

[11] , wherein the thickness of the intermediate layer (D) is 5 μm or more and 100 μm or less.

[13] A method for manufacturing an electronic device according to any one of [1] to

[12] , wherein the electronic device includes a semiconductor package.

[14] A method for manufacturing an electronic device according to

[13] , wherein the semiconductor package includes a fan-out type package.

[0010] According to the present invention, it is possible to provide a method for manufacturing an electronic device in which the holding power of the object is improved.

[0011] This is a schematic cross-sectional view illustrating an example of a method for manufacturing the electronic device according to this embodiment. This is a schematic cross-sectional view illustrating an example of a method for manufacturing the electronic device according to this embodiment. This is a schematic cross-sectional view illustrating an example of the structure of the adhesive film used in the method for manufacturing the electronic device according to this embodiment, together with the workpiece and support member. This is a schematic cross-sectional view illustrating an example of the structure of the adhesive film used in the method for manufacturing the electronic device according to this embodiment, together with the workpiece and support member.

[0012] In this specification, the term "(meth)acrylate" encompasses both acrylate and methacrylate. The same applies to similar terms such as "(meth)acryloyl." For each component described in this specification, one type may be used, or two or more types may be used in combination. Furthermore, unless otherwise specified, the numerical range "A to B" refers to a range between A and B. To avoid complexity, if there are multiple identical components in the same drawing, only one may be assigned a reference numeral, and none of them may be assigned a reference numeral. Drawings are for illustrative purposes only. The shapes and dimensional ratios of each component in the drawings do not necessarily correspond to actual articles.

[0013] Conventionally, adhesive films sometimes contained thermally expandable microspheres in the adhesive resin layer that came into contact with the object. The inventors' investigations revealed that these thermally expandable microspheres contained coarse particles, such as aggregates of thermally expandable microspheres and irregularly shaped particles derived from thermally expandable microspheres that failed to form spheres during the manufacturing process. It was found that these coarse particles caused irregularities on the surface of the adhesive film (the surface of the adhesive resin layer). When irregularities occur on the surface of the adhesive film, objects temporarily fixed by the adhesive film become more likely to detach from it. In other words, irregularities on the surface of the adhesive film reduce the adhesive film's ability to hold objects. This can lead to manufacturing defects in the production process of electronic devices using adhesive films. Further investigations by the inventors revealed that the coarse particles contained in the thermally expandable microspheres were present in small amounts relative to the total thermally expandable microspheres. Furthermore, it was found that it is difficult to distinguish between a group of thermally expandable microspheres with a relatively low coarse particle content (a group of thermally expandable microspheres that yields an adhesive film with high object retention) and a group of thermally expandable microspheres with a relatively high coarse particle content (a group of thermally expandable microspheres that yields an adhesive film with low object retention) from the perspective of particle size distribution.

[0014] <Method for Manufacturing an Electronic Device> The method for manufacturing an electronic device according to this embodiment includes a step of preparing a structure comprising an adhesive film having a base layer (A), an adhesive resin layer (B), and an adhesive resin layer (C), a workpiece temporarily fixed to the adhesive resin layer (B), and a support member temporarily fixed to the adhesive resin layer (C). The method for manufacturing an electronic device according to this embodiment includes a step of processing the workpiece temporarily fixed to the adhesive resin layer (B). In the method for manufacturing an electronic device according to this embodiment, the base layer (A) is located between the adhesive resin layer (B) and the adhesive resin layer (C). In the method for manufacturing an electronic device according to this embodiment, the adhesive resin layer (C) includes thermally expandable microspheres. In the method for manufacturing an electronic device according to this embodiment, the sphericity R of the thermally expandable microspheres, calculated by the following formula (1), is 0.93 or higher. In equation (1), n ​​represents the total number of thermally expandable microspheres. Also, i represents an integer between 1 and n, inclusive. ｉThis indicates the equivalent circular diameter of the i-th thermally expandable microsphere. Also, Y ｉ This indicates the circularity of the i-th thermally expandable microsphere. The manufacturing method of the electronic device of this embodiment can improve the holding force of the object by having the above configuration.

[0015] The reason for this is not entirely clear, but the following reasons can be inferred. It is thought that the coarse particles contained in the thermally expandable microspheres have a shape that deviates more from a perfect sphere compared to normal thermally expandable microspheres. Here, the sphericity R (hereinafter also referred to as sphericity R), calculated by equation (1) and used to evaluate the thermally expandable microspheres of the adhesive film in this embodiment, is a parameter that evaluates both the particle size (equivalent diameter of a circle) and the particle shape (degree of circularity). For this reason, it is thought that the amount of coarse particles, which was difficult to evaluate using particle size distribution, can now be evaluated by using sphericity R. Furthermore, it is thought that the thermally expandable microspheres of the adhesive film used in the manufacturing method of the electronic device in this embodiment, when the sphericity R is above a predetermined value, reduce the surface irregularities of the adhesive film caused by coarse particles, thereby improving the object-holding power of the adhesive film. As a result, it is thought that the manufacturing method of the electronic device in this embodiment can improve the object-holding power.

[0016] The following describes a method for manufacturing an electronic device (manufacturing method Y) when the adhesive resin layer (C) of the adhesive film 10 of this embodiment, which will be described later, is in contact with the support member 30.

[0017] [Manufacturing Method Y] Manufacturing method Y includes, for example, the following two steps: (1) A step of preparing a structure 100 including an adhesive film 10 and a workpiece 20 temporarily fixed to the adhesive film 10 (step Y1) (2) A step of processing the workpiece 20 temporarily fixed to the adhesive film 10 (step Y2)

[0018] As described above, the adhesive film 10 of this embodiment has improved object retention. Therefore, the manufacturing method of an electronic device using the adhesive film 10 of this embodiment (manufacturing method Y) can improve object retention. Specifically, manufacturing method Y can reduce the peeling of the adhesive film 10 from the support member 30 during the manufacturing process. This can improve the yield of the electronic device.

[0019] The following describes each step of manufacturing method Y with reference to Figure 1. The adhesive film 10 used in manufacturing method Y comprises a base layer (A) and an adhesive resin layer (C), as well as an additional adhesive resin layer (B) on the first surface A1 side of the base layer (A). In other words, the adhesive film 10 used in manufacturing method Y comprises a base layer (A), an adhesive resin layer (B), and an adhesive resin layer (C). Furthermore, in the adhesive film 10 used in manufacturing method Y, the base layer (A) is located between the adhesive resin layer (B) and the adhesive resin layer (C).

[0020] (Process Y1) In process Y1, a structure 100 is prepared, which includes an adhesive film 10 and a workpiece 20 temporarily fixed to the adhesive resin layer (B) of the adhesive film 10. The structure 100 is also temporarily fixed to a support member 30 by the adhesive resin layer (C) of the adhesive film 10. In other words, process Y1 includes the process of preparing a structure 100 which includes an adhesive film 10, a workpiece 20 temporarily fixed to the adhesive resin layer (B) of the adhesive film 10, and a support member 30 temporarily fixed to the adhesive resin layer (C) of the adhesive film 10. Note that the temporary fixing of the adhesive resin layer (B) of the adhesive film 10 to the workpiece 20 and the temporary fixing of the adhesive resin layer (C) of the adhesive film 10 to the support member 30 may be performed simultaneously, or one temporary fixing may be performed after the other temporary fixing.

[0021] Such a structure 100 can be manufactured, for example, by the following procedure. First, an adhesive film 10 is attached to the support member 30 so that the adhesive resin layer (C) faces the support member 30. A protective film called a separator may be attached to the adhesive resin layer (C). In this case, the protective film is peeled off and the exposed surface of the adhesive resin layer (C) is attached to the surface of the support member 30.

[0022] Next, the structure 100 can be manufactured by attaching the workpiece 20 to the adhesive resin layer (B) of the adhesive film 10 which is attached to the support member 30.

[0023] (Process Y2) In process Y2, the workpiece 20, which is temporarily fixed to the adhesive film 10, is processed. The content of the processing applied to the workpiece 20 is not particularly limited. In Figure 1, the workpiece 20 is the workpiece 40 after processing. The processing applied to the workpiece 20 may be, for example, the sealing of electronic components with a sealing material. Alternatively, the processing applied to the workpiece 20 may be, for example, the dicing of electronic components using a dicing device. Alternatively, the processing applied to the workpiece 20 may be, for example, the processing of a thin glass substrate, such as forming electronic components on a thin glass substrate.

[0024] (Step Y3) The manufacturing method Y preferably further includes step Y3 after step Y2. In step Y3, the adhesive force of the adhesive resin layer (C) is reduced by applying an external stimulus, thereby peeling the structure 100 from the support member 30.

[0025] For example, after processing the workpiece 20, the support member 30 can be separated from the structure 100 by heating the structure 100 to a temperature of 160°C or higher to reduce the adhesive strength of the adhesive resin layer (C). Specifically, by heating the structure 100, the thermally expandable microspheres in the adhesive resin layer (C) of the adhesive film 10 are foamed, thereby reducing the adhesive strength.

[0026] Furthermore, manufacturing method Y may include additional steps other than steps Y1 to Y3, as needed.

[0027] Next, we will explain manufacturing method Y using a specific example (manufacturing method Ya). Manufacturing method Ya is a manufacturing method Y in which the processing applied to the workpiece 20 is the sealing of an electronic component 24 with a sealing material 50.

[0028] [Manufacturing Method Ya] Manufacturing method Ya includes, for example, the following two steps: (1) A step of preparing a structure 400 including an adhesive film 10 and an electronic component 24 temporarily fixed to the adhesive film 10 (step Y1a) (2) A step of sealing the electronic component 24 with a sealing material 50 (step Y2a)

[0029] The following describes each step of manufacturing method Ya, with reference to Figures 2 and 3.

[0030] (Step Y1a) In step Y1a, a structure 400 is prepared, comprising an adhesive film 10, an electronic component 24 temporarily fixed to an adhesive resin layer (B), and a support substrate 31 temporarily fixed to an adhesive resin layer (C). The structure 400 can be manufactured, for example, by attaching the electronic component 24 to the adhesive resin layer (B) of the adhesive film 10. Step Y1a corresponds to step Y1 of manufacturing method Y.

