Alcohol effect dispelling and liver protecting functional water with high-concentration stable hydrogen molecules and preparation process of functional water

Abstract

The invention provides a high-concentration stable hydrogen molecule hangover-alleviating and liver-protecting functional water and a preparation process thereof, and the preparation process comprises the following steps: S1, preparing a fermentation liquid: selecting roots, stems, leaves and fruits of hydrogen-rich plants as raw materials, cleaning, sterilizing and disinfecting, crushing, sieving with a 10-30-mesh sieve, adding water, mixing, and filtering to obtain the fermentation liquid; fermenting for 12-48 hours to obtain fermentation liquor, filtering, collecting gas, and carrying out gas separation to obtain hydrogen for later use; s2, hydrogen-water mixing: hydrogen and water are stirred and mixed under the action of ultrasonic waves, the mixing time is 15-45 min, and hydrogen-rich water is obtained; s3, preparing micro-nano bubbles: filling the hydrogen-rich water into a high-speed shearing machine, applying a magnetic field to the hydrogen-rich water to magnetize the hydrogen-rich water, and shearing the hydrogen-rich water at a high speed by using magnetic force to obtain the high-concentration micromolecular bubble hydrogen-rich water. The alcohol effect dispelling and liver protecting functional water with the high-concentration stable hydrogen molecules and the preparation process of the alcohol effect dispelling and liver protecting functional water have the advantages of being high in concentration, small in bubble particle size, low in oxidation-reduction potential and long in dissolution time.

Description

Technical Field

[0001] The present invention relates to the technical field of hydrogen-rich water preparation technology, and in particular to alcohol-resolving and liver-protecting functional water with high-concentration stable hydrogen molecules and a preparation process thereof. Background Art

[0002] Hydrogen-rich water contains a certain concentration of hydrogen. The hydrogen molecules contained in it can activate the activity of acetaldehyde dehydrogenase, quickly convert the toxic metabolite acetaldehyde into acetic acid and water, reduce blood alcohol concentration, selectively remove hydroxyl free radicals produced by alcohol metabolism, and reduce liver oxidative damage.

[0003] Hydrogen-rich water produced from hydrogen-producing materials usually uses metallic magnesium as a raw material, and is made into a rod-shaped structure with a certain shape and size through a specific process. During use, the hydrogen rod is placed in water, and the metallic magnesium reacts with the water to generate hydrogen and magnesium hydroxide, and the hydrogen dissolves in the water to form hydrogen-rich water. However, the magnesium particles in the hydrogen rod are easily oxidized. As the number of uses increases, the hydrogen production effect decreases, and a certain amount of magnesium ions are released into the water. If consumed, it will also have a certain impact on human health. Therefore, the hydrogen rod needs to be cleaned regularly to avoid bacterial growth and ensure the safety and hygiene of the water quality. The hydrogen content of hydrogen produced by hydrogen rods is affected by many factors, including the number of uses, the sealing condition of the container, the reaction time, etc. These factors need to be controlled to ensure the stability and enrichment of the hydrogen content; however, how to prepare hydrogen-rich water at room temperature and pressure and maintain a certain concentration and increase the dissolution time is still a problem that needs to be solved. Summary of the Invention

[0004] To solve the above technical problems, the present invention provides the following technical solution: a functional water for detoxifying and protecting the liver with high concentration of stable hydrogen molecules and a preparation process thereof, comprising the following steps:

[0005] S1. Preparation of fermentation liquid: Roots, stems, leaves, and fruits of hydrogen-rich plants are selected as raw materials, cleaned and sterilized, crushed through a 10-30 mesh sieve, added with water and mixed, fermented for 12-48 hours to obtain fermentation liquid, filtered, and gas is collected for gas separation to obtain hydrogen for later use;

[0006] S2. Mixing hydrogen water: Stirring hydrogen gas and water separately under the action of ultrasound for 15-45 minutes to obtain hydrogen-rich water;

[0007] S3. Preparation of micro-nano bubbles: The hydrogen-rich water is charged into a high-speed shearing machine, and a magnetic field is applied to the machine to magnetize the hydrogen-rich water. The hydrogen-rich water is sheared at high speed by magnetic force to obtain high-concentration small molecule bubble hydrogen-rich water.

[0008] Preferably, the hydrogen-rich plants are Perilla frutescens, Vallisneria aquaticum, Myriophyllum, Polygonum hydropiper, and Water chestnut.

[0009] Preferably, in step S1, the mass volume ratio of powder to water g / mL is 8-12:20.

[0010] Preferably, the fermentation conditions in step S1 are a temperature of 30-40° C., a pH of 5-7, and an illumination of 100-200 lux.

[0011] Preferably, the amount of hydrogen introduced in step S2 is 0.2-0.5 m3 / s.

[0012] Preferably, the water introduction rate in step S2 is 5-10 L / s.

[0013] Preferably, the ultrasonic treatment time in step S2 is 200-480 minutes, and the ultrasonic power is 20-100 KHz.

[0014] Preferably, in step S3, the high-speed shear rate is 800-1500 rpm, the shearing times are 2-5 times, and each shearing time is 10-30 minutes.

[0015] Preferably, the magnetic field strength in step S3 is 3500-5000 GS.

[0016] Compared with the prior art, the present invention has the following beneficial effects:

[0017] This alcohol-detoxifying and liver-protecting functional water with high-concentration stable hydrogen molecules and its preparation process have high concentration and small bubble particle size, low redox potential, long dissolution time, and can effectively scavenge DPPH free radicals, ·OH free radicals, and ·O2- free radicals. The scavenging capacity of DPPH free radicals is 95.2-98.8%, the scavenging capacity of ·OH free radicals is 98.1-99.7%, and the scavenging capacity of ·O2- free radicals is 90.3-98.9%. The hydrogen molecules in the hydrogen-rich water can activate the activity of acetaldehyde dehydrogenase, quickly converting the toxic metabolite acetaldehyde into acetic acid and water, reducing blood alcohol concentration, selectively scavenging hydroxyl free radicals (·OH) produced by alcohol metabolism, reducing liver oxidative damage, reducing liver lipid deposition, and alleviating alcohol-induced steatosis.

[0018] The present invention adopts a fermentation method to produce hydrogen, which has high purity and strong reducing ability; hydrogen and water are stirred and mixed separately under the action of ultrasound, and the hydrogen and water are mixed vigorously multiple times to make the mixing of hydrogen and water more complete, and the high pressure state during the mixing process can make water molecules lock hydrogen, thereby increasing the amount of hydrogen dissolved in water and improving the hydrogen content in water. The hydrogen-rich water is treated with micro-nano bubble technology, which can greatly promote the solubility of hydrogen and make it dissolve quickly. Using hydrogen-rich water to prepare micro-nano bubbles can promote the solubility of hydrogen and make it dissolve quickly; applying a magnetic field during the high-speed shear process disperses the gas into micro-nano-scale bubbles, improving the uniformity and stability of the bubbles, and effectively controlling the size and distribution of the bubbles, thereby better controlling the properties and performance of the hydrogen-rich water.

[0019] Other features and advantages of the present application will be described in the following description, and in part will become apparent from the description, or will be understood by practicing the present application. The purpose and other advantages of the present application can be realized and obtained by the structures specifically pointed out in the written description.

[0020] The technical solution of the present application is further described in detail below through examples. DETAILED DESCRIPTION

[0021] In order to better understand the technical content of the present invention, specific examples are provided below to further illustrate the present invention.

[0022] Unless otherwise specified, the experimental methods used in the examples of the present invention are all conventional methods.

[0023] Unless otherwise specified, the materials, reagents, etc. used in the examples of the present invention can be obtained from commercial sources.

[0024] Example 1

[0025] A functional water for detoxifying and protecting the liver with high concentration of stable hydrogen molecules and a preparation process thereof, comprising the following steps:

[0026] S1. Preparation of fermentation liquid: Roots, stems, leaves, and fruits of hydrogen-rich plants are selected as raw materials, cleaned and sterilized, crushed through a 10-30 mesh sieve, added with water and mixed, fermented for 12-48 hours to obtain fermentation liquid, filtered, and gas is collected for gas separation to obtain hydrogen for later use;

[0027] S2. Mixing hydrogen water: Stirring hydrogen gas and water separately under the action of ultrasound for 15-45 minutes to obtain hydrogen-rich water;

[0028] S3. Preparation of micro-nano bubbles: The hydrogen-rich water is charged into a high-speed shearing machine, and a magnetic field is applied to the machine to magnetize the hydrogen-rich water. The hydrogen-rich water is sheared at high speed by magnetic force to obtain high-concentration small molecule bubble hydrogen-rich water.

[0029] Example 2

[0030] A method for preparing high-concentration small-molecule bubble hydrogen-rich water comprises the following steps:

[0031] S1. Preparation of fermentation broth: The roots, stems, and leaves of Perilla frutescens were selected as raw materials, cleaned and sterilized, crushed through a 30-mesh sieve, and mixed with water to obtain a powder-to-water mass volume ratio of 12:20 g / mL. The fermentation was carried out at 40°C, pH 7, and 200 lux of light for 12-48 h to obtain a fermentation broth, which was filtered and the gas was collected for gas separation to obtain hydrogen for later use;

[0032] S2. Mixing hydrogen water: Stir and mix hydrogen and water separately under the action of ultrasound. The ultrasonic power is 100KHz, the ultrasound is continued for 480 minutes, the hydrogen introduction rate is 0.5m3 / s, the water introduction rate is 10L / s, and the mixing time is 45 minutes to obtain hydrogen-rich water.