[0031] (Process Y2a) In process Y2a, the electronic component 24, which has been temporarily fixed to the adhesive film 10, is sealed with a sealing material 50. For example, the electronic component 24 can be sealed by curing the sealing material 50 at a temperature of 150°C or lower while the electronic component 24 is covered with the sealing material 50. Process Y2a corresponds to process Y2 of manufacturing method Y.

[0032] The sealing material 50 is not particularly limited, but for example, it is an epoxy resin-based sealing material using epoxy resin. The form of the sealing material 50 is also not particularly limited, but for example, it is granular, sheet-like, or liquid. In particular, the sealing material 50 is preferably a liquid epoxy resin-based sealing material from the viewpoint of improving the affinity between the adhesive film 10 and the sealing material 50 and reducing uneven sealing of the electronic components 24. Examples of such epoxy resin-based sealing materials include the T693 / R4000 series, T693 / R1000 series, T693 / R5000 series, etc., manufactured by Nagase ChemteX Corporation.

[0033] As the sealing method, for example, transfer molding, injection molding, compression molding, casting molding, etc. can be mentioned.

[0034] (Step Y3a) The manufacturing method Ya preferably further includes step Y3a after step Y2a. In step Y3a, by applying an external stimulus, the adhesive force of the adhesive resin layer (C) is reduced, and the support substrate 31 is peeled off from the structure 400. The support substrate 31 can be separated from the adhesive film 10, for example, by heating to a temperature of 160°C or higher after sealing the electronic component 24 to reduce the adhesive force of the adhesive resin layer (C).

[0035] (Step Y4a) The manufacturing method Ya preferably further includes step Y4a after step Y3a. In step Y4a, the adhesive film 10 is peeled off from the electronic component 24 sealed with the sealing material 50 to obtain the electronic device 500. As the method for peeling the adhesive film 10 from the electronic component 24 sealed with the sealing material 50, for example, a method of mechanically peeling, a method of peeling after reducing the adhesive force on the surface of the adhesive film 10, etc. can be mentioned.

[0036] (Step Y5a) The manufacturing method Ya preferably further includes step Y5a between step Y1a and step Y2a. In step Y5a, the structure 400 obtained in step Y1a is heated. Thereby, in the adhesive film 10, the adhesive force of the adhesive resin layer (B) with respect to the electronic component 24 can be improved. As a result, when the electronic component 24 is sealed with the sealing material 50 in the sealing step Y2a, it is possible to reduce the displacement of the position of the electronic component 24 due to the pressure caused by the flow of the sealing material 50 or the outgas derived from moisture.

[0037] In step Y5a, the upper limit temperature when heating the structure 400 is not particularly limited as long as it can improve the adhesive strength of the adhesive resin layer (B) to the electronic component 24, but it is preferably less than 160°C, more preferably 155°C or less, and even more preferably 150°C or less. Thereby, the rapid generation of outgassing derived from moisture contained in the adhesive film 10 can be reduced. As a result, in steps Y5a and Y2a, it is possible to further reduce the displacement of the position of the electronic component 24 due to outgassing derived from moisture. Further, when the temperature when heating the structure 400 is less than or equal to the above upper limit value, the thermal expansion of the thermally expandable microspheres in the adhesive resin layer (C) is reduced, so that the reduction in the adhesive strength of the adhesive film 10 to the support substrate 31 is reduced. As a result, in step Y2a of sealing the electronic component 24, it is possible to reduce the peeling of the adhesive film 10 from the support substrate 31.

[0038] In step Y5a, the lower limit temperature when heating the structure 400 is not particularly limited as long as it can improve the adhesive strength of the adhesive resin layer (B) to the electronic component 24, but it is preferably 70°C or higher, more preferably 80°C or higher, even more preferably 90°C or higher, and even more preferably 100°C or higher. Thereby, the heating time in step Y5a can be shortened. As a result, the manufacturing time of the electronic device 600 can be shortened, and the productivity of the electronic device 600 can be improved.

[0039] The heating time of the structure 400 is not particularly limited as long as it can improve the adhesive strength of the adhesive resin layer (B) to the electronic component 24, but for example, it is 1 minute or more and 120 minutes or less, preferably 5 minutes or more and 80 minutes or less.The method of heating the structure 400 is not particularly limited, and examples thereof include heat treatment methods such as an oven, a dryer, a heating roll, and a drying furnace.

[0040] Whether the adhesive strength of the adhesive resin layer (B) to the electronic component 24 has been improved can be determined, for example, by the shear strength between the electronic component 24 and the adhesive film 10.

[0041] (Step Y6a) The manufacturing method Ya preferably further includes step Y6a after step Y4a. In step Y6a, a wiring layer 510 and bumps 520 are formed on the exposed surface of the obtained electronic device 500.

[0042] The wiring layer 510 comprises a pad (not shown), which is an external connection terminal formed on its outermost surface, and wiring (not shown) that electrically connects the electronic component 24 to the pad. The wiring layer 510 can be formed by conventionally known methods and may have a multilayer structure.

[0043] The electronic device 500 can then be manufactured by forming bumps 520 on the pads of the wiring layer 510. Examples of bumps 520 include solder bumps and gold bumps. Solder bumps can be formed, for example, by placing solder balls on the pads which are external connection terminals of the wiring layer 510 and heating them to melt the solder (reflow). Gold bumps can be formed by methods such as ball bonding, plating, and Au ball transfer.

[0044] (Step Y7a) The manufacturing method Ya preferably further includes step Y7a after step Y6a. In step Y7a, multiple electronic devices 600 can be manufactured by dicing the electronic device 500. A known method can be used for dicing the electronic device 500.

[0045] <Applications of the Method for Manufacturing Electronic Devices> The method for manufacturing electronic devices of this embodiment can improve the holding force of the object, and therefore its applications are not particularly limited and can be used in the manufacturing of electronic devices that include a step of temporarily fixing various objects. Here, in this specification, "object" means an object that is temporarily fixed by an adhesive film. The object includes, for example, one or more selected from the group consisting of a workpiece and a support member. Here, in this specification, "workpiece" means an object that is processed while it is temporarily fixed to another object by an adhesive film. Also, in this specification, a support member means a member that temporarily fixes the workpiece with an adhesive film. The workpiece includes, for example, one or more selected from the group consisting of an electronic component and a substrate.

[0046] Examples of electronic components include semiconductor chips, semiconductor panels, semiconductor packages, electrical elements, display devices, thermal heads, and solar cells. Examples of semiconductor chips include ICs, LSIs, discrete components, light-emitting diodes, and photodetectors. Examples of electrical elements include ceramic capacitors and oscillators. Examples of semiconductor packages include fan-out type packages.

[0047] Examples of substrates include semiconductor substrates, package substrates in which multiple semiconductor chips are encapsulated together with a sealing resin, printed circuit boards (multilayer ceramic sheets), green sheets for multilayer ceramic capacitors, and thin glass substrates. Examples of semiconductor substrates include silicon substrates, germanium substrates, gallium-arsenide substrates, gallium-phosphorus substrates, and gallium-arsenide-aluminum substrates. Preferably, the semiconductor substrate includes a semiconductor substrate on which circuits are formed on the surface. Examples of package substrates in which multiple semiconductor chips are encapsulated together with a sealing resin include mold array package substrates, fan-out type package substrates, and wafer-level package substrates. Examples of thin glass substrates include glass substrates having a thickness of 10 μm to 150 μm.

[0048] The support member is not particularly limited as long as it can hold the workpiece with an adhesive film. Examples of support members include support substrates and support bases. Examples of support substrates include silicon substrates, glass substrates, SUS substrates, copper substrates, and acrylic substrates.

[0049] The adhesive film of this embodiment can temporarily fix at least one of electronic components and substrates. Furthermore, the adhesive film of this embodiment can be applied to one or more types selected from the group consisting of, for example, tapes for temporarily fixing electronic components, tapes for processing substrates, dicing tapes, backgrinding tapes, and surface protection tapes.

[0050] The adhesive film of this embodiment can be used as a temporary fixing tape for electronic components, for example, to manufacture an electronic device including a fan-out type package. In this case, the electronic device of this embodiment includes a semiconductor package. The semiconductor package includes, for example, a fan-out type package. The adhesive film of this embodiment may also be used as a temporary fixing tape for electronic components to temporarily fix other types of electronic components.

[0051] Furthermore, the adhesive film of this embodiment can be used as a dicing tape, for example, to temporarily fix electronic components in the dicing process of electronic components. Examples of electronic component dicing processes include the dicing process of semiconductor packages; the dicing process of electrical elements such as ceramic capacitors; and the dicing process of other electronic components such as semiconductor chips, semiconductor panels, display devices, thermal heads, and solar cells.

[0052] Furthermore, the adhesive film of this embodiment can be used as a backgrind tape, for example, to temporarily fix electronic components in the backgrinding process of electronic components.

[0053] Furthermore, the adhesive film of this embodiment can be used as a substrate processing tape, for example, to temporarily fix a thin glass substrate in the processing step of a thin glass substrate. Note that the substrate processing tape is not limited to thin glass substrates and may be used in the processing steps of other types of substrates.

[0054] Furthermore, the adhesive film of this embodiment can be used as a surface protection tape, for example, to protect the surface of an object.

[0055] <Structure of the Adhesive Film> Next, the thermally expandable microspheres and each layer that constitute the adhesive film used in the manufacturing method of the electronic device of this embodiment will be described.

[0056] [Thermally Expandable Microspheres] Thermally expandable microspheres are, for example, tiny spherical resin compositions that expand upon heating. The thermally expandable microspheres of this embodiment include, for example, a thermoplastic resin, a volatile expanding agent, and other additives.

[0057] A thermally expandable microsphere preferably comprises a shell and a volatile expanding agent within the shell. More preferably, the thermally expandable microsphere has a structure in which the volatile expanding agent is contained within the space inside the shell. With such a structure, for example, when heated, the volatile expanding agent volatilizes and turns into a gas, causing the shell to expand.

[0058] The shell preferably includes a thermoplastic resin as the material for forming the shell. The thermoplastic resin used as the material for forming the shell includes, for example, one or more selected from the group consisting of vinylidene chloride-acrylonitrile copolymer, polyvinyl alcohol, polyvinyl butyral, polymethyl methacrylate, polyacrylonitrile, polyvinylidene chloride, and polysulfone.

[0059] A volatile expanding agent is, for example, a substance that turns into a gas when heated. The volatile expanding agent includes, for example, one or more selected from the group consisting of ethane, ethylene, propane, propene, n-butane, isobutane, butene, isobutene, n-pentane, isopentane, neopentane, n-hexane, heptane, and petroleum ether. From the viewpoint of being able to improve the foaming rate of the thermally expandable microspheres, the volatile expanding agent preferably includes one or more selected from the group consisting of propane, n-butane, isobutane, n-pentane, isopentane, and neopentane.

[0060] Thermally expandable microspheres can be manufactured, for example, by coacervation, interfacial polymerization, or the like.

[0061] The sphericity R of the thermally expandable microspheres of the present embodiment is 0.93 or more, preferably 0.94 or more, more preferably 0.95 or more, from the viewpoint of improving the holding force of the object. The upper limit of the sphericity R is not particularly limited, but for example, it may be less than 1.00, may be 0.99 or less, may be 0.98 or less, or may be 0.97 or less. The sphericity R of the thermally expandable microspheres of the present embodiment is 0.93 or more and less than 1.00, preferably 0.94 or more and 0.99 or less, more preferably 0.95 or more and 0.98 or less, and still more preferably 0.95 or more and 0.97 or less, from the viewpoint of improving the holding force of the object.

[0062] The sphericity R can be adjusted, for example, by adjusting the type of thermally expandable microspheres, the pretreatment method of thermally expandable microspheres, and the like. In addition, specifically, the method described in the examples can be adopted as the method for calculating the sphericity R.

[0063] In the cumulative frequency distribution curve based on volume of the thermally expandable microspheres measured by a laser diffraction / scattering particle size distribution analyzer, the particle diameter D at the time when the cumulative frequency is 50% ５０ is preferably 1 μm or more and 30 μm or less, more preferably 5 μm or more and 25 μm or less, and still more preferably 10 μm or more and 20 μm or less, from the viewpoint of improving the peelability of the adhesive film. The measurement method of the particle diameter D ５０ can specifically adopt the method described in the examples.

[0064] In the cumulative frequency distribution curve based on volume of the thermally expandable microspheres measured by a laser diffraction / scattering particle size distribution analyzer, the particle diameter D at the time when the cumulative frequency is 99.9% ９９．９ is preferably 10 μm or more and 50 μm or less, more preferably 20 μm or more and 45 μm or less, and still more preferably 30 μm or more and 40 μm or less, from the viewpoint of improving the peelability of the adhesive film. The measurement method of the particle diameter D ９９．９ can specifically adopt the method described in the examples.

[0065] The foaming temperature of the thermally expandable microspheres is preferably 160°C or higher, more preferably 165°C or higher, even more preferably 170°C or higher, even more preferably 175°C or higher, and even more preferably 180°C or higher, from the viewpoint of facilitating the formation of the adhesive resin layer (C) containing the thermally expandable microspheres. The upper limit of the foaming temperature of the thermally expandable microspheres is not particularly limited, but may be, for example, 300°C or lower, 275°C or lower, 250°C or lower, 225°C or lower, or 200°C or lower. The foaming temperature of the thermally expandable microspheres is preferably 160°C or higher and 300°C or lower, more preferably 165°C or higher and 275°C or lower, even more preferably 170°C or higher and 250°C or lower, even more preferably 175°C or higher and 225°C or lower, and even more preferably 180°C or higher and 200°C or lower, from the viewpoint of facilitating the formation of the adhesive resin layer (C) containing the thermally expandable microspheres.

[0066] [Base layer (A)] The base layer (A) is a layer provided for the purpose of improving the handling properties, mechanical properties, heat resistance, and other properties of the adhesive film. The base layer (A) is not particularly limited, but an example is a resin film. The base layer (A) has a first surface A1 and a second surface A2 which is the surface opposite to the first surface A1.

[0067] The resins constituting the resin film include, for example, thermoplastic resins. The resins constituting the resin film include, for example, one or more selected from the group consisting of polyolefins, polyesters, polyamides, poly(meth)acrylates, polyvinyl chloride, polyvinylidene chloride, polyimides, polyetherimides, ethylene-vinyl acetate copolymers, polyacrylonitriles, polycarbonates, polystyrenes, ionomers, polysulfones, polyethersulfones, polyphenylene ethers, and aromatic polyetherketones. Polyolefins include, for example, one or more selected from the group consisting of polyethylene, polypropylene, poly(4-methyl-1-pentene), and poly(1-butene). Polyesters include, for example, one or more selected from the group consisting of polyethylene terephthalate, polybutylene terephthalate, and polyethylene naphthalate. Polyamides include, for example, one or more selected from the group consisting of nylon-6, nylon-66, and polymetaxylene adipamide. Aromatic polyether ketones include, for example, one or more selected from the group consisting of polyether ketone (PEK), polyether ether ketone (PEEK), polyether ketone ketone (PEKK), polyether ether ketone ketone (PEEKK), and polyether ketone esters.

[0068] The resin constituting the resin film preferably comprises one or more selected from the group consisting of polypropylene, polyethylene terephthalate, polyethylene naphthalate, polyamide, polyimide, and polyetheretherketone, from the viewpoint of improving the balance of transparency, mechanical strength, and price, more preferably comprising one or more selected from the group consisting of polyethylene terephthalate and polyethylene naphthalate, and even more preferably comprising polyethylene terephthalate.

[0069] The base layer (A) may be a single layer or two or more layers. The resin film used to form the base layer (A) is, for example, a stretched film, and is preferably a film stretched in one or two axes from the viewpoint of improving the mechanical strength of the base layer (A).

[0070] From the viewpoint of improving film properties, the thickness of the substrate layer (A) is preferably 1 μm to 500 μm, more preferably 5 μm to 400 μm, even more preferably 10 μm to 300 μm, even more preferably 20 μm to 200 μm, even more preferably 25 μm to 100 μm, even more preferably 30 μm to 50 μm, and even more preferably 35 μm to 45 μm.

[0071] [Adhesive Resin Layer (B)] The adhesive film of this embodiment may further comprise an adhesive resin layer (B). The adhesive resin layer (B) is a layer located on one side (first surface A1 side) of the base layer (A). The adhesive resin layer (B) is, for example, a layer for temporarily fixing an object by contacting its surface. The adhesive resin layer (B) can, for example, temporarily fix at least one of the workpiece and the support member.

[0072] The adhesive resin (B1) constituting the adhesive resin layer (B) preferably includes one or more selected from the group consisting of (meth)acrylic adhesive resins, silicone adhesive resins, urethane adhesive resins, olefin adhesive resins, and styrene adhesive resins, from the viewpoint of improving the balance between adhesive strength and heat resistance. The adhesive resin (B1) constituting the adhesive resin layer (B) more preferably includes a (meth)acrylic adhesive resin, from the viewpoint of easily adjusting the adhesive strength.

[0073] As the adhesive resin layer (B), for example, a radiation-crosslinked adhesive resin layer whose adhesive strength can be reduced by radiation can be used. The radiation-crosslinked adhesive resin layer (B) becomes easier to peel off the adhesive film from the object because its adhesive strength decreases due to crosslinking upon irradiation with radiation. Examples of radiation include ultraviolet rays, electron beams, and infrared rays. As the radiation-crosslinked adhesive resin layer, an ultraviolet-crosslinked adhesive resin layer is preferred.

[0074] The adhesive resin layer (B) preferably further contains, in addition to the adhesive resin (B1), a crosslinking agent (B2) having two or more crosslinkable functional groups in one molecule. The crosslinking agent (B2) is used to react with the functional groups of the adhesive resin (B1) to adjust the adhesive strength and cohesive strength of the adhesive resin layer (B).

[0075] The crosslinking agent (B2) includes, for example, one or more selected from the group consisting of epoxy crosslinking agents, isocyanate crosslinking agents, aziridine crosslinking agents, tetrafunctional epoxy crosslinking agents, and melamine crosslinking agents, and preferably includes one or more selected from the group consisting of epoxy crosslinking agents, isocyanate crosslinking agents, and aziridine crosslinking agents.

[0076] From the viewpoint of improving the balance between the adhesive strength and heat resistance performance of the adhesive resin layer (B), the content of the crosslinking agent (B2) in the adhesive resin layer (B) is preferably 0.1 parts by mass or more and 15 parts by mass or less, more preferably 1 part by mass or more and 12 parts by mass or less, even more preferably 3 parts by mass or more and 10 parts by mass or less, and even more preferably 5 parts by mass or more and 8 parts by mass or less, when the content of the adhesive resin (B1) in the adhesive resin layer (B) is 100 parts by mass.

[0077] From the viewpoint of improving the balance between adhesive strength and heat resistance, the total content of the adhesive resin (B1) and crosslinking agent (B2) in the adhesive resin layer (B) is preferably 50% to 100% by mass, more preferably 70% to 100% by mass, even more preferably 90% to 100% by mass, and even more preferably 95% to 100% by mass, when the total amount of the adhesive resin layer (B) is 100% by mass.

[0078] In the adhesive film of this embodiment, when the adhesive strength of the adhesive resin layer (C) is reduced by heat treatment and the support member is peeled off from the adhesive resin layer (C), the content of thermally expandable microspheres in the adhesive resin layer (B) is preferably 0.1% by mass or less, more preferably 0.05% by mass or less, even more preferably 0.01% by mass or less, and even more preferably 0% by mass, when the total amount of the adhesive resin layer (B) is 100% by mass.

[0079] The thickness of the adhesive resin layer (B) is preferably 1 μm to 40 μm, more preferably 2 μm to 30 μm, even more preferably 3 μm to 25 μm, even more preferably 4 μm to 20 μm, and even more preferably 5 μm to 15 μm, from the viewpoint of improving the balance between adhesive strength and heat resistance.

[0080] The adhesive resin layer (B) can be formed, for example, by applying an adhesive onto the substrate layer (A). The adhesive may be dissolved in a solvent and applied as a coating solution, applied as an aqueous emulsion, or applied directly as a liquid adhesive. The substrate layer (A) and the adhesive resin layer (B) may be formed by co-extrusion molding, or by laminating (layering) a film-like substrate layer (A) and a film-like adhesive resin layer (B).

[0081] [Adhesive resin layer (C)] The adhesive resin layer (C) is a layer located on the second surface A2 side of the base layer (A). Preferably, the adhesive resin layer (C) is a layer whose adhesive strength decreases with heat treatment. This allows the adhesive film to be peeled off the object by heat treatment.

[0082] The adhesive resin layer (C) of this embodiment includes thermally expandable microspheres, from the viewpoint of improving thermal release properties.

[0083] In the adhesive resin layer (C) of this embodiment, the temperature at which the adhesive strength decreases or is lost is preferably 160°C or higher, more preferably 165°C or higher, even more preferably 170°C or higher, even more preferably 175°C or higher, and even more preferably 180°C or higher. Such an adhesive resin layer (C) can be formed by selecting the type of thermally expandable microspheres in the adhesive resin layer (C).

[0084] Here, the decrease or loss of adhesive strength due to heating at a temperature of 160°C or higher can be evaluated, for example, by the following (Method for Evaluating Decrease in Adhesion Strength). In this specification, loss of adhesive strength means, for example, when the 180° peel strength measured under conditions of 23°C and a tensile speed of 300 mm / min becomes less than 0.5 N / 25 mm. (Method for Evaluating Decrease in Adhesion Strength) The adhesive resin layer (C) side of the adhesive film is attached to a stainless steel plate and heat-treated at 140°C for 1 hour. Next, it is heated at a temperature of 160°C or higher for 2 minutes. After heating, the peel strength of the adhesive film from the stainless steel plate is measured. The specific heating temperature when heating at a temperature of 160°C or higher is appropriately set depending on the type of gas generated, the type of thermally expandable microspheres, the temperature at which the gas is generated, and the temperature at which the thermally expandable microspheres expand (foaming temperature).

[0085] From the viewpoint of improving thermal release properties, the content of thermally expandable microspheres in the adhesive resin layer (C) is preferably 5% to 50% by mass, more preferably 6% to 45% by mass, even more preferably 7% to 40% by mass, even more preferably 8% to 35% by mass, even more preferably 9% to 30% by mass, and even more preferably 10% to 25% by mass, when the total amount of the adhesive resin layer (C) is 100% by mass.

[0086] From the viewpoint of improving thermal release properties, the content of thermally expandable microspheres in the adhesive resin layer (C) is preferably 1 to 150 parts by mass, more preferably 3 to 100 parts by mass, even more preferably 5 to 50 parts by mass, even more preferably 8 to 40 parts by mass, even more preferably 10 to 30 parts by mass, and even more preferably 12 to 28 parts by mass, when the content of adhesive resin (C1) in the adhesive resin layer (C) is 100 parts by mass.

[0087] The adhesive resin (C1) constituting the adhesive resin layer (C) includes, for example, one or more types selected from the group consisting of (meth)acrylic adhesive resins, silicone adhesive resins, urethane adhesive resins, olefin adhesive resins, polyester adhesive resins, polyamide adhesive resins, fluorine adhesive resins, and styrene adhesive resins.

[0088] The adhesive resin (C1) constituting the adhesive resin layer (C) preferably includes one or more selected from the group consisting of (meth)acrylic adhesive resins, silicone adhesive resins, urethane adhesive resins, olefin adhesive resins, and styrene adhesive resins, from the viewpoint of improving thermal release properties. The adhesive resin (C1) constituting the adhesive resin layer (C) more preferably includes a (meth)acrylic adhesive resin, from the viewpoint of easily adjusting the adhesive strength.

[0089] Examples of the (meth)acrylic adhesive resin (c) used in the adhesive resin layer (C) include copolymers comprising a constituent unit (c1) of an alkyl (meth)acrylate and a constituent unit (c2) having a functional group that can react with a crosslinking agent (C2).

[0090] (Meth)acrylic adhesive resin (c) can be produced, for example, by copolymerizing a monomer that forms a constituent unit (c1) of an alkyl (meth)acrylate (hereinafter also referred to as monomer (c1)) and a monomer that forms a constituent unit (c2) having a functional group that can react with a crosslinking agent (C2) (hereinafter also referred to as monomer (c2)).

[0091] The monomer (c1) preferably comprises one or more selected from the group consisting of an alkyl (meth)acrylate having an alkyl group having about 1 to 12 carbon atoms, more preferably an alkyl (meth)acrylate having an alkyl group having 1 to 8 carbon atoms, and even more preferably one or more selected from the group consisting of methyl (meth)acrylate, ethyl (meth)acrylate, butyl (meth)acrylate, and 2-ethylhexyl (meth)acrylate.

[0092] The content of constituent unit (c1) in the (meth)acrylic adhesive resin (c) is preferably 10% by mass or more and 99% by mass or less, more preferably 50% by mass or more and 97% by mass or less, and even more preferably 85% by mass or more and 95% by mass or less, when the total amount of the (meth)acrylic adhesive resin (c) is 100% by mass.

[0093] The monomer (c2) includes, for example, one or more selected from the group consisting of (meth)acrylic acid, itaconic acid, mesaconic acid, citraconic acid, fumaric acid, maleic acid, monoalkyl itaconic acid, monoalkyl mesaconic acid, monoalkyl citraconic acid, monoalkyl fumaric acid, monoalkyl maleic acid, glycidyl (meth)acrylate, 2-hydroxyethyl (meth)acrylate, (meth)acrylamide, and t-butylaminoethyl (meth)acrylate. Preferably, the monomer (c2) includes one or more selected from the group consisting of (meth)acrylic acid, 2-hydroxyethyl (meth)acrylate, and (meth)acrylamide.

[0094] The content of constituent units (c2) in the (meth)acrylic adhesive resin (c) is preferably 1% by mass or more and 40% by mass or less, more preferably 3% by mass or more and 20% by mass or less, and even more preferably 5% by mass or more and 15% by mass or less, when the total amount of the (meth)acrylic adhesive resin (c) is 100% by mass.

[0095] Polymerization reaction mechanisms for (meth)acrylic adhesive resin (c) include radical polymerization, anionic polymerization, and cationic polymerization. From the viewpoint of the manufacturing cost of (meth)acrylic adhesive resin (c), the influence of the functional groups of the monomer, and the influence of ions on the surface of the target object, radical polymerization is preferred as the polymerization reaction mechanism for (meth)acrylic adhesive resin (c).

[0096] The radical polymerization initiator includes, for example, one or more selected from the group consisting of organic peroxides, inorganic peroxides, and azo compounds. The organic peroxide includes, for example, one or more selected from the group consisting of benzoyl peroxide, di-t-butyl peroxide, dicumyl peroxide, 3,3,5-trimethylhexanoyl peroxide, di-2-ethylhexyl peroxydicarbonate, methyl ethyl ketone peroxide, t-butyl peroxyphthalate, t-butyl peroxybenzoate, di-t-butyl peroxyacetate, t-butyl peroxyisobutyrate, t-butyl peroxy-2-hexanoate, t-butyl peroxy-2-ethylhexanoate, t-butyl peroxy-3,5,5-trimethylhexanoate, acetyl peroxide, isobutyryl peroxide, octanoyl peroxide, t-butyl peroxide, and di-t-amyl peroxide. The inorganic peroxide includes, for example, one or more selected from the group consisting of ammonium persulfate, potassium persulfate, and sodium persulfate. The azo compound includes, for example, one or more selected from the group consisting of 2,2'-azobisisobutyronitrile, 2,2'-azobis-2-methylbutyronitrile, and 4,4'-azobis-4-cyanovaleric acid.

[0097] The radical polymerization initiator in the (meth)acrylic adhesive resin (c) preferably includes an organic peroxide, more preferably t-butylperoxy-2-ethylhexanoate, from the viewpoint of improving the balance between the adhesive strength and heat resistance performance of the adhesive resin layer (C).

[0098] The adhesive resin layer (C) further comprises an adhesive resin (C1) and preferably a crosslinking agent (C2) having two or more crosslinkable functional groups per molecule. The crosslinking agent (C2) is used to react with the functional groups of the adhesive resin (C1) to adjust the adhesive strength and cohesive strength of the adhesive resin layer (C).

[0099] The crosslinking agent (C2) includes, for example, one or more selected from the group consisting of epoxy crosslinking agents, isocyanate crosslinking agents, aziridine crosslinking agents, tetrafunctional epoxy crosslinking agents, and melamine crosslinking agents. The epoxy crosslinking agent includes, for example, one or more selected from the group consisting of sorbitol polyglycidyl ether, polyglycerol polyglycidyl ether, pentaerythritol polyglycidyl ether, diglycerol polyglycidyl ether, glycerol polyglycidyl ether, neopentyl glycol diglycidyl ether, and resolcin diglycidyl ether. The isocyanate crosslinking agent includes, for example, one or more selected from the group consisting of tetramethylene diisocyanate, hexamethylene diisocyanate, trimethylolpropane toluene diisocyanate 3 adduct, polyisocyanate, diphenylmethane diisocyanate, and tolylene diisocyanate. Aziridine crosslinking agents include, for example, one or more selected from the group consisting of trimethylolpropane-tri-β-aziridinylpropionate, tetramethylolmethane-tri-β-aziridinylpropionate, N,N'-diphenylmethane-4,4'-bis(1-aziridinecarboxamide), N,N'-hexamethylene-1,6-bis(1-aziridinecarboxamide), N,N'-toluene-2,4-bis(1-aziridinecarboxamide), and trimethylolpropane-tri-β-(2-methylaziridine)propionate. Tetrafunctional epoxy crosslinking agents include, for example, one or more selected from the group consisting of N,N,N',N'-tetraglycidyl-m-xylenediamine and 1,3-bis(N,N'-diglycidylaminomethyl)cyclohexane. Melamine-based crosslinking agents include, for example, hexamethoxymethylolmelamine.

[0100] In the adhesive resin layer (C), the crosslinking agent (C2) preferably includes one or more selected from the group consisting of epoxy crosslinking agents, isocyanate crosslinking agents, and aziridine crosslinking agents, from the viewpoint of improving the balance between adhesive strength and thermal release properties.

[0101] The crosslinking agent (C2) content in the adhesive resin layer (C) is preferably within a range where the number of functional groups in the crosslinking agent (C2) does not exceed the number of functional groups in the adhesive resin (C1). However, it may be included in excess as needed, such as when new functional groups are generated in the crosslinking reaction or when the crosslinking reaction is slow. From the viewpoint of improving the balance between adhesive strength and thermal release properties, the lower limit of the crosslinking agent (C2) content in the adhesive resin layer (C) is preferably 0.1 parts by mass or more, more preferably 1 part by mass or more, and even more preferably 2 parts by mass or more, when the adhesive resin (C1) content in the adhesive resin layer (C) is 100 parts by mass. Furthermore, from the viewpoint of improving storage stability, the upper limit of the crosslinking agent (C2) content in the adhesive resin layer (C) is preferably 10 parts by mass or less, more preferably 5 parts by mass or less, and even more preferably 4 parts by mass or less, when the adhesive resin (C1) content in the adhesive resin layer (C) is 100 parts by mass.

[0102] The adhesive resin layer (C) preferably further contains a tackifying resin (C3) from the viewpoint of improving adhesive strength. Including the tackifying resin (C3) in the adhesive resin layer (C) makes it easier to adjust the adhesion to the object at or near room temperature.

[0103] The tackifying resin (C3) includes, for example, one or more selected from the group consisting of rosin resins, terpene resins, natural rosin resins, petroleum resins, and coumarone-indene resins. Rosin resins include, for example, rosin derivatives that have undergone treatment such as esterification. Terpene resins include, for example, one or more selected from the group consisting of α-pinene resins, β-pinene resins, dipentene resins, and terpene phenol resins. Natural rosin resins include one or more selected from the group consisting of gum resins, wood resins, and tall oil resins. Petroleum resins include, for example, resins obtained by hydrogenating, disproportionating, polymerizing, or maleating natural rosin resins.

[0104] In the adhesive resin layer (C) of this embodiment, the softening point of the tackifying resin (C3) is preferably 100°C to 160°C, more preferably 120°C to 150°C, from the viewpoint of reducing contamination of the target object and improving adhesion to the target object.

[0105] From the viewpoint of improving adhesion to the object during work, the content of the tackifying resin (C3) in the adhesive resin layer (C) is preferably 1 part by mass or more, more preferably 2 parts by mass or more, even more preferably 3 parts by mass or more, and even more preferably 4 parts by mass or more, when the content of the adhesive resin (C1) in the adhesive resin layer (C) is 100 parts by mass. From the viewpoint of improving the balance between adhesion to the object and adhesiveness at room temperature, the content of the tackifying resin (C3) in the adhesive resin layer (C) is preferably 100 parts by mass or less, more preferably 50 parts by mass or less, even more preferably 25 parts by mass or less, and even more preferably 10 parts by mass or less, when the content of the adhesive resin (C1) in the adhesive resin layer (C) is 100 parts by mass.

[0106] The adhesive resin layer (C) may also contain additives such as plasticizers as other components.

[0107] The lower limit of the total content of adhesive resin (C1), crosslinking agent (C2), tackifying resin (C3), and thermally expandable microspheres in the adhesive resin layer (C) is preferably 50% by mass or more, more preferably 70% by mass or more, even more preferably 90% by mass or more, and even more preferably 95% by mass or more, when the total amount of the adhesive resin layer (C) is 100% by mass. The upper limit is not particularly limited, but for example, it is 100% by mass or less.

[0108] The adhesive resin layer (C) may be a single layer or a multi-layer layer.

[0109] The thickness of the adhesive resin layer (C) is preferably 10 μm or more, more preferably 15 μm or more, even more preferably 20 μm or more, and even more preferably 25 μm or more, from the viewpoint of improving the balance of adhesiveness and heat release properties. The thickness of the adhesive resin layer (C) is preferably 100 μm or less, more preferably 75 μm or less, even more preferably 50 μm or less, and even more preferably 40 μm or less, from the viewpoint of improving the handlingability of the adhesive film 10. The thickness of the adhesive resin layer (C) is preferably 10 μm or more and 100 μm or less, more preferably 15 μm or more and 75 μm or less, even more preferably 20 μm or more and 50 μm or less, and even more preferably 25 μm or more and 40 μm or less, from the viewpoint of improving the balance of adhesiveness, heat release properties, and handling properties.

[0110] The adhesive resin layer (C) can be formed, for example, by applying an adhesive coating solution onto the substrate layer (A), or by transferring the adhesive resin layer (C) formed on the separator onto the substrate layer (A). Examples of methods for applying the adhesive coating solution include the roll coater method, the reverse roll coater method, the gravure roll method, the bar coat method, the comma coater method, and the die coater method.

[0111] There are no particular restrictions on the drying conditions for the applied adhesive, but for example, it may be dried at 80 to 170°C for 15 seconds to 5 minutes. In order to sufficiently promote the crosslinking reaction between the crosslinking agent and the adhesive, the adhesive coating solution may be heated at 40 to 80°C for about 5 to 300 hours after the drying is complete.

[0112] The base material layer (A) and the adhesive resin layer (C) may be formed by co-extrusion molding, or they may be formed by laminating (layering) a film-like base material layer (A) and a film-like adhesive resin layer (C).

[0113] [Intermediate layer (D)] The adhesive film of this embodiment may further include an intermediate layer (D). The intermediate layer (D) is a layer provided as, for example, a surface-absorbing resin layer, an impact-absorbing layer, an anchor coat layer, etc.

[0114] The intermediate layer (D) preferably contains a thermoplastic resin. When the adhesive film of this embodiment is used, for example, as a tape for temporarily fixing electronic components, the intermediate layer (D) more preferably contains one or more selected from the group consisting of polyolefin resins, polystyrene resins, (meth)acrylic resins, urethane resins, silicone resins, polyester resins, polyamide resins, and fluororesins, and even more preferably contains one or more selected from the group consisting of polyolefin resins, polystyrene resins, and (meth)acrylic resins.

[0115] When the adhesive film of this embodiment is used, for example, as a tape for temporarily fixing electronic components, the thickness of the intermediate layer (D) is preferably 5 μm to 100 μm, more preferably 10 μm to 50 μm, and even more preferably 15 μm to 25 μm, from the viewpoint of improving the ability of the adhesive film to absorb unevenness.

[0116] The intermediate layer (D) preferably contains a thermoplastic resin. When the adhesive film of this embodiment is used, for example, as a dicing tape, the intermediate layer (D) more preferably contains one or more selected from the group consisting of olefin resins, ethylene-(meth)acrylic acid ester copolymers, ethylene-vinyl ester copolymers, polyvinyl chloride, polyvinylidene chloride, polyolefin-based thermoplastic elastomers, polystyrene-based thermoplastic elastomers, polyurethane-based thermoplastic elastomers, 1,2-polybutadiene-based thermoplastic elastomers, trans-polyisoprene-based thermoplastic elastomers, chlorinated polyethylene-based thermoplastic elastomers, and polyester-based elastomers. Olefin resins include, for example, one or more selected from the group consisting of ethylene resins, propylene polymers, 1-butene polymers, 4-methyl-1-pentene polymers, ethylene-α-olefin copolymers, ethylene-cyclic olefin copolymers, ethylene-α-olefin-cyclic olefin copolymers, ethylene-α-olefin-unconjugated polyene copolymers, ethylene-α-olefin-conjugated polyene copolymers, ethylene-aromatic vinyl copolymers, ethylene-α-olefin-aromatic vinyl copolymers, and copolymers thereof. Furthermore, ethylene resins include, for example, one or more selected from the group consisting of high-density polyethylene resins (HDPE), medium-density polyethylene resins (MDPE), low-density polyethylene resins (LDPE), ultra-low-density polyethylene resins (ULDPE), and linear low-density polyethylene resins (LLDPE). Ethylene-(meth)acrylic acid ester copolymers include, for example, one or more selected from the group consisting of ethylene-(meth)acrylic acid ethyl copolymer, ethylene-(meth)acrylic acid methyl copolymer, ethylene-(meth)acrylic acid propyl copolymer, ethylene-(meth)acrylic acid butyl copolymer, ethylene-(meth)acrylic acid hexyl copolymer, ethylene-(meth)acrylic acid 2-hydroxyethyl copolymer, ethylene-(meth)acrylic acid 2-hydroxypropyl copolymer, and ethylene-(meth)acrylic acid glycidyl copolymer.Ethylene vinyl ester copolymers include, for example, one or more selected from the group consisting of ethylene vinyl acetate copolymer, ethylene vinyl propionate copolymer, ethylene vinyl butyrate copolymer, and ethylene vinyl stearate copolymer.

[0117] When the adhesive film of this embodiment is used, for example, in a dicing tape, the intermediate layer (D) more preferably comprises one or more selected from the group consisting of ethylene-α-olefin copolymer and ethylene-vinyl ester copolymer, more preferably comprises one or more selected from the group consisting of ethylene-α-olefin copolymer and ethylene-vinyl acetate copolymer, and more preferably comprises ethylene-vinyl acetate copolymer.

[0118] When the adhesive film of this embodiment is used, for example, as a dicing tape, the content of vinyl acetate units in the ethylene-vinyl acetate copolymer in the adhesive film of this embodiment is preferably 10% to 35% by mass, more preferably 12% to 30% by mass, and even more preferably 15% to 25% by mass, when the total amount of the ethylene-vinyl acetate copolymer is 100% by mass, from the viewpoint of improving the balance of crosslinkability, flexibility, weather resistance, and transparency. The vinyl acetate content can be measured, for example, in accordance with JIS K6730:1994.

[0119] When the adhesive film of this embodiment is used, for example, in a dicing tape, the number of carbon atoms in the α-olefin of the ethylene-α-olefin copolymer used as the thermoplastic resin in the adhesive film of this embodiment is preferably 3 to 20, more preferably 3 to 10, and even more preferably 3 to 8. The α-olefin used in the ethylene-α-olefin copolymer includes, for example, one or more selected from the group consisting of propylene, 1-butene, 1-pentene, 1-hexene, 3-methyl-1-butene, 3,3-dimethyl-1-butene, 4-methyl-1-pentene, 1-octene, 1-decene, and 1-dodecene. From the viewpoint of availability, the α-olefin used in the ethylene-α-olefin copolymer preferably includes one or more selected from the group consisting of propylene, 1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, and 1-octene. The ethylene-α-olefin copolymer may be a random copolymer or a block copolymer, but from the viewpoint of flexibility, a random copolymer is preferred.

[0120] The intermediate layer (D) may contain additives such as plasticizers as other components. The intermediate layer (D) may be a single layer or a multilayer layer.

[0121] <Structure of the Adhesive Film> Several examples of the structure of the adhesive film 10 of this embodiment will be described. The adhesive film 10 of this embodiment may have a structure like that shown in Figure 4 or Figure 5 below.

[0122] In the adhesive film 10 of this embodiment, the surface on the side with the adhesive resin layer (C) is in contact with the support member 30. In this case, the workpiece 20 is located on the first surface A1 side of the base material layer (A) of the adhesive film 10, and the support member 30 is located on the second surface A2 side of the base material layer (A). The adhesive film 10 of this embodiment may have a structure as shown in Figures 4 and 5 below, for example.

[0123] The adhesive film 10 in Figure 4 further comprises an adhesive resin layer (B) on the first surface A1 side of the base layer (A). In this case, the base layer (A) is located between the adhesive resin layer (B) and the adhesive resin layer (C).

[0124] In Figure 4, the adhesive film 10 is in contact with the workpiece 20 on the side with the adhesive resin layer (B) and with the support member 30 on the side with the adhesive resin layer (C). The adhesive film 10 in Figure 4 temporarily fixes the workpiece 20 with the adhesive resin layer (B). The adhesive film 10 in Figure 4 is also temporarily fixed to the support member 30 with the adhesive resin layer (C).

[0125] The adhesive film 10 in Figure 4 may further include an intermediate layer (D) selected from at least one of the following: between the base layer (A) and the adhesive resin layer (B), and between the base layer (A) and the adhesive resin layer (C). Note that the intermediate layer (D) is not shown in Figure 4. Furthermore, the adhesive film 10 in Figure 4 may further include an intermediate layer (D) in both the space between the base layer (A) and the adhesive resin layer (B), and between the base layer (A) and the adhesive resin layer (C). In this case, the intermediate layer (D) located between the base layer (A) and the adhesive resin layer (B) may have a different configuration from, or the same configuration as, the intermediate layer (D) located between the base layer (A) and the adhesive resin layer (C).

[0126] The adhesive film 10 in Figure 5 is an example of the adhesive film 10 in Figure 4, in which an intermediate layer (D) is further provided between the base layer (A) and the adhesive resin layer (C).

[0127] <Method for Manufacturing Adhesive Film> Next, an example of a method for manufacturing the adhesive film 10 of this embodiment will be described. The adhesive film 10 of this embodiment can be formed, for example, by applying an adhesive resin layer (C) onto a base layer (A), or by transferring an adhesive resin layer (C) formed on a separator onto the base layer (A). Alternatively, the adhesive film 10 of this embodiment may be formed by laminating (layering) the base layer (A) and the adhesive resin layer (C) in this order. Alternatively, the adhesive film 10 of this embodiment may be formed by co-extrusion molding of the base layer (A) and the adhesive resin layer (C) in this order.

[0128] One method for applying an adhesive resin layer (C) onto a substrate layer (A) is to apply an adhesive coating solution capable of forming an adhesive resin layer (C). Examples of methods for applying the adhesive coating solution include the roll coater method, the reverse roll coater method, the gravure roll method, the bar coat method, the comma coater method, and the die coater method. There are no particular restrictions on the drying conditions of the adhesive coating solution, but it is preferably dried at a temperature range of 80 to 200°C for 10 seconds to 10 minutes, and more preferably at a temperature range of 80 to 170°C for 15 seconds to 5 minutes. In the adhesive coating solution, in order to sufficiently promote the crosslinking reaction between the crosslinking agent and the adhesive resin, the adhesive coating solution may be heated at a temperature range of 40 to 80°C for about 5 to 300 hours after the drying of the adhesive coating solution is completed.

[0129] If the adhesive film 10 of this embodiment further comprises an adhesive resin layer (B), the adhesive film 10 of this embodiment can be formed, for example, by applying the adhesive resin layer (B) and the adhesive resin layer (C) to a base layer (A), or by transferring the adhesive resin layer (B) and the adhesive resin layer (C) formed on a separator to the base layer (A). Alternatively, if the adhesive film 10 of this embodiment comprises an adhesive resin layer (B), the adhesive film 10 of this embodiment may be formed by laminating (layering) the adhesive resin layer (B), the base layer (A), and the adhesive resin layer (C) in this order. Alternatively, the adhesive film 10 of this embodiment may be formed by co-extrusion molding of the adhesive resin layer (B), the base layer (A), and the adhesive resin layer (C) in this order.

[0130] If the adhesive film 10 of this embodiment further comprises an intermediate layer (D), the adhesive film 10 of this embodiment can be formed, for example, the adhesive film 10 shown in Figure 5, by laminating (layering) an adhesive resin layer (B), a base layer (A), an intermediate layer (D), and an adhesive resin layer (C) in this order; by co-extruding an adhesive resin layer (B), a base layer (A), an intermediate layer (D), and an adhesive resin layer (C) in this order; by laminating (layering) the base layer (A) and the intermediate layer (D) and then applying the adhesive resin layer (B) and the adhesive resin layer (C), respectively; or by laminating (layering) the base layer (A) and the intermediate layer (D) and then transferring the adhesive resin layer (B) and the adhesive resin layer (C), respectively, that have been formed on a separator.

[0131] Although embodiments of the present invention have been described above, these are merely examples, and various other configurations can be adopted. Furthermore, the present invention is not limited to the embodiments described above, and modifications, improvements, etc., that do not impair the effects of the present invention are included in the present invention.

[0132] This embodiment will be described in detail below with reference to examples and other relevant information. However, this embodiment is not limited in any way to the descriptions of these examples.

[0133] The details of the materials used to produce the adhesive film are as follows:

[0134] <Adhesive Resin Solution SB1> To deionized pure water, 0.5 parts by mass of 4,4'-azobis-4-cyanovaleric acid (manufactured by Otsuka Chemical Co., Ltd., trade name: ACVA) as a polymerization initiator, 74.3 parts by mass of n-butyl acrylate, 13.7 parts by mass of methyl methacrylate, 9 parts by mass of 2-hydroxyethyl methacrylate, and 3 parts by mass of a polymerizable 1-propenyl group introduced to the benzene ring of the ammonium salt of the sulfate ester of polyoxyethylene nonylphenyl ether (manufactured by Daiichi Kogyo Seiyaku Co., Ltd., trade name: Aqualon HS-1025) were added. Emulsion polymerization was carried out at 70-72°C for 8 hours under stirring to obtain an acrylic resin emulsion. This was neutralized with ammonia water (pH = 7.0) to obtain adhesive resin solution SB1 with a solid content concentration of 42.5%.

[0135] <Adhesive Resin Solution SB2> In deionized pure water, 0.5 parts by mass of ammonium persulfate, 63 parts by mass of 2-ethylhexyl acrylate, 21 parts by mass of n-butyl acrylate, 9 parts by mass of methyl methacrylate, 3 parts by mass of 2-hydroxyethyl methacrylate, 1 part by mass of polytetramethylene glycol diacrylate (manufactured by Nippon Oil & Fats Co., Ltd., trade name: ADT-250), and 2 parts by mass of polyoxyethylene nonylphenyl ether sulfate ammonium salt with a polymerizable 1-propenyl group introduced to the benzene ring (manufactured by Daiichi Kogyo Seiyaku Co., Ltd., trade name: Aqualon HS-1025) were added as polymerization initiators. Emulsification polymerization was carried out at 70-72°C for 8 hours under stirring to obtain an acrylic resin emulsion. This was neutralized with ammonia water (pH = 7.0) to obtain adhesive resin solution SB2 with a solid content concentration of 56.5%.

[0136] <Adhesive Coating Solution B1> Adhesive coating solution B1 was obtained by mixing 57.4 parts by mass of adhesive resin solution SB1, 42.6 parts by mass of adhesive resin solution SB2, 0.4 parts by mass of dimethylethanolamine, and 3.4 parts by mass of an epoxy compound (manufactured by Nagase ChemteX, Ex-1610), which is a crosslinking agent.

[0137] <Adhesive Resin Solution SC1> In a mixed solvent containing ethyl acetate and toluene, 0.536 parts by mass of t-butylperoxy-2-ethylhexanoate (manufactured by Nippon Oil & Fats Co., Ltd., trade name: Perbutyl O (registered trademark)) as a polymerization initiator, 34.9 parts by mass of 2-ethylhexyl acrylate, 41 parts by mass of n-butyl acrylate, 14.7 parts by mass of ethyl acrylate, and 9.4 parts by mass of 2-hydroxyethyl methacrylate were added. Solution polymerization was carried out at 83-87°C for 11 hours under stirring to obtain an acrylic resin solution with a solid content of 45% by mass. This was designated as Adhesive Resin Solution SC1.