[0033] S3. Preparation of micro-nano bubbles: The above hydrogen-rich water is charged into a high-speed shearing machine with a high-speed shear rate of 1500 rpm, 5 shearing times, and each shearing for 30 minutes. At the same time, a magnetic field is applied to magnetize the hydrogen-rich water with a magnetic field strength of 5000 GS. The magnetic force is used to perform high-speed shearing on the hydrogen-rich water to obtain high-concentration small molecule bubble hydrogen-rich water.

[0034] Example 3

[0035] A method for preparing high-concentration small-molecule bubble hydrogen-rich water comprises the following steps:

[0036] S1. Preparation of fermentation broth: The roots, stems, and leaves of Perilla frutescens were selected as raw materials, cleaned and sterilized, crushed through a 20-mesh sieve, and mixed with water to obtain a powder-to-water mass volume ratio of 10:20 (g / mL). The fermentation was carried out at 35°C, pH 5-7, and 150 lux illumination for 24 h to obtain a fermentation broth, which was filtered and the gas was collected for gas separation to obtain hydrogen for later use;

[0037] S2. Mixing hydrogen water: Stir and mix hydrogen and water separately under the action of ultrasound. The ultrasonic power is 60KHz, the ultrasound is carried out for 350 minutes, the hydrogen introduction rate is 0.3m3 / s, the water introduction rate is 8L / s, and the mixing time is 30min to obtain hydrogen-rich water.

[0038] S3. Preparation of micro-nano bubbles: The above hydrogen-rich water is charged into a high-speed shearing machine with a high-speed shear rate of 1200 rpm, 3 shearing times, and each shearing for 20 minutes. At the same time, a magnetic field is applied to magnetize the hydrogen-rich water with a magnetic field strength of 4200 GS. The magnetic force is used to perform high-speed shearing on the hydrogen-rich water to obtain high-concentration small molecule bubble hydrogen-rich water.

[0039] Example 4

[0040] The difference between this embodiment and embodiment 3 is that the ultrasonic treatment time in step S2 is 120 minutes and the ultrasonic power is 10 KHz.

[0041] Example 5

[0042] The difference between this embodiment and embodiment 3 is that the high-speed shear rate in step S3 is 2000 rpm.

[0043] Comparative Example 1

[0044] The difference between this comparative example and Example 3 is that no fermentation liquid is used to produce hydrogen, and the hydrogen is selected from the hydrogen in the electrolyte.

[0045] Comparative Example 2

[0046] The difference between this comparative example and Example 3 is that the micro-nano bubbles in step S3 are not performed.

[0047] Comparative Example 3

[0048] The difference between this comparative example and Example 3 is that no magnetic field is applied to assist the high-speed shearing process in step S3.

[0049] The hydrogen-rich water prepared by the present invention has a high concentration and a small bubble particle size, with a concentration range of 1657-1850ppb, a bubble particle size of 282.6-310.9nm, and an oxidation-reduction potential of -481 to -520mV. The small particle size can exist in water for a long time, all for more than 72 hours, and the dissolution time reaches 83 hours.

[0050] Compared with the comparative example 1, the present invention has higher purity and stronger reducing ability by selecting hydrogen-rich plants for fermentation;

[0051] Compared with Comparative Example 2, the embodiment group treated the hydrogen-rich water with micro-nano bubble technology. The hydrogen bubbles had a large surface area, a slow rising speed in the water, and were charged on the bubble surface. The bubbles also had good stability and a long lifespan, thus greatly promoting the solubility of hydrogen and causing it to dissolve quickly.

[0052] Compared with Comparative Example 3, the embodiment group applies a magnetic field during the high-speed shear process. The intensity and direction of the magnetic field can achieve all-round shearing of hydrogen-rich water to different degrees and modes, disperse the gas into micro-nano-scale bubbles, improve the uniformity and stability of the bubbles, and effectively control the size and distribution of the bubbles, thereby better controlling the properties and performance of the hydrogen-rich water.