[0138] <Adhesive Coating Solution C1> 100 parts by mass of adhesive resin solution SC1 and 0.9 parts by mass of isocyanate-based crosslinking agent (manufactured by Mitsui Chemicals, Inc., product name: Olestar P49-75S) (2 parts by mass per 100 parts by mass of adhesive resin) were mixed, and the solid content concentration was adjusted to 40% with ethyl acetate to obtain adhesive coating solution C1.

[0139] Here, we will explain the thermally expandable microspheres used in the adhesive resin layer (C). The following thermally expandable microspheres were used.

[0140] - Thermally expandable microsphere 1 Thermally expandable microspheres (manufactured by Sekisui Chemical Co., Ltd., product name: Advancell EM-503) were passed through a sieve with a mesh size of 38 μm, and the thermally expandable microspheres that passed through the sieve were collected to obtain thermally expandable microsphere 1. The sphericity R measured according to the method for measuring sphericity below was 0.94. In addition, the volume-based cumulative frequency distribution curve of thermally expandable microsphere 1 was measured according to the method for measuring particle size distribution below. In the volume-based cumulative frequency distribution curve of thermally expandable microsphere 1, the particle size D at the cumulative frequency of 99.9% was ９９．９ The particle size D was 35.3 μm. Furthermore, in the volume-based cumulative frequency distribution curve of the thermally expandable microsphere 1, the particle size D at a cumulative frequency of 50% ５０ It was 15.5 μm.

[0141] (Method for measuring sphericity) Mixture 1 was prepared by adding 50 mL of pure water to 0.2 g of thermally expandable microspheres 1. Next, sample 1 was prepared by dispersing the thermally expandable microspheres 1 in pure water by ultrasonic treatment of mixture 1 for 10 minutes using an ultrasonic cleaning device (product name: AS12GTU, manufactured by AS ONE Corporation).

[0142] Next, sample 1 was placed in a flow-type particle image analyzer (product name: FPIA-3000, manufactured by Sysmex Corporation). By passing sample 1 through the imaging cell of the flow-type particle image analyzer, the thermally expandable microspheres 1 were captured as still images. At this time, the image of the thermally expandable microspheres 1 projected onto a plane was defined as the particle image of the thermally expandable microspheres 1 (hereinafter also referred to as the particle image). In the particle image, the length of the perimeter of the particle was defined as the perimeter of the particle image. Also, in the particle image, the area of ​​the particle was defined as the particle area of ​​the particle image.

[0143] Next, the equivalent circular diameter for the particle image was calculated using the following equation (2): Equation (2): (Equivalent circular diameter) = 2 × {(particle area) / π} １／２ Next, the circularity of the particle image was calculated using the following equation (3): Equation (3): (Circularity) = [2 × {(Particle Area) × π} １／２ ] / (perimeter)

[0144] Finally, particle images were taken of 20,519 randomly selected thermally expandable microspheres 1. For these particle images, the perimeter, particle area, equivalent diameter, and circularity were calculated. Using these calculations, the sphericity R was calculated from equation (1) above.

[0145] (Method for measuring particle size distribution) 0.2 g of thermally expandable microspheres 1 were placed in a 500 mL beaker. Next, 50 mL of pure water and 0.1 mL of surfactant were added to the 500 mL beaker and stirred with a glass rod for 1 minute. The surfactant used was an aqueous solution of Triton X-100 (manufactured by Fujifilm Wako Pure Chemical Industries, Ltd.) diluted 500 times with pure water. Next, sample 2 was prepared by dispersing the thermally expandable microspheres 1 in pure water using an ultrasonic cleaning device (product name: AS12GTU, manufactured by AS ONE Corporation). Next, sample 2 in the 500 mL beaker was placed in a laser diffraction particle size analyzer (product name: Mastersizer, manufactured by Malvern Panalogical). Next, the volume-based cumulative frequency distribution curve of the thermally expandable microspheres 1 by laser diffraction scattering was measured using the laser diffraction particle size analyzer.

[0146] - Thermally expandable microspheres 2 Thermally expandable microspheres (manufactured by Kureha Corporation, product name: S2340D) were passed through a sieve with a mesh size of 38 μm, and the thermally expandable microspheres that passed through the sieve were collected to obtain thermally expandable microspheres 2. The sphericity R, measured in the same manner as described above (method for measuring sphericity), was 0.95.

[0147] - Thermally expandable microsphere 3 Thermally expandable microsphere 3 was defined as a thermally expandable microsphere (manufactured by Sekisui Chemical Co., Ltd., product name: Advancell EM-503) that had not undergone any processing. The sphericity R measured in the same manner as above (method for measuring sphericity) was 0.90. In addition, the volume-based cumulative frequency distribution curve of thermally expandable microsphere 3 was measured in the same manner as above (method for measuring particle size distribution). In the volume-based cumulative frequency distribution curve of thermally expandable microsphere 3, the particle size D at which the cumulative frequency reached 99.9% was ９９．９ The particle size D was 40.8 μm. Furthermore, in the volume-based cumulative frequency distribution curve of the thermally expandable microsphere 3, the particle size D at a cumulative frequency of 50% ５０ It was 16.2 μm.

[0148] - Thermally expandable microspheres 4 Thermally expandable microspheres 4 were obtained by passing thermally expandable microspheres (manufactured by Sekisui Chemical Co., Ltd., product name: Advancell EM-503) through a sieve with a mesh size of 100 μm and collecting the thermally expandable microspheres that passed through the sieve. The sphericity R, measured in the same manner as described above (method for measuring sphericity), was 0.92. In addition, the volume-based cumulative frequency distribution curve of thermally expandable microspheres 4 was measured in the same manner as described above (method for measuring particle size distribution). In the volume-based cumulative frequency distribution curve of thermally expandable microspheres 4, the particle size D at the cumulative frequency of 99.9% was ９９．９ The particle size D was 35.4 μm. Furthermore, in the volume-based cumulative frequency distribution curve of the thermally expandable microsphere 4, the particle size D at which the cumulative frequency reached 50% was... ５０ It was 15.3 μm.

[0149] - Thermally expandable microspheres 5 Thermally expandable microspheres 5 were obtained by passing thermally expandable microspheres (manufactured by Matsumoto Oil & Fat Pharmaceutical Co., Ltd., product name: FN180S) through a sieve with a mesh size of 50 μm and collecting the thermally expandable microspheres that passed through the sieve. The sphericity R, measured in the same manner as described above (method for measuring sphericity), was 0.88. In addition, the volume-based cumulative frequency distribution curve of thermally expandable microspheres 5 was measured in the same manner as described above (method for measuring particle size distribution). In the volume-based cumulative frequency distribution curve of thermally expandable microspheres 5, the particle size D at the cumulative frequency of 99.9% was ９９．９ The particle size D was 35.3 μm. Furthermore, in the volume-based cumulative frequency distribution curve of the thermally expandable microsphere 5, the particle size D at which the cumulative frequency reached 50% was...５０ It was 15.4 μm.

[0150] <Adhesive Coating Solution C2> Adhesive coating solution C2 was prepared by mixing 100 parts by mass of adhesive resin solution SC1, 2.25 parts by mass of polymerized rosin ester tackifier (manufactured by Arakawa Chemical Industries, Ltd., trade name: Pencel D-125) (5 parts by mass per 100 parts by mass of adhesive resin), 1.2 parts by mass of isocyanate crosslinking agent (manufactured by Mitsui Chemicals, Inc., trade name: Olestar P49-75S) (2.67 parts by mass per 100 parts by mass of adhesive resin), and 6.75 parts by mass of thermally expandable microspheres 1 (15 parts by mass per 100 parts by mass of adhesive resin), and adjusting the solid content concentration to 30% with ethyl acetate.

[0151] <Adhesive Coating Solution C3> Adhesive coating solution C3 was prepared by mixing 100 parts by mass of adhesive resin solution SC1, 2.25 parts by mass of polymerized rosin ester tackifier (manufactured by Arakawa Chemical Industries, Ltd., trade name: Pencel D-125) (5 parts by mass per 100 parts by mass of adhesive resin), 1.2 parts by mass of isocyanate crosslinking agent (manufactured by Mitsui Chemicals, Inc., trade name: Olestar P49-75S) (2.67 parts by mass per 100 parts by mass of adhesive resin), and 6.75 parts by mass of thermally expandable microspheres 2 (15 parts by mass per 100 parts by mass of adhesive resin), and adjusting the solid content concentration to 30% with ethyl acetate.

[0152] <Adhesive Coating Solution C4> Adhesive coating solution C4 was prepared by mixing 100 parts by mass of adhesive resin solution SC1, 2.25 parts by mass of polymerized rosin ester tackifier (manufactured by Arakawa Chemical Industries, Ltd., trade name: Pencel D-125) (5 parts by mass per 100 parts by mass of adhesive resin), 1.2 parts by mass of isocyanate crosslinking agent (manufactured by Mitsui Chemicals, Inc., trade name: Olestar P49-75S) (2.67 parts by mass per 100 parts by mass of adhesive resin), and 6.75 parts by mass of thermally expandable microspheres 3 (15 parts by mass per 100 parts by mass of adhesive resin), and adjusting the solid content concentration to 30% with ethyl acetate.

[0153] <Adhesive Coating Solution C5> Adhesive coating solution C5 was prepared by mixing 100 parts by mass of adhesive resin solution SC1, 2.25 parts by mass of polymerized rosin ester tackifier (manufactured by Arakawa Chemical Industries, Ltd., trade name: Pencel D-125) (5 parts by mass per 100 parts by mass of adhesive resin), 1.2 parts by mass of isocyanate crosslinking agent (manufactured by Mitsui Chemicals, Inc., trade name: Olestar P49-75S) (2.67 parts by mass per 100 parts by mass of adhesive resin), and 6.75 parts by mass of thermally expandable microspheres 4 (15 parts by mass per 100 parts by mass of adhesive resin), and adjusting the solid content concentration to 30% with ethyl acetate.

[0154] <Adhesive Coating Solution C6> Adhesive coating solution C6 was prepared by mixing 100 parts by mass of adhesive resin solution SC1, 2.25 parts by mass of polymerized rosin ester tackifier (manufactured by Arakawa Chemical Industries, Ltd., product name: Pencel D-125) (5 parts by mass per 100 parts by mass of adhesive resin), 1.2 parts by mass of isocyanate crosslinking agent (manufactured by Mitsui Chemicals, Inc., product name: Olestar P49-75S) (2.67 parts by mass per 100 parts by mass of adhesive resin), and 6.75 parts by mass of thermally expandable microspheres 5 (15 parts by mass per 100 parts by mass of adhesive resin), and adjusting the solid content concentration to 30% with ethyl acetate.

[0155] [Example 1] A polyethylene terephthalate (PET) film (38 μm thick), which is a base layer (A), was covered with a 10 μm thick adhesive resin layer (B) formed by drying adhesive coating liquid B1. Next, a 20 μm thick intermediate layer (D) formed by drying adhesive coating liquid C1 was applied to the surface of the PET film opposite to the adhesive resin layer (B), and a 30 μm thick heat-peelable adhesive resin layer (C) formed by drying adhesive coating liquid C2 was applied on top of that to obtain an adhesive film.

[0156] [Example 2] A polyethylene terephthalate (PET) film (38 μm thick), which is the base layer (A), was covered with a 10 μm thick adhesive resin layer (B) formed by drying adhesive coating liquid B1. Next, a 20 μm thick intermediate layer (D) formed by drying adhesive coating liquid C1 was applied to the surface of the PET film opposite to the adhesive resin layer (B), and a 30 μm thick heat-peelable adhesive resin layer (C) formed by drying adhesive coating liquid C3 was applied on top of that to obtain an adhesive film.

[0157] [Comparative Example 1] A polyethylene terephthalate (PET) film (38 μm thick), which is a base layer (A), was provided with a 10 μm thick adhesive resin layer (B) formed by drying adhesive coating liquid B1. Next, a 20 μm thick intermediate layer (D) formed by drying adhesive coating liquid C1 was provided on the surface of the PET film opposite to the adhesive resin layer (B), and a 30 μm thick heat-peelable adhesive resin layer (C) formed by drying adhesive coating liquid C4 was provided on top of that to obtain an adhesive film.

[0158] [Comparative Example 2] A polyethylene terephthalate (PET) film (38 μm thick), which is a base layer (A), was provided with a 10 μm thick adhesive resin layer (B) formed by drying adhesive coating liquid B1. Next, a 20 μm thick intermediate layer (D) formed by drying adhesive coating liquid C1 was provided on the surface of the PET film opposite to the adhesive resin layer (B), and a 30 μm thick heat-peelable adhesive resin layer (C) formed by drying adhesive coating liquid C5 was provided on top of that to obtain an adhesive film.

[0159] [Comparative Example 3] A polyethylene terephthalate (PET) film (38 μm thick), which is a base layer (A), was provided with a 10 μm thick adhesive resin layer (B) formed by drying adhesive coating liquid B1. Next, a 20 μm thick intermediate layer (D) formed by drying adhesive coating liquid C1 was provided on the surface of the PET film opposite to the adhesive resin layer (B), and a 30 μm thick heat-peelable adhesive resin layer (C) formed by drying adhesive coating liquid C6 was provided on top of that to obtain an adhesive film.

[0160] (Examples 1-2, Comparative Examples 1-3) The physical properties of the adhesive films in each example were measured by the following method. The measurement results are shown in Table 1.

[0161] <Method for Evaluating Chip Dislodgement> The following operations were performed using the adhesive film of each example. The adhesive resin layer (C) side of the adhesive film was attached to a circular SUS substrate (material: SUS304) with a diameter of 320 mm and a thickness of 1.5 mm. Next, 1300 electronic components (4.7 mm x 3.9 mm chips) were placed on the adhesive resin layer (B) of the adhesive film and pressed firmly to obtain structure 1. Then, structure 1 was heated at 130°C for 30 minutes. Next, using a compression molding machine, the chips on the adhesive resin layer (B) were compressed and sealed using a liquid epoxy resin-based encapsulant (manufactured by Sumitomo Bakelite Co., Ltd., product name: G730) at 125°C for 500 seconds, and then heated at 150°C for 1 hour (post-mold cure). This obtained structure 2 in which the electronic components were sealed with epoxy resin. Next, structure 3 was obtained by debonding the support substrate from structure 2 by heating structure 2 at 190°C for 60 seconds. In this specification, debonding means peeling the object (in this case, the support substrate) from the adhesive film by reducing the adhesive strength of the adhesive resin layer (C) of the adhesive film through heat treatment. Next, structure 4 was obtained by peeling the adhesive film from structure 3 at an angle of 180° while heated to 100°C. Next, the presence or absence of chip breakage was observed visually for structure 4. This evaluation was performed under the condition of a sample size n=2. The average value for each sample was taken as the number of chip breakages. If the number of chip breakages was less than 5, it was evaluated as A; if it was 5 or more but less than 20, it was evaluated as B; and if it was 20 or more, it was evaluated as C.

[0162] <Method for Evaluating Epoxy Resin Indentations> The following procedure was performed using the adhesive film of each example. For structure 4 obtained in the <Method for Evaluating Chip Dislodgement> above, the presence or absence of epoxy resin indentations was observed visually by observing the surface of the epoxy resin that was in contact with the adhesive film. This evaluation was performed under the condition of a sample size n=2. The average value for each sample was taken as the number of epoxy resin indentations. If the number of epoxy resin indentations was less than 5, it was evaluated as A; if it was 5 or more but less than 20, it was evaluated as B; and if it was 20 or more, it was evaluated as C.

[0163] This application claims priority based on Japanese Patent Application No. 2024-168464, filed on 27 September 2024, and incorporates all of its disclosures herein.

[0164] 10 Adhesive film 20 Object to be processed 24 Electronic component 30 Support member 31 Support substrate 40 Object to be processed after processing 50 Encapsulating material 100 Structure 400 Structure 500 Electronic device 510 Wiring layer 520 Bump 600 Electronic device A Base material layer A1 First surface A2 Second surface B Adhesive resin layer C Adhesive resin layer D Intermediate layer

Claims

1. A method for manufacturing an electronic device, comprising the steps of: preparing a structure including an adhesive film comprising a base layer (A), an adhesive resin layer (B), and an adhesive resin layer (C); a workpiece temporarily fixed to the adhesive resin layer (B); and a support member temporarily fixed to the adhesive resin layer (C); and processing the workpiece temporarily fixed to the adhesive resin layer (B), wherein the base layer (A) is located between the adhesive resin layer (B) and the adhesive resin layer (C), the adhesive resin layer (C) contains thermally expandable microspheres, and the sphericity R of the thermally expandable microspheres, calculated by the following formula (1), is 0.93 or greater. (In formula (1) above, n represents the total number of thermally expandable microspheres, i represents an integer between 1 and n, X ｉ represents the equivalent circular diameter of the i-th thermally expandable microsphere, Y ｉ (This indicates the circularity of the i-th thermally expandable microsphere.) 2. In the volume-based cumulative frequency distribution curve of the thermally expandable microspheres measured by a laser diffraction scattering particle size distribution analyzer, the particle size D at which the cumulative frequency reaches 50% ５０ A method for manufacturing an electronic device according to claim 1, wherein the particle size is 1 μm or more and 30 μm or less.

3. In the volume-based cumulative frequency distribution curve of the thermally expandable microspheres, measured by a laser diffraction scattering particle size distribution analyzer, the particle size D at the cumulative frequency of 99.9% is... ９９．９ A method for manufacturing an electronic device according to claim 1 or 2, wherein the thickness is 10 μm or more and 50 μm or less.

4. The method for manufacturing an electronic device according to any one of claims 1 to 3, wherein the foaming temperature of the thermally expandable microspheres is 160°C or higher.

5. The method for manufacturing an electronic device according to any one of claims 1 to 4, wherein the adhesive resin layer (C) is a layer whose adhesive strength decreases when heated.

6. The method for manufacturing an electronic device according to any one of claims 1 to 5, wherein the adhesive resin layer (C) comprises one or more selected from the group consisting of (meth)acrylic adhesive resins, silicone adhesive resins, urethane adhesive resins, olefin adhesive resins, and styrene adhesive resins.

7. A method for manufacturing an electronic device according to any one of claims 1 to 6, wherein the content of the thermally expandable microspheres in the adhesive resin layer (C) is 5% by mass or more and 50% by mass or less when the total amount of the adhesive resin layer (C) is 100% by mass.

8. The method for manufacturing an electronic device according to any one of claims 1 to 7, wherein the substrate layer (A) comprises one or more selected from the group consisting of polypropylene, polyethylene terephthalate, polyethylene naphthalate, polyamide, polyimide, and polyetheretherketone.

9. The method for manufacturing an electronic device according to any one of claims 1 to 8, wherein the thickness of the adhesive resin layer (C) is 10 μm or more and 100 μm or less.

10. The method for manufacturing an electronic device according to any one of claims 1 to 9, wherein the thickness of the adhesive resin layer (B) is 1 μm or more and 40 μm or less.

11. A method for manufacturing an electronic device according to any one of claims 1 to 10, further comprising an intermediate layer (D) between the base material layer (A) and the adhesive resin layer (B), and at least one between the base material layer (A) and the adhesive resin layer (C).

12. The method for manufacturing an electronic device according to claim 11, wherein the thickness of the intermediate layer (D) is 5 μm or more and 100 μm or less.

13. A method for manufacturing an electronic device according to any one of claims 1 to 12, wherein the electronic device includes a semiconductor package.

14. The method for manufacturing an electronic device according to claim 13, wherein the semiconductor package includes a fan-out type package.

Images