[0053] It is important to note that the construction and arrangement of the present application shown in a number of different exemplary embodiments are merely illustrative. Although only a few embodiments are described in detail in this disclosure, it should be readily understood by those who refer to this disclosure that many modifications are possible (e.g., the size, scale, structure, shape, and proportion of various elements, as well as parameter values ​​(e.g., temperature, pressure, etc.), mounting arrangements, use of materials, color, changes in orientation, etc.) without departing substantially from the novel teachings and advantages of the subject matter described in this application. For example, an element shown as integrally formed may be composed of multiple parts or elements, the position of the element may be inverted or otherwise changed, and the nature, number, or position of the discrete elements may be altered or changed. Therefore, all such modifications are intended to be included within the scope of the present invention. The order or sequence of any process or method steps may be changed or reordered according to alternative embodiments. In the claims, any "means plus function" clause is intended to cover the structure described herein that performs the function, and is not only structurally equivalent but also equivalent structures. Other replacements, modifications, changes, and omissions may be made in the design, operating conditions, and arrangement of the exemplary embodiments without departing from the scope of the present invention. Therefore, the invention is not limited to the specific embodiments, but extends to various modifications that still fall within the scope of the appended claims.

[0054] Additionally, in order to provide a concise description of exemplary embodiments, all features of an actual embodiment (i.e., those features that are not relevant to the best mode presently contemplated for carrying out the invention or those that are not relevant to implementing the invention) may not be described.

[0055] It will be appreciated that in the development of any actual embodiment, as in any engineering or design project, numerous implementation-specific decisions may be made. Such a development effort may be complex and time-consuming, but will, for those of ordinary skill having the benefit of this disclosure, be a routine undertaking of design, fabrication, and production without undue experimentation.

[0056] It should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention and are not intended to limit the present invention. Although the present invention has been described in detail with reference to the preferred embodiments, those skilled in the art should understand that the technical solutions of the present invention may be modified or replaced by equivalents without departing from the spirit and scope of the technical solutions of the present invention, which should all be included in the scope of the claims of the present invention.

Claims

1. A functional water for detoxifying and protecting liver with high concentration of stable hydrogen molecules and its preparation process, characterized in that: The following steps are involved: S1. Preparation of fermentation liquid: Roots, stems, leaves, and fruits of hydrogen-rich plants are selected as raw materials, cleaned and sterilized, crushed through a 10-30 mesh sieve, added with water and mixed, fermented for 12-48 hours to obtain fermentation liquid, filtered, and gas is collected for gas separation to obtain hydrogen for later use; S2. Mixing hydrogen water: Stirring hydrogen gas and water separately under the action of ultrasound for 15-45 minutes to obtain hydrogen-rich water; S3. Preparation of micro-nano bubbles: The hydrogen-rich water is charged into a high-speed shearing machine, and a magnetic field is applied to the machine to magnetize the hydrogen-rich water. The hydrogen-rich water is sheared at high speed by magnetic force to obtain high-concentration small molecule bubble hydrogen-rich water.

2. The alcohol-detoxifying and liver-protecting functional water with high concentration of stable hydrogen molecules and its preparation process according to claim 1 is characterized in that: The hydrogen-rich plants are perilla, aquatic Vallisneria, foxtail algae, Polygonum hydropiper, and water chestnut.

3. The alcohol-detoxifying and liver-protecting functional water with high concentration of stable hydrogen molecules and its preparation process according to claim 1 is characterized in that: The mass volume ratio of the powder to water in step S1 is g / mL 8-12:

20.

4. The alcohol-detoxifying and liver-protecting functional water with high concentration of stable hydrogen molecules and its preparation process according to claim 1, characterized in that: The fermentation conditions in step S1 are a temperature of 30-40° C., a pH of 5-7, and an illumination of 100-200 lux.

5. The alcohol-detoxifying and liver-protecting functional water with high concentration of stable hydrogen molecules and its preparation process according to claim 1, characterized in that: The amount of hydrogen introduced in step S2 is 0.2-0.5 m3 / s.

6. The alcohol-detoxifying and liver-protecting functional water with high concentration of stable hydrogen molecules and its preparation process according to claim 1, characterized in that: The amount of water introduced in step S2 is 5-10 L / s.

7. The alcohol-detoxifying and liver-protecting functional water with high concentration of stable hydrogen molecules and its preparation process according to claim 1, characterized in that: In step S2, the ultrasonic treatment time is 200-480 minutes, and the ultrasonic power is 20-100 KHz.

8. The alcohol-detoxifying and liver-protecting functional water with high concentration of stable hydrogen molecules and its preparation process according to claim 1, characterized in that: In step S3, the high-speed shearing rate is 800-1500 rpm, the shearing times are 2-5 times, and each shearing time is 10-30 minutes.

9. The alcohol-detoxifying and liver-protecting functional water with high concentration of stable hydrogen molecules and its preparation process according to claim 1, characterized in that: The magnetic field strength in step S3 is 3500-5000 GS